Gas buildup in Lake Nyos, Cameroon: The recharge process and its consequences

Abstract

The gases dissolved in Lake Nyos, Cameroon, were quantified recently (December 1989 and September 1990) by two independent techniques: in-situ measurements using a newly designed probe and laboratory analyses of samples collected in pre-evacuated stainless steel cylinders. The highest concentrations of CO 2 and CH 4 were 0.30 mol/kg and 1.7 mmol/kg, respectively, measured in cylinders collected 1 m above lake bottom. Probe measurements of in-situ gas pressure at three different stations showed that horizontal variations in total dissolved gas were negligible. Total dissolved-gas pressure near the lake bottom is 1.06 MPa (10.5 atm), 50% as high as the hydrostatic pressure of 2.1 MPa (21 atm). Comparing the CO 2 profile constructed from the 1990 data to one obtained in May 1987 shows that CO 2 concentrations have increased at depths to below 150 m. Based on these profiles, the average rate of CO 2 input to bottom waters was 2.6 × 10 8 mol/a. Increased deep-water temperatures require an average heat flow of 0.32 MW into the hypolimnion over the same time period. The transport rates of CO 2 , heat, and major ions into the hypolimnion suggest that a low-temperature reservoir of free CO 2 exists a short distance below lake bottom and that convective cycling of lake water through the sediments is involved in transporting the CO 2 into the lake from the underlying diatreme. Increased CH 4 concentrations at all depths below the oxycline and a high 14 C content (41% modern) in the CH 4 4 m above lake bottom show that much of the CH 4 is biologically produced within the lake. The CH 4 production rate may vary with time, but if the CO 2 recharge rate remains constant, CO 2 saturation of the entire hypolimnion below 50 m depth would require ∼140a, given present-day concentrations.