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U.S. Geological Survey unconventional petroleum systems research in south Mississippi: Observations on burial history and thermal maturity in the Cretaceous

Shale hydrocarbon ‘resource’ plays have revolutionized the United States energy mix over the last 5 years. These plays are diverse in lithology and age but share the common feature of occurring in ‘tight’ formations which require hydraulic (hydro-) fracturing for economic flow rates. In general, economic success requires an organic-rich reservoir with a quartz- or carbonate-rich mineralogy that responds to artificial stimulation by fracturing. The U.S. Geological Survey (USGS) is tasked with estimating the quantity and quality of undiscovered hydrocarbons reservoired in shales. In support of that mission, we began an investigation of unconventional petroleum systems in the southern part of the Mississippi Salt Basin in 2012, building on earlier reconnaissance work that identified this area as potentially prospective for ‘shale’ gas (Enomoto et al., 2012). While our recent studies (Valentine et al., 2014a; Hackley et al., 2014) have suggested poor ‘shale’ gas prospectivity (due to low organic content, low porosity, high clay content, and significant depth), at least for the Aptian section, they also have generated a wealth of new information about thermal maturity in the Cretaceous of south Mississippi. In addition, our work to-date has set the stage for future USGS evaluation of unconventional hydrocarbons reservoired in the Upper Cretaceous Tuscaloosa Marine Shale (TMS). Here, we summarize recent USGS thermal maturity studies in the south Mississippi Salt Basin.

Mississippi

Quantifying the uncertainty in site amplification modeling and its effects on site-specific seismic-hazard estimation in the upper Mississippi embayment and adjacent areas

The Mississippi embayment, located in the central United States, and its thick deposits of sediments (over 1 km in places) have a large effect on earthquake ground motions. Several previous studies have addressed how these thick sediments might modify probabilistic seismic-hazard maps. The high seismic hazard associated with the New Madrid seismic zone makes it particularly important to quantify the uncertainty in modeling site amplification to better represent earthquake hazard in seismic-hazard maps. The methodology of the Memphis urban seismic-hazard-mapping project (Cramer et al., 2004) is combined with the reference profile approach of Toro and Silva (2001) to better estimate seismic hazard in the Mississippi embayment. Improvements over previous approaches include using the 2002 national seismic-hazard model, fully probabilistic hazard calculations, calibration of site amplification with improved nonlinear soil-response estimates, and estimates of uncertainty. Comparisons are made with the results of several previous studies, and estimates of uncertainty inherent in site-amplification modeling for the upper Mississippi embayment are developed. I present new seismic-hazard maps for the upper Mississippi embayment with the effects of site geology incorporating these uncertainties.

Bulletin of the Seismological Society of America

Late cretaceous and subsequent structural development of the northern Mississippi Embayment area

During early Late Cretaceous the area of the northern Mississippi Embayment was occupied by a structural and topographic dome standing nearly 1000 feet above sea level. Rocks as old as Cambrian were exposed on its crest. Downwarping of the dome, which commenced in Late Cretaceous time, resulted in the development of the Mississippi Embayment syncline, now filled with sediments of Cretaceous , Paleocene, and Eocene age. The flanks of the Mississippi Embayment syncline slope uniformly about 30 feet per mile. Most of the bending occurred near the synclinal axis, which generally follows the present course of the Mississippi River. Faults cutting the Paleozoic basement and, in some areas, extending upward into the overlying younger rocks resulted from superposition of the narrow synclinal bend across the now-buried structural high. Adjustment also probably occurred by faulting of Paleozoic rocks along the Tennessee River, where the eastern flank of the syncline was bent downward. As a result of structural movements during the Cretaceous and later periods, the old dome has been depressed beneath the Mississippi Embayment and now forms the Pascola arch connecting the Ozark and Nashville domes.

MIssissippi

Binary coefficients and clustering in biostratigraphy

The large data arrays common in biostratigraphy make subjective groupings difficult. Because of this, biostratigraphers have commonly based conclusions on the occurrences of relatively few species. The use of binary similarity coefficients, cluster analysis techniques, and digital computers allows a polythetic approach to biostratigraphy. The approach is free of circular and a priori reasoning in that it is established that assemblage zones (major clusters in a dendrogram) are present before the biostratigraphic utility of various taxa for the recognition of the zones is determined. A measure for determining the biostratigraphic fidelity of a species for established zones is proposed. Published data on the distribution of ostracodes and foraminifers from the Eocene and Oligocene of Mississippi and Alabama are used to demonstrate a method of using coefficients and clustering in establishing a zonation.

Alabama, Mississippi

Late quaternary geologic history of the lower Chippewa Valley, Wisconsin

The lower Chippewa Valley in west-central Wisconsin extends 65 miles from the Cary terminal moraine in Chippewa County to the Mississippi River Valley. The Chippewa Valley and its tributaries were filled with a valley train of sand and gravel during the maximum stand of the Cary ice, and entrenchment of this deposit has formed the Wissota terrace, a prominent geomorphic feature that can be traced the length of the valley. Several lower terraces in the valley indicate progressive downcutting of the Wissota terrace sediments. Erosion and deposition in the Mississippi Valley are closely linked to the post-Cary history of the lower Chippewa Valley, for these factors controlled the outlet level of the Chippewa River. This outlet was substantially lower than at present throughout much of post-Cary Pleistocene and early Recent time. The modern Chippewa River has built a delta into the Mississippi Valley. The Chippewa River is aggrading the lower part of its valley, a meandering river is slowly eroding the central part; stream erosion in the upper part is restricted by sills of hard bedrock.

Wisconsin

Correlation of the Carrizo Sand in Arkansas and adjacent states

The Carrizo Sand (Eocene), the basal unit of the Claiborne Group, can be recognized in the subsurface throughout much of southeastern Arkansas and is correlated with the Carrizo Sand of Louisiana and the Meridian Sand Member of the Tallahatta Formation of Mississippi. The term Carrizo Sand is appropriate for use in Arkansas , as the stratigraphic terminology most workers apply to the Claiborne Group in Arkansas conforms with the terminology of Louisiana. A surface exposure of the Carrizo Sand in Arkansas is lithologically identical with described exposures of the Carrizo in northwestern Louisiana.

Arkansas, Louisiana, Mississippi, Tennessee

Tuscaloosa formation in Tennessee

Late Cretaceous Tuscaloosa Formation occurs as discontinuous remnants that cap many of the ridges in the Western Highland Rim. Typically the formation consists of well-rounded, poorly sorted chert gravel which is trimodal in size distribution. The gravel fraction (mode 15 to 40+ mm) consists of Devonian and Mississippian chert and a small percentage of sandstone pebbles. The medium sand fraction (mode 0.5 mm) consists mainly of angular to well-rounded chert grains developed by attrition during transport. Well-rounded and frosted quartz grains also are present. The fine fraction (mode 0.15 mm) consists of clay, authi-genic (?) mica, and quartz. At its eastern limit the Tuscaloosa is locally well sorted and contains quartz pebbles and a large proportion of quartz sand. Also present in the same area are well-sorted, heavy-mineral-bearing sands and bimodal (0.04, 0.2 mm) siltstone, which contains sand-sized pellet aggregates and fragmentary plant fossils. The finest fraction (less than 0.044 mm) of both eastern and western facies of the Tuscaloosa consists of 60-80 per cent quartz, 5-30 per cent kaolin, and 5-30 per cent montmorillonite, all of which are present in Devonian and Mississippian bedrock. Minor exotic constituents include volcanic(?) glass and heavy minerals. The Mississippian chert gravel in the Tuscaloosa is of local origin, but the Devonian chert was transported from a western source. Other components from a western source are sandstone pebbles and frosted sand grains, both of which probably were derived from Cambrian or Ordovician formations that cropped out on the Pascola arch, an eastward-sloping extension of the Ozark dome. Quartz pebbles, heavy minerals, and some of the angular quartz sand present at the eastern edge of the Tuscaloosa may have been derived from Pennsylvanian sandstone and conglomerates that cropped out north and south of the Pascola arch. Most of the Tuscaloosa Formation is believed to be of nonmarine origin, deposited on the eastward-sloping flank of the Pascola arch. The eastern facies of the Tuscaloosa is believed to be partly marine in origin, the exotic components having been swept in by longshore currents. During deposition of the Tuscaloosa , the Ozark dome and the Cincinnati arch were connected by the Pascola arch, which is now deeply buried beneath the Mississippi Embayment, At that time the Pascola arch stood structurally about 3000 feet higher than at present, and its structural shape and dimensions were comparable to the present Nashville dome. During deposition of the Tuscaloosa the Nashville dome was structurally about 1000 feet lower than at present, and its crest probably was submerged beneath the sea.

Tennessee

Age, genesis, and paleoclimatic interpretation of the Sangamon/Loveland complex in the Lower Mississippi Valley, USA

For more than a century, the Sangamon paleosol (the Sangamon) has been an integral part of geologic and pedologic investigations in the central United States, including the Upper Mississippi and Lower Missouri River Valleys. Compositional, pedologic, micromorphologic, stratigraphic, and age data indicate that the prominent reddish paleosol developed in silt-rich deposits of the Lower Mississippi Valley, from southernmost Illinois to northwestern Mississippi, represents multiple periods of soil formation, and is wholly or in part time equivalent to the Sangamon of the central United States. Thermoluminescence data, for localities where the Sangamon developed in loess, indicate that the primary period of loess deposition was from 190 to 130 ka (oxygen isotope stage, OIS6), that loess deposition continued intermittently from 130 to 74 ka (OIS5), and that deposition was wholly or in part coeval with Loveland loess deposition in the central United States. Beryllium-10, chemical, and pedologic data indicate that in the Lower Mississippi Valley: (1) the Sangamon represents a minimum time period of 60-80 k.y.; (2) there were at least two periods of soil formation, ca. 130-90 ka and 74-58 ka (OIS4); and (3) rates of weathering and pedogenesis equaled or exceeded the net loess-accumulation rate until at least 46 ka (OIS3) and resulted in development of a paleosol in the overlying basal Roxana Silt. Along a N-S transect from southern Illinois to western Mississippi, Sangamon macroscopic characteristics as well asthe micro-morphology, chemistry, and mineralogy, suggest a regional paleoclimate during periods of soil formation that: (1) was warm to hot, with a wider range in temperature, precipitation, and evapotranspiration than present; (2) had seasonal to decadal or longer periods of drought; and (3) had down-valley (southward) trends of increasing temperature and precipitation and decreasing seasonality and variation in annualto decadal precipitation. ?? 2011 Geological Society of America.

Geological Society of America Bulletin

Origin of a classic cratonic sheet sandstone: Stratigraphy across the Sauk II-Sauk III boundary in the Upper Mississippi Valley

The origin of cratonic sheet sandstones of Proterozoic and early Paleozoic age has been a long-standing problem for sedimentologists. Lower Paleozoic strata in the Upper Mississippi Valley are best known for several such sandstone bodies, the regional depositional histories of which are poorly understood. We have combined outcrop and subsurface data from six states to place the Upper Cambrian Wonewoc (Ironton and Galesville) Sandstone in a well-constrained stratigraphic framework across thousands of square kilometers. This framework makes it possible for the first time to construct a regional-scale depositional model that explains the origin of this and other cratonic sheet sandstones.

Geological Society of America Bulletin

Seismic velocity model of the central United States (Version 1): Description and simulation of the 18 April 2008 Mt. Carmel, Illinois, Earthquake

We have developed a new three‐dimensional seismic velocity model of the central United States (CUSVM) that includes the New Madrid Seismic Zone (NMSZ) and covers parts of Arkansas, Mississippi, Alabama, Illinois, Missouri, Kentucky, and Tennessee. The model represents a compilation of decades of crustal research consisting of seismic, aeromagnetic, and gravity profiles; geologic mapping; geophysical and geological borehole logs; and inversions of the regional seismic properties. The density, P ‐ and S ‐wave velocities are synthesized in a stand‐alone spatial database that can be queried to generate the required input for numerical seismic‐wave propagation simulations. We test and calibrate the CUSVM by simulating ground motions of the 18 April 2008 M w 5.4 Mt. Carmel, Illinois, earthquake and comparing the results with observed records within the model area. The selected stations in the comparisons reflect different geological site conditions and cover distances ranging from 10 to 430 km from the epicenter. The results, based on a qualitative and quantitative goodness‐of‐fit (GOF) characterization, indicate that both within and outside the Mississippi Embayment the CUSVM reasonably reproduces: (1) the body and surface‐wave arrival times and (2) the observed regional variations in ground‐motion amplitude, cumulative energy, duration, and frequency content up to a frequency of 1.0 Hz. In addition, we discuss the probable structural causes for the ground‐motion patterns in the central United States that we observed in the recorded motions of the 18 April Mt. Carmel earthquake.

Illinois

Q for P waves in the sediments of the Virginia Coastal Plain

The seismic quality factor Q for P waves in Atlantic Coastal Plain sediments is estimated using data from the 2004 U.S. Geological Survey seismic survey in eastern Virginia. The estimates are based on spectral ratios derived from reflections and sediment-guided P waves in Late Cretaceous and Tertiary sediments within the annular trough of the Late Eocene Chesapeake Bay impact structure. The estimates of Q for the frequency range of 10-150 Hz are from 75 to 100, with the best estimate of 80 based on multichannel stacking of spectral ratios from receivers in the offset range of 200-2000 m. This result is approximately a factor of 2 larger than the results previously reported for the Charleston, South Carolina, area, and it is approximately one-half of that recently reported for the Mississippi Embayment.

Bulletin of the Seismological Society of America

Studies of pre-Selma Cretaceous core samples from the outcrop area in western Alabama

In 1954 four core holes were drilled in the pre-Selma Cretaceous strata of the Alabama Coastal Plain in order to get unweathered samples within a few miles of the outcrops. During the next few years several specialists studied the cores, and their reports are published as consecutive parts of this bulletin. Watson H. Monroe, who spent many years studying the Coastal Plain strata in Alabama and Mississippi, conceived and supervised the drilling and planned the later studies. His earlier published report (W. H. Monroe, 1955, Cores of pre-Selma Cretaceous rocks in the outcrop area in western Alabama: Gulf Coast Geol. Societies Trans., v. 5, p. 11-37) contains a brief description of the stratigraphy, together with logs and other information regarding the core holes, and he has provided the introductory chapter to this bulletin. Richard E. Bergenback studied the petrology of the cores, which included finding the distribution of grain sizes, determining the mineralogy of the grains and the matrix of the sediments, and having X-Ray identifications made of the clay minerals. Norman F. Sohl studied the mollusks and other large fossils obtained from the cores and compared them with other faunal suites collected in Alaban1a and Texas. Esther R. Applin studied the sparse microfauna, comparing it with faunas obtained from deep wells downdip in Georgia, Alabama, and Mississippi and with outcrop samples fron1 Texas, and has described a new species of Foraminifera. Estella B. Leopold and Helen M. Pakiser obtained a large pollen and spore assemblage by digesting carbonaceous layers of some of the cores in acid; this flora includes much new material, which is not described here. The Bergenback, Sohl, and Applin reports discuss the probable environment in which the sediments accumulated. Louis C. Conant, who spent several years studying and mapping these sediments, has written a summary chapter integrating some of the surface and subsurface information. Quarter-cuts of the cores belonging to the U.S. National Museum have been deposited on indefinite loan with the Alabama Geological Survey at University, Ala., and with the Shell Oil Co. at Jackson, Miss. They are available there for inspection and study.

Bulletin

Correlation of the outcropping cretaceous formations of the Atlantic and Gulf Coastal Plain and trans-Pecos Texas

This is Number 9 of a series of correlation charts prepared by the Committee on Stratigraphy of the National Research Council, which will cover the post-Proterozoic sedimentary formations of North America. For general information about the project the reader is referred to the general introduction preceding this paper. The senior author, Lloyd W. Stephenson, is responsible for that part of the chart treating of the Upper Cretaceous series in the Atlantic and Gulf Coastal Plain (exceptions noted below) and the Lower Cretaceous series of the North Atlantic Coastal Plain; with respect to the Upper Cretaceous his presentation is based largely on his personal knowledge of the paleontology and stratigraphy of the area, gained from field and laboratory studies ranging from reconnaissance to detailed; all published information has been considered, and much of it utilized, but it is not practicable to include a complete bibliography. References are given to papers presenting views differing from those of the author, and to recent papers not yet listed in bibliographies. A complete bibliography of Texas geology through 1932 is given by Sellards (1933, p. 819-965). Watson H. Monroe has collaborated in the preparation of that part of the chart showing therelations of the Upper Cretaceous units in Alabama and Mississippi. The classification shown in the Upper Cretaceous part of the Delaware column is based on a recently published paper by Charles W. Carter (1937, p. 237-281). Philip B. King is responsible for the remainder of the chart covering the Lower Cretaceous (Comanche series) of central Texas (largely compiled from published sources) and all of the Cretaceous in trans-Pecos Texas (from personal knowledge and published sources). In March 1941 this part of the chart was checked by R. W. Imlay, and changes were made by King at his suggestion. References to the more important literature are given. In a correlation chart of this kind, in which age equivalencies are expressed by horizontal lining, it is obviously impossible to indicate relative thicknesses by vertical spacing. Hiatuses are indicated by vertical lining. The red-line overprint is intended to indicate certain important lithologic and faunal boundaries, and to assist the eye in recognizing the age relationships of the geologic units

Geological Society of America Bulletin

Near-surface structural model for deformation associated with the February 7, 1812, New Madrid, Missouri, earthquake

The February 7, 1812, New Madrid, Missouri, earthquake (M [moment magnitude] 8) was the third and final large-magnitude event to rock the northern Mississippi Embayment during the winter of 1811–1812. Although ground shaking was so strong that it rang church bells, stopped clocks, buckled pavement, and rocked buildings up and down the eastern seaboard, little coseismic surface deformation exists today in the New Madrid area. The fault(s) that ruptured during this event have remained enigmatic. We have integrated geomorphic data documenting differential surficial deformation (supplemented by historical accounts of surficial deformation and earthquake-induced Mississippi River waterfalls and rapids) with the interpretation of existing and recently acquired seismic reflection data, to develop a tectonic model of the near-surface structures in the New Madrid, Missouri, area. This model consists of two primary components: a north-northwest–trending thrust fault and a series of northeast-trending, strike-slip, tear faults. We conclude that the Reelfoot fault is a thrust fault that is at least 30 km long. We also infer that tear faults in the near surface partitioned the hanging wall into subparallel blocks that have undergone differential displacement during episodes of faulting. The northeast-trending tear faults bound an area documented to have been uplifted at least 0.5 m during the February 7, 1812, earthquake. These faults also appear to bound changes in the surface density of epicenters that are within the modern seismicity, which is occurring in the stepover zone of the left-stepping right-lateral strike-slip fault system of the modern New Madrid seismic zone.

Missouri

Comparative hydrogeology: An example of its use

As a start toward needed classifications of hydrogeologic settings, a type of setting is described. The setting includes areas where soluble materials are exposed to considerable recharge from precipitation and where both the topographic relief and permeability are inappreciable. Typical areas of this setting are (1) the Black Belt of the Coastal Plain of Alabama and Mississippi, underlain by chalk of the Selma Group, and (2) a 25-sq-mi area near Harrisburg, Cabarrus County, North Carolina, underlain by gabbro in the Piedmont province. Hydrologic conditions that may be inferred and that are easily discernible from this type of setting include: excessive evapotranspiration, low water-table gradient, water table near land surface, thin soils, ground-water movement being almost inappreciable, and the zone of movement being almost limited to a thin zone that includes the contact between the soil and rock, inappreciable ground-water discharge to streams leading, in turn, to a low base flow in streams, low drainage density, and subsurface water relatively high in dissolved mineral matter. Evaluation of the hydrogeologic setting described leads inductively into the undeveloped field of comparative hydrology, which represents a quick useful means of discerning the significance of processes and principles in particular environments. The setting reveals the significance of solution by subsurface water in developing some plains. Comparative hydrology, using the described setting and typical karst settings as examples, allows an advanced analysis of some pertinent factors.

Alabama, Mississippi, North Carolina

Seismic background noise levels across the continental United States from USArray Transportable Array: The influence of geology and geography

Since 2004, the most complete estimate of background noise levels across the continental U.S. was attained using 61 broadband seismic stations to calculate power spectral density (PSD) probability density functions. To improve seismic noise estimates across the U.S., we examine vertical component seismic data from the EarthScope USArray Transportable Array seismic network that rolled across the U.S. and southeastern Canada between 2004 and 2015 and form a large (10 TB) PSD database from 1679 stations that contains no smoothing or binning of the spectral estimates. Including station outages, our database has a mean of 98.9% data completeness, and we present maps showing the spatial and temporal variability of seismic noise in six bands of interest between 0.2- and 75-s period. At 0.2 s period, seismic noise across the eastern U.S. is predominantly anthropogenically generated and may be subsequently amplified more than 20 decibels in the sandy and water-saturated sediments of the southeastern U.S. Coastal Plain and Mississippi Embayment. In these sediments, 1 s noise shows similar amplification and is generated through a variety of mechanisms including cultural activity throughout Kentucky and the southeastern Appalachian Mountains, lake waves around the Great Lakes, and ocean waves throughout New England, the Pacific Northwest, and Florida. Both 0.2 and 1 s noise levels are the lowest in the Intermountain West portion of the U.S. We attribute this to a combination of installations on crystalline rocks and reduced population density. Finally, we find that sensors emplaced in sandy, water-saturated sediments observe median, diurnal variations in vertical component power at 18 to 75 s period, which we infer arise through local deformation driven by pressure variations. Ultimately, our results underscore that for shallow (<5 m depth) sensor installation, bedrock provides superior broadband noise performance compared to unconsolidated sediments.

Bulletin of the Seismological Society of America

Two pollen diagrams from southeastern Minnesota: Problems in the regional late-glacial and postglacial vegetational history

Kirchner Marsh and Lake Carlson are located 3 miles apart in Dakota County about 15 miles south of Minneapolis in the St. Croix moraine, which was formed by the Superior lobe during the Gary phase of the Wisconsin glaciation. During the Mankato phase that followed, the Des Moines lobe advanced to within a few miles of the sites. The region today is in a mixed-oak forest, with a maplebasswood forest 15 miles to the west and a re-entrant of the prairie on the sand plain south of the moraine. The general limit of coniferous trees is about 50 miles northeast of the sites, although outliers, especially of Pinus strobus, may be found along the Mississippi Valley a few miles to the east. One sediment core 12-13 m long from each site was analyzed for pollen content at 5-25-cm intervals. Diagrams based on percentage of total pollen (trees, shrubs, wind-pollinated herbs) show essentially identical sequences at the two sites, starting with the late-glacial phase of ice retreat. The diagrams have been subdivided into pollen zones according to the A-B-C sequence introduced by Deevey for New England. The late-glacial pollen record starts at Kirchner Marsh with a short Picea-Cyperaceae-Gramineae phase (Zone K), believed to represent a spruce parkland. Its C-14 date of 13,270 BP and the stratigraphy indicate a pre- Two Creeks and post- Gary correlation. Apparently the Kirchner site did not become established as a lake until this time owing to persistence of dead ice in the moraine. The absence of pollen of specific tundra indicators and the presence of pollen of such thermophilous plants as Fraxinus, Quercus, Corylus, Ambrosia, Humulus, and Typha latifolia imply that the climate was cool rather than cold. Zone A-a, which follows, correlates with the Two Creeks interstade. It is marked by the dominance of Picea, with appreciable percentages of Fraxinus and Ambrosia and with minor amounts of other thermophilous plants and the normal boreal associates of spruce like Betula, Larix, and Salix. Zone A-b, starting 12,050 C-14 years ago, correlates with the Valders ice advance. It is represented at both Kirchner and Carlson and shows the withdrawal of Fraxinus and Ambrosia and the slight rise of Artemisia. Except for the absence of pine in the late-glacial assemblage the vegetation implied by these three zones seems to have its closest modern counterpart in the southern fringe of the Boreal Forest of the Riding Mountain region of southwest Manitoba. It is concluded that pine did not migrate southward with the spruce during the Wisconsin glaciation, at least in the western Great Lakes region, and was thus eliminated from this region. During the lateglacial phases of ice retreat, herbs and spruce pioneered on the deglaciated terrain; pine did not follow until the destruction of the spruce forest at the end of the late-glacial phase. Zone B introduces postglacial time. It represents the time of rapid Vegetational succession following the deterioration of the spruce forest. Simultaneous maxima of Betula, Alnus, Fraxinus, and Abies occurred 10,230 years ago at Kirchner Marsh. These were followed rapidly by a Pinus maximum and then a rise of Ulmus, Quercus, and other deciduous types, dated as 9300 years ago at the correlative site of Madeha. This succession may represent differential rates of migration from refuges south and east of Minnesota . Deciduous trees dominate the C Zones. Zone C-a shows Ulmus and Ostrya /Carpinus followed by Quercus; it probably represents principally a mesic maple-basswood forest changing to oak. Zone C-b represents the advance of prairie into the region at the expense of the oak woodland or savanna. The large and abrupt fluctuations in the curves for Ambrosia-type and Chenopodiineae, especially at the Carlson site, may record encroachment of annual weeds onto intermittently dried lake bottoms. C-14 dates place Zone C-b between 7100 and 5100 years ago. In Zone C-c the Quercus again dominates until the abrupt increase in Ambrosiatype and Chenopodiineae that marks the time of forest clearance and land settlement 50-75 years ago.

Minnesota