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USGS2016

Geology and undiscovered resource assessment of the potash-bearing Central Asia Salt Basin, Turkmenistan, Uzbekistan, Tajikistan, and Afghanistan: Chapter AA in Global mineral resource assessment

Undiscovered potash resources in the Central Asia Salt Basin (CASB) of Turkmenistan, Uzbekistan, Tajikistan, and Afghanistan were assessed as part of a global mineral resource assessment led by the U.S. Geological Survey. The term “potash” refers to potassium-bearing, water-soluble salts derived from evaporite basins, where seawater dried up and precipitated various salt compounds; the word for the element “potassium” is derived from potash. Potash is produced worldwide at amounts exceeding 30 million metric tons per year, mostly for use in fertilizers. The term “potash” is used by industry to refer to potassium chloride, as well as potassium in sulfate, nitrate, and oxide forms. For the purposes of this assessment, the term “potash” refers to potassium ores and minerals and potash ore grades. Resource and production values are usually expressed by industry in terms of K 2 O (potassium oxide) or muriate of potash (KCl, potassium chloride). The CASB hosts significant discovered potash resources and originated in an inland sea during Late Jurassic time. Seawater flowed into the CASB, mostly from its extreme northwestern margin near the modern Caspian Sea, during several evaporation episodes that deposited at least five different packages of evaporites, with virtually all potash in the second and fourth packages. In this study, the CASB was subdivided into three tracts (permissive areas) for evaluation: the Amu Darya tract in the west, the Gissar tract in the center, and the Afghan-Tajik tract in the east. The Gissar and Amu Darya tracts were quantitatively assessed, whereas the Afghan‑Tajik tract was only qualitatively assessed because of the commonly extreme depth (as deep as 7 km) of the Jurassic salt, extensive deformation, and a lack of known potash deposits. Two approaches were used to estimate amounts of undiscovered potash in the CASB. Stratabound evaporite deposits in the Amu Darya tract were evaluated using an Adaptive Geometric Estimation (AGE) approach, which estimates in-place potash volumes and tonnages. The Gissar tract was evaluated by using the AGE approach for stratabound deposits and the three-part form of assessment of Singer and Menzie (2005) for discrete halokinetic deposits. In the three-part form of assessment, numbers of undiscovered deposits were estimated and combined with grade and tonnage models to probabilistically forecast the amount of undiscovered potash. The Amu Darya tract is estimated to contain 38 billion metric tons of undiscovered potash as K 2 O by using the AGE approach for stratabound deposits. The hybrid stratabound-halokinetic Gissar tract is estimated to contain between 1 and 16 billion metric tons of undiscovered potash as K 2 O. Chapter 1 of this report provides an overview of the history of the CASB and summarizes evaporite potash deposition, halokinesis, and dissolution processes that have affected the current distribution of potash-bearing salt in the CASB. Chapter 2 describes the Gissar tract, an uplifted region that contains a mix of stratabound and halokinetic potash deposits and all of the discovered and exploited potash deposits of the CASB. Chapter 3 describes the Amu Darya tract, where evaporite deposits remain flat-lying and undeformed since their original deposition. Chapter 4 describes the highly deformed and compressed Afghan-Tajik tract and what is known of the deeply-buried Jurassic salt. Chapter 5 describes the spatial databases included with this report, which contain a collection of CASB potash information. Appendixes A and B summarize descriptive models for stratabound and halokinetic potash-bearing salt deposits, respectively. Appendix C summarizes the AGE method used to evaluate the Gissar and Amu Darya tracts. Appendixes D and E contain grade and thickness data for the Gissar and Amu Darya tracts. Appendix F provides the SYSTAT script used to estimate undiscovered K2 O in a CASB tract. Appendix G provides a potash glossary, and appendix H provides biographies of assessment participants.

Scientific Investigations Report↗

USGS2013

Porphyry copper assessment of Southeast Asia and Melanesia: Chapter D in Global mineral resource assessment

The U.S. Geological Survey collaborated with member countries of the Coordinating Committee for Geoscience Programmes in East and Southeast Asia (CCOP) on an assessment of the porphyry copper resources of Southeast Asia and Melanesia as part of a global mineral resource assessment. The region hosts world-class porphyry copper deposits and underexplored areas that are likely to contain undiscovered deposits. Examples of known porphyry copper deposits include Batu Hijau and Grasberg in Indonesia; Panguna, Frieda River, and Ok Tedi in Papua New Guinea; and Namosi in Fiji. This assessment covers the countries of Cambodia, Indonesia, Lao People’s Democratic Republic, Malaysia, Myanmar, Papua New Guinea, Singapore, Thailand, and parts of southeastern China, India, the Solomon Islands, Vanuatu, and Fiji. Twenty-two geographic areas were delineated as tracts that are permissive for porphyry copper deposits in Southeast Asia. Permissive tracts are grouped into four broadly defined geographic/geologic areas, as follows: (1) the Indochina Peninsula area, (2) Indonesian and Malaysian Islands, (3) New Guinea Island and Papuan New Guinea islands, and (4) Melanesia. Individual tracts range from less than 1,000 to more than 350,000 square kilometers in area. Permissive tracts are based on mapped and inferred subsurface (<1 kilometer depth) distributions of igneous rocks of specific age ranges that define magmatic arcs and magmatic belts that are likely to contain porphyry copper deposits. Most of these magmatic arcs are subduction-related, although some have porphyry-style deposits occurring in postcollisional and (or) poorly understood tectonic settings. Although maps at a variety of different scales were used in the compilation, the final tract boundaries are intended for use at a scale of 1:1,000,000. Global grade and tonnage models for porphyry copper deposits were evaluated. Most of the known deposits are best described as fitting the copper-gold (Cu-Au) subtype of porphyry copper deposit. For some permissive tracts, a general porphyry copper-gold-molybdenum (Cu-Au-Mo) model was used. Assessment participants estimated numbers of undiscovered deposits at different levels of confidence for most of the permissive tracts. These estimates were combined with grade and tonnage models using a Monte Carlo simulation to estimate undiscovered resources. Additional resources in extensions of deposits with identified resources were not evaluated. Assessment results, presented in tables and graphs, show mean amounts of metal and mineralized rock in undiscovered deposits at different quantile levels, as well as the arithmetic mean for each tract. This assessment estimated a mean of 89 undiscovered porphyry copper deposits for the assessed permissive tracts in Southeast Asia and Melanesia. About 288 million metric tons (Mt) of copper and 18,000 metric tons (t) of gold, as well as byproduct molybdenum and silver, could be associated with undiscovered deposits. This represents about four times the number of deposits with identified resources (23) already discovered in Southeast Asia; reliable reported identified resources for those 23 deposits total 84 Mt of copper and 6,000 t of gold. Eleven permissive tracts have no known porphyry copper deposits with reported resources. Three of those 11 tracts lacked sufficient information for a probabilistic assessment and are discussed in qualitative terms. On a regional basis, both the Indochina Peninsula area and the Indonesian-Malaysian Islands area are estimated to contain about 10 times as much in place copper in undiscovered porphyry copper deposits as has been identified to date. For the New Guinea Island areas, the ratio of undiscovered to identified copper resources is about 2. Some parts of the region have a long history of porphyry exploration cycles and mine development, interrupted at times by political and social unrest, environmental concerns, and natural disasters. Changes in mining laws within the region and the recent high price of gold on the world market have prompted renewed interest in porphyry copper deposits in Southeast Asia and Melanesia. However, predicted undiscovered deposits may not be found, and if found, may not be developed. This assessment includes an overview of the assessment results with summary tables. Detailed descriptions of each tract are included in appendixes, with estimates of numbers of undiscovered deposits, and probabilistic estimates of amounts of copper, molybdenum, gold, and silver that could be contained in undiscovered deposits for each permissive tract. A geographic information system (GIS) that accompanies the report includes tract boundaries and a database of known porphyry copper deposits and significant prospects.

Scientific Investigations Report↗

USGS1955

Uranium-bearing minerals in placer deposits of the Red River Valley, Elk City district, Idaho County, Idaho

Uranium-bearing multiple oxide minerals were first recognized in the jig-bed concentrate of !the Tyee Mining Company'ss gold dredge on the Red River about 10 miles south of Elk City. Idaho County, Idaho, in late 1951 or early 1952. The gravels of the placer deposits were derived from the Idaho batholith and a roof pendant of Precambrian rocks in the batholith. Three samples taken for analysis show that the jig-bed concenuate contains 0.134 percent uranium. The nonmagnetic, non-radioactive fractions of the samples assayed 0.2 percent niobium, but no columbite was recognized in the samples. The uranium-bearing placer mineals are brannerite. euxenitte, davidite. betafite, and also contain niobium; ilmenite in the gravels may also contain some niobium. Pegmatites are believed to be the somce of the uranium- and niobium-bearing minerals, but the possibility of finding a pegmatite in the area ,that can be mined economically for uranium or niobium is remote.

Idaho↗

USGS1956

Synthesis of calcium vanadate minerals and related compounds

Synthesis of natural vanadates shows that most of them are stable in an acid environment. Phase studies of a portion of the system CaO-V 2 O 5 -H 2 O indicate that calcium vanadates are an indicator of environmental pH conditions. Some minerals, such as pascoute, indicate rapid evaporation of vanadite solutions; other minerals, such as hewettite, show that slow evaporation took place. Cursory examination of systems K 2 O-UO 2 -(NO 3 ) 2 -V 2 O 5 and CaO-UO 2 (NO 3 ) 2 -V 2 O 5 , both in aqueous solution, has yielded information on the relationships among carnotite, tyuyamunite, and rauvite.

Trace Elements Investigations↗

USGS1962

Physical properties of evaporite minerals

The data in the following tables were abstracted from measurements of physical properties of evaporite minerals or of equivalent synthetic compounds. The compounds considered are the halide and sulfate salts which supposedly precipitated from evaporating ocean water and which form very extensive and thick "rock salt" beds. These beds are composed almost entirely of NaCl. In places where the beds are deeply buried and where fractures occur in the overlying rocks, the salt is plastically extruded upward as in a pipe to form the "salt domes". Most of the tables are for NaCl, both the natural (halite) and the synthetic salt, polycrystalline and single crystals. These measurements have been collected for use 1) in studies on storage of radioactive wastes in salt domes or beds, 2) in calculations concerned with nuclear tests in salt domes and beds, and 3) in studies of phenomena in salt of geologic interest. Rather than an exhaustive compilation of physical property measurements, there tables represent a summary of data from accessible sources. As limitations of time have presented making a more systematic and comprehensive selection, the data given may seem arbitrarily chosen. Some of the data listed are old, and newer, more accurate data are undoubtedly available. Halite (an synthetic NaCl) has been very thoroughly studied because of its relatively simple and highly symmetrical crystal structure, its easy availability naturally or synthetically, both in single crystals and polycrystalline, its useful and scientifically interesting properties, and its role as a compound of almost purely ionic bonding. The measurements of NaCl in the tables, however, represent only a small part of the total number of observations; discrimination was necessary to keep the size of the tabulations manageable. The physical properties of the evaporite minerals other than halite and sylvite have received only desultory attention of experiementalists, and appear in only a few tables. The effects of temperature, hydrostatic pressure, stress difference, and other mechanical, eletrical, and optical conditions on the physical properties have probably been observed more completely on NaCl than on any other solid substance, which makes it a unique and important substance. Several new and important phenomena have been observed first on it. The mechanical properties of NaCl, for example, depend very strongly on the condition and the composition of the gas or liquid in contact with the sample surface; the data are sparse as yet and are not reported here.

Trace Elements Investigations↗

USGS2012

Analyzing legacy U.S. Geological Survey geochemical databases using GIS: applications for a national mineral resource assessment

This report emphasizes geographic information system analysis and the display of data stored in the legacy U.S. Geological Survey National Geochemical Database for use in mineral resource investigations. Geochemical analyses of soils, stream sediments, and rocks that are archived in the National Geochemical Database provide an extensive data source for investigating geochemical anomalies. A study area in the Egan Range of east-central Nevada was used to develop a geographic information system analysis methodology for two different geochemical datasets involving detailed (Bureau of Land Management Wilderness) and reconnaissance-scale (National Uranium Resource Evaluation) investigations. ArcGIS was used to analyze and thematically map geochemical information at point locations. Watershed-boundary datasets served as a geographic reference to relate potentially anomalous sample sites with hydrologic unit codes at varying scales. The National Hydrography Dataset was analyzed with Hydrography Event Management and ArcGIS Utility Network Analyst tools to delineate potential sediment-sample provenance along a stream network. These tools can be used to track potential upstream-sediment-contributing areas to a sample site. This methodology identifies geochemically anomalous sample sites, watersheds, and streams that could help focus mineral resource investigations in the field.

Egan Range↗

USGS2019

Resource Assessment Economic Filter (RAEF)—A graphical user interface supporting implementation of simple engineering mine cost analyses of quantitative mineral resource assessment simulations

Economic evaluations of undiscovered mineral resources provide important context in which to consider the results of quantitative mineral resource assessments. The U.S. Geological Survey economic analysis method uses a simple engineering cost model approach developed by the U.S. Bureau of Mines that applies mine and mill engineering cost equations to simulated undiscovered deposits. The important characteristics of these deposits are derived from Monte Carlo simulations that combine probabilistic estimates of undiscovered deposits that might occur in a study area and a grade-tonnage model defined for a specific deposit type. This report describes the Resource Assessment Economic Filter (RAEF), a graphical user interface (GUI) tool that applies a set of mine cost equations to the deposits under consideration. RAEF, which is written in the open-source statistical programming language R, is an easy-to-use tool to apply user-defined mine, mill, and study area parameters to simulated deposits. For a given deposit type, it estimates the undiscovered resources that might be economic to extract. In addition, RAEF provides a series of graphical, tabular, and statistical summaries that document the results of the economic filter analysis.

Techniques and Methods↗

USGS1986

Simulation of mine drainage for preliminary development of oil shale and associated minerals, Piceance basin, northwestern Colorado

The Piceance basin of northwestern Colorado contains large resources of oil shale, nahcolite, and dawsonite. Development of these minerals will require drainage of water from mines. A six-layer hydrologic model of the basin was prepared to simulate mine drainage for mineral development. Streams and major tributaries were simulated as head-dependent nodes. Stream nodes were gaining or losing, but the rate of loss was constrained by the leakance of the streambed and the stream stage. Springs also were simulated as head-dependent nodes that stop flowing if the aquifer head declines below the spring orifice. (USGS)

Water-Resources Investigations Report↗

USGS2023

Outlining potential biomarkers of exposure and effect to critical minerals: Nutritionally essential trace elements and the rare earth elements

Emerging and low-carbon technologies and innovations are driving a need for domestic sources, sustainable use, and availability of critical minerals (CMs)—those vital to the national and economic security of the United States. Understanding the known and potential health effects of exposures to such mineral commodities can inform prudent and environmentally responsible handling and harvesting. We review the occurrence, use, predominant exposure pathways, and adverse outcome pathways (AOP) for human and fish receptors of those CMs that are nutritionally essential trace metals (specifically, cobalt, chromium, manganese, nickel, and zinc), as well as the rare earth elements. Biological responses to some elements having comparable biogeochemistry can sometimes be similar. Candidate quantifiable biomarkers for assessing potential AOP are conveyed.

Toxics↗

USGS1987

The solubilities of some major and minor element minerals in ground waters associated with a sandstone-hosted uranium deposit

Ground-water samples from 41 wells penetrating basal Oakville sandstone (Miocene) in S Texas were chemically analysed to identify chemical changes related to nearby U orebodies. The coverage included a 240 km 2 area which contains several fault-related U deposits. Factors affecting the hydrochemistry include: 1) relatively high permeabilities of buried fluvial-channel sediments; 2) upwards leakage of brines along growth faults into the aquifer; 3) development of a redox interface (Eh = 0 volts) within the aquifer; and 4) the semi-arid climate. Variations in the saturation index (SI) for chemically reduced minerals of U, As, Mo, Se and for associated minerals such as pyrite outlined the position of known deposits. The SI increases towards zero as the deposits are approached from updip distances of 3-4.5 km, then decreases again downdip. The radiogenic pathfinders Ra and Rn showed very strong anomalies with ore, but diminished to background levels at short distances from ore. A strong He anomaly is deflected in the direction of ground-water flow away from the ore.-R.A.H.

Bulletin de Mineralogie↗

USGS2024

Apatite and monazite geochemistry record magmatic and metasomatic processes in rare earth element mineralization at Mountain Pass, California

The largest rare earth element (REE) deposit in the United States is a carbonatite intrusion at Mountain Pass in the Mojave Desert, California. Despite a clear spatiotemporal association of alkaline silicate and carbonatite intrusions at Mountain Pass, a genetic model of their mutual formation has not been resolved. The Mountain Pass carbonatite has long been upheld as an example of a primary magmatic body, but recent work has suggested it could be fluid-derived. This study investigates the geochemistry of apatite and monazite grains from the alkaline silicate and carbonatite stocks and dikes of the Mountain Pass district, to elucidate the magmatic history of the intrusive suite and identify the role of fluids in rare earth element mineralization. Three apatite populations are identified in the alkaline silicate rocks. A primary magmatic apatite group supports intrusion of the stocks as separate pulses of magma derived from a spatially extensive metasomatized mantle source region. The second group implicates the role of a regional fluid that mobilized light rare earth elements from apatite grains. A minor group of inherited apatite cores, identified by low Sr and negative Eu anomalies, supports assimilation of crustal material in the formation of the intrusive suite. Analyses of monazite and apatite grains from the carbonatite orebody also reveal a mix of primary magmatic and metasomatic (fluid-related) minerals. Compositional similarities between primary phosphates in the carbonatite and alkaline silicate rocks support a genetic link between the intrusive suites. The presence of fluids regionally and within the carbonatite orebody indicates the Mountain Pass carbonatite should not be classified as a purely magmatic REE deposit.

Arizona, California, Nevada↗

USGS1997

Day one road log: Mid-Tertiary igneous rocks and mineral deposits in the central Wasatch Mountains, Utah

Today's field trip examines late Eocene and Oligocene granitoid intrusions, cogenetic volcanic rocks (Keetley Volcanics), and associated hydrothermally altered and mineralized rocks in the central Wasatch Mountains. Because of late Cenozoic tilting related to Basin and Range extension, a continuum of mid-Tertiary paleodepths is exposed that ranges from about 11 km on the west side of the Little Cottonwood stock to the actual paleosurface on the east side of the range (Fig. 1; John, 1989a). Consequently, we will see a wide variety of textures and styles of emplacement in the intrusive rocks, and a correspondingly wide variety of hydrothermal alteration types and mineral deposits (Lawton et al., 1980; John, 1989a). Mid-Tertiary igneous rocks in the central Wasatch Mountains consist of three phaneritic stocks exposed in the western and central parts of the range (Little Cottonwood, Alta, and Clayton Peak stocks); six porphyry to fine-grained phaneritic stocks exposed in the middle and eastern parts of the range, primarily in the Park City mining district (Flagstaff, Glencoe, Mayflower, Ontario, Pine Creek, and Valeo stocks); a subvolcanic porphyry complex (Park Premier stock) exposed near the Park Premier mine which is now partly covered by water filling the Jordanelle Reservoir; and coeval volcanic rocks (Keetley Volcanics), subvolcanic intrusions, and a volcanic neck (Indian Hollow plug) are exposed on the east side of the range (Figs. 2 and 3). The intrusive rocks range from coarse-grained, coarsely porphyritic on the west to fine-grained, porphyroaphanitic on the east (John, 1989a). They form a high-K, calc-alkaline series (Vogel

Utah↗

USGS1953

Analysis of mixed-layer clay mineral structures

Among the enormously abundant natural occurrences of clay minerals, many examples are encountered in which no single specific crystallization scheme extends through a single ultimate grain. The characterization of such assemblages becomes an analysis of the distribution of matter within such grains, rather than the simple identification of mineral species. It having become established that the particular coordination complex typified by mica is a common component of many natural subcrystalline assemblages, the opportunity is afforded to analyze scattering from random associations of these complexes with other structural units. Successful analyses have been made of mixed hydration states of montmorillonite, of montmorillonite with mica, of vermiculite with mica, and of montmorillonite with chlorite, all of which are variants of the mica complex, and of halloysite with hydrated halloysite.

Conference Paper↗

USGS1982

Margaritasite: a new mineral of hydrothermal origin from the Pena Blanca uranium district, Mexico.

Margaritasite, (Cs,K,H3O)2(UO2)2V2O8.nH2O (where Cs > K, H3O and n approx 1), a 10.514, b 8.425, c 7.25 A, beta 106.01o, P21/a, Z = 2, is a newly recognized uranium ore mineral named for the Margaritas deposit, Pena Blanca uranium district, Chihuahua, Mexico, at which it was discovered. A Cs-rich analogue of carnotite, margaritasite is the natural equivalent of synthetic Cs-uranyl vanadate (A.M. 43- 799, 50-825). A fine-grained yellow mineral, it is most easily distinguished from carnotite by XRD; X-ray powder patterns (CuKalpha radiation) show that the (001) reflection of margaritasite lies at 12.7o (2theta ), while that of carnotite is found at 13.8o (2theta ). The shift of the (001) reflection in margaritasite reflects the structural changes caused when Cs occupies the sites filled by K in carnotite. Synthesis experiments indicate that margaritasite also differs from carnotite in a higher-T hydrothermal origin. Chemical analyses and XRD data for margaritasite and synthetic Cs- carnotite, and chemical analyses for rocks from Sierra Pena Blanca and vicinity, are tabulated.-J.A.Z.

American Mineralogist↗

USGS1985

PERMEABILITY CHANGES IN CRYSTALLINE ROCKS DUE TO TEMPERATURE: EFFECTS OF MINERAL ASSEMBLAGE.

The change in permeability with time of granite, quartzite, anorthosite and gabbro was measured while these rocks were subjected to a temperature gradient. Permeability reductions of up to two orders of magnitude were observed, with the greatest reactions occurring in the quartzite. These changes are thought to be caused by dissolution of minerals at high temperatures, and redeposition of the dissolved material at lower temperatures. Quartz appears to be an important mineral in this self-sealing process. If very low permeability is desired around a nuclear waste repository in crystalline rocks, then a quartz-rich rock may be the most appropriate host.

Conference Paper↗

USGS1985

Geology of the Silsilah ring complex, and associated tin mineralization, Kingdom of Saudi Arabia - a synopsis.

A tin greisen deposit is associated with an alkali-feldspar granite that forms part of a ring complex at Jabal as Silsilah. The petrological and geochemical characteristics of the Fawwarah alkali-feldspar granite resemble those of granites located elsewhere that are also associated with deposits of Sn, W and rare metals. The alkali-feldspar granite is peraluminous, incompatible trace-element-enriched, and is characterized by a flat chondrite-normalized REE pattern that includes a very large, negative Eu anomaly. The distinctive mineralogy of the alkali-feldspar granite includes zinnwaldite and topaz. Differentiation and mineral fractionation controlled magma evolution while components of the ring complex were sequentially emplaced. Evolution of the ring complex and its associated tin deposit concluded with local, intense alteration of the Fawwarah alkali-feldspar granite to a cassiterite-bearing greisen. Samples of greisens suggest that the locus of economic tin deposits is not restricted to the two known, strongly mineralized greisens.-J.A.Z.

American Mineralogist↗

USGS1985

ELECTROCHEMICAL PROPERTIES OF ROCKS AND MINERALS.

Many phenomena and processes in the earth sciences are a result of the electrochemical properties of rocks and minerals. Examples include formation of mineral deposits and petroleum reservoirs control of drilling muds, and success or failure of toxic waste isolation barriers. Such phenomena can be observed at a distance using geophysical techniques to measure various electrical properties of the earth.

Conference Paper↗

USGS1985

TRENDS IN BOREHOLE GEOPHYSICS FOR MINERAL EXPLORATION: ASSAYING AND REMOTE DETECTION.

Several borehole geophysical techniques have been developed in recent years. Assaying technique development has been concentrated on nuclear methods, with some progress being made on using electrical and magnetic properties for mineral identification. Adaptation of conventional surface geophysical techniques to the borehole for locating near-misses of mineralized zones has led to the development of borehole resistivity, electromagnetic (EM), gravity and magnetic methods to the borehole environment. This paper discusses some of the applications and pitfalls of these new techniques.

Conference Paper↗