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Groundwater & aquifers

Find USGS groundwater and aquifer publications. Search an aquifer name or place, compare source-supplied dates and open reports for hydrogeology, recharge and water-level studies.

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At least 631 records · Page 35Linked to original sources

USGS2009

Geohydrology and Water Quality of the Valley-Fill Aquifer System in the Upper Sixmile Creek and West Branch Owego Creek Valleys in the Town of Caroline, Tompkins County, New York

In 2002, the U.S. Geological Survey, in cooperation with the Town of Caroline and Tompkins County Planning Department, began a study of the valley-fill aquifer system in upper Sixmile Creek and headwaters of West Branch Owego Creek valleys in the Town of Caroline, NY. The purpose of the study is to provide geohydrologic data to county and town planners as they develop a strategy to manage and protect their water resources. The first aquifer reach investigated in this series is in the Town of Caroline and includes the upper Sixmile Creek valley and part of West Branch Owego Creek valley. The portions of the valley-fill aquifer system that are comprised of saturated coarse-grained sediments including medium to coarse sand and sandy gravel form the major aquifers. Confined sand and gravel units form the major aquifers in the western and central portions of the upper Sixmile Creek valley, and an unconfined sand and gravel unit forms the major aquifer in the eastern portion of the upper Sixmile Creek valley and in the headwaters of the West Branch Owego Creek valley. The valley-fill deposits are thinnest near the edges of the valley where they pinch out along the till-mantled bedrock valley walls. The thickness of the valley fill in the deepest part of the valley, at the western end of the study area, is about 100 feet (ft); the thickness is greater than 165 ft on top of the Valley Heads Moraine in the central part of the valley. An estimated 750 people live over and rely on groundwater from the valley-fill aquifers in upper Sixmile Creek and West Branch Owego Creek valleys. Most groundwater withdrawn from the valley-fill aquifers is pumped from wells with open-ended 6-inch diameter casings; the remaining withdrawals are from shallow dug wells or cisterns that collect groundwater that discharges to springs (especially in the Brooktondale area). The valley-fill aquifers are the sources of water for about 200 households, several apartment complexes, two mobile home parks, a school, and several farms and small businesses. Most groundwater that is withdrawn from pumped wells is returned to the groundwater system via septic systems. Groundwater in the upper and basal confined aquifers in the upper Sixmile Creek valley is under artesian conditions everywhere except where the water discharges to springs along bluffs in the western end of the Sixmile Creek valley. Principal sources of recharge to the confined aquifers are (1) the sides of the valley where the confined aquifers may extend up along the flank of the bedrock valley wall and crop out at land surface or are overlain and in contact with surficial coarse-grained deltaic and fluvial sediments that provide a pathway through which direct precipitation and seepage losses from tributary streams can reach the buried aquifers, or (2) where the buried aquifers are isolated and receive recharge only from adjacent fine-grained sediment and bedrock. The base-flow and runoff components of total streamflow at two streamgages, Sixmile Creek at Brooktondale and Sixmile Creek at Bethel Grove, were calculated using hydrograph-separation techniques from 2003 to 2007 discharge records. Base flow constituted 64 and 56 percent of the total annual flow at the Brooktondale and Bethel Grove streamgages, respectively. Water-quality samples were collected from 2003 to 2005, with 10 surface-water samples collected seasonally during base-flow conditions at the Sixmile Creek at Brooktondale streamgage, and 12 samples were collected during base-flow conditions at several selected tributaries from 2004 to 2005. The predominant cation detected in the surface-water samples was calcium, but moderate amounts of magnesium, silica, and sodium were also detected; the major anions were bicarbonate, chloride, and sulfate. Sodium and chloride concentrations were relatively low in all samples but increased downstream from the Sixmile Creek sampling site at Six Hundred Road near Slaterville Springs, NY, to B

Scientific Investigations Report↗

USGS2011

Simulated effects of allocated and projected 2025 withdrawals from the Potomac-Raritan-Magothy aquifer system, Gloucester and Northeastern Salem Counties, New Jersey

Withdrawals from the Potomac-Raritan-Magothy aquifer system in New Jersey, which includes the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers, are the principal source of groundwater supply in northern Gloucester and northeastern Salem Counties in the New Jersey Coastal Plain. Water levels in these aquifers have declined in response to pumping. With increased population growth and development expected in Gloucester County and parts of Salem County over the next 2 decades (2005-2025), withdrawals from these aquifers also are expected to increase. A steady-state groundwater-flow model, developed to simulate flow in the Potomac-Raritan-Magothy aquifer system in northern Gloucester and northeastern Salem Counties, was calibrated to withdrawal conditions in 1998, when groundwater withdrawals from the Potomac-Raritan-Magothy aquifer system in the model area were more than 10,100 Mgal/yr (million gallons per year). Withdrawals from water-purveyor wells accounted for about 63 percent of these withdrawals, and withdrawals from industrial self-supply wells accounted for about 32 percent. Withdrawals from agricultural-irrigation, commercial self-supply, and domestic self-supply wells accounted for the remaining 5 percent. Results of the 2000 baseline groundwater-flow simulation, incorporating average annual 1999-2001 groundwater withdrawals, indicate that the average simulated water levels in the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers are 31, 27, and 30 feet below the National Geodetic Vertical Datum of 1929 (NGVD 29), respectively, and the lowest simulated water levels are 77, 65, and 59 feet below NGVD 29, respectively. In the full-allocation scenario, the maximum State-permitted (allocated) groundwater withdrawals totaled 16,567 Mgal/yr, an increase of 72 percent from the 2000 baseline simulation. Results of the full-allocation simulation indicate that the average simulated water levels in the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers are 49, 43, and 48 feet below NGVD 29, respectively, which are 18, 16, and 18 feet lower, respectively, than in the 2000 baseline simulation. The lowest simulated water levels are 156, 95, and 69 feet below NGVD 29, respectively, which are 79, 30, and 10 feet lower, respectively, than in the 2000 baseline simulation. Simulated net flow from the Potomac-Raritan-Magothy aquifer system to streams is 8,441 Mgal/yr in the 2000 baseline simulation but is 6,018 Mgal/yr in the full-allocation scenario, a decrease of 29 percent from the 2000 baseline simulation. Simulated net flow in the 2000 baseline simulation is 1,183 Mgal/yr from the aquifer system to the Delaware River but in the full-allocation scenario is 1,816 Mgal/yr from the river to the aquifer system. Four other simulations were conducted that incorporated full-allocation conditions at water-purveyor wells in Critical Area 2 but increased or decreased withdrawals at selected water-purveyor wells outside Critical Area 2 and agricultural-irrigation and industrial-self-supply wells in the study area. The results of the four simulations also indicate net flow from the Delaware River to the Potomac-Raritan-Magothy aquifer system. A growth scenario was developed to simulate future withdrawals in 2025 estimated from population projections for municipalities in the Salem-Gloucester study area. Simulated withdrawals for this scenario totaled 10,261 Mgal/yr, an increase of 6 percent from the 2000 baseline simulation. This total includes about 25 Mgal/yr withdrawn from the Englishtown aquifer system for domestic self-supply. This scenario incorporated full-allocation withdrawals at water-purveyor wells in Critical Area 2, and increased withdrawals at water-purveyor wells outside Critical Area 2. Results of this simulation indicate that the average simulated water levels in the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers are 32, 29, and 32 feet below NGVD 29, respectively, which are 1, 2, and

Scientific Investigations Report↗

USGS2015

Simulation of groundwater flow and analysis of the effects of water-management options in the North Platte Natural Resources District, Nebraska

The North Platte Natural Resources District (NPNRD) has been actively collecting data and studying groundwater resources because of concerns about the future availability of the highly inter-connected surface-water and groundwater resources. This report, prepared by the U.S. Geological Survey in cooperation with the North Platte Natural Resources District, describes a groundwater-flow model of the North Platte River valley from Bridgeport, Nebraska, extending west to 6 miles into Wyoming. The model was built to improve the understanding of the interaction of surface-water and groundwater resources, and as an optimization tool, the model is able to analyze the effects of water-management options on the simulated stream base flow of the North Platte River. The groundwater system and related sources and sinks of water were simulated using a newton formulation of the U.S. Geological Survey modular three-dimensional groundwater model, referred to as MODFLOW–NWT, which provided an improved ability to solve nonlinear unconfined aquifer simulations with wetting and drying of cells. Using previously published aquifer-base-altitude contours in conjunction with newer test-hole and geophysical data, a new base-of-aquifer altitude map was generated because of the strong effect of the aquifer-base topography on groundwater-flow direction and magnitude. The largest inflow to groundwater is recharge originating from water leaking from canals, which is much larger than recharge originating from infiltration of precipitation. The largest component of groundwater discharge from the study area is to the North Platte River and its tributaries, with smaller amounts of discharge to evapotranspiration and groundwater withdrawals for irrigation. Recharge from infiltration of precipitation was estimated with a daily soil-water-balance model. Annual recharge from canal seepage was estimated using available records from the Bureau of Reclamation and then modified with canal-seepage potentials estimated using geophysical data. Groundwater withdrawals were estimated using land-cover data, precipitation data, and published crop water-use data. For fields irrigated with surface water and groundwater, surface-water deliveries were subtracted from the estimated net irrigation requirement, and groundwater withdrawal was assumed to be equal to any demand unmet by surface water. The groundwater-flow model was calibrated to measured groundwater levels and stream base flows estimated using the base-flow index method. The model was calibrated through automated adjustments using statistical techniques through parameter estimation using the parameter estimation suite of software (PEST). PEST was used to adjust 273 parameters, grouped as hydraulic conductivity of the aquifer, spatial multipliers to recharge, temporal multipliers to recharge, and two specific recharge parameters. Base flow of the North Platte River at Bridgeport, Nebraska, streamgage near the eastern, downstream end of the model was one of the primary calibration targets. Simulated base flow reasonably matched estimated base flow for this streamgage during 1950–2008, with an average difference of 15 percent. Overall, 1950–2008 simulated base flow followed the trend of the estimated base flow reasonably well, in cases with generally increasing or decreasing base flow from the start of the simulation to the end. Simulated base flow also matched estimated base flow reasonably well for most of the North Platte River tributaries with estimated base flow. Average simulated groundwater budgets during 1989–2008 were nearly three times larger for irrigation seasons than for non-irrigation seasons. The calibrated groundwater-flow model was used with the Groundwater-Management Process for the 2005 version of the U.S. Geological Survey modular three-dimensional groundwater model, MODFLOW–2005, to provide a tool for the NPNRD to better understand how water-management decisions could affect stream base flows of the North Platte River at Bridgeport, Nebr., streamgage in a future period from 2008 to 2019 under varying climatic conditions. The simulation-optimization model was constructed to analyze the maximum increase in simulated stream base flow that could be obtained with the minimum amount of reductions in groundwater withdrawals for irrigation. A second analysis extended the first to analyze the simulated base-flow benefit of groundwater withdrawals along with application of intentional recharge, that is, water from canals being released into rangeland areas with sandy soils. With optimized groundwater withdrawals and intentional recharge, the maximum simulated stream base flow was 15–23 cubic feet per second (ft 3 /s) greater than with no management at all, or 10–15 ft 3 /s larger than with managed groundwater withdrawals only. These results indicate not only the amount that simulated stream base flow can be increased by these management options, but also the locations where the management options provide the most or least benefit to the simulated stream base flow. For the analyses in this report, simulated base flow was best optimized by reductions in groundwater withdrawals north of the North Platte River and in the western half of the area. Intentional recharge sites selected by the optimization had a complex distribution but were more likely to be closer to the North Platte River or its tributaries. Future users of the simulation-optimization model will be able to modify the input files as to type, location, and timing of constraints, decision variables of groundwater withdrawals by zone, and other variables to explore other feasible management scenarios that may yield different increases in simulated future base flow of the North Platte River.

Nebraska↗

USGS2013

Groundwater quality in the Madera and Chowchilla subbasins of the San Joaquin Valley, California

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s untreated groundwater quality and increases public access to groundwater-quality information. The Madera and Chowchilla subbasins of the San Joaquin Valley constitute one of the study units being evaluated. The Madera-Chowchilla study unit is about 860 square miles and consists of the Madera and Chowchilla groundwater subbasins of the San Joaquin Valley Basin (California Department of Water Resources, 2003; Shelton and others, 2009). The study unit has hot, dry summers and cool, moist winters. Average annual rainfall ranges from 11 to 15 inches, most of which occurs between November and February. The main surface-water features in the study unit are the San Joaquin, Fresno, and Chowchilla Rivers, and the Madera and Chowchilla canals. Land use in the study unit is about 69 percent (%) agricultural, 28% natural (mainly grasslands), and 3% urban. The primary crops are orchards and vineyards. The largest urban area is the city of Madera. The primary aquifer system is defined as those parts of the aquifer corresponding to the perforated intervals of wells listed in the California Department of Public Health (CDPH) database. In the Madera-Chowchilla study unit, these wells typically are drilled to depths between 200 and 800 feet, consist of a solid casing from land surface to a depth of about 140 to 400 feet, and are perforated below the solid casing. Water quality in the primary aquifer system may differ from that in the shallower and deeper parts of the aquifer system. The primary aquifer system in the study unit consists of Quaternary-age alluvial-fan and fluvial deposits that were formed by the rivers draining the Sierra Nevada. Sediments consist of gravels, sands, silts, and clays and generally are coarser closest to the Sierra Nevada and become finer towards the center of the basin. The structure and composition of the deposits in the Madera-Chowchilla study unit are different from those in other parts of the eastern San Joaquin Valley because the Fresno and Chowchilla Rivers primarily drain the Sierra Nevada foothills, whereas the larger rivers drain higher elevations with greater sediment supply. These differences in the sources of sediments are important because they may affect the groundwater chemistry and the physical structure of the sedimentary deposits. Some of the clay layers are lacustrine deposits, the most extensive of which, the Corcoran Clay, underlies the western part of the study unit and divides the primary aquifer system into an unconfined to semi-confined upper system and a largely confined lower system. Regional lateral flow of groundwater is southwest towards the valley trough. Irrigation return flows are the major source of groundwater recharge, and groundwater pumping is the major source of discharge. Groundwater on a lateral flow path may be repeatedly extracted by pumping wells and reapplied at the surface multiple times before reaching the valley trough, resulting in a substantial component of downward vertical flow (Burow and others, 2004; Phillips and others, 2007; Faunt, 2009). This flow pattern enhances movement of water from shallow depths to the primary aquifer system.

California↗

USGS2022

Areas contributing recharge to selected production wells in unconfined and confined glacial valley-fill aquifers in Chenango River Basin, New York

In the Chenango River Basin of central New York, unconfined and confined glacial valley-fill aquifers are an important source of drinking-water supplies. The risk of contaminating water withdrawn by wells that tap these aquifers might be reduced if the areas contributing recharge to the wells are delineated and these areas protected from land uses that might affect the water quality. The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation and the New York State Department of Health, began an investigation in 2019 to improve understanding of groundwater flow and delineate areas contributing recharge to 16 production wells clustered in three study areas in the basin as part of an effort to protect the source of water to these wells. Areas contributing recharge were delineated on the basis of numerical steady-state groundwater-flow models representing long-term average hydrologic conditions. In the Cortland study area, four water suppliers operate 10 production wells that withdraw a total average rate of 2,480 gallons per minute from an unconfined aquifer consisting of well-sorted sand and gravel deposits. Simulated areas contributing recharge to these wells at their average pumping rates covered a total area of 6.93 square miles. Simulated areas contributing recharge extend upgradient from the wells to upland till deposits and to groundwater divides. Some simulated areas contributing recharge include isolated areas remote from the wells. Short simulated groundwater traveltimes from recharging locations to discharging wells indicated that the wells are vulnerable to contamination from land-surface activities; 50 percent of the traveltimes were 10 years or less. Land cover in some of the areas contributing recharge included a substantial amount of urban and agriculture land use. The groundwater-flow model of the Cortland study area was calibrated to available hydrologic data by inverse modeling using nonlinear regression. The parameter variance-covariance matrix from model calibration was used to create parameter sets that reflect the uncertainty of the parameter estimates and the correlation among parameters to evaluate the uncertainty associated with the single, predicted contributing areas to the wells. This analysis led to contributing areas expressed as a probability distribution. Because of the effects of parameter uncertainty, the size of the probabilistic contributing areas was larger than the size of the single, predicted contributing area for the wells. Thus, some areas not in the single, predicted contributing area might actually be in the contributing area, including additional areas of urban and agriculture land use that have the potential to contaminate groundwater. Additional areas that might be in the contributing area included recharge originating near the pumping wells that have relatively short groundwater-flow paths and traveltimes. In each of the Greene and Cincinnatus study areas, one water supplier operates three wells that are screened near the top of the bedrock surface in a confined aquifer consisting of poorly to well-sorted sand and gravel deposits. This confined aquifer is overlain by a lacustrine confining unit of very fine sand, silt, and clay, which in turn is overlain by a thin unconfined aquifer of sand and gravel. The groundwater-flow models for these two areas were manually calibrated because of the limited hydrologic data. Simulated areas contributing recharge to the Greene study area wells covered a total area of 0.35 square mile for the average pumping rate of 170 gallons per minute. The contributing areas extended southeastward of the wells to the groundwater divide in the till uplands. The contributing areas also included remote, isolated areas on the opposite side of the Chenango River from the wells primarily in the till uplands. For the Cincinnatus study area wells, which have a low average pumping rate (34 gallons per minute), the simulated contributing areas totaled 0.06 square mile and were on the same side of the river as the wells, but they are isolated areas remote from the wells primarily in the till-covered bedrock uplands. Land cover in these contributing areas for both study areas is primarily agriculture and forested, with the contributing areas to the Greene study area wells also including some urban land uses. Because the Greene and Cincinnatus study area wells are screened relatively deep and some flow paths to the wells partly travel through the confining unit, which impedes the connection with surface sources of recharge, overall groundwater traveltimes are greater than for wells in the Cortland study area. Fifty percent of Cortland study area wells, but only 9 and 44 percent of Greene and Cincinnatus study area wells, respectively, have groundwater traveltimes of 10 years or less.

New York↗

USGS2013

Simulation of groundwater flow in the "1,500-foot" sand and "2,000-foot" sand and movement of saltwater in the "2,000-foot" sand of the Baton Rouge area, Louisiana

Groundwater withdrawals have caused saltwater to encroach into freshwater-bearing aquifers beneath Baton Rouge, Louisiana. Groundwater investigations in the 1960s identified a freshwater-saltwater interface located at the Baton Rouge Fault, across which abrupt changes in water levels occur. Aquifers south of the fault generally contain saltwater, and aquifers north of the fault contain freshwater, though limited saltwater encroachment has been detected within 7 of the 10 aquifers north of the fault. The 10 aquifers beneath the Baton Rouge area, which includes East and West Baton Rouge Parishes, Pointe Coupee Parish, and East and West Feliciana Parishes, provided about 167 million gallons per day (Mgal/day) for public supply and industrial use in 2010. Groundwater withdrawals from an aquifer that is 2,000-feet (ft) deep in East Baton Rouge Parish (the “2,000-foot” sand of the Baton Rouge area) have caused water-level drawdown up to 356 ft and induced saltwater movement northward across the fault. Groundwater withdrawals from the “2,000-foot” sand averaged 23.9 Mgal/d during 2010. Saltwater encroachment threatens wells that are located about 3 miles north of the fault, where industrial withdrawals account for about 66 percent of the water withdrawn from the “2,000-foot” sand in East Baton Rouge Parish. Constant and variable-density groundwater models were developed with the MODFLOW and SEAWAT groundwater modeling codes to evaluate strategies to control saltwater migration, including changes in the distribution of groundwater withdrawals and installation of “scavenger” wells to intercept saltwater before it reaches existing production wells. Five hypothetical scenarios simulated the effects of different groundwater withdrawal options on groundwater levels within the “1,500-foot” sand and the “2,000-foot” sand and the transport of saltwater within the “2,000-foot” sand. Scenario 1 is considered a base case for comparison to the other four scenarios and simulates continuation of 2007 reported groundwater withdrawals. Scenario 2 simulates discontinuation of withdrawals from seven selected industrial wells located in the northwest corner of East Baton Rouge Parish, and water levels within the “1,500-foot” sand were predicted to be about 15 to 20 ft higher under this withdrawal scenario than under scenario 1. Scenario 3 simulates the effects of a scavenger well, which withdraws water from the base of the “2,000-foot” sand at a rate of 2 Mgal/d, at two possible locations on water levels and concentrations within the “2,000-foot” sand. In comparison to the concentrations simulated in scenario 1, operation of the scavenger well in the locations specified in scenario 3 reduces the chloride concentrations at all existing chloride-observation well locations. Scenario 4 simulates a 3.6 Mgal/d reduction in total groundwater withdrawals from selected wells screened in the “2,000-foot” sand that are located in the Baton Rouge industrial district. For scenario 4, the median and mean plume concentrations are slightly lower than scenario 1. Scenario 5 simulates the effect of total cessation of groundwater withdrawals from the “2,000-foot” sand in the industrial district. The simulated chloride-concentration distribution in scenario 5 reflects the change in groundwater flow direction. Although some saltwater would continue to cross the Baton Rouge Fault and encroach toward municipal supply wells, further encroachment toward the industrial district would be abated.

Louisiana;Mississippi↗

USGS2023

Evaluation of hydrologic processes in the eastern Snake River Plain aquifer using uranium and strontium isotopes, Idaho National Laboratory, eastern Idaho

Waste constituents discharged to the eastern Snake River Plain aquifer at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) pose risks to the water quality of the aquifer. To understand these risks, the U.S. Geological Survey, in cooperation with the DOE, is conducting geochemical studies to better understand the hydrologic processes at the INL that affect the movement of groundwater and waste constituents. In this study, we used natural uranium ( 234 U/ 238 U) and strontium ( 87 Sr/ 86 Sr) isotope ratios of surface water and groundwater to identify the sources of water, the mixing of different source waters, and the flow directions in the shallow part (upper 250 feet) of the aquifer at the INL. Samples were collected from 17 sites at and near the INL that represent the source-water contributions to the aquifer. These source-water sites included surface water, regional groundwater, and springs. Groundwater samples from 63 sites were collected at and near the INL. For all sites, sample collection dates ranged from 1979 to 2019, but groundwater samples collected at the INL are representative of wet climate cycles when the Big Lost River (BLR) was flowing onto the INL. The 234 U/ 238 U activity ratios and 87 Sr/ 86 Sr from groundwater at the INL were plotted on graphs within ternary mixing webs in which the three end members of the mixing web represented specific sources of recharge. The large number of sources of recharge required numerous mixing webs, representing various geographic locations at the INL, so that each mixing web represented an area with just three sources of recharge. Considerations for determining the sources of recharge to groundwater sites included chemical signatures in addition to 234 U/ 238 U and 87 Sr/ 86 Sr, hydrologic context, and geographic location. The mixing webs were used to estimate the percentage of recharge from specific sources to groundwater at wells. The results of this study identified groundwater from the Lemhi Range as a source of recharge to the INL, which was a previously unsuspected source of recharge. The estimated spatial distribution of recharge from the BLR and groundwater from the Lost River Range also decreased and increased, respectively, relative to the spatial distribution estimated from an earlier study. Upwelling geothermal water was identified at only one well, which indicates that the upward movement of deep groundwater to the shallow part of the aquifer is largely nonexistent. Mixing between surface water and groundwater, different groundwater recharge sources, or both is ubiquitous at the INL. Mixing of water fully explains the distribution of 234 U/ 238 U and 87 Sr/ 86 Sr in groundwater at the INL and thus renders unnecessary the hypothesis that fast and slow flow zones at the INL are required to explain the distribution of 234 U/ 238 U and 87 Sr/ 86 Sr.

Idaho↗

USGS2010

Regional groundwater-flow model of the Lake Michigan Basin in support of Great Lakes Basin water availability and use studies

A regional groundwater-flow model of the Lake Michigan Basin and surrounding areas has been developed in support of the Great Lakes Basin Pilot project under the U.S. Geological Survey's National Water Availability and Use Program. The transient 2-million-cell model incorporates multiple aquifers and pumping centers that create water-level drawdown that extends into deep saline waters. The 20-layer model simulates the exchange between a dense surface-water network and heterogeneous glacial deposits overlying stratified bedrock of the Wisconsin/Kankakee Arches and Michigan Basin in the Lower and Upper Peninsulas of Michigan; eastern Wisconsin; northern Indiana; and northeastern Illinois. The model is used to quantify changes in the groundwater system in response to pumping and variations in recharge from 1864 to 2005. Model results quantify the sources of water to major pumping centers, illustrate the dynamics of the groundwater system, and yield measures of water availability useful for water-resources management in the region. This report is a complete description of the methods and datasets used to develop the regional model, the underlying conceptual model, and model inputs, including specified values of material properties and the assignment of external and internal boundary conditions. The report also documents the application of the SEAWAT-2000 program for variable-density flow; it details the approach, advanced methods, and results associated with calibration through nonlinear regression using the PEST program; presents the water-level, drawdown, and groundwater flows for various geographic subregions and aquifer systems; and provides analyses of the effects of pumping from shallow and deep wells on sources of water to wells, the migration of groundwater divides, and direct and indirect groundwater discharge to Lake Michigan. The report considers the role of unconfined conditions at the regional scale as well as the influence of salinity on groundwater flow. Lastly, it describes several categories of limitations and discusses ways of extending the regional model to address issues at the local scale. Results of the simulations portray a regional groundwater-flow system that, over time, has largely maintained its natural predevelopment configuration but that locally has been strongly affected by well withdrawals. The quantity of rainfall in the Lake Michigan Basin and adjacent areas supports a dense surface-water network and recharge rates consistent with generally shallow water tables and predominantly shallow groundwater flow. At the regional scale, pumping has not caused major modifications of the shallow flow system, but it has resulted in decreases in base flow to streams and in direct discharge to Lake Michigan (about 2 percent of the groundwater discharged and about 0.5 cubic foot per second per mile of shoreline). On the other hand, well withdrawals have caused major reversals in regional flow patterns around pumping centers in deep, confined aquifers - most noticeably in the Cambrian-Ordovician aquifer system on the west side of Lake Michigan near the cities of Green Bay and Milwaukee in eastern Wisconsin, and around Chicago in northeastern Illinois, as well as in some shallow bedrock aquifers (for example, in the Marshall aquifer near Lansing, Mich.). The reversals in flow have been accompanied by large drawdowns with consequent local decrease in storage. On the west side of Lake Michigan, groundwater withdrawals have caused appreciable migration of the deep groundwater divides. Before the advent of pumping, the deep Lake Michigan groundwater-basin boundaries extended west of the Lake Michigan surface-water basin boundary, in some places by tens of miles. Over time, the pumping centers have replaced Lake Michigan as the regional sink for the deep flow system. The regional model is intended to support the framework pilot study of water availability and use for the Great Lakes Basin (Reeves, in press).

Illinois, Indiana, Michigan, Wisconsin↗

USGS2021

Geohydrology and water quality of the stratified-drift aquifers in West Branch Cayuga Inlet and Fish Kill Valleys, Newfield, Tompkins County, New York

From 2011 to 2016, the U.S. Geological Survey, in cooperation with the Town of Newfield and the Tompkins County Planning Department, performed a study of the stratified-drift aquifers in the West Branch Cayuga Inlet and Fish Kill Valleys in Newfield, Tompkins County, New York. Both confined and unconfined aquifers were identified, mostly in the valleys. The confined aquifer consists of a discontinuous sand and gravel layer that overlies bedrock and is commonly confined by overlying fine-grained sediments. The unconfined aquifer consists of surficial ice contact sand and gravel, alluvial silt, sand and gravel, and areas where several large tributary streams deposited alluvial fans in the valley, all of which were deposited during and after the last glacial recession. The unconfined aquifers are primarily recharged by direct infiltration of precipitation at the land surface, by surface runoff and shallow subsurface flow from adjacent hillsides, and by seepage loss from streams crossing the aquifer, especially on alluvial fans. The confined aquifers are primarily recharged by groundwater stored in the overlying sand and gravel aquifer that slowly seeps downward through the underlying confining layer. Other sources of recharge are precipitation that falls directly on the surficial confining unit and adjacent valley walls, which then slowly seeps downward and enters the confined aquifer, and groundwater flow from bordering till and bedrock and from bedrock below the valley. There may also be some recharge where confining units are absent or where parts of the confining units contain sediments with moderate permeability. The groundwater naturally discharges to the Fish Kill and West Branch Cayuga Inlet streams and to wetlands overlying the aquifer boundaries, with additional losses due to evapotranspiration. Groundwater is pumped from the aquifers by domestic, municipal, and agricultural wells. Approximately 57.9 million gallons per year was withdrawn from the stratified-drift (sand and gravel) aquifers. Groundwater samples were collected from 11 wells, and surface water samples were collected at 2 sites, one each from Fish Kill and West Branch Cayuga Inlet. None of the common ions (for example, sodium, chloride, and magnesium) exceeded existing drinking water standards at either surface water site. The concentration of nitrate plus nitrite detected was 0.4 milligram per liter as nitrogen in the West Branch Cayuga Inlet site. Total phosphorus was detected at 0.01 milligram per liter as phosphate for both sites. Of the 11 wells sampled, 8 were finished in confined sand and gravel aquifers, 1 was finished in unconfined sand and gravel, and 2 were finished in shale bedrock. Groundwater quality in the study area generally met Federal and State drinking-water standards. However, of the 11 samples taken, 2 exceeded the U.S. Environmental Protection Agency drinking water advisory taste threshold of 20 milligrams per liter for sodium, 8 exceeded the secondary maximum contaminant level of 300 micrograms per liter for iron, and 9 exceeded the secondary maximum contaminant level of 50 micrograms per liter for manganese.

New York↗

USGS2003

The behavior of U- and Th-series nuclides in groundwater

Groundwater has long been an active area of research driven by its importance both as a societal resource and as a component in the global hydrological cycle. Key issues in groundwater research include inferring rates of transport of chemical constituents, determining the ages of groundwater, and tracing water masses using chemical fingerprints. While information on the trace elements pertinent to these topics can be obtained from aquifer tests using experimentally introduced tracers, and from laboratory experiments on aquifer materials, these studies are necessarily limited in time and space. Regional studies of aquifers can focus on greater scales and time periods, but must contend with greater complexities and variations. In this regard, the isotopic systematics of the naturally occurring radionuclides in the U- and Th- decay series have been invaluable in investigating aquifer behavior of U, Th, and Ra. These nuclides are present in all groundwaters and are each represented by several isotopes with very different half-lives, so that processes occurring over a range of time-scales can be studied (Table 1 ⇓ ). Within the host aquifer minerals, the radionuclides in each decay series are generally expected to be in secular equilibrium and so have equal activities (see Bourdon et al. 2003 ). In contrast, these nuclides exhibit strong relative fractionations within the surrounding groundwaters that reflect contrasting behavior during release into the water and during interaction with the surrounding host aquifer rocks. Radionuclide data can be used, within the framework of models of the processes involved, to obtain quantitative assessments of radionuclide release from aquifer rocks and groundwater migration rates. The isotopic variations that are generated also have the potential for providing fingerprints for groundwaters from specific aquifer environments, and have even been explored as a means for calculating groundwater ages.

Reviews in Mineralogy and Geochemistry↗

USGS2020

Inventory and analysis of groundwater resources: Theodore Roosevelt National Park, North Dakota

Industrial and commercial developments in western North Dakota potentially could affect the sources of water that contribute to wells, spring flow, and seeps within Theodore Roosevelt National Park. Without basic water resources data, accurately predicting the effects of water withdrawals and water quality concerns related to industrial and commercial developments near the park would be challenging. Water resources in the park include surface water and groundwater. The Little Missouri River and its tributaries cross all three Theodore Roosevelt National Park units and are the primary surface-water features in the park. Groundwater resources include well discharges, springs, and seeps. The geology and hydrogeology of Theodore Roosevelt National Park are defined by the surrounding Williston Basin. Four aquifers are sources of groundwater to the park: unconsolidated aquifers including alluvial systems, the upper Fort Union aquifer, the lower Fort Union aquifer, and the Fox Hills-lower Hell Creek aquifer. Data used for wells, springs, seeps, and water quality in this report were compiled from the U.S. Geological Survey National Water Information System or from the North Dakota State Water Commission. An inventory of 16 wells was completed for sites within the boundaries of the park. In addition to well data, an inventory of 11 springs and seeps was completed. The groundwater-quality analysis had two objectives: (1) to characterize the groundwater chemistry in aquifers underlying the park and (2) to spatially map selected physical properties and chemical constituents of interest. Groundwater-quality data from the North Dakota State Water Commission were summarized, mapped, and used to characterize groundwater for each aquifer in the study area. Spatial concentration distribution maps were constructed for selected physical properties and chemical constituents using summary statistics and exceedances. Piper diagrams were used to classify and characterize groundwater for each aquifer. Future research to help fill data gaps in water resources information for Theodore Roosevelt National Park, including recommendations from previous studies, consists of the following: (1) evaluating the variability in discharge from springs and seeps in comparison to changes in precipitation or other recharge sources, (2) evaluating flow control measures for flowing artesian wells, (3) completing a water rights review, and (4) performing routine water-quality monitoring for wells and springs.

North Dakota↗

USGS1999

The role of groundwater chemistry in the transport of bacteria to water-supply wells

Static mini-columns and in situ injection and recovery tests were used to assess the effects of modest changes in groundwater chemistry upon the pH-dependence of bacterial attachment, a primary determinant of bacterial mobility in drinking water aquifers. In uncontaminated groundwater (<1 mg l-1 dissolved organic carbon, DOC), bacterial attachment to aquifer grain surfaces declined steadily from 93 to 20% in response to an increase in pH from 5.8 to 7.8. However, bacterial attachment in modestly-contaminated groundwater (4 mg l-1 DOC) was relatively insensitive to pH change from pH 3.5 to pH 8, as was bacterial attachment in uncontaminated groundwater amended with only ~3 mg l-1 of purified humic acid. Destruction by UV-oxidation of the DOC in contaminated groundwater partially restored the pH-dependence of bacterial attachment. Results from static column tests and from a small-scale (3.6 m) natural-gradient injection and recovery study suggest that low concentrations of surfactants can also substantively alter the attraction of groundwater bacteria for grain surfaces and, therefore can alter the transport of bacteria to water-supply wells. This phenomenon was pH-sensitive and dependent upon the nature of the surfactant. At pH 7.6, 200 mg l-1 of the non-ionic surfactant, Imbentin, caused a doubling of fractional bacterial attachment in aquifer-sediment columns, but had little effect under slightly acidic conditions (e.g. at pH 5.8). In contrast, 1 mg l-1 of linear alkylbenzene sulphonate (LAS) surfactant, a common sewage-derived contaminant, decreased the fractional bacterial attachment by more than 30% at pH 5.8, but had little effect at pH 7.3.Static mini-columns and in situ injection and recovery tests were used to assess the effects of modest changes in groundwater chemistry upon the pH-dependence of bacterial attachment, a primary determinant of bacterial mobility in drinking water aquifers. In uncontaminated groundwater (<1 mg l-1 dissolved organic carbon, DOC), bacterial attachment to aquifer grain surfaces declined steadily from 93 to 20% in response to an increase in pH from 5.8 to 7.8. However, bacterial attachment in modestly-contaminated groundwater (4 mg l-1 DOC) was relatively insensitive to pH change from pH 3.5 to pH 8, as was bacterial attachment in uncontaminated groundwater amended with only approx. 3 mg l-1 of purified humic acid. Destruction of UV-oxidation of the DOC in contaminated groundwater partially restored the pH-dependence of bacterial attachment. Results from the static column tests and from a small-scale (3.6 m) natural-gradient injection and recovery study suggest that low concentrations of surfactants can also substantively alter the attraction of groundwater bacteria for grain surfaces and, therefore can alter the transport of bacteria to water-supply wells. This phenomenon was pH-sensitive and dependent upon the nature of the surfactant. At pH 7.6, 200 mg l-1 of the non-ionic surfactant, Imbentin, caused a doubling of fractional bacterial attachment in aquifer-sediment columns, but had little effect under slightly acidic conditions (e.g. at pH 5.8). In contrast, 1 mg l-1 of linear alkylbenzene sulphonate (LAS) surfactant, a common sewage-derived contaminant, decreased the fractional bacterial attachment by more than 30% at pH 5.8, but had little effect at pH 7.3.

Conference Paper↗

USGS2021

Borehole analysis, single-well aquifer testing, and water quality for the Burnpit well, Mount Rushmore National Memorial, South Dakota

Mount Rushmore National Memorial (hereafter referred to as “the memorial”), in western South Dakota, is maintained by the National Park Service (NPS) and includes 1,278 acres of land in the east-central part of the Black Hills. An ongoing challenge for NPS managers at the memorial is providing water from sustainable and reliable sources for operations, staff, and the increasing number of visitors. In 2020, the U.S. Geological Survey (USGS) and NPS completed a hydrological study of the Burnpit well (well 5), a 580-foot-deep open hole groundwater well completed in metamorphic (crystalline) rock at the memorial. The purpose of this study was to estimate the geological and hydraulic properties of the aquifer supplying the well and to determine the water quality of the groundwater from the well. The study provides NPS staff and managers background information for assessing future uses for the well. Methods for data collection and analysis for the study included borehole and video camera analysis in 2020, aquifer testing by the NPS in 2009 and the USGS in 2020, and water-quality sampling in 2020. Borehole camera video generally matched the lithology recorded in the well log. Fractures recorded in the well log and observed with the borehole camera, including more than 20 less prominent fractures and rough sidewall areas, indicated a fractured aquifer. The fractures are the primary conduits for groundwater flow through the rock and into the well. Transmissivity was estimated for the upper and lower water-level drawdown zones at the Burnpit well with data from the NPS and USGS using the Theis and Cooper-Jacob methods. Transmissivity for the NPS test using the Theis method was 9.0 and 11 feet squared per day (ft 2 /d) for the upper and lower drawdown zones, respectively. Using the Cooper-Jacob method, the transmissivity was 22 and 14 ft 2 /d for the upper and lower drawdown zones of the aquifer, respectively. Transmissivity estimates from data from the USGS test were similar. The Theis method, applied to the upper and lower drawdown zones of the aquifer, produced transmissivity estimates of 7.7 and 10 ft 2 /d, and the Cooper-Jacob method produced estimates of 9.7 and 12 ft 2 /d, respectively. Storativity (specific yield) estimated using the Theis method for the NPS aquifer-test data was 0.85 and 0.92 for the upper and lower drawdown zones of the aquifer, respectively. The Cooper-Jacob method applied to the NPS aquifer-test data produced storativity estimates of 0.11 and 0.50 for the upper and lower drawdown zones, respectively. The Theis method applied to the USGS aquifer-test data estimated storativity values of 0.77 and 1.0 for the upper and lower drawdown zones, respectively. The Cooper-Jacob method estimated storativity of 0.50 and 0.60 for the upper and lower drawdown zones of the USGS aquifer test, respectively. The estimated storativity values from the NPS and USGS aquifer tests for the upper and lower drawdown zones were higher than expected for limestones and schists. The hypothetical equilibrium drawdown for the Burnpit well was estimated after the NPS test in 2009 at no more, and possibly less, than 35 gallons per minute. The NPS noted that the sustainable yield likely was overestimated because the water level did not stabilize during the NPS aquifer test. The specific capacity for the NPS aquifer test in 2009 was 0.16 gallon per minute per foot ([gal/min]/ft) of drawdown at 3 hours, and the specific capacity for the USGS aquifer test in 2020 was 0.13 (gal/min)/ft of drawdown at 3 hours. The rate of water-level recovery after pumping ceased was 0.017 and 0.013 (gal/min)/ft for the NPS and USGS aquifer tests, respectively. The water-level recovery rate was nearly an order of magnitude less than the specific capacity estimated during pumping, indicating that water levels in the Burnpit well may not recover quickly enough during pumping to provide for a continuous source of water. Water-quality samples were collected at the Burnpit well on June 24 and July 23, 2020, and analyzed for field-measured properties, major ions, metals, nutrients, and perchlorate. Iron, zinc, and lithium concentrations for unfiltered samples in the well were at least three times greater than the mean filtered sample concentrations reported for crystalline aquifers in the Black Hills. Manganese concentrations were less than the mean concentration for crystalline aquifers but exceeded the U.S. Environmental Protection Agency (EPA) secondary drinking-water standards. The iron concentration from the June 24 sample was about 11 times greater than the EPA secondary drinking-water standards and mean concentrations from crystalline aquifers in the Black Hills. Arsenic concentrations in Burnpit well samples collected in 2020 were greater than the EPA primary drinking-water standard and the mean concentration for crystalline aquifers in the Black Hills. Arsenic occurs naturally in the rock of crystalline aquifers, and concentrations from samples in the Black Hills commonly exceed the EPA primary drinking-water standard of 10 micrograms per liter. High concentrations of arsenic, iron, and manganese metals in the Burnpit well make groundwater from the well in its natural state unusable as a drinking-water source, and water treatment would be necessary to reduce the trace element concentrations to less than the EPA primary and secondary drinking-water standards. However, if the memorial has immediate nonpotable water requirements, such as for construction and fire suppression, groundwater from the Burnpit well could provide water without causing additional stress to current (2021) drinking-water sources.

South Dakota↗

USGS2012

Assessing the vulnerability of public-supply wells to contamination: Rio Grande aquifer system in Albuquerque, New Mexico

This fact sheet highlights findings from the vulnerability study of a public-supply well in Albuquerque, New Mexico (hereafter referred to as “the study well”). The study well produces about 3,000 gallons of water per minute from the Rio Grande aquifer system. Water samples were collected at the study well, at two other nearby public-supply wells, and at monitoring wells installed in or near the simulated zone of contribution to the study well. Untreated water samples from the study well contained arsenic at concentrations exceeding the Maximum Contaminant Level (MCL) of 10 micrograms per liter (µg/L) established by the U.S. Environmental Protection Agency for drinking water. Volatile organic compounds (VOCs) and nitrate also were detected, although at concentrations at least an order of magnitude less than established drinking-water standards, where such standards exist. Overall, study findings point to four primary influences on the movement and (or) fate of contaminants and the vulnerability of the public-supply well in Albuquerque: (1) groundwater age (how long ago water entered, or recharged, the aquifer), (2) groundwater development (introduction of manmade recharge and discharge sources), (3) natural geochemical conditions of the aquifer, and (4) seasonal pumping stresses. Concentrations of the isotope carbon-14 indicate that groundwater from most sampled wells in the local study area is predominantly water that entered, or recharged, the aquifer more than 6,000 years ago. However, the additional presence of the age tracer tritium in several groundwater samples at concentrations above 0.3 tritium units indicates that young (post-1950) recharge is reaching the aquifer across broad areas beneath Albuquerque. This young recharge is mixing with the thousands-of-years-old water, is migrating to depths as great as 245 feet below the water table, and is traveling to some (but not all) of the public-supply wells sampled. Most groundwater samples containing a fraction of young water also contain manmade VOCs, including chloroform (a byproduct of drinking-water chlorination), which indicates that the source of young recharge is, at least in part, infiltration of chlorinated municipal-supply water from leaking waterlines and sewerlines or from turf watering. Other likely manmade, urban recharge sources are seepage from constructed ponds and unlined portions of a stormwater diversion channel. A regional-scale computer-model simulation of groundwater flow and transport to the public-supply well shows that manmade sources of recharge and discharge that were added after about 1930 have greatly altered directions of groundwater flow near Albuquerque and have caused water levels to decline by as much as 120 feet. Local-scale simulations show that seasonal changes in the pumping schedule of the study well affect the age and quality of water produced by the well. Increased pumping during the summer causes significant volumes of water to flow downward from the shallow to the intermediate zones of the aquifer, causing a higher fraction of young water to be produced by the well in the summer than in the winter months and a corresponding increase in VOC detections in the summer relative to the winter. During the winter when the study-well pump is idle for several hours each day, old, high-arsenic water from the deep zone of the aquifer travels up the wellbore and exits into the intermediate zone of the aquifer. When the pump is activated in the winter (for a relatively short time each day), some of the leaked, high-arsenic water is recaptured by the well. This results in a higher arsenic concentration (commonly more than 12 µg/L) in water produced in the winter than in the summer, and a smaller fraction of young water being produced by the well in the winter than in the summer (6 percent in the winter, compared to 11 percent in the summer). Knowledge of the vertical flow direction (both natural and pumping-enhanced) in the vicinity of a long-screened well, coupled with understanding of variations in contaminant concentrations with depth in the aquifer, can help water managers predict the positive or negative effect that wellbore flow will have on water quality and can lead to development of strategies to mitigate contamination (such as changes in pumping schedules or development of devices to inhibit wellbore flow when the pump is off).

New Mexico↗

USGS2012

Quality of water from crystalline rock aquifers in New England, New Jersey, and New York, 1995-2007

Crystalline bedrock aquifers in New England and parts of New Jersey and New York (NECR aquifers) are a major source of drinking water. Because the quality of water in these aquifers is highly variable, the U.S. Geological Survey (USGS) statistically analyzed chemical data on samples of untreated groundwater collected from 117 domestic bedrock wells in New England, New York, and New Jersey, and from 4,775 public-supply bedrock wells in New England to characterize the quality of the groundwater. The domestic-well data were from samples collected by the USGS National Water-Quality Assessment (NAWQA) Program from 1995 through 2007. The public-supply-well data were from samples collected for the U.S. Environmental Protection Agency (USEPA) Safe Drinking Water Act (SDWA) Program from 1997 through 2007. Chemical data compiled from the domestic wells include pH, specific conductance, dissolved oxygen, alkalinity, and turbidity; 6 nitrogen and phosphorus compounds, 14 major ions, 23 trace elements, 222 radon gas (radon), 48 pesticide compounds, and 82 volatile organic compounds (VOCs). Additional samples were collected from the domestic wells for the analysis of gross alpha- and gross beta-particle radioactivity, radium isotopes, chlorofluorocarbon isotopes, and the dissolved gases methane, carbon dioxide, nitrogen, and argon. Chemical data compiled from the public-supply wells include pH, specific conductance, nitrate, iron, manganese, sodium, chloride, fluoride, arsenic, uranium, radon, combined radium ( 226 radium plus 228 radium), gross alpha-particle radioactivity, and methyl tert -butyl ether (M t BE). Patterns in fluoride, arsenic, uranium, and radon distributions were discernable when the data were compared to lithology groupings of the bedrock, indicating that the type of bedrock has an effect on the quality of groundwater from NECR aquifers. Fluoride concentrations were significantly higher in groundwater samples from the alkali granite, peraluminous granite, and metaluminous granite lithology groups than from samples in the other lithology groups. Water samples from 1.4 percent of 2,167 studied wells had fluoride concentrations that were equal to or greater than the maximum contaminant level (MCL) of 4 milligrams per liter (mg/L) and 7.5 percent of the wells had fluoride concentrations that were equal to or greater than the secondary MCL of 2 mg/L. For arsenic, groundwater samples from the calcareous metasedimentary rocks in the New Hampshire-Maine geologic province, peraluminous granite, and pelitic rocks lithology groups had higher concentrations than did samples from the other lithology groups. Water samples from 13.3 percent of 2,054 studied wells had arsenic concentrations that were equal to or greater than the MCL of 10 micrograms per liter (μg/L), about double the national rate of occurrence in community-supply systems and in domestic wells of the United States. Uranium concentrations were significantly higher in groundwater samples from the peraluminous granite, alkali granite, and calcareous metasedimentary rocks in the New Hampshire-Maine geologic province lithology groups than from samples in the other lithology groups. Water samples from 14.2 percent of 556 studied wells had uranium concentrations equal to or greater than the MCL of 30 μg/L. Radon activities were equal to or greater than the proposed MCL of 300 picocuries per liter (pCi/L) in 95 percent of 943 studied wells, and 33 percent of the wells had radon activities were equal to or greater than the proposed alternative maximum contaminant level (AMCL) of 4,000 pCi/L. Radon activities exceeded the proposed AMCL in 20 percent or more of groundwater samples in each of the studied lithology groups with a minimum of 9 samples, but radon activities were significantly higher in groundwater samples from the alkali granite, peraluminous granite, and Narragansett basin metasedimentary rocks lithology groups. Water samples from 3.2 percent of 564 studied wells had combined radium activities equal to or greater than the MCL of 5 pCi/L; however, combined radium activities were not significantly different among the studied lithology groups. Land use and population density also were evaluated to explain patterns in water quality. Concentrations of nitrate, sodium, chloride, and MtBE from the studied wells were significantly greater in areas of high population density (≥50 persons per square kilometer) than in areas of low population density (<50 persons per square kilometer). Concentrations of sodium, chloride, and M t BE from the studied wells were significantly greater in areas classified as developed (urban lands) than in areas classified as undeveloped (forested), agricultural, or mixed (no dominant land use). Nitrate concentrations from the public-supply wells were not significantly different among the four land use categories, but nitrate concentrations from the domestic wells were significantly greater in areas classified as developed than in areas classified as undeveloped, agricultural, or mixed. Chloride to bromide mass ratios in the domestic well samples indicate that the groundwater was probably affected by at least three halogen sources: local precipitation and recharge waters, remnant seawater and connate waters evolved from seawater, and recharge waters affected by road salt. The groundwater in the NECR aquifers generally contained low concentrations of nitrate, VOCs, and pesticides. Less than 1 percent of water samples from 4,781 studied wells had concentrations of nitrate greater than the MCL of 10 mg/L. Less than 1 percent of water samples from 1,299 studied wells exceeded the USEPA advisory level of 20 to 40 μg/L for M t BE. None of the other studied VOCs exceeded a human health benchmark. M t BE (36 percent frequency detection) and chloroform (32.9 percent frequency detection) were the most frequently detected (>0.02 μg/L) VOCs in the domestic wells. M t BE was detected more often in water samples with apparent ages of less than 25 years than in water samples with apparent ages greater than 25 years. This finding is consistent with the time period of high M t BE use in areas in the United States where reformulated gasoline was mandated. The largest pesticide concentration was an estimated concentration of 0.06 μg/L for the herbicide metolachlor. Deethylatrazine, a degradate of atrazine, (18 percent frequency detection) and atrazine (8 percent frequency detection) were the only pesticide compounds detected (>0.001 μg/L) in more than 3 percent of the domestic wells. None of the detected pesticide compounds exceeded human health benchmarks. Concentrations of nitrate and gross alpha-particle activities were significantly greater in the water samples from the domestic wells than in samples from the public-supply wells. Concentrations of sodium, chloride, iron, manganese, and uranium were significantly greater in the water samples from the public-supply wells than in the samples from the domestic wells. One possible explanation may be related to differences in field processing (filtered samples from the domestic wells compared to unfiltered samples from the public-supply wells). The high frequency of detections for a wide variety of manmade and naturally occurring contaminants in both domestic and public-supply wells shows the vulnerability of NECR aquifers to contamination. The highly variable water quality and the association with highly variable lithology of crystalline bedrock underscores the importance of testing individual wells to determine if concentrations for the most commonly detected contaminants exceed human health benchmarks.

Connecticut, Maine, Massachusetts, New Hampshire, ↗

USGS2010

Groundwater-quality data in the South Coast Range-Coastal study unit, 2008: Results from the California GAMA Program

Groundwater quality in the approximately 766-square-mile South Coast Range–Coastal (SCRC) study unit was investigated from May to December 2008, as part of the Priority Basins Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basins Project was developed in response to legislative mandates (Supplemental Report of the 1999 Budget Act 1999-00 Fiscal Year; and, the Groundwater Quality Monitoring Act of 2001 [Sections 10780-10782.3 of the California Water Code, Assembly Bill 599]) to assess and monitor the quality of groundwater in California, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The SCRC study unit was the 25th study unit to be sampled as part of the GAMA Priority Basins Project. The SCRC study unit was designed to provide a spatially unbiased assessment of untreated groundwater quality in the primary aquifer systems and to facilitate statistically consistent comparisons of untreated groundwater quality throughout California. The primary aquifer systems (hereinafter referred to as primary aquifers) were defined as that part of the aquifer corresponding to the perforation interval of wells listed in the California Department of Public Health (CDPH) database for the SCRC study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from the quality of groundwater in the primary aquifers; shallow groundwater may be more vulnerable to surficial contamination. In the SCRC study unit, groundwater samples were collected from 70 wells in two study areas (Basins and Uplands) in Santa Barbara and San Luis Obispo Counties. Fifty-five of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and 15 wells were selected to aid in evaluation of specific water-quality issues (understanding wells). In addition to the 70 wells sampled, 3 surface-water samples were collected in streams near 2 of the sampled wells in order to better comprehend the interaction between groundwater and surface water in the area. The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, polar pesticides and metabolites, and pharmaceutical compounds), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], and 1,2,3-TCP), naturally occurring inorganic constituents (trace elements, nutrients, dissolved organic carbon [DOC], major and minor ions, silica, total dissolved solids [TDS], and alkalinity), and radioactive constituents (gross alpha and gross beta radioactivity). Naturally occurring isotopes (stable isotopes of hydrogen and oxygen in water, stable isotopes of nitrogen and oxygen in dissolved nitrate, stable isotopes of sulfur in dissolved sulfate, stable isotopes of carbon in dissolved inorganic carbon, activities of tritium, and carbon-14 abundance), and dissolved gases (including noble gases) also were measured to help identify the sources and ages of the sampled groundwater. In total, 298 constituents and field water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and matrix-spikes) were collected at approximately 3 to 12 percent of the wells in the SCRC study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Differences between replicate samples generally were less than 10 percent relative and/or standard deviation, indicating acceptable analytical reproducibility. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 84 percent of the compounds. This study did not attempt to evaluate the quality of drinking water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and/or blended with other waters to maintain water quality. Regulatory thresholds apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-regulatory thresholds established for aesthetic concerns by CDPH. Comparisons between data collected for this study and thresholds for drinking water are for illustrative purposes only and are not indicative of compliance or noncompliance with those thresholds. Most organic and inorganic constituents that were detected in groundwater samples from the 55 grid wells in the SCRC study unit were detected at concentrations less than drinking-water thresholds. In addition, all detections of organic constituents in SCRC grid well samples were less than health-based thresholds. In total, VOCs were detected in 33 percent of the 55 grid wells sampled and pesticides and pesticide degradates were detected in 27 percent of grid wells sampled in the SCRC study unit. In the Basins study area, VOCs and pesticides and pesticide degradates were detected in approximately 33 percent of the 39 grid wells. In the Uplands study area, VOCs were detected in approximately 31 percent and pesticides and pesticide degradates were detected in approximately 13 percent of the 16 grid wells. Trace elements and minor ions were sampled for at 32 grid wells and nutrients at 33 grid wells in the SCRC study unit, and most detections were less than health-based thresholds. Exceptions in the Basins study area include one detection of arsenic greater than the USEPA maximum contaminant level (MCL-US) of 10 µg/L and three detections of nitrite plus nitrate, as nitrogen (NO2-+NO3-) greater than the MCL-US of 10 mg/L. Exceptions in the Uplands study area include two detections of arsenic greater than the MCL-US and eight detections of molybdenum greater than the USEPA lifetime health advisory level (HAL-US) of 40 µg/L. All detections of major and minor ions and gross alpha and gross beta radioactivity from the SCRC grid wells were less than health-based thresholds. Results for trace elements, major ions, and TDS with non-enforceable thresholds set for aesthetic concerns from 16 Basins study area grid wells showed that iron concentrations greater than the CDPH secondary maximum contaminant level (SMCL-CA) of 300 µg/L were detected in grid wells. Manganese concentrations greater than the SMCL-CA of 50 µg/L were detected in six grid wells. Chloride concentrations greater than the recommended SMCL-CA threshold of 250 mg/L were detected in one grid well. Sulfate concentrations greater than the recommended SMCL-CA threshold of 250 mg/L were measured in 12 grid wells and 3 of these wells also were greater than the upper SMCL-CA threshold of 500 mg/L. TDS concentrations greater than the SMCL-CA recommended threshold of 500 mg/L were measured in 14 of the 16 Basins study area grid wells and concentrations in 5 of these wells also were greater than the SMCL-CA upper threshold of 1,000 mg/L. In the Uplands study area, iron concentrations greater than the SMCL-CA were detected in 2 of 16 grid wells and manganese concentrations greater than the SMCL-CA were detected in 3 grid wells. TDS and sulfate concentrations greater than the recommended SMCL-CA thresholds were detected in 11 and 2 grid wells, respectively, but none of these concentrations were greater than the SMCL-CA upper thresholds.

California↗

USGS2025

Quality of groundwater used for domestic supply in the Gilroy-Hollister basin and surrounding areas, California, 2022

More than 2 million Californians rely on groundwater from domestic wells for drinking-water supply. This report summarizes a 2022 California Groundwater Ambient Monitoring and Assessment Priority Basin Project (GAMA-PBP) water-quality survey of 33 domestic and small-system drinking-water supply wells in the Gilroy-Hollister Valley groundwater basin and the surrounding areas, where more than 20,000 residents are estimated to utilize privately owned domestic wells. The study area includes the Llagas subbasin in the north, the North San Benito subbasin in the south, and the surrounding uplands. The study was focused on groundwater resources used for domestic drinking-water supply, which are mostly drawn from shallower parts of aquifer systems rather than those of groundwater resources used for public drinking-water supply in the same area. This assessment characterized the quality of ambient groundwater in the aquifer before filtration or treatment, rather than the quality of drinking water delivered to the tap. To provide context, the measured concentrations of constituents in groundwater were compared to Federal and California State regulatory and non-regulatory benchmarks for drinking-water quality. A grid-based method was used to estimate the areal proportions of groundwater resources used for domestic drinking wells that have water-quality constituents present at high concentrations (above the benchmark), moderate concentrations (between one-half of the benchmark and the benchmark for inorganic constituents, or between one-tenth of the benchmark and the benchmark for organic constituents), and low concentrations (less than one-half or one-tenth the benchmark for inorganic and organic constituents, respectively). This method provides statistically representative results at the study-area scale and permits comparisons to other GAMA-PBP study areas. In the study area, inorganic constituents in groundwater were greater than regulatory benchmarks (U.S. Environmental Protection Agency [EPA] or State of California maximum contaminant levels [MCLs]) for public drinking-water quality in 24 percent of domestic groundwater resources. The inorganic constituents present at concentrations greater than MCLs for drinking water were nitrate (as nitrogen), barium, chromium, and selenium. Total dissolved solids (TDS) or manganese were present at concentrations greater than the secondary maximum contaminant levels (SMCLs) that the State of California uses as aesthetic-based benchmarks in 48 percent of domestic groundwater resources. No volatile organic compounds or pesticide constituents were present at concentrations greater than regulatory benchmarks. Total coliform bacteria and enterococci were detected in 4 percent of domestic groundwater resources. Per- and polyfluoroalkyl substances (PFAS) were detected in 19 percent of domestic groundwater resources, and 10 percent had concentrations greater than recently enacted (April 2024) EPA MCLs. Physical and chemical factors from natural and anthropogenic sources that could affect the groundwater quality were evaluated using results from statistical testing of associations between constituent concentrations and potential explanatory variables. In this study, relevant physical factors include well construction characteristics, groundwater age, site proximity to groundwater recharge or discharge zones, and potential sources of contamination. Relevant chemical factors include the initial chemistry of the recharge water, the mineralogy of the aquifer sediments, and the subsequent shifts in chemistry as biologic and geologic reactions alter groundwater in the subsurface. Nitrate concentrations were correlated to agricultural land use, distance from the boundary of the Gilroy-Hollister Valley groundwater basin, and the proportion of modern (post-1950s) water captured by the well. Denitrification under anoxic redox conditions can mitigate some nitrate derived from fertilizer application. Total dissolved solids primarily were derived from water-rock interactions with soils and aquifer materials in the study area, but there were high concentrations where agricultural practices contributed additional TDS. Mineralogy of aquifer sediments and rocks also affect barium, selenium, boron, and chromium concentrations in the Gilroy-Hollister Valley groundwater basin. PFAS were positively correlated with urban land use and the proportion of modern water captured by the well.

California↗

USGS2011

Conceptual model and numerical simulation of the groundwater-flow system of Bainbridge Island, Washington

Groundwater is the sole source of drinking water for the population of Bainbridge Island. Increased use of groundwater supplies on Bainbridge Island as the population has grown over time has created concern about the quantity of water available and whether saltwater intrusion will occur as groundwater usage increases. A groundwater-flow model was developed to aid in the understanding of the groundwater system and the effects of groundwater development alternatives on the water resources of Bainbridge Island. Bainbridge Island is underlain by unconsolidated deposits of glacial and nonglacial origin. The surficial geologic units and the deposits at depth were differentiated into aquifers and confining units on the basis of areal extent and general water-bearing characteristics. Eleven principal hydrogeologic units are recognized in the study area and form the basis of the groundwater-flow model. A transient variable-density groundwater-flow model of Bainbridge Island and the surrounding area was developed to simulate current (2008) groundwater conditions. The model was calibrated to water levels measured during 2007 and 2008 using parameter estimation (PEST) to minimize the weighted differences or residuals between simulated and measured hydraulic head. The calibrated model was used to make some general observations of the groundwater system in 2008. Total flow through the groundwater system was about 31,000 acre-ft/ yr. The recharge to the groundwater system was from precipitation and septic-system returns. Groundwater flow to Bainbridge Island accounted for about 1,000 acre-ft/ yr or slightly more than 5 percent of the recharge amounts. Groundwater discharge was predominately to streams, lakes, springs, and seepage faces (16,000 acre-ft/yr) and directly to marine waters (10,000 acre-ft/yr). Total groundwater withdrawals in 2008 were slightly more than 6 percent (2,000 acre-ft/yr) of the total flow. The calibrated model was used to simulate predevelopment conditions, during which no groundwater pumping or secondary recharge occurred and currently developed land was covered by conifer forests. Simulated water levels in the uppermost aquifer generally were slightly higher at the end of 2008 than under predevelopment conditions, likely due to increased recharge from septic returns and reduced evapotranspiration losses due to conversion of land cover from forests to current conditions. Simulated changes in water levels for the extensively used sea-level aquifer were variable, although areas with declines between zero and 10 feet were common and generally can be traced to withdrawals from public-supply drinking wells. Simulated water-level declines in the deep (Fletcher Bay) aquifer between predevelopment and 2008 conditions ranged from about 10 feet in the northeast to about 25 feet on the western edge of the Island. These declines are related to groundwater withdrawals for public-supply purposes. The calibrated model also was used to simulate the possible effects of increased groundwater pumping and changes to recharge due to changes in land use and climactic conditions between 2008 and 2035 under minimal, expected, and maximum impact conditions. Drawdowns generally were small for most of the Island (less than 10 ft) for the minimal and expected impact scenarios, and were larger for the maximum impact scenario. No saltwater intrusion was evident in any scenario by the year 2035. The direction of flow in the deep Fletcher Bay aquifer was simulated to reverse direction from its predevelopment west to east direction to an east to west direction under the maximum impact scenario.

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