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Research about Massachusetts

Source-linked reports with geographic coverage including Massachusetts.

At least 379 records · Page 21Linked to original sources
USGS2004

Changes in ground-water quality near two granular-iron permeable reactive barriers in a sand and gravel aquifer, Cape Cod, Massachusetts, 1997-2000

Two experimental permeable reactive barriers (PRBs) of granular zero-valent iron were emplaced in the path of a tetrachloroethene plume (the Chemical Spill-10 plume) at the Massachusetts Military Reservation, Cape Cod, Massachusetts, in June 1998. The goal of the field experiment was to achieve emplacement of a granular-iron PRB deeper than attempted before. The PRBs were expected to create a reducing environment and degrade the tetrachloroethene by reductive dechlorination. The goal of the work presented in this report was to observe temporary and sustained changes to the ground-water chemistry downgradient from the PRBs. A hydraulic-fracturing method involving injection of the granular iron with a guar-biopolymer and enzyme slurry was used to install the parallel 30- to 33-foot-wide wall-shaped barriers at a depth of 82 to 113 feet below land surface. An acetic acid and enzyme mixture was subsequently injected in wells near the barriers to degrade the guar biopolymer. Prior to the emplacement, tetrachloroethene concentrations in the Chemical Spill-10 plume at the study area were as high as 250 micrograms per liter. Other water properties in the plume generally were similar to the properties of uncontaminated ground water in the area, which typically has dissolved oxygen concentrations of 250 to 375 micromoles per liter, pH of 5.5 to 6.0, and specific conductance of 60 to 90 microsiemens per centimeter. Water-quality samples were collected periodically from monitoring wells near the PRBs to determine how the emplacement of the granular-iron walls altered the ground-water quality. In addition, an automated well-sampling device measured temperature, specific conductance, pH, and dissolved oxygen every 1–4 days for 16 months in a well downgradient from the two parallel PRBs. Temporary increases (lasting about 5 to 6 months) in specific conductance were observed downgradient from the PRBs as a result of the sodium chloride, potassium carbonate, and other salts included in the slurry and the acetic acid and enzyme mixture that was subsequently injected to degrade the guar biopolymer. Temporary increases in the concentrations of major cations (sodium, potassium, magnesium, and calcium) were observed downgradient from the PRBs, as were temporary but substantial increases in the dissolved and total organic carbon concentrations. Methane was detected, sulfate concentrations decreased temporarily, and concentrations of dissolved inorganic carbon increased in samples from wells downgradient from the PRBs. A sustained (longer than 12 months) reducing environment, in which dissolved oxygen concentrations decreased to zero, the pH increased to about 6.8, and dissolved iron concentrations increased substantially, developed as a result of the oxidation (corrosion) of the granular iron; this zone persisted at least 65 feet downgradient from the PRBs. The pH and dissolved iron concentrations increased with distance from the granular-iron walls. Concentrations of arsenic, cobalt, manganese, and phosphorus increased, and nitrate concentrations were reduced to below the detection limit downgradient from the walls. A sustained decrease of tetrachloroethene concentrations was not observed; however, reductive dechlorination products were observed at wells downgradient from the PRBs during several rounds of sampling. The emplacement of zero-valent iron in the aquifer to remove tetrachloroethene from the ground water caused changes in the water chemistry that persisted farther downgradient from the PRBs than has been observed at other sites because of the low chemical reactivity of the quartz-dominated aquifer sediments and the low ambient dissolved chemical concentrations in the ground water. The small transverse dispersion in the aquifer and the probable long-term persistence of the iron indicate that the chemically altered zone probably will extend a substantial distance downgradient from the PRBs for a substantial period of time (years); further investigation would be needed to determine this distance.

Massachusetts↗
USGS2004

Evaluation of strategies for balancing water use and streamflow reductions in the upper Charles River basin, eastern Massachusetts

The upper Charles River basin, located 30 miles southwest of Boston, Massachusetts, is experiencing water shortages during the summer. Towns in the basin have instituted water-conservation programs and water-use bans to reduce summertime water use. During July through October, streamflow in the Charles River and its tributaries regularly falls below 0.50 cubic foot per second per square mile, the minimum streamflow used by the U.S. Fish and Wildlife Service as its Aquatic Base Flow standard for maintaining healthy freshwater ecosystems. To examine how human water use could be changed to mitigate these water shortages, a numerical ground-water flow model was modified and used in conjunction with response coefficients and optimization techniques. Streamflows at 10 locations on the Charles River and its tributaries were determined under various water-use scenarios and climatic conditions. A variety of engineered solutions to the water shortages were examined for their ability to increase water supplies and summertime streamflows. Results indicate that although human water use contributes to the problem of low summertime streamflows, human water use is not the only, or even the primary, cause of low flows in the basin. The lowest summertime streamflows increase by 12 percent but remain below the Aquatic Base Flow standard when all public water-supply pumpage and wastewater flows in the basin are eliminated in a simulation under average climatic conditions. Under dry climatic conditions, the same measures increase the lowest average monthly streamflow by 95 percent but do not increase it above the Aquatic Base Flow standard. The most promising water-management strategies to increase streamflows and water supplies, based on the study results, include wastewater recharge to the aquifer, altered management of pumping well schedules, regional water-supply sharing, and water conservation. In a scenario that simulated towns sharing water supplies, streamflow in the Charles River as it exits the basin increased by 18 percent during July through September and an excess water-supply capacity of 13.4 cubic feet per second, above and beyond average use, would be available to all towns in the basin. These study results could help water suppliers and regulators evaluate strategies for balancing ground-water development and streamflow reductions in the basin.

Massachusetts↗
USGS2003

Applicability of tetrazolium salts for the measurement of respiratory activity and viability of groundwater bacteria

A study was undertaken to measure aerobic respiration by indigenous bacteria in a sand and gravel aquifer on western Cape Cod, MA using tetrazolium salts and by direct oxygen consumption using gas chromatography (GC). In groundwater and aquifer slurries, the rate of aerobic respiration calculated from the direct GC assay was more than 600 times greater than that using the tetrazolium salt 2-(4-iodophenyl)-3-(4-nitrophenyl)-5-phenyl tetrazolium chloride (INT). To explain this discrepancy, the toxicity of INT and two additional tetrazolium salts, sodium 3′-[1-(phenylamino)-carbonyl]-3,4-tetrazolium]-bis(4-methoxy-6-nitro) benzenesulfonic acid hydrate (XTT) and 5-cyano-2,3-ditolyl tetrazolium chloride (CTC), to bacterial isolates from the aquifer was investigated. Each of the three tetrazolium salts was observed to be toxic to some of the groundwater isolates at concentrations normally used in electron transport system (ETS) and viability assays. For example, incubation of cells with XTT (3 mM) caused the density of four of the five groundwater strains tested to decline by more than four orders of magnitude. A reasonable percentage (>57%) of cells killed by CTC and INT contained visible formazan crystals (the insoluble, reduced form of the salts) after 4 h of incubation. Thus, many of the cells reduced enough CTC or INT prior to dying to be considered viable by microscopic evaluation. However, one bacterium ( Pseudomonas fluorescens ) that remained viable and culturable in the presence of INT and CTC, did not incorporate formazan crystals into more than a few percent of cells, even after 24 h of incubation. This strain would be considered nonviable based on traditional tetrazolium salt reduction assays. The data show that tetrazolium salt assays are likely to dramatically underestimate total ETS activity in groundwater and, although they may provide a reasonable overall estimate of viable cell numbers in a community of groundwater bacteria, some specific strains may be falsely considered nonviable by this assay due to poor uptake or reduction of the salts.

Massachusetts↗
USGS2003

Testing ground-water-management alternatives in the Upper Charles River Basin, eastern Massachusetts

Ground water pumped from municipal wells supplies most of the drinking water used in the Upper Charles River Basin. This area, along the Interstate 495 corridor in eastern Massachusetts, has undergone rapid land development and population growth in recent years. The increased water demand associated with this growth has created concerns about the effects of current and future withdrawals on streamflow and pond levels in the basin. To aid water-resource planning in the basin, a computer model of the hydrologic system was developed to test the effects of current and hypothetical ground-water withdrawals and other water-management practices. The model is applied using optimization methods that can help balance water-supply and environmental needs.

Massachusetts↗
USGS2003

Coastal vulnerability assessment of Cape Cod National Seashore to sea-level rise

A coastal vulnerability index (CVI) was used to map the relative vulnerability of the coast to future sea-level rise within the Cape Cod National Seashore (CACO). The CVI ranks the following in terms of their physical contribution to sea-level rise-related coastal change: geomorphology, regional coastal slope, rate of relative sea-level rise, shoreline change rates, mean tidal range and mean wave height. The rankings for each variable were combined and an index value calculated for 1-minute grid cells covering the park. The CVI highlights those regions where the physical effects of sea-level rise might be the greatest. This approach combines the coastal system's susceptibility to change with its natural ability to adapt to changing environmental conditions, yielding a quantitative, although relative, measure of the park's natural vulnerability to the effects of sea-level rise. CACO consists of high glacial cliffs, beaches, sand spits, and salt marsh wetlands. The areas most vulnerable to sea-level rise are those with the lowest regional coastal slopes, geomorphologic types that are susceptible to inundation, and the highest rates of shoreline change. Most of CACO's infrastructure lies on high elevation uplands away from the shore; most high use areas are accessible by foot only. The CVI provides an objective technique for evaluation and long-term planning by scientists and park managers.

Massachusetts↗
USGS2003

Long-term hydrologic monitoring protocol for coastal ecosystems

The Cape Cod National Seashore serves as a National Park Service prototype-monitoring park for the Atlantic and Gulf Coast biogeographic region. The U.S. Geological Survey, in cooperation with the National Park Service, is charged with designing and testing monitoring protocols for implementation at the Cape Cod National Seashore. It is expected that many of the protocols will have direct application at other coastal park units, as well as U.S. Fish and Wildlife Service coastal refuges, within the biogeographic region. The Long-term Coastal Ecosystem Monitoring Program at the Cape Cod National Seashore will rely upon numerous protocols that are relevant to the major ecosystem types (Estuaries and Salt Marshes, Barrier Islands/Spits/Dunes, Ponds and Freshwater Wetlands, Coastal Uplands). The hydrologic monitoring protocol is associated with all of these ecosystem types. The overall monitoring program is designed so that all of the protocols are interrelated. Roman and Barrett (1999)present a conceptual description of the entire monitoring program.

Massachusetts↗
USGS2003

Delineation of water sources for public-supply wells in three fractured-bedrock aquifer systems in Massachusetts

Fractured-bedrock aquifer systems in West Newbury, Maynard, and Paxton, Massachusetts, were studied to advance methods of data collection and analysis for delineating contributing areas to public-supply wells completed in fractured rock and for determining the effects of pumping on streams and wetlands. Contributing areas, as defined for this study, include all areas through which ground water flows from recharge areas to wells. In West Newbury, exploratory public-supply wells at two locations were completed in phyllite of the Eliot Formation. Aquifer testing indicated that subhorizontal and steeply dipping fractures that parallel two sets of foliation form elongated transmissive zones in the bedrock aquifer near the two well locations and also form a vertical hydraulic connection to surficial materials consisting of till at one location and marine clay at the other location. Recharge to bedrock is largely through a thin veneer of till over bedrock, but leakage through thick drumlin tills also recharges bedrock. Simulated contributing areas for the three supply wells pumped at a combined rate of 251 gallons per minute encompass about 1.3 square miles and extend to ground-water divides within most of a subbasin of the Artichoke River. Pumping likely would reduce streamflow in the Artichoke River subbasin by approximately the pumping rate. Pumping is likely to affect wetland areas underlain by till near the wells because of the vertical hydraulic connection to surficial materials. In Maynard, three exploratory public-supply wells were completed in coarse-grained schist of the Nashoba Formation. Aquifer testing indicated that a dense network of fractures in bedrock forms a laterally extensive transmissive zone in bedrock that is well connected vertically to surficial materials consisting of sandy till, lacustrine silts, sand and gravel, and wetland deposits. The simulated contributing area for the three supply wells pumped at a combined rate of 780 gallons per minute encompasses about 1.8 square miles of the Fort Pond Brook drainage area. Pumping likely would reduce streamflow in Fort Pond Brook by about the same amount as the pumping rate, and wetland-water levels within a 2,000-foot radius from the wells are likely to be lowered below the land surface by pumping. In Paxton, three existing supply wells are completed in granofels and schist of the Paxton and Littleton Formations. Aquifer testing demonstrated that a shallow bedrock well completed to a depth of 150 feet is closely connected hydraulically to overlying till. Two deep wells, however, receive much of their water from fractures at depths below 500 feet. Ground-water flow in bedrock appears to be mostly through parting fractures along a foliation set that dips gently (10 degrees) eastward. These parting fractures at depth are poorly connected vertically to shallow bedrock.

Massachusetts↗