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Characterizing the proposed geologic repository for high-level radioactive waste at Yucca Mountain, Nevada: hydrology and geochemistry

This hydrology and geochemistry volume is a companion volume to the 2007 Geological Society of America Memoir 199, The Geology and Climatology of Yucca Mountain and Vicinity, Southern Nevada and California , edited by Stuckless and Levich. The work in both volumes was originally reported in the U.S. Department of Energy regulatory document Yucca Mountain Site Description , for the site characterization study of Yucca Mountain, Nevada, as the proposed U.S. geologic repository for high-level radioactive waste. The selection of Yucca Mountain resulted from a nationwide search and numerous committee studies during a period of more than 40 yr. The waste, largely from commercial nuclear power reactors and the government's nuclear weapons programs, is characterized by intense penetrating radiation and high heat production, and, therefore, it must be isolated from the biosphere for tens of thousands of years. The extensive, unique, and often innovative geoscience investigations conducted at Yucca Mountain for more than 20 yr make it one of the most thoroughly studied geologic features on Earth. The results of these investigations contribute extensive knowledge to the hydrologic and geochemical aspects of radioactive waste disposal in the unsaturated zone. The science, analyses, and interpretations are important not only to Yucca Mountain, but also to the assessment of other sites or alternative processes that may be considered for waste disposal in the future. Groundwater conditions, processes, and geochemistry, especially in combination with the heat from radionuclide decay, are integral to the ability of a repository to isolate waste. Hydrology and geochemistry are discussed here in chapters on unsaturated zone hydrology, saturated zone hydrology, paleohydrology, hydrochemistry, radionuclide transport, and thermally driven coupled processes affecting long-term waste isolation. This introductory chapter reviews some of the reasons for choosing to study Yucca Mountain as a repository site.

Nevada

Comparative analysis of the geological evolution of the northern and southern Appalachian orogen: Late Ordovician-Permian

Review of the major post-Middle Ordovician lithotectonic elements of the Appalachian orogen indicates that the middle to late Paleozoic geologic evolution of the Appalachian margin was less uniform than that of the early Paleozoic. Evolutionary divergence betweenthe northern and southern segments of the orogen started in the Late Ordovician to Silurian with staggered accretion of the first peri-Gondwanan elements to reach the Laurentia margin, Carolinia in the south and Ganderia in the north. Divergence was amplified duringthe Silurian, specifi cally with respect to the nature of the Laurentian margin and the history of accretion. During this time frame, the northern margin was convergent, whereas the amagmatic southern margin may well have been a transform boundary. In terms of accretion, the Late Silurian-Early Devonian docking of Avalonia was restricted to the northern segment, whereas the southern Appalachians appear to have been largely quiescent during this interval. The evolutionary paths of the two segments of the margin converge on a commonhistory in the Late Devonian during the Famennian event; we suggest that this tectonism was related to the initial marginwide interaction of Laurentia with the peri-Gondwanan blocks of Meguma and Suwanee, providing a uniform tectonic template for margin evolution. The Laurentian-Gondwanan collision is marked by second-order divergences in history. Specifi cally, during the Carboniferous, the southern segment records a larger component of shortening than the northern Appalachians. ?? 2010 Geological Society of America.

Memoir of the Geological Society of America

Yucca Mountain, Nevada - A proposed geologic repository for high-level radioactive waste

Yucca Mountain in Nevada represents the proposed solution to what has been a lengthy national effort to dispose of high-level radioactive waste, waste which must be isolated from the biosphere for tens of thousands of years. This chapter reviews the background of that national effort and includes some discussion of international work in order to provide a more complete framework for the problem of waste disposal. Other chapters provide the regional geologic setting, the geology of the Yucca Mountain site, the tectonics, and climate (past, present, and future). These last two chapters are integral to prediction of long-term waste isolation. ?? 2007 Geological Society of America. All rights reserved.

Memoir of the Geological Society of America

Global biotic events evident in the Paleogene marine strata of the eastern San Francisco Bay area, California

Paleogene marine strata in the eastern San Francisco Bay area are exposed in discontinuous outcrops in the various tectonic blocks. Although there are many missing intervals, the strata were previously thought to span most of the Paleocene and Eocene. Revision of biochronology and calibration to the international time scale as well as to the global oxygen isotope curve and sea-level curves indicate that the strata are latest Paleocene through middle Eocene in age and contain faunal changes that are linked to the overall global climate trends and hyperthermals of that time. The Paleocene-Eocene thermal maximum, third Eocene thermal maximum, early Eocene climatic optimum, and middle Eocene climatic optimum are all identified in the eastern San Francisco Bay marine strata. The dominance of smoothly finished, dissolution-resistant agglutinated benthic foraminiferal species corresponds with a rapid shoaling and rapid deepening (overcorrection) of the calcium compensation depth associated with the Paleocene-Eocene thermal maximum. The benthic foraminiferal extinction event was a dramatic turnover of benthic foraminiferal species that occurred shortly after the onset of the Paleocene-Eocene thermal maximum. Opportunistic species such as Bulimina , which indicate environmental stress and lower oxygen conditions, are commonly associated with the Paleocene-Eocene thermal maximum. Environmental changes similar to those observed during the Paleocene-Eocene thermal maximum also characterize the third Eocene thermal maximum, based on the agglutinated and opportunistic species. The early Eocene climatic optimum is noted by the presence of foraminiferal assemblages that indicate a stable, warmer water mass, abundant food, and an influx of terrigenous material. The onset and end of the middle Eocene climatic optimum are recognized by the dominance of siliceous microfossils. This research updates the age and environmental interpretations of the Paleogene formations occurring in the vicinity of Mount Diablo, eastern San Francisco Bay area. The revised interpretations, which are based on foraminifers and calcareous nannoplankton, make it possible to identify various global climatic and biotic events.

California

Deciphering multiple Mesoproterozoic and Paleozoic events recorded in zircon and titanite from the Baltimore Gneiss, Maryland: SEM imaging, SHRIMP U-Pb geochronology, and EMP analysis

The Baltimore Gneiss , exposed in antiforms in the eastern Maryland Piedmont, consists of a suite of felsic and mafic gneisses of Mesoproterozoic age. Zircons from the felsic gneisses are complexly zoned, as shown in cathodoluminescence imaging ; most zircon grains have multiple overgrowth zones, some of which are adjacent and parallel to elongate cores. Sensitive high-resolution ion microprobe ( SHRIMP ) analyses of oscillatory-zoned cores indicate that the volcanic protoliths of the felsic gneisses crystallized at ca. 1.25 Ga. These rocks were subsequently affected by at least three Mesoproterozoic growth events , at ca. 1.22, 1.16, and 1.02 Ga. Foliated biotite granite intruded the Baltimore Gneiss metavolcanic sequence at ca. 1075 Ma. The Slaughterhouse Granite (renamed herein) also is Mesoproterozoic , but extremely discordant U-Pb data from high-U, metamict zircons preclude calculating a precise age. The 1.25 Ga rocks of the Baltimore Gneiss are coeval with rocks emplaced in the Grenville Province during the Elzevirian orogeny, and the 1.22 Ga zircon overgrowths are coincident with a later stage of this event . Younger zircon overgrowths formed during the Ottawan phase of the Grenville orogeny. Backscattered electron imaging of titanites from felsic gneisses and foliated biotite granite reveals that many of the grains contain cores, intermediate mantles, and rims. Electron microprobe traverses across zoned grains show regular variations in composition. SHRIMP ages for titanite from the foliated biotite granite are 374 ± 8, 336 ± 8, and 301 ± 12 Ma. The ca. 374 Ma age suggests growth of titanite during a thermal event following the Acadian orogeny, whereas the late Paleozoic titanite growth ages may be due to greenschist-facies replacement reactions associated with Alleghanian metamorphism and deformation.

Maryland

Geology of the Yucca Mountain site area, southwestern Nevada

Yucca Mountain in southwestern Nevada is a prominent, irregularly shaped upland formed by a thick apron of Miocene pyroclastic-flow and fallout tephra deposits, with minor lava flows, that was segmented by through-going, large-displacement normal faults into a series of north-trending, eastwardly tilted structural blocks. The principal volcanic-rock units are the Tiva Canyon and Topopah Spring Tuffs of the Paintbrush Group, which consist of volumetrically large eruptive sequences derived from compositionally distinct magma bodies in the nearby southwestern Nevada volcanic field, and are classic examples of a magmatic zonation characterized by an upper crystal-rich (>10% crystal fragments) member, a more voluminous lower crystal-poor (<5% crystal fragments) member, and an intervening thin transition zone. Rocks within the crystal-poor member of the Topopah Spring Tuff, lying some 280 m below the crest of Yucca Mountain, constitute the proposed host rock to be excavated for the storage of high-level radioactive wastes. Separation of the tuffaceous rock formations into subunits that allow for detailed mapping and structural interpretations is based on macroscopic features, most importantly the relative abundance of lithophysae and the degree of welding. The latter feature, varying from nonwelded through partly and moderately welded to densely welded, exerts a strong control on matrix porosities and other rock properties that provide essential criteria for distinguishing hydrogeologic and thermal mechanical units, which are of major interest in evaluating the suitability of Yucca Mountain to host a safe and permanent geologic repository for waste storage. A thick and varied sequence of surficial deposits mantle large parts of the Yucca Mountain site area. Mapping of these deposits and associated soils in exposures and in the walls of trenches excavated across buried faults provides evidence for multiple surface-rupturing events along all of the major faults during Pleistocene and Holocene times; these paleoseismic studies form the basis for evaluating the potential for future earthquakes and fault displacements. Thermoluminescence and U-series analyses were used to date the surficial materials involved in the Quaternary faulting events. The rate of erosional downcutting of bedrock on the ridge crests and hillslopes of Yucca Mountain, being of particular concern with respect to the potential for breaching of the proposed underground storage facility, was studied by using rock varnish cation-ratio and 10 Be and 36 Cl cosmogenic dating methods to determine the length of time bedrock outcrops and hillslope boulder deposits were exposed to cosmic rays, which then served as a basis for calculating long-term erosion rates. The results indicate rates ranging from 0.04 to 0.27 cm/k.y., which represent the maximum downcutting along the summit of Yucca Mountain under all climatic conditions that existed there during most of Quaternary time. Associated studies include the stratigraphy of surficial deposits in Fortymile Wash, the major drainage course in the area, which record a complex history of four to five cut-and-fill cycles within the channel during middle to late Quaternary time. The last 2-4 m of incision probably occurred during the last pluvial climatic period, 22-18 ka, followed by aggradation to the present time. Major faults at Yucca Mountain-from east to west, the Paintbrush Canyon, Bow Ridge, Stagecoach Road, Solitario Canyon, Fatigue Wash, Windy Wash, and Northern and Southern Crater Flat Faults-trend predominantly north, are spaced 1-5 km apart, have bedrock displacements ranging from 125 m to as much as 500 m, and exhibit Quaternary movements of several centimeters to a few meters. Displacements are predominantly down to the west, and bedrock/alluvium contacts commonly are marked by fault-line scarps. The predominant northerly fault trend changes to a more northeasterly trend in adjacent areas south

Nevada

Overlapping plutonism, volcanism, and tectonism in the boulder batholith region, western Montana

It is well known that the Boulder batholith region experienced intensive plutonism, volcanism, and tectonism that all began in Late Cretaceous time, after at least 700 m.y. of structural and igneous inactivity except for sporadic epeirogeny. Recent stratigraphic, structural, paleontologic, arid, especially, radiometric evidence makes it possible to date these dynamic events rather closely. The time relations that are revealed do not form a simple sequence of volcanism-folding-thrusting-batholith emplacement, as has often been supposed, but involve an intertwined complex. Significant volcanism began ∼ 85 m.y. ago in late Coniacian or early Santonian time, with deposition of the thick, local tuffaceous Slim Sam Formation. Volcanism climaxed from 77 to 79 m.y. ago, in early Campanian time, when the region was buried under at least 10,000 feet of calc-alkalic volcanic and volcaniclastic rocks, which included many sheets of welded tuff - the Elkhorn Mountains Volcanics -, and a vast amount of contemporaneous ash was airborne beyond the region. Major volcanism ceased ∼ 73 m.y. ago, late in the Campanian, not to recur until early Eocene time, ∼ 50 m.y. ago. The bulk of the batholith was emplaced beneath and within the volcanic edifice in early and middle Campanian time, during a 6 m.y. span from 78 to 72 m.y. ago, and some leucocratic masses were intruded during the next few million years, so that the whole batholith was emplaced within about 10 m.y. Folding at and near the site of the batholith began in late Coniacian or Santonian time and culminated before middle Campanian time; the main folding north and east of the batholith was post-Campanian, probably Maestrichtian. Thrusting began before middle Santonian time, and recurred intermittently well into the Maestrichtian, or even a little later. Thus volcanism, plutonism, folding, and thrusting began and ended within a few million years of each other, during the last 20 m.y. of the Cretaceous. Major folding, thrusting, and volcanism started about the same time, though not always at the same places, and a little earlier than plutonism. In any given locality, volcanism ended before major folding; the climax of plutonism followed the climax of volcanism; thrusting preceded and accompanied plutonism near the batholith, but followed plutonism farther away; thrusting ended a little later than folding. These dynamic processes so closely related in time and space must also be genetically related in the Boulder batholith region. Gilluly's (1965) conclusion that the orogeny which produced the great Cretaceous thrusts of Montana was "essentially without plutonic associations" is not tenable.

Montana

Resurgent cauldrons

Resurgent cauldrons are defined as cauldrons (calderas) in which the cauldron block, following subsidence, has been uplifted, usually in the form of a structural dome. Seven of the best known resurgent cauldrons are: Valles, Toba, Creede, San Juan, Silverton, Lake City, and Timber Mountain. Geologic summaries of these and Long Valley, California, a probable resurgent caldera, are presented. Using the Valles caldera as a model, but augmented by information from other cauldrons, seven stages of volcanic, structural, sedimentary, and plutonic events are recognized in the development of resurgent cauldrons. They are: (I) Regional tumescence and generation of ring fractures; (II) Calderaforming eruptions; (III) Caldera collapse; (IV) Preresurgence volcanism and sedimentation; (V) Resurgent doming; (VI) Major ring-fracture volcanism; (VII) Terminal solfatara and hot-spring activity. These stages define the terminal cycle of resurgent cauldrons, which in the Valles caldera spanned more than 1 million years. The known and inferred occurrence of the seven stages in the eight cauldrons discussed, together with some time control in four cauldrons, indicates that resurgent doming is early in the postcollapse history; hence, it seems part of a pattern and not fortuitous. Doming of the cauldron block by magma pressure is preferred to doming by stock or laccolithic intrusion, although these processes may be subsidiary. Magma rise that produces doming may be explained in several ways, but the principal cause is not known. Nor is it known why some otherwise similar calderas do not have resurgent domes, although size and thickness of the cauldron block and the degree to which it was deformed during caldera collapse may be factors. All known resurgent structures are larger than 8 miles in diameter and are associated with silicic and, presumably, high-viscosity magmas. Genetically, resurgent cauldrons belong to a cauldron group in which subsidence of a central mass takes place along ring fractures and is related to eruption of voluminous ash flows, thereby differing from Kilauean-type calderas. It is proposed that typical Krakatoan-type calderas differ in that collapse is chaotic and ring fractures are not essential to their formation. Krakatoan calderas typically occur in the andesitic volcanoes of island arcs or the eugeosynclinal environment, and their sub-volcanic analogues are not known, whereas resurgent and related Glen Coe-type cauldrons are more common in cratonic or post-orogenic environments as are their sub-volcanic analogues - granitic ring complexes. Granitic ring complexes, such as Lirue, Sande, Ossipee, and Alnsj0, are probably the closest sub-volcanic analogues of resurgent calderas. The source areas of most of the ash-flow sheets of western United States and Mexico are yet to be found. It is suggested that many of them will prove to be resurgent structures. Present evidence suggests that ore deposits are more commonly associated with resurgent cauldrons than with other cauldron types.

Memoir of the Geological Society of America

Middle tertiary volcanic field in the southern Rocky Mountains

A widespread volcanic field covered most of the Southern Rocky Mountains in middle Tertiary time, 40 to 25 m.y. ago (approximately Oligocene time). This field covered an erosion surface that beveled structures formed during the Laramide orogeny in Late Cretaceous and early Tertiary time. The source vents from which the volcanic rocks were derived were largely restricted to the deformed area. Recognized volcanic centers lie mostly within a broad triangular area bounded on the east by the Rocky Mountain front, on the northwest by the northeast-trending Colorado mineral belt lineament, and on the southwest by the southern margin of the recurrently active Uncompahgre-San Luis uplift. Local volcanic centers existed also in the Never Summer Mountains and Rabbit Ears Range north of the mineral belt lineament. The resulting volcanic field thus consisted of a major southern segment covering all of south-central Colorado and adjacent New Mexico and a northern segment extending into the mountain areas of north-central Colorado. The two segments were linked along the trend of the Colorado mineral belt. Most of the volcanic field consisted of volcanic rock of intermediate composition derived from many widely scattered volcanoes. Extensive aprons of volcaniclastic rocks around these volcanoes coalesced to provide a virtually continuous cover of volcanic material. In places, the volcanic activity became more silicic with time, great ash-flow tuff sheets were erupted, and the source areas subsided to form calderas. The largest ash-flow field and most of the calderas formed in the San Juan Mountains. Other ash flows apparently were derived from areas in the Sawatch Range in central Colorado and the Never Summer Mountains in northern Colorado. Large near-surface batholiths were emplaced beneath the San Juan Mountains and beneath the region that extends northeastward from the Elk Mountains and Sawatch Range along the trend of the Colorado mineral belt as far as the Rocky Mountain front. These batholiths are manifested by two large gravity lows and by many exposed epizonal plutons that represent cupolas on the larger underlying bodies. The batholith in central Colorado probably consists of plutons of both Laramide (70 to 55 m.y.) and middle Tertiary (40 to 25 m.y.) ages.

Rocky Mountains

Estimation of depth to magnetic source using maximum entropy power spectra, with application to the Peru-Chile Trench

Estimations of the depth to magnetic sources using the power spectrum of magnetic anomalies generally require long magnetic profiles. The method developed here uses the maximum entropy power spectrum (MEPS) to calculate depth to source on short windows of magnetic data; resolution is thereby improved. The method operates by dividing a profile into overlapping windows, calculating a maximum entropy power spectrum for each window, linearizing the spectra, and calculating with least squares the various depth estimates. The assumptions of the method are that the source is two dimensional and that the intensity of magnetization includes random noise; knowledge of the direction of magnetization is not required. The method is applied to synthetic data and to observed marine anomalies over the Peru-Chile Trench. The analyses indicate a continuous magnetic basement extending from the eastern margin of the Nazca plate and into the subduction zone. The computed basement depths agree with acoustic basement seaward of the trench axis, but deepen as the plate approaches the inner trench wall. This apparent increase in the computed depths may result from the deterioration of magnetization in the upper part of the ocean crust, possibly caused by compressional disruption of the basaltic layer. Landward of the trench axis, the depth estimates indicate possible thrusting of the oceanic material into the lower slope of the continental margin.

Memoir of the Geological Society of America

Fission-track ages of apatite in the Wasatch Mountains, Utah: An uplift study

Apatite fission-track ages from basement rocks in the Wasatch Mountains between Ogden and Bountiful, Utah, range from 5 m.y. near the Wasatch fault along the west margin of the mountains to 94 m.y. on the crest of the range and show a correlation with altitude within individual fault blocks. Analysis of these ages yields an uplift rate of 0.4 mm/yr for the last 10 m.y. for the fault blocks having the most sustained rapid uplift. A variety of intermediate ages of apatite from the crest of the range and at lower altitudes is interpreted as representing fault blocks with rocks having mixed ages due to various degrees of tilting and varying but lesser amounts of uplift.

Utah

Chapter 4: Cretaceous thrusting and Neogene block rotation in the northern Portneuf Range region, southeastern Idaho

The Putnam thrust has long been recognized as an important Mesozoic structure in the northern Portneuf Range, southeastern Idaho. At most localities, the thrust places Ordovician rocks above Permian and Pennsylvanian rocks, although near its southeastern extent, it ramps laterally downsection to the southeast. At its southeasternmost exposures, Cambrian rocks are juxtaposed above Mississippian rocks. New work indicates that the hanging wall of the Putnam thrust contains three imbricate thrust slices or subplates, which are, from structurally lowest to highest (and generally from north to south), the Lone Pine subplate, the Narrows subplate, and the Bear Canyon-Toponce subplate. The steeply south-dipping, east-trending Narrows thrust overlies the Lone Pine subplate, underlies the Narrows subplate, and is a lateral ramp that merges eastward into the Putnam thrust. Where exposed, the Narrows thrust places Late Proterozoic quartzite of the Brigham Group over Ordovician and Cambrian rocks. The Bear Canyon thrust overlies the Narrows subplate and underlies the Bear Canyon-Toponce subplate, dips eastward along the west side of the Portneuf Range, and places lower Brigham Group quartzite above Cambrian limestone and Cambrian and Late Proterozoic upper Brigham Group quartzite and argillite. At its northern extent, the Bear Canyon thrust curves to the east, where it merges with the Putnam thrust. On the east side of the range, the intensely folded Toponce thrust places upper Brigham Group quartzite above Ordovician rocks; the Toponce is believed to be an eastward extension of the Bear Canyon thrust. East-dipping rocks within the Lone Pine subplate were not strongly deformed during Cretaceous thrusting, in contrast to rocks within the Narrows subplate, where east-vergent recumbent folds, cleavage directions that fan about northerly strikes, and tectonic thickening and thinning of beds indicate intense, thrust-parallel shear. The deformation and thrust geometry within the Narrows subplate suggest that the Narrows subplate actually consists of several horses within a foreland-dipping duplex. Late Miocene and younger basin deposits occur in north-trending valleys adjacent t o the northern Portneuf Range and, to the west, the Bannock and Pocatello ranges. At most places, the Neogene deposits dip to the east by as much as 35°, indicating that late Miocene and younger extension and down-to-the-east rotation occurred along mostly west-dipping listric faults that are inferred to merge on at least one regional detachment. Although range-bounding faults account for a large component of extension and rotation, an additional large component was contributed by numerous, relatively small-displacement normal faults within mountain ranges.

Idaho

Stratigraphy and history of the Moenkopi formation of Triassic age

The Moenkopi formation of Triassic age is composed of a series of deposits that form a wedge thinning eastward from a maximum of about 2000 feet in western Utah and southern Nevada to the vanishing point along an irregular margin in western Colorado, northeastern Arizona, and western New Mexico. Partly marine and partly continental in the thick western sections, it is entirely continental in the east. Invertebrate faunas indicate that deposition began either during or preceding the middle of the Early Triassic (Meekoceras zone) and continued into late Early Triassic (Tirolites zone) and probably into Medial Triassic time. Vertebrate faunas also indicate an Early Triassic and probably, in part, a Medial Triassic age . Studies of the deposits indicate three major transgressions and three regressions across southern Utah and northern Arizona. Analysis of sedimentary rock types and original structures in them suggests a complex mixture of environments involved in the development of the formation : stream beds, lagoons, playas, flood plains or tidal flats, shallow sea floors, and others. Some types are clear cut and readily demonstrated; others are open to question. Evidence from flora, fauna, and sediments indicates a semiarid to arid climate. Except for uplift in the Uncompahgre region of Colorado indicated by conglomeratic beds in the Moenkopi near by, the entire region probably remained very low and flat during Moenkopi deposition.

Colorado, Arizona, New Mexico

Chapter 22: Environments and facies of existing bays on the central Texas coast

The estuaries and neritic waters along the central Texas coast are characterized by broad ranges of environmental factors, providing conditions favorable to temperate organisms in winter and tropical organisms in summer. Dredging in the coastal waters revealed a number of distinct faunal facies, the distribution of which appears to be controlled primarily by salinity. Characteristic assemblages are found in the following areas: closed bays, polyhaline bays, a highly saline lagoon, passes, beaches on the open Gulf, and shallow waters of the open gulf. In the closed bays three subfacies are recognized-one in the bay heads, one on the reefs, and one in the interreef areas; in the open gulf the assemblages living close to shore are differentiated from those found 2-4 miles off shore. In most stations each facies is characterized by an abundance of certain living forms. Dead shells and other skeletal parts are much more widely distributed, but many such strays may be recognized as transported elements by their rarity or by their eroded surfaces. Each group of organisms has one or more centers of maximum development in numbers of species. The Foraminifera, for example, attain their greatest development in the polyhaline bays and near the heads of passes, the ostracodes near the bay heads, mollusks in the polyhaline bays and in the Gulf, and diatoms under normal marine conditions in the Gulf. The reef assemblage of the closed bays is poor in numbers of species, but the individuals are so numerous that they form extensive deposits.

Texas