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New crystal-structure refinements of Pca 2 1 boracite, Mg 3 ClB 7 O 13 , and R ϵ c ericaite, Fe 2.4 Mg 0.6 ClB 7 O 13 , show that some boron and oxygen atoms are involved in the ‘ferro’ transitions as well as the metal and halogen atoms. The atomic displacements associated with the polarity changes are as large as 0.6Å.
A molecular orbital description, based on spin-unrestricted X α-scattered wave calculations, is given for the electronic structures of mixed valence iron oxides and silicates. The cluster calculations show that electron hopping and optical intervalence charge-transger result from weak FeFe bonding across shared edges of FeO 6 coordination polyhedra. In agreement with Zener's double exchange model, FeFe bonding is found to stabilize ferromagnetic coupling between Fe 2+ and Fe 3+ cations.
The authors describe the conversion of an Endeco-174 current meter to a solid-state recording current meter. A removable solid-state module was designed to fit in the space originally occupied by an 8-track tape cartridge. The module contains a CPU and 128 kilobytes of nonvolatile CMOS memory. The solid-state module communicates with any terminal or computer using an RS-232C interface at 4800 baud rate. A primary consideration for conversion was to keep modifications of the current meter to a minimum. The communication protocol was designed to emulate the Endeco tape translation unit, thus the need for a translation unit was eliminated and the original data reduction programs can be used without any modification. After conversion, the data recording section of the current meter contains no moving parts; the storage capacity of the module is equivalent to that of the original tape cartridge.
In Love et al. (2023), 5 estimated geopotentials on long lines for the March 1989 storm are incorrect. This was the result of incorrect calculation of line integrals. This error affects the two paragraphs of Section 11 and Figure 10 of that paper. The most significant impact of this error is that we overestimated the average ratio of the geopotentials measured the long lines during the March 1940 storm to the estimated geopotentials for the March 1989 storm. Instead of being a factor of 9 higher, the average ratio is only 9% higher. This means the inductive geoeffectiveness of the March 1940 storm was comparable to, or just slightly greater than, the geoeffectiveness of the March 1989 storm. Corrected paragraphs and a corrected figure are provided here.
The Landsat Data Continuity Mission (LDCM) is a scientific endeavor to extend the longest continuous multi-spectral imaging record of Earth's land surface. The observatory consists of a spacecraft bus integrated with two imaging instruments; the Operational Land Imager (OLI), built by Ball Aerospace & Technologies Corporation in Boulder, Colorado, and the Thermal Infrared Sensor (TIRS), an in-house instrument built at the Goddard Space Flight Center (GSFC). Both instruments are integrated aboard a fine-pointing, fully redundant, spacecraft bus built by Orbital Sciences Corporation, Gilbert, Arizona. The mission is scheduled for launch in January 2013. This paper will describe the innovative end-to-end approach for efficiently managing high volumes of simultaneous realtime and playback of image and ancillary data from the instruments to the reception at the United States Geological Survey's (USGS) Landsat Ground Network (LGN) and International Cooperator (IC) ground stations. The core enabling capability lies within the spacecraft Command and Data Handling (C&DH) system and Radio Frequency (RF) communications system implementation. Each of these systems uniquely contribute to the efficient processing of high speed image data (up to 265Mbps) from each instrument, and provide virtually error free data delivery to the ground. Onboard methods include a combination of lossless data compression, Consultative Committee for Space Data Systems (CCSDS) data formatting, a file-based/managed Solid State Recorder (SSR), and Low Density Parity Check (LDPC) forward error correction. The 440 Mbps wideband X-Band downlink uses Class 1 CCSDS File Delivery Protocol (CFDP), and an earth coverage antenna to deliver an average of 400 scenes per day to a combination of LGN and IC ground stations. This paper will also describe the integrated capabilities and processes at the LGN ground stations for data reception using adaptive filtering, and the mission operations approach fro- the LDCM Mission Operations Center (MOC) to perform the CFDP accounting, file retransmissions, and management of the autonomous features of the SSR.
Germanium (Ge) is a metal used in emerging energy technologies, communications, and defense, and has been deemed critical by the United States due to its essential applications and scarce supply. Germanium is recovered as a byproduct of zinc (Zn) sulfides, and mining and processing of these materials lead to waste that could act both as a source of extractable Ge and a source for exposure to humans and ecosystems. Yet the distribution, speciation, and mineral hosts of Ge in mining-impacted areas are poorly understood. The Tar Creek Superfund Site, a former Zn mining area and Ge producer, is a natural laboratory to understand the environmental behavior and economic implications of Ge in mine wastes. We studied the distribution and behavior of Ge in solid wastes at the Tar Creek Superfund Site using bulk and microanalytical techniques. In wastes at this site we find that Ge has been redistributed from its original host, sphalerite (ZnS), to the fine-grained weathering product hemimorphite (Zn4Si2O7(OH)2·H2O), which impacts germanium's mobility, bioaccessibility, and potential for recovery. We provide chemical and mineralogical evidence of this redistribution, along with an evaluation of the oxidation state and molecular-scale substitution of Ge into sphalerite, hemimorphite, and quartz. Geochemical modeling shows that hemimorphite is more stable than sphalerite in waste piles and provides a stable secondary repository for Ge. However, hemimorphite is fine-grained, and if ingested or inhaled is readily soluble, with the potential to release Ge. Lastly, we discuss other sites internationally where similar behavior may be important. This study shows that weathering can have a significant impact on the distribution, speciation, and mineral hosts of Ge in mine wastes; directly influence mobilization from waste piles and subsequent availability to humans and ecosystems; and dictate metallurgical strategies to target Ge for recovery.
Interpretation of abundant seismic data suggests that Kilauea's primary conduit within the upper mantle is concentrically zoned to about 34-km depth. This zoned structure is inferred to contain a central core region of relatively higher permeability, surrounded by numerous dikes that are in intermittent hydraulic communication with each other and with the central core. During periods of relatively high magma transport, the entire cross section of the conduit is utilized. During periods of relatively low to moderate transport, however, only the central core is active. As the conduit penetrates the oceanic crust and enters the volcanic shield, it simultaneously supplies the deeper sections of the rift zones (6-to 10-km depth) and the roots of the summit reservoir with picritic magma. The rift zones at depth are inferred to be almost wholly molten and to possess a high degree of fluid continuity from Heiheiahulu in the East Rift Zone, 45 km westward through the roots of the summit magma reservoir, and well into the Southwest Rift Zone. Higher in the shield, the subcaldera magma reservoir and the shallow rift zones occupy the 2-to 4-km depth interval. Summit-differentiated olivine tholeiite (ρ ≈ 2.62 g cm −3 ) is periodically injected laterally along a horizon of neutral buoyancy within the rift zones, where the density of the magma is just balanced by the in situ density of the shield (Ryan, 1987 a , b ). Deep rift zone intrusions push seaward the deep tectonic blocks of the volcano's south flank. Shallow rift intrusions build a sheeted dike complex, inferred to be in isostatic equilibrium with the higher-density deep rift cores below. General finite element analyses are presented for the deformation and stress fields surrounding such dikes in the horizontal and vertical planes. The dike tip in two and three dimensions is surrounded by a tubular core of tensile (σ 1 , σ 2 ) and shear stress (τ max ). The displacement field is characterized by counterrotating cells on either side of the dike tip which, in vertical orientation, produce the characteristic subsidence above the dike complex, with uplift on either side, forming a ridge-trough-ridge structure. A finite element model of Kilauea's shield computes the displacement fields and principal stress (σ 1 ) distributions resulting from intrusive activity on each or both of the rift zones. Within the summit region, tensile stress lobes produced by the three-dimensional upward extension of the intrusions superpose constructively to produce calderawide regimes of tensile stress, conducive to caldera development. Parametric studies of (1) intrusion in the East Rift Zone only, (2) intrusion in the Southwest Rift Zone only, and (3) intrusion in both rift zones demonstrate their unique kinematic contributions. For case 1, the caldera undergoes a counterclockwise rotation (torque up state) conducive to the development of rightstepping en echelon eruptive fissures, as exemplified by the August 14, 1971, eruption. For case 2, the caldera undergoes a clockwise rotation (torque down state) conducive to the development of left-stepping eruptive fissures, as occurred during the December 31, 1974, eruption. For case 3, the caldera substructure is driven due southward, producing the southward migration of the upper portions of the summit magma reservoir.