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Research about Colorado

Source-linked reports with geographic coverage including Colorado.

At least 667 records · Page 37Linked to original sources

Rocky Mountain hydroclimate: Holocene variability and the role of insolation, ENSO, and the North American Monsoon

Over the period of instrumental records, precipitation maximum in the headwaters of the Colorado Rocky Mountains has been dominated by winter snow, with a substantial degree of interannual variability linked to Pacific ocean–atmosphere dynamics. High-elevation snowpack is an important water storage that is carefully observed in order to meet increasing water demands in the greater semi-arid region. The purpose here is to consider Rocky Mountain water trends during the Holocene when known changes in earth's energy balance were caused by precession-driven insolation variability. Changes in solar insolation are thought to have influenced the variability and intensity of the El Niño Southern Oscillation (ENSO), Pacific Decadal Oscillation (PDO), and North American Monsoon and the seasonal precipitation balance between rain and snow at upper elevations. Holocene records are presented from two high elevation lakes located in northwest Colorado that document decade-to-century scale precipitation seasonality for the past ~ 7000 years. Comparisons with sub-tropical records of ENSO indicate that the snowfall-dominated precipitation maxima developed ~ 3000 and 4000 years ago, coincident with evidence for enhanced ENSO/PDO dynamics. During the early-to-mid Holocene the records suggest a more monsoon affected precipitation regime with reduced snowpack, more rainfall, and net moisture deficits that were more severe than recent droughts. The Holocene perspective of precipitation indicates a far broader range of variability than that of the past century and highlights the non-linear character of hydroclimate in the U.S. west.

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Zinc isotope investigation of surface and pore waters in a mountain watershed impacted by acid rock drainage

The pollution of natural waters with metals derived from the oxidation of sulfide minerals like pyrite is a global environmental problem. However, the metal loading pathways and transport mechanisms associated with acid rock drainage reactions are often difficult to characterize using bulk chemical data alone. In this study, we evaluated the use of zinc (Zn) isotopes to complement traditional geochemical tools in the investigation of contaminated waters at the former Waldorf mining site in the Rocky Mountains, Colorado, U.S.A. Geochemical signatures and statistical analysis helped in identifying two primary metal loading pathways at the Waldorf site. The first was characterized by a circumneutral pH, high alkalinity, and high Zn/Cd ratios. The second was characterized by acidic pHs and low Zn/Cd ratios. Zinc isotope signatures in surface water samples collected across the site were remarkably similar (the δ 66 Zn, relative to JMC 3-0749-L, for most samples ranged from 0.20 to 0.30‰ ± 0.09‰ 2σ). This probably suggests that the ultimate source of Zn is consistent across the Waldorf site, regardless of the metal loading pathway. The δ 66 Zn of pore water samples collected within a nearby metal-impacted wetland area, however, were more variable, ranging from 0.20 to 0.80‰ ± 0.09‰ 2σ. Here the Zn isotopes seemed to reflect differences in groundwater flow pathways. However, a host of secondary processes might also have impacted Zn isotopes, including adsorption of Zn onto soil components, complexation of Zn with dissolved organic matter, uptake of Zn into plants, and the precipitation of Zn during the formation of reduced sulfur species. Zinc isotope analysis proved useful in this study; however, the utility of this isotopic tool would improve considerably with the addition of a comprehensive experimental foundation for interpreting the complex isotopic relationships found in soil pore waters.

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MiniSipper: A new in situ water sampler for high-resolution, long-duration acid mine drainage monitoring

Abandoned hard-rock mines can be a significant source of acid mine drainage (AMD) and toxic metal pollution to watersheds. In Colorado, USA, abandoned mines are often located in remote, high elevation areas that are snowbound for 7–8 months of the year. The difficulty in accessing these remote sites, especially during winter, creates challenging water sampling problems and major hydrologic and toxic metal loading events are often under sampled. Currently available automated water samplers are not well suited for sampling remote snowbound areas so the U.S. Geological Survey (USGS) has developed a new water sampler, the MiniSipper, to provide long-duration, high-resolution water sampling in remote areas. The MiniSipper is a small, portable sampler that uses gas bubbles to separate up to 250 five milliliter acidified samples in a long tubing coil. The MiniSipper operates for over 8 months unattended in water under snow/ice, reduces field work costs, and greatly increases sampling resolution, especially during inaccessible times. MiniSippers were deployed in support of an U.S. Environmental Protection Agency (EPA) project evaluating acid mine drainage inputs from the Pennsylvania Mine to the Snake River watershed in Summit County, CO, USA. MiniSipper metal results agree within 10% of EPA-USGS hand collected grab sample results. Our high-resolution results reveal very strong correlations (R 2 > 0.9) between potentially toxic metals (Cd, Cu, and Zn) and specific conductivity at the Pennsylvania Mine site. The large number of samples collected by the MiniSipper over the entire water year provides a detailed look at the effects of major hydrologic events such as snowmelt runoff and rainstorms on metal loading from the Pennsylvania Mine. MiniSipper results will help guide EPA sampling strategy and remediation efforts in the Snake River watershed.

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Geophysical study of the San Juan Mountains batholith complex, southwestern Colorado

One of the largest and most pronounced gravity lows over North America is over the rugged San Juan Mountains of southwestern Colorado (USA). The mountain range is coincident with the San Juan volcanic field (SJVF), the largest erosional remnant of a widespread mid-Cenozoic volcanic field that spanned much of the southern Rocky Mountains. A buried, low-density silicic batholith complex related to the volcanic field has been the accepted interpretation of the source of the gravity low since the 1970s. However, this interpretation was based on gravity data processed with standard techniques that are problematic in the SJVF region. The combination of high-relief topography, topography with low densities, and the use of a common reduction density of 2670 kg/m 3 produces spurious large-amplitude gravity lows that may distort the geophysical signature of deeper features such as a batholith complex. We applied an unconventional processing procedure that uses geologically appropriate densities for the uppermost crust and digital topography to mostly remove the effect of the low-density units that underlie the topography associated with the SJVF. This approach resulted in a gravity map that provides an improved representation of deeper sources, including reducing the amplitude of the anomaly attributed to a batholith complex. We also reinterpreted vintage seismic refraction data that indicate the presence of low-velocity zones under the SJVF. Assuming that the source of the gravity low on the improved gravity anomaly map is the same as the source of the low seismic velocities, integrated modeling corroborates the interpretation of a batholith complex and then defines the dimensions and overall density contrast of the complex. Models show that the thickness of the batholith complex varies laterally to a significant degree, with the greatest thickness (∼20 km) under the western SJVF, and lesser thicknesses (<10 km) under the eastern SJVF. The largest group of nested calderas on the surface of the SJVF, the central caldera cluster, is not correlated with the thickest part of the batholith complex. This result is consistent with petrologic interpretations from recent studies that the batholith complex continued to be modified after cessation of volcanism and therefore is not necessarily representative of synvolcanic magma chambers. The total volume of the batholith complex is estimated to be 82,000–130,000 km 3 . The formation of such a large felsic batholith complex would inevitably involve production of a considerably greater volume of residuum, which could be present in the lower crust or uppermost mantle. The interpreted vertically averaged density contrast (–60 to –110 kg/m 3 ), density (2590–2640 kg/m 3 ), and seismic expression of the batholith complex are consistent with results of geophysical studies of other large batholiths in the western United States.

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Prevalence and effects of West Nile virus on wild American kestrel (Falco sparverius) populations in Colorado

To assess the potential impacts of West Nile virus (WNV) on a wild population of free-ranging raptors, we investigated the prevalence and effects of WNV on American Kestrels ( Falco sparverius ) breeding along the Front Range of the Rocky Mountains in northern Colorado. We monitored kestrel nesting activity at 131 nest boxes from March to August 2004. Of 81 nest attempts, we obtained samples from 111 adults and 250 young. We did not detect WNV in sera; however, 97.3% (108/111) of adults tested positive for WNV neutralizing antibodies, which possibly represented passive transfer of maternal antibodies. Clutch size, hatching, and fledging success in our study did not differ from that previously reported for this species, suggesting that previous WNV exposure in kestrels did not have an effect on reproductive parameters measured in the breeding populations we studied in 2004.

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Weather effects on avian breeding performance and implications of climate change

The influence of recent climate change on the world’s biota has manifested broadly, resulting in latitudinal range shifts, advancing dates of arrival of migrants and onset of breeding, and altered community relationships. Climate change elevates conservation concerns worldwide because it will likely exacerbate a broad range of identified threats to animal populations. In the past few decades, grassland birds have declined faster than other North American avifauna, largely due to habitat threats such as the intensification of agriculture. We examine the effects of local climatic variations on the breeding performance of a bird endemic to the shortgrass prairie, the Lark Bunting ( Calamospiza melanocorys ) and discuss the implications of our findings relative to future climate predictions. Clutch size, nest survival, and productivity all positively covaried with seasonal precipitation, yet relatively intense daily precipitation events temporarily depressed daily survival of nests. Nest survival was positively related to average temperatures during the breeding season. Declining summer precipitation may reduce the likelihood that Lark Buntings can maintain stable breeding populations in eastern Colorado although average temperature increases of up to 38C (within the range of this study) may ameliorate declines in survival expected with drier conditions. Historic climate variability in the Great Plains selects for a degree of vagility and opportunism rather than strong site fidelity and specific adaptation to local environments. These traits may lead to northerly shifts in distribution if climatic and habitat conditions become less favorable in the drying southern regions of the Great Plains. Distributional shifts in Lark Buntings could be constrained by future changes in land use, agricultural practices, or vegetative communities that result in further loss of shortgrass prairie habitats.

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Estimating risks to aquatic life using quantile regression

One of the primary goals of biological assessment is to assess whether contaminants or other stressors limit the ecological potential of running waters. It is important to interpret responses to contaminants relative to other environmental factors, but necessity or convenience limit quantification of all factors that influence ecological potential. In these situations, the concept of limiting factors is useful for data interpretation. We used quantile regression to measure risks to aquatic life exposed to metals by including all regression quantiles (τ = 0.05–0.95, by increments of 0.05), not just the upper limit of density (e.g., 90 th quantile). We measured population densities (individuals/0.1 m 2 ) of 2 mayflies (Rhithrogena spp., Drunella spp.) and a caddisfly (Arctopsyche grandis), aqueous metal mixtures (Cd, Cu, Zn), and other limiting factors (basin area, site elevation, discharge, temperature) at 125 streams in Colorado. We used a model selection procedure to test which factor was most limiting to density. Arctopsyche grandis was limited by other factors, whereas metals limited most quantiles of density for the 2 mayflies. Metals reduced mayfly densities most at sites where other factors were not limiting. Where other factors were limiting, low mayfly densities were observed despite metal concentrations. Metals affected mayfly densities most at quantiles above the mean and not just at the upper limit of density. Risk models developed from quantile regression showed that mayfly densities observed at background metal concentrations are improbable when metal mixtures are at US Environmental Protection Agency criterion continuous concentrations. We conclude that metals limit potential density, not realized average density. The most obvious effects on mayfly populations were at upper quantiles and not mean density. Therefore, we suggest that policy developed from mean-based measures of effects may not be as useful as policy based on the concept of limiting factors.

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Geology along Mosca Pass Trail, Great Sand Dunes National Park and Preserve, Colorado

Mosca Pass Trail takes the hiker on a journey into the Earth's crust. Here you can see the results of tremendous tectonic forces that bend and tear rocks apart and raise mountain ranges. The trail begins near the Sangre de Cristo fault, which separates the Sangre de Cristo Range from the San Luis Valley. The valley is part of the Rio Grande rift, a series of fault basins extending from southern New Mexico to central Colorado, wherein the Earth's crust has been pulled apart during the last 30 million years. Thousands of feet of sediment, brought by streams mostly from the Sangre de Cristo Range, fill the San Luis Valley beneath the Great Sand Dunes. The trail ends at Mosca Pass overlooking Huerfano Park. The park is part of the larger Raton Basin, formed by compression of the Earth's crust during the Laramide orogeny, which occurred 70&ndash;40 million years ago. Massive highlands, the remnants of which are preserved in the Sangre de Cristo Range, were uplifted and pushed over the western side of the Raton Basin. Streams eroded the highland as it rose and filled the Raton Basin with sediment. After the sediment was compacted and cemented to form sedimentary rock, the Huerfano River and other streams began to excavate the basin. Over an unknown but long timespan that probably lasted millions of years, relatively soft sedimentary rocks were removed by the river to form the valley we call "Huerfano Park." Between the ends of the trail, the hiker walks through an erosional "window," or opening, into red sedimentary rocks overridden by gneiss, a metamorphic rock, during the Laramide orogeny. This window gives the hiker a glimpse into the Laramide highland of 70&ndash;40 million years ago that preceded the present-day Sangre de Cristo Range. The window is the focus of this trail guide. At the east end of the trail, near Mosca Pass, another trail follows the ridgeline south to Carbonate Mountain. Immediately after reaching the first summit above tree line, this trail crosses a narrow valley where red rocks mark an extension of the window across the range. Stunning vistas of the Sangre de Cristo Range extend north to the horizon. The uplifted range stands in sharp contrast to the San Luis Valley on the west and Huerfano Park on the east.

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Geospatial database for regional environmental assessment of central Colorado.

In conjunction with the future planning needs of the U.S. Department of Agriculture, Forest Service, the U.S. Geological Survey conducted a detailed environmental assessment of the effects of historical mining on Forest Service lands in central Colorado. Stream sediment, macroinvertebrate, and various filtered and unfiltered water quality samples were collected during low-flow over a four-year period from 2004&ndash;2007. This report summarizes the sampling strategy, data collection, and analyses performed on these samples. The data are presented in Geographic Information System, Microsoft Excel, and comma-delimited formats. Reports on data interpretation are being prepared separately.

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Geodatabase of sites, basin boundaries, and topology rules used to store drainage basin boundaries for the U.S. Geological Survey, Colorado Water Science Center

This geodatabase and its component datasets are part of U.S. Geological Survey Digital Data Series 650 and were generated to store basin boundaries for U.S. Geological Survey streamgages and other sites in Colorado. The geodatabase and its components were created by the U.S. Geological Survey, Colorado Water Science Center, and are used to derive the numeric drainage areas for Colorado that are input into the U.S. Geological Survey's National Water Information System (NWIS) database and also published in the Annual Water Data Report and on NWISWeb. The foundational dataset used to create the basin boundaries in this geodatabase was the National Watershed Boundary Dataset. This geodatabase accompanies a U.S. Geological Survey Techniques and Methods report (Book 11, Section C, Chapter 6) entitled "Digital Database Architecture and Delineation Methodology for Deriving Drainage Basins, and Comparison of Digitally and Non-Digitally Derived Numeric Drainage Areas." The Techniques and Methods report details the geodatabase architecture, describes the delineation methodology and workflows used to develop these basin boundaries, and compares digitally derived numeric drainage areas in this geodatabase to non-digitally derived areas. 1. COBasins.gdb: This geodatabase contains site locations and basin boundaries for Colorado. It includes a single feature dataset, called BasinsFD, which groups the component feature classes and topology rules. 2. BasinsFD: This feature dataset in the "COBasins.gdb" geodatabase is a digital container that holds the feature classes used to archive site locations and basin boundaries as well as the topology rules that govern spatial relations within and among component feature classes. This feature dataset includes three feature classes: the sites for which basins have been delineated (the "Sites" feature class), basin bounding lines (the "BasinLines" feature class), and polygonal basin areas (the "BasinPolys" feature class). The feature dataset also stores the topology rules (the "BasinsFD_Topology") that constrain the relations within and among component feature classes. The feature dataset also forces any feature classes inside it to have a consistent projection system, which is, in this case, an Albers-Equal-Area projection system. 3. BasinsFD_Topology: This topology contains four persistent topology rules that constrain the spatial relations within the "BasinLines" feature class and between the "BasinLines" feature class and the "BasinPolys" feature classes. 4. Sites: This point feature class contains the digital representations of the site locations for which Colorado Water Science Center basin boundaries have been delineated. This feature class includes point locations for Colorado Water Science Center active (as of September 30, 2009) gages and for other sites. 5. BasinLines: This line feature class contains the perimeters of basins delineated for features in the "Sites" feature class, and it also contains information regarding the sources of lines used for the basin boundaries. 6. BasinPolys: This polygon feature class contains the polygonal basin areas delineated for features in the "Sites" feature class, and it is used to derive the numeric drainage areas published by the Colorado Water Science Center.

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Biosolids, crop, and groundwater data for a biosolids-application area near Deer Trail, Colorado, 2009 and 2010

During 2009 and 2010, the U.S. Geological Survey monitored the chemical composition of biosolids, crops, and groundwater related to biosolids applications near Deer Trail, Colorado, in cooperation with the Metro Wastewater Reclamation District. This monitoring effort was a continuation of the monitoring program begun in 1999 in cooperation with the Metro Wastewater Reclamation District and the North Kiowa Bijou Groundwater Management District. The monitoring program addressed concerns from the public about potential chemical effects from applications of biosolids to farmland in the area near Deer Trail, Colo. This report presents chemical data from 2009 and 2010 for biosolids, crops, and alluvial and bedrock groundwater. The chemical data include the constituents of highest concern to the public (arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, zinc, and plutonium) in addition to many other constituents. The groundwater section also includes data for precipitation, air temperature, and depth to groundwater at various groundwater-monitoring sites.

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Comparison of 2008-2009 water years and historical water-quality data, upper Gunnison River Basin, Colorado

Population growth and changes in land use have the potential to affect water quality and quantity in the upper Gunnison River Basin. In 1995, the U.S. Geological Survey (USGS), in cooperation with the Bureau of Land Management, City of Gunnison, Colorado River Water Conservation District, Crested Butte South Metropolitan District, Gunnison County, Hinsdale County, Mount Crested Butte Water and Sanitation District, National Park Service, Town of Crested Butte, U.S. Forest Service, Upper Gunnison River Water Conservancy District, and Western State College, established a water-quality monitoring program in the upper Gunnison River Basin to characterize current water-quality conditions and to assess the effects of increased urban development and other land-use changes on water quality. The monitoring network has evolved into two groups of sites: (1) sites that are considered long term and (2) sites that are considered rotational. Data from the long-term sites assist in defining temporal changes in water quality (how conditions may change over time). The rotational sites assist in the spatial definition of water-quality conditions (how conditions differ throughout the basin) and address local and short-term concerns. Biannual summaries of the water-quality data from the monitoring network provide a point of reference for stakeholder discussions regarding the location and purpose of water-quality monitoring sites in the upper Gunnison River Basin. This report compares and summarizes the data collected during water years 2008 and 2009 to the historical data available at these sites. The introduction provides a map of the sampling sites, definitions of terms, and a one-page summary of selected water-quality conditions at the network sites. The remainder of the report is organized around the data collected at individual sites. Data collected during water years 2008 and 2009 are compared to historical data, State water-quality standards, and Federal water-quality guidelines. A seasonal Kendall test for trend analysis is completed when there is sufficient data (typically >5 years) at the station. Data were collected following USGS protocols.

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Watershed scale response to climate change--Yampa River Basin, Colorado

General Circulation Model simulations of future climate through 2099 project a wide range of possible scenarios. To determine the sensitivity and potential effect of long-term climate change on the freshwater resources of the United States, the U.S. Geological Survey Global Change study, "An integrated watershed scale response to global change in selected basins across the United States" was started in 2008. The long-term goal of this national study is to provide the foundation for hydrologically based climate change studies across the nation. Fourteen basins for which the Precipitation Runoff Modeling System has been calibrated and evaluated were selected as study sites. Precipitation Runoff Modeling System is a deterministic, distributed parameter watershed model developed to evaluate the effects of various combinations of precipitation, temperature, and land use on streamflow and general basin hydrology. Output from five General Circulation Model simulations and four emission scenarios were used to develop an ensemble of climate-change scenarios for each basin. These ensembles were simulated with the corresponding Precipitation Runoff Modeling System model. This fact sheet summarizes the hydrologic effect and sensitivity of the Precipitation Runoff Modeling System simulations to climate change for the Yampa River Basin at Steamboat Springs, Colorado.

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Watershed scale response to climate change--East River Basin, Colorado

General Circulation Model simulations of future climate through 2099 project a wide range of possible scenarios. To determine the sensitivity and potential effect of long-term climate change on the freshwater resources of the United States, the U.S. Geological Survey Global Change study, "An integrated watershed scale response to global change in selected basins across the United States" was started in 2008. The long-term goal of this national study is to provide the foundation for hydrologically based climate change studies across the nation. Fourteen basins for which the Precipitation Runoff Modeling System has been calibrated and evaluated were selected as study sites. Precipitation Runoff Modeling System is a deterministic, distributed parameter watershed model developed to evaluate the effects of various combinations of precipitation, temperature, and land use on streamflow and general basin hydrology. Output from five General Circulation Model simulations and four emission scenarios were used to develop an ensemble of climate-change scenarios for each basin. These ensembles were simulated with the corresponding Precipitation Runoff Modeling System model. This fact sheet summarizes the hydrologic effect and sensitivity of the Precipitation Runoff Modeling System simulations to climate change for the East River Basin, Colorado.

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Wildfire effects on source-water quality--Lessons from Fourmile Canyon fire, Colorado, and implications for drinking-water treatment

Forested watersheds provide high-quality source water for many communities in the western United States. These watersheds are vulnerable to wildfires, and wildfire size, fire severity, and length of fire season have increased since the middle 1980s (Westerling and others, 2006). Burned watersheds are prone to increased flooding and erosion, which can impair water-supply reservoirs, water quality, and drinking-water treatment processes. Limited information exists on the degree, timing, and duration of the effects of wildfire on water quality, making it difficult for drinking-water providers to evaluate the risk and develop management options. In order to evaluate the effects of wildfire on water quality and downstream ecosystems in the Colorado Front Range, the U.S. Geological Survey initiated a study after the 2010 Fourmile Canyon fire near Boulder, Colorado. Hydrologists frequently sampled Fourmile Creek at monitoring sites upstream and downstream of the burned area to study water-quality changes during hydrologic conditions such as base flow, spring snowmelt, and summer thunderstorms. This fact sheet summarizes principal findings from the first year of research. Stream discharge and nitrate concentrations increased downstream of the burned area during snowmelt runoff, but increases were probably within the treatment capacity of most drinking-water plants, and limited changes were observed in downstream ecosystems. During and after high-intensity thunderstorms, however, turbidity, dissolved organic carbon, nitrate, and some metals increased by 1 to 4 orders of magnitude within and downstream of the burned area. Increases of such magnitude can pose problems for water-supply reservoirs, drinking-water treatment plants, and downstream aquatic ecosystems.

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The Fort Collins Science Center

With a focus on biological research, the U.S. Geological Survey Fort Collins Science Center (FORT) develops and disseminates science-based information and tools to support natural resource decision-making. This brochure succinctly describes the integrated science capabilities, products, and services that the FORT science community offers across the disciplines of aquatic systems, ecosystem dynamics, information science, invasive species science, policy analysis and social science assistance, and trust species and habitats.

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Summary and evaluation of the quality of stormwater in Denver, Colorado, 2006-2010

Stormwater in the Denver area was sampled by the U.S. Geological Survey, in cooperation with the Urban Drainage and Flood Control District, in a network of 5 monitoring stations - 3 on the South Platte River and 2 on streams tributary to the South Platte River, Sand Creek, and Toll Gate Creek beginning in January 2006 and continuing through December 2010. Stormwater samples were analyzed at the U.S. Geological Survey National Water Quality Laboratory during 2006-2010 for water-quality properties such as pH, specific conductance, hardness, and residue on evaporation at 105 degrees Celsius; for constituents such as major ions (calcium, magnesium), organic carbon and nutrients, including ammonia plus organic nitrogen, ammonia, dissolved nitrite plus nitrate, total phosphorus, and orthophosphate; and for metals, including total recoverable and dissolved phases of copper, lead, manganese, and zinc. Samples collected during selected storms were also analyzed for bacteriological indicators such as Escherichia coli and fecal coliform at the Metro Wastewater Reclamation Laboratory. About 200 stormwater samples collected during storms characterize the quality of storm runoff during 2006-2010. In general, the quality of stormwater (2006-2010) has improved for many water-quality constituents, many of which had lower values and concentrations than those in stormwater collected in 2002-2005. However, the physical basis, processes, and the role of dilution that account for these changes are complex and beyond the scope of this report. The water-quality sampling results indicate few exceptions to standards except for dissolved manganese, dissolved zinc, and Escherichia coli . Stormwater collected at the South Platte River below Union Avenue station had about 10 percent acute or chronic dissolved manganese exceedances in samples; samples collected at the South Platte River at Denver station had less than 5 percent acute or chronic dissolved manganese exceedances. In contrast, samples collected at Toll Gate Creek above 6th Avenue at Aurora station, Sand Creek at mouth near Commerce City station, and the South Platte River at Henderson station, each had about 30 to 50 percent exceedances of both acute and chronic dissolved manganese standards. Of the samples collected at Sand Creek at mouth near Commerce City, 1 sample exceeded the acute standard and 4 samples exceeded the chronic standard for dissolved zinc, but no samples collected from the other sites exceeded either standard for zinc. Almost all samples of stormwater analyzed for Escherichia coli exceeded Colorado numeric standards. A numerical standard for fecal coliform is no longer applicable as of 2004. Results from the 2002-2005 study indicated that the general quality of stormwater had improved during 2002-2005 compared to 1998-2001, having fewer exceedances of Colorado standards, and showing downward trends for many water-quality values and concentrations. These trends coincided with general downward or relatively similar mean streamflows for the 2002-2005 compared to 1998-2001, which indicates that dilution may be a smaller influence on values and concentrations than other factors. For this report, downward trends were indicated for many constituents at each station during 2006-2010 compared to 2002-2005. The trends for mean streamflow for 2006-2010 compared to 2002-2005 are upward at all sites except for the South Platte River at Henderson, indicating that dilution by larger flows could be a factor in the downward concentration trends. At the South Platte River below Union Avenue station, downward trends were indicated for hardness, dissolved ammonia, dissolved orthophosphate, and dissolved copper. Upward trends at South Platte River below Union Avenue were indicated for pH. At the South Platte River at Denver station, downward trends were indicated for total ammonia plus organic nitrogen, dissolved ammonia, dissolved nitrite plus nitrate, dissolved orthophosphate, total phosphorus, dissolved organic carbon, and dissolved lead, manganese, and zinc, and total recoverable zinc. An upward trend in properties and constituents at South Platte River at Denver was indicated for pH. At Toll Gate Creek above 6th Avenue at Aurora, downward trends were indicated for residue on evaporation, total ammonia plus organic nitrogen, dissolved ammonia, dissolved orthophosphate, total phosphorus, and total recoverable copper, lead, manganese, and zinc. Upward trends in properties and constituents at Toll Gate Creek above 6th Avenue at Aurora were indicated for pH, specific conductance, and dissolved nitrite plus nitrate. At Sand Creek at mouth near Commerce City, downward trends were indicated for hardness, dissolved calcium, total ammonia plus organic nitrogen, and dissolved ammonia, orthophosphate, manganese, and zinc. An upward trend in properties and constituents at Sand Creek at mouth near Commerce City was indicated for pH. Downward trends at South Platte River at Henderson were indicated for specific conductance, hardness, dissolved magnesium, residue on evaporation, total ammonia plus organic nitrogen, dissolved ammonia, dissolved nitrite plus nitrate, dissolved orthophosphate, total phosphorus, dissolved lead and manganese, and total recoverable copper, lead, manganese, and zinc.

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Water chemistry of surface waters affected by the Fourmile Canyon wildfire, Colorado, 2010-2011

In September 2010, the Fourmile Canyon fire burned about 23 percent of the Fourmile Creek watershed in Boulder County, Colo. Water-quality sampling of Fourmile Creek began within a month after the wildfire to assess its effects on surface-water chemistry. Water samples were collected from five sites along Fourmile Creek (above, within, and below the burned area) monthly during base flow, twice weekly during snowmelt runoff, and at higher frequencies during storm events. Stream discharge was also monitored. Water-quality samples were collected less frequently from an additional 6 sites on Fourmile Creek, from 11 tributaries or other inputs, and from 3 sites along Boulder Creek. The pH, electrical conductivity, temperature, specific ultraviolet absorbance, total suspended solids, and concentrations (dissolved and total) of major cations (calcium, magnesium, sodium, and potassium), anions (chloride, sulfate, alkalinity, fluoride, and bromide), nutrients (nitrate, ammonium, and phosphorus), trace metals (aluminum, arsenic, boron, barium, beryllium, cadmium, cobalt, chromium, copper, iron, mercury, lithium, manganese, molybdenum, nickel, lead, rubidium, antimony, selenium, strontium, vanadium, and zinc), and dissolved organic carbon are here reported for 436 samples collected during 2010 and 2011.

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