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Geology, water resources and usable ground-water storage capacity of part of Solano County, California

The area described is confined largely to the valley-floor and foothill lands of Solano County, which lies directly between Sacramento, the State capital, and San Francisco. The area is considered in two subareas: The Putah area, which extends from Putah Creek southward to the Montezuma Hills and from the foothills of the Coast Ranges eastward to the west edge of the Yolo Bypass; and the Suisun-Fairfield area, which is to the southwest in the notch in the Coast Ranges through which the waters of the Great Central Valley of California reach San Francisco Bay. There are no known hydrologic interconnections between the two subareas, through either surface streams or underground aquifers. The climate of the area is characterized by warm, rainless summers and by cool winters in which temperatures seldom drop much below freezing. The rainfall ranges from about 17 inches per year along the east side to perhaps 24 inches in the foothills to the west, and irrigation is necessary for all crops except dry-farmed grains, pastures, and some orchards. PUTAH AREA The Putah area occupies the southwestern corner of the Sacramento Valley, a topographic and structural basin underlain by a thick accumulation of sediments eroded from the surrounding hills and mountains by the Sacramento River and its tributaries. The eastern Coast Ranges and foothills lying west of the Sacramento Valley are a generally northward-trending belt of eastward-dipping sedimentary rocks that range in age from Cretaceous to Pleistocene. Successively younger strata are exposed eastward, and the essentially undeformed deposits of late Pleistocene and Recent age that immediately underlie the valley lap onto the tilted sediments of the foothills. Most of the streams of the Putah area rise east of the high ridge of Cretaceous rocks marking the western boundaries of Solano and Yolo Counties, but Putah Creek, the largest stream in the area, rises far west of that ridge and flows across it in a deep, narrow canyon. Putah Creek and the smaller streams have constructed an alluvial plain, herein designated the Putah plain, which slopes eastward and southeastward from the foothills toward the Sacramento River. A large part of the Putah plain is traversed by a branching set of distributary channel ridges or natural levees formed at times of overflow of Putah Creek. The rocks in the Putah area range in age from Cretaceous to Recent. For the purposes of this investigation they are divided into eight geologic or stratigraphic units, from youngest to oldest: (1) Stream-channel deposits, (2) younger alluvium, (3) older alluvium, (4) Tehama formation and related continental sediments, (5) volcanic sedimentary rocks, (6) basalt, (7) undifferentiated sedimentary rocks of Paleocene(?) and Eocene age, and (8) undifferentiated rocks of Cretaceous age. The stream-channel deposits are predominantly loose sand and gravel along the channel of Putah Creek. In part they are actively moving downstream and shifting. The younger alluvium, of Recent age, consists of flood-plain deposits underlying the Putah plain, Vaca Valley, Pleasants Valley, and the small valleys in the foothills north of Putah Creek and in the English Hills. Exposures of younger alluvium are characterized by soils lacking significant profile development and in many places by channel-ridge topography. The older alluvium occupies the stratigraphic interval between the younger alluvium and the Tehama formation and related continental sediments and is probably of late Pleistocene age. Its contact with the underlying Tehama formation and related continental sediments is unconformable near the foothills, but it may be gradational beneath much of the Putah plain. The base of the older alluvium is not well defined at many places but is inferred to be at the bottom of an irregular and ill-defined zone of coarse deposits, which ranges from about 50 feet to more than 150 feet below the land surface. Exposures of the older

Water Supply Paper↗

Prediction uncertainty and data worth assessment for groundwater transport times in an agricultural catchment

Uncertainties about the age of base-flow discharge can have serious implications for the management of degraded environmental systems where subsurface pathways, and the ongoing release of pollutants that accumulated in the subsurface during past decades, dominate the water quality signal. Numerical groundwater models may be used to estimate groundwater return times and base-flow ages and thus predict the time required for stakeholders to see the results of improved agricultural management practices. However, the uncertainty inherent in the relationship between (i) the observations of atmospherically-derived tracers that are required to calibrate such models and (ii) the predictions of system age that the observations inform have not been investigated. For example, few if any studies have assessed the uncertainty of numerically-simulated system ages or evaluated the uncertainty reductions that may result from the expense of collecting additional subsurface tracer data. In this study we combine numerical flow and transport modeling of atmospherically-derived tracers with prediction uncertainty methods to accomplish four objectives. First, we show the relative importance of head, discharge, and tracer information for characterizing response times in a uniquely data rich catchment that includes 266 age-tracer measurements (SF 6 , CFCs, and 3 H) in addition to long term monitoring of water levels and stream discharge. Second, we calculate uncertainty intervals for model-simulated base-flow ages using both linear and non-linear methods, and find that the prediction sensitivity vector used by linear first-order second-moment methods results in much larger uncertainties than non-linear Monte Carlo methods operating on the same parameter uncertainty. Third, by combining prediction uncertainty analysis with multiple models of the system, we show that data-worth calculations and monitoring network design are sensitive to variations in the amount of water leaving the system via stream discharge and irrigation withdrawals. Finally, we demonstrate a novel model-averaged computation of potential data worth that can account for these uncertainties in model structure.

Maryland↗

Hydrogeologic framework and hydrologic budget components of the Columbia Plateau Regional Aquifer System, Washington, Oregon, and Idaho

The Columbia Plateau Regional Aquifer System (CPRAS) covers an area of about 44,000 square miles in a structural and topographic basin within the drainage of the Columbia River in Washington, Oregon, and Idaho. The primary aquifers are basalts of the Columbia River Basalt Group (CRBG) and overlying sediment. Eighty percent of the groundwater use in the study area is for irrigation, in support of a $6 billion per year agricultural economy. Water-resources issues in the Columbia Plateau include competing agricultural, domestic, and environmental demands. Groundwater levels were measured in 470 wells in 1984 and 2009; water levels declined in 83 percent of the wells, and declines greater than 25 feet were measured in 29 percent of the wells. Conceptually, the system is a series of productive basalt aquifers consisting of permeable interflow zones separated by less permeable flow interiors; in places, sedimentary aquifers overly the basalts. The aquifer system of the CPRAS includes seven hydrogeologic units-the overburden aquifer, three aquifer units in the permeable basalt rock, two confining units, and a basement confining unit. The overburden aquifer includes alluvial and colluvial valley-fill deposits; the three basalt units are the Saddle Mountains, Wanapum, and Grande Ronde Basalts and their intercalated sediments. The confining units are equivalent to the Saddle Mountains-Wanapum and Wanapum-Grande Ronde interbeds, referred to in this study as the Mabton and Vantage Interbeds, respectively. The basement confining unit, referred to as Older Bedrock, consists of pre-CRBG rocks that generally have much lower permeabilities than the basalts and are considered the base of the regional flow system. Based on specific-capacity data, median horizontal hydraulic conductivity (Kh) values for the overburden, basalt units, and bedrock are 161, 70, and 6 feet per day, respectively. Analysis of oxygen isotopes in water and carbon isotopes in dissolved inorganic carbon from groundwater samples indicates that groundwater in the CPRAS ranges in age from modern (<50 years) to Pleistocene (>10,000 years). The oldest groundwater resides in deep, downgradient locations indicating that groundwater movement and replenishment in parts of this regional aquifer system have operated on long timescales under past natural conditions, which is consistent with the length and depth of long flow paths in the system. The mean annual recharge from infiltration of precipitation for the 23-year period 1985-2007 was estimated to be 4.6 inches per year (14,980 cubic feet per second) using a polynomial regression equation based on annual precipitation and the results of recharge modeling done in the 1980s. A regional-scale hydrologic budget was developed using a monthly SOil WATer (SOWAT) Balance model to estimate irrigation-water demand, groundwater flux (recharge or discharge), direct runoff, and soil moisture within irrigated areas. Mean monthly irrigation throughout the study area peaks in July at 1.6 million acre-feet (MAF), of which 0.45 and 1.15 MAF are from groundwater and surface-water sources, respectively. Annual irrigation water use in the study area averaged 5.3 MAF during the period 1985-2007, with 1.4 MAF (or 26 percent) supplied from groundwater and 3.9 MAF supplied from surface water. Mean annual recharge from irrigation return flow in the study area was 4.2 MAF (1985-2007) with 2.1 MAF (50 percent) occurring within the predominately surface-water irrigated regions of the study area. Annual groundwater-use estimates were made for public supply, self-supplied domestic, industrial, and other uses for the period 1984 through 2009. Public supply groundwater use within the study area increased from 200,600 acre-feet per year (acre-ft/yr) in 1984 to 269,100 acre-ft/yr in 2009. Domestic self-supplied groundwater use increased from 54,580 acre-ft/yr in 1984 to 71,160 acre-ft/yr in 2009. Industrial groundwater use decreased from 53,390 acre-ft/yr in 1984 t

Scientific Investigations Report↗

Base of principal aquifer for the Elkhorn-Loup model area, North-Central Nebraska

In Nebraska, the water managers in the Natural Resources Districts and the Nebraska Department of Natural Resources are concerned with the effect of ground-water withdrawal on the availability of surface water and the long-term effects of ground-water withdrawal on ground- and surface-water resources. In north-central Nebraska, in the Elkhorn and Loup River Basins, ground water is used for irrigation, domestic supply, and public supply; surface water is used in this area for irrigation, recreation, and hydropower production. In recognition of these sometimes competing ground- and surface-water uses in the Elkhorn and Loup River Basins, the U.S. Geological Survey, the Lewis and Clark Natural Resources District, the Lower Elkhorn Natural Resources District, the Lower Loup Natural Resources District, the Lower Niobrara Natural Resources District, the Lower Platte North Natural Resources District, the Middle Niobrara Natural Resources District, the Upper Elkhorn Natural Resources District, and the Upper Loup Natural Resources District agreed to cooperatively study water resources in the Elkhorn and Loup River Basins. The goals of the overall study were to construct and calibrate a regional ground-water flow model of the area and to use that flow model as a tool to assess current and future effects of ground-water irrigation on stream base flow and to help develop long-term water-resource management strategies for this area, hereafter referred to as the Elkhorn-Loup model area. The Elkhorn-Loup model area covers approximately 30,800 square miles, and extends from the Niobrara River in the north to the Platte River in the south. The western boundary of the Elkhorn-Loup model area coincides with the western boundary of the Middle Niobrara, Twin Platte, and Upper Loup Natural Resources Districts; the eastern boundary coincides with the approximate location of the western extent of glacial till in eastern Nebraska. The principal aquifer in most of the Elkhorn-Loup model area is the High Plains aquifer; the principal aquifer in the remaining part of the Elkhorn-Loup model area is an unnamed alluvial aquifer. The upper surface of the geologic units that directly underlie the aquifer is called the 'base of aquifer' in this report. The geologic unit that forms the base of aquifer in the Elkhorn-Loup model area varies by location. The Tertiary-age Brule Formation generally is the base of aquifer in the west; the Cretaceous-age Pierre Shale generally is the base of aquifer in the east. The purpose of this report is to update the altitude and configuration of the base of the principal aquifer in the Elkhorn-Loup model area and a 2-mile buffer area around the Elkhorn-Loup model area, using base-of-aquifer data from test holes, registered water wells, and oil and gas wells within the Elkhorn-Loup model area and a 20-mile buffer area around the Elkhorn-Loup model area that have become available since the publication of earlier maps of the base of aquifer for this area. The base-of-aquifer map is important for the Elkhorn-Loup ground-water flow model because it defines the model's lower boundary. The accuracy of the Elkhorn-Loup ground-water flow model and the accuracy of the model's predictions about the effects of ground-water irrigation on stream base flow are directly related to the accuracy of the model's lower boundary.

Scientific Investigations Map↗

Map showing saturated thickness of unconsolidated aquifer in southwestern Kansas, January 1978

The principal aquifer in the 13-county area of southwestern Kansas occurs in the heterogeneous, unconsolidated alluvial deposits of Tertiary and Quaternary age. The main body of this ground-water reservoir is designated as the unconsolidated aquifer. The map showing the saturated thickness of deposits in the unconsolidated aquifer was prepared by comparing maps showing the altitude and configuration of the underlying bedrock surface and of the potentiometric (water-level) surface in the unconsolidated aquifer in January 1978. About 75 percent of the area (1,460 square miles), as shown within the aquifer boundaries, is underlain by sufficient saturated material to supply ground water for irrigation. Saturated thicknesses range from less than 50 feet to about 630 feet. In the remainder of the area, except for isolated channels, the saturated material generally is thin and yields little or no water to wells.

Kansas↗

Hydrogeological framework, numerical simulation of groundwater flow, and effects of projected water use and drought for the Beaver-North Canadian River alluvial aquifer, northwestern Oklahoma

This report describes a study of the hydrology, hydrogeological framework, numerical groundwater-flow models, and results of simulations of the effects of water use and drought for the Beaver-North Canadian River alluvial aquifer, northwestern Oklahoma. The purpose of the study was to provide analyses, including estimating equal-proportionate-share (EPS) groundwater-pumping rates and the effects of projected water use and droughts, pertinent to water management of the Beaver-North Canadian River alluvial aquifer for the Oklahoma Water Resources Board. The Beaver-North Canadian River alluvial aquifer consists of unconsolidated sand, gravel, silt, and clay in varying proportions that underlies the Beaver and North Canadian River Valleys for approximately 175 miles (mi) from the Oklahoma Panhandle to the western edge of Oklahoma City in central Oklahoma. The aquifer as delineated for this study varies from 4 to 12 mi wide and is as thick as 308 feet (ft) in the northwest where the aquifer includes the Ogallala Formation. There are two distinct but in most areas hydraulically connected alluvial units that compose the Beaver-North Canadian River alluvial aquifer: a Quaternary-age topographically higher terrace deposit and a topographically lower, younger alluvium along the active river channel that includes active and Quaternary-age alluvium. The Beaver River composes the headwaters of the North Canadian River, which begins at the confluence of the Beaver River and Wolf Creek. The aquifer is divided for water management into two geographic areas: Reach I upstream from Canton Dam and Reach II downstream from Canton Dam. Reach I covers an area of approximately 874 square miles (mi 2 ), and Reach II covers an area of approximately 371 mi 2 . The Beaver-North Canadian River alluvial aquifer crosses several climatic zones, from semiarid in the west to continental subhumid in the east. Mean annual precipitation varies from 23.5 inches (in.) in the western part of this aquifer to 35.7 in. in the east. Surface-water demands were met through numerous temporary and permanent surface-water diversions from the Beaver and North Canadian Rivers during the period of study. During the study period, seven diversions removed a mean annual 2,000 acre-feet (acre-ft) of water from Reach I. There were 14 diversions from Reach II with a mean annual permitted volume of approximately 81,000 acre-ft, including diversion into the Lake Hefner Canal for the Oklahoma City public water supply. During the period of this study, 17 temporary surface-water diversion permits were active in Reach I, with total permitted volumes of 2,000 acre-ft, and 41 diversions were active in Reach II, with total permitted volumes of 38,000 acre-ft. The total water use for each temporary permit was assumed to be taken over the 3-month period allotted to temporary withdrawal permits. The groundwater-use analysis full period of record, 1967&ndash;2011, was divided into two sub-intervals because of varying water use, 1970&ndash;80 and 1981&ndash;2011. Groundwater use in Reach I and Reach II was substantially greater from 1970 to 1980 compared to the rest of the period, and the sub-period 1981&ndash;2011 was used because this period includes recent population growth and modern irrigation methods. The total mean annual groundwater use in Reach I was 15,309 acre-feet per year (acre-ft/yr) during 1967&ndash;2011; 20,724 acre-ft/yr during 1970&ndash;80, and 13,739 acre-ft/yr during 1981&ndash;2011. Total mean annual groundwater use in Reach II was similar but slightly less than in Reach I, with 14,098 acre-ft/yr during 1967&ndash;2011; 19,963 acre-ft/yr during 1970&ndash;80; and 12,285 acre-ft/yr during 1981&ndash;2011. Irrigation composed 72 percent of groundwater use in Reach I and 48 percent of groundwater use in Reach II during the 1967&ndash;2011 period. Public water supply was a much smaller proportion of total groundwater use in Reach I (15 percent) than in Reach II (39 percent). The proportion of groundwater use for power was 10 percent in Reach I and 5.2 percent in Reach II. All other water-use categories in Reach I only composed 2.2 percent of groundwater use in Reach I. In Reach II, industrial, mining, and commercial categories combined accounted for 4.4 percent of groundwater use; recreation, fish, and wildlife groundwater use accounted for 2.3 percent; and nonirrigated agriculture accounted for 1.5 percent of groundwater use. Permian-age bedrock underlies the Beaver-North Canadian River alluvial aquifer. In the east, the Dog Creek Shale, the Duncan Sandstone, and the Blaine and Chickasha Formations, none of which are notable sources of groundwater in the study area, underlie the Beaver-North Canadian River alluvial aquifer. In the northwestern part of Reach I, bedrock is composed of the Rush Springs and Marlow Formations, which are productive aquifers in some areas. The Cloud Chief Formation is not a source of groundwater. One hydrogeological unit was delineated in the Beaver-North Canadian River alluvial aquifer, composed of the terrace deposits and alluvium, with limited flow between this unit and bedrock units. Groundwater in this aquifer generally flows from northwest to southeast and across the aquifer toward the Beaver and North Canadian Rivers. Groundwater recharge from precipitation was estimated for the entire Beaver-North Canadian River alluvial aquifer and then itemized for both reaches by using a soil-water-balance (SWB) model. At two locations in Reach I, a water-table fluctuation method was used to estimate local recharge. Total mean annual groundwater recharge from the soil-water-balance method was estimated to be approximately 136,400 acre-ft in Reach I and 82,400 acre-ft in Reach II; the mean annual recharge for both reaches combined was approximately 218,800 acre-ft. Two sites in Reach I located at observation wells with continuous water-level measurements and nearby streamflow-gaging stations with precipitation gages were used to estimate the percentage of precipitation that becomes groundwater recharge. The Woodward site was located at observation well OW-4 near the Woodward, Okla. (07237500), streamflow-gaging station. Total precipitation and recharge for the Woodward and Seiling sites were calculated for the water year 2013. The Woodward site had a total of 14.18 in. of precipitation and 6.3 in. of recharge was calculated, equaling 44 percent of precipitation. The mean percentage of precipitation that was estimated to become recharge in the SWB model for the period 1980&ndash;2011 at that location was 9.2 percent, although adjacent SWB-model cells were as high as 20 percent of precipitation. The Seiling site had a total of 26.84 in. of precipitation during the water year 2013, and a total of 6.9 in. of recharge was estimated, equaling 25.9 percent of precipitation. At the Seiling site, the mean percentage of precipitation that became recharge in the SWB model for the period 1980&ndash;2011 was 23.0 percent. The principal inflow to the Beaver-North Canadian River alluvial aquifer was estimated to be surface recharge from precipitation, and plant evapotranspiration was estimated to be the greatest discharge, followed by stream and lake base flow, groundwater pumping, and flow to seeps and springs along the eastern margin of the aquifer. Reach I also included inflow from the High Plains aquifer as lateral inflow of groundwater, though this flow was estimated to be a very minor component of the total water budget. Most of the Beaver and North Canadian Rivers were determined to be gaining streamflow from groundwater, but several reaches in Reach I upstream from Wolf Creek were determined to be losing streamflow through infiltration to the aquifer. Aquifer hydrogeologic characteristics were estimated from borehole lithologic logs, well-construction information, and published aquifer tests and during numerical model calibration. The maximum saturated aquifer thickness in Reach I was estimated to be 308 ft, and the mean thickness was estimated to be 36 ft. The maximum saturated thickness in Reach II was estimated to be 86 ft, and the mean thickness was estimated to be 29 ft. Mean hydraulic conductivity of Reach I was estimated to be 70 feet per day (ft/d) with a range of 7&ndash;279 ft/d. Mean hydraulic conductivity in Reach II was estimated to be 92 ft/d with a range of 4&ndash;279 ft/d. Both reach models were calibrated manually by using trial-and-error adjustment of recharge, hydraulic conductivity, specific yield, and conductance of boundary conditions. The Reach I model used 28 head observations during the steady-state period of 1980 and 487 head observations during the transient period of 1981&ndash;2011. The root-mean-square error of head residuals (observed minus simulated head) was 3.86 ft, and 83 percent of head residuals were between -5 and 5 ft. The Reach II model was calibrated to 75 steady-state head observations and 134 head observations during the transient period. The root-mean-square error of head residuals for that reach was 3.58 ft, and similar to Reach I, 85 percent of residuals were between -5 and 5 ft. Several analyses were performed by using the numeric groundwater-flow models as predictive tools, including estimating the EPS pumping rate for both reaches. The EPS is defined by the Oklahoma Water Resources Board as an annual per-acre groundwater-pumping rate that will reduce saturated thickness in half of the aquifer to 5 ft or less over a period of 20 years; additional estimates were made for periods of 40 and 50 years. Other analyses included using models to estimate the effects of groundwater pumping and a prolonged drought on groundwater in storage and streamflow and lake storage of water. The EPS pumping rate was found to be approximately 0.57 acre-feet per acre per year ([acre-ft/acre]/yr) in Reach I and 0.73 (acre-ft/acre)/yr in Reach II for a 20-year period. For a 40-year period, the annual EPS pumping rate was determined to be 0.54 (acre-ft/acre)/yr in Reach I and 0.61 (acre-ft/acre)/yr in Reach II. For a 50-year period, the EPS pumping rate was determined to be 0.53 (acre-ft/acre)/yr in Reach I and 0.61 (acre-ft/acre)/yr in Reach II. Groundwater pumping at the 2011 rate for 50 years resulted in a 3.6-percent decrease in the amount of water in groundwater storage in Reach I and a decrease of 2.5 percent in the amount of groundwater in storage in Reach II. A cumulative 32-percent increase in pumping greater than the 2011 rate over a period of 50 years caused a decrease in groundwater storage of 4.0 percent in Reach I and 3.3 percent in Reach II. A hypothetical severe drought was simulated by using aquifer recharge flow rates during the drought year of 2011 for a period of 10 years. All other flows including evapotranspiration and groundwater pumping were set at estimated 2011 rates. The hypothetical drought caused a decrease in water in aquifer storage by about 7 percent in Reach I and 7 percent in Reach II. Another analysis of the effects of hypothetical drought estimated the effects of drought on streamflow and lake storage. The hypothetical drought was simulated by decreasing recharge by 75 percent for a selected 10-year period (1994&ndash;2004) during the 1980&ndash;2011 simulation. In Reach I, the amounts of water stored in Canton Lake and streamflow at the Seiling, Okla., streamflow-gaging station were analyzed. Streamflow at the Seiling station decreased by a mean of 75 percent and was still diminished by 10 percent after 2011. In Reach II, the effect of drought on the streamflow at the Yukon, Okla., streamflow-gaging station was examined. The greatest mean streamflow decrease was approximately 60 percent during the simulated drought, and after 2011, the mean decrease in streamflow was still about 5 percent. Canton Lake storage decreased by as much as 83 percent during the simulated drought and did not recover by 2011.

Oklahoma↗

No evidence for cottonwood forest decline along a flow-augmented western U.S. river

In contrast to many other arid region rivers, streamflow in the South Platte River is heavily augmented by trans-basin water imports and irrigation return flows. Hydrological changes began in the 1880s, resulting in channel narrowing and the development of a continuous Populus-Salix forest by the mid-twentieth century. We assessed the composition, structure and regeneration status of the riparian forest and identified environmental variables affecting annual Populus deltoides tree growth. We sampled forest structure at four sites in 2015, and conducted dendroecological analysis at seven additional sites in 2019. The riparian forest was dominated by P. deltoides , which occurred at all sites, comprising 79% of total tree basal area and 62% of total tree density. Age structure data indicated ongoing though episodic recruitment of P. deltoides , at least over the past ~130 years. We tested 14 linear mixed effects models to describe the effect of climate and streamflow on individual tree growth (modeled as the log of BAI, n = 237 trees). The most parsimonious model selected with AICc explained 28.6% of BAI variability, and included hydrology and climate factors during the growing season (i.e., June–August streamflow, June–July PDSI), some aspects of off-season (i.e., previous November and March) streamflow, along with tree age and study site effects. The riparian forest developed in response to, and has been maintained by, current climate conditions and water management regimes. It may be negatively affected by future climate change and increased urban water demand in the basin.

Colorado↗

Geohydrology and water quality of the Mississippi River alluvial aquifer, northeastern Louisiana

The Mississippi River alluvial aquifer in northeastern Louisiana is in the alluvium of the Mississippi, Arkansas, and Ouachita Rivers and underlies approximately 5,000 square miles (13,000 square kilometers) in the Mississippi River valley. The aquifer, of Pleistocene age, is a southeastward-thickening wedge of sand and gravel that ranges in thickness from about 20 to 135 feet (6 to 41 metres). These sediments are essentially flat lying with an irregular base. Fine sand, silt, and clay of Holocene age overlie and generally confine the aquifer. These fine-grained deposits range in thickness from 0 to 100 feet (0 to 30 metres) but generally do not exceed 40 feet (12 metres). Water levels in the Mississippi River alluvial aquifer generally are less than 30 feet (9 metres) below land surface. Annual water-level fluctuations have a maximum range of about 20 feet (6 metres) near the Mississippi River and a minimum range of only a few feet in interstream areas. Seasonal declines occur locally, especially in Morehouse Parish, because of large withdrawals for irrigation. The Mississippi River alluvial aquifer can yield water in sufficient quantity for most uses throughout the area. Aquifer tests indicate that the transmissivity ranges from 13,000 to 45,000 feet squared per day (1,200 to 4,200 metres squared per day). The hydraulic conductivity ranges from 130 to 530 feet per day (40 to 160 metres per day). Storage coefficients range from 0.001 to 0.05. Large diameter wells yield as much as 7,000 gallons per minute (440 litres per second) near Tallulah in Madison Parish. The quality of ground water in the Mississippi River alluvial aquifer varies areally and with depth, but generally the water is hard to very hard and high in iron concentration, Where fresh, the water typically is a calcium bicarbonate type generally ranging in hardness from 200 to 600 mg/1 (milligrams per litre) and in iron concentration from 0.00 to 30 mg/1. However, in southern Richland Parish and local areas in adjacent parishes, a hardness of less than 100 mg/1 and an iron concentration of less than 0.30 mg/1 are common. Fresh water occurs to or below the base of the alluvial aquifer in most of the area. The chloride concentration typically is less than 50 mg/1. However, chloride concentrations are as high as 4,000 mg/1 in parts of the area. At some localities, salty water (chloride concentrations greater than 250 mg/1) occurs in the aquifer at depths less than 30 feet (9 metres). The largest occurrence of salty water is in Franklin Parish near and parallel to the subsurface contact between clays of the Jackson Group and sands of the Cockfield Formation of the Claiborne Group. Thus, salty water moving from the Cockfield into the alluvium may be the source of some of the high-chloride water. Smaller bodies of salty water occur in the aquifer along the Jackson-Cockfield contact in Madison and Caldwell Parishes. Probably some contamination from pits formerly used for disposal of salty water occurs in northern Franklin and southern Richland Parishes, Other small occurrences of salty water in Concordia, Morehouse, Ouachita, and Tensas Parishes may be related to contamination by salt-water disposal pits and wells, leaky oil-well casings, and oil-well drilling mishaps.

Louisiana↗

Hydrogeologic characterization, groundwater chemistry, and vulnerability assessment, Ute Mountain Ute Reservation, Colorado and Utah

The U.S. Geological Survey, in cooperation with the Ute Mountain Ute Tribe (UMUT), initiated a study in 2016 to increase understanding of the hydrogeology and chemistry of groundwater within select areas of the Ute Mountain Ute Reservation (UMUR) in Colorado and Utah, identify vulnerabilities to the system and other natural resources, and outline information needs to aid in the understanding and protection of groundwater resources. The results presented for this study can be used to support the UMUT’s goal of protecting their vital groundwater resources on the UMUR. Hydrogeologic conditions were characterized for the surficial aquifer contained in Quaternary-age unconsolidated surficial deposits and the Dakota aquifer contained in the Cretaceous-age Dakota Sandstone. In the surficial aquifer, median depth to water ranges from about 5.4 to 17.2 feet below land surface in the Farm and Ranch Enterprise area and 11 to 34 feet below land surface in the Towaoc area, and the water table slopes generally southwest or south. A map of depth to the top of the Dakota Sandstone was constructed from existing well data. Depths range from zero in outcrop areas to more than 3,000 feet below land surface on mesas in the southeastern part of the UMUR. Groundwater-chemistry data were collected by the UMUT from 13 springs and 31 wells from 1996 through 2017. Specific conductance was much lower for samples from springs than from wells; median values were 512 and 6,024 microsiemens per centimeter at 25 degrees Celsius, respectively. Spring samples were well oxygenated. A few well samples were anoxic (dissolved oxygen concentrations less than 0.5 milligrams per liter [mg/L]), indicating reducing conditions in the aquifer. About 75 percent of spring samples had fresh water (total dissolved solids concentrations less than 1,000 mg/L), and about 85 percent of well samples had brackish or highly saline water (total dissolved solids concentrations greater than 1,000 mg/L). Water type for springs on the Ute Mountains was calcium bicarbonate. Lower-altitude springs had a calcium-sulfate water type. Most well samples had sodium as the dominant cation, and sulfate, bicarbonate, and chloride as the dominant anions. Fluoride concentrations in about 45 percent of well samples were greater than an agricultural-use standard of 2 mg/L. Nitrate plus nitrite concentrations in most spring and well samples were less than about 1.6 mg/L per liter. Concentrations in samples from wells in the irrigated agricultural area were elevated; the maximum concentration was 78.5 mg/L. About one-half of the trace-element samples had concentrations that were less than laboratory reporting limits. Only aluminum, arsenic, and selenium in spring samples, and boron and selenium in well samples, were detected at concentrations greater than surface-water standards or water-quality standards for agricultural use of groundwater. Only three organic compounds, the pesticides alachlor and atrazine and the volatile organic compound di(2-ethylhexyl) phthalate, were detected in well samples. The Escherichia coli bacteria was detected in 47 and 23 percent of samples from wells and springs, respectively. The E. coli detections included samples from three culturally significant springs, which did not meet the UMUT cultural-use standard of total absence of E. coli. Tritium and carbon-14 were the primary environmental tracers used for interpreting groundwater ages for Lopez 2 Spring and five wells (AP–1, 5000 Block, Cottonwood Spring, Goodknight, and SE Toe). Water from the AP–1 well contained a mixture of pre- and post-1950s recharge. Tritium and carbon-14 recharge ages for Lopez 2 Spring (post-1950s in age), Goodknight and SE Toe wells (pre-1950s in age), and Cottonwood Spring well (primarily pre-1950s in age) are supported by helium-4 data. The helium-4 data for the 5000 Block well are inconsistent with the tritium and carbon-14 age of pre-1950s recharge because of interference caused by high methane concentrations in the water. Springs and surficial deposits are more vulnerable to contamination from anthropogenic chemicals than deeper bedrock wells. Bedrock aquifers are vulnerable in areas where the geologic formations containing the aquifers are exposed at the land surface. Groundwater in deep bedrock aquifers is likely thousands of years old and is not currently affected by present-day land uses. Both shallow and deep groundwater are vulnerable to naturally occurring salts and minerals, such as of total dissolved solids, major ions, nitrate, and trace elements. Effects of a changing climate on water resources and other ecological characteristics of the UMUR could include changes in evapotranspiration, a decrease in snowpack, decreased aquifer recharge and flow of springs, a decrease in soil moisture, and increased occurrence of wildfires and forest mortality. Of particular interest for the UMUT are possible effects of a changing climate on medicinal and culturally important plants and springs Several information needs were identified during this study that would aid in the understanding and protection of groundwater resources on the UMUR. These include well-completion information for bedrock wells, the collection of environmental tracer data at additional wells, the addition of methane and hydrocarbon analysis to well sampling plans, and the resampling of springs and wells that were last sampled in 2002 or earlier.

Colorado↗

Distribution and condition of larval and juvenile Lost River and shortnose suckers in the Williamson River Delta restoration project and Upper Klamath Lake, Oregon

Federally endangered Lost River sucker (Deltistes luxatus) and shortnose sucker (Chasmistes brevirostris) were once abundant throughout their range but populations have declined. They were extirpated from several lakes in the 1920s and may no longer reproduce in other lakes. Poor recruitment to the adult spawning populations is one of several reasons cited for the decline and lack of recovery of these species and may be the consequence of high mortality during juvenile life stages. High larval and juvenile sucker mortality may be exacerbated by an insufficient quantity of suitable or high-quality rearing habitat. In addition, larval suckers may be swept downstream from suitable rearing areas in Upper Klamath Lake into Keno Reservoir, where they are assumed lost to Upper Klamath Lake populations. The Nature Conservancy flooded about 3,600 acres (1,456 hectares) to the north of the Williamson River mouth (Tulana) in October 2007, and about 1,400 acres (567 hectares) to the south and east of the Williamson River mouth (Goose Bay Farms) in October 2008, in order to retain larval suckers in Upper Klamath Lake, create nursery habitat, and improve water quality. The U.S. Geological Survey joined a long-term research and monitoring program in collaboration with The Nature Conservancy, the Bureau of Reclamation, and Oregon State University in 2008 to assess the effects of the Williamson River Delta restoration on the early life-history stages of Lost River and shortnose suckers. The primary objectives of the research were to describe habitat colonization and use by larval and juvenile suckers and non-sucker fishes and to evaluate the effects of the restored habitat on the health and condition of juvenile suckers. This report summarizes data collected in 2010 by the U.S. Geological Survey as a part of this monitoring effort and follows two annual reports on data collected in 2008 and 2009. Restoration modifications made to the Williamson River Delta appeared to provide additional suitable rearing habitat for endangered Lost River and shortnose suckers from 2008 to 2010 based on sucker catches. Mean larval sample density was greater for both species in the Williamson River Delta than adjacent lake habitats in all 3 years. In addition to larval suckers, at least three age classes of juvenile suckers were captured in the delta. The shallow Goose Bay Farms and Tulana Emergent were among the most used habitats by age-0 suckers in 2009. Both of these environments became inaccessible due to low water in 2010, however, and were not sampled after July 19, 2010. In contrast, age-1 sucker catches shifted from the shallow water (about 0.5-1.5 m deep) on the eastern side of the Williamson River Delta in May, to deeper water environments (greater than 2 m) by the end of June or early July in all 3 years. Differential distribution among sucker species within the Williamson River Delta and between the delta and adjacent lakes indicated that shortnose suckers likely benefited more from the restored Williamson River Delta than Lost River or Klamath largescale suckers (Catostomus snyderi) . Catch rates in shallow-water habitats within the delta were higher for shortnose and Klamath largescale sucker larvae than for larval Lost River suckers in 2008, 2009, and 2010. Shortnose suckers also comprised the greatest portion of age-0 suckers captured in the Williamson River Delta in all 3 years of the study. The relative abundance of age-1 shortnose suckers was high in our catches compared to age-1 Lost River suckers in 2009 and 2010. The restored delta also created habitat for several piscivorous fishes, but only two appeared to pose a meaningful threat of predation to suckers - fathead minnows (Pimephales promelas) and yellow perch (Perca flavescens) . Fathead minnows that prey on larval but not juvenile suckers dominated catches in all sampling areas. Yellow perch also were abundant throughout the study area, but based on their gape size and co-occurrence with suckers, most were only capable of preying on larvae. Low May lake-surface elevation, below average snow pack, and anticipated irrigation demands indicated late summer water levels in Upper Klamath Lake would be unusually low in 2010. In response to concerns by the Fish and Wildlife Service and The Nature Conservancy that low-water conditions might strand fish on the delta, low water seine surveys were implemented. Eleven fishes, including both endangered suckers, were captured in seine surveys, including both species of suckers, which continued to use shallow water less than 0.4 m deep through September 21. Lake elevation declined to 1,261.54 m (4,138.9 feet) in mid-September 2010, but did not appear to strand fish or cause large-scale fish mortality.

Oregon↗

Chapter 11 The phosphoria formation: A model for forecasting global selenium sources to the environment

Mining of the Permian Phosphoria Formation — a marine, oil-generating, phosphatic shale — provided the selenium (Se) source implicated in the recent deaths of livestock in southeast Idaho. Field studies and the geohydrologic balance of Se in southeast Idaho confirm risk to animals from exposure to Se through leaching of mined waste shale into streams, discharge of regional drainage, and impoundment of drainage in wetland areas. Forage grown to stabilize waste rock contoured into hills or used as cross-valley fill provides an additional mechanism of Se exposure for the environment (Mackowiak et al., Chapter 19). The average Se concentration of the Meade Peak Member of the Phosphoria Formation is an order of magnitude higher than those of other exploited marine shales that have been linked to incidences of Se toxicosis via oil refining and irrigation in the western United States. The Phosphoria Formation accumulated in an environment that preserved organic matter and contributed to the formation of economic-grade phosphate and oil deposits. The addition of this phosphate-mining case study enables a comprehensive approach to the identification of marine sedimentary Se sources and a more complete range of ecotoxic field studies on which to establish the conditions and anthropogenic connections that determine uptake, release, and recycling of Se in food webs. A constructed conceptual model of Se pollution indicates that ancient organic-rich depositional marine basins, unre- stricted by age, are linked to the contemporary global distribution of Se source rocks. A global plot shows (a) the areal association of major basins hosting phosphate deposits and petroleum source rocks and (b) the importance of paleo-latitudinal setting in influencing the composition of the deposits. Given the geographic patterns, Se emerges as a contami- nant within specific regions of the globe that may limit phosphate mining, oil refining, and drainage of agricultural lands because of potential ecological risks to vulnerable food webs. Selenium also may serve as a geochemical exploration tool that signals an ancient productive biological environment.

Handbook of Exploration and Environmental Geochemi↗

Hydrology of Northern Utah Valley, Utah County, Utah, 1975-2005

The ground-water resources of northern Utah Valley, Utah, were assessed during 2003-05 to describe and quantify components of the hydrologic system, determine a hydrologic budget for the basin-fill aquifer, and evaluate changes to the system relative to previous studies. Northern Utah Valley is a horst and graben structure with ground water occurring in both the mountain-block uplands surrounding the valley and in the unconsolidated basin-fill sediments. The principal aquifer in northern Utah Valley occurs in the unconsolidated basin-fill deposits where a deeper unconfined aquifer occurs near the mountain front and laterally grades into multiple confined aquifers near the center of the valley. Sources of water to the basin-fill aquifers occur predominantly as either infiltration of streamflow at or near the interface of the mountain front and valley or as subsurface inflow from the adjacent mountain blocks. Sources of water to the basin-fill aquifers were estimated to average 153,000 (+/- 31,500) acre-feet annually during 1975-2004 with subsurface inflow and infiltration of streamflow being the predominant sources. Discharge from the basin-fill aquifers occurs in the valley lowlands as flow to waterways, drains, ditches, springs, as diffuse seepage, and as discharge from flowing and pumping wells. Ground-water discharge from the basin-fill aquifers during 1975-2004 was estimated to average 166,700 (+/- 25,900) acre-feet/year where discharge to wells for consumptive use and discharge to waterways, drains, ditches, and springs were the principal sources. Measured water levels in wells in northern Utah Valley declined an average of 22 feet from 1981 to 2004. Water-level declines are consistent with a severe regional drought beginning in 1999 and continuing through 2004. Water samples were collected from 36 wells and springs throughout the study area along expected flowpaths. Water samples collected from 34 wells were analyzed for dissolved major ions, nutrients, and stable isotopes of hydrogen and oxygen. Water samples from all 36 wells were analyzed for dissolved-gas concentration including noble gases and tritium/helium-3. Within the basin fill, dissolved-solids concentration generally increases with distance along flowpaths from recharge areas, and shallower flowpaths tend to have higher concentrations than deeper flowpaths. Nitrate concentrations generally are at or below natural background levels. Dissolved-gas recharge temperature data support the conceptual model of the basin-fill aquifers and highlight complexities of recharge patterns in different parts of the valley. Dissolved-gas data indicate that the highest elevation recharge sources for the basin-fill aquifer are subsurface inflow derived from recharge in the adjacent mountain block between the mouths of American Fork and Provo Canyons. Apparent ground-water ages in the basin-fill aquifer, as calculated using tritium/helium-3 data, range from 2 to more than 50 years. The youngest waters in the valley occur near the mountain fronts with apparent ages generally increasing near the valley lowlands and discharge area around Utah Lake. Flowpaths are controlled by aquifer properties and the location of the predominant recharge sources, including subsurface inflow and recharge along the mountain front. Subsurface inflow is distributed over a larger area across the interface of the subsurface mountain block and basin-fill deposits. Subsurface inflow occurs at a depth deeper than that at which mountain-front recharge occurs. Recharge along the mountain front is often localized and focused over areas where streams and creeks enter the valley, and recharge is enhanced by the associated irrigation canals.

Utah↗

Hydrology of the middle San Pedro area, southeastern Arizona

In the middle San Pedro Watershed in southeastern Arizona, groundwater is the primary source of water supply for municipal, domestic, industrial, and agricultural use. The watershed comprises two smaller subareas, the Benson subarea and the Narrows-Redington subarea. Early 21st century projections for heavy population growth in the watershed have not yet become a reality, but increased groundwater withdrawals could have undesired consequences - such as decreased base flow to the San Pedro River, and groundwater-level declines - that would lead to the need to deepen existing wells. This report describes the hydrology, hydrochemistry, water quality, and development of a groundwater budget for the middle San Pedro Watershed, focusing primarily on the elements of groundwater movement that could be most useful for the development of a groundwater model Precipitation data from Tombstone, Arizona, and base flow at the stream-gaging station on the San Pedro River at Charleston both show relatively dry periods during the 1960s through the mid-1980s and in the mid-1990s to 2009, and wetter periods from the mid-1980s through the mid-1990s. Water levels in four out of five wells near the mountain fronts show cyclical patterns of recharge, with rates of recharge greatest in the early 1980s through the mid-1990s. Three wells near the San Pedro River recorded their lowest levels during the 1950s to the mid-1960s. The water-level record from one well, completed in the confined part of the coarse-grained lower basin fill, showed a decline of approximately 21 meters. Annual flow of the San Pedro River, measured at the Charleston and Redington gages, has decreased since the 1940s. The median annual streamflow and base flow at the gaging station on the river near Tombstone has decreased by 50 percent between the periods 1968–1986 and 1997–2009. Estimates of streamflow infiltration along the San Pedro River during 1914–2009 have decreased 44 percent, with the largest decreases in the months June–October in the Benson subarea. In the Narrows-Redington subarea, streamflow infiltration has decreased about 65 percent during 1914–2009. The average annual outflow (27.6 hm 3 /year [cubic hectometers per year]) from the Benson subarea aquifer for water years 2001 through 2009 exceeded the inflows (20.0 hm 3 / yr) by 7.60 hm 3 /yr. In the Narrows-Redington subarea for the same period, the average annual outflow (15.7 hm 3 /yr) from the aquifer system exceeded the inflows (13.8 hm 3 /yr) by nearly 2 hm 3 /yr. The largest withdrawals of groundwater in both subareas are for irrigation; these withdrawals peaked in 1973 and have been steadily decreasing since then. Recharge from streamflow infiltration exceeded recharge from the mountain-front and from ephemeral channels in the Benson subarea. In the Narrows-Redington subarea, however, recharge from mountain-front and ephemeral channel recharge exceeded recharge from streamflow infiltration. Evapotranspiration by phreatophytes accounts for the largest outflow of groundwater for both subareas—78 percent of the outflow in the Narrows-Redington subarea and 62 percent of the outflow in the Benson subarea. Precipitation, surface-water, and groundwater chemistry and isotope data indicated the relative age and residence time of groundwater, the amount of interaction between geologic sources and groundwater, and how recharge elevation and season were related to the presence of modern water. The bedrock aquifer receives modern recharge (

Arizona↗

Numerical simulation of the alluvium and terrace aquifer along the North Canadian River from Canton Lake to Lake Overholser, central Oklahoma

Alluvium and terrace deposits of Quaternary age, which cover an area of about 400 square miles along the North Canadian River between Canton Lake and Lake Overholser, locally yield as much as 500 gallons per minute to wells. The deposits are as much as 100 feet thick and consist of clay, silt, sand, and gravel, with sand-sized material dominating. The underlying bedrock is Permian sandstone and shale. The amount of water stored in the aquifer during 1980 was estimated to be 4.00 x 1010 cubic feet. A digital model was used to estimate the ability of the aquifer to continue to supply water for irrigation, industry, and domestic use. A block-centered, finite-difference model with 1 mile node spacing was used to project the amount and distribution of water in the aquifer in the future. The model was calibrated using the aquifer discharge to the North Canadian River and the difference between computed and measured heads. The model was calibrated using recharge rate of 1 inch per year, a horizontal hydraulic conductivity of 4.5 x 10 -4 feet per second and a specific yield of 0.16. Model simulations using the 1979 pumping rate, a projected pumping rate (based on expected increases in water use), and double the projected increase in pumping rate were made to 1993. With the 1979 pumping rate, the volume of water in storage in 1993 is 3.88 x 10 10 cubic feet and ground-water discharge to the North Canadian River is 10.9 cubic feet per second. With the projected pumping increase, the volume of water in storage is 3.81 x 1010 cubic feet and ground-water discharge to the stream is 6.91 cubic feet per second. At double the projected increase in pumping rate, the volume of water in storage is 3.74 x 1010 cubic feet and the ground-water discharge is 2.93 cubic feet per second.

Water-Resources Investigations Report↗

Ground-water resources and geology of northern and central Johnson County, Wyoming

Northern and central Johnson County, Wyo., is an area of about 2,600 square miles that lies principally in the western part of the Powder River structural basin but also includes the east flank of the Bighorn Mountains. Sedimentary rocks exposed range in age from Cambrian to Recent and have an average total thickness of about 16,000 feet. Igneous and metamorphic rocks of Precambrian age crop out in the Bighorn Mountains. Rocks of pre-Tertiary age, exposed on the flanks and in the foothills of the Bighorns, dip steeply eastward and lie at great depth in the Powder River basin. The rest of the project area is underlain by a thick sequence of interbedded sandstone, siltstone, and shale of Paleocene and Eocene age. Owing to the regional structure, most aquifers in Johnson County contain water under artesian pressure. The Madison Limestone had not been tapped for water in Johnson County at the time of the present investigation (1963), but several wells in eastern Big Horn and Washakie Counties, on the west flank of the Bighorn Mountains, reportedly have flows ranging from 1,100 to 2,800 gallons per minute. Comparable yields can probably be obtained from the Madison in Johnson County in those areas where the limestone is fractured or cavernous. The Tensleep Sandstone reportedly yields 600 gallons per minute to a pumped irrigation well near its outcrop in the southwestern part of the project area. Several flowing wells tap the formation on the west flank of the Bighorn Mountains. The Madison Limestone and the Tensleep Sandstone have limited potential as sources of water because they can be developed economically only in a narrow band paralleling the Bighorn Mountain front in the southwestern part of the project area. Overlying the Tensleep Sandstone is about 6,000 feet of shale, siltstone, and fine-grained sandstone that, with a few exceptions, normally yields only small quantities of water to wells. The Cloverly Formation and the Newcastle Sandstone may yield moderate quantities of water to wells; but, in some areas, properly constructed wells tapping both formations might yield large quantities of water. The Shannon Sandstone Member of the Cody Shale will probably yield only small quantities of water to Wells, but it is the best potential source of ground water in the stratigraphic interval between the Newcastle and Parkman Sandstones. The Parkman Sandstone and the Lance Formation yield water to relatively shallow wells principally in the southwestern part of the project area. The Fort Union Formation yields adequate supplies of water for stock and domestic use from relatively shallow wells near its outcrop almost everywhere in the county. A few deep wells tap the Fort Union along the Powder River valley in the northeastern part of Johnson County. Some of these wells flow, but their flows rarely exceed 10 gallons per minute; larger yields could be undoubtedly be obtained by pumping. The Wasatch Formation is the principal source of ground water in Johnson County. It yields adequate supplies to many relatively shallow stock and domestic wells, some of which flow, but much larger yields probably would require pumping lifts that are prohibitive for most purposes. The Kingsbury Conglomerate and Moncrief Members of the Wasatch Formation, though, may yield moderate quantities of water in some places. Alluvial deposits underlying the valleys of the Powder River and Crazy Woman, Clear, and Piney Creeks are potential sources of moderate to large supplies of water in the Powder River drainage basin. The permeability of these deposits decreases with distance from the Bighorn Mountain front, so that largest yields can probably be obtained along the upper reaches of these streams. Most ground water utilized in the project area is for domestic and stock supplies and is obtained from drilled wells and from springs. Water for irrigation is obtained almost entirely by diverting flows of perennial streams. The discharge of wel

Water Supply Paper↗

Insights into controls on hexavalent chromium in groundwater provided by environmental tracers, Sacramento Valley, California, USA

Environmental tracers are useful for determining groundwater age and recharge source, yet their application in studies of geogenic Cr(VI) in groundwater has been limited. Environmental tracer data from 166 wells located in the Sacramento Valley, northern California, were interpreted and compared to Cr concentrations to determine the origin and age of groundwater with elevated Cr(VI), and better understand where Cr(VI) becomes mobilized and how it evolves along flowpaths. In addition to major ion and trace element concentrations, the dataset includes &delta; 18 O, &delta; 2 H, 3 H concentration, 14 C activity (of dissolved inorganic C), &delta; 13 C, 3 He/ 4 He ratio, and noble gas concentrations (He, Ne, Ar, Kr, Xe). Noble gas recharge temperatures (NGTs) were computed, and age-related tracers were interpreted in combination to constrain the age distribution in samples and sort them into six different age categories spanning from <60 yr old to >10,000 yr old. Nearly all measured Cr is in the form of Cr(IV). Concentrations range from <1 to 46 &mu;g L &minus;1 , with 10% exceeding the state of California&rsquo;s Cr(VI) maximum contaminant level of 10 &mu;g L &minus;1 . Two groups with elevated Cr(VI) (⩾5 &mu;g L &minus;1 ) were identified. Group 1 samples are from the southern part of the valley and contain modern (<60 yr old) water, have elevated NO 3 &minus; concentrations (>3 mg L &minus;1 ), and commonly have &delta; 18 O values enriched relative to local precipitation. These samples likely contain irrigation water and are elevated due to accelerated mobilization of Cr(VI) in the unsaturated zone (UZ) in irrigated areas. Group 2 samples are from throughout the valley and typically contain water 1000&ndash;10,000 yr old, have &delta; 18 O values consistent with local precipitation, and have unexpectedly warm NGTs. Chromium(VI) concentrations in Group 2 samples may be elevated for multiple reasons, but the hypothesis most consistent with all available data (notably, the warm NGTs) is a relatively long UZ residence time due to recharge through a deep UZ near the margin of the basin. A possible explanation for why Cr(VI) may be primarily mobilized in the UZ rather than farther along flowpaths in the oxic portion of the saturated zone is more dynamic cycling of Mn in the UZ due to transient moisture and redox conditions.

California↗

Ground water in the Eola-Amity Hills area, northern Willamette Valley, Oregon

The Eola-Amity Hills area ,comprises about 230 square miles on the west side of the Willamette Valley between Salem and McMinnville, Oreg. The area is largely rural, and agriculture is the principal occupation. Rocks ranging in age from Eocene to Recent underlie the area. The oldest rocks are a sequence more than 5,000 feet thick of marine-deposited shale and siltstone strata, with thin interbeds of sandstone that range in age from Eocene to middle Oligocene. They are widely exposed in and west of the Eola-Amity Hills and underlie younger sedimentary and volcanic rocks throughout the study area. In the Eola-Amity Hills and Red Hills of Dundee, the Columbia River Group, a series of eastward-dipping basaltic lava flows locally of Miocene age, and conformably overlies the marine sedimentary rocks. The Columbia River Group ranges in thickness from less than 1 foot to about 900 feet and has an average thickness of about 200 feet. The formation is exposed in the Eola-Amity Hills and Red Hills of Dundee and, at places, extends to the east beneath younger rocks. Overlying the Columbia River Group and marine sedimentary rocks are nonmarine sedimentary deposits that range in thickness from less than 1 foot, where they lap up (to an altitude of about 200 ft) on the flanks of the higher hills, to several hundred feet along the east margin of the study area. These deposits include the Troutdale Formation of Pliocene age, the Willamette Silt of late Pleistocene age, and alluvium of the Willamette River and its tributaries. The Troutdale Formation and the alluvium of the Willamette River contain the most productive aquifers in the Eola-Amity Hills area. These aquifers, which consist mainly of sand and gravel, generally yield moderate to large quantities of water to properly constructed wells. Basalt of the Columbia River Group yields small to moderate quantities of water to wells, and the marine sedimentary rocks and Willamette Silt generally yield small but adequate quantities of water for domestic and stock supplies. Ground water from the Columbia River Group and nonmarine sedimentary rocks is chemically suitable for irrigation and other uses, as is the water from shallow depths in the marine sedimentary rocks. However, water from depths of more than several hundred feet in the marine sedimentary rocks contains large amounts of chloride and other dissolved mineral constitutents that make it unsuitable for most uses. Samples from three fairly closely spaced wells obtaining water from depth zones of 50 to 77, 191 to 201, and about 2,000 feet contained 172, 1,160, and 26,000 ppm (parts per million) of chloride, respectively. About 6,100 acre-feet of ground water was pumped from wells and withdrawn from springs for various uses during 1964; of this amount about 4,800 acre-feet was used for irrigation. The total volume of ground water withdrawn and put to beneficial use each year is small compared with the amount that discharges naturally by evapotranspiration and through undeveloped seeps and springs. Much of the natural discharge could be intercepted and put to beneficial use by pumping from wells. Major problems affecting the development of ground water in the area include a) uneven areal distribution of permeable rocks, (b) undesirable chemical quality of the ground water locally in the marine sedimentary rocks, and (c) fine sand entering wells that tap the Troutdale Formation and thereby causing loss of well efficiency and costly wear on pumps and water-supply systems.

Water Supply Paper↗

Ground-water resources of the Rapid Valley unit, Cheyenne Division, South Dakota, with a section on the surface waters of Rapid Valley

The Rapid Valley unit is in Pennington County, S. Dak., and extends from the east city limits of Rapid City southeastward for 21 miles along Rapid Creek. The bedrock formations that underlie the region are chiefly marine in origin, and they generally dip eastward from the center of the Black Hills uplift. The exposed formations are of Cretaceous age and consist of the Greenhorn limestone, the Carlile shale, the Niobrara formation, and the Pierre shale. The Pierre shale, which underlies the unconsolidated flood plain and terrace deposits in much Of the region is exposed in the erosional slopes along the south side of the valley and in the deeper draws on the north side. The areas in which the other formations are exposed are relatively small and are restricted to the western part of-the region. Four terraces are present on the north side of Rapid Creek. The lowest terrace and the flood plain in the western half of the region are irrigated at the present time, and the two lower terraces and the flood plain in the eastern half have been proposed for irrigation. Abundant supplies of ground water occur in the flood plain and terrace deposits where they are now irrigated. Because the waterbearing materials consist of interfingering layers of differing permeability, the ground water is under water-table conditions in some places whereas it is confined in others. Locally, where there is a confining layer below other water-bearing materials or where a confined layer is itself saturated, the ground water may occur under both water-table and artesian conditions. Seepage from irrigation canals, which is the principal source of recharge, causes high ground-water levels from June to November; as a result, parts of the areas have become waterlogged. In the parts of the region that are not now affected by irrigation, the surface of the ground water is only a few feet above the bedrock surface and 6 ft to 42 ft below land surface; its position is relatively constant throughout the year. Harmful concentrations of salt in the soil are in part due to evaporation of ground water. These are found only locally in the Rapid Valley region and do not present a serious problem at this time. It is thought, however, that the fine-grained materials underlying the Rapid terrace may contain sufficient salt to cause detrimental salt accumulations in the soil if the proposed irrigation causes ground-water levels to rise close to the surface. Lining of the irrigation canals would reduce the amount of seepage and would effect a lowering of ground-water levels, if irrigation practices are extended to other areas, drainage facilities will be necessary both to avoid aggravating the existing conditions of waterlogging and to prevent the waterlogging of other low-lying lands. The flow of Rapid Creek is affected by a variety of conditions. A few miles west of Rapid City, where Rapid Creek flows over the Englewood and Pahasapa limestones and the Minnelusa sandstone, there is a loss of about 8 cfs of water in a distance of a few miles. In the 3-mile reach of Rapid Creek between the Canyon Lake stream-gaging station and the Rapid City stream-gaging station there is a gain of about 20 cfs; much of this gain in flow may be attributed to the inflow from Cleghorn and Jackson springs and to the addition of water from the State-owned cement plant. In the Rapid Valley unit, the flow of the creek during the irrigation season is affected largely by the amount of water diverted for irrigation. The irrigation canals act as bypass channels, much of the water being returned to Rapid Creek by way of spillage into normally dry tributary creek channels and by movement through ground-water bodies that discharge into Rapid Creek.

South Dakota↗