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Results for “Groundwater Monitoring and Remediation”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

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At least 19 recordsLinked to original sources
USGS2011

Demonstration and validation of a regenerated cellulose dialysis membrane diffusion sampler for monitoring groundwater quality and remediation progress at DoD sites: Perchlorate and ordnance compounds

This final technical report documents the demonstration and validation of regenerated cellulose dialysis membrane diffusion samplers (RCDM samplers) for use in collecting groundwater samples for perchlorate and a suite of explosives compounds. This project, ER-0313, was funded by the Environmental Security Technology Certification Program (ESTCP). The primary objectives of the project were; (1) to determine the usefulness of RCDM samplers in collecting perchlorate and a suite of explosives compounds from groundwater, (2) to determine the optimum equilibration times for these constituents to diffuse into the RCDM sampler, (3) to compare water-quality results and sampling costs from samples collected with RCDM samplers to samples collected with a low-flow purging technique, and (4) to transfer the technology while gaining regulatory acceptance. Equilibration times were determined in bench-scale testing for perchlorate and 14 nitroaromatic and nitramine explosives compounds. Field comparisons were conducted at two Department of Defense (DoD) sites: (1) Aberdeen Proving Grounds (APG), Maryland, and, (2) Picatinny Arsenal, New Jersey. Samples collected with the two sampling techniques were compared graphically and statistically to determine the significance of any differences found. RCDM samplers were found to cost significantly less than samples collected with a low-flow purging procedure. Sampling time was reduced by 84%, compared to low-flow purging. The total sampling costs per sample were calculated to be 71% less with an RCDM sampler, compared to low-flow purging.

Maryland, New Jersey↗
USGS2014

Effects of a dual-pump crude-oil recovery system, Bemidji, Minnesota, USA

A crude-oil spill occurred in 1979 when a pipeline burst near Bemidji, MN. In 1998, the pipeline company installed a dual-pump recovery system designed to remove crude oil remaining in the subsurface at the site. The remediation from 1999 to 2003 resulted in removal of about 115,000 L of crude oil, representing between 36% and 41% of the volume of oil (280,000 to 316,000 L) estimated to be present in 1998. Effects of the 1999 to 2003 remediation on the dissolved plume were evaluated using measurements of oil thicknesses in wells plus measurements of dissolved oxygen in groundwater. Although the recovery system decreased oil thicknesses in the immediate vicinity of the remediation wells, average oil thicknesses measured in wells were largely unaffected. Dissolved-oxygen measurements indicate that a secondary plume was caused by disposal of the pumped water in an upgradient infiltration gallery; this plume expanded rapidly immediately following the start of the remediation in 1999. The result was expansion of the anoxic zone of groundwater upgradient and beneath the existing natural attenuation plume. Oil-phase recovery at this site was shown to be challenging, and considerable volumes of mobile and entrapped oil remain in the subsurface despite remediation efforts.

Minnesota↗
USGS2015

Arsenic cycling in hydrocarbon plumes: secondary effects of natural attenuation

Monitored natural attenuation is widely applied as a remediation strategy at hydrocarbon spill sites. Natural attenuation relies on biodegradation of hydrocarbons coupled with reduction of electron acceptors, including solid phase ferric iron (Fe(III)). Because arsenic (As) adsorbs to Fe-hydroxides, a potential secondary effect of natural attenuation of hydrocarbons coupled with Fe(III) reduction is a release of naturally occurring As to groundwater. At a crude-oil-contaminated aquifer near Bemidji, Minnesota, anaerobic biodegradation of hydrocarbons coupled to Fe(III) reduction has been well documented. We collected groundwater samples at the site annually from 2009 to 2013 to examine if As is released to groundwater and, if so, to document relationships between As and Fe inside and outside of the dissolved hydrocarbon plume. Arsenic concentrations in groundwater in the plume reached 230 µg/L, whereas groundwater outside the plume contained less than 5 µg/L As. Combined with previous data from the Bemidji site, our results suggest that (1) naturally occurring As is associated with Fe-hydroxides present in the glacially derived aquifer sediments; (2) introduction of hydrocarbons results in reduction of Fe-hydroxides, releasing As and Fe to groundwater; (3) at the leading edge of the plume, As and Fe are removed from groundwater and retained on sediments; and (4) downgradient from the plume, patterns of As and Fe in groundwater are similar to background. We develop a conceptual model of secondary As release due to natural attenuation of hydrocarbons that can be applied to other sites where an influx of biodegradable organic carbon promotes Fe(III) reduction.

Minnesota↗
USGS2007

Preliminary delineation of contaminated water-bearing fractures intersected by open-hole bedrock wells

Contaminated water‐bearing fractures intersected by open‐hole bedrock wells were preliminarily delineated through a combination of geophysical logging, vertical‐flow measurements, and downhole water sampling as part of remedial site investigations in southeastern New York. The wells investigated range from 100 to 450 feet in depth, have only shallow surface casing, and intersect multiple water‐bearing zones. The distribution of water‐bearing zones that intersect the wells was determined from single‐point resistance, caliper, fluid‐resistivity, temperature, and acoustic‐televiewer logs. Measurable flow in the wells was downward from upper producing zones to lower receiving zones that are poorly connected in the aquifer and that differ in hydraulic head as a result of nearby pumping. A down hole sampler was used to collect discrete and composite water samples for analysis of volatile organic compounds from producing zones that are self‐purging as a result of flow in the wells. The results obtained at two of the study sites are presented—the Spring Valley wellfield and the Mahopac business district. At the Spring Valley wellfield, a supply well completed in Mesozoic sandstone and conglomerate intersects water‐bearing zones at depths of 204 to 245 feet that produced contaminated water that was received by a zone at 278 feet. In the same well, a deeper zone at 345 feet produced uncontaminated water that was received by a zone at 403 feet. Correlation of information from the well, geophysical logs and drill cores from nearby monitoring wells, and bedrock outcrops indicates that most of the water‐bearing zones are bedding‐plane separations that probably provide pathways for contaminant transport in the bedrock aquifer for significant distances. In the Mahopac business district, a deep test well completed in Precambrian gneiss intersected shallow waterbearing zones at 50 to 79 feet that produced contaminated water that was received by deep zones at 260 and 328 feet. The water‐bearing zones consist of single or closely spaced multiple fractures with dips of 5 to 50 degrees. By analogy with the results from this test well, deep open‐hole wells in the area may serve as “short circuits” in the ground water flow system and allow direct transport of contaminants to deeper zones in the fractured‐bedrock aquifer. The methods presented can be used to investigate ground water flow and contamination in fractured‐bedrock aquifers in advance of more focused monitoring programs. The methods can be applied in existing open‐hole wells before test drilling and monitoring well installation to provide for efficient program design. The methods also can be used during the installation of monitoring wells to help determine completion depths and open intervals and to ensure that the wells are not serving as conduits for the flow of contaminated water.

New York↗
USGS2015

1DTempPro V2: new features for inferring groundwater/surface-water exchange

A new version of the computer program 1DTempPro extends the original code to include new capabilities for (1) automated parameter estimation, (2) layer heterogeneity, and (3) time-varying specific discharge. The code serves as an interface to the U.S. Geological Survey model VS2DH and supports analysis of vertical one-dimensional temperature profiles under saturated flow conditions to assess groundwater/surface-water exchange and estimate hydraulic conductivity for cases where hydraulic head is known.

Groundwater Monitoring & Remediation↗
USGS2013

Ambient changes in tracer concentrations from a multilevel monitoring system in Basalt

Starting in 2008, a 4-year tracer study was conducted to evaluate ambient changes in groundwater concentrations of a 1,3,6-naphthalene trisulfonate tracer that was added to drill water. Samples were collected under open borehole conditions and after installing a multilevel groundwater monitoring system completed with 11 discrete monitoring zones within dense and fractured basalt and sediment layers in the eastern Snake River aquifer. The study was done in cooperation with the U.S. Department of Energy to test whether ambient fracture flow conditions were sufficient to remove the effects of injected drill water prior to sample collection. Results from thief samples indicated that the tracer was present in minor concentrations 28 days after coring, but was not present 6 months after coring or 7 days after reaming the borehole. Results from sampling the multilevel monitoring system indicated that small concentrations of the tracer remained in 5 of 10 zones during some period after installation. All concentrations were several orders of magnitude lower than the initial concentrations in the drill water. The ports that had remnant concentrations of the tracer were either located near sediment layers or were located in dense basalt, which suggests limited groundwater flow near these ports. The ports completed in well-fractured and vesicular basalt had no detectable concentrations.

Idaho↗
USGS2021

Accuracy of flowmeters measuring horizontal flow in fractured-rock simulators

Laboratory evaluations of flowmeter response to flow in fractured-rock simulators are needed to improve understanding of data collected in field settings. The ability of flowmeters to accurately measure the velocity and direction of water flowing between parallel plates was used as a surrogate for instrument response in fractured-rock aquifers. A colloidal borescope flowmeter and a heat-pulse flowmeter were deployed in a fractured rock simulator with 4-inch and 6-inch inner-diameter, uncased wells with 0.39- and 1.0-inch fracture apertures and groundwater velocities from 35 to 975 ft/d. The colloidal borescope measurements and applied velocities were positively correlated in all wells and apertures (the coefficient of determination [ r 2 ] = 0.61–0.89) and most accurately measured direction at higher velocities. The mean directional error in colloidal borescope measurements was less than 17° in 6-inch wells and 31° in the 4-inch wells at velocities between 92 and 958 ft/d. Heat-pulse flowmeter measurements were 0.001 to 0.004 times less than applied rates and may indicate that water was moving around rather than through the instrument's integrated packer. The mean directional error of heat-pulse flowmeter measurements were about 18 and 42° in the 0.39- and 1.0-inch fractures, respectively, for groundwater velocities within the manufacturer's suggested range of application (0.5–100 ft/d). Measurements made at vertical increments and fracture positions in the well using the colloidal borescope indicate that laminar flow occurs within the central 50% of the fracture but measurements above or below are likely affected by eddy currents.

Groundwater Monitoring & Remediation↗
USGS2023

One Ranney well can make a difference: The impacts of a radial collector well on groundwater level and quality in the Cedar River alluvial aquifer

The City of Cedar Rapids, Iowa, depends on groundwater from the Cedar River alluvial aquifer for residential and industrial use. In 2020, the city completed an additional radial collector well, or Ranney well, and was concerned that pumping from the well at high rates may lower water level elevations in the aquifer, reduce yields from nearby production wells, and change the quality of produced water. During an operational test of the well's pumps, the U.S. Geological Survey and the city collected water level and water quality data to evaluate the effects of increased pumping rates on the aquifer and nearby production wells. Results indicated that a high rate of pumping from the new well caused sustained declines in water levels near the well and other nearby production wells, and, if maintained, the aquifer water level in the vicinity would continue to decline to levels observed during the 2012 drought. Aquifer specific conductance and temperature were altered and matched trends and values of the river, and river-to-well travel time was shortened from 7-17 days to about 3 days. Results may also provide insights to other municipal water resource managers when considering wellfield design, production expectations, and long-term management strategies for radial collector well production during drought, low streamflow, and times when high concentrations of nitrate-N or organic pesticide compounds in the river may limit production options.

Iowa↗
USGS2007

Design and implementation of evapotranspiration measuring equipment for Owens Valley, California

As part of a plant survivability and ground water study in Owens Valley, California, semipermanent installations are used to measure continuous range‐land evapotranspiration in the valley's phreatophyte community. A proposed mobile installation also has been designed. The semipermanent micrometeoro‐logical station collects continuous data for solution of the Bowen ratio/energy budget equation and the Penman combination equation. Three sites were chosen for this type of installation to provide a representative sampling of Owens Valley. The proposed mobile aerodynamic installation should be capable of calculating evapotranspiration by the eddy correlation method. This instrumentation will be used throughout the valley for short periods of time (up to five days). Many problems with equipment operation, calibration and design have been identified and resolved by means of improved calibration techniques, systematic error‐removal techniques, reduced cycle times, modified equipment design and proper observer training. The collected evapotranspiration data will be instrumental in developing a one‐dimensional evapotranspiration flux algorithm for a model of valleywide ground water flow.

California↗
USGS2007

A wireline piston core barrel for sampling cohesionless sand and gravel below the water table

A coring device has been developed to obtain long and minimally disturbed samples of saturated cohesionless sand and gravel. The coring device, which includes a wireline and piston, was developed specifically for use during hollow-stem auger drilling but it also offers possibilities for cable tool and rotary drilling. The core barrel consists of an inner liner made of inexpensive aluminum or plastic tubing, a piston for core recovery, and an exterior steel housing that protects the liner when the core barrel is driven into the aquifer. The core barrel, which is approximately 1.6m (5.6 feet) long, is advanced ahead of the lead auger by hammering at the surface on drill rods that are attached to the core barrel. After the sampler has been driven 1.5m (5 feet), the drill rods are detached and a wireline is used to hoist the core barrel, with the sample contained in the aluminum or plastic liner, to the surface. A vacuum developed by the piston during the coring operation provides good recovery of both the sediment and aquifer fluids contained in the sediment. In the field the sample tubes can be easily split along their length for on-site inspection or they can be capped with the pore water fluids inside and transported to the laboratory. The cores are 5cm (2 inches) in diameter by 1.5m (5 feet) long. Core acquisition to depths of 35m (115 feet), with a recovery greater than 90 percent, has become routine in University of Waterloo aquifer studies. A large diameter (12.7cm [5 inch]) version has also been used successfully. Nearly continuous sample sequences from sand and gravel aquifers have been obtained for studies of sedimentology, hydraulic conductivity, hydrogeochemistry and microbiology.

Groundwater Monitoring & Remediation↗
USGS2007

Organic contamination of ground water at Gas Works Park, Seattle, Washington

Gas Works Park, in Seattle, Washington, is located on the site of a coal and oil gasification plant that ceased operation in 1956. During operation, many types of wastes, including coal, tar, and oil, accumulated on-site. The park soil is currently (1986) contaminated with compounds such as polynuclear aromatic hydrocarbons, volatile organic compounds, trace metals, and cyanide. Analyses of water samples from a network of observation wells in the park indicate that these compounds are also present in the ground water. Polynuclear aromatic hydrocarbons and volatile organic compounds were identified in ground water samples in concentrations as large as 200 mg/L. Concentrations of organic compounds were largest where ground water was in contact with a non-aqueous phase liquid in the soil. Where no non-aqueous phase liquid was present, concentrations were much smaller, even if the ground water was in contact with contaminated soils. This condition is attributed to weathering processes in which soluble, low-molecular-weight organic compounds are preferentially dissolved from the non-aqueous phase liquid into the ground water. Where no non-aqueous phase liquid is present, only stained soils containing relatively insoluble, high-molecular-weight compounds remain. Concentrations of organic contaminants in the soils may still remain large.

Washington↗
USGS2007

Field methods for measurement of ground water redox chemical parameters

An inexpensive, versatile, and portable system is presented, which facilitates rapid field determinations of redox potentials, pH, conductivity, ferrous and total iron, nitrite, specific conductance, dissolved oxygen, and temperature. Accuracy is facilitated by on‐site measurements of most parameters using specially constructed flow‐through cells and, for several analyses, sealed reagent ampoules, which can be broken and developed inside a flowing stream of ground water. Coupled with laboratory analyses of more stable ground water parameters, this system can provide accurate and relatively inexpensive determinations of redox conditions in ground water.

Groundwater Monitoring & Remediation↗
USGS2007

Application of electromagnetic logging to contamination investigations in glacial sand-and-gravel aquifers

Electromagnetic (EM) logging provides an efficient method for high‐resolution, vertical delineation of electrically conductive contamination in glacial sand‐and‐gravel aquifers. LM. gamma, and lithologic logs and specific conductance data from sand‐and‐gravel aquifers at five sites in the northeastern United States were analyzed to define the relation of KM conductivity to aquifer lithology and water quality. Municipal waste disposal, septic waste discharge, or highway deicing salt application at these sites has caused contaminant plumes in which the dissolved solids concentration and specific conductance of ground water exceed background levels by as much as 10 to 20 limes. The major hydrogeologic factors that affected KM log response at the five sites were the dissolved solids concentration of the ground water and the silt and clay content in the aquifer. KM conductivity of sand and gravel with uncontaminated water ranged from less than 5 to about 10 millisiemens per meter (mS/m); that of silt and clay zones ranged from about 15 to 45 mS/m: and that of the more highly contaminated zones in sand and gravel ranged from about 10 to more than 80 mS/m. Specific conductance of water samples from screened intervals in sand and gravel at selected monitoring well installations was significantly correlated with KM conductivity. CM logging can be used in glacial sand‐and‐gravel aquifer investigations to (1) determine optimum depths for the placement of monitoring well screens: (2) provide a nearly continuous vertical profile of specific conductance to complement depth‐specific water quality samples; and (3) identify temporal changes in water quality through sequential logging. Detailed lithologic or gamma logs, preferably both, need to be collected along with the F.M logs to define zones in which elevated EM conductivity is caused by the presence of sill and clay beds rather than contamination.

Connecticut, Massachusetts, New York, Vermont↗
USGS2007

Detection of contaminant plumes by bore­ hole geophysical logging

Two borehole geophysical methods—electromagnetic induction and natural gamma radiation logs—were used to vertically delineate landfill leachate plumes in a glacial aquifer. Geophysical logs of monitoring wells near two land-fills in a glacial aquifer in west-central Vermont show that borehole geophysical methods can aid in interpretation of geologic logs and placement of monitoring well screens to sample landfill leachate plumes. Zones of high electrical conductance were delineated from the electromagnetic log in wells near two landfills. Some of these zones were found to correlate with silt and clay units on the basis of drilling and gamma logs. Monitoring wells were screened specifically in zones of high electrical conductivity that did not correlate to a silt or clay unit. Zones of high electrical conductivity that did not correlate to a silt or clay unit were caused by the presence of ground water with a high specific conductance, generally from 1000 to 2370 μS/cm (microsiemens per centimeter at 25 degrees Celsius). Ambient ground water in the study area has a specific conductance of approximately 200 to 400 μS/cm. Landfill leachate plumes were found to be approximately 5 to 20 feet thick and to be near the water table surface.

Groundwater Monitoring & Remediation↗
USGS2007

Fate of MTBE relative to benzene in a gasoline-contaminated aquifer (1993-98):

Methyl tert -butyl ether (MTBE) and benzene have been measured since 1993 in a shallow, sandy aquifer contaminated by a mid-1980s release of gasoline containing fuel oxygenates. In wells downgradient of the release area, MTBK was detected before benzene, reflecting a chromatographic-like separation of these compounds in the direction of ground water flow. Higher concentrations of MTBE and benzene were measured in the deeper sampling ports of multilevel sampling wells located near the release area, and also up to 10 feet (3 m) below the water table surface in nested wells located farther from the release area. This distribution of higher concentrations at depth is caused by recharge events that deflect originally horizontal ground water flowlines. In the laboratory, microcosms containing aquifer material incubated with uniformly labeled 14 C-MTBE under aerobic and anaerobic. Fe(III)-reducing conditions indicated a low but measurable biodegradation potential (<3% 14 C-MTBW as 14 CO 2 ) after a seven-month incubation period, Tert -butyl alcohol (TBA), a proposed microbial-MTBE transformation intermediate, was detected in MTBE-contaminated wells, but TBA was also measured in unsaturated release area sediments. This suggests that TBA may have been present in the original fuel spilled and does not necessarily reflect microbial degradation of MTBE. Combined, these data suggest that milligram per liter to microgram per liter decreases in MTBE concentrations relative to benzene are caused by the natural attenuation processes of dilution and dispersion with less-contaminated ground water in the direction of flow rather than biodegradation at this point source gasoline release site.

Groundwater Monitoring & Remediation↗
USGS2007

Elements in cottonwood trees as an indicator of ground water contaminated by landfill leachate

Ground water at the Norman Landfill Research Site is contaminated by a leachate plume emanating from a closed, unlined landfill formerly operated by the city of Norman, Oklahoma, Ground water contaminated by the leachate plume is known to be elevated in the concentration of many, organic and inorganic constituents. Specific conductance, alkalinity, chloride, dissolved organic carbon, boron, sodium, strontium, and deuterium in ground water are considered to be indicators of the leachate plume at this site. Leaf samples of broad-leafed cottonwood, Populus deltoides, were collected from 57 sites around the closed landfill. Cottonwood, a phreatophyte or “well plant,” functions as a & surrogate well and serves as a ground water quality sampler. The leaf samples were combusted to ash and analyzed by instrumental neutron activation for 35 elements and by prompt-gamma instrumental neutron activation, for boron. A monitoring well was located within a few meters of a sampled cottonwood tree at 15 of the 57 sites, and ground water samples were collected from these monitoring wells simultaneously with a leaf sample. The chemical analyses of the ground water and leaf samples from these 15 sites indicated that boron, bromine, sodium, and strontium concentrations in leaves were significantly correlated with leachate indicator constituents in ground water. A point-plot map of selected percentiles indicated high concentrations of boron, bromine, and sodium in leaf ash from sites downgradient of the most recent landfill and from older landfills nearby. Data from leaf analysis greatly extended the known areal extent of the leachate plume previously determined from a network of monitoring wells and geophysical surveys. This phytosgeochemical study provided a cost-effective method for assessing the extent of a leachate plume from an old landfill. Such a method may be useful as a preliminary sampling tool to guide the design of hydrogeochemical and geophysical studies.

Oklahoma↗
USGS2007

Can contaminant transport models predict breakthrough?

A solute breakthrough curve measured during a two-well tracer test was successfully predicted in 1986 using specialized contaminant transport models. Water was injected into a confined, unconsolidated sand aquifer and pumped out 125 feet (38.3 m) away at the same steady rate. The injected water was spiked with bromide for over three days; the outflow concentration was monitored for a month. Based on previous tests, the horizontal hydraulic conductivity of the thick aquifer varied by a factor of seven among 12 layers. Assuming stratified flow with small dispersivities, two research groups accurately predicted breakthrough with three-dimensional (12-layer) models using curvilinear elements following the arc-shaped flowlines in this test. Can contaminant transport models commonly used in industry, that use rectangular blocks, also reproduce this breakthrough curve? The two-well test was simulated with four MODFLOW-based models, MT3D (FD and HMOC options), MODFLOWT, MOC3D, and MODFLOW-SURFACT. Using the same 12 layers and small dispersivity used in the successful 1986 simulations, these models fit almost as accurately as the models using curvilinear blocks. Subtle variations in the curves illustrate differences among the codes. Sensitivities of the results to number and size of grid blocks, number of layers, boundary conditions, and values of dispersivity and porosity are briefly presented. The fit between calculated and measured breakthrough curves degenerated as the number of layers and/or grid blocks decreased, reflecting a loss of model predictive power as the level of characterization lessened. Therefore, the breakthrough curve for most field sites can be predicted only qualitatively due to limited characterization of the hydrogeology and contaminant source strength.

Alabama↗