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At least 271 records · Page 15Linked to original sources

USGS1996

A digital photogrammetric method for measuring horizontal surficial movements on the slumgullion earthflow, Hinsdale county, Colorado

The traditional approach to making aerial photographic measurements uses analog or analytic photogrammetric equipment. We have developed a digital method for making measurements from aerial photographs which uses geographic information system (GIS) software, and primarily DOS-based personal computers. This method, which is based on the concept that a direct visual comparison can be made between images derived from two sets of aerial photographs taken at different times, was applied to the surface of the active portion of the Slumgullion earthflow in Colorado to determine horizontal displacement vectors from the movements of visually identifiable objects, such as trees and large rocks. Using this method, more of the slide surface can be mapped in a shorter period of time than using the standard photogrammetric approach. More than 800 horizontal displacement vectors were determined on the active earthflow surface using images produced by our digital photogrammetric technique and 1985 (1:12,000-scale) and 1990 (1:6,000-scale) aerial photographs. The resulting displacement field shows, with a 2-m measurement error (??? 10%), that the fastest moving portion of the landslide underwent 15-29 m of horizontal displacement between 1985 and 1990. Copyright ?? 1996 Elsevier Science Ltd.

Computers & Geosciences↗

USGS2009

Factors influencing coastal cutthroat trout (Oncorhynchus clarkii clarkii) seasonal survival rates: A spatially continuous approach within stream networks

Mark-recapture methods were used to examine watershed-scale survival of coastal cutthroat trout (Oncorhynchus clarkii clarkii) from two headwater stream networks. A total of 1725 individuals (???100 mm, fork length) were individually marked and monitored seasonally over a 3-year period. Differences in survival were compared among spatial (stream segment, subwatershed, and watershed) and temporal (season and year) analytical scales, and the effects of abiotic (discharge, temperature, and cover) and biotic (length, growth, condition, density, movement, and relative fish abundance) factors were evaluated. Seasonal survival was consistently lowest and least variable (years combined) during autumn (16 September - 15 December), and evidence suggested that survival was negatively associated with periods of low stream discharge. In addition, relatively low (-) and high (+) water temperatures, fish length (-), and boulder cover (+) were weakly associated with survival. Seasonal abiotic conditions affected the adult cutthroat trout population in these watersheds, and low-discharge periods (e.g., autumn) were annual survival bottlenecks. Results emphasize the importance of watershed-scale processes to the understanding of population-level survival.

Canadian Journal of Fisheries and Aquatic Sciences↗

USGS2020

Estimation of nonlinear water-quality trends in high-frequency monitoring data

Recent advances in high-frequency water-quality sensors have enabled direct measurements of physical and chemical attributes in rivers and streams nearly continuously. Water-quality trends can be used to identify important watershed-scale changes driven by natural and anthropogenic influences. Statistical methods to estimate trends using high-frequency data are lacking. To address this gap, an evaluation of the generalized additive model (GAM) approach to test for trends in high-frequency data was conducted. Our proposed framework includes methods for handling serial correlation, trend estimation and slope-change detection, and trend interpretation at arithmetic scale for log-transformed variables. Water-temperature and turbidity data, representing two analytes with different temporal patterns, collected from the James River at Cartersville, Virginia, USA, were chosen for this analysis. Results indicated that the model, including flow, season, time covariates, and interaction between flow and season performed well for both analytes. The same model structure was applied to specific conductance data, collected from a small highly urbanized watershed, with satisfactory model performance. The water temperature GAM results indicated that the significant decreasing-then-increasing patterns after 2012 were mainly driven by air temperature changes. The turbidity trend was not significant over time. The specific conductance results showed a consistently upward trend over the last decade due to ever-increasing urbanization in the small watershed. This study suggests that the GAM method has great potential as a useful tool for trend analysis on high-frequency data, and for informing watershed managers of hydro-climatic and human influences on water quality by detecting crucial signal variation over time.

Chesapeake Bay watershed↗

USGS2019

The tangled tale of Kīlauea’s 2018 eruption as told by geochemical monitoring

Changes in magma chemistry that affect eruptive behavior occur during many volcanic eruptions, but typical analytical techniques are too slow to contribute to hazard monitoring. We used rapid energy-dispersive X-ray fluorescence analysis to measure diagnostic elements in lava samples within a few hours of collection during the 2018 Kīlauea eruption. The geochemical data provided important information for field crews and civil authorities in advance of changing hazards during the eruption. The appearance of hotter magma was recognized several days before the onset of voluminous eruptions of fast-moving flows that destroyed hundreds of homes. We identified, in near-real time, interactions between older, colder, stored magma – including the unexpected eruption of andesite – and hotter magma delivered during dike emplacement.

Hawaii↗

USGS2023

Centurial persistence of forever chemicals at military fire training sites

Drinking water contamination by per- and polyfluoroalkyl substances (PFAS) is widespread near more than 300 United States (U.S.) military bases that used aqueous film-forming foams (AFFF) for fire training and firefighting activities. Much of the PFAS at these sites consist of precursors that can transform into terminal compounds of known health concern but are omitted from standard analytical methods. Here, we estimate the expected duration and contribution of precursor biotransformation to groundwater PFAS contamination at an AFFF-contaminated military base on Cape Cod, Massachusetts, United States, by optimizing a geochemical box model using measured PFAS concentrations from a multidecadal time series of groundwater and a soil survey in the source zone. A toolbox of analytical techniques used to reconstruct the mass budget of PFAS showed that precursors accounted for 46 ± 8% of the extractable organofluorine (a proxy for total PFAS) across years. Terminal PFAS still exceed regulatory limits by 2000-fold decades after AFFF use ceased. Measurements and numerical modeling show that sulfonamido precursors are retained in the vadose zone and their slow biotransformation into perfluoroalkyl sulfonates (half-life > 66 yr) sustains groundwater concentrations of perfluorobutane sulfonate (PFBS) and perfluorohexane sulfonate (PFHxS). The estimated PFAS reservoir in the vadose zone and modeled flux into groundwater suggest PFAS contamination above regulatory guidelines will persist for centuries without remediation.

Massachusetts↗

USGS2002

Corn leaf nitrate reductase - A nontoxic alternative to cadmium for photometric nitrate determinations in water samples by air-segmented continuous-flow analysis

Development, characterization, and operational details of an enzymatic, air-segmented continuous-flow analytical method for colorimetric determination of nitrate + nitrite in natural-water samples is described. This method is similar to U.S. Environmental Protection Agency method 353.2 and U.S. Geological Survey method 1-2545-90 except that nitrate is reduced to nitrite by soluble nitrate reductase (NaR, EC 1.6.6.1) purified from corn leaves rather than a packed-bed cadmium reactor. A three-channel, air-segmented continuous-flow analyzer-configured for simultaneous determination of nitrite (0.020-1.000 mg-N/L) and nitrate + nitrite (0.05-5.00 mg-N/L) by the nitrate reductase and cadmium reduction methods-was used to characterize analytical performance of the enzymatic reduction method. At a sampling rate of 90 h-1, sample interaction was less than 1% for all three methods. Method detection limits were 0.001 mg of NO2- -N/L for nitrite, 0.003 mg of NO3-+ NO2- -N/L for nitrate + nitrite by the cadmium-reduction method, and 0.006 mg of NO3- + NO2- -N/L for nitrate + nitrite by the enzymatic-reduction method. Reduction of nitrate to nitrite by both methods was greater than 95% complete over the entire calibration range. The difference between the means of nitrate + nitrite concentrations in 124 natural-water samples determined simultaneously by the two methods was not significantly different from zero at the p = 0.05 level.

Environmental Science & Technology↗

USGS2004

Incorporating uncertainty into mercury-offset decisions with a probabilistic network for National Pollutant Discharge Elimination System permit holders: An interim report

This interim report describes an alternative approach for evaluating the efficacy of using mercury (Hg) offsets to improve water quality. Hg-offset programs may allow dischargers facing higher-pollution control costs to meet their regulatory obligations by making more cost effective pollutant-reduction decisions. Efficient Hg management requires methods to translate that science and economics into a regulatory decision framework. This report documents the work in progress by the U.S. Geological Survey’s Western Geographic Science Center in collaboration with Stanford University toward developing this decision framework to help managers, regulators, and other stakeholders decide whether offsets can cost effectively meet the Hg total maximum daily load (TMDL) requirements in the Sacramento River watershed. Two key approaches being considered are: (1) a probabilistic approach that explicitly incorporates scientific uncertainty, cost information, and value judgments; and (2) a quantitative approach that captures uncertainty in testing the feasibility of Hg offsets. Current fate and transport-process models commonly attempt to predict chemical transformations and transport pathways deterministically. However, the physical, chemical, and biologic processes controlling the fate and transport of Hg in aquatic environments are complex and poorly understood. Deterministic models of Hg environmental behavior contain large uncertainties, reflecting this lack of understanding. The uncertainty in these underlying physical processes may produce similarly large uncertainties in the decisionmaking process. However, decisions about control strategies are still being made despite the large uncertainties in current Hg loadings, the relations between total Hg (HgT) loading and methylmercury (MeHg) formation, and the relations between control efforts and Hg content in fish. The research presented here focuses on an alternative analytical approach to the current use of safety factors and deterministic methods for Hg TMDL decision support, one that is fully compatible with an adaptive management approach. This alternative approach uses empirical data and informed judgment to provide a scientific and technical basis for helping National Pollutant Discharge Elimination System (NPDES) permit holders make management decisions. An Hg-offset system would be an option if a wastewater-treatment plant could not achieve NPDES permit requirements for HgT reduction. We develop a probabilistic decision-analytical model consisting of three submodels for HgT loading, MeHg, and cost mitigation within a Bayesian network that integrates information of varying rigor and detail into a simple model of a complex system. Hg processes are identified and quantified by using a combination of historical data, statistical models, and expert judgment. Such an integrated approach to uncertainty analysis allows easy updating of prediction and inference when observations of model variables are made. We demonstrate our approach with data from the Cache Creek watershed (a subbasin of the Sacramento River watershed). The empirical models used to generate the needed probability distributions are based on the same empirical models currently being used by the Central Valley Regional Water Quality Control Cache Creek Hg TMDL working group. The significant difference is that input uncertainty and error are explicitly included in the model and propagated throughout its algorithms. This work demonstrates how to integrate uncertainty into the complex and highly uncertain Hg TMDL decisionmaking process. The various sources of uncertainty are propagated as decision risk that allows decisionmakers to simultaneously consider uncertainties in remediation/implementation costs while attempting to meet environmental/ecologic targets. We must note that this research is on going. As more data are collected, the HgT and cost-mitigation submodels are updated and the uncertainties may be reduced. Subsequently, the value of using a probabilistic framework for estimating and explicitly stating these uncertainties within a decisionmaking process can be estimated when new data are collected. Future work includes the design and implementation of a Bayesian network decision support system (BN-DSS) to produce mitigation scenarios for offset-project evaluation in the Cache Creek watershed. The decisionmaker, a wastewater-treatment plant, is expected to evaluate potential Hg-offset programs in terms of changes in HgT load changes, MeHg-production potential, project cost, and other suitability criteria. Subsequently, scenarios can be analyzed by performing sensitivity analyses and ranking environmental and economic uncertainties in terms of the decisionmaker’s preferences and risk choices. Such an analysis allows decisionmakers and stakeholders to explore various scenarios and predict the consequences of different stated preferences over outcomes.

Open-File Report↗

USGS2005

Transport of chemical and microbial compounds from known wastewater discharges: Potential for use as indicators of human fecal contamination

The quality of drinking and recreational water is currently (2005) determined using indicator bacteria. However, the culture tests used to analyze for these bacteria require a long time to complete and do not discriminate between human and animal fecal material sources. One complementary approach is to use chemicals found in human wastewater, which would have the advantages of (1) potentially shorter analysis times than the bacterial culture tests and (2) being selected for human-source specificity. At 10 locations, water samples were collected upstream and at two successive points downstream from a wastewaster treatment plant (WWTP); a treated effluent sample was also collected at each WWTP. This sampling plan was used to determine the persistence of a chemically diverse suite of emerging contaminants in streams. Samples were also collected at two reference locations assumed to have minimal human impacts. Of the 110 chemical analytes investigated in this project, 78 were detected at least once. The number of compounds in a given sample ranged from 3 at a reference location to 50 in a WWTP effluent sample. The total analyte load at each location varied from 0.018 μg/L at the reference location to 97.7 μg/L in a separate WWTP effluent sample. Although most of the compound concentrations were in the range of 0.01−1.0 μg/L, in some samples, individual concentrations were in the range of 5−38 μg/L. The concentrations of the majority of the chemicals present in the samples generally followed the expected trend:  they were either nonexistent or at trace levels in the upstream samples, had their maximum concentrations in the WWTP effluent samples, and then declined in the two downstream samples. This research suggests that selected chemicals are useful as tracers of human wastewater discharge.

Environmental Science & Technology↗

USGS1998

Rocky 7 prototype Mars rover field geology experiments: 1. Lavic Lake and Sunshine volcanic field, California

Experiments with the Rocky 7 rover were performed in the Mojave Desert to better understand how to conduct rover-based, long-distance (kilometers) geological traverses on Mars. The rover was equipped with stereo imaging systems for remote sensing science and hazard avoidance and 57 Fe Mössbauer and nuclear magnetic resonance spectrometers for in situ determination of mineralogy of unprepared rock and soil surfaces. Laboratory data were also obtained using the spectrometers and an X ray diffraction (XRD)/XRF instrument for unprepared samples collected from the rover sites. Simulated orbital and descent image data assembled for the test sites were found to be critical for assessing the geologic setting, formulating hypotheses to be tested with rover observations, planning traverses, locating the rover, and providing a regional context for interpretation of rover-based observations. Analyses of remote sensing and in situ observations acquired by the rover confirmed inferences made from orbital and simulated descent images that the Sunshine Volcanic Field is composed of basalt flows. Rover data confirmed the idea that Lavic Lake is a recharge playa and that an alluvial fan composed of sediments with felsic compositions has prograded onto the playa. Rover-based discoveries include the inference that the basalt flows are mantled with aeolian sediment and covered with a dense pavement of varnished basalt cobbles. Results demonstrate that the combination of rover remote sensing and in situ analytical observations will significantly increase our understanding of Mars and provide key connecting links between orbital and descent data and analyses of returned samples.

Journal of Geophysical Research E: Planets↗

USGS2012

Absence of fractionation of mercury isotopes during trophic transfer of methylmercury to freshwater fish in captivity

We performed two controlled experiments to determine the amount of mass-dependent and mass-independent fractionation (MDF and MIF) of methylmercury (MeHg) during trophic transfer into fish. In experiment 1, juvenile yellow perch ( Perca flavescens ) were raised in captivity on commercial food pellets and then their diet was either maintained on unamended food pellets (0.1 μg/g MeHg) or was switched to food pellets with 1.0 μg/g or 4.0 μg/g of added MeHg, for a period of 2 months. The difference in δ 202 Hg (MDF) and Δ 199 Hg (MIF) between fish tissues and food pellets with added MeHg was within the analytical uncertainty (δ 202 Hg, 0.07 ‰; Δ 199 Hg, 0.06 ‰), indicating no isotope fractionation. In experiment 2, lake trout ( Salvelinus namaycush ) were raised in captivity on food pellets and then shifted to a diet of bloater ( Coregonus hoyi ) for 6 months. The δ 202 Hg and Δ 199 Hg of the lake trout equaled the isotopic composition of the bloater after 6 months, reflecting reequilibration of the Hg isotopic composition of the fish to new food sources and a lack of isotope fractionation during trophic transfer. We suggest that the stable Hg isotope ratios in fish can be used to trace environmental sources of Hg in aquatic ecosystems.

Environmental Science & Technology↗

USGS2002

Groundwater contamination downstream of a contaminant penetration site. I. Extension-expansion of the contaminant plume

This study concerns the possible use of boundary layer (BL) approach for the analysis and evaluation of contaminant transport in groundwater due to contaminant penetration into the groundwater aquifer through a site of limited size. The contaminant penetration may occur through either the upper (surface) or lower (bedrock) boundary of the aquifer. Two general cases of contaminant penetration mechanisms are considered: (1) the contaminant is transferred through an interface between a contaminating and freshwater fluid phases, and (2) the contaminant arrives at groundwater by leakage and percolation. For the purpose of BL evaluation the contaminant plume is divided into three different sections: (1) the penetration section, (2) the extension-expansion section, and (3) the spearhead section. In each section a different BL method approach yields simple analytical expressions for the description of the contaminant plume migration and contaminant transport. Previous studies of the BL method can be directly applied to the evaluation of contaminant transport at the contaminant penetration section. The present study extends those studies and concerns the contaminant transport in the two other sections, which are located downstream of the penetration section. This study shows that the contaminant concentration profiles in sections 2 and 3 incorporate two BLs: (1) an inner BL adjacent to the aquifer bottom or surface boundary, and (2) an outer BL, which develops above or below the inner one. The method developed in the present study has been applied to practical issues concerning salinity penetration into groundwater in south central Kansas.

Journal of Environmental Science and Health - Part↗

USGS2013

Whole-body concentrations of elements in three fish species from offshore oil platforms and natural areas in the Southern California Bight, USA

There is concern that offshore oil platforms off Southern California may be contributing to environmental contaminants accumulated by marine fishes. To examine this possibility, 18 kelp bass (Paralabrax clathratus Girard, 1854), 80 kelp rockfish (Sebastes atrovirens Jordan and Gilbert, 1880), and 98 Pacific sanddab (Citharichthys sordidus Girard, 1854) were collected from five offshore oil platforms and 10 natural areas during 2005–2006 for whole-body analysis of 63 elements. Forty-two elements were excluded from statistical comparisons as they (1) consisted of major cations that were unlikely to accumulate to potentially toxic concentrations; (2) were not detected by the analytical procedures; or (3) were detected at concentrations too low to yield reliable quantitative measurements. The remaining 21 elements consisted of aluminum, arsenic, barium, cadmium, chromium, cobalt, copper, gallium, iron, lead, lithium, manganese, mercury, nickel, rubidium, selenium, strontium, tin, titanium, vanadium, and zinc. Statistical comparisons of these elements indicated that none consistently exhibited higher concentrations at oil platforms than at natural areas. However, the concentrations of copper, selenium, titanium, and vanadium in Pacific sanddab were unusual because small individuals exhibited either no differences between oil platforms and natural areas or significantly lower concentrations at oil platforms than at natural areas, whereas large individuals exhibited significantly higher concentrations at oil platforms than at natural areas.

California↗

USGS2020

Using saline or brackish aquifers as reservoirs for thermal energy storage, with example calculations for direct-use heating in the Portland Basin, Oregon, USA

Tools to evaluate reservoir thermal energy storage (RTES; heat storage in slow-moving or stagnant geochemically evolved permeable zones in strata that underlie well-connected regional aquifers) are developed and applied to the Columbia River Basalt Group (CRBG) beneath the Portland Basin, Oregon, USA. The performance of RTES for heat storage and recovery in the Portland Basin is strongly dependent on the operational schedule of heat injection and extraction. We examined the effects of the operational schedule, based on an annual solar hot water supply pattern and a building heating demand model, using heat and fluid flow simulations with SUTRA. We show RTES to be feasible for supply of heating energy for a large combined research/teaching building on the Oregon Health and Science University South Waterfront expansion, an area of planned future development. Initially, heat is consumed to increase the reservoir temperature, and conductive heat loss is high due to high temperature gradients between the reservoir and surrounding rock. Conductive heat loss continues into the future, but the rate of heat loss decreases, and heat recovery efficiency of the RTES system increases over time. Simulations demonstrate the effects of varying heat-delivery rate and temperature on the heat production history of the reservoir. If 100% of building heating needs are to be supplied by combined solar/RTES, then the solar system must be sized to meet building needs plus long-term thermal losses (i.e., conductive losses once the system is heated to pseudo-steady state) from the RTES system. If the solar heating system barely meets these criteria, then during early years, less than 100% of the building demand will be supplied until the reservoir is fully-heated. The duration of supplying less than 100% of building demand can be greatly shortened by pre-heating the reservoir before building heating operations or by adding extra heat from external sources during early years. Analytic solutions are developed to evaluate efficacy and to help design RTES systems (e.g., well-spacing, thermal source sizing, etc.). A map of thermal energy storage capacity is produced for the CRBG beneath the Portland Basin. The simulated building has an annual heat load of ∼1.9 GWh, and the total annual storage capacity of the Portland Basin is estimated to be 43,400 GWh assuming seasonal storage of heat yields water from which 10 °C can be extracted via heat exchange, indicating a tremendous heating capacity of the CRBG.

Oregon↗

USGS2016

Radiometric dating of marine-influenced coal using Re–Os geochronology

Coal deposits are integral to understanding the structural evolution and thermal history of sedimentary basins and correlating contemporeous estuarine and fluvial delatic strata with marine sections. While marine shales may readily lend themselves to Re–Os dating due to the dominance of hydrogenous Re and Os, the lack of a chronometer for near-shore sedimentary environments hampers basinwide correlations in absolute time. Here, we employ the Re–Os geochronometer, along with total organic carbon (TOC) and Rock–Eval data, to determine the timing and conditions of a marine incursion at the top of the Matewan coal bed, Kanawha Formation, Pottsville Group, West Virginia, USA. The observed range for hydrogen index (HI: 267–290 mg hydrocarbon/gram total organic carbon) for these coal samples suggests dominance of aliphatic hydrocarbons with low carbon (<C 19 ) chain length. Average Re ( 107.6±16.4 ng/g ) and Os ( 0.52±0.09 ng/g ) concentrations of the marine-influenced Matewan coal are higher by few orders of magnitude than published data for terrestrial coal. A Re–Os isochron for the Matewan coal provides an age of 325±14 Ma (Model 3; MSWD = 12; n=19 ; 2 σ ). This is the first Re–Os age derived from coal samples; the age overlaps a new composite Re–Os age of 317±2 Ma for the immediately overlying Betsie Shale Member. External precision for replicate Os analyses carried out for several Matewan coal samples shows a positive correlation with their HI. The HI, which is low in terrestrial organic matter, reflects the degree of marine influence. Thus, samples with the most profound marine influence also have the best analytical reproducibility. Equilibration of Os isotopes with seawater under marine conditions overwhelms variability inherited from terrestrial plant debris, decreasing scatter on the isochron. The 187 Re/ 188 Os ratios of the Matewan coal (&sim;3300–5135) are higher than most of those previously published for Phanerozoic black shale (mostly <2000). Mass balance calculations based on Re/TOC and Os/TOC ratios for the Matewan coal indicate that both Re and Os are primarily marine in origin, and their high 187 Re/ 188 Os ratios confirm efficient removal of both elements from a sulfidic water column into the coal. We show that Re–Os geochronology of marine-influenced coal can be a viable tool for constraining depositional ages.

West Virginia↗

USGS1996

Loess studies in central United States: Evolution of concepts

Few words in the realm of earth science have caused more debate than "loess". It is a common term that was first used as a name of a silt deposit before it was defined in a scientific sense. Because this "loose" deposit is easily distinguished from other more coherent deposits, it was recognized as a matter of practical concern and later became the object of much scientific scrutiny. Loess was first recognized along the Rhine Valley in Germany in the 1830s and was first noted in the United States in 1846 along the lower Mississippi River where it later became the center of attention. The use of the name eventually spread around the world, but its use has not been consistently applied. Over the years some interpretations and stratigraphic correlations have been validated, but others have been hotly contested on conceptual grounds and semantic issues. The concept of loess evolved into a complex issue as loess and loess-like deposits were discovered in different parts of the US. The evolution of concepts in the central US developed in four indefinite stages: the eras of (1) discovery and development of hypotheses, (2) conditional acceptance of the eolian origin of loess, (3) "bandwagon" popularity of loess research, and (4) analytical inquiry on the nature of loess. Toward the end of the first era around 1900, the popular opinion on the meaning of the term loess shifted from a lithological sense of loose silt to a lithogenetic sense of eolian silt. However, the dual use of the term fostered a lingering skepticism during the second era that ended in 1944 with an explosion of interest that lasted for more than a decade. In 1944, R.J. Russell proposed and H.N. Fisk defended a new non-eolian, property-based, concept of loess. The eolian advocates reacted with surprise and enthusiasm. Each side used constrained arguments to show their view of the problem, but did not examine the fundamental problem, which was not in the proofs of their hypothesis, but in the definition of the term. Between 1944 and about 1950, the debates about loess reached a maximum level of complexity. The main semantic problem was submersed in peripheral arguments about physical properties and genetic interpretations. The scholarly treatment of the subject by Fisk and Russell stimulated quality responses from a diversity of earth scientists interested in academic and applied studies, particularly geo-history, pedology, soil mechanics and stratigraphy. The long-lasting popularity of loess studies during the bandwagon era lasted to about 1970. By that time, the analytical and technical interests had attracted the mainstream into the fourth era with a focus beyond the old arguments. Although Fisk and Russell found themselves defending an unpopular theory, they stimulated a scientific interest in the late Quaternary history of the Mississippi Valley that may never be exceeded.

Engineering Geology↗

USGS2002

Snow chemistry of the Cascade-Sierra Nevada Mountains

This investigation assesses geographic variations in atmospheric deposition in Washington, Oregon, and California using snow cores from the Cascade-Sierra Nevada Mountains, collected from late February to mid-March 1983. A statistical analysis of the analytical and sampling precision was made. The snowpack in the higher Cascades and Sierra Nevada is not strongly influenced by anthropogenic activities at present. The pH of snow samples ranges from 5.11 to 5.88. Sulfate and nitrate correlate with H+ in some segments of the sample traverse. The SO4 data show apparent influence from major source areas in Washington and California; nitrate does not. An apparent decrease in NH4 in snow in Washington and California suggests atmospheric interactions resulting in the removal of NH4. The NH4 reduction raises questions about nutrient supply to the mountain vegetation. Heavy-metal correlations included Cd, Cu, and Fe with Pb, and Mn with K and DOC, among others. No correlation was found between constituents and snow-water content.

California, Oregon, Washington↗

USGS2016

Pre/post-closure assessment of groundwater pharmaceutical fate in a wastewater‑facility-impacted stream reach

Pharmaceutical contamination of contiguous groundwater is a substantial concern in wastewater-impacted streams, due to ubiquity in effluent, high aqueous mobility, designed bioactivity, and to effluent-driven hydraulic gradients. Wastewater treatment facility (WWTF) closures are rare environmental remediation events; offering unique insights into contaminant persistence, long-term wastewater impacts, and ecosystem recovery processes. The USGS conducted a combined pre/post-closure groundwater assessment adjacent to an effluent-impacted reach of Fourmile Creek, Ankeny, Iowa, USA. Higher surface-water concentrations, consistent surface-water to groundwater concentration gradients, and sustained groundwater detections tens of meters from the stream bank demonstrated the importance of WWTF effluent as the source of groundwater pharmaceuticals as well as the persistence of these contaminants under effluent-driven, pre-closure conditions. The number of analytes (110 total) detected in surface water decreased from 69 prior to closure down to 8 in the first post-closure sampling event approximately 30 d later, with a corresponding 2 order of magnitude decrease in the cumulative concentration of detected analytes. Post-closure cumulative concentrations of detected analytes were approximately 5 times higher in proximal groundwater than in surface water. About 40% of the 21 contaminants detected in a downstream groundwater transect immediately before WWTF closure exhibited rapid attenuation with estimated half-lives on the order of a few days; however, a comparable number exhibited no consistent attenuation during the year-long post-closure assessment. The results demonstrate the potential for effluent-impacted shallow groundwater systems to accumulate pharmaceutical contaminants and serve as long-term residual sources, further increasing the risk of adverse ecological effects in groundwater and the near-stream ecosystem.

Iowa↗

USGS2021

Multi-region assessment of chemical mixture exposures and predicted cumulative effects in USA wadeable urban/agriculture-gradient streams

Chemical-contaminant mixtures are widely reported in large stream reaches in urban/agriculture-developed watersheds, but mixture compositions and aggregate biological effects are less well understood in corresponding smaller headwaters , which comprise most of stream length, riparian connectivity, and spatial biodiversity. During 2014–2017, the U.S. Geological Survey (USGS) measured 389 unique organic analytes (pharmaceutical, pesticide, organic wastewater indicators) in 305 headwater streams within four contiguous United States (US) regions. Potential aquatic biological effects were evaluated for estimated maximum and median exposure conditions using multiple lines of evidence, including occurrence/concentrations of designed-bioactive pesticides and pharmaceuticals and cumulative risk screening based on vertebrate-centric ToxCast™ exposure-response data and on invertebrate and nonvascular plant aquatic life benchmarks. Mixed-contaminant exposures were ubiquitous and varied, with 78% (304) of analytes detected at least once and cumulative maximum concentrations up to more than 156,000 ng/L. Designed bioactives represented 83% of detected analytes. Contaminant summary metrics correlated strong-positive (rho (ρ): 0.569–0.719) to multiple watershed-development metrics, only weak-positive to point-source discharges (ρ: 0.225–353), and moderate- to strong-negative with multiple instream invertebrate metrics (ρ: −0.373 to −0.652). Risk screening indicated common exposures with high probability of vertebrate-centric molecular effects and of acute toxicity to invertebrates, respectively. The results confirm exposures to broad and diverse contaminant mixtures and provide convincing multiple lines of evidence that chemical contaminants contribute substantially to adverse multi-stressor effects in headwater-stream communities.

Science of the Total Environment↗