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Rodney J. Weick

Publications and source records attributed to Rodney J. Weick.

3 recordsLinked to original sources

Aquifer-scale controls on the distribution of nitrate and ammonium in ground water near La Pine, Oregon, USA

Geochemical and isotopic tools were applied at aquifer, transect, and subtransect scales to provide a framework for understanding sources, transport, and fate of dissolved inorganic N in a sandy aquifer near La Pine, Oregon. NO3 is a common contaminant in shallow ground water in this area, whereas high concentrations of NH4-N (up to 39 mg/L) are present in deep ground water. N concentrations, N/Cl ratios, tracer-based apparent ground-water ages, N isotope data, and hydraulic gradients indicate that septic tank effluent is the primary source of NO3. N isotope data, N/Cl and N/C relations, 3H data, and hydraulic considerations point to a natural, sedimentary organic matter source for the high concentrations of NH4, and are inconsistent with an origin as septic tank N. Low recharge rates and flow velocities have largely restricted anthropogenic NO3 to isolated plumes within several meters of the water table. A variety of geochemical and isotopic data indicate that denitrification also affects NO3 gradients in the aquifer. Ground water in the La Pine aquifer evolves from oxic to increasingly reduced conditions. Suboxic conditions are achieved after about 15-30 y of transport below the water table. NO3 is denitrified near the oxic/suboxic boundary. Denitrification in the La Pine aquifer is characterized well at the aquifer scale with a redox boundary approach that inherently captures spatial variability in the distribution of electron donors.

Oregon

Evaluation of Approaches for Managing Nitrate Loading from On-Site Wastewater Systems near La Pine, Oregon

This report presents the results of a study by the U.S. Geological Survey, done in cooperation with the Oregon Department of Environmental Quality and Deschutes County, to develop a better understanding of the effects of nitrogen from on-site wastewater disposal systems on the quality of ground water near La Pine in southern Deschutes County and northern Klamath County, Oregon. Simulation models were used to test the conceptual understanding of the system and were coupled with optimization methods to develop the Nitrate Loading Management Model, a decision-support tool that can be used to efficiently evaluate alternative approaches for managing nitrate loading from on-site wastewater systems. The conceptual model of the system is based on geologic, hydrologic, and geochemical data collected for this study, as well as previous hydrogeologic and water quality studies and field testing of on-site wastewater systems in the area by other agencies. On-site wastewater systems are the only significant source of anthropogenic nitrogen to shallow ground water in the study area. Between 1960 and 2005 estimated nitrate loading from on-site wastewater systems increased from 3,900 to 91,000 pounds of nitrogen per year. When all remaining lots are developed (in 2019 at current building rates), nitrate loading is projected to reach nearly 150,000 pounds of nitrogen per year. Low recharge rates (2-3 inches per year) and ground-water flow velocities generally have limited the extent of nitrate occurrence to discrete plumes within 20-30 feet of the water table; however, hydraulic-gradient and age data indicate that, given sufficient time and additional loading, nitrate will migrate to depths where many domestic wells currently obtain water. In 2000, nitrate concentrations greater than 4 milligrams nitrogen per liter (mg N/L) were detected in 10 percent of domestic wells sampled by Oregon Department of Environmental Quality. Numerical simulation models were constructed at transect (2.4 square miles) and study-area (247 square miles) scales to test the conceptual model and evaluate processes controlling nitrate concentrations in ground water and potential ground-water discharge of nitrate to streams. Simulation of water-quality conditions for a projected future build-out (base) scenario in which all existing lots are developed using conventional on-site wastewater systems indicates that, at equilibrium, average nitrate concentrations near the water table will exceed 10 mg N/L over areas totaling 9,400 acres. Other scenarios were simulated where future nitrate loading was reduced using advanced treatment on-site systems and a development transfer program. Seven other scenarios were simulated with total nitrate loading reductions ranging from 15 to 94 percent; simulated reductions in the area where average nitrate concentrations near the water table exceed 10 mg N/L range from 22 to 99 percent at equilibrium. Simulations also show that the ground-water system responds slowly to changes in nitrate loading due to low recharge rates and ground-water flow velocity. Consequently, reductions in nitrate loading will not immediately reduce average nitrate concentrations and the average concentration in the aquifer will continue to increase for 25-50 years depending on the level and timing of loading reduction. The capacity of the ground-water system to receive on-site wastewater system effluent, which is related to the density of homes, presence of upgradient residential development, ground-water recharge rate, ground-water flow velocity, and thickness of the oxic part of the aquifer, varies within the study area. Optimization capability was added to the study-area simulation model and the combined simulation-optimization model was used to evaluate alternative approaches to management of nitrate loading from on-site wastewater systems to the shallow alluvial aquifer. The Nitrate Loading Management Model (NLMM) was formulated to find the minimum red

Scientific Investigations Report

Organic wastewater compounds, pharmaceuticals, and coliphage in ground water receiving discharge from onsite wastewater treatment systems near La Pine, Oregon: Occurrence and implications for transport

The occurrence of organic wastewater compounds (components of 'personal care products' and other common household chemicals), pharmaceuticals (human prescription and nonprescription medical drugs), and coliphage (viruses that infect coliform bacteria, and found in high concentrations in municipal wastewater) in onsite wastewater (septic tank effluent) and in a shallow, unconfined, sandy aquifer that serves as the primary source of drinking water for most residents near La Pine, Oregon, was documented. Samples from two types of observation networks provided basic occurrence data for onsite wastewater and downgradient ground water. One observation network was a group of 28 traditional and innovative (advanced treatment) onsite wastewater treatment systems and associated downgradient drainfield monitoring wells, referred to as the 'innovative systems network'. The drainfield monitoring wells were located adjacent to or under onsite wastewater treatment system drainfield lines. Another observation network, termed the 'transect network', consisted of 31 wells distributed among three transects of temporary, stainless-steel-screened, direct-push monitoring wells installed along three plumes of onsite wastewater. The transect network, by virtue of its design, also provided a basis for increased understanding of the transport of analytes in natural systems. Coliphage were frequently detected in onsite wastewater. Coliphage concentrations in onsite wastewater were highly variable, ranging from less than 1 to 3,000,000 plaque forming units per 100 milliliters. Coliphage were occasionally detected (eight occurrences) at low concentrations in samples from wells located downgradient from onsite wastewater treatment system drainfield lines. However, coliphage concentrations were below method detection limits in replicate or repeat samples collected from the eight sites. The consistent absence of coliphage detections in the replicate or repeat samples is interpreted to indicate that the detections reported for ground-water samples represented low-level field or laboratory contamination, and it would appear that coliphage were effectively attenuated to less than 1 PFU/100 mL over distances of several feet of transport in the La Pine aquifer and (or) overlying unsaturated zone. Organic wastewater compounds were frequently detected in onsite wastewater. Of the 63 organic wastewater compounds in the analytical schedule, 45 were detected in the 21 samples of onsite wastewater. Concentrations of organic wastewater compounds reached a maximum of 1,300 ug/L (p-cresol). Caffeine was detected at concentrations as high as 320 ug/L. Fourteen of the 45 compounds were detected in more than 90 percent of onsite wastewater samples. Fewer (nine) organic wastewater compounds were detected in ground water, despite the presence of nitrate and chloride likely from onsite wastewater sources. The nine organic wastewater compounds that were detected in ground-water samples were acetyl-hexamethyl-tetrahydro-naphthalene (AHTN), caffeine, cholesterol, hexahydrohexamethyl-cyclopentabenzopyran, N,N-diethyl-meta-toluamide (DEET), tetrachloroethene, tris (2-chloroethyl) phosphate, tris (dichloroisopropyl) phosphate, and tributyl phosphate. Frequent detection of household-chemical type organic wastewater compounds in onsite wastewater provides evidence that some of these organic wastewater compounds may be useful indicators of human waste effluent dispersal in some hydrologic environments. The occurrence of organic wastewater compounds in ground water downgradient from onsite wastewater treatment systems demonstrates that a subgroup of organic wastewater compounds is transported in the La Pine aquifer. The consistently low concentrations (generally less than 1 ug/L) of organic wastewater compounds in water samples collected from wells located no more than 19 feet from drainfield lines indicates that the reactivity (sorption, degradation) of this suite of organic waste.

Oregon