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Research about San Francisco Bay

Source-linked reports with geographic coverage including San Francisco Bay.

At least 235 records · Page 13Linked to original sources

The impact of human activities on sediments of San Francisco Bay, California: an overview

This note introduces a set of eight papers devoted to a detailed study of two sediment cores from San Francisco Bay with an overview of the region and a chronology of human activities. Data used in this study to constrain the range of sediment ages at different depths include , and concentrations in the sediment and the age of shell fragments. In order of first detectable appearance in the record, the indicators of contamination that were analyzed include PAHs>Hg>Ag, Cu, Pb, Zn>DDT, PCB>foraminiferal Cd/Ca. This study also documents a large memory effect for estuarine contamination caused by sediment mixing and resuspension. Once an estuary such as San Francisco Bay has been contaminated, decades must pass before contaminant levels in surface sediment will return to background levels, even if external contaminant inputs have been entirely eliminated.

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Sediment chronology in San Francisco Bay, California, defined by 210 Pb, 234 Th, 137 Cs, and 239,340 Pu

Sediment chronologies based on radioisotope depth profiles were developed at two sites in the San Francisco Bay estuary to provide a framework for interpreting historical trends in organic compound and metal contaminant inputs. At Richardson Bay near the estuary mouth, sediments are highly mixed by biological and/or physical processes. Excess penetration ranged from 2 to more than 10 cm at eight coring sites, yielding surface sediment mixing coefficients ranging from 12 to 170 cm 2 /year. At the site chosen for contaminant analyses, excess activity was essentially constant over the upper 25 cm of the core with an exponential decrease below to the supported activity between 70 and 90 cm. Both and penetrated to 57-cm depth and have broad subsurface maxima between 33 and 41 cm. The best fit of the excess profile to a steady state sediment accumulation and mixing model yielded an accumulation rate of 0.825 g/cm 2 /year (0.89 cm/year at sediment surface), surface mixing coefficient of 71 cm 2 /year, and 33-cm mixed zone with a half-Gaussian depth dependence parameter of 9 cm. Simulations of and profiles using these parameters successfully predicted the maximum depth of penetration and the depth of maximum and activity. Profiles of successive 1-year hypothetical contaminant pulses were generated using this parameter set to determine the age distribution of sediments at any depth horizon. Because of mixing, sediment particles with a wide range of deposition dates occur at each depth. A sediment chronology was derived from this age distribution to assign the minimum age of deposition and a date of maximum deposition to a depth horizon. The minimum age of sediments in a given horizon is used to estimate the date of first appearance of a contaminant from its maximum depth of penetration. The date of maximum deposition is used to estimate the peak year of input for a contaminant from the depth interval with the highest concentration of that contaminant. Because of the extensive mixing, sediment-bound constituents are rapidly diluted with older material after deposition. In addition, contaminants persist in the mixed zone for many years after deposition. More than 75 years are required to bury 90% of a deposited contaminant below the mixed zone. Reconstructing contaminant inputs is limited to changes occurring on a 20-year time scale. In contrast, mixing is much lower relative to accumulation at a site in San Pablo Bay. Instead, periods of rapid deposition and/or erosion occurred as indicated by frequent sand-silt laminae in the X-radiograph. , , and excess activity all penetrated to about 120 cm. The distinct maxima in the fallout radionuclides at 105–110 cm yielded overall linear sedimentation rates of 3.9 to 4.1 cm/year, which are comparable to a rate of 4.5±1.5 cm/year derived from the excess profile.

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Constraints on the sedimentation history of San Francisco Bay from 14C and 10Be

Industrialization and urbanization around San Francisco Bay as well as mining and agriculture in the watersheds of the Sacramento and San Joaquin rivers have profoundly modified sedimentation patterns throughout the estuary. We provide some constraints on the onset of these erosional disturbances with 10Be data for three sediment cores: two from Richardson Bay, a small embayment near the mouth of San Francisco Bay, and one from San Pablo Bay, mid-way between the river delta and the mouth. Comparison of pre-disturbance sediment accumulation determined from three 14C-dated mollusk shells in one Richardson Bay core with more recent conditions determined from the distribution of 210Pb and 234Th [Fuller, C.C., van Geen, A., Baskaran, M, Anima, R.J., 1999. Sediment chronology in San Francisco Bay, California, defined by 210Pb, 234Th, 239,240Pu.] shows that the accumulation rate increased by an order of magnitude at this particular site. All three cores from San Francisco Bay show subsurface maxima in 10Be concentrations ranging in magnitude from 170 to 520 x 106 atoms/g. The transient nature of the increased 10Be input suggests that deforestation and agricultural develop- ment caused basin-wide erosion of surface soils enriched in 10Be. probably before the turn of the century.

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Stable lead isotopic analyses of historic and contemporary lead contamination of San Francisco Bay estuary

Variations in stable lead isotopic composition (240Pb, 206Pb, 207Pb, 208Pb) in three sediment cores from the San Francisco Bay estuary document temporal changes in sources of lead during the past two centuries. Sediment, with lead from natural geologic sources, and relatively homogeneous lead isotopic compositions are overlain by sediments whose isotopic compositions indicate change in the sources of lead associated with anthropogenic modification of the estuary. The first perturbations of lead isotopic composition in the cores occur in the late 1800s concordant with the beginning of industrialization around the estuary. Large isotopic shifts, toward lower 206Pb/207Pb, occur after the turn of the century in both Richardson and San Pablo Bays. A similar relationship among lead isotopic compositions and lead concentrations in both Bays suggest contamination from the same source (a lead smelter). The uppermost sediments (post 1980) of all cores also have a relatively homogenous lead isotopic composition distinct from pre-anthropogenic and recent aerosol signatures. Lead isotopic compositions of leachates from fourteen surface sediments and five marsh samples from the estuary were also analyzed. These analyses suggest that the lead isotopic signature identified in the upper horizons of the cores is spatially homogeneous among recently deposited sediments throughout the estuary. Current aerosol lead isotopic compositions [Smith, D.R., Niemeyer, S., Flegal, A.R., 1992. Lead sources to California sea otters: industrial inputs circumvent natural lead biodepletion mechanisms. Environmental Research 57, 163-175] are distinct from the isotopic compositions of the surface sediments, suggesting that the major source of lead is cycling of historically contaminated sediments back through the water column. Both the upper core sediments and surface sediments apparently derive their lead predominantly from sources internal to the estuary. These results support the idea that geochemical cycling of lead between sediments and water accounts for persistently elevated lead concentrations in the water column despite 10-fold reduction of external source inputs to San Francisco Bay [Flegal, A.R., Rivera-Duarte, I., Ritson, P.I., Scelfo, G., Smith, G.J., Gordon, M., Sanudo-Wilhelmy, S.A., 1996. Metal contamination in San Francisco Waters: historic perturbations, contemporary concentrations, and future considerations in San Francisco Bay. In: Hollobaugh, J.T. (Ed.), The Ecosystem. AAAS, pp. 173-188].

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Sedimentary record of anthropogenic and biogenic polycyclic aromatic hydrocarbons in San Francisco Bay, California

Dated sediment cores collected from Richardson and San Pablo Bays in San Francisco Bay were used to reconstruct a history of polycyclic aromatic hydrocarbon (PAH) contamination. The sedimentary record of PAHs in Richardson Bay shows that anthropogenic inputs have increased since the turn of the century, presumably as a result of increasing urbanization and industrialization around the Bay Area. Concentrations range from about 0.04-6.3 ??g g-1. The dominant origin of the PAHs contributing to this modern contamination is from combustion processes. Depth profiles in San Pablo Bay indicate higher concentrations of PAHs since the 1950s than during the late 1800s, also presumably resulting from an increase in urbanization and industrialization. Total PAHs in San Pablo Bay range from about 0.04-1.3 ??g g-1. The ratios of methylphenanthrenes/phenanthrene and (methylfluoranthenes + methylpyrenes)/fluoranthene were sensitive indicators of anthropogenic influences in the estuary. Variations in the ratio of 1,7-dimethylphenanthrene/2,6-dimethylphenanthrene indicate a gradual replacement of wood by fossil-fuel as the main combustion source of PAHs in. San Francisco Bay sediments. The profile of perylene may be an indicator of eroding peat from marshlands.

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A record of hydrocarbon input to San Francisco Bay as traced by biomarker profiles in surface sediment and sediment cores

San Francisco Bay is one of the world's largest urbanized estuarine systems. Its water and sediment receive organic input from a wide variety of sources; much of this organic material is anthropogenically derived. To document the spatial and historical record of the organic contaminant input, surficial sediment from 17 sites throughout San Francisco Bay and sediment cores from two locations Richardson Bay and San Pablo Bay were analyzed for biomarker constituents. Biomarkers, that is, 'molecular fossils', primarily hopanes, steranes, and n-alkanes, provide information on anthropogenic contamination, especially that related to petrogenic sources, as well as on recent input of biogenic material. The biomarker parameters from the surficial sediment and the upper horizons of the cores show a dominance of anthropogenic input, whereas the biomarker profiles at the lower horizons of the cores indicate primarily biogenic input. In the Richardson Bay core the gradual upcore transition from lower maturity background organics to a dominance of anthropogenic contamination occurred about 70-100 years ago and corresponds to the industrial development of the San Francisco Bay area. In San Pablo Bay, the transition was very abrupt, reflecting the complex depositional history of the area. This sharp transition, perhaps indicating a depositional hiatus or erosional period, dated at pre-1952, is clearly visible. Below, the hiatus the biomarker parameters are immature; above, they are mature and show an anthropogenic overlay. Higher concentrations of terrigenous n-alkanes in the upper horizons in this core are indicative of an increase in terrigenous organic matter input in San Pablo Bay, possibly a result of water diversion projects and changes in the fresh water flow into the Bay from the Delta. Alternatively, it could reflect a dilution of organic material in the lower core sections with hydraulic mining debris.

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Historical trends of metals in the sediments of San Francisco Bay, California

Concentrations of Ag, Al, Cr, Cu, Fe, Hg, Mn, Ni, Pb, V and Zn were determined in six sediment cores from San Francisco Bay (SFB) and one sediment core in Tomales Bay (TB), a reference estuary. SFB cores were collected from between the head of the estuary and its mouth (Grizzly Bay, GB; San Pablo Bay, SP; Central Bay, CB; Richardson Bay, RB, respectively) and ranged in length from 150 to 250 cm. Concentrations of Cr, V and Ni are greater than mean crustal content in SFB and TB sediments, and greater than found in many other coastal sediments. However, erosion of ultramafic rock formations in the watershed appears to be the predominant source. Baseline concentrations of other metals were determined from horizons deposited before sediments were influenced by human activities and by comparing concentrations to those in TB. Baseline concentrations of Cu co-varied with Al in the SFB sediments and ranged from 23.7±1.2 μg/g to 41.4±2.4 μg/g. Baseline concentrations of other metals were less variable: Ag, 0.09±0.02 μg/g; Pb, 5.2±0.7 μg/g; Hg, 0.06±0.01 μg/g; Zn, 78±7 μg/g. The earliest anthropogenic influence on metal concentrations appeared as Hg contamination (0.3–0.4 μg/g) in sediments deposited at SP between 1850 and 1880, apparently associated with debris from hydraulic gold mining. Maximum concentrations of Hg within the cores were 20 times baseline. Greater inventories of Hg at SP and GB than at RB verified the importance of mining in the watershed as a source. Enrichment of Ag, Pb, Cu and Zn first appeared after 1910 in the RB core, later than is observed in Europe or eastern North America. Maximum concentrations of Ag and Pb were 5–10 times baseline and Cu and Zn concentrations were less than three times baseline. Large inventories of Pb to the sediments in the GB and SP cores appeared to be the result of the proximity to a large Pb smelter. Inventories of Pb at RB are similar to those typical of atmospheric inputs, although influence from the Pb smelter is also suspected. Concentrations of Hg and Pb have decreased since the 1970s (to 0.30 μg/g and 25 μg/g, respectively) and were similar among all cores in 1990. Early Ag contamination was perhaps a byproduct of the Pb smelting process, but a modern source of Ag is also indicated, especially at RB and CB.

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Chlorinated hydrocarbon pesticides and polychlorinated biphenyls in sediment cores from San Francisco Bay

Sediment cores of known chronology from Richardson and San Pablo Bays in San Francisco Bay, CA, were analyzed for a suite of chlorinated hydrocarbon pesticides and polychlorinated biphenyls to reconstruct a historic record of inputs. Total DDTs (DDT = 2,4'- and 4,4'-dichlorodiphenyltrichloroethane and the metabolites, 2,4'- and 4,4'-DDE, -DDD) range in concentration from 4-21 ng/g and constitute a major fraction (> 84%) of the total pesticides in the top 70 cm of Richardson Bay sediment. A subsurface maximum corresponds to a peak deposition date of 1969-1974. The first measurable DDT levels are found in sediment deposited in the late 1930's. The higher DDT inventory in the San Pablo relative to the Richardson Bay core probably reflects the greater proximity of San Pablo Bay to agricultural activities in the watershed of the Sacramento and San Joaquin rivers. Total polychlorinated biphenyls (PCBs) occur at comparable levels in the two Bays (< 1-34 ng/g). PCBs are first detected in sediment deposited during the 1930's in Richardson Bay, about a decade earlier than the onset of detectable levels of DDTs. PCB inventories in San Pablo Bay are about a factor of four higher in the last four decades than in Richardson Bay, suggesting a distribution of inputs not as strongly weighed towards the upper reaches of the estuary as DDTs. The shallower subsurface maximum in PCBs compared to DDT in the San Pablo Bay core is consistent with the imposition of drastic source control measures four these constituents in 1970 and 1977 respectively. The observed decline in DDT and PCB levels towards the surface of both cores is consistent with a dramatic drop in the input of these pollutants once the effect of sediment resuspension and mixing is taken into account.

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Specific conductance, water temperature, and water level data, San Francisco Bay, California, water year 1998

Specific conductance and water temperature data are continuously recorded at four sites in San Francisco Bay, California: San Pablo Strait at Point San Pablo, Central San Francisco Bay at Presidio Military Reservation, Pier 24 at Bay Bridge, and South San Francisco Bay at San Mateo Bridge near Foster City (Figure 1). Water level data are recorded only at San Pablo Strait at Point San Pablo. These data were recorded by the Department of Water Resources (DWR) before 1988, by the US Geological Survey (USGS) National Research Program from 1988 to 1989, and by the USGS-DWR cooperative program since 1990. This article presents time-series plots of data from the four sites in San Francisco Bay during water year 1998 (1 October 1997 through 30 September 1998).

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Source character of microseismicity in the San Francisco Bay block, California, and implications for seismic hazard

We examine relocated seismicity within a 30-km-wide crustal block containing San Francisco Bay and bounded by two major right-lateral strike-slip fault systems, the Hayward and San Andreas faults, to determine seismicity distribution, source character, and possible relationship to proposed faults. Well-located low-level seismicity ( M d ≦ 3.0) has occurred persistently within this block throughout the recording interval (1969 to 1995), with the highest levels of activity occurring along or directly adjacent to (within ∼5 km) the bounding faults and falling off toward the long axis of the bay. The total seismic moment release within the interior of the Bay block since 1969 is equivalent to one M L 3.8 earthquake, one to two orders of magnitude lower than activity along and within 5 km of the bounding faults. Focal depths of reliably located events within the Bay block are generally less than 13 km with most seismicity in the depth range of 7 to 12 km, similar to focal depths along both the adjacent portions of the San Andreas and Hayward faults. Focal mechanisms for M d 2 to 3 events within the Bay block mimic focal mechanisms along the adjacent San Andreas fault zone and in the East Bay, suggesting that Bay block is responding to a similar regional stress field. Two potential seismic source zones have been suggested within the Bay block. Our hypocentral depths and focal mechanisms suggest that a proposed subhorizontal detachment fault 15 to 18 km beneath the Bay is not seismically active. Several large-scale linear NW-trending aeromagnetic anomalies within the Bay block were previously suggested to represent large through-going subvertical fault zones. The two largest earthquakes (both M d 3.0) in the Bay block since 1969 occur near two of these large-scale linear aeromagnetic anomalies; both have subvertical nodal planes with right-lateral slip subparallel to the magnetic anomalies, suggesting that structures related to the anomalies may be capable of brittle failure. Geodetic, focal mechanism and seismicity data all suggest the Bay block is responding elastically to the same regional stresses affecting the bounding faults; however, continuous Holocene reflectors across the proposed fault zones suggest that if the magnetic anomalies represent basement fault zones, then these faults must have recurrence times one to several orders of magnitude longer than on the bounding faults.

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Elemental contaminants in the livers and ingesta of four subpopulations of the American coot (Fulica americana): An herbivorous winter migrant in San Francisco Bay

Water birds with diets high in animal foods in the San Francisco Bay area are exposed to trace elements that are potentially health impairing. Water birds with herbivorous diets have been less thoroughly examined. The concentrations of trace elements in the livers and the esophageal contents of an herbivorous water bird, the American coot ( Fulica americana ) were measured to compare levels of contaminant exposure among different locations in the Bay system and with other water birds. A total of 39 coots were collected from four sites: Napa River and Mare Island Strait in the north, Berkeley in the middle, and Coyote Creek in the south. Livers of Berkeley samples differed significantly from those of Napa River and Mare Island Strait by their greater concentrations of As and B and lower concentrations of Cu, but they seemed to be within normal ranges for birds. Otherwise the concentrations of trace elements in the livers did not differ among sites. Ingesta samples from Berkeley differed from the other sites because they tended to be higher in Al, V, and Zn. In contrast to waterfowl, livers from the herbivorous coots in San Francisco Bay showed little exposure to Cd, Hg, Pb, or Se. Coot ingesta showed few samples with measurable levels of Cd, Hg, or Se and had low levels of Pb. The herbivorous diet of coots may shield them from exposure to such elements. However, high levels of V were present in coot livers and ingesta from all four sites, suggesting adaptation to this toxic element.

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Integrated Natural Resource Science Program, San Francisco Bay

The San Francisco Bay-Delta estuary and its watershed have been a focus of intense human activity and environmental impact since 1848 when gold was discovered in the foothills of California's Sierra Nevada mountains. As the estuary and its watershed continue to be changed by human activities, resource managers, environmental regulators, elected officials, and the public seek credible, unbiased scientific information about the factors related to observed changes in order to restore impaired species, habitats and ecological functions.

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Multibeam data and socio-economic issues in west-central San Francisco Bay

San Francisco Bay is the largest estuary on the conterminous U.S. Pacific Coast and is one of the world's largest natural harbors. It is a biologically productive and diverse environment. San Francisco Bay has a maritime economy that annually generates over $7.5 billion, handles 50 million tons of cargo, and involves thousands of jobs. Recent investigations by the USGS in this estuary help address both socio-economic and scientific issues: *Trimming pinnacles may prevent a calamitous oil spill. *Can San Francisco Bay accept more dredge spoil? *Bay floor biological habitats are quite varied. *How thick and how variable is the sediment fill in central San Francisco Bay?

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Studies of the San Francisco Bay, California, estuarine ecosystem: Regional monitoring program results, 1997

As part of a regional monitoring program, water samples were collected in the San Francisco Bay estuary during 20 cruises from January through November 1997. Conductivity, temperature, light attenuation, turbidity, oxygen, and in-vivo chlorophyll fluorescence were measured longitudinally and vertically in the main channel of the estuary from south of the Dumbarton Bridge in the southern part of the Bay to Rio Vista on the Sacramento River. Discrete water samples were analyzed for chlorophyll a, phaeopigments, suspended participate matter, and dissolved oxygen. Water density was calculated from salinity, temperature, and pressure (depth), and is included in the data summaries.

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Changes in production and respiration during a spring phytoplankton bloom in San Francisco Bay, California, USA: Implications for net ecosystem metabolism

We present results of an intensive sampling program designed to measure weekly changes in ecosystem respiration (oxygen consumption in the water column and sediments) around the 1996 spring bloom in South San Francisco Bay, California, USA. Measurements were made at a shallow site (2 m, where mean photic depth was 60% of the water column height) and a deep site (15 m, mean photic depth was only 20% of the water column). We also estimated phytoplankton primary production weekly at both sites to develop estimates of net oxygen flux as the sum of pelagic production (PP), pelagic respiration (PR) and benthic respiration (BR). Over the 14 wk period from February 5 to May 14, PP ranged from 2 to 210, PR from 9 to 289, and BR from 0.1 to 48 mmol O2 m-2 d-1, illustrating large variability of estuarine oxygen fluxes at the weekly time scale. Pelagic production exceeded total respiration at the shallow site, but not at the deep site, demonstrating that the shallow domains are net autotrophic but the deep domains are net heterotrophic, even during the period of the spring bloom. If we take into account the potential primary production by benthic microalgae, the estuary as a whole is net autotrophic during spring, net heterotrophic during the nonbloom seasons, and has a balanced net metabolism over a full annual period. The seasonal shift from net autotrophy to heterotrophy during the transition from spring to summer was accompanied by a large shift from dominance by pelagic respiration to dominance by benthic respiration. This suggests that changes in net ecosystem metabolism can reflect changes in the pathways of energy flow in shallow coastal ecosystems.

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