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Assessment of potential for natural attenuation of chlorinated ethenes and ethanes in ground water at a petrochemical reclamation site, Harris County, Texas

Redox conditions in the Numerous Sand Channels Zone beneath a petrochemical reclamation site in Harris County, Texas, range from sulfate reducing to methanogenic as indicated by the presence of methane in ground water and the range of molecular hydrogen concentrations. Assessment of the potential for reductive dechlorination using BIOCHLOR as a screening tool indicated conditions favoring anaerobic degradation of chlorinated organic compounds in the Numerous Sand Channels Zone. Evidence supporting reductive dechlorination includes apparently biogenic cis -1,2-dichloroethene; an increased ratio of 1,2-dichloroethane to 1,1,2-trichloroethane downgradient from the assumed contaminant source area; ethene and methane concentrations greater than background concentrations within the area of the contaminant plume; and a positive correlation of the ratio of ethene to vinyl chloride as a function of methane concentrations. The body of evidence presented in this report argues for hydrogenolysis of trichloroethene to cis -1,2-dichloroethene; of 1,1,2-trichloroethane to 1,2-dichloroethane; and of vinyl chloride to ethene within the Numerous Sand Channels Zone. Simulations using BIOCHLOR yielded apparent first-order decay constants for reductive dechlorination in the sequence tetrachloroethene trichloroethene cis -1,2-dichloroethene vinyl chloride ethene within the range of literature values reported for each compound and apparent first-order decay constants for reductive dechlorination in the sequence 1,1,2-trichloroethane 1,2-dichloroethane slightly greater than literature values reported for each compound along the upgradient segment of a simulated ground-water flowpath. Except for vinyl chloride, apparent rates of reductive dechlorination for all simulated species show a marked decrease along the downgradient segment of the simulated ground-water flowpath. Evidence for reductive dechlorination of chlorinated ethenes within the Numerous Sand Channels Zone indicates potential for natural attenuation of chlorinated ethenes. Reductive dechlorination of chlorinated ethanes apparently occurs to a lesser extent, indicating relatively less potential for natural attenuation of chlorinated ethanes. Additional data are needed on the concentrations and distribution of chlorinated ethenes and ethanes in individual fine sand intervals of the Numerous Sand Channels Zone. This information, combined with lower minimum reporting levels for future chloroethane analyses, might enable a more complete and quantitative assessment of the potential for natural attenuation at the site.

Texas

Stormflow chemistry in the Santa Ana River below Prado Dam and at the diversion downstream from Imperial Highway, southern California, 1995-98

The Santa Ana River drains about 2,670 square miles of the densely populated coastal area of southern California, near Los Angeles. Almost all the flow in the river, more than 200,000 acre-feet annually, is diverted into ponds where it infiltrates and recharges underlying aquifers. About 2 million people are dependent on these aquifers for water supply. Stormflow in the Santa Ana River is considered a source of "high-quality" water suitable for use as a source of ground-water recharge. To test this assumption, stormflow samples were collected at two locations--below Prado Dam and at the diversion point downstream from Imperial Highway--for 12 winter storms between 1995 and 1998. Nitrate concentrations decreased during stormflow from a median concentration of 7.8 milligrams per liter in base flow to concentrations less than 1 milligram per liter in some large storms. Concentrations of chemically reduced forms of nitrogen (nitrite, ammonia, and organic nitrogen) increased during stormflow and are the predominant forms of nitrogen in large stormflows. Dissolved organic carbon (DOC) concentrations increased from a median concentration of 4.6 milligrams per liter in base flow to more than 20 milligrams per liter in some stormflows. Concentrations of DOC were especially high during the first storm of the rainy season, and large increases in DOC concentrations were measured even as a result of small early season storms that did not cause large increases in streamflow. DOC present during early season stormflow had less ultraviolet absorbance at 254 nanometers (UV 254 ) per unit of carbon than did DOC from late season stormflows. DOC in water held in storage behind Prado Dam had the highest UV 254 absorbance per unit of carbon. Maximum pesticide concentrations in stormflow did not exceed U.S. Environmental Protection Agency Maximum Contaminant Levels. Most pesticide concentrations were less than 1 microgram per liter and less than the detection limits obtained using standard drinking water analyses. Increases in concentrations of pesticides such as diazinon, malathion, and chlorpyrifos in stormflow result from runoff from urban areas downstream from Prado Dam. In general, large late season stormflows have the most pesticide detections of all stormflows sampled. Concentrations of methyl tert-butyl ether (MTBE), a gasoline additive, during base flow were as high as 0.9 microgram per liter and concentrations decreased during stormflow. Like pesticides, the concentrations did not exceed the U.S. Environmental Protection Agency Maximum Contaminant Levels for MTBE.

California

Regional evaluation of evapotranspiration in the Everglades

Nine sites in the Florida Everglades were selected and instrumented for collection of data necessary for evapotranspiration-determination using the Bowen-ratio energy-budget method. The sites were selected to represent the sawgrass or cattail marshes, wet prairie, and open-water areas that constitute most of the natural Everglades system. At each site, measurements necessary for evapotranspiration (ET) calculation and modeling were automatically made and stored on-site at 15- or 30-minute intervals. Data collected included air temperature and humidity at two heights, wind speed and direction, incoming solar radiation, net solar radiation, water level and temperature, soil moisture content, soil temperature, soil heat flux, and rainfall. Data summarized in this report were collected from January 1996 through December 1997, and the development of site-specific and regional models of ET for this period is described. Latent heat flux is the energy flux density equivalent of the ET rate. Modified Priestley-Taylor models of latent heat flux as a function of selected independent variables were developed at each site. These models were used to fill in periods of missing latent heat flux measurement, and to develop regional models of the entire Everglades region. The regional models may be used to estimate ET in wet prairie, sawgrass or cattail marsh, and open-water portions of the natural Everglades system. The models are not applicable to forested areas or to the brackish areas adjacent to Florida Bay. Two types of regional models were developed. One type of model uses measurements of available energy at a site, together with incoming solar energy and water depth, to estimate hourly ET. This available-energy model requires site data for net radiation, water heat storage, and soil heat flux, as well as data for incoming solar radiation and water depth. The other type of model requires only incoming solar energy, air temperature, and water depth data to provide estimates of hourly ET. The second model thus uses data that are more readily available than the data required for the available-energy model. Computed ET mean annual totals for all nine sites for the 1996-97 period ranged from 42.4 inches per year at a site where the water level is below land surface for several months each year to 57.4 inches per year at an open-water site with no emergent vegetation. Although the density of photosynthetically-active plant leaves has been shown to relate directly to ET in some studies, it does not appear to relate directly to ET in the Everglades, based on comparison of annual ET data with leaf-area index, defined as the Normalized Difference Vegetation Index (NDVI), data from satellite imagery. NDVI and ET appear to be inversely related in the Everglades. The greatest ET rates occurred at open-water sites where the NDVI data indicated the lowest leaf-area index. Among the remaining vegetated sites, there is no clear relation between ET and NDVI, though the highest ET rate corresponded to the lowest NDVI and one of the lowest ET rates corresponded to the highest NDVI value. The variation in ET follows a seasonal pattern, with lowest monthly ET totals occurring in December through February, and highest ET occurring in May through August. The greatest range in monthly ET among all nine sites for the 2-year period occurred at site 3: from 1.81 inches in December 1997 to 6.84 inches in July 1996. A study to compare the Bowen-ratio/energy balance method of ET measurement with the eddy-correlation method was done at one site from June 22, 1998, through September 28, 1998. This comparison indicated that both methods gave comparable values of the Bowen ratio, but there was a considerable difference in available energy measured by the two methods. The mean of all 30-minute measured turbulent heat fluxes from the eddy-correlation apparatus for June 22 through September 29, 1998, was 137.4 watts per square meter, and the mean of the corresponding measured energy was 163.6 watts per square meter, or about 20 percent greater. The disagreement in mean energy fluxes measured by the two methods is problematical and is not fully understood. Although the difference seems to be related to friction velocity, and is practically non-existent at values of friction velocity greater than 0.3 meter per second, the "correctness" of either method cannot be determined with the data available.

Florida

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October 1998 (43.5 centimeters total for both months) resulted in an increase in water levels in all wells in October 1998. This was followed by unusually low amounts of rainfall during November 1998 through May 1999, when rainfall was 40.7 centimeters below 30-year mean monthly values. The presence of karst features (sinkholes, springs, solution conduits) and the highly permeable sands that overlie the Upper Floridan aquifer provide for rapid movement of water containing elevated nitrate concentrations to the aquifer. Nitrate was the dominant form of nitrogen in ground water collected at all sites and nitrate concentrations ranged from less than 0.02 to 22 milligrams per liter (mg/L), as nitrogen. Water samples from most wells showed substantial monthly or seasonal fluctuations in nitrate concentrations. Generally, water samples from wells with nitrate concentrations higher than 10 mg/L showed the greatest amount of monthly fluctuation. For example, water samples from six of eight wells had monthly nitrate concentrations that varied by at least 5 mg/L during the study period. Water from most wells with lower nitrate concentrations (less than 6 mg/L) also showed large monthly fluctuations. For instance, nitrate concentrations in water from four sites showed monthly variations of more than 50 percent. Large fluctuations in nitrate concentrations likely result from seasonal agricultural practices (fertilizer application and animal waste spreading) at a particular site. For example, an increase in nitrate concentrations observed in water samples from seven sites in February or March 1999 most likely results from application of synthetic fertilizers during the late winter months. Lower nitrate concentrations were detected in water samples from five of eight wells sampled during high-flow conditions for the Suwannee River in March 1998 compared to low-flow conditions in November 1998. Evidence for reduction of nitrate due to denitrification reactions was observed at one site (AC-1), as indicated by elevated concentrations of nitrogen gas and a corresponding increase in nitrogen isotope (d15N-NO3) values with a decrease in nitrate concentrations. Denitrification is unlikely at other sites based on the presence of dissolved oxygen concentrations greater than 2 mg/L in ground water and no observed trend between nitrate concentrations and values d15N-NO3 values. Nitrate was the dominant nitrogen species in most monthly rainfall samples; however, ammonium concentrations were similar or greater than nitrate during November and December 1998. During February through May 1999, both nitrate and ammonium concentrations were substantially higher in monthly rainfall samples collected at the study area compared to mean monthly concentrations at the Bradford Forest site located east of the study area, which is part of the National Atmospheric Deposition Program/National Trends Network. Also, higher nitrogen deposition rates in the study area compared to those at Bradford Forest could indicate that substantial amounts of ammonia are volatilized from fertilizers and animal wastes, released to the atmosphere, and incorporated as nitrate and ammonium in rainfall deposited in the middle Suwannee River Basin. Ground-water samples from most sites had d15N-NO3 values that indicated a mixture of inorganic and organic sources of nitrogen, which corresponded to multiple land uses where both synthetic fertilizers and manure are used on fields near these sites. Distinct d15N-NO3 signatures, however, were observed at some sites. For example, water samples from areas of row-crop farming as the dominant land use had d15N-NO3 values less than 4 per mil, indicating an inorganic nitrogen source such as synthetic fertilizer. In contrast, d15N-NO3 values greater than 9 per mil were found in water samples from three sites where manure from dairy and or poultry operations is spread on fields throughout the year.

Florida

Shoals and valley plugs in the Hatchie River watershed

Agricultural land use and gully erosion have historically contributed more sediment to the streams of the Hatchie River watershed than those streams can carry. In 1970, the main sedimentation problem in the watershed occurred in the tributary flood plains. This problem motivated channelization projects (U.S. Department of Agriculture, 1970). By the mid-1980's, concern had shifted to sedimentation in the Hatchie River itself where channelized tributaries were understood to contribute much of the sediment. The Soil Conservation Service [Natural Resources Conservation Service (NRCS) since 1996] estimated that 640,000 tons of bedload (sand) accumulates in the Hatchie River each year and identified roughly the eastern two-thirds of the watershed, where loess is thin or absent, as the main source of sand (U.S. Department of Agriculture, 1986a). The U.S. Geological Survey (USGS), in cooperation with the West Tennessee River Basin Authority (WTRBA), conducted a study of sediment accumulation in the Hatchie River and its tributaries. This report identifies the types of tributaries and evaluates sediment, shoal formation, and valley-plug problems. The results presented here may contribute to a better understanding of similar problems in West Tennessee and the rest of the southeastern coastal plain. This information also will help the WTRBA manage sedimentation and erosion problems in the Hatchie River watershed. The source of the Mississippi section of the Hatchie River is in the sand hills southwest of Corinth, Mississippi (fig. 1). This section of the Hatchie River flows northward in an artificial drainage canal, gathering water from tributary streams that also are channelized. The drainage canal ends 2 miles south of the Tennessee State line. The Tennessee section of the Hatchie River winds north and west in a meandering natural channel to the Mississippi River. Although most of the Hatchie River tributaries are also drainage canals, the river's main stem has kept most of its natural character. The Hatchie River flows through a wide valley bottom occupied mostly by riverine wetland. Historically, the valley bottom has supported hardwood forests. Since publication of the first Hatchie River report (U.S. Department of Agriculture, 1970), the channel of the river has become shallower, and flooding has increased (U.S. Department of Agriculture 1986b). These wetter conditions inhibit growth of hardwoods and lead to premature hardwood mortality. The NRCS has predicted that despite efforts to control erosion in the uplands, most of the valley-bottom forest will die. '...swamping may be so prevalent as to change most of the Hatchie River Basin flood plain into a marsh condition, with the only remnants of the present bottomland hardwood timber remaining. (U.S. Department of Agriculture, 1986b). Loss of channel depth has been concentrated in short reaches near tributary mouths. At the mouths of Richland, Porters, Clover, and Muddy Creeks, navigation has become difficult for recreational users (Johnny Carlin, West Tennessee River Basin Authority, oral commun., 1998). As the low-gradient alluvial system of the Hatchie River accumulates sediment, another common outcome has been the formation of valley plugs, areas where 'channels are filled with sediment, and all the additional bedload brought downstream is then spread out over the flood plain until a new channel has been formed' (Happ, 1975). Valley plugs typically form where the slope of a sand-laden tributary decreases downstream, or where the tributary joins its parent stream (Happ and others, 1940; Diehl, 1994, 1997; Smith and Diehl, 2000).

Mississippi, Tennessee

Water quality of selected springs and public-supply wells, Pine Ridge Indian Reservation, South Dakota, 1992-97

This report presents results of a water-quality study for the Pine Ridge Indian Reservation, South Dakota. The study was a cooperative effort between the U.S. Geological Survey and the Water Resources Department of the Oglala Sioux Tribe. Discharge and water-quality data were collected during 1992-97 for 14 contact springs located in the northwestern part of the Reservation. Data were collected to evaluate potential alternative sources of water supply for the village of Red Shirt, which currently obtains water of marginal quality from a well completed in the Inyan Kara aquifer. During 1995-97, water-quality data also were collected for 44 public-supply wells that serve about one-half of the Reservation's population. Quality-assurance sampling was used to evaluate the precision and accuracy of environmental samples. Ten of the springs sampled contact the White River Group, and four contact the Pierre Shale. Springs contacting the White River Group range from calcium bicarbonate to sodium bicarbonate water types. Two springs contacting the Pierre Shale have water types similar to this; however, sulfate is the dominant anion for the other two springs. In general, springs contacting the White River Group are shown to have better potential as alternative sources of water supply for the village of Red Shirt than springs contacting the Pierre Shale. Nine of the springs with better water quality were sampled repeatedly; however, only minor variability in water quality was identified. Six of these nine springs, of which five contact the White River Group, probably have the best potential for use as water supplies. Discharge from any of these six springs probably would provide adequate water supply for Red Shirt during most periods, based on a limited number of discharge measurements collected. Concentrations of lead exceeded the U.S. Environmental Protection Agency (USEPA) action level of 15 µg/L for three of these six springs. Five of these six springs also had arsenic concentrations that exceeded 10 µg/L, which could be problematic if the current maximum contaminant level (MCL) is lowered. Blending of water from one or more springs with water from the existing Inyan Kara well may be an option to address concerns regarding both quantity and quality of existing and potential sources. All nine springs that were sampled for indicator bacteria had positive detections on one or more occasions during presumptive tests. Although USEPA standards for bacteria apply only to public-water supplies, local residents using spring water for domestic purposes need to be aware of the potential health risks associated with consuming untreated water. One spring contacting the White River Group and two springs contacting the Pierre Shale exceeded 15 pCi/L for gross alpha; these values do not necessarily constitute exceedances of the MCL, which excludes radioactivity contributed by uranium and radon. Additional sampling using different analysis techniques would be needed to conclusively determine if any samples exceeded this MCL. Nine springs were sampled for selected pesticides and tritium. The pesticides atrazine, carbaryl, and 2,4-D were not detected in any of the samples. The nine springs were analyzed for tritium in order to generally assess the age of the water and to determine if concentrations exceeded the MCL established for gross beta-particle activity. Tritium results indicated two springs are composed primarily of water recharged prior to atmospheric testing of nuclear bombs and two other springs have a relatively large percentage of test-era water. The remaining five springs had tritium values that indicated some percentage of test-era water; however, additional sampling would be needed to determine whether water is predominantly pre- or post-bomb age. Of the 44 public-supply wells sampled, 42 are completed in the Arikaree aquifer, one is completed in an alluvial aquifer, and one is completed in the Inyan Kara aquifer. Water from the alluvial well is a sodium bicarbonate water type, water from Arikaree aquifer ranges from calcium bicarbonate to sodium bicarbonate types, and water from the Inyan Kara well is a calcium sulfate bicarbonate type. Of the 44 wells sampled, 28 (64 percent) tested positive for indicator bacteria in presumptive tests. Because these were single samples that generally were collected upstream from chemical treatment feeders, positive detections do not necessarily constitute exceedances of drinking-water standards. A single sample from an Arikaree well exceeded the MCL for arsenic of 50 µg/L. Arsenic exceeded 10 µg/L for six additional Arikaree wells and for the alluvial well and the Inyan Kara well, which could be problematic if the current MCL is lowered. The alluvial well also exceeded the secondary maximum contaminant level (SMCL) for dissolved solids, which is non-enforceable, and the action level for lead. The Inyan Kara well exceeded the SMCL's for iron and for manganese and the MCL of 5 pCi/L for radium-226 and 228 combined. Several Arikaree wells exceeded SMCL's for either pH, sulfate, dissolved solids, iron, or manganese. One Arikaree well exceeded the MCL of 4.0 mg/L for fluoride and another exceeded the MCL of 10 mg/L for nitrite plus nitrate. Ten Arikaree wells equalled or exceeded 15 pCi/L for gross alpha; however, these values do not necessarily constitute exceedances of the MCL, which excludes radioactivity contributed by uranium and radon. Additional sampling using different analysis techniques would be needed to conclusively determine if any samples exceeded this MCL. Eight wells, all from the Arikaree aquifer, equalled or exceeded the proposed MCL of 20 µg/L for uranium and 33 wells (75 percent) equalled or exceeded one-half of the proposed MCL. Although this standard has only been proposed, additional information regarding the extent of elevated uranium concentrations in the Arikaree aquifer, and the geochemical processes involved, may be beneficial. It was determined from analyses of uranium isotope data for five wells that the source of elevated uranium concentrations is naturally occurring, rather than anthropogenic.

South Dakota

Hydrology and water and sediment quality at James Campbell National Wildlife Refuge near Kahuku, Island of Oahu, Hawaii

The James Campbell National Wildlife Refuge occupies two lowland marsh and pond complexes on the northern coastal plain of Oahu: the mostly natural ponds and wetlands of the Punamano Unit and the constructed ponds of the Kii Unit. The U.S. Fish and Wildlife Service manages the Refuge primarily to protect and enhance habitat for four endangered species of Hawaiian waterbirds. Kii Unit is fed by artesian wells and rainfall, whereas Punamano Unit is fed naturally by rainfall, runoff, and ground-water seepage. Streams drain from the uplands into lowland ditches that pass through Kii Unit on their way to the ocean. A high-capacity pump transfers water from the inner ditch terminus at Kii to the ocean outlet channel. Stormwaters also exit the inner ditch system over flood-relief swales near the outlet pump and through a culvert with a one-way valve. A hydrologic investigation was done from November 1996 through February 1998 to identify and quantify principal inflows and outflows of water to and from the Refuge, identify hydraulic factors affecting flooding, document ground-water/surface-water interactions, determine the adequacy of the current freshwater supply, and determine water and sediment quality. These goals were accomplished by installing and operating a network of stream-gaging stations, meteorology stations, and shallow ground-water piezometers, by computing water budgets for the two Refuge units, and by sampling and analyzing water and pond-bottom sediments for major ions, trace metals, and organic compounds. Streamflow during the study was dominated by winter stormflows, followed by a gradual recession of flow into summer 1997, as water that had been stored in alluvial fans drained to lowland ditches. Outflow at the ditch terminus in 1997 was 125 million gallons greater than measured inflow to the coastal plain, mainly reflecting gains from ground water along the ditches between outlying gages and the ditch terminus. Of the measured 1997 outflow, 98 percent was through the Kii outlet pump, with the outlet culvert valve only opening for brief periods during storms. Large volumes of stormflow overflowed the flood-relief swales unmeasured. The largest storm of the study, in November 1996, was estimated to have a flood frequency of about 3 to 4 years. Streamflow exceeded culvert capacity and overtopped Kamehameha Highway at Kalaeokahipa Stream and Hospital ditch. Slight overbank flooding in Kii ditch resulted strictly from high discharge. Minor overbank flooding farther out on the coastal plain probably was caused mainly by the small hydraulic gradients available to convey stormflows along the lowland ditches. Stormwaters flooded Kii ponds and flowed back upstream along Punamano ditch into Punamano marsh, introducing suspended sediment and possibly other contaminants to the Refuge. Two smaller storms in January 1997 resulted in smaller flows and no overbank flooding. The Kii outlet pump ran continuously for 7 days during the November 1996 storm and for 1 to 2 days during the January 1997 storms. During all three storms, the outlet culvert valve opened and the inner ditches overtopped the flood-relief swales, allowing free outflow of water from the inner ditch. Backwater effects hindered drainage during the January 1997 storms at Hospital ditch at Kamehameha Highway, and at Punamano ditch at Nudist Camp Road (where the backflow into Punamano marsh in November 1996 constituted an extreme backwater effect). A probable marine backwater effect was imposed at the ocean outlet ditch during the November 1996 storm through a combination of high spring tides and wave setup from large surf. Whether this backwater effect propagated upstream in the ditches to affect inland sites could not be determined conclusively. A sand plug may have built up in the ocean outlet channel before the November 1996 storm, but if so, it probably washed out prior to, or early in the storm, and was not present at the time of peak stage at inland sites. A season-long buildup of the sand plug in late 1997 was inferred from rising water levels in the outlet ditch. Seawater flows up the outlet channel or over the sand berm and into the outer ditch system on most high tides, and particularly during spring high tides. Ponds and ditches of the Refuge and surrounding lowlands have mud- and clay-lined bottoms that form an effective confining unit and inhibit interaction with an underlying shallow limestone aquifer. At Kii Unit, pond levels are higher than adjacent ditch levels and underlying ground-water levels, establishing lateral and downward head gradients that could foster seepage losses from the ponds. Regional ground-water discharge from the Koolau aquifer to the coastal-plain sediments is mostly diffuse, but is concentrated where ridges of Koolau Basalt plunge beneath coastal-plain sediments near Punamano Unit and at the head of Hospital ditch. Kii ditch gains brackish ground water downstream of Kamehameha Highway. Wastewater disposal from the sewage treatment plant adjoining Kii Unit poses little or no threat to Refuge habitat. Disposal is at six injection wells located 0.45 mi away at Kahuku, and the wells inject into confined limestone aquifers that do not extend to Kii Unit. The natural freshwater supply to Punamano Unit is adequate for maintaining the wildlife habitat, judging from stable pond levels and low salinities there. A monthly water budget for Punamano showed an apparent annual deficit in measurable flows in 1997, requiring unmeasured ground-water gains equalling 51 inches of water. The freshwater supply to Kii Unit is inadequate according to Refuge managers, because there is not enough water to manipulate levels adequately in the ponds during most of the year, and particularly during the driest months. This is confirmed by monthly deficits in the water budget for the Kii ponds during summer months. However, the Kii budget showed an annual surplus in measurable flows for 1997 equalling 24 inches of water. Unmeasured losses are required to explain the apparent annual surplus, such as discharge to the ditches through pond water-control structures and downward and/or lateral ground-water seepage. The apparent surplus at Kii is strictly hydrologic and is not a surplus in a management sense; it cannot be stored or used to supply the Refuge, but instead reflects losses from the system that render this amount of water unavailable for use. The budget year, 1997, was drier than normal (24 percent below long-term mean rainfall) and so the measured potential evaporation for 1997 was probably higher than the long-term mean. Few metals or organic compounds of potential concern were detected in pond and ditch waters and in pond-bottom sediments. Detected pesticides were at trace levels or just above minimum reporting limits. Exceptions that exceeded quality guidelines for freshwater sediment were copper and zinc in sediment from Kii ponds C and D, and copper in sediment from Punamano north pond. Therefore, urban and agricultural runoff probably have contributed little in the way of harmful metals or organic compounds to the Refuge, although the potential for such contribution remains from periodic flooding of the ponds by ditch stormflows. Salinity was low throughout most Refuge waters, qualifying as fresh to slightly brackish and suitable for the environmental needs of Refuge fauna. Higher salinities have been observed in ditches during past periods of sugarcane cultivation and saltwater aquaculture, however. Resumption of saltwater aquaculture could raise ditch salinities if saltwater effluents are disposed directly into the ditches, as they were in the past.

Hawaii

Water quality of the Quaternary and Ada-Vamoosa aquifers on the Osage Reservation, Osage County, Oklahoma, 1997

The project was to provide information on the quality of ground water from rural-domestic-water wells within the Osage Reservation and compare the water-quality to proximity to oil wells. About 38,500 oil wells have been drilled in the Reservation since drilling began in 1896. About 1,480 square miles or 64 percent of the Reservation is within a quarter mile of an oil well. The unconfined Quaternary sand aquifer covers about 315 square miles or about 14 percent of the Reservation and the confined Ada-Vamoosa sandstone aquifer covers about 800 square miles or about 35 percent of the Reservation. Fifty-eight percent of the Quaternary aquifer and 69 percent of the outcrop area of the Ada-Vamoosa aquifer are within a quarter mile of an oil well. One hundred twenty domestic ground-water wells were sampled from the Quaternary and Ada-Vamoosa aquifers. Forty-nine percent of the Reservation is underlain by the aquifers. Ground-water quality is good on most of the Reservation, but the use of domestic-water-supply wells tend to minimize water-quality problems. Existing water-supply wells commonly are located in areas that produce usable volumes of potable water. Several constituents in samples from the Ada-Vamoosa aquifer within a quarter mile of an oil well were significantly greater than from the aquifer not near oil wells. The constituents include specific conductance, dissolved solids, sodium, sulfate, chloride, bromide, and silica. These ions are probably derived from brine water. In the Ada-Vamoosa aquifer subgroups, 57 percent of the samples near oil wells and 24 percent of the samples not near oil wells had dissolved-solids concentrations greater than 500 milligrams per liter. The water quality in the Quaternary and Ada-Vamoosa aquifers is similar in areas where no oil wells have been drilled but is significantly different for several constituents. Median concentrations of major constituents from the Ada-Vamoosa aquifer not near oil wells were less than or equal to values from the Quaternary aquifer. Sixty-four percent of the water-quality samples from the Quaternary and 51 percent from the Ada-Vamoosa aquifers have dissolved-solids concentrations less than the secondary drinking water regulations of 500 milligrams per liter. Fifty-nine percent of the aquifer samples in the Quaternary aquifer subgroups not near oil wells and 70 percent of the samples near oil wells had dissolved solids less than 500 milligrams per liter. Areas in the Ada-Vamoosa aquifer near Hominy, Pershing, and Hula Lake have dissolved-solids concentrations greater than the secondary drinking water regulations. Water-quality samples from the Quaternary aquifer in these areas also have dissolved-solids concentrations greater than 500 milligrams per liter.

Oklahoma

Biodegradation of chlorinated ethenes at a karst site in middle Tennessee

This report presents results of field and laboratory investigations examining the biodegradation of chlorinated ethenes in a karst aquifer contaminated with trichloroethylene (TCE). The study site, located in Middle Tennessee, was selected because of the presence of TCE degradation byproducts in the karst aquifer and available site hydrologic and chlorinated-ethene information. Additional chemical, biological, and hydrologic data were gathered to evaluate whether the occurrence of TCE degradation byproducts in the karst aquifer was the result of biodegradation within the aquifer or simply transport into the aquifer. Geochemical analysis established that sulfate-reducing conditions, essential for reductive dechlorination of chlorinated solvents, existed in parts of the contaminated karst aquifer. Other areas of the aquifer fluctuated between anaerobic and aerobic conditions and contained compounds associated with cometabolism, such as ethane, methane, ammonia, and dissolved oxygen. A large, diverse bacteria population inhabits the contaminated aquifer. Bacteria known to biodegrade TCE and other chlorinated solvents, such as sulfate-reducers, methanotrophs, and ammonia-oxidizers, were identified from karst-aquifer water using the RNA-hybridization technique. Results from microcosms using raw karst-aquifer water found that aerobic cometabolism and anaerobic reductive-dechlorination degradation processes were possible when appropriate conditions were established in the microcosms. These chemical and biological results provide circumstantial evidence that several biodegradation processes are active in the aquifer. Additional site hydrologic information was developed to determine if appropriate conditions persist long enough in the karst aquifer for these biodegradation processes to be significant. Continuous monitoring devices placed in four wells during the spring of 1998 indicated that pH, specific conductance, dissolved oxygen, and oxidation-reduction potentials changed very little in areas isolated from active ground-water flow paths. These stable areas in the karst aquifer had geochemical conditions and bacteria conducive to reductive dechlorination of chlorinated ethenes. Other areas of the karst aquifer were associated with active ground-water flow paths and fluctuated between anaerobic and aerobic conditions in response to rain events. Associated with this dynamic environment were bacteria and geochemical conditions conducive to cometabolism. In summary, multiple lines of evidence developed from chemical, biological, and hydrologic data demonstrate that a variety of biodegradation processes are active in this karst aquifer.

Tennessee

Method for estimating water use and interbasin transfers of freshwater and wastewater in an urbanized basin

Techniques for management of drainage basins that use water budgets to balance available water resources with actual or anticipated water use require accurate and precise estimates of basin withdrawals, interbasin transfers of freshwater, unaccounted-for use, water use, consumptive use, inflow and infiltration, basin return flow, and interbasin transfers of wastewater. Frequently, interbasin transfers of freshwater and wastewater are not included in basin water budgets because they occur within public water-delivery and wastewater-collection systems. A new 10-step method was developed to improve estimates of inflow and infiltration and interbasin transfers using readily available statewide data. The accuracy and precision of water-use estimates determined by this method are improved through careful application of coefficients for small users and the use of metered values for large users. The method was developed and tested with data for the Ten Mile River Basin in southeastern Massachusetts. This report uses examples from the basin to illustrate each step of the method.

Massachusetts

The mineral economy of Brazil--Economia mineral do Brasil

This study depicts the Brazilian government structure, mineral legislation and investment policy, taxation, foreign investment policies, environmental laws and regulations, and conditions in which the mineral industry operates. The report underlines Brazil's large and diversified mineral endowment. A total of 37 mineral commodities, or groups of closely related commodities, is discussed. An overview of the geologic setting of the major mineral deposits is presented. This report is presented in English and Portuguese in pdf format.

Data Series

The effects of the Chesapeake Bay impact crater on the geological framework and correlation of hydrogeologic units of the lower York-James Peninsula, Virginia

This report documents the highly variable structure, stratigraphy, and buried topography of the outer rim of the Chesapeake Bay impact crater created by its impact and burial. Lithologies of cores are correlated with borehole geophysical logs to characterize the physical properties of the stratigraphic units and their geophysical signatures. The correlation between cores, well cuttings, and borehole geophysical logs is augmented with seismic-reflection data, and these data are compiled into a lithostratigraphic cross section that illustrates the geological framework of the lower York-James Peninsula and immediate surrounding areas.

Virginia

Simulation of the effects of development of the ground-water flow system of Long Island, New York

Extensive development on Long Island since the late 19th century and projections of increased urbanization and ground-water use makes effective water-resource management essential for preservation of the island's hydrologic environment and maintenance of a reliable source of water supply. This report presents results of a ground-water flow simulation analysis of the effects of development on the Long Island ground-water system. It describes ground-water levels, stream-flow, and the ground-water budget for the predevelopment period (pre-1900), the 1960's drought, and a more recent (1968-83) period with significant hydrologic stress. The report also presents estimated effects of a proposed water-supply strategy for the year 2020. Long Island has three major aquifers-the upper glacial (water-table), the Magothy, and the Lloyd aquifers-that are separated to varying degrees by confining units. Before development, recharge from precipitation entered the ground-water system at a rate of more than 1.1 billion gallons per day. An equal amount discharged to streams (41 percent), the shore (52 percent), and subsea boundaries (7 percent) . Urbanization and withdrawal of more than 400 Mgal/d (million gallons per day) from wells have resulted in local effects that include declines in ground-water levels, drying up and burial of streams and wetlands, reduction of ground-water recharge by increased overland flow to the ocean, a general decrease in ground-water discharge, and salt water intrusion. In some areas, the reduction in recharge is mitigated by leakage from water-supply and wastewater disposal lines, and infiltration of storm water through recharge basins. During 1968-83, a net loss of 240 Mgal/d from the ground-water system caused a decrease in ground-water discharge to streams (135 Mgal/d), to the shore (82 Mgal/d), and to subsea boundaries (23Mgal/d).The greatest adverse effects have been in western Long Island, where the most severe development has occurred. This analysis shows stream base flow to be highly sensitive to water-table fluctuations, and long streams to be more sensitive than short ones. A water-supply scenario for the year 2020 was simulated that employs redistribution of pumping centers to mitigate extreme local effects . Although the net stress on the ground-water system was projected to increase 57 Mgal/d (24 percent) above that of 1968-83, redistribution of ground-water withdrawals across the island would allow recovery of cones of depression in western Long Island, thereby reducing the threat of salt water intrusion and increasing base flow of some streams . The increased stress would cause a net decrease in base flow island wide of 44 Mgal/d; total base flow would be 281 Mgal/d - 39 percent below predevelopment levels or 14 percent below 1968-83 levels. The most severe effects would be in Nassau and western Suffolk Counties.

New York

Streamflow, base flow, and ground-water recharge in the Housatonic River basin, western Massachusetts and parts of eastern New York and northwestern Connecticut

Streamflows for selected flow durations from 1 to 99 percent and the August median streamflows were estimated for 11 long-term streamflow-gaging stations in and near the study area. Estimates of streamflow and associated standard errors were determined for selected flow durations from 50 to 99 percent and the August median streamflows for 21 low-flow partial-record stations and for selected flow durations from 1 to 99 percent and the August median streamflows for two partial-record stations and seven short-term discontinued streamflow-gaging stations. Median streamflows per square mile for the 10-, 50-, and 90-percent flow durations and the August median streamflows were 3.90, 1.01, 0.185, and 0.248 cubic feet per second per square mile. Streamflows per square mile at selected flow-duration discharges between 1 and 99 percent at the 41 stations were related to basin characteristics to explain differences in streamflow characteristics. Basin characteristics included basin elevations, extent of stratified-drift deposits, land use, aspect, and underlying bedrock geology types. Most streamflow differences were positively correlated to basin elevation differences, most likely because precipitation increases with elevation, and to stratified-drift deposits, which allow more precipitation to recharge the ground water and to discharge later than do till and bedrock deposits. Mean base flow was computed from continuous records of daily mean discharge at 11 long-term streamflow-gaging stations in and near the study area. Mean annual base flow ranged from 13.4 to 24.5 inches per year. Minimum annual base flow ranged from 45 to 72 percent of mean annual rates at the 11 long-term stations, and the ratio of base flow to streamflow (base-flow index) ranged from 0.55 to 0.80. Base-flow durations between 1 and 99 percent were calculated from streamflow records at the 11 long-term streamflow-gaging stations. Base flow accounted for 45.5 to 85.0 percent of total annual streamflow at the 1- and 99-percent flow durations. Ground-water-recharge rates were computed from continuous records of daily mean discharge at 11 long-term streamflow-gaging stations in and near the study area. Mean annual ground-water-recharge rates ranged from 17.5 to 22.4 inches per year at 10 of the 11 long-term stations. Mean annual ground-water-recharge rates ranged from 2 to 7 inches per year higher than base flow. Minimum annual ground-water-recharge rates ranged from 48 to 72 percent of mean annual ground-water-recharge rates. Mean annual potential ground-water recharge was estimated from monthly climatological data collected at six climatological stations in and near the study area. Mean potential ground-water recharge ranged from about 17.9 to 28.9 inches per year, with a median value of 22.6 inches per year. This median value compares well to that calculated by use of streamflow records at the 11 streamflow-gaging stations (20.0 inches per year). Streamflows per square mile for the 10-, 50-, and 90-percent flow durations at stations in and near the study area were similar to those computed for other unregulated long-term continuous streamflow-gaging stations in central and eastern Massachusetts. Base-flow and ground-water-recharge rates in the study area compared closely to results from other studies in southeastern Massachusetts and Rhode Island, which were based on the same computational methods.

Connecticut, Massachusetts, New York

Water-quality assessment of the New England coastal basins in Maine, Massachusetts, New Hampshire, and Rhode Island: Environmental settings and implications for water quality and aquatic biota

The New England Coastal Basins in Maine, Massachusetts, New Hampshire, and Rhode Island constitute one of 59 study units selected for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. England Coastal Basins study unit encompasses the fresh surface waters and ground waters in a 23,000 square-mile area that drains to the Atlantic Ocean. Major basins include those of the Kennebec, Androscoggin, Saco, Merrimack, Charles, Blackstone, Taunton, and Pawcatuck Rivers. Defining the environmental setting of the study unit is the first step in designing and conducting a multi-disciplinary regional water-quality assessment. The report describes the natural and human factors that affect water quality in the basins and includes descriptions of the physiography, climate, geology, soils, surface- and ground-water hydrology, land use, and the aquatic ecosystem. Although surface-water quality has greatly improved over the past 30 years as a result of improved wastewater treatment at municipal and industrial wastewater facilities, a number of water-quality problems remain. Industrial and municipal wastewater discharges, combined sewer overflows, hydrologic modifications from dams and water diversions, and runoff from urban land use are the major causes of water-quality degradation in 1998. The most frequently detected contaminants in ground water in the study area are volatile organic compounds, petroleum-related products, nitrates, and chloride and sodium. Sources of these contaminants include leaking storage tanks, accidental spills, landfills, road salting, and septic systems and lagoons. Elevated concentrations of mercury are found in fish tissue from streams and lakes throughout the study area.

Maine, Massachusetts, New Hampshire, Rhode Island

Environmental setting and water-quality issues in the lower Tennessee River basin

The goals of the National Water-Quality Assessment Program are to describe current water-quality conditions for a large part of the Nation's water resources, identify water-quality changes over time, and identify the primary natural and human factors that affect water quality. The lower Tennessee River Basin is one of 59 river basins selected for study. The water-quality assessment of the lower Tennessee River Basin study unit began in 1997. The lower Tennessee River Basin study unit encompasses an area of about 19,500 square miles and extends from Chattanooga, Tennessee, to Paducah, Kentucky. The study unit had a population of about 1.5 million people in 1995. The study unit was subdivided into subunits with relatively homogeneous geology and physiography. Subdivision of the study unit creates a framework to assess the effects of natural and cultural settings on water quality. Nine subunits were delineated in the study unit; their boundaries generally coincide with level III and level IV ecoregion boundaries. The nine subunits are the Coastal Plain, Transition, Western Highland Rim, Outer Nashville Basin, Inner Nashville Basin, Eastern Highland Rim, Plateau Escarpment and Valleys, Cumberland Plateau, and Valley and Ridge.The lower Tennessee River Basin consists of predominantly forest (51 percent) and agricultural land (40 percent). Activities related to agricultural land use, therefore, are the primary cultural factors likely to have a widespread effect on surface- and ground-water quality in the study unit. Inputs of total nitrogen and phosphorus from agricultural activities in 1992 were about 161,000 and 37,900 tons, respectively. About 3.7 million pounds (active ingredient) of pesticides was applied to crops in the lower Tennessee River Basin in 1992. State water-quality agencies identified nutrient enrichment and pathogens as water-quality issues affecting both surface and ground water in the lower Tennessee River Basin. Water-quality data collected by State and Federal agencies between 1980 and 1996 were summarized to characterize surface- and ground-water quality of the subunits with respect to these issues. Median concentrations of nitrogen species generally were less than 1 milligram per liter in surface and ground water in all subunits, and were highest throughout the subunits that had the largest percentages of agricultural land use. Median phosphorus concentrations also were less than 1 milligram per liter in all subunits. Phosphatic limestones present in two subunits had a larger effect on phosphorus concentrations in surface and ground water than did the amount of agricultural land use in these subunits. Median counts of fecal coliform were higher in surface water than in ground water in all subunits. The highest median counts in surface water were in the Valley and Ridge (7,500 colonies per 100 milliliters) and the Outer Nashville Basin subunits (5,000 colonies per 100 milliliters). Highest median counts in ground water were in the Inner and Outer Nashville Basin subunit. Natural setting likely has an important effect with respect to fecal contamination of surface and ground water in the lower Tennessee River Basin.

Alabama, Georgia, Kentucky, Mississippi, Tennessee

Characterization and simulation of the quantity and quality of water in the Highland Lakes, Texas, 1983-92

The Highland Lakes, located in central Texas, are a series of seven reservoirs on the Colorado River (Lake Buchanan, Inks Lake, Lake Lyndon B. Johnson, Lake Marble Falls, Lake Travis, Lake Austin, and Town Lake). The reservoirs provide hydroelectric power for the area. In addition, Lake Austin and Town Lake also provide the public water supply for the Austin metropolitan area. Saline water released from Natural Dam Salt Lake during 1987–89 caused increased concern among water managers that high-salinity water entering the Highland Lakes could result in waterquality problems, necessitating additional treatment of the water. The maximum dissolved solids concentrations for the reservoirs after the saline inflow were about two to three times the average concentrations before the inflow. The maximum concentrations of chloride and sulfate after the inflow were about three to five times the average concentrations before the inflow. The concentrations of dissolved solids, chloride, and sulfate in Lake Buchanan, Inks Lake, Lake Lyndon B. Johnson, and Lake Marble Falls were less than the concentrations of the applicable water-quality standards by the end of 1990. Concentrations of these constituents in Lake Travis, Lake Austin, and Town Lake did not decrease to previous levels, which were less than the concentrations of the applicable waterquality standards, until the end of 1991. Constituent concentrations for Lake Buchanan and Inks Lake; for Lake Lyndon B. Johnson and Lake Marble Falls; and for Lake Travis, Lake Austin, and Town Lake were similar because of the relative storage capacities and location of tributary inflows. From the initial increase in constituent concentrations in Lake Buchanan (summer 1987) in response to the saline inflow, the high-salinity water passed through the entire Highland Lakes in about 3.5 years. A mathematical mass-balance model was used to simulate the input and movement of highsalinity water through the Highland Lakes and to estimate monthly mean concentrations of dissolved solids, chloride, and sulfate for wet, average, and dry hydrologic conditions. The simulated median monthly concentrations during the 10-year simulation period for each reservoir generally are larger for the average condition than for the wet condition and generally are larger for the dry condition than for the average condition. The simulated concentrations of dissolved solids, chloride, and sulfate decreased to levels less than the concentrations of the applicable water-quality standards in about 2 to 5 years after the saline water inflow of 1987–89 was simulated for the three hydrologic conditions. Results from the simulations indicate that saline inflows to the Highland Lakes similar to those of the releases from Natural Dam Salt Lake during 1987–89 are unlikely to cause large increases in future concentrations of dissolved solids, chloride, and sulfate in the Highland Lakes. The results also indicate that high-salinity water will continue to be diluted as it is transported downstream through the Highland Lakes, even during extended dry periods.

Texas
Compare source metadata on this page
WorkPublishedSource identifierSource
Assessment of potential for natural attenuation of chlorinated ethenes and ethanes in ground water at a petrochemical reclamation site, Harris County, Texas2000wri004121usgs
Stormflow chemistry in the Santa Ana River below Prado Dam and at the diversion downstream from Imperial Highway, southern California, 1995-982000wri004127usgs
Regional evaluation of evapotranspiration in the Everglades2000wri004217usgs
Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida2000wri004219usgs
Shoals and valley plugs in the Hatchie River watershed2000wri004279usgs
Water quality of selected springs and public-supply wells, Pine Ridge Indian Reservation, South Dakota, 1992-972000wri994063usgs
Hydrology and water and sediment quality at James Campbell National Wildlife Refuge near Kahuku, Island of Oahu, Hawaii2000wri994171usgs
Water quality of the Quaternary and Ada-Vamoosa aquifers on the Osage Reservation, Osage County, Oklahoma, 19972000wri994231usgs
Biodegradation of chlorinated ethenes at a karst site in middle Tennessee2000wri994285usgs
Method for estimating water use and interbasin transfers of freshwater and wastewater in an urbanized basin2000wri994287usgs
The mineral economy of Brazil--Economia mineral do Brasil1999ds53usgs
Digital geologic map of Loudoun County, Virginia1999ofr99150usgs
The effects of the Chesapeake Bay impact crater on the geological framework and correlation of hydrogeologic units of the lower York-James Peninsula, Virginia1999pp1612usgs
Simulation of the effects of development of the ground-water flow system of Long Island, New York1999wri984069usgs
Streamflow, base flow, and ground-water recharge in the Housatonic River basin, western Massachusetts and parts of eastern New York and northwestern Connecticut1999wri984232usgs
Water-quality assessment of the New England coastal basins in Maine, Massachusetts, New Hampshire, and Rhode Island: Environmental settings and implications for water quality and aquatic biota1999wri984249usgs
Environmental setting and water-quality issues in the lower Tennessee River basin1999wri994080usgs
Characterization and simulation of the quantity and quality of water in the Highland Lakes, Texas, 1983-921999wri994087usgs

These are bibliographic comparisons, not experimental rankings. Follow the original document for methods and conditions.