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Inelastic properties of several high pressure crystalline phases of H2O: Ices II, III, and V

We have performed deformation experiments on cylinders of polycrystalline H 2 O at temperatures from 178 to 257 K at pressures to 500 MPa in the stability fields of ices II, III, and V. Ice II is the strongest of the phases, having a strength under laboratory conditions roughly comparable to that of ice I h . Ice V is somewhat weaker than ice II. Ice III is extremely weak and over geologic times must behave essentially as a liquid bounded below by ice V and above by ice II or I h . Phase relationships are complicated by a number of phase metastabilities, the most important of which is the existence of ice III in the ice II field for extended periods of time. Even under deformation at temperatures as low as 211 K (over 30 K below the ice III field), the transformations from III to II can not be made to happen in the laboratory.

Journal de Physique Colloques

Inelastic properties of ice Ih at low temperatures and high pressures

The aim of our research programme is to explore the rheological behavior of H 2 O ices under conditions appropriate to the interiors of the icy satellites of the outer planets in order to give insight into their deformation. To this end, we have performed over 100 constant-strain-rate compression tests at pressures to 500 MPa and temperatures as low as 77 K. At P > 30 MPa, ice I h fails by a shear instability producing faults in the maximum shear stress orientation and failure strength typically is independent of pressure. This unusual faulting behavior is thought to be connected with phase transformations localized in the shear zones. The steady-state strength follows rheological laws of the thermally-activated power-law type, with different flow law parameters depending on the range of test temperatures. The flow laws will be discussed with reference to the operating deformation mechanisms as deduced from optical-scale microstructures and comparison with other work.

Journal de Physique Colloques