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Predevelopment water levels, groundwater recharge, and selected hydrologic properties of aquifer materials, Hinkley and Water Valleys, California

Hydrologic and geophysical data were collected to support updates to an existing groundwater-flow model of Hinkley Valley, California, in the Mojave Desert about 80 miles northeast of Los Angeles, California. These data provide information on predevelopment (pre-1930) water levels, groundwater recharge, and selected hydrologic properties of aquifer materials. A predevelopment groundwater-level map, drawn using water-level measurements from 48 wells collected as early as 1918, showed groundwater movement from recharge areas along the Mojave River to evaporative discharge areas near the margin of Harper (dry) Lake in Water Valley. During predevelopment conditions, depth to water ranged from near land surface along the Mojave River to above land surface near Harper (dry) Lake, consistent with flowing wells in Water Valley at that time. Depths to water in much of Hinkley Valley downgradient from the Lockhart fault were less than 20 feet below land surface. By 2017, water-level declines as a result of agricultural pumping, were as much as 60 feet near the Hinkley compressor station. Areal recharge from infiltration of precipitation on the valley floor is negligible. Average annual recharge as infiltration of runoff from upland drainages to Hinkley and Water Valleys averages 64.7 acre-feet per year. In most years recharge does not occur; in years when it occurs, recharge to Hinkley Valley is typically about 296 acre-feet. In contrast, average recharge as infiltration of streamflow from the Mojave River from 1931 to 2015 was between 13,400 and 17,100 acre-feet per year; in some years recharge from the Mojave River exceeded 100,000 acre-ft. Estimates of predevelopment groundwater movement through Hinkley Gap and groundwater discharge to Harper (dry) Lake ranged from 570 to 1,900 and 820 to 2,460 acre-feet per year, respectively; at the time of this study in 2017, groundwater movement through Hinkley Gap was estimated to be about 83 acre-feet per year. Hydraulic-conductivity values estimated from slug-test data for 95 monitoring wells ranged from less than 0.1 to 680 feet per day (ft/d); values generally decreased with depth. Median hydraulic-conductivity values calculated from nuclear magnetic resonance (NMR) data for Mojave River alluvium and near-shore lake deposits were 73 and 11 ft/d, respectively; median hydraulic-conductivity values for locally derived alluvium and weathered bedrock were 6 and 2 ft/d, respectively. Hydraulic-conductivity values, estimated from NMR data for formerly saturated deposits overlying the 2017 water table, were as high as 300 ft/d near the Hinkley compressor station. Downgradient from the Hinkley compressor station, formerly saturated deposits had hydraulic-conductivity values of about 150 ft/d, which were higher than values in saturated material. Coarse-textured, permeable material in formerly saturated deposits above the 2017 water table may have allowed groundwater, released from the Hinkley compressor station that may have contained Cr(VI), to move rapidly downgradient. The Lockhart fault is an impediment to groundwater flow within Hinkley Valley. Groundwater-flow directions from horizontal point-velocity probe data were deflected to the west on the upgradient side of the fault compared to the nominal direction of groundwater flow estimated from water-level data. Younger groundwater was present on the upgradient and downgradient sides of the fault, and older groundwater with unadjusted carbon-14 ages as old as 5,650 years before present was in water from wells within splays of the Lockhart fault, consistent with limited groundwater movement across the fault. As a result, groundwater and Cr(VI) released from the Hinkley compressor station moved to the northwest along the downgradient side of the fault. Coupled well-bore flow and depth-dependent water-quality data show water from wells C-01 and IW-03 within the Q4 2015 (October–December 2015) regulatory Cr(VI) plume was yielded from thin layers within the aquifer that are composed of well-sorted lake-margin (beach) deposits that likely have high lateral and longitudinal connectivity. Collectively, data show highly permeable deposits above the regional water table and thin permeable deposits within saturated portions of the upper aquifer that may have conducted groundwater and Cr(VI) downgradient when releases from the Hinkley compressor station first occurred.

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Sequestration and reoxidation of chromium in experimental microcosms

Groundwater containing hexavalent chromium, Cr(VI), downgradient from the Pacific Gas and Electric Company (PG&E) Hinkley compressor station in the Mojave Desert, 80 miles northeast of Los Angeles, California, is undergoing bioremediation using added ethanol as a reductant in a volume of the aquifer defined as the in situ reactive zone (IRZ). This treatment reduces Cr(VI) to trivalent chromium, Cr(III), which is rapidly sequestered by sorption to aquifer particle surfaces and by co-precipitation within iron (Fe) or manganese (Mn) bearing minerals forming in place as reduction proceeds. Successful mitigation of the Cr(VI) plume is projected to require 10–95 years, at which time bioremediation with ethanol will likely cease. This projection assumes that Cr(VI) removal is permanent and that no Cr(III) will oxidize back to Cr(VI) in the event of changing hydrologic conditions that may cause oxygen-rich water to re-enter the IRZ. Laboratory microcosm experiments were done to explore the process of reductive sequestration of Cr(VI) to Cr(III) and the potential for reoxidation of Cr(III) to Cr(VI). In reductive sequestration experiments, batch microcosms were prepared with aquifer materials collected from sites upgradient of the Cr(VI) regulatory plume. Control microcosms were prepared using Fe- and Mn-coated quartz sand. Unfiltered Mojave River groundwater containing an added tracer of isotopically labeled chromium-50 were reacted with microcosm materials for up to 2 years; during this time, bio-reduction was stimulated by repeated additions of diluted ethanol to maintain reduced conditions within appropriate ranges, avoiding sulfate reducing or methanogenic conditions as much as possible while mimicking field conditions. Analysis of chromium-50, Fe, and Mn obtained by sequential extraction from microcosms harvested (incubation terminated and microcosm contents analyzed) at various times showed that some aqueous chromium (Cr) was sorbed to particle surfaces within hours; reduction to Cr(III) and incorporation into amorphous and crystalline solid phases occurred during the next few months. Amorphous Cr-containing fractions included Fe and Mn hydroxides and organic matter. Ultimately, most of the chromium-50 tracer was present in the less reactive crystalline phase. However, Fe and Mn were broadly distributed at later stages of reduction, and both were spatially co-located with Cr on a micrometer (μm) scale. Solid-phase data collected using scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) and X-ray absorption spectroscopy (XAS) indicated that some Cr(III) was associated with mixed valence Fe oxides like magnetite and Fe-Mn oxides like jacobsite. Additionally, Cr(III) was observed within several μm of Fe and Mn embedded in clays and in mineral coatings. To evaluate the potential for reoxidation of Cr(III) to Cr(VI), additional batch microcosms of aquifer materials and mixtures of Fe- and Mn-coated sand were first reduced for more than 1 year and subsequently oxidized for almost 2 years. Hexavalent chromium was formed and was available for release to the aqueous phase during oxidation of all materials; however, the timing and amount of Cr(VI) formed and released varied among substrates. Artificial substrates containing more Mn produced more Cr(VI). Site material characteristic of recent Mojave River deposits contained within the IRZ produced the least Cr(VI) during oxidation, while site materials composed of older Mojave River aquifer material (containing more Mn) produced more Cr(VI). Site material collected from within the IRZ contained more Cr but produced an intermediate amount of Cr(VI) following oxidation. The combined results of microcosm chemistry and solid-phase analyses showed that the nature and locus of Cr(III) sequestration influenced its vulnerability to reoxidation to Cr(VI). It was concluded that co-location of Cr with Mn at later stages of reduction influenced the susceptibility of Cr(III) to reoxidation in microcosms. Reoxidation of Cr(III) to Cr(VI) was observed in experiments with previously reduced material after just 14 days exposure to oxygen. As much as 10 percent of added Cr was oxidized to Cr(VI) in microcosms prepared using recent Mojave River aquifer material, and as much as 20 percent of added Cr was oxidized to Cr(VI) in microcosms prepared using older Mojave River aquifer material. Less Cr(VI) (less than 3 percent of Cr added before reduction) was released to the aqueous phase, and this release occurred following longer oxygen exposure. Site managers may need to plan for long-term monitoring and the possibility of active maintenance of anoxic conditions within the IRZ to ensure permanent sequestration of Cr after bioremediation with ethanol ceases.

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Summary and conclusions

Executive Summary Chromium concentrations in rock and aquifer material in Hinkley and Water Valleys in the Mojave Desert, 80 miles northeast of Los Angeles, California, are generally low compared to the average chromium concentration of 185 milligrams per kilogram (mg/kg) in the average bulk continental crust. Chromium concentrations in felsic, coarse-textured “Mojave-type” deposits, composed of Mojave River stream (alluvium) and lake-margin (beach) deposits sourced from the Mojave River, are as low as 5 mg/kg, with a median concentration of 23 mg/kg in aquifer materials adjacent to the screened intervals of sampled wells. The most abundant chromium-containing mineral within aquifer materials in Hinkley and Water Valleys is magnetite. Magnetite is resistant to weathering, and about 90 percent of chromium remains within unweathered mineral grains. However, chromium-containing hornblende diorite and basalt are present in surrounding uplands, and chromium-containing actinolite is present within some aquifer materials. Although geologic abundance of chromium is clearly important, hexavalent chromium, Cr(VI), concentrations in alkaline oxic groundwater are related to additional factors. Hexavalent chromium concentrations in groundwater are influenced by a combination of processes including (1) mineralogy and the weathering rates of chromium-containing minerals; (2) texture of aquifer deposits; (3) accumulation of chromium weathered from minerals within surface coatings on mineral grains; (4) oxidation of accumulated Cr(III) to Cr(VI) in the presence of manganese oxides (Mn oxides), including the abundance and oxidation states of those Mn oxides; (5) pH-dependent desorption of chromium from coatings on the surfaces of mineral grains into groundwater during appropriate aqueous geochemical conditions; and (6) age (time since recharge) of groundwater. The pH of groundwater increases with groundwater age (time since recharge) as a result of silicate weathering, and desorption of Cr(VI) from aquifer deposits increases with increasing pH as long as groundwater remains oxic. In the absence of the detailed geologic, geochemical, and hydrologic data collected as part of this study, pH-dependent sorption, evaluated as the Cr(VI) occurrence probability at the measured pH, is an effective indicator of natural or anthropogenic Cr(VI). The Pacific Gas and Electric Company (PG&E) Hinkley compressor station is used to compress natural gas as it is transported through a pipeline from Texas to California. Between 1952 and 1964, cooling water containing Cr(VI) was discharged to unlined ponds and released into groundwater in unconsolidated aquifers. The extent of groundwater containing evidence of at least some anthropogenic Cr(VI) was 5.5 square miles (mi 2 ) and was estimated using a summative scale incorporating geologic, geochemical, and hydrologic data collected from more than 100 wells between March 2015 and November 2017. The summative-scale Cr(VI) plume extent is larger than the 2.2 mi 2 extent of the October–December 2015 (Q4 2015) regulatory Cr(VI) plume but is smaller than the 8.3 mi 2 maximum mapped extent of Cr(VI) greater than the interim regulatory Cr(VI) background concentration of 3.1 micrograms per liter (μg/L). The summative-scale Cr(VI) plume is within felsic, low-chromium aquifer material deposited by the Mojave River described as Mojave-type deposits and is within the area covered by the PG&E monitoring well network. Background Cr(VI) concentrations were calculated using the computer program ProUCL 5.1 as the upper 95-percent tolerance limit, UTL 95 , using data from wells outside the summative-scale Cr(VI) plume extent collected between April 2017 and March 2018. The overall UTL 95 for undifferentiated, unconsolidated deposits in the eastern and western subareas and the northern subarea upgradient of the Mount General fault in Hinkley Valley was 3.8 μg/L; this value is similar to the overall UTL 95 value of 3.9 μg/L calculated for Mojave-type deposits in Hinkley and Water Valleys, and is similar to the maximum Cr(VI) concentration of older groundwater in contact with Mojave-type deposits of 3.6 μg/L. In most cases the overall UTL 95 value may be an acceptable Cr(VI) background value near the Cr(VI) plume margin; however, UTL 95 values for the various subareas in Hinkley and Water Valleys provide greater resolution of Cr(VI) background that may be important for some purposes. The UTL 95 values for undifferentiated, unconsolidated deposits in the eastern, western, and northern subareas upgradient of the Mount General fault were 2.8, 3.8, and 4.8 μg/L, respectively. The UTL 95 value of 2.8 μg/L for wells screened in undifferentiated, unconsolidated deposits in the eastern subarea is important for plume management because the Hinkley compressor station and most of the summative-scale Cr(VI) plume are within the eastern subarea. A UTL 95 value of 2.3 μg/L was calculated for Mojave-type deposits downgradient from the Hinkley compressor station. This value represents Cr(VI) concentrations that may have been present in that part of the aquifer had Cr(VI) not been released from the Hinkley compressor station, and it reflects coarser textured deposits in this area and the proximity of those deposits to recharge areas along the Mojave River that results in younger (post-1952), less alkaline groundwater than in wells farther downgradient. This value may be a suitable metric for Cr(VI) cleanup goals within the Cr(VI) plume after regulatory updates. A separate UTL 95 value of 5.8 μg/L was calculated for mudflat/playa deposits and older groundwater near Mount General in the eastern subarea. The UTL 95 values calculated for undifferentiated, unconsolidated deposits in the northern subarea downgradient from the Mount General fault and in Water Valley, including lacustrine (lake) deposits and material eroded from basalt and Miocene deposits, were 9.0 and 6.4 μg/L, respectively. Hexavalent chromium concentrations in more than 70 domestic wells sampled between January 27 and 31, 2016, ranged from less than the study reporting level of 0.1–4.0 μg/L, with a median concentration of 1.2 μg/L. Hexavalent chromium concentrations in water from domestic wells did not exceed UTL 95 values within subareas where the wells were located. Water from 47 percent of domestic wells sampled between January 27 and 31, 2016, had arsenic, uranium, or nitrate concentrations above a maximum contaminant level. Anthropogenic Cr(VI) within groundwater downgradient from the Hinkley compressor station is treated by PG&E using bioremediation by adding ethanol as a reductant within a volume of aquifer known as the in situ reactive zone (IRZ). Laboratory microcosm studies showed that Cr(VI) is rapidly reduced to Cr(III) with additions of ethanol. Reduced Cr(III) is sorbed and is sequestered into crystalline iron and manganese oxides on the surfaces of mineral grains within the microcosms during a period of several months. Trivalent chromium was reoxidized back to Cr(VI) within 2 weeks of return to oxic (oxygen present) conditions within the microcosms. As much as 10 percent of added Cr was oxidized to Cr(VI) in microcosms prepared using recent Mojave River aquifer material, and as much as 20 percent of added Cr was oxidized to Cr(VI) in microcosms prepared using older Mojave River aquifer material. Less Cr(VI) (less than 3 percent of Cr added before reduction) was released to the aqueous phase, and this release occurred following longer time periods of oxygen exposure. Sequestration of chromium with manganese oxides during reduction facilitates reoxidation of Cr(III) to Cr(VI) under oxic conditions. Future maintenance of anoxic (oxygen absent) conditions would ensure continued sequestration of chromium as Cr(III) within IRZ treated portions of the Cr(VI) plume. Although Cr(VI) within the summative-scale Cr(VI) plume may have an anthropogenic history associated with releases from the Hinkley compressor station, Cr(VI) concentrations less than the UTL 95 values for the various subareas may not require regulatory attention. The regulatory Cr(VI) plume can be updated using the UTL 95 values calculated as part of this study. The updated regulatory Cr(VI) plume extent would lie within the summative-scale Cr(VI) plume extent. The authority to establish regulatory Cr(VI) background values, clean-up goals, and future site management practices resides with the Lahontan Regional Water Quality Control Board.

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Distribution and abundance of Southwestern Willow Flycatchers (Empidonax traillii extimus) on the upper San Luis Rey River, San Diego County, California—2022 data summary

Executive Summary We surveyed for Southwestern Willow Flycatchers ( Empidonax traillii extimus ; flycatcher) along the upper San Luis Rey River near Lake Henshaw in Santa Ysabel, California, in 2022. Surveys were completed at four locations: three downstream from Lake Henshaw, where surveys occurred from 2015 to 2021 (Rey River Ranch [RRR], Cleveland National Forest [CNF], Vista Irrigation District [VID]), and one at VID Lake Henshaw (VLH) that has been surveyed annually since 2018. There were 71 territorial flycatchers detected at 3 locations (RRR, CNF, VLH), and 6 transient flycatchers of unknown subspecies detected at VID and VLH. Downstream from Lake Henshaw, four territorial flycatchers, including two males and two females, were detected at RRR and CNF. In total, two territories were established consisting of two pairs at these locations. At VLH, we detected 67 territorial flycatchers, including 30 males, 34 females, and 3 flycatchers of unknown sex. In total, 40 territories were established, containing 35 pairs (24 monogamous pairings and 5 polygynous groups consisting of 4 males each pairing with 2 different females, and 1 male pairing with 3 different females), and 5 flycatchers of undetermined breeding status (3 males and 2 flycatchers of unknown sex). Brown-headed cowbirds ( Molothrus ater ; cowbird) were detected at all four survey locations. Flycatchers used five habitat types in the survey area: (1) mixed willow riparian, (2) willow-cottonwood, (3) willow-oak, (4) willow-ash, and (5) oak-sycamore. Of the flycatcher locations, 83 percent were located in habitat characterized as mixed willow riparian, and 92 percent were in habitat with greater than 95-percent native plant cover. Exotic vegetation was not prevalent in the survey area. There were 22 nests incidentally located during surveys: 5 were successful, 1 was seen with eggs on the last visit, 10 failed, and the outcome of the remaining 6 nests was unknown. Three of these nests were parasitized by cowbirds. There were 13 juveniles detected at VLH; no juveniles were detected at RRR or CNF. Five banded flycatchers were detected during surveys, three of which were confirmed to be adults that held territories in previous years. In addition, two flycatchers with a single dark blue federal band, indicating that they were banded as nestlings in a previous demographic study downstream from Lake Henshaw (Howell and others, 2022), were resighted during surveys.

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Near-field receiving-water monitoring of trace metals and a benthic community near the Palo Alto Regional Water Quality Control Plant in south San Francisco Bay, California—2020

Trace-metal concentrations in sediment and in the clam Limecola petalum (World Register of Marine Species, 2020; formerly reported as Macoma balthica and M. petalum ), clam reproductive activity, and benthic macroinvertebrate community structure were investigated in a mudflat 1 kilometer (km) south of the discharge of the Palo Alto Regional Water Quality Control Plant (PARWQCP) in south San Francisco Bay, California. This report includes the data collected by the U.S. Geological Survey (USGS) for January 2020–December 2020 (Cain and others, 2022). These data append to long-term datasets extending back to 1974. A major focus of the report is an integrated description of the 2020 data within the context of the longer, multidecadal dataset. This dataset supports the City of Palo Alto’s Near-Field Receiving- Water Monitoring Program, initiated in 1994. Silver and copper contamination substantially decreased at the site in the 1980s following the implementation by PARWQCP of advanced wastewater-treatment and source-control measures. Since the 1990s, concentrations of these elements in surface sediments have continued to decrease, although more slowly. For example, from 1994 to 2020, the minimum annual mean silver concentration—0.20 milligram per kilogram (mg/kg)—was observed in multiple years. In 2020, silver concentrations ranged from 0.18 to 0.28 mg/kg. These concentrations are 2 to 3 times higher than the regional background concentration. Presently (2020), sediment-copper concentrations appear to be near the regional background level. Over the same period (1994–2020), sedimentary iron and zinc exhibited modest decreases. Sedimentary aluminum, chromium, mercury, nickel, and selenium have not exhibited any trend. Since 1994, silver and copper concentrations in L. petalum have varied seasonally, apparently in response to a combination of site-specific metal exposures and cyclic growth and reproduction, as reported previously. Seasonal patterns for other elements, including chromium, mercury, nickel, selenium, and zinc, generally were similar in timing and magnitude as those for silver and copper. Downward trends in the silver and zinc concentrations in L. petalum during 1994–2020 were evident and appeared to be related to the general physiological condition of the clam, indicated by a condition index. Biological effects of elevated silver and copper contamination at the Palo Alto site have been interpreted from data collected during and after the recession of these contaminants. Concentrations of both elements in the soft tissues of L. petalum decreased with sedimentary copper and silver. This pattern was associated with changes in the reproductive activity of L. petalum , as well as the structure of the benthic invertebrate community. Reproductive activity of L. petalum increased as metal concentrations in L. petalum decreased (Hornberger and others, 2000), and presently is stable with almost all animals initiating reproduction in the fall and spawning the following spring. Analyses of the benthic community structure indicate that the infaunal invertebrate community has shifted from one dominated by several opportunistic species when silver and copper exposures were highest to one in which the species abundance is more evenly distributed, a pattern that indicates a more stable community that is subjected to fewer stressors. Importantly, this long-term change is unrelated to other metals and other measured environmental factors, including salinity and sediment composition. In addition, two of the opportunistic species ( Ampelisca abdita and Streblospio benedicti ) that brood their young and live on the surface of the sediment in tubes have shown a continual decrease in dominance coincident with the decrease in metals. Both species had short-lived rebounds in abundance in 2008, 2009, and 2010 and showed signs of increasing abundance in 2020. Heteromastus filiformis (a subsurface polychaete worm that lives in the sediment, consumes sediment and organic particles residing in the sediment, and reproduces by laying its eggs on or in the sediment) showed a concurrent increase in dominance and, in the last several years before 2008, showed a stable population. H. filiformis abundance increased slightly from 2011 to 2012 and returned to pre-2011 numbers in 2020. The reproductive mode of most species that were present in 2020 was indicative of species that were capable of movement either as pelagic larvae or as mobile adults. Although oviparous species were lower in number in this group, the authors hypothesize that these species will return slowly as more species move back into the area. The use of functional ecology was highlighted in the 2020 benthic community data, which showed that the animals that have now returned to the mudflat are those that can respond successfully to a physical, nontoxic disturbance. Today, community data show a mix of species that consume the sediment, or filter feed, those that have pelagic larvae that must survive landing on the sediment, and those that brood their young. The long-term recovery observed after the 1970s can be ascribed to the decrease in sediment pollutants.

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Witnessing history: Comparison of a century of sedimentary and written records in a California protected area

We use a combination of proxy records from a high-resolution analysis of sediments from Searsville Lake and adjacent Upper Lake Marsh and historical records to document over one and a half centuries of vegetation and socio-ecological change—relating to logging, agricultural land use change, dam construction, chemical applications, recreation, and other drivers—on the San Francisco Peninsula. A relatively open vegetation with minimal oak ( Quercus ) and coast redwood ( Sequoia sempervirens ) in the late 1850s reflects widespread logging and grazing during the nineteenth century. Forest and woodland expansion occurred in the early twentieth century, with forests composed of coast redwood and oak, among other taxa, as both logging and grazing declined. Invasive species include those associated with pasturage ( Rume x , Plantago ), landscape disturbance ( Urtica , Amaranthaceae), planting for wood production and wind barriers ( Eucalyptus ), and agriculture. Agricultural species, including wheat, rye, and corn, were more common in the early twentieth century than subsequently. Wetland and aquatic pollen and fungal spores document a complex hydrological history, often associated with fluctuating water levels, application of algaecides, raising of Searsville Dam, and construction of a levee. By pairing the paleoecological and historical records of both lakes, we have been able to reconstruct the previously undocumented impacts of socio-ecological influences on this drainage, all of which overprinted known climate changes. Recognizing the ecological manifestations of these impacts puts into perspective the extent to which people have interacted with and transformed the environment in the transition into the Anthropocene.

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Time-lapse seafloor surveys reveal how turbidity currents and internal tides in Monterey Canyon interact with the seabed at centimeter-scale

Here we show how ultra-high resolution seabed mapping using new technology can help to understand processes that sculpt submarine canyons. Time-lapse seafloor surveys were conducted in the axis of Monterey Canyon, ∼50 km from the canyon head (∼1,840 m water depth) over an 18-month period. These surveys comprised 5-cm resolution multibeam bathymetry, 1-cm resolution lidar bathymetry, and 2-mm resolution stereophotographic imagery. Bathymetry data reveal centimeter-scale textures that would be undetectable by more traditional survey methods. Upward-looking Acoustic Doppler Current Profilers at the site recorded the flow character of internal tides and the passage of three turbidity currents, while sediment cores collected from the site record flow deposits. Combined with flow and core data, the bathymetry shows how turbidity currents and internal tides modify the seabed. The turbidity currents drape sediment across the site, infilling bedform troughs and smoothing erosional features carved by the internal tides (e.g., rippled scours). Turbidity currents with speeds of 0.9–3.3 m/s failed to cause notable bedform movement, which is surprising given that flows with similar speeds produced rapid bedform migration elsewhere, including the upper Monterey Canyon. The lack of migration may be related to the character of the underlying substrate or indicate that turbidity currents at the site lack dense, near-bed layers. The scale of scours produced by the internal tides (≤0.7 m/s) approaches the scale of features recorded in the ancient rock record. Thus, these results illustrate how the scale gap between seabed mapping technology and the rock record may eventually be bridged.

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Forest structure and residual tree growth at the Northwest Gateway project area, Lassen Volcanic National Park, California

Mechanical thinning and prescribed fire are common mitigation treatments to reduce fire hazards. However, these treatments are infrequently applied together within national parks. The Northwest Gateway project at Lassen Volcanic National Park is an exception to this pattern. Various thinning prescriptions were applied to the project area in 2014, with a subset of the area prescribed burned in 2018 and 2019. To determine responses to these treatments, we analyzed forest structure and fuels data across a network of long-term monitoring plots measured before treatments and in multiple years following treatments. Additionally, we assessed patterns in individual tree growth from cores taken from 101 individual yellow pines (ponderosa pine, Pinus ponderosa Douglas ex Lawson & C. Lawson, and Jeffery pine, P. jeffreyi Grev. & Balf.) within the project unit. Basal area and stem density were reduced following thinning treatments for pole-sized (≤15-centimeter diameter at base height) and overstory trees (>15-centimeter diameter at base height), with sharper reductions in pole-sized trees. Proportional change in live basal area after thinning was highest for pole-size Abies , with more than 80-percent basal area and stem density removed on average. There were large reductions in pole-sized Pinus and Populus . However, Populus trees were not targeted for removal, suggesting that these trees died via other mechanisms. Thinning treatments also resulted in reductions in stand density index values and in surface fuel loading when followed by prescribed fire, particularly for small fuels size classes (such as litter/duff, 1-hour, and 10-hour fuels). Growth of individual residual yellow pine, measured in terms of annual basal area increment, indicated a strong growth release in the years following thinning treatments. Taken together, these results indicate that forest restoration treatments at the Northwest Gateway project area were effective at reducing stand density and encouraging growth of residual Pinus . Interestingly, our results also indicated that although thinning followed by prescribed fire was most effective at reducing surface fuel loads, harvest techniques such as whole tree yarding may effectively reduce the accumulation of post-treatment residual fuels, especially when combined with hand piling and other targeted treatments.

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Protocol for the reintroduction of California red-legged frogs to Santa Monica Mountains National Recreation Area

Once common and widespread in Southern California, California red-legged frogs ( Rana draytonii ) began declining sometime in the middle of the 20th century. They were listed as threatened under the Endangered Species Act in 1996. Three small and isolated populations remained in Los Angeles and Ventura Counties by the start of the 21st century. The nearest population of California red-legged frogs to Santa Monica Mountains National Recreation Area is critically small, located 15 km to the north, yet there is evidence of persistence, including successful reproduction each year it has been measured. A potential solution to alleviate small population size and isolation is to reintroduce a species back to habitable historical locations nearby. In 2011, we initiated a project to reintroduce California red-legged frogs back to the Santa Monica Mountains, where historical records showed they were once widespread. We developed a procedure to transfer partial egg masses into tadpole rearing pens located within streams determined to be suitable for the species. This translocation protocol outlines our procedure and results for the first five years of the project. It is our hope that this protocol will guide and inform similar conservation efforts for California red-legged frogs in other parts of their range as well as other amphibian conservation efforts throughout the world.

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Bivalve effects on the food web supporting delta smelt—A long-term study of bivalve recruitment, biomass, and grazing rate patterns with varying freshwater outflow

Phytoplankton are an important and limiting food source in the Sacramento-San Joaquin Delta and San Francisco Bay in California. Decreasing phytoplankton biomass is one possible factor for the pelagic organism decline and the decline of the protected Hypomesus transpacificus (delta smelt). Bivalves Corbicula fluminea and Potamocorbula amurensis (hereafter C. fluminea and P. amurensis , respectively) have been shown to control phytoplankton biomass throughout San Francisco Bay and the Sacramento-San Joaquin Delta; therefore, their distribution and population dynamics are of great interest. We describe the distribution and dynamics of bivalve biomass using samples from California Department of Water Resources’ (DWR) 2019 benthic monitoring program. As one element of DWR’s and the Bureau of Reclamation’s Environmental Monitoring Program (EMP), the DWR benthic monitoring program examines the effect of water project operations on the estuary as prescribed by a series of Water Rights Decisions mandated by the California State Water Resources Control Board (SWRCB). The biomass and grazing rate values of both bivalves had similar patterns, therefore, comments on biomass distribution can be applied to grazing rate data. Biomass and recruitment values of C. fluminea were too low at station C9 (Old River upstream from Clift on Court Forebay Intake) to describe a temporal pattern. Corbicula fluminea biomass values were consistently high at station D24 (Sacramento River). Station D4L (confluence of San Joaquin and Sacramento Rivers) biomass values were low during the first half of the year and high the rest of the year. Corbicula fluminea biomass values at station P8 (San Joaquin River) were the highest and most consistent on that river. Station D16 (San Joaquin River) and station D28A (central delta) biomass values were near zero with a small peak in May. Potamocorbula amurensis biomass values were near zero at station D4L (confluence of San Joaquin and Sacramento Rivers). Biomass values were strongly seasonal at station D6 (Suisun Bay). Station D41 (San Pablo Bay) had the highest P. amurensis biomass values. Station D7 (Grizzly Bay) and station D41A (San Pablo Bay) had low biomass values in January-June or July and maximum biomass values in August. Corbicula fluminea recruits in the Sacramento River stations peaked twice, from January to June and from September to December. At the San Joaquin River stations, C. fluminea recruitment peaked from May to July or August and from November to December. Peak recruit abundance was higher on the Sacramento River than the San Joaquin River. Potamocorbula amurensis recruitment was more seasonal than C. fluminea , with a high number of recruits followed by periods with no recruits. Station D4L had few recruits except in January. Station D6 had low recruitment from January to February, increased in August, and peaked from November to December. Station D7 had fewer recruits than station D6 but had a similar temporal pattern, although winter recruits continued into April instead of February. Station D41 recruits were sparce and present only from May to July. Station D41A had the most recruits from January to July, and again in September.

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Strontium isotope chronostratigraphic age of a sirenian fossil site on Santa Rosa Island, Channel Islands National Park, California

Fossils in the order Sirenia (family Dugongidae) from Santa Rosa Island, part of Channel Islands National Park in southern California, provide rare temporal and spatial links between earlier and later evolutionary forms of dugongids, and add information about their dispersal into the northeastern Pacific region. Marine sedimentary rocks containing these fossils have characteristics of both the late Oligocene to middle Miocene Vaqueros Sandstone and the early to middle Miocene Rincon formation observed elsewhere. To determine a more precise age of the fossils, marine invertebrate shells were collected from the same exposures as the sirenian fossils for chronostratigraphic assessment using strontium isotope compositions and the well-calibrated seawater strontium evolution curve. Shells used for analysis were from bivalve mollusks ( Pycnodonte sp. [oyster] and Lyropecten sp. [scallop]) and crustaceans ( Balanus sp. [barnacle]). Results show a wide range of 87 Sr/ 86 Sr values, indicating that shell materials experienced varying degrees of diagenetic alteration. Strontium concentrations and 87 Sr/ 86 Sr values in subsamples of Pycnodonte shell show correlations between original shell material and a secondary component having lower strontium concentrations and less radiogenic (lower) 87 Sr/ 86 Sr. In contrast, all Lyropecten shell analyses yielded a uniform 87 Sr/ 86 Sr value (0.708440±0.000010 [2× standard deviation]) over a wide range of strontium concentrations (around 900 to 1,800 micrograms per gram [μg/g]). Results for Balanus shell subsamples show a range of strontium compositional behavior between the other two types of shell. Acetic acid leachates of sandy matrix confirm that diagenetic fluids had low 87 Sr/ 86 Sr values consistent with the least radiogenic values in Pycnodonte subsamples. A simple mixing model between two calcite end-members can explain observed Pycnodonte data, although actual diagenetic processes likely involved secondary dissolution/reprecipitation or strontium ion exchange between shell material and pore fluid. Data indicate that only Lyropecten subsamples have retained their original 87 Sr/ 86 Sr compositions, resulting in a best-estimate age of 20.08±0.11 million years ago (Ma) (±95-percent confidence interval [CI]). Although Dugongidae fossils have been found in Miocene and younger sediments along the west coast of North America, the Santa Rosa Island specimens represent some of the earliest and most accurately dated sirenian fossils in the region. Chronostratigraphic results also constrain the timing of the transgressional processes represented by shallow-water (Vaqueros Sandstone) to deep-water (Rincon formation) depositional environments.

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Estimates of predator densities using mobile DIDSON surveys: Implications for survival of Central Valley Chinook Salmon

The Sacramento–San Joaquin Delta (hereafter, “the Delta”) is one of the estuaries with the most invasive species in the world, and nonnative predators may be a major factor in the observed decline of Central Valley Chinook Salmon Oncorhynchus tshawytscha over recent decades. In order for managers to take actions that might reduce predation-related mortality for these ecologically, culturally, and economically valuable fish, it is important to understand the factors influencing the distribution and abundance of piscivores in the Delta. In this study, we used a dual-frequency identification sonar (i.e., DIDSON) to conduct mobile surveys to quantify the abundances of piscivores in the Delta. We then used these data to identify the habitat features that are correlated with the abundance of piscivores. Prior to conducting the surveys, we used DIDSON data from captured fish to develop an algorithm to distinguish piscivores from nonpiscivores with high confidence (98% accuracy). A generalized linear mixed-effects model fit to these survey data indicated that predator abundances were most associated with areas of increased submerged aquatic vegetation patches, and channels that are straighter, with increased bathymetric complexity. When applied to the entire survey area, this model was successfully able to predict known areas of high predator densities. These results indicate that one approach to reduce predator densities in key locations throughout the Delta, and improve juvenile salmonid outmigration survival, is to reduce the extent of invasive submerged aquatic vegetation. Because experimental predator removals have been largely ineffective in the Delta, efforts to manipulate habitat to discourage nonnative predator recruitment and favor native species recruitment may provide a more effective solution to improve salmonid survival rates.

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Distribution and abundance of Least Bell’s Vireos (Vireo bellii pusillus), Southwestern Willow Flycatchers (Empidonax traillii extimus), and Coastal California Gnatcatchers (Polioptila californica californica) at the Santa Fe Dam, Los Angeles County, California—2022 data summary

In 2022, we surveyed for Least Bell’s Vireos ( Vireo bellii pusillus ; vireo), Southwestern Willow Flycatchers ( Empidonax traillii extimus ; flycatcher), and Coastal California Gnatcatchers ( Polioptila californica californica ; gnatcatcher) in the Santa Fe Dam detention basin and along the San Gabriel River upstream from the Santa Fe Dam near Irwindale, California. Four vireo surveys were completed between April 21 and July 13, 2022; three flycatcher surveys were completed between May 18 and July 13, 2022; and four gnatcatcher surveys were completed between April 21 and July 13, 2022. We detected seven territorial male vireos, including four that were paired and three with undetermined breeding status. We also detected one transient vireo. Two juvenile vireos were observed during surveys. Vireo territories were found in riparian scrub, willow ( Salix spp.)-cottonwood ( Populus spp.), and mixed willow habitat, with mixed willow the most commonly-recorded habitat type. Black willow ( S. gooddingii ) was the dominant plant species in most vireo territories. We detected 10 transient flycatchers in riparian scrub (5 individuals), mixed willow (4 individuals), and non-native vegetation (1 individual). Black willow and mule fat ( Baccharis salicifolia ) were the predominant plant species in flycatcher locations. We detected four territorial male gnatcatchers, two of which were paired and two of undetermined breeding status. We also detected one territorial female gnatcatcher. One juvenile gnatcatcher was observed during surveys. All gnatcatchers were detected in coastal sage scrub. The dominant shrub species at gnatcatcher locations were California sagebrush ( Artemisia californica ) and scale broom ( Lepidospartum squamatum ).

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Shallow deformation on the Kirby Hills fault, Sacramento–San Joaquin Delta, California (USA), revealed from high-resolution seismic reflection data and coring in a fluvial system

The Sacramento–San Joaquin Delta (Delta) in California (USA) is an important part of the state’s freshwater system and is also a major source of agricultural and natural resources. However, the Delta is traversed by a series of faults that make up the easternmost part of the San Andreas fault system at this latitude and pose seismic hazard to this region. In this study, we use new high-resolution chirp subbottom data to map and characterize the shallow expression of the Kirby Hills fault, where it has been mapped to cross the Sacramento River at the western extent of the Delta. The fault is buried here, but we document a broad zone of deformation associated with the eastern strand of the fault that changes in character, along strike, across ~600 m of the river channel. Radiocarbon dates from sediment cores collected in the Sacramento River provide some minimum constraints on the age of deformation. We do not observe evidence of the western strand as previously mapped. We also discuss difficulties of conducting a paleoseismologic study in a fluvial environment.

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User needs assessment for postfire debris-flow inundation hazard products

Debris flows are a type of mass movement that is more likely after wildfires, and while existing hazard assessments evaluate the rainfall intensities that are likely to trigger debris flows, no operational hazard assessment exists for identifying the areas where they will run out after initiation. Fifteen participants who work in a wide range of job functions associated with southern California postfire hazards were selected using purposive sampling for unstructured interviews about useful characteristics and needs for postfire debris-flow inundation hazard assessments. The interview guide was developed by a team of social and physical scientists following best practices for engaging with users. The guide focused on target information that could influence ongoing or not-yet-initiated research on debris-flow physics and hazard assessment methodology. Following standard methods for user needs assessment, the audio from the unstructured interviews was recorded, transcribed, and analyzed using a thematic coding scheme. Participants reported engaging with postfire debris-flow inundation as one of multiple postfire hazards and their information needs reflect this breadth. Most participants were from organizations with life and property mandates, and this focused their concerns on where debris-flow inundation could impact people’s physical safety, the ability of populations to egress, and damage to property. Common comments included, (1) the need to interpret inundation hazard assessments in the context of forecast rainfall—which are typically associated with different timeframes, 15 and 60 minutes, respectively; (2) the need to provide multiple scenarios in a hazard assessment to show how the hazard changes under different external factors such as varying rainfall intensity; and (3) the tension between fully reflecting all sources of uncertainty in identifying impacted areas and a high level of precision needed to determine evacuation zones in order to reduce evacuation fatigue. Participants saw utility in both low-resolution hazard assessments over large areas and fine-resolution targeted assessments over small areas, noting that the identification of target areas could pose an ethical challenge because some areas might be prioritized over others. Participants were concerned about the hazard posed by the continuum of postfire hydrologic hazards, including hyperconcentrated flows. Finally, participants recognized that the shrinking time window between the end of fire season and the start of the wet season in southern California makes the production, interpretation, and use of rapid postfire debris-flow inundation hazard assessments both important and challenging.

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Preliminary surficial geologic map of Leuhman Ridge and the surrounding area, Edwards Air Force Base and Air Force Research Laboratory, Kern and San Bernardino Counties, California

This preliminary geologic map presents mapping of the Leuhman Ridge area of Edwards Air Force Base, California, conducted between April 2020 and June 2021. The report focuses on surficial materials and bedrock to evaluate potential faults and other geologic features that may influence groundwater movement. The preliminary work confirms that the Spring Fault, previously mapped by Dibblee (1960, 1967), is a Quaternary-active fault but does not find convincing evidence to support the existence of the Leuhman Fault (Dibblee, 1960; 1967) within the map area. Several more possible and probable faults are identified by a combination of geomorphic lineaments and brecciated rock. Pleistocene and Holocene eolian deposits are widespread, manifesting as sand sheets, dunes, and admixtures into alluvial fans. Also, an incised pediment forms much of the upland south of Leuhman Ridge. In general, field observations indicate that Quaternary alluvial and eolian deposits are thin; this suggests that secondary bedrock porosity and permeability, defined by degree of weathering and fracture density that includes fault-related fracturing, are more important factors in the location and flow patterns of groundwater.

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Sediment deposition, erosion, and bathymetric change in San Francisco Bay, California, 1971–1990 and 1999–2020

Bathymetric change analyses document historical patterns of sediment deposition and erosion, providing valuable insight into the sediment dynamics of coastal systems, including pathways of sediment and sediment-bound contaminants. In 2014 and 2015, the Office for Coastal Management, in partnership with the National Oceanic and Atmospheric Administration (NOAA) Office of Coastal Management, provided funding for new bathymetric surveys of large portions of San Francisco Bay. A total of 93 bathymetric surveys were conducted during this 2-year period, using a combination of interferometric sidescan and multibeam sonar systems. These data, along with recent NOAA, U.S. Geological Survey (USGS), U.S. Army Corps of Engineers, and private contractor surveys collected from 1999 to 2020 (hereinafter referred to as 2010s), were used to create the most comprehensive bathymetric digital elevation models (DEMs) of San Francisco Bay since the 1980s. Comparing DEMs created from these 2010s surveys with USGS DEMs created from NOAA’s 1971–1990 (hereinafter referred to as 1980s) surveys provides information on the quantities and patterns of erosion and deposition in San Francisco Bay during the 9 to 47 years between surveys. This analysis reveals that in the areas surveyed in both the 1980s and 2010s, the bay floor lost about 34 million cubic meters of sediment since the 1980s. Results from this study can be used to assess how San Francisco Bay has responded to changes in the system, such as sea-level rise and variation in sediment supply from the Sacramento-San Joaquin Delta and local tributaries, and supports the creation of a new, system-wide sediment budget. This report provides data on the quantities and patterns of sediment volume change in San Francisco Bay for ecosystem managers that are pertinent to various sediment-related issues, including restoration of tidal marshes, exposure of legacy contaminated sediment, and strategies for the beneficial use of dredged sediment.

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Geochronologic and geochemical data from metasedimentary and associated rocks in the Lane Mountain area, San Bernardino County, California

Eugeoclinal metasedimentary and metavolcanic rocks in the Lane Mountain area, California, are considered part of the El Paso terrane, which is commonly thought to have been displaced several hundred kilometers (km) southeastward from its place of origin during late Paleozoic truncation of the North American continental margin. Uranium-lead dating of detrital zircons from this area was undertaken to limit the depositional ages of these nearly non-fossiliferous metamorphic rocks. Analysis of detrital zircons from 17 metasedimentary rock samples yielded a composite age distribution that ranges from Archean to Jurassic and has significant peaks at ~2,800 2,400 mega-annum (Ma), 2,100–1,600 Ma, and ~300–200 Ma. The Proterozoic and Archean ages indicate derivation from continental sources in ancestral North America, whereas the late Paleozoic and Mesozoic ages are interpreted as derived from a magmatic arc that began to develop along the continental margin in Permian to Triassic time. The 17 detrital zircon samples are from quartzitic and conglomeratic rocks of the Carbide, Williams Well, and Noble Well formations, which were informally named by T.H. McCulloh in 1960. The zircon data indicate that the oldest rocks in the Carbide formation are quartzites likely correlative with the Ordovician Eureka Quartzite of the Cordilleran miogeocline. These rocks lie structurally above the rest of the Carbide formation, different units of which yielded zircons that indicate maximum depositional ages ranging from middle Paleozoic to Late Triassic. Zircons from the Williams Well and Noble Well formations indicate maximum depositional ages of late Paleozoic and Early Jurassic, respectively. The Noble Well formation is interpreted to correlate with the lithologically similar, Early Jurassic, Fairview Valley Formation of the Black and Quartzite Mountain areas some 60 km to the southwest. The above interpretations depend on the presumption that the detrital zircons in these samples did not undergo extreme, postdepositional lead loss, which would result in misleadingly young ages. Although such lead loss is considered unlikely for these samples, further work could test the validity of this interpretation. Zircons from six additional samples were also analyzed: (1) a quartzite from which all the zircons are interpreted to have formed by Late Jurassic metamorphism; (2) three samples interpreted as albitized igneous rocks of Middle Permian age; and (3) two samples interpreted as fine-grained monzonite to diorite of Late Jurassic age. Both sets of igneous rocks were initially thought to be metasedimentary but were reinterpreted as igneous largely on the basis of the zircon data. Based on the interpretations presented here, this study demonstrates that the depositional, magmatic, and deformational history of the El Paso terrane was longer and more complex than previously thought and will require reevaluation of existing tectonic models involving this terrane.

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