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Results for “Journal of Geophysical Research Atmospheres”

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USGS2011

The influence of the Atlantic Warm Pool on the Florida panhandle sea breeze

In this paper we examine the variations of the boreal summer season sea breeze circulation along the Florida panhandle coast from relatively high resolution (10 km) regional climate model integrations. The 23 year climatology (1979–2001) of the multidecadal dynamically downscaled simulations forced by the National Centers for Environmental Prediction–Department of Energy (NCEP‐DOE) Reanalysis II at the lateral boundaries verify quite well with the observed climatology. The variations at diurnal and interannual time scales are also well simulated with respect to the observations. We show from composite analyses made from these downscaled simulations that sea breezes in northwestern Florida are associated with changes in the size of the Atlantic Warm Pool (AWP) on interannual time scales. In large AWP years when the North Atlantic Subtropical High becomes weaker and moves further eastward relative to the small AWP years, a large part of the southeast U.S. including Florida comes under the influence of relatively strong anomalous low‐level northerly flow and large‐scale subsidence consistent with the theory of the Sverdrup balance. This tends to suppress the diurnal convection over the Florida panhandle coast in large AWP years. This study is also an illustration of the benefit of dynamic downscaling in understanding the low‐frequency variations of the sea breeze.

Florida↗

USGS2012

Sulfur dioxide and particles in quiescent volcanic plumes from Poás, Arenal, and Colima Volcanos, Costa Rica and Mexico

Measurements of SO 2 emission rates and concentrations and of particle distribution, size, shape, and composition were made in quiescent volcanic plumes emitted into the troposphere from Poás and Arenal volcanos, Costa Rica, and Colima volcano, Mexico. SO 2 emission rates were 700±180 metric tons per day (t/d) for Poás, 210±30 t/d for Arenal, and 320±50 t/d for Colima. The concentrations of SO 2 calculated from the COSPEC/lidar data were 5–380 ppb. Concentrations of SO 2 measured directly by flame photometry were 10–250 ppb. Particles collected in the plumes with a quartz crystal microbalance impactor were mostly less than 3 μm in diameter and consisted of droplets of dilute sulfur-bearing solutions and minor amounts of larger silicate particles coated with a sulfur-bearing film or crust. Total particle concentrations were 4.7 μg/m 3 for Poás and 18.8 μg/m 3 for Colima. Comparison of concentrations of SO 2 in the plumes with gas samples collected at fumaroles on the ground suggests that the plumes are diluted by the atmosphere by factors of up to 10 5 .

Journal of Geophysical Research Atmospheres↗

USGS2023

VogCast: A framework for modeling volcanic air pollution and its application to the 2022 eruption of Mauna Loa Volcano, Hawai'i

Volcanic activity and the associated gas emissions into the atmosphere often result in adverse air quality conditions and present a hazard to human health and the environment. Building on a decade-long effort to provide operational surface sulfur dioxide and sulfate aerosol forecasts for the State of Hawai'i, we present an air quality modeling framework called VogCast. VogCast is designed to simplify ensemble air quality prediction on a regional scale by linking together multiple state-of-the-art models of meteorology, emissions, and dispersion. The framework is open-source and introduces a new dynamic plume-rise algorithm for distributing pollutants vertically. Using radar and satellite data, we demonstrate that VogCast reasonably captured the mean injection height, the location, and the general envelope of the vog plume during Mauna Loa's 2022 eruption. The results suggest that during the 12-day eruption period model performance varied between days with trade and non-trade wind conditions. Our findings also highlight the importance of sulfur dioxide emission rate and vent parameter inputs for improving forecast accuracy. The broad goal of this work is to better our understanding of vog dispersion and improve air quality prediction for impacted communities.

Hawaii↗

USGS2018

Investigating the origin of continual radio frequency impulses during explosive volcanic eruptions

Volcanic lightning studies have revealed that there is a relatively long‐lasting source of very high frequency radiation associated with the onset of explosive volcanic eruptions that is distinct from radiation produced by lightning. This very high frequency signal is referred to as “continual radio frequency (CRF)” due to its long‐lasting nature. The discharge mechanism producing this signal was previously hypothesized to be caused by numerous, small (10–100 m) leader‐forming discharges near the vent of the volcano. To test this hypothesis, a multiparametric data set of electrical and volcanic activity occurring during explosive eruptions of Sakurajima Volcano in Japan was collected from May to June 2015. Our observations show that a single CRF impulse has a duration on the order of 160 ns (giving an upper limit on discharge length of 10 m) and is distinct from near‐vent lightning discharges that were on the order of 30 m in length. CRF impulses did not produce discernible electric field changes and occurred in the absence of a net static electric field. Lightning mapping data and infrared video observations of the eruption column showed that CRF impulses originated from the gas thrust region of the column. These observations indicate that CRF impulses are not produced by small, leader‐forming discharges but rather are more similar to a streamer discharge, likely on the order of a few meters in length.

Sakurajima Volcano↗

USGS2019

Laboratory experiments of volcanic ash resuspension by wind

Fresh volcanic eruption deposits tend to be loose, bare, and readily resuspended by wind. Major resuspension events in Patagonia, Iceland, and Alaska have lofted ash clouds with potential to impact aircraft, infrastructure, and downwind communities. However, poor constraints on this resuspension process limit our ability to model this phenomenon. Here, we present laboratory experiments measuring threshold shear velocities and emission rates of resuspended ash under different environmental conditions, including relative humidity of 25–75% and simulated rainfall with subsequent drying. Eruption deposits were replicated using ash collected from two major eruptions: the 18 May 1980 eruption of Mount St. Helens and the 1912 eruption of Novarupta, in Alaska's Valley of Ten Thousand Smokes. Samples were conditioned in a laboratory chamber and prepared with bulk deposit densities of 1,300–1,500 kg/m 3 . A control sample of dune sand was included for comparison. The deposits were subjected to different wind speeds using a modified PI‐SWERL® instrument. Under a constant relative humidity of 50% and shear velocities 0.4–0.8 m/s, PM 10 emission by resuspension ranged from 10 to >100 mg·m −2 ·s −1 . Addition of liquid water equivalent to 5 mm of rainfall had little lasting effect on Mount St. Helens wind erosion potential, while the Valley of Ten Thousand Smokes deposits exhibited lower emissions for at least 12 days. The results indicate that particle resuspension due to wind erosion from ash deposits potentially exceeds that of most desert surfaces and approaches some of the highest emissions ever measured.

Journal of Geophysical Research - Atmospheres↗

USGS2023

Flow development and entrainment in turbulent particle-laden jets

Explosive eruptions expel volcanic gases and particles at high pressures and velocities. Within this multiphase fluid, small ash particles affect the flow dynamics, impacting mixing, entrainment, turbulence, and aggregation. To examine the role of turbulent particle behavior, we conducted an analogue experiment using a particle-laden jet. We used compressed air as the carrier fluid, considering turbulent conditions at Reynolds numbers from approximately 5,000 to 20,000. Two different particles were examined: 14-μm diameter solid nickel spheres and 13-μm diameter hollow glass spheres. These resulted in Stokes numbers between 1 and 35 based on the convective scale. The particle mass percentage in the mixture is varied from 0.3% to more than 20%. Based on a 1-D volcanic plume model, these Stokes numbers and mass loadings corresponded to millimeter-scale particle diameters at heights of 4–8 km above the vent during large, sustained eruptions. Through particle image velocimetry, we measured the mean flow behavior and the turbulence statistics in the near-exit region, primarily focusing on the dispersed phase. We show that the flow behavior is dominated by the particle inertia, with high Stokes numbers reducing the entrainment by more than 40%. When applied to volcanic plumes, these results suggest that high-density particles can greatly increase the probability of column collapse.

Journal of Geophysical Research: Atmospheres↗

USGS1999

Carbon cycling in boreal wetlands: A comparison of three approaches

Three independent methods were used to measure net ecosystem production (NEP) in four wetlands near Thompson, Manitoba, Canada. The first method calculated NEP by subtracting heterotrophic respiration from net primary productivity, using both measurements and estimates derived from the literature. The second method used radiocarbon data from cores to derive long-term NEP averaged over the past several decades. The third method used direct measurement of NEP combined with a model to fill in for days with no data. The three methods, with their independently derived uncertainties, all show the same magnitude and pattern of NEP variation across four different wetland types. However, direct measurement yielded distinctly lower estimates of NEP in the most productive sites. Highest NEP (31–180 gC m −2 yr −1 ) was observed in the two wetlands with the highest proportion of sedge vegetation. A bog collapse scar and a nutrient-rich fen had NEP values not significantly different from zero. The maximum NEP at sites with intermediate nutrient status is due to slower overall decomposition and is likely associated with greater allocation of production below ground by sedges. The three methods for estimating NEP differ in the effort required, the sources of error, and in the timescale over which they apply. Used in combination, they allow estimation of parameters such as below- ground production and the contribution of heterotrophic decomposition to total soil respiration. Using the radiocarbon method, we also derived estimates of the rate of N accumulation in the four wetland types.

Manitoba↗

USGS2008

Reconstructed historical land cover and biophysical parameters for studies of land-atmosphere interactions within the eastern United States

Over the past 350 years, the eastern half of the United States experienced extensive land cover changes. These began with land clearing in the 1600s, continued with widespread deforestation, wetland drainage, and intensive land use by 1920, and then evolved to the present-day landscape of forest regrowth, intensive agriculture, urban expansion, and landscape fragmentation. Such changes alter biophysical properties that are key determinants of land-atmosphere interactions (water, energy, and carbon exchanges). To understand the potential implications of these land use transformations, we developed and analyzed 20-km land cover and biophysical parameter data sets for the eastern United States at 1650, 1850, 1920, and 1992 time slices. Our approach combined potential vegetation, county-level census data, soils data, resource statistics, a Landsat-derived land cover classification, and published historical information on land cover and land use. We reconstructed land use intensity maps for each time slice and characterized the land cover condition. We combined these land use data with a mutually consistent set of biophysical parameter classes, to characterize the historical diversity and distribution of land surface properties. Time series maps of land surface albedo, leaf area index, a deciduousness index, canopy height, surface roughness, and potential saturated soils in 1650, 1850, 1920, and 1992 illustrate the profound effects of land use change on biophysical properties of the land surface. Although much of the eastern forest has returned, the average biophysical parameters for recent landscapes remain markedly different from those of earlier periods. Understanding the consequences of these historical changes will require land-atmosphere interactions modeling experiments.

Journal of Geophysical Research D: Atmospheres↗

USGS1997

Case study modeling of turbulent and mesoscale fluxes over the BOREAS region

Results from aircraft and surface observations provided evidence for the existence of mesoscale circulations over the Boreal Ecosystem-Atmosphere Study (BOREAS) domain. Using an integrated approach that included the use of analytical modeling, numerical modeling, and data analysis, we have found that there are substantial contributions to the total budgets of heat over the BOREAS domain generated by mesoscale circulations. This effect is largest when the synoptic flow is relatively weak, yet it is present under less favorable conditions, as shown by the case study presented here. While further analysis is warranted to document this effect, the existence of mesoscale flow is not surprising, since it is related to the presence of landscape patches, including lakes, which are of a size on the order of the local Rossby radius and which have spatial differences in maximum sensible heat flux of about 300 W m-2. We have also analyzed the vertical temperature profile simulated in our case study as well as high-resolution soundings and we have found vertical profiles of temperature change above the boundary layer height, which we attribute in part to mesoscale contributions. Our conclusion is that in regions with organized landscapes, such as BOREAS, even with relatively strong synoptic winds, dynamical scaling criteria should be used to assess whether mesoscale effects should be parameterized or explicitly resolved in numerical models of the atmosphere.

Journal of Geophysical Research D: Atmospheres↗

USGS2004

Effects of the fungicides mancozeb and chlorothalonil on fluxes of CO2, N2O, and CH4 in a fertilized Colorado grassland soil

[1] Management of agricultural soil plays an important role in present and future atmospheric concentrations of the greenhouse gases carbon dioxide (CO 2 ), nitrous oxide (N 2 O), and methane (CH 4 ). Pesticides are used as management tools in crop production, but little is known about their effects on soil‐atmosphere exchange of CO 2 , N 2 O, and CH 4 . Field studies described in this paper determined the effect of two commonly used fungicides, mancozeb and chlorothalonil, on trace gas exchange. Separate experimental plots, 1 m 2 , were established in nitrogen fertilized no‐tilled native grassland and tilled soils with and without fungicide application. Two studies were conducted. The first study was initiated in June 1999 and lasted for 1 year with monthly flux measurements from tilled and no‐till soils. The second study commenced in August 2001 with twelve weekly measurements from tilled soils only. From both studies mancozeb suppressed emissions of CO 2 and N 2 O in the tilled soil by an average of 28% and 47%, respectively. This suppression corresponded with efficacy periods of 14–29 and 56–77 days, respectively. From the no‐till soils mancozeb decreased CO 2 and N 2 O emissions by 33% and 80% for periods of 29 and 94 days, respectively. Mancozeb inhibited CH 4 consumption in the first study by 46% and 71% in the tilled and no‐till soil for periods of 8 and 29 days, respectively, but had no effect in the second study. From both studies chlorothalonil initially suppressed CO 2 and N 2 O emissions and enhanced CH 4 uptake in the tilled soil by an average of 37%, 40%, and 115%, respectively. These effects corresponded with efficacy periods of 14–29, 21–56, and 1–14 days, respectively. In the no‐till soil chlorothalonil inhibited CO 2 and N 2 O emissions and enhanced CH 4 uptake by 29%, 48%, and 86% for periods of 29, 56, and 56 days, respectively. Following the initial period of suppression, chlorothalonil subsequently enhanced N 2 O emissions in the tilled soil by an average of 51% and in the no‐till soil by 81% before returning to near background levels. The beginning of increased N 2 O emissions from the chlorothalonil‐amended plots corresponded with a maximum soil concentration of the chlorothalonil degradate, 4‐hydroxy‐2, 5, 6‐trichloroisophthalonitrile. The site specific global warming potential (GWP) resulting from the fluxes of CO 2 , N 2 O, and CH 4 from all soils was determined to decrease by an average 26% and 21% as a result of a single application of mancozeb or chlorothalonil, respectively. The decrease in CO 2 emissions in the fungicide‐amended plots potentially could result in the conservation of as much as 1200 and 2400 kg C ha −1 yr −1 organic carbon in the tilled and no‐till plots, respectively. Therefore it is feasible that application of certain fungicides to agricultural soil might lead to enhanced soil carbon sequestration and thus have additional positive effects on atmospheric CO 2 concentrations.

Journal of Geophysical Research D: Atmospheres↗

USGS2008

Northerly surface winds over the eastern North Pacific Ocean in spring and summer

Persistent spring and summer northerly surface winds are the defining climatological feature of the western coast of North America, especially south of the Oregon coast. Northerly surface winds are important for upwelling and a vast array of other biological, oceanic, and atmospheric processes. Intermittence in northerly coastal surface wind is characterized and wind events are quantitatively defined using coastal buoy data south of Cape Mendocino on the northern California coast. The defined wind events are then used as a basis for composites in order to explain the spatial evolution of various atmospheric and oceanic processes. Wind events involve large-scale changes in the three-dimensional atmospheric circulation including the eastern North Pacific subtropical anticyclone and southeast trade winds. Composites of QSCAT satellite scatterometer wind estimates from 1999 to 2005 based on a single coastal buoy indicate that wind events typically last 72-96 h and result in anomalies in surface wind and Ekman pumping that extend over 1000 kin from the west coast of North America. It may be useful to consider ocean circulation and dependent ecosystem dynamics and the distribution of temperature, moisture, and aerosols in the atmospheric boundary layer in the context of wind events defined herein. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research D: Atmospheres↗

USGS2008

Diurnal and vertical variability of the sensible heat and carbon dioxide budgets in the atmospheric surface layer

The diurnal and vertical variability of heat and carbon dioxide (CO2) in the atmospheric surface layer are studied by analyzing measurements from a 213 in tower in Cabauw (Netherlands). Observations of thermodynamic variables and CO2 mixing ratio as well as vertical profiles of the turbulent fluxes are used to retrieve the contribution of the budget terms in the scalar conservation equation. On the basis of the daytime evolution of turbulent fluxes, we calculate the budget terms by assuming that turbulent fluxes follow a linear profile with height. This assumption is carefully tested and the deviation ftom linearity is quantified. The budget calculation allows us to assess the importance of advection of heat and CO2 during day hours for three selected days. It is found that, under nonadvective conditions, the diurnal variability of temperature and CO2 is well reproduced from the flux divergence measurements. Consequently, the vertical transport due to the turbulent flux plays a major role in the daytime evolution of both scalars and the advection is a relatively small contribution. During the analyzed days with a strong contribution of advection of either heat or carbon dioxide, the flux divergence is still an important contribution to the budget. For heat, the quantification of the advection contribution is in close agreement with results from a numerical model. For carbon dioxide, we qualitatively corroborate the results with a Lagrangian transport model. Our estimation of advection is compared with, traditional estimations based on the Net Ecosystem-atmosphere Exchange (NEE). Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research D: Atmospheres↗

USGS2003

Oxygen-18 concentrations in recent precipitation and ice cores on the Tibetan Plateau

A detailed study of the climatic significance of δ 18 O in precipitation was completed on a 1500 km southwest-northeast transect of the Tibetan Plateau in central Asia. Precipitation samples were collected at four meteorological stations for up to 9 years. This study shows that the gradual impact of monsoon precipitation affects the spatial variation of δ 18 O-T relationship along the transect. Strong monsoon activity in the southern Tibetan Plateau results in high precipitation rates and more depleted heavy isotopes. This depletion mechanism is described as a precipitation “amount effect” and results in a poor δ 18 O-T relationship at both seasonal and annual scales. In the middle of the Tibetan Plateau, the effects of the monsoon are diminished but continue to cause a reduced correlation of δ 18 O and temperature at the annual scale. At the monthly scale, however, a significant δ 18 O-T relationship does exist. To the north of the Tibetan Plateau beyond the extent of the effects of monsoon precipitation, δ 18 O in precipitation shows a strong temperature dependence. δ 18 O records from two shallow ice cores and historic air temperature data were compared to verify the modern δ 18 O-T relationship. δ 18 O in Dunde ice core was positively correlated with air temperature from a nearby meteorological station in the north of the plateau. The δ 18 O variation in an ice core from the southern Plateau, however, was inversely correlated with precipitation amount at a nearby meteorological station and also the accumulation record in the ice core. The long-term variation of δ 18 O in the ice core record in the monsoon regions of the southern Tibetan Plateau suggest past monsoon seasons were probably more expansive. It is still unclear, however, how changes in large-scale atmosphere circulation might influence summer monsoon precipitation on the Tibetan Plateau.

Journal of Geophysical Research D: Atmospheres↗

USGS2006

Atmospheric mercury emissions from substrates and fumaroles associated with three hydrothermal systems in the western United States

This paper quantifies atmospheric mercury (Hg) emissions from substrates and fumaroles associated with three hydrothermal systems: Lassen Volcanic Center, California (LVC); Yellowstone Caldera, Wyoming (YC); and Dixie Valley, Nevada (DV). Substrate Hg fluxes were measured using field chamber methods at thermal and nonthermal sites. The highest Hg fluxes (up to 541 ng m −2 h −1 ) were measured at thermal active areas. Fluxes from altered and unaltered nonthermal sites were <10 ng m −2 h −1 and were comparable to those measured in natural low-Hg background regions for YC and DV, and at LVC they were slightly elevated. Similarly, reactive gaseous mercury concentrations were higher in thermal active areas. Using a Geographic Information System framework for scaling, estimated area-average Hg emissions from substrates were 0.9–3.8 ng m −2 h −1 at LVC, 0.8–2.8 ng m −2 h −1 at YC, and 0.4–0.5 ng m −2 h −1 at DV. At LVC, nonthermal areas were the primary substrate source of atmospheric Hg (>98%). At YC, substrate Hg emissions were dominated (50 to 90%) by acidically altered thermal areas. Substrate emissions at DV were low and primarily from nonthermal areas (66% to 75%). Fumarole emissions at LVC (91–146 kg yr −1 ) and YC (0.18–1.6 kg yr −1 for Mud Volcano) were estimated by applying Hg:H 2 O and Hg:CO 2 ratios in hydrothermal gas samples to H 2 O and CO 2 emissions. Applying total area-average emissions from substrates and thermal features at LVC, YC, and DV to similar systems across the conterminous United States, yearly atmospheric Hg emissions from active hydrothermal systems are projected to be 1.3–2.1 Mg.

Journal of Geophysical Research D: Atmospheres↗

USGS2003

Multiple oxygen and sulfur isotopic analyses on water-soluble sulfate in bulk atmospheric deposition from the southwestern United States

Sulfate is a major component of bulk atmospheric deposition (including dust, aerosol, fog, and rain). We analyzed sulfur and oxygen isotopic compositions of water-soluble sulfate from 40 sites where year-round dust traps collect bulk atmospheric deposition in the southwestern United States. Average sulfur and oxygen isotopic compositions (δ 34 S and δ 18 O) are 5.8 ± 1.4 (CDT) and 11.2 ± 1.9 (SMOW) (n = 47), respectively. Samples have an oxygen 17 anomaly (Δ 17 O), with an average value of 1.0 ± 0.6‰. Except for a weak positive correlation between δ 18 O and Δ 17 O values (r 2 ≈ 0.4), no correlation exists for δ 18 O versus δ 34 S, Δ 17 O versus δ 34 S, or any of the three isotopic compositions versus elevation of the sample site. Exceptional positive Δ 17 O values (up to 4.23‰) are found in samples from sites in the vicinity of large cities or major highways, and near-zero Δ 17 O values are found in samples close to dry lakes. Comparison of isotopic values of dust trap sulfate and desert varnish sulfate from the region reveals that varnish sulfate has average isotopic values that are ∼4.8‰ lower for δ 18 O, ∼2.1‰ higher for δ 34 S, and ∼0.3‰ lower for Δ 17 O than those of the present-day bulk deposition sulfate. Although other factors could cause the disparity, this observation suggests a possibility that varnish sulfate may have recorded a long-term atmospheric sulfate deposition during the Holocene or Pleistocene, as well as the differences between sulfur and oxygen isotopic compositions of the preindustrial bulk deposition sulfate and those of the industrial era.

Journal of Geophysical Research D: Atmospheres↗

USGS1997

Moss and soil contributions to the annual net carbon flux of a maturing boreal forest

We used input and decomposition data from 14 C studies of soils to determine rates of vertical accumulation of moss combined with carbon storage inventories on a sequence of burns to model how carbon accumulates in soils and moss after a stand-killing fire. We used soil drainage—moss associations and soil drainage maps of the old black spruce (OBS) site at the BOREAS northern study area (NSA) to areally weight the contributions of each moderately well drained, feathermoss areas; poorly drained sphagnum—feathermoss areas; and very poorly drained brown moss areas to the carbon storage and flux at the OBS NSA site. On this very old (117 years) complex of black spruce, sphagnum bog veneer, and fen systems we conclude that these systems are likely sequestering 0.01–0.03 kg C m −2 yr −1 at OBS-NSA today. Soil drainage in boreal forests near Thompson, Manitoba, controls carbon storage and flux by controlling moss input and decomposition rates and by controlling through fire the amount and quality of carbon left after burning. On poorly drained soils rich in sphagnum moss, net accumulation and long-term storage of carbon is higher than on better drained soils colonized by feathermosses. The carbon flux of these contrasting ecosystems is best characterized by soil drainage class and stand age, where stands recently burned are net sources of CO 2 , and maturing stands become increasingly stronger sinks of atmospheric CO 2 . This approach to measuring carbon storage and flux presents a method of scaling to larger areas using soil drainage, moss cover, and stand age information.

Journal of Geophysical Research D: Atmospheres↗

USGS2006

Atmospheric chemistry of a 33-34 hour old volcanic cloud from Hekla Volcano (Iceland): Insights from direct sampling and the application of chemical box modeling

On 28 February 2000, a volcanic cloud from Hekla volcano, Iceland, was serendipitously sampled by a DC-8 research aircraft during the SAGE III Ozone Loss and Validation Experiment (SOLVE I). It was encountered at night at 10.4 km above sea level (in the lower stratosphere) and 33-34 hours after emission. The cloud is readily identified by abundant SO2 (???1 ppmv), HCl (???70 ppbv), HF (???60 ppbv), and particles (which may have included fine silicate ash). We compare observed and modeled cloud compositions to understand its chemical evolution. Abundances of sulfur and halogen species indicate some oxidation of sulfur gases but limited scavenging and removal of halides. Chemical modeling suggests that cloud concentrations of water vapor and nitric acid promoted polar stratospheric cloud (PSC) formation at 201-203 K, yielding ice, nitric acid trihydrate (NAT), sulfuric acid tetrahydrate (SAT), and liquid ternary solution H2SO4/H2O/HNO3 (STS) particles. We show that these volcanically induced PSCs, especially the ice and NAT particles, activated volcanogenic halogens in the cloud producing >2 ppbv ClOx. This would have destroyed ozone during an earlier period of daylight, consistent with the very low levels of ozone observed. This combination of volcanogenic PSCs and chlorine destroyed ozone at much faster rates than other PSCs that Arctic winter. Elevated levels of HNO3 and NOy in the cloud can be explained by atmospheric nitrogen fixation in the eruption column due to high temperatures and/or volcanic lightning. However, observed elevated levels of HOx remain unexplained given that the cloud was sampled at night. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research D: Atmospheres↗

USGS1997

Winter CO2 fluxes in a boreal forest

We measured soil respiration during two winters in three different ecotypes of the BOREAS northern study area. The production of CO 2 was continuous throughout the winter and, when totaled for the winter of 1994–1995, was equivalent to the release of ∼40–55 g C/m 2 from the soil surface. As soils cooled in the early winter, the CO 2 production rate decreased in a manner that appeared to be exponentially related to shallow soil temperatures. This exponential relationship was not observed when soils began to warm, possibly indicating that there may be additional or different processes responsible for increased CO 2 production during winter warming events. We also measured CO 2 concentrations in soil gas and the Δ 14 C of the soil CO 2 . These measurements show that the CO 2 produced in winter is not simply the return to the atmosphere of the carbon fixed during the previous growing season. We suggest that the wintertime production of CO 2 originates, at least in part, from the decomposition of old organic carbon stored at depth in the soil.

Journal of Geophysical Research D: Atmospheres↗