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The Scientific Results volumes of the Proceedings of the Ocean Drilling Program contain specialty papers presenting the results of extensive research in various aspects of scientific ocean drilling. The authors of the papers published in this volume have enabled future investigators to gain ready access to the results of their research, and I acknowledge their contributions with thanks. Each paper submitted to a Scientific Results volume undergoes rigorous peer review by at least two specialists in the author's research field. A paper typically goes through at least one revision cycle before being accepted for publication. We seek to maintain a peer-review system comparable to those of the most highly regarded journals in the geological sciences. Each Scientific Results volume has an Editorial Review Board that is responsible for obtaining peer reviews of papers submitted to the volume. This board usually is made up of the two co-chief scientists for the cruise, the ODP staff scientist for the cruise, and one external specialist who is familiar with the geology of the area investigated. In addition, the volume has an ODP staff editor who assists with manuscripts that require English-language attention and who coordinates volume assembly. Scientific Results volumes may also contain short reports of useful data that are not ready for final interpretation. Papers of this type, which may be found together in a section in the back of the volume, are called Data Reports and include no interpretation of results. Data Report papers are read carefully by at least one specialist to make sure they are well organized, comprehensive, and discuss the techniques or procedures thoroughly. To acknowledge the contributions made by this volume's Editorial Review Board, the Board members are designated Editors of the volume and are so listed on the title page. Reviewers of manuscripts for this volume, whose efforts are so essential to the success of the publication, are listed in the front of the book, without attribution to a particular manuscript. On behalf of the Ocean Drilling Program, I extend sincere appreciation to members of the Editorial Review Boards and to the reviewers for giving their generous contribution of time and effort, which ensures that only papers of high scientific quality are published in the Proceedings .
High molecular weight aliphatic hydrocarbons were extracted from sediments at two sites (741 and 742) drilled during ODP Leg 119 in Prydz Bay. The distributions of n-alkanes and triterpenoid and steroid hydrocarbons suggest that the n- alkanes and steranes are mainly of terrestrial origin and that the hydrocarbons are immature to slightly mature in the Lower Cretaceous sediments and immature to mature in the Tertiary sediments. At Site 741, the Lower Cretaceous depositional sequence, which is generally characterized by immature hydrocarbons, is interrupted by sediment having more mature components, suggesting a change of source during part of Early Cretaceous time. At Site 742, the mature geochemical parameters of a Pliocene sample correlate with results reported elsewhere for Site 739. In all but one of the other Tertiary samples, the geochemical parameters indicate intermediate maturity. The Lower Cretaceous and Pliocene sediments average about 1.9% organic carbon, a value of interest from the point of view of potential sources of petroleum offshore of Antarctica.
Sites 679, 680, and 681 of the Ocean Drilling Program were drilled along an east-west transect across an organic-rich, diatomaceous, coastal upwelling facies that occurs as a shelf/slope lens along the Peru continental margin. Seven 60-cm-long, unsplit core sections from these sites were tested for consolidation, triaxial shear strength, and geotechnical index properties. The testing showed that the sediment has unusually high water content, Atterberg limits, degree of overconsolidation, compressibility, and shear strength. The sediment has unusually low density and grain specific gravity. Atterberg limits, grain specific gravity, compressibility, and apparent excess maximum past stress increase linearly with organic-carbon content, which also correlates positively with diatom content. Overconsolidation measured in these tests is probably not a result of sediment erosion or slumping, but rather the result of diagenesis or interparticle bonding by organic matter. High shear strengths were measured throughout, but particularly high relative shear strengths (as indicated by friction angles and degrees of dilatancy during shear) occur near 20 mbsf. This "crustlike" behavior is probably produced by early diagenesis (perhaps including dolotomization) within the upper 20 m, and is complemented by interlocking of diatoms.
Ocean Drilling Program (ODP) Site 1034 (48°38.000´N, 123°30.000´W) was drilled at a water depth of 200 m in the Saanich Inlet, an anoxic fjord on the southeastern coast of Vancouver Island, British Columbia, to a depth of 118.2 meters below seafloor (mbsf). The uppermost 50 m consists of very well-laminated (triplet varves) diatomaceous muds deposited over the past 7000 yr. Below, sediments become progressively less distinctly laminated and reflect better oxygenated bottom-water conditions. The oldest sediments recovered at Site 1034 were dated as 14 to 15 ka (see Shipboard Scientific Party, 1998). Varved sediments recovered during Leg 169S in the Saanich Inlet offer an excellent opportunity to compare the interannual variability of recent climatic elements (e.g., sea-surface temperature, salinity, precipitation) with those of late Quaternary periods that were characterized by climates appreciably different from those of today. A large amount of recent diatom data from Saanich Inlet exists, which can serve as a baseline for such comparisons: Sancetta (1989a, 1989b, 1990) investigated modern processes controlling the accumulation of diatoms and spacial and temporal trends of diatom flux in the Inlet; Sancetta and Calvert (1988) documented the annual cycle of sedimentation in the fjord. McQuoid (1995) and McQuoid and Hobson (1997) studied the modern pattern of diatom succession in the Saanich Inlet and analyzed the diatoms in laminae couplets in frozen sediment cores for the years 1900 to 1991 A.D. During the hypsithermal warming of the early Holocene (~10-6 ka), climatic conditions throughout much of northern North America were warmer and drier than those of the present (Pielou, 1991; Hebda and Whitlock, 1997), largely as a result of increased solar insolation, which peaked between 10 and 9 ka at 65°N (Berger and Loutre, 1991). Temperatures are estimated to have been 2° to 4°C warmer than today for most of this interval, reaching a maximum between ~9 and 7 ka (Hebda and Whitlock, 1997). According to Heusser (1983) and Heusser (1985), rapid warming occurred at ~10 ka in southwestern British Columbia with summer conditions that were drier and as warm or warmer than today lasting until ~6 ka. Clague and Mathewes (1989) report that treeline elevation in the southeastern coast mountains of British Columbia reached elevations that were between 60 and 130 m higher than today between 9.1 and 8.2 ka. Thompson et al. (1993) argue that the driest conditions (period of maximum summer drought) of the Holocene were reached in western North America at 9 ka. The warmer and drier conditions of this Holocene thermal maximum were gradually replaced by cooler and wetter conditions (Hebda, 1995; Hebda and Whitlock, 1997). This report describes the intra-annual variability of the diatom assemblages at Site 1034, during a 8-yr interval near 9 ka. Pollen and dinoflagellates are being studied from the same samples by R. Hebda and P. Mudie (unpubl. data).
Hydrocarbon gases (methane, ethane, propane, isobutane, «-butane, ethene, and propene) are present in Tertiary and Quaternary shelf, upper-slope, and lower-slope deposits of the Peruvian continental margin. Methane dominates the composition of the hydrocarbon gas at all 10 sites examined during Ocean Drilling Program (ODP) Leg 112. Generation of methane is regulated by the amount of sulfate in pore water. Wherever sulfate concentrations approach or equal zero, methane concentrations increase rapidly, reaching values near 100,000 /tL/L of wet sediment at eight of the 10 sites. Methane at all 10 sites results from methanogenesis, which is inhibited where sulfate is present and microbial reduction of sulfate occurs. Hydrocarbon gases heavier than methane also are present, but at much lower concentrations than methane. These hydrocarbons are thought to result from early thermal and microbial diagenesis, based on relative gas compositions and trends of concentrations with depth. With few exceptions, the results obtained in the shipboard and shore-based laboratories are comparable for methane and ethane in sediments of Leg 112. Reanalyses of canned sediments from ODP Leg 104 and from Deep Sea Drilling Project (DSDP) Legs 76 and 84 show that gas samples can be stored for as long as 8 yr, but the amounts of individual hydrocarbon gases retained vary. Nevertheless, the trends of the data sets with depth are similar for fresh and stored samples.
Geochemical studies at three ODP Leg 104 sites on the Wring Plateau help define the distribution of hydrocarbon gases in sediment of this prominent feature of the Norwegian continental margin. Low levels of hydrocarbon gas were encountered in sediment of the outer part of the plateau, but sediment of the inner part of the plateau is very gassy. The molecular composition of inner plateau gases ( > 99.9% methane) and the carbon isotopic composition of the methane (avg. = - 76%o relative to the PDB standard) clearly show that the gas is biogenic. Heavier hydrocarbon gases accompany this methane, and their presence is probably a result of both chemical and microbial low-temperature diagenesis. Although these heavier hydrocarbons were not detected in sediment of the outer part of the plateau during shipboard analyses, subsequent shore-based analyses showed that these compounds are present at very low concentrations. Methane in the gassy sediment of the inner part of the plateau may be present as gas hydrates, judging from sedimentological and inorganic geochemical considerations, but no discernible gas hydrates were recovered during drilling.
Boreholes from Island Beach, Allaire, Atlantic City, and Mays Landing, NJ provide an excellent chronology of lower to middle Eocene passive margin sequences and allow analysis of long-term sea-level changes and sedimentation patterns. These New Jersey sequences are tied directly to the geomagnetic polarity time scale through magnetostratigraphy. Integrated stratigraphy (including magnetostratigraphy, lithostratigraphy, plankton biostratigraphy, and benthic foraminiferal biofacies studies) reveals that these sections contain a relatively continuous record of lowermost Eocene to middle Eocene deposition interrupted by short hiatuses. A sequence boundary at the base of the section spans the Paleocene/Eocene boundary, representing a hiatus from 55.8 to 54.7 Ma. A second sequence boundary is associated with a hiatus from 54.0 to 53.4 Ma. A third sequence boundary is associated with a hiatus from 52.9 to 52.3 Ma. Two major unconformities occur near the lower/middle Eocene boundary at all three boreholes. The first represents a hiatus between 50.9 and ~50.5 to 49.9 Ma; the second, between ~49.6 and 48.6 Ma. Early Eocene water depths inferred from benthic foraminiferal biofacies analysis varied from 150 to 200 m and reached their maximum depth between 53.4 and 53.2 Ma. In the middle Eocene, the sedimentation record is less continuous with hiatuses from 48.3 to 47.9 Ma, 46.9 to 44.5 Ma, and 43.4 to ~41.2 Ma. A major lithofacies change from carbonate dominated to siliciclastic dominated occurred by 41.2 Ma. Of the 14 sequences inferred by Exxon for the early to middle Eocene, nine are resolvable on the New Jersey Margin and the remaining five appear to be combined with others. Thus the New Jersey record is consistent with the Exxon record for the early to middle Eocene, although the New Jersey record is better dated. Comparison of the record of sedimentation with the global δ 18 O record shows interesting parallels. It is unlikely that early Eocene sequence boundaries are the result of glacioeustasy because hiatuses from the New Jersey Coastal Plain in this interval do not match increases in the δ 18 O record. In the late middle Eocene, concomitant increases in the planktonic and benthic δ 18 O records coincide with the timing of hiatuses on the New Jersey Coastal Plain. Increases in the δ 18 O records between 43 and 41 Ma coincide with a New Jersey hiatus and a corresponding change in sedimentation type from carbonate dominated to siliciclastic dominated. We conclude that these represent evidence of the first Antarctic ice cap and the beginning of the “Icehouse” world.
Synthetic seismograms provide a crucial link between lithologic variations within a drill hole and reflectors on seismic profiles crossing the site. In essence, they provide a ground-truth for the interpretation of seismic data. Using a combination of core and logging data, we created synthetic seismograms for Ocean Drilling Program Sites 1165 and 1166, drilled during Leg 188, and Site 742, drilled during Leg 119, all in Prydz Bay, Antarctica. Results from Site 1165 suggest that coring penetrated a target reflector initially thought to represent the onset of drift sedimentation, but the lithologic change across the boundary does not show a change from predrift to drift sediments. The origin of a shallow reflector packet in the seismic line across Site 1166 and a line connecting Sites 1166 and 742 was resolved into its constituent sources, as this reflector occurs in a region of large-scale, narrowly spaced impedance changes. Furthermore, Site 1166 was situated in a fluvio-deltaic system with widely variable geology, and bed thickness changes were estimated between the site and both seismic lines.
Gas hydrates were recovered during coring by Ocean Drilling Program (ODP) Leg 112 at Sites 685 and 688 on the Peruvian outer continental margin at latitudes of 9° and 11.5°S, where water depths are 5070 and 3820 m, respectively. In addition, nearby Sites 682 and 683 yielded compelling evidence that gas hydrates are present, but gas hydrates were not directly observed there. Anomalous acoustic reflectors, known as bottom-simulating reflectors (BSRs), on marine seismic profiles from the region also provided inferential evidence that gas hydrates are present. Geothermal gradients of about 43 and 49°C/km were calculated on the basis of relations between depths to BSRs, bottom-water temperatures, and the pressure-temperature stability field of gas hydrates. Geochemical studies revealed that methane concentrations increase rapidly with depth after pore-water sulfate concentrations have been depleted. The relationship between methane and sulfate suggests that microbial processes account for the generation of methane, and the relationship between the carbon isotopic composition of methane and dissolved carbon dioxide supports this suggestion. We believe that decreasing chlorinity in pore water from squeezed sediment at the four sites results mainly from the decomposition of gas hydrates and is a dilution artifact observed as a result of the squeezing procedure. Maximum chlorinity values at or near the surface result from excess salt that comes from the formation of gas hydrates composed of freshwater. Record alkalinity attests to the intensity of diagenetic processes and has significant effects on salinity profiles at these sites. Gas hydrates were recovered at 99 and 166 meters below the seafloor (mbsf) at Site 685, and at 141 mbsf at Site 688 in Pleistocene diatomaceous mud. Methane constitutes more than 99% of the hydrocarbon gas mixture in the gas hydrates. The volumetric ratio of methane to water in the sample from Site 685 is 100, indicating that the sampled gas hydrate is either undersaturated with respect to methane or had partially decomposed during core recovery or both. The discovery of gas hydrates in lower slope deposits of the Peruvian outer continental margin extends our knowledge of gas-hydrate formation and occurrence in the Circum-Pacific region.
The Leg 104 organic geochemistry program consisted of monitoring (a) hydrocarbon gases, (b) organic and inorganic carbon, and (c) parameters resulting from Rock-Eval pyrolysis at three sites on the Vdring Plateau. The results amplify some of those obtained earlier on Deep Sea Drilling Project (DSDP) Leg 38. In a regional sense there is an inverse correlation between amounts of hydrocarbon gas and organic carbon. For example, significant concentrations of methane are present only at Site 644 in the inner part of the plateau where organic carbon contents are always less than 1%; in contrast, at Site 642 on the outer plateau, methane concentrations are very low (ppm range) whereas amounts of organic carbon approach 2%. Only at Site 644 are the environmental conditions such that methanogenesis is an active diagenetic process. Because of the importance of routine gas analyses to the Ocean Drilling Program (ODP), a procedure was devised to improve the use of Vacutainers for collection of gas samples. Comparison of methods for determining organic carbon showed that at Sites 643 and 644 Rock-Eval TOC could be used as a measure of organic carbon, but not at Site 642. Although no liquid or solid hydrocarbons were encountered at any of the sites, a catalog of potential organic geochemical contaminants was developed in anticipation of such a discovery.
Two distinct hydrogeochemical regimes currently dominate the Peruvian continental margin. One, in shallower water (150-450 m) shelf to upper-slope regions, is characterized by interstitial waters with strong positive chloride gradients with depth. The maximum measured value of 1043 mM chloride at Site 680 at ITS corresponds to a degree of seawater evaporation of ~2 times. Major ion chemistry and strontioum isotopic composition of the interstitial waters suggest that a subsurface brine that has a marine origin and is of pre-early Miocene "age," profoundly influences the chemistry and diagenesis of this shelf environment. Site 684 at ~9°S must be closest to the source of this brine, which becomes diluted with seawater and/or interstitial water as it flows southward toward Site 686 at ~13°S (and probably beyond) at a rate of approximately 3 to 4 cm/yr, since early Miocene time. The other regime, in deep water (3000-5000 m) middle to lower-slope regions, is characterized by interstitial waters with steep negative and nonsteady-state chloride gradients with depth. The minimum measured value of 454 mM chloride, at Site 683 at ITS, corresponds to —20% dilution of seawater chloride The most probably sources of these low-chloride fluids are gas hydrate dissociation and mineral (particularly clay) dehydration reactions. Fluid advection is consistent with (1) the extent of dilution shown in the chloride profiles, (2) the striking nonsteady-state depth profiles of chlorides at Sites 683 and 688 and of 87Sr/86Sr ratios at Site 685, and (3) the temperatures resulting from an average geothermal gradient of 50°C/km and required for clay mineral dehydration reactions. Strontium isotope data reveal two separate fluid regimes in this slope region: a more northerly one at Sites 683 and 685 that is influenced by fluids with a radiogenic continental strontium signature, and a southerly one at Sites 682 and 688 that is influenced by fluids with a nonradiogenic oceanic signatures. Stratigraphically controlled fluid migration seems to prevail in this margin. Because of its special tectonic setting, Site 679 at ITS is geochemically distinct. The interstitial waters are characterized by seawater chloride concentrations to —200 mbsf and deeper by a significantly lower chloride concentration of about two-thirds of the value in seawater, suggesting mixing with a meteoric water source. Regardless of the hydrogeochemical regime, the chemistry and isotopic compositions of the interstitial waters at all sites are markedly modified by diagenesis, particularly by calcite and dolomite crystallization.
We report the results of downhole stable isotopic ( ẟ 13 C org [organic carbon] and ẟ 15 N) and elemental measurements (total organic carbon [TOC], total nitrogen [TN], and carbon/nitrogen [C/N]) of sedimentary organic matter (SOM) along with stable isotopic measurements ( ẟ 18 O and ẟ 13 C) of left-coiling Neogloboquadrina pachyderma planktonic foraminifers from Ocean Drilling Program Site 1166. TOC and TN measurements indicate a large change from organic-rich preglacial sediments with primary organic matter to organic-poor early glacial and glacial sediments, with mainly recycled organic matter. Results of the stable isotopic measurements of SOM show a range of values that are typical of both marine and terrestrial organic matter, probably reflecting a mixture of the two. However, C/N values are mostly high (>15), suggesting greater input and/or preservation of terrestrial organic matter. Foraminifers are only present in glacial/glaciomarine sediments of latest Pliocene to Pleistocene age at Site 1166 (lithostratigraphic Unit I). The majority of this unit has ẟ 13 C org and TOC values that are similar to those of glacial sediments recovered at Site 1167 (lithostratigraphic Unit II) on the slope and may have the same source(s). Although the low resolution of the N. pachyderma (s.) ẟ 18 O and ẟ 13 C data set precludes any specific paleoclimatic interpretation, downcore variations in foraminifer ẟ 18 O and ẟ 13 C values of 0.5 to 1 amplitude may indicate glacial-interglacial changes in ice volume/temperature in the Prydz Bay region.
Geochemical analyses of the middle Eocene through lower Oligocene lithologic Unit IIIC (260-518 meters below sea floor [mbsf]) indicate a relatively constant geochemical composition of the detrital fraction throughout this depositional interval at Ocean Drilling Program (ODP) Site 647 in the southern Labrador Sea. The main variability occurs in redox-sensitive elements (e.g., iron, manganese, and phosphorus), which may be related to early diagenetic inability in anaerobic pore waters during bacterial decomposition of organic matter. Initial preservation of organic matter was mediated by high sedimentation rates (36 m/m.Y.). High iron (Fe) and manganese (Mn) contents are associated with carbonate concretions of siderite, manganosiderite, and rhodochrosite. These concretions probably formed in response to elevated pore-water alkalinity and total dissolved carbon dioxide (CO2) concentrations resulting from bacterial sulfate reduction, as indicated by nodule stable-isotope compositions and pore-water geochemistry. These nodules differ from those found in upper Cenozoic hemipelagic sequences in that they are not associated with methanogenesis. Phosphate minerals (carbonate-fluorapatite) precipitated in some intervals, probably as the result of desorption of phosphorus from iron and manganese during reduction. The bulk chemical composition of the sediments differs little from that of North Atlantic Quaternary abyssal red clays, but may contain a minor hydrothermal component. The silicon/ aluminum (Si/Al) ratio, however, is high and variable and probably reflects original variations in biagenic opal, much of which is now altered to smectite and/or opal CT. An increase in the sodium/potassium (Na/K) ratio in the upper Eocene corresponds to the beginning of coarser-grained feldspar flux to the site, possibly marking the onset of more vigorous deep currents. Although the Site 647 cores provide a nearly complete high-resolution, high-latitude Eocene-Oligocene record, the high sedimentation rate and somewhat unusual diagenetic conditions have led to variable alteration of benthic foraminifers and fine-fraction carbonate and have overprinted the original stable-isotope records. Planktonic foraminifers are less altered, but on the whole, there is little chance of sorting out the nature and timing of environmental change on the basis of our stable-isotope analyses.
Drilling during Leg 119 (1988) and Leg 188 (2000; Sites 1165–1167) of the Ocean Drilling Program (ODP) provides direct evidence for long- and short-term changes in Cenozoic paleoenvironments in the Prydz Bay region. Cores from across the continental margin reveal that in preglacial times the present shelf was an alluvial plain system with austral conifer woodland in the Late Cretaceous that changed to cooler Nothofagus rainforest scrub by the middle to late Eocene (Site 1166). Earliest recovered evidence of nearby mountain glaciation is seen in late Eocene–age grain textures in fluvial sands. In the late Eocene to early Oligocene, Prydz Bay permanently shifted from being a fluvio-deltaic complex to an exclusively marine continental shelf environment. This transition is marked by a marine flooding surface later covered by overcompacted glacial sediments that denote the first advance of the ice sheet onto the shelf. Cores do not exist for the early Oligocene to early Miocene, and seismic data are used to infer the transition from a shallow to normal depth prograding continental shelf with submarine canyons on the slope and channel/levees on the rise. Cores from the continental rise at Site 1165 show long-term (millions of years) early Miocene and younger decreases in sedimentation rates as well as short-term (Milankovitch periods) cyclicity between principally biogenic and terrigenous sediment supply—resulting from the cyclic presence of onshore glaciers and changes in ocean circulation. Middle Miocene transitions include rapid decreases in sedimentation rates, increased ice-rafted debris, shifts in clays and other minerals, and regional erosion of the slope and rise. These transitions may reflect enhanced glacial erosion and reduced glacial meltwater from progressively colder ice. At this time, seismic data show that depocenters began to shift from the outer continental rise to the base of the continental slope coincident with the initial stages of the glacial erosion and overdeepening of the continental shelf. During the late Miocene to early Pliocene there was a transition to greater subglacial activity on the shelf and more pronounced cyclic facies variations on the continental rise. At this time, severe glacial morphologies initiated on the shelf with the erosion of Prydz Channel and other troughs by fast-moving ice and the deposition of overcompacted glacial diamictons by slow-moving ice on adjacent banks. The Prydz trough-mouth fan also began to form with alternating deposition of debris flows (ice at shelf edge) and muddy units (reduced ice) (Site 1167). The fan also records a transition during the late Pleistocene for times younger than 780 k.y. when short-term glacial variations continued but ice reached the shelf edge only a few times. Both short-term and long-term transitions characterize the Cenozoic evolution of the Prydz Bay region from the Cretaceous nonglacial to late Neogene full-glacial paleoenvironments. These transitions are known only from ODP cores, and further insights will require additional drilling.
During Ocean Drilling Program Leg 167, the California continental margin was drilled from about 30°N to 42°N to sample high-resolution paleoceanographic and paleoclimatic records in the California Current system. Because of typically high sedimentation rates along the margin (80 to >200 m/m.y.), drilling has proved necessary to collect late Pleistocene sedimentary records that usually are sampled by standard piston cores in other oceanic regions. Triple piston coring on Leg 167 enabled us to construct continuous submillennial paleoceanographic records to about 2 Ma. In the offshore drill sites, continuous records were constructed into the Miocene. The oldest sediments recovered on Leg 167 have an age of ~14 Ma. The California margin has an active diagenetic system driven by the degradation of organic matter. Leg 167 drilling provided a means to quantify the diagenetic processes within the deep sediment column and to study the links between sediment diagenesis and primary productivity. This synthesis chapter also documents the oceanographic variability along the California margin at all time scales, from 10 3 to 10 6 yr. Millennial-scale variability is found in Santa Barbara Basin (drilled during Leg 146) and in nearby basins drilled during Leg 167. Leg 167 cores also captured millennial-scale variability in the northern and central California margin. Orbitally forced insolation changes invoke a strong response throughout the California margin. Sea-surface temperature (SST) measured by the alkenone U k' 37 paleothermometer is highly coherent with the oxygen isotope record, being cold in glacials and much warmer in interglacials. Faunal and floral plankton assemblages vary strongly on the glacial-interglacial scale. Coastal plant communities show a glacial-interglacial variability that is most pronounced in the north, near the Cordilleran Ice Sheet. Major changes in the sediments prior to the Pleistocene mark major late Neogene oceanographic events. Opaline silica burial in the middle and upper Miocene sections have step-like drops from high opal deposition in the middle Miocene. One major drop occurs at ~11 Ma and is roughly correlative with the eastern equatorial Pacific Miocene carbonate crash. A second major drop occurs at about 8 Ma, equivalent in age to the end of the Monterey Formation. A third drop occurs slightly younger than the end of the Miocene. A lower Pliocene interval, roughly from 5 to 4.2 Ma, is low in all biogenic components. It separates the Miocene high-opal sediments from upper Pliocene high-carbonate sediments. High CaCO 3 deposition occurred all along the entire California margin in the late Pliocene, but CaCO 3 burial dropped abruptly with the beginning of Northern Hemisphere glaciation (2.6 Ma).
Sedimentary extractable organic matter was analyzed at three ODP Leg 104 sites in the Norwegian Sea. Organic carbon content ranged from less than 0.1% to a maximum of 1.8%. Extractable organic matter content and unresolved complex mixture concentrations were low and randomly distributed. Low levels of aliphatic (branched and normal) and aromatic hydrocarbons were detected in all of the sediments analyzed. Total aliphatic and aromatic hydrocarbon concentrations ranged from 176 to 3,214 and 6 to 820 ppb, respectively. The concentrations of individual aliphatic (n-C15 to n-C32) and aromatic (two- to five-ring) hydrocarbons were generally less than 50 ppb and less than 10 ppb, respectively. No significant trend with sub-bottom depth was observed in either bulk organic matter or individual hydrocarbon concentrations. The predominant source of Cenozoic sedimentary hydrocarbons is concluded to be ice-rafted debris from the adjacent continent. All sites contain a mixture of recycled, mature petroleum-related and terrestrially derived hydrocarbons.