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Geologic cross section C-C' through the Appalachian basin from Erie County, north-central Ohio, to the Valley and Ridge province, Bedford County, south-central Pennsylvania

Geologic cross section C-C' is the third in a series of cross sections constructed by the U.S. Geological Survey (USGS) to document and improve understanding of the geologic framework and petroleum systems of the Appalachian basin. Cross section C-C' provides a regional view of the structural and stratigraphic framework of the Appalachian basin from north-central Ohio to the Valley and Ridge province in south-central Pennsylvania, a distance of approximately 260 miles (mi). This cross section is a companion to cross sections E-E' and D-D' that are located about 50 to 125 mi and 25 to 50 mi, respectively, to the southwest. Cross section C-C' contains much information that is useful for evaluating energy resources in the Appalachian basin. Although specific petroleum systems are not identified on the cross section, many of their key elements (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Other aspects of petroleum systems (such as the timing of petroleum generation and preferred migration pathways) may be evaluated by burial history, thermal history, and fluid flow models based on what is shown on the cross section. Cross section C-C' also provides a general framework (stratigraphic units and general rock types) for the coal-bearing section, although the cross section lacks the detail to illustrate key elements of coal systems (such as paleoclimate, coal quality, and coal rank). In addition, cross section C-C' may be used as a reconnaissance tool to identify plausible geologic structures and strata for the subsurface storage of liquid waste or for the sequestration of carbon dioxide.

Kentucky;Maryl;Ohio;Pennsylvania;Tennessee;Virgini

Water-resources activities of the U.S. Geological Survey in Pennsylvania, 1986-87

The U.S. Geological Survey 's water-resources activities in Pennsylvania are described. Some activities are topics of general interest to the water resources community while others are related to current water issues. The report also describes the mission of the Water Resources Division of the U. S. Geological Survey, and program funding, water issues, a listing of selected literature on water resources in Pennsylvania, and how to obtain reports and information. (USGS)

Open-File Report

U. S. Geological Survey programs in Pennsylvania

The U.S. Geological Survey (USGS) is involved in mapping and studying land, mineral, biological, and water resources and determining the risk from earthquakes and other natural hazards, which are of importance to the citizens of Pennsylvania. This Fact Sheet describes how the USGS is addressing some of the major environmental issues in Pennsylvania, which include availability of mineral resources; contamination of the environment by hazardous wastes; effects of coal mining, oil and gas production, and agriculture on the environment; nutrient input to streams and estuaries; and adequacy of good-quality water supplies. Information on acquiring the thousands of map, book, and aerial photographic products of the USGS also is given.

Fact Sheet

Activities of the United States Geological Survey in Pennsylvania

Since the late 1800's, when the U.S. Geological Survey first established a presence in Pennsylvania, the focus of our work has changed from general hydrologic and geologic appraisals to issue-oriented investigations; from predominantly data collection to a balanced program of data collection, interpretation, and research; and from traditional, hand-drawn mapping to digitally produced coverages with specialized themes. Yet our basic mission has not changed. It is as relevant to the resource issues of today as it was when our geologists first arrived in western Pennsylvania in 1884. Continuing in this proud heritage and tradition, the U.S. Geological Survey is moving confidently toward the next century, evolving organizationally and technologically to better meet the needs of our many constituencies. One major organizational change is the recent accession of employees from the former National Biological Service, who now form the Survey's fourth program division, the Biological Resources Division. These employees join forces with colleagues in our other three divisions: Water Resources, Geologic, and National Mapping. More than any other change in decades, the addition of this biological expertise creates new and exciting opportunities for scientific research and public service. This report provides an overview of recent activities in Pennsylvania conducted by the four program divisions and is intended to inform those interested in U.S. Geological Survey products and services. Additional information is available on our home page (at http://wwwpah2o.er.usgs.gov/). Together with numerous Federal, State, and local agencies and organizations who are our customers and partners, we at the U.S. Geological Survey look forward to providing continued scientific contributions and public service to Pennsylvania and the Nation.

Pennsylvania

Digital mapping techniques '03 - Workshop proceedings

The Digital Mapping Techniques '03 (DMT'03) workshop was attended by nearly 90 technical experts from 36 agencies, universities, and private companies, including representatives from 22 state geological surveys (see Appendix A). Although the meeting was slightly smaller than DMT'02 it was, considering the budget deficits in nearly all 50 states, very well attended. This workshop was similar in nature to the previous six meetings, held in Lawrence, Kansas (Soller, 1997), in Champaign, Illinois (Soller, 1998), in Madison, Wisconsin (Soller, 1999), in Lexington, Kentucky (Soller, 2000), in Tuscaloosa, Alabama (Soller, 2001), and in Salt Lake City, Utah (Soller, 2002). This year's meeting was hosted by the Pennsylvania Geological Survey, from June 1-4, 2003, on the Millersville University campus in Millersville, Pennsylvania. As in the previous meetings, the objective was to foster informal discussion and exchange of technical information. This objective was well met, as attendees continued to share and exchange knowledge and information, and to renew friendships and collegial work begun at past DMT workshops. All the DMT workshops have been coordinated by the Association of American State Geologists (AASG) and U.S. Geological Survey (USGS) Data Capture Working Group, which was formed in August 1996, to support the AASG and the USGS in their effort to build a National Geologic Map Database (see Soller and Berg, this volume, and <http://ncgmp.usgs.gov/ngmdbproject/ standards/datacapt/>). The Working Group was formed because increased production efficiencies, standardization, and quality of digital map products were needed for the database— and the State and Federal geological surveys—to provide more high-quality digital maps to the public. At the 2003 meeting, oral and poster presentations and special discussion sessions emphasized 1) methods for creating and publishing map products (here, "publishing" includes Web-based release); 2) digital cartographic techniques, 3) analytical GIS techniques; 4) continued development of the National Geologic Map Database; 5) progress toward building and implementing a standard geologic map data model and standard science language, and 6) the need to archive both the published products and the data and observational data that support it.

Open-File Report

Evaluation of radon occurrence in groundwater from 16 geologic units in Pennsylvania, 1986–2015, with application to potential radon exposure from groundwater and indoor air

Results from 1,041 groundwater samples collected during 1986‒2015 from 16 geologic units in Pennsylvania, associated with 25 or more groundwater samples with concentrations of radon-222, were evaluated in an effort to identify variations in radon-222 activities or concentrations and to classify potential radon-222 exposure from groundwater and indoor air. Radon-222 is hereafter referred to as “radon.” Radon concentrations in groundwater greater than or equal to the proposed U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) for public-water supply systems of 300 picocuries per liter (pCi/L) were present in about 87 percent of the water samples, whereas concentrations greater than or equal to the proposed alternative MCL (AMCL) for public water-supply systems of 4,000 pCi/L were present in 14 percent. The highest radon concentrations were measured in groundwater from the schists, gneisses, and quartzites of the Piedmont Physiographic Province. In this study, conducted by the U.S. Geological Survey in cooperation with the Pennsylvania Department of Health and the Pennsylvania Department of Environmental Protection, groundwater samples were aggregated among 16 geologic units in Pennsylvania to identify units with high median radon concentrations in groundwater. Graphical plots and statistical tests were used to determine variations in radon concentrations in groundwater and indoor air. Median radon concentrations in groundwater samples and median radon concentrations in indoor air samples within the 16 geologic units were classified according to proposed and recommended regulatory limits to explore potential radon exposure from groundwater and indoor air. All of the geologic units, except for the Allegheny (Pa) and Glenshaw (Pcg) Formations in the Appalachian Plateaus Physiographic Province, had median radon concentrations greater than the proposed EPA MCL of 300 pCi/L, and the Peters Creek Schist (Xpc), which is in the Piedmont Physiographic Province, had a median radon concentration greater than the EPA proposed AMCL of 4,000 pCi/L. Median concentrations of radon in groundwater and indoor air were determined to differ significantly among the geologic units (Kruskal-Wallis test, significance probability, p<0.001), and Tukey’s test indicated that radon concentrations in groundwater and indoor air in the Peters Creek Schist (Xpc) were significantly higher than those in the other units. Also, the Peters Creek Schist (Xpc) was determined to be the area with highest potential of radon exposure from groundwater and indoor air and one of two units with the highest percentage of population assumed to be using domestic self-supplied water (81 percent), which puts the population at greater potential of exposure to radon from groundwater. Potential radon exposure determined from classification of geologic units by median radon concentrations in groundwater and indoor air according to proposed and recommended regulatory limits is useful for drawing general conclusions about the presence, variation, and potential radon exposure in specific geologic units, but the associated data and maps have limitations. The aggregated indoor air radon data have spatial accuracy limitations owing to imprecision of geocoded test locations. In addition, the associated data describing geologic units and the public water supplier’s service areas have spatial and interpretation accuracy limitations. As a result, data and maps associated with this report are not recommended for use in predicting individual concentrations at specific sites nor for use as a decision-making tool for property owners to decide whether to test for radon concentrations at specific locations. Instead, the data and maps are meant to promote awareness regarding potential radon exposure in Pennsylvania and to point out data gaps that exist throughout the State.

Pennsylvania

Baseline groundwater quality from 20 domestic wells in Sullivan County, Pennsylvania, 2012

Water samples were collected from 20 domestic wells during August and September 2012 and analyzed for 47 constituents and properties, including nutrients, major ions, metals and trace elements, radioactivity, and dissolved gases, including methane and radon-222. This study, done in cooperation with the Pennsylvania Department of Conservation and Natural Resources, Bureau of Topographic and Geologic Survey (Pennsylvania Geological Survey), provides a groundwater-quality baseline for central and southern Sullivan County prior to drilling for natural gas in the Marcellus Shale. The analytical results for the 20 groundwater samples collected during this study indicate that only one constituent (gross-alpha radioactivity) in one sample was found to exceed the U.S. Environmental Protection Agency (USEPA) primary drinking water maximum contaminant level (MCL). Water samples from 85 percent of the sampled wells exceeded the proposed USEPA MCL of 300 picocuries per liter (pCi/L) for radon-222; however, only two water samples (10 percent of sampled wells) exceeded the proposed USEPA alternate maximum contaminant level (AMCL) of 4,000 pCi/L for radon-222. In a few samples, the concentrations of total dissolved solids, iron, manganese, and chloride exceeded USEPA secondary maximum contaminant levels (SMCL). In addition, water samples from two wells contained methane concentrations greater than 1 milligram per liter (mg/L). In general, most of the water-quality problems involve aesthetic considerations, such as taste or odor from elevated concentrations of total dissolved solids, iron, manganese, and chloride that develop from natural interactions of water and rock minerals in the subsurface. The total dissolved solids concentration ranged from 31 to 664 mg/L; the median was 130 mg/L. The total dissolved solids concentration in one water sample exceeded the USEPA SMCL of 500 mg/L. Chloride concentrations ranged from 0.59 to 342 mg/L; the median was 12.9 mg/L. The concentration of chloride in one water sample exceeded the USEPA SMCL of 250 mg/L. Concentrations of dissolved iron ranged from less than 3.2 to 6,590 micrograms per liter (&micro;g/L); the median was 11.5 &micro;g/L. The iron concentration in samples from 20 percent of the sampled wells exceeded the USEPA SMCL of 300 &micro;g/L. Concentrations of dissolved manganese ranged from less than 0.13 to 1,710 &micro;g/L; the median was 38.5 &micro;g/L. The manganese concentration in samples from 35 percent of the sampled wells exceeded the USEPA SMCL of 50 &micro;g/L. Activities of radon-222 ranged from 169 to 15,300 picocuries per liter (pCi/L); the median was 990 pCi/L. The gross alpha-particle radioactivity ranged from below detection to 33 pCi/L; the median was 1.5 pCi/L. The gross alpha-particle radioactivity of one water sample exceeded the USEPA MCL of 15 pCi/L. Concentrations of dissolved methane ranged from less than 0.001 to 51.1 mg/L. Methane was not detected in water samples from 13 wells, and the methane concentration was less than 0.07 mg/L in samples from five wells. The highest dissolved methane concentrations were 4.1 and 51.1 mg/L, and the pH of the water from both wells was greater than 8. Water samples from these wells were analyzed for isotopes of carbon and hydrogen in the methane. The isotopic ratio values fell in the range for a thermogenic (natural gas) source. The water samples from these two wells had the highest concentrations of arsenic, boron, bromide, chloride, fluoride, lithium, molybdenum, and sodium of the 20 wells sampled.

Pennsylvania

Geologic cross section A–A′ through the Appalachian basin from the southern margin of the Ontario Lowlands province, Genesee County, western New York, to the Valley and Ridge province, Lycoming County, north-central Pennsylvania

Introduction Geologic cross section A–A′ is the fifth in a series of cross sections constructed by the U.S. Geological Survey (USGS) to document and improve understand­ing of the geologic framework and petroleum systems of the Appalachian basin. Cross section A–A′ provides a regional view of the structural and stratigraphic frame­work of the Appalachian basin from the southern mar­gin of the Ontario Lowlands province in western New York, across the Allegheny Plateau province of central New York and north-central Pennsylvania, to the Valley and Ridge province in north-central Pennsylvania, a dis­tance of approximately 176 miles. This cross section is a companion to cross sections E–E′, D–D′, C–C′ , and I–I′ that are located approximately 100 to 500 miles to the southwest. Cross section A–A′ complements earlier geologic or strati­graphic cross sections through the central New York and north-central Pennsylvania part of the Appalachian basin. Although some of these other cross sections show more structural and stratigraphic detail, they are of more limited extent geographically and stratigraphically. Cross section A–A′ contains much information that is useful for evaluating energy resources in the Appalachian basin. Although the Appalachian basin petroleum systems are not shown on the cross section, many of their key elements (such as source rocks, reservoir rocks, seals, and traps) can be inferred from lithologic units, unconformities, and geologic structures shown on the cross section. Important oil- and gas-bearing formations like the Oriskany Sandstone, Medina Group sandstones, Tuscarora Sandstone, and the Marcellus and Utica Shales are present on cross-section A–A′ .

New York, Pennsylvania

Assessment of severity and distribution of corrosive ground water in Pennsylvania

Relations between corrosive ground water, water chemistry, and geology in Pennsylvania were evaluated by use of a modified version of the Langelier Saturation Index (LSIsn) and a geologic contact dataset in a Geographic Information System. Water-chemistry information for water samples collected from 4,839 combined private and public-supply wells from 1900 to 1993 was used to calculate the LSIsn. Thirty-eight lithologic subgroups within four major rock types-carbonate, siliciclastic, crystalline, and unconsolidated-in Pennsylvania were grouped together if the mean of ranked LSIsn values were not significantly different. A water is considered corrosive if the LSIsn value is negative, preventing the precipitation of calcium carbonate, therefore, allowing corrosive reactions with the interior of piping systems. Statistical tests of the LSIsn values show the least corrosive waters are in the carbonate lithologic subgroup, and the most corrosive waters are in the quartzite lithologic subgroup. Approximately 58 percent of the 4,839 LSIsn values were considered moderately to extremely corrosive. A map showing the location of 4,839 wells and associated corrosivity range within 11 lithologic subgroups will aid in identifying potential areas of corrosive ground water in Pennsylvania.

Open-File Report

Evaluation of agricultural best-management practices in the Conestoga River headwaters, Pennsylvania: Characterization of surface-runoff and ground-water quantity and quality in a small carbonate basin near Churchtown, Pennsylvania, prior to terracing and implementation of nutrient management: Water-quality study of the Conestoga River headwaters, Pennsylvania

The U.S. Geological Survey, in cooperation with the Pennsylvania Department of Environmental Protection1 , conducted a study as part of the U.S. Department of Agriculture's Rural Clean Water Program to determine the effects of agricultural best-management practices on surface-water and ground-water quality in the Conestoga River headwaters basin. This report describes Field-Site 1 and characterizes the surface-runoff and ground-water quantity and quality at the site from January 1983 through September 1984, before the implementation of terracing and nutrient-management best-management practices. The 22.1-acre site, part of two dairy farms, was cropland used primarily for the production of corn and alfalfa, and is underlain by carbonate rock. During the 21-month study period, 91.2 inches of precipitation fell, of which 66 percent occurred during the 1984 water year. Of the 169 storms of 0.10 inch or larger, 97 produced measurable runoff. The average annual application of nutrients to the 14.4 acres of cornfields was 410 pounds per acre of nitrogen and 110 pounds per acre of phosphorus. About three times more nutrients were applied during 1984 water year than during the 1983 water year. The approximate soil-nitrate concentration as nitrogen for the study period was 8.2 milligrams per kilogram in the top 8 inches of soil. Runoff for the study period totalled 714,000 cubic feet, or 9.8 percent of total precipitation. Eighty-eight percent of the runoff occurred during the 1984 water year. Regression analyses indicate that total runoff was controlled primarily by total precipitation amounts during storms and by antecedent moisture conditions; mean event and maximum instantaneous discharges are controlled by precipitation intensity and by antecedent moisture conditions. Regression analyses also suggest that crop cover on the corn acreage affected runoff amounts and rates. Mean concentrations in runoff ranged from 24 to 73,000 milligrams per liter for suspended sediment, 0.45 to 24 milligrams per liter for total phosphorus, and 1.5 to 55 milligrams per liter for total nitrogen. Of the total nitrogen in instantaneous runoff samples, a median of 72 percent was total organic nitrogen. Results of multiple regression analyses suggest that mean nitrogen concentrations in runoff (1) increased with increased surface-nitrogen applications made prior to runoff, and (2) were diluted with increased precipitation duration. Runoff from storms on frozen ground produced the highest loads of nitrogen in runoff. Over the 21-month study period, an estimated 258 tons of suspended sediment, 314 pounds of nitrogen, and 176 pounds of phosphorus were transported with runoff from the site. Of this, 88 percent of the nitrogen and phosphorus loads and 94 percent of the suspended-sediment load were discharged during the wet 1984 water year. The loads for the study period represent 2.5 percent of the total nitrogen and 5.5 percent of the total phosphorus applied to the site as manure and commercial fertilizer. The ground-water basin at the site is slightly larger than the surface-water basin. Ground-water levels, except at one well, responded quickly to recharge; water levels peaked several hours to a day after precipitation. Surface-applied materials moved rapidly to the water table through macropores and slowly by transport through micropores in the unsaturated zone. Median concentrations of dissolved nitrate ranged from 9.2 to 13 milligrams per liter as nitrogen for ground-water samples collected monthly from five wells and a spring. Dissolved nitrate comprised 93 percent (median percentage) of the total nitrogen in ground-water samples. The effect of recharge on ground-water nitrate concentrations was affected by variations in nutrient availability at the land surface and in the unsaturated zone. A lag time of 1 to 3 months was observed between the time that nitrogen was applied to the land surface and local maximums in nitrate concentrations were detected in ground water unaffected by recharge events. Approximately 3,187,000 cubic feet of ground water and an associated 2,200 pounds of nitrate-nitrogen discharged from the site during the study period. For the study period, 42 percent of the precipitation recharged to ground water, 10 percent became runoff, and 48 percent evapotranspired. Inputs of nitrogen to the study area were estimated to be 93 percent from manure, 5 percent from commercial fertilizer, and 2 percent from precipitation. Nitrogen outputs from the system were estimated to be 38 percent to crop uptake, 39 percent to volatilization, 20 percent to ground-water discharge, and 3 percent to surface runoff.

Pennsylvania