Geology topics

Research about California

Source-linked reports with geographic coverage including California.

At least 793 records · Page 44Linked to original sources

USGS2022

Linkages between land-use change and groundwater management foster long-term resilience of water supply in California

Study Region We created a 270-m coupled model of land-use and groundwater conditions, LUCAS-W[ater], for California’s Central Coast. This groundwater-dependent region is undergoing a dramatic reorganization of groundwater management under California’s 2014 Sustainable Groundwater Management Act (SGMA). Study Focus Understanding land-use and land-cover change supports long-term sustainable water management. Anthropogenic water demand has depleted groundwater aquifers worldwide, while future water shortages will likely affect land-use change, creating system feedbacks. Our novel participatory approach fused changes in land-use and associated water use from county-scale data to local water agencies’ estimates of total sustainable supply, scaling up local hydro-geologic knowledge from heterogeneous aquifers and diverse management approaches to a regional level. We assessed five stakeholder-driven scenarios with the same historic rates of urban and agricultural land-use change, but different water and land-use management, analyzing how management strategies altered both the spatial pattern of development and subsequent water sustainability from 2001 to 2061. New Hydrological Insights for the Region Transformative strategies using demand-side interventions that coupled water availability to land-use more effectively achieved long-term sustainability than adaptive strategies using supply-side interventions to increase water supplies. Limiting water withdrawals within SGMA regulated basins resulted in leakage of development into unregulated basins, increasing groundwater pumping there. Protecting ecosystems, farmlands, and recharge areas from development reduced leakage into undeveloped basins without negatively affecting water sustainability.

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USGS2022

Occurrence of water and thermogenic gas from oil-bearing formations in groundwater near the Orcutt Oil Field, California, USA

Study region Santa Barbara County, California, USA. Study focus To analyze a wide array of newly collected chemical, isotopic, dissolved gas, and age dating tracers in conjunction with historical data from groundwater and oil wells to determine if water and/or thermogenic gas from oil-bearing formations have mixed with groundwater in the Orcutt Oil Field and surrounding area. New hydrological insights for the region Three of 15 groundwater samples had compositions indicating potential mixing with water and/or thermogenic gas from oil-bearing formations. Relevant indicators included salinity tracers (TDS, Cl, Br), NH 3, DOC, enriched δ 13 C-DIC, δ 2 H-CH 4 , δ 13 C-CH 4 , and δ 13 C-C 2 H 6 values, and trace amounts of C3-C5 gas. The potential sources/pathways for oil-bearing formation water and/or thermogenic gas in groundwater overlying and adjacent to the Orcutt Oil Field include: (1) upward movement from formations developed for oil production due to: (a) natural migration; or (b) anthropogenic activity such as injection and/or movement along wellbores; and (2) oil and gas shows in overlying non-producing oil-bearing formations. Groundwater age tracers, elevated 4 He concentrations, and isotopic compositions of noble gases indicated legacy produced water ponds were not a source. This phase of the study relied on samples and data from existing infrastructure. Additional data on potential end-member compositions from new and existing wells and assessments of potential vertical head gradients and pathways between oil and groundwater zones may yield additional insight.

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USGS2022

Collateral damage: Anticoagulant rodenticides pose threats to California condors

Anticoagulant rodenticides (ARs) are widespread environmental contaminants that pose risks to scavenging birds because they routinely occur within their prey and can cause secondary poisoning. However, little is known about AR exposure in one of the rarest avian scavengers in the world, the California condor ( Gymnogyps californianus ). We assessed AR exposure in California condors and surrogate turkey vultures ( Cathartes aura ) to gauge potential hazard to a proposed future condor flock by determining how application rate and environmental factors influence exposure. Additionally, we examined whether ARs might be correlated with prolonged blood clotting time and potential mortality in condors. Only second-generation ARs (SGARs) were detected, and exposure was detected in all condor flocks. Liver AR residues were detected in 42% of the condors (27 of 65) and 93% of the turkey vultures (66 of 71). Although concentrations were generally low (<10 ng/g ww), 48% of the California condors and 64% of the turkey vultures exposed to ARs exceeded the 5% probability of exhibiting signs of toxicosis (>20 ng/g ww), and 10% and 13% exceeded the 20% probability of exhibiting signs toxicosis (>80 ng/g ww). There was evidence of prolonged blood clotting time in 16% of the free-flying condors. For condors, there was a relationship between the interaction of AR exposure index (legal use across regions where condors existed) and precipitation, and the probability of detecting ARs in liver. Exposure to ARs may complicate recovery efforts of condor populations within their current range and in the soon to be established northern California experimental population. Continued monitoring of AR exposure using plasma blood clotting assays and residue analysis would allow for an improved understanding of their hazard to condors, particularly if paired with recent movement data that could elucidate exposure sources on the landscape occupied by this endangered species.

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USGS2022

Comparing imidacloprid, clothianidin, and azoxystrobin runoff from lettuce fields using a soil drench or treated seeds in the Salinas Valley, California

Neonicotinoid insecticide use has increased over the last decade, including as agricultural seed treatments (application of chemical in a coating to the seed prior to planting). In California, multiple crops, including lettuce, can be grown using neonicotinoid treated seeds or receive a direct neonicotinoid soil application (drenching) at planting. Using research plots, this study compared pesticide runoff in four treatments: (1) imidacloprid seed treatment; (2) clothianidin seed treatment; (3) imidacloprid drench and an azoxystrobin seed treatment; and (4) a control with no pesticidal treatment. Neonicotinoid and azoxystrobin concentrations were measured in surface water runoff during six irrigations events in the 2020 growing seasons. Results showed runoff concentrations up to 1308 (±1200) ng L −1 for imidacloprid drench treatment, 431 (±100) ng L −1 for clothianidin seed treatment, 135 (±60) ng L −1 for imidacloprid seed treatment, 13 (±10) ng L −1 for azoxystrobin seed treatment (treatments averaged). The percent of applied mass in runoff over the entire sampling period varied by compound; the imidacloprid seed treatment and drench were similar (0.015 and 0.019%, respectively) to the clothianidin seed treatment (0.036%) while the azoxystrobin seed treatment was much higher (15%). Although the proportion of imidacloprid in runoff was similar for imidacloprid treatments, the mass applied during soil drench was > 4x the amount applied from the imidacloprid seed treatment. Surface soils were collected before planting and at the end of the trial. The neonicotinoids were detected in soil throughout the study and average maximum concentrations were 9–13 ng g −1 ; azoxystrobin was detected in only two soils at concentrations up to 0.57 ng g −1 . These results elucidate the comparative mass runoff resulting from planting treated seed and soil drench applications and highlight the value of additional work to characterize off-site transport from the many commodities that may be utilizing treated seeds.

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USGS2022

Using active source seismology to image the Palos Verdes Fault damage zone as a function of distance, depth, and geology

Fault damage zones provide a window into the non-elastic processes of an earthquake. Geological and seismic tomography methods have been unable to measure damage zones at depth with sufficient spatial sampling to evaluate the relative influence of depth, distance, and lithological variations. Here, we identify and analyze the damage zone of the Palos Verdes Fault offshore southern California using two 3D seismic reflection datasets. We apply a novel algorithm to identify discontinuities attributed to faults and fractures in large seismic volumes and examine the spatial distribution of fault damage in sedimentary rock surrounding the Palos Verdes Fault. Our results show that damage through fracturing is most concentrated around mapped faults and decays exponentially to a distance of ∼2 km, where fracturing reaches a clearly defined and relatively undamaged background for all examined depths and lithologies (450 m to 2.2 km). This decrease in fracturing with distance from the central fault strand exhibits similar functional form to outcrop studies. However, here we extend analysis to distances seldom accessible (∼10 km lateral distance). Separating the data by geologic units we find that the damage decay and background level differs for each unit, with the older and deeper units having higher levels of background fracturing and shallower exponential decays of fracturing with distance from the fault. Surprisingly, these differences in damage decay and background level trade-off result in a consistent damage zone width regardless of lithology or depth. We find that the damage zone has similar decay trends on both sides of the fault. When examining the damage zone at shorter (4 km vs 17 km) along strike distances, the damage zone has a more complex decay trend and at least two strands are resolvable.

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USGS2022

Long-term effects of prescribed fire on large tree growth in mixed conifer forests at Lassen Volcanic National Park, California

Prescribed fire in dry coniferous forests of the western U.S. is used to reduce fire hazards. How large, old trees respond to these treatments is an important management consideration. Growth is a key indicator of residual tree condition, which can be predictive of mortality and response to future disturbance. Using a combination of long-term plot records and dendrochronological samples, we analyzed the effects of prescribed fire treatments from the early 1990 s on forest structure and individual tree growth in mixed-conifer forests of Lassen Volcanic National Park in northern California. Prescribed fire reduced stand live tree basal area and stem density at our sites up to 10 years following fire. Within two prescribed fire burn units and two adjacent unburned stands, we analyzed tree cores from 136 large (mean stem diameter > 70 cm) yellow pine ( Pinus jeffreyi and P. ponderosa ) and 136 large (mean stem diameter > 50 cm) white fir ( Abies concolor ). After accounting for annual precipitation, basal area increment for individual trees initially declined up to < 3 years post-fire for white fir and > 10 years post-fire for yellow pine, presumably in response to tree injuries. Growth improved for both species at a site that was burned twice, particularly for white fir. Recent average basal area increment was positively related to crown ratio and negatively associated with an index of local competition. Our findings suggest that forest management, such as prescribed fire and mechanical thinning, may be beneficial in terms of maintaining or improving tree growth among large residual trees. However, managers may want to balance the benefits of these treatments against inadvertent injury and mortality of large trees.

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USGS2022

Projecting the remaining habitat for the western spadefoot (Spea hammondii) in heavily urbanized southern California

Extensive urbanization in coastal southern California has reduced natural habitat in this biodiversity hotspot. To better conserve ecological communities, state and federal agencies, along with local jurisdictions and private stakeholders, developed regional conservation plans for southern California. Although many protected areas exist within this region, the patchwork nature of these protected areas might not provide good coverage for species that require multiple habitat components, such as amphibians with complex life histories. Because of declines in the past century, the status of the western spadefoot ( Spea hammondii ) in southern California is of concern to state and federal wildlife agencies. Species distribution models (SDMs) can aid in determining the conservation status of imperiled species by projecting where suitable habitat remains and how much is protected from further development. We built SDMs that integrated site-occupancy data from systematic pitfall trapping surveys and presence-only data from biodiversity databases and citizen science platforms to project the current distribution of western spadefoots in southern California. Western spadefoot occurrence was positively related to the cover of grassland or shrub/scrub and the % sand in the soil within a 1000 m buffer, and was negatively related to slope, elevation, and distance to ephemeral streams or vernal pools . Most of the remaining unprotected habitat for western spadefoots is in the southern half of its historical range in western San Diego and Riverside counties. A few large tracts of spadefoot habitat exist on U.S. Department of Defense lands and smaller tracts remain on ecological reserves owned by state and local government agencies. Only small patches of habitat remain in the northern half of this clade’s historical range in Ventura, Orange, Los Angeles, and San Bernardino counties. Existing regional conservation plans provide ostensible spatial coverage of the majority of extant habitat for western spadefoots in southern California, but most of the habitat within the jurisdiction of these plans lacks formal protection, exposing this species to further declines as urbanization continues in the 21st century.

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USGS2022

Seasonal impoundment management reduces nitrogen cycling but not resilience to surface fire in a tidal wetland

Hydrology and salinity regimes of many impounded wetlands are manipulated to provide seasonal habitats for migratory waterfowl , with little-known consequences for ecosystem structure and function. Managed hydrology can alter ecosystems by directly changing soil properties and processes and by influencing plant community dynamics. Additionally, management history may influence ecosystem response to disturbance, including fires. To better understand how wetland management regime influences ecosystem response to disturbance, we quantified elevation, soil nitrogen concentrations and process rates, and plant community structure and diversity in a natural experiment following the 2018 Branscombe Fire. We measured paired burned-unburned patches in both tidally-influenced and managed, seasonally-impounded wetlands in Suisun Marsh, California, USA. Unburned ecosystem structure and nutrient cycling differed by wetland management history; unburned impounded wetlands were ∼1 m lower in elevation and plant community composition was dominated by succulents whereas the unburned tidal wetland was dominated by graminoids. Unburned impounded wetland soil nitrogen cycling (potential nitrification and denitrification) rates were <28% of those measured in unburned tidal wetland soils and soil extractable nitrate, ammonium, and dissolved inorganic phosphorus concentrations were also substantially lower in unburned impounded than unburned tidal wetlands. Despite these differences in pre-disturbance (i.e., unburned) conditions, all soil processes recovered to baseline levels within 6 months after surface fire, and we found no evidence of plant community change 1 year after fire in either wetland management type. Overall, water management history exerted stronger control on ecosystem processes and structure than surface fire disturbance. Low extractable soil nitrate and potential denitrification rates may indicate limitation of soil nitrogen removal in impounded wetlands, with implications for downstream environmental quality and eutrophication across managed landscapes.

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USGS2022

Quantitative SWOT analysis: A structured and collaborative approach to reintroduction site selection for the endangered Pacific pocket mouse

Species extinction and loss of biodiversity are major crises in the Anthropocene. Translocations of threatened and endangered species, the movement of individuals to augment existing or establish new populations, are increasingly important conservation tools, but have historically had limited success. Selection of a suitable receiver site is essential to translocation success, with poor site suitability cited as one of the most common reasons for relocation failure. We utilized a quantitative SWOT (Strengths, Weaknesses, Opportunities, Threats) analysis to evaluate and prioritize potential receiver sites for the Pacific pocket mouse ( Perognathus longimembris pacificus ), an endangered subspecies of heteromyid rodent endemic to coastal southern California. With only three remaining extant populations, a conservation breeding and reintroduction program is underway with the goal of creating additional wild populations in new or historic locations throughout its indigenous range. Here we describe our use of SWOT analysis and discuss the strengths of this approach as well as improvements that could be made to the evaluation process for other species. Overall, we found that using a structured, transparent, and collaborative process was a valuable tool for prioritizing receiver sites. SWOT analysis is a flexible, repeatable, and proactive approach for identifying receiver sites and the preparations necessary to improve species-specific suitability. This approach has the potential to result in successful relocation compared to less structured site selection processes where poor site suitability is ultimately identified as a major factor in failure to establish wild populations.

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USGS2022

Late Jurassic-Early Cretaceous orogenic gold mineralization in the Klamath Mountains, California: Constraints from 40Ar/39Ar dating of hydrothermal muscovite

The Klamath Mountains gold province is the second most important historical producer in California, having produced more than 7 Moz of gold from both lode and placer sources. Hydrothermal muscovite grains from gold-bearing veins provide the first 40 Ar/ 39 Ar age constraints indicative of a protracted period of mineralization in the Klamath Mountains. The data indicate that the window for orogenic gold mineralization in the Klamath Mountains was from ∼160–140 Ma, coinciding in age with the oldest orogenic gold deposits in the Sierra Nevada foothills province to the south, although mineralization continued in the latter along the Mother Lode belt for another 20–30 million years. Despite the broad age overlap between hydrothermal activity and magmatism, the former relates to a regional thermal event, and there is no genetic link between the two. Instead, a correlation exists between the timing of lode gold formation and discrete tectonic events, changes in stress regime, and fault movement. The maximum age corresponds to a major plate reorganization in the Pacific basin and initial gold mineralization continuing into the Sierra Nevada foothills gold province to the south. The minimum age corresponds to the westerly lateral offset of the Klamath Mountains from the Sierra Nevada and the then-active arc, marking the termination of both magmatism and gold-producing hydrothermal activity in the Klamath Mountains. Lode gold mineralization in the Klamath Mountains is compatible with a crustal source of metals and fluids that were released during metamorphic devolatilization and focused via hydrothermal fluid flow along regional faults.

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USGS2022

An 11,300 yr record of paleoclimatology and paleoceanography of the central California coast in a gravity core from Pioneer Seamount

Diatom, pollen, silicoflagellate, and biogenic opal analyses from a 155 cm-long gravity core from Pioneer Seamount, offshore Santa Cruz, California (PS1410-06 GC, latitude 37.3°N, longitude 123.4°W, water depth 2165 m) are compiled for the last ~11,300 years and compared with those of ODP 1019 and TN062-O550 from northern California. The relative abundance record of the subtropical diatom Fragilariopsis doliolus has similar bimodal Holocene patterns in all three cores, suggesting that sea surface temperatures (SST) were lower during the middle part of the Holocene than they were during the later and earlier parts. The relative abundance of coastal redwood ( Sequoia sempervirens ) pollen, a proxy for fog and coastal upwelling, displays stepwise increases in ODP 1019 and TN062-O550 between ~ 4000 and 3000 cal yr. BP, but its relative abundance in PS1410-06 GC increases gradually throughout the past 10,200 yr without any major steps. Similarly, biogenic silica (opal) displays stepwise increases at ~3600 and 2900 cal yr. BP in ODP 1019 and TN062-O550, respectively, whereas opal increases more gradually in PS1410-06 GC during the past 10,100 yr with relatively minor steps at ~3100 and ~2600 cal yr. BP. Together, coastal redwood and opal argue for a more gradual late Holocene increase in coastal upwelling along the coast of central California compared with that off northern California, where onshore-offshore gradients are more distinct.

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USGS2022

Understanding rates of change: A case study using fossil pollen records from California to assess the potential for and challenges to a regional data synthesis

Insights into the rates at which ecosystems and vegetation respond to a changing climate is fundamental to anticipating impacts of projected climate change. Characterization of vegetation change over millennia to centuries has potential to make an important contribution toward this goal, and regional scale syntheses of fossil pollen data can provide the foundation for this understanding. However, challenges of data analysis and integration are nontrivial. Here we present a case study in which publicly available fossil pollen data for California are assessed and analyzed. The data are selected according to a clearly defined selection criteria, and a Rate of Change (RoC) value is calculated to assess rates of vegetation change in California from ~15k BP (before A.D. 1950) to the present. Our results highlight several challenges presented by the extant data sets, including temporal sampling variation within and between records, large age control uncertainties, and sparse, geographically biased coverage. Recommendations for methodological refinements to better characterize ecological rates of change include increasing sampling frequency, maintaining a consistent temporal spacing within records, and applying probabilistic approaches to existing pollen data sets.

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USGS2022

Environmental evolution of peat in the Sacramento – San Joaquin Delta (California) during the Middle and Late Holocene as deduced from pollen, diatoms and magnetism

We studied the sequence of climatic and hydrological events associated with the formation of peat during the Holocene, using pollen, diatoms and environmental magnetism from peat cores at three locations in the Sacramento-San Joaquin Delta of California: Browns Island, Franks Wetland and Webb Track Levee. Our data show that peat first formed under relatively dry conditions in a freshwater environment before 6.5 ka BP. Subsequently, pollen accumulation rates were highest prior to intervals with high peat accretion rates but are inversely correlated with organic accumulation rate. Intervals of high peat accretion were preceded by pulses of terrigenous material. During intensive drainage episodes, high flows delivered abundant, coarser-grained sediment to the marshes, which inundated the existing vegetation and decreased the rate of biochemical decay. The build-up of undecomposed organic material led to the acceleration of peat accretion. Our data support the rarely discussed hypothesis that most of the peat in the Sacramento-San Joaquin Delta formed in freshwater marshes that were fed by rivers draining from the Sierra Nevada, rather than in saltwater wetlands resulting from sea level rise and estuarine submergence. This result has important implications for current attempts to remediate and restore the Delta ecosystem.

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USGS2022

Impact of climate change on mollusks and other invertebrate resources at the Dominican University of California archaeological site (CA-MRN-254), Marin County, California

We have identified and provided ecological interpretations of 30 taxa recovered at two shellmounds at the Dominican University of California archaeology site in Marin County, California (CA-MRN-254). A Q-mode cluster analysis was used to group the samples according to their faunal similarity. The clusters ranged from a diverse grouping of 100 samples with 27 taxa (Cluster A) to those with a more restricted assemblage (4–9 taxa in Clusters B to E). The Q-mode clusters were then used to interpret the variability in food resources utilized through the 1800 years of site occupation. During the Intermediate Middle Period (A.D.100-300), the inhabitants appeared to be selective in the marine taxa they used, evident by the presence of Cluster B and E assemblages. A diverse (Cluster A) assemblage was then utilized at the site at one or both of the shellmounds through the remainder of the occupancy period, including the Middle/Late Period Transition (A.D. 700–900) and Late Period Phase 1C (A.D. 900–1300), coincident with the extensive drought conditions of the Medieval Climatic Anomaly (MCA) in the San Francisco Bay area. These findings suggest the marine invertebrate resources utilized by the site occupants were not significantly affected by the persistent aridity associated with the MCA.

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USGS2022

Using Landsat and MODIS satellite collections to examine extent, timing, and potential impacts of surface water inundation in California croplands☆

The state of California, United States of America produces many crop products that are both utilized domestically and exported throughout the world. With nearly 39,000 km 2 of croplands, monitoring unintentional and intentional surface water inundation is important for water resource management and flood hazard readiness. We examine inundation dynamics in California croplands from 2003 to 2020 by intersecting monthly surface water maps (n = 216 months) derived using two satellite remote sensing platforms (Landsat and Moderate Resolution Imaging Spectroradiometer [MODIS]) with a high-quality cropland map generated by the California Department of Water Resources. Surface water maps were produced using the Dynamic Surface Water Extent model, in which satellite image pixels are classified into different levels of detection confidence. Our analysis focused on calculating monthly and annual occurrence of “high confidence” water for each satellite collection across eight cropland types and 58 counties. Results indicate that 49.9% (MODIS) to 56.4% (Landsat) of croplands were inundated at least once during the 18-year timespan. Rice crops, due to their unique need of consistent surface water and dominance as a crop type in CA, had the highest proportion of and mean annual inundation area, while citrus crops had the lowest. Mean monthly inundation patterns in most croplands followed California's precipitation patterns with high inundation during the winter and spring rainy season. At the county level, croplands in the southern Central Valley typically had high occurrences of inundation in conjunction with large crop areas. Exposure and sensitivity of inundation for three crop types (citrus, deciduous, and vineyards) that are typically less associated with intentional inundation were geographically variable, but overall were generally highest in counties in the southern Central Valley, California's primary agricultural region. Flood and precipitation related crop insurance claims indicated that rice had the highest mean indemnity payout for any month with damages typically occurring in March and April. Insurance claims were also high in deciduous fruit and nut crops, which had peak damages in February. A comparison between inundation results and insurance claims suggests that the inundation mapped by our process coincides with claim activity. These data elucidate water inundation patterns across the state that can serve to inform farmers, insurers, decision makers, resource managers, and flood mitigation professionals.

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USGS2022

New-generation pesticides are prevalent in California's Central Coast streams

Pesticides are widely recognized as important biological stressors in streams, especially in heavily developed urban and agricultural areas like the Central California Coast region. We assessed occurrence and potential toxicity of pesticides in small streams in the region using two analytical methods: a broad-spectrum (223 compounds) method in use since 2012 and a newly developed method for 30 additional new-generation fungicides and insecticides. At least one pesticide compound was identified in 83 of the 85 streams sampled. About one-half (48%) of the 253 pesticides measured were detected at least once and 27 were detected in 10% or more of samples. Three of the top 4, and 6 of the top 10 most frequently detected compounds (chlorantraniliprole, dinotefuran, boscalid, thiamethoxam, clothianidin and the fluopicolide degradate 2,6-dichlorobenzamide) were analyzed by the new method. Pesticide mixtures were common, with two or more pesticide compounds detected in 81% of samples and 10 or more in 32% of samples. The pesticide count at a site was relatively consistent over the 6-week study. Four sites with mixed land-use in the lower basin (<5 km from the sampling site) tended to have the highest pesticide counts and the highest concentrations. Potential toxicity (assessed by comparison to benchmarks) to invertebrates was much more common than potential toxicity to fish or plants and was associated with a wide array of insecticides. The common occurrence of new-generation pesticides highlights the need to continuously update analytical methods to keep pace with changing pesticide use for a fuller assessment of pesticide occurrence and effects on the environment.

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USGS2022

Stable isotopes provide insight into sources and cycling of N compounds in the Sacramento-San Joaquin Delta, California, USA

River deltas and their diverse array of aquatic environments are increasingly impacted by anthropogenic inputs of nitrogen (N). These inputs can alter the N biogeochemistry of these systems and promote undesirable phenomena including harmful algae blooms and invasive aquatic macrophytes. To examine N sources and biogeochemical processes in the Sacramento-San Joaquin Delta, a river delta located in central California, USA, that is fed primarily by the Sacramento River, we utilized a multi-tracer approach that measured N species concentrations and stable isotope values monthly from April 2011 to November 2012 in samples collected from the channelized mainstem of the Sacramento River, two channelized distributaries of the Sacramento River, and the Cache Slough Complex, a network of Sacramento River tributaries and shallow water wetland habitat. We found that the Sacramento River and its channelized distributaries received N primarily in the form of NH 4 + from treated wastewater effluent and that NH 4 + was lost rapidly while NO 3 − was gained more slowly during subsequent downstream transit, driven by an array of biogeochemical processes whose identities could be constrained via examination of stable isotope values. The Cache Slough Complex, which was characterized by lower net flows and higher water residence times than the Sacramento River and its distributaries, received variable inputs of low conductivity water elevated in NH 4 + from the Sacramento River and higher conductivity water elevated in NO 3 − from landward tributaries. Deviations from expected conservative mixing of these sources were spatially variable but broadly indicative of local inputs of treated wastewater effluent NO 3 − , conversion of Sacramento River NH 4 + to NO 3 − via nitrification, uptake of NH 4 + and NO 3 − by phytoplankton, and remineralization of organic N. These findings highlight both the diversity in N dynamics in anthropogenically impacted river delta environments and the utility of a multi-tracer approach in constraining these processes in such complex systems.

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USGS2022

Pesticide exposure of wild bees and honey bees foraging from field border flowers in intensively managed agriculture areas

Bees are critical for food crop pollination, yet their populations are declining as agricultural practices intensify. Pollinator-attractive field border plantings (e.g. hedgerows and forb strips) can increase bee diversity and abundance in agricultural areas, however recent studies suggest these plants may contain pesticides. Pesticide exposure for wild bees in agricultural areas remains largely unknown, however this information is needed to inform agricultural practices and pesticide regulations meant to protect bees. It is important to determine whether border plantings that attract and support pollinators by providing floral resources may also deliver pesticides to them. In this study, we collected various samples for pesticide residue analysis including: multiple species of wild bees, honey bees, flowers from four types of bee-attractive field border plants, and soil. Silicone bands were also utilized as passive aerial samplers of pesticide residues. The five pesticides detected most frequently across all samples were the insecticide bifenthrin, the herbicides thiobencarb, metolaclor, and propanil, and the fungicide fluopyram. We detected the greatest number of parent pesticides in passive aerial samplers (24), followed by soil (21). Pesticides were also detected in field border plant flowers (16), which do not receive direct pesticides applications and many of which were not applied to adjacent field crops. Pesticide concentrations were lower in bees than in flowers but higher in bees than in soils. Pesticide residue per bee (ng/bee) increased with increasing wild bee size, though pesticide concentration (ng/g) did not increase. While honey bees and wild bees contained a similar number and concentration of pesticides overall, pesticide mixtures varied by bee type, and included some mixtures known to cause sublethal effects. The results from this study highlight the benefits of measuring more sample types to capture the total exposome of bees, including a greater range of bee species, as well as the need to consider exposure to pesticides at the landscape level.

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