Geology topics
Publications and source records attributed to William R. Hemphill.
The purpose of the Workshop on Luminescence Techniques was threefold: (1) to review the state-of-the-art capabilities of luminescence methods, (2) to consider a variety of concepts for the development of future luminescence sensor systems, and (3) to discuss appropriate research and development strategies for advancing the current state-of-the-art.
Experiments with an imaging airborne Fraunhofer line discriminator (FLD) are being conducted to establish the feasibility of delineating the areal extent of luminescent materials on the earth's surface from aircraft and spacecraft. All luminescence measurements are related to a standard set of conditions with rhodamine wt dye used as a reference standard. The FLD has a minimum detectable rhodamine wt concentration of 0.1 parts per billion (ppb) at a signal-to-noise ratio of 5.0. Luminescence, when expressed in a signal-to-noise ratio (R) is related to equivalent ppb rhodamine wt through the relationship ppb=(0.1R-0.4). Luminescent materials imaged from an aircraft altitude of approximately 2400 m above terrain include fluorite in association with molybdenum, Pinenut Mountains, Nevada (R=62.0); mineralized playas, Claunch, New Mexico (R=960.0); uranium and vanadium-bearing outcrops, Big Indian Valley, Utah (R=105.0); uranophane sandstones, Sandia Mountains, New Mexico (R=60.0); phosphate outcrops, Pine Mountain, California (R=76.0); and marine oil slicks, Santa Barbara Channel, California (R=24.0). Correlation between the amount of fluorite in the rocks and soils of the Pinenut Mountains and luminescence, measured by the FLD, is as high as 0.88 at the 95 percent confidence level.
Luminescence is the property of some materials to emit light when excited by external stimuli such as ultraviolet or visible light or by chemical or mechanical action. The Fraunhofer line discriminator (FLO) is an airborne electro-optical device which operates as a non-imaging radiometer and permits detection of solar stimulated luminescence several orders of magnitude below the intensity detectable with the human eye. A prototype FLO, used in 1969 to monitor the dynamic of water currents in the San Francisco area, was than 5 parts per Airborne tests o a redesigned FLO, featuring an order of magnitude improvement in sensitivity, permitted measurement of differences in the luminescence of trees containing geochemically anomalous concentrations of Colorado) and molybdenum (near Gardnerville, Nevada) trees growing in background areas nearby. In the tests near Denver, luminescence-contrast between stressed and non-stressed trees tended to be greater during periods when cloud cover was 10 percent or less; in most cases, contrast insignificant when cloud cover exceeded 10 percent. In other airborne test the FLO distinguished luminescing phosphate rock and gypsum from sands one and siltstone near Pine Mountain, California; dispersal of oil in a natural seep from uncontaminated sea water in the Santa Barbara Channel; cattle feed lot and municiple sewage effluents near Denver; and paper and phosphate processing effluents in eastern and central Florida. Procedures employing a laboratory fluorescence spectrometer permit prediction of the detectivity with an FLO prior to monitoring an airborne test. Luminescence spectra of the material are corrected for wavelength variation in spectrometer source, detector sensitivity, and solar illumination. By comparing these results with the luminescence of a rhodamine WT dye standard, the luminescence .of the material may be expressed in terms of rhodamine dye equivalency at the wavelength of several Fraunhofer lines. The FLO detectivity may be assessed at each Fraunhofer line, and the optimum line for field observation of the material may be selected. Future work will include the integration of the FLO with a line scan imaging system in order to assess the contribution of two-dimensional spatial resolution to the interpretability and usefulness of luminescence data. It should also include 1) investigation of luminescence polarization of some materials, particularly metal stressed plants, 2) an assessment of the use of pulsed lasers to stimulate phosphorescence decay time in the nanosecond and microsecond ranges; and 3) a study to determine the feasibility of conducting an FLO experiment from the Space Shuttle or other spacecraft.
Response of an experimental Fraunhofer line discriminator(FLD) to a wide range of surficial deposits common in deserts and semideserts was tested in the laboratory and from an 1-1-19 helicopter. By design the instrument sensed radiation from the ground specifically at the sodium D2 Fraunhofer line (5890 angstroms). It is capable of detecting a fluorescence component emanating from ground targets irradiated by sunlight along the line of flight, provided the aircraft is nearly level. However, no signals attributable to fluorescence were recorded during 540 miles of aerial traverses over southeastern California and west-central Arizona. It is concluded that exposed surfaces of target materials throughout the traverses were either non-luminescent at 5890 A or not sufficiently so to be detectable. It cannot be ruled out that the lack of fluorescence is partly attributable to surficial coatings of non-luminescent weathered material. The principal route surveyed from the air was from Needles, California to Furnace Creek Ranch, Death Valley and return via the Amargosa River valley, Silurian Lake (dry), Silver Lake (dry), and Soda Lake (dry). Principal targets traversed were unconsolidated elastic sediments ranging from silty clay to cobbles, and a wide range of evaporite deposits. Evaporite minerals thought to have been viewed in high concentrations are halite (sodium chloride), gypsum (hydrous calcium sulfate), probably other sulfate minerals, borax and probably ulexite (hydrous sodium borates), possibly colemanite (hydrous calcium borate), and probably some carbonate minerals. Extensive manganese-rich outcrops midway between Needles and Prescott had to be by-passed because of low sun-angles, cloudiness, and a heavy load in relation to altitude (above 5,000 feet). Several of the more common evaporite minerals were tested under the FLD on the ground, while being irradiated by bright sunlight. Minerals tested were chiefly from salt fiats (salars) in the Atacama Desert of northern Chile, and included halite, gypsum, ulexite, thenardite (sodium sulfate), aragonite (calcium carbonate) and nitrate ore containing soda niter (sodium nitrate). Crude oil from the Santa Barbara leak was tested in its natural state and in solutions of methyl-isobutyl-ketone (MIBK). Petroliferous sandstone samples containing both high and moderate concentrations of oil were tested on both fresh and weathered surfaces. No response definitely attributable to fluorescence at 5890 A was noted from any of the foregoing geologic materials, although a possible very weak response to one oil sample in MBK solution appears on the record. Although no fluorescence was detected, the mechanical operation of the FLD was satisfactory throughout 8 hours of flight, with attendant vibrations, and during a wide range of sun angles, from 13° to 33°. In accord with design, the FLD showed no appreciable response to moderate contrasts in reflectivity among targets, although there was a marked response to strong contrasts in reflectivity. Airborne tests also established that a minimum instrumental warm-up time of seven minutes is required, and that response is not entirely independent of either the vertical angle (tilt) or horizontal angle (flight direction) of the aircraft.
An experimental Fraunhofer line discriminator detected solar-stimulated yellow fluorescence (5890 A) emitted by Rhodamine WT dye in aqueous solutions. Concentration of 1 part per billion was detected in tap water 1/2-meter deep. In extremely turbid San Francisco Bay, dye was monitored in concentrations of less than 5 parts per billion from helicopter and ship. Applications include studies of current dynamics and dispersion. Potential applications of the technique could include sensing oil spills, fish oils, lignin sulfonates, other fluorescent pollutants, and chlorophyll fluorescence.
Carbonate rocks and evaporite deposits commonly exhibit relatively high reflectance in the ultraviolet (<3600A), and some outcrops of these materials are selectively shown on ultraviolet imagery. Other materials which are commonly strongly imaged on ultraviolet imagery and photography include water, snow, concrete, and metallic objects, particularly aluminum. Outdoor tests of an active ultraviolet imaging system have demonstrated the feasibility of imaging ultraviolet stimulated luminescence of such minerals as talc, dolomite, and deweylite along quarry faces from distances of several hundred feet. The system features a cathode ray tube transmitter, an image dissector receiver, and a video monitor on which the distribution of luminescent material is imaged as the outcrop is scanned. A pulsed ultraviolet laser emitting at 3371A has been used successfully in the laboratory to stimulate phosphorescence of selected rock and mineral specimens and to discriminate between them on the basis of decay time which ranges from less than three to more than 10 microseconds. Initial results suggest that sodic feldspars have longer decay periods than calcic feldspars. Some granites also appear to have decay periods significantly different from other types of granite in the same locality. Outdoor tests with a high-resolution grating spectrometer were successful in detecting luminescent materials by means of the so-called "Fraunhofer line-depth method". This method is advantageous because it uses the sun so an ultraviolet source and therefore ifs independent of low-powered artificial sources such as cathode ray tubes, lasers, and mercury vapor lamps„ A Fraunhofer line- discriminator suitable for aircraft operation has been constructed, and initial on-the- ground tests are being performed on Rhodamine WT, a luminescent dye used by hydrologists and oceanographers in studies of current dynamics in streams and estuaries.
Study of the Gemini V photograph of the Salt Range and Potwar Plateau, West Pakistan, indicates that small-scale orbital photographs permit recognition of the regional continuity of some geologic features, particularly faults and folds that could he easily overlooked on conventional air photographs of larger scale. Some stratigraphic relationships can also be recognized on the orbital photograph, but with only minimal previous geologic knowledge of the area, these interpretations are less conclusive or reliable than the interpretation of structure. It is suggested that improved atmospheric penetration could be achieved through the use of color infrared film. Photographic expression of topography could also be improved by deliberately photographing some areas during periods of low sun angle.
No abstract available.
Preliminary field tests of an active ultraviolet imaging system have shown that it is possible to produce linages of the terrain from distances as great as 75 feet by means of reflected ultraviolet light at wavelengths longer than 3300 A. Minerals that luminesce when exposed to ultraviolet energy have been detected from distances as great as 200 feet. With appropriate design modifications, it may be possible to utilize a similar system in detecting luminescing minerals from greater distances. Also, with a similar system and appropriate auxiliary equipment such as image intensifiers, it may be possible to discriminate between naturally occurring materials on the basis of reflected ultraviolet energy at wavelengths shorter than 3000 A. In this part of the spectrum image contrast for some rock types may exceed that from visible light. Information from these and related ultraviolet spectralanalysis studies may be useful in evaluating data obtained from passive ultraviolet systems in lunar orbit as well as from active systems on the lunar surface.
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