USGS Science⌕ Search

Geology topics

J.R. Gillison

Publications and source records attributed to J.R. Gillison.

12 recordsLinked to original sources
USGS2002

Determination of selected elements in whole coal and in coal ash from the eight argonne premium coal samples by atomic absorption spectrometry, atomic emission spectrometry, and ion-selective electrode

Methods for the determination of 24 elements in whole coal and coal ash by inductively coupled argon plasma-atomic emission spectrometry, flame, graphite furnace, and cold vapor atomic absorption spectrometry, and by ion-selective electrode are described. Coal ashes were analyzed in triplicate to determine the precision of the methods. Results of the analyses of NBS Standard Reference Materials 1633, 1633a, 1632a, and 1635 are reported. Accuracy of the methods is determined by comparison of the analysis of standard reference materials to their certified values as well as other values in the literature.

Energy & Fuels↗
USGS1986

The Georges Bank monitoring program 1985: Analysis of trace metals in bottom sediments during the third year of monitoring

Of the 12 elements analyzed in bulk (undifferentiated) sediments collected adjacent to drilling rigs on Georges Bank, only barium was found to increase in concentration during the period when eight exploratory wells were drilled (July 1981 until September 1982). The maximum postdrilling concentration of barium (a major element in drilling mud) reached 172 ppm in bulk sediments near the drill site in block 410. This concentration is higher than the predrilling concentration at this location by a factor of 5.9. This maximum barium concentration is within the range of predrilling concentrations (28-300 ppm) measured in various sediment types from the regional stations of this program. No drilling-related changes in the concentrations of the 11 other metals have been observed in bulk sediments at any of the locations sampled in this program. We estimate that about 25 percent of the barite discharged at block 312 was present in the sediments within 6 km of the rig, 4 weeks after drilling was completed at this location (drilling period was December 8, 1981-June 27, 1982). For almost a year following completion of this well, the inventory of barite decreased rapidly, with a half-life of 0.34 year. During the next year, the inventory decreased at a slower rate (half-life of 3.4 years). The faster rate probably reflects resuspension and sediment transport of bariterich material residing at the sediment surface. Elevated barium concentrations in post-drilling sediment-trap samples from block 312 indicate that such resuspension can occur up to at least 25 m above the sea floor. As the remaining barite particles are reworked deeper into the sediments by currents and bioturbation, removal by sediment-transport processes is slower. The barite discharged during the exploratory phase of drilling is associated with the fine fraction of sediment and is widely distributed around the bank. We found evidence for barium transport to Great South Channel, 115 km west of the drilling, and to stations 2 and 3, 35 km east of the easternmost drilling site. Small increases in barium concentrations, present in the fine fraction of sediment only, were measured also at the heads of both Lydonia and Oceanographer Canyons, located 8 and 39 km, respectively, seaward of the nearest exploratory well.

Georges Bank↗
USGS1984

The Georges Bank monitoring program, 1984: Analysis of trace metals in bottom sediments during the second year of monitoring

Of the 12 elements analyzed in bulk (undifferentiated) sediments collected adjacent to drilling rigs on Georges Bank, only barium was found to increase in concentration during the drilling period (July 1981 until September 1982). The maximum postdrilling concentration of barium (a major element in drilling mud) reached 172 ppm in bulk sediments near the drill site in block 410. This concentration is a factor of 5.9 times higher than the predrilling concentration at that location. This maximum postdrilling barium concentration is within the range of predrilling concentrations {28-300 ppm} measured in various sediment types from the regional stations of this program. No drilling-related changes in the concentrations of chromium or other metals have been observed in bulk sediments at any of the locations sampled in this program to date. We estimate that between 21 percent and 31 percent of the barite (principal barium-bearing mineral} discharged at block 312 was present in the sediments within 6 km of the rig, 4 weeks after drilling was completed. The barite deposited near this well was found to decrease in concentration with a half-life of 0.4year. At this rate, the average barium concentration in sediments within 6 km of the drilling rig in block 312 is expected to be only 10 percent higher than the predrilling concentration within approximately 1.5 years. Although the inventory of the barite discharged on Georges Bank is based on only a few data points, most (approximately 69 percent) of the barite discharged by the eight exploratory wells apparently can be found in sediments west of the drilling locations. The increase in barium concentration above background can be measured in the fine fraction of sediment at a distance of 65 km to the west of block 312. Analysis of sediment-trap samples collected 25 m above the bottom in block 312 indicates that the dispersion of barmm-rich fine sediment is enhanced by resuspension from the sea floor and transport to the west with the mean current flow. Evidence exists of small accumulations of barium near the heads of Lydonia and Oceanographer Canyons. However, the increased concentrations can be defined only by analyzing the fine fraction of sediment.

Georges Bank↗