USGS Science⌕ Search

SEARCH · USGS Science

Results for “Green Chemistry”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 19 recordsLinked to original sources
USGS2019

Control of invasive sea lampreys using the piscicides TFM and niclosamide: Toxicology, successes & future prospects

The invasion of the Laurentian Great Lakes of North America by sea lampreys ( Petromyzon marinus ) in the early 20th century contributed to the depletion of commercial, recreational and culturally important fish populations, devastating the economies of communities that relied on the fishery. Sea lamprey populations were subsequently controlled using an aggressive integrated pest-management program which employed barriers and traps to prevent sea lamprey from migrating to their spawning grounds and the use of the piscicides (lampricides) 3-trifluoromethyl-4-nitrophenol (TFM) and niclosamide to eliminate larval sea lampreys from their nursery streams. Although sea lampreys have not been eradicated from the Great Lakes, populations have been suppressed to less than 10% of their peak numbers in the mid-1900s. The ongoing use of lampricides provides the foundation for sea lamprey control in the Great Lakes, one of the most successful invasive species control programs in the world. Yet, significant gaps remain in our understanding of how lampricides are taken-up and handled by sea lampreys, how lampricides exert their toxic effects, and how they adversely affect non-target invertebrate and vertebrates species. In this review we examine what has been learned about the uptake, handling and elimination, and the mode of TFM and niclosamide toxicity in lampreys and in non-target animals, particularly in the last 10 years. It is now clear that the mode of TFM toxicity is the same in non-target fishes and lampreys, in which TFM interferes with oxidative phosphorylation by the mitochondria leading to decreased ATP production. Vulnerability to TFM is related to abiotic factors such as water pH and alkalinity, which we propose changes the relative amounts of the bioavailable un-ionized form of TFM in the gill microenvironment. Niclosamide, which is also a molluscicide used to control snails in areas prone to schistosomiasis infections of humans, also likely works by uncoupling oxidative phosphorylation, but less is known about other aspects of its toxicology. The effects of TFM include reductions in energy stores, particularly glycogen and high energy phosphagens. However, non-target fishes readily recover from sub-lethal TFM exposure as demonstrated by the rapid restoration of energy stores and clearance of TFM. Although both TFM and niclosamide are non-persistent in the environment and critical for sea lamprey control, increasing public and institutional concerns about pesticides in the environment makes it imperative to explore other means of sea lamprey control. Accordingly, we also address possible “next-generation” strategies of sea lamprey control including genetic tools such as RNA interference and CRISPR-Cas9 to impair critical physiological processes (e.g. reproduction, digestion, metamorphosis) in lamprey, and the use of green chemistry to develop more environmentally benign chemical methods of sea lamprey control.

Great Lakes↗
USGS2014

Petrology and chemistry of the Green Acres gabbro complex near Winchester, Riverside County, California

The Cretaceous Green Acres layered igneous complex, northeast of Winchester, California, is composed of a suite of olivine- and hornblende-bearing gabbros in the Peninsular Ranges batholith within the Perris tectonic block. A consistent mineral assemblage is observed throughout the complex, but there is considerable textural and modal heterogeneity. Both preclude a consistent set of principles based on appearance and mineralogy on which to delineate map units. Distinct changes in the chemistry of olivine, pyroxene, and hornblende, however, serve to define discrete mappable units, and the complex has been divided into five geochemical map units on this basis. Limited whole-rock data show the Green Acres complex is chemically comparable to other Peninsular Ranges batholith gabbroic rocks, and rare earth element (REE) concentrations and patterns are typical of magmas generated in convergent margin settings. For the complex as a whole, olivine is Fo 80–35 , plagioclase is An 100–64 , clinopyroxene is Wo 49–41 En 48–38 Fs 18–6 and Wo 36–26 En 65–42 Fs 30–8 , and orthopyroxene is Wo 5–0 En 78–42 Fs 50–21 , where Fo is forsterite, An is anorthite, Wo is wollastonite, En is enstatite, and Fs is ferrosilite. The Mg/(Mg + ΣFe) atomic ratio in hornblende ranges from 0.84 to 0.50. Magmatic lineations and modal and textural layering are prevalent throughout the complex. Mineral chemistry does not change in any systematic way within and between layers in any map unit. Although the strike of layering varies, in any map unit at any given location it is the same in all units irrespective of intrusive order. Thin dikes, typically late-stage hornblende gabbro, commonly intrude parallel to layering. The strikes of magmatic lineations and modal layers are consistent with the populations of strikes of fabrics in the metamorphic basement as well as tectonic features in surrounding, postgabbro granitic rocks. These relations imply that the regional state of stress at the time of gabbro emplacement played a role in layer formation in conjunction with thermal and hydraulic pressure perturbations.

California↗
USGS2009

Hydrolysis of polycarbonate in sub-critical water in fused silica capillary reactor with in situ Raman spectroscopy

The advantages of using fused silica capillary reactor (FSCR) instead of conventional autoclave for studying chemical reactions at elevated pressure and temperature conditions were demonstrated in this study, including the allowance for visual observation under a microscope and in situ Raman spectroscopic characterization of polycarbonate and coexisting phases during hydrolysis in subcritical water .

Green Chemistry↗
USGS1970

Green River oil shale—concept of origin extended: An interdisciplinary problem being attacked from both ends

A much fuller understanding of the Green River oil shale and its organic chemistry will emerge when the geologists, paleontologists, organic chemists, biologists, paleolimnologists, and biogeochemists, who are now working on it, integrate their findings with those of the others. We know from the geology, paleontology, and paleolimnology that the biologic progenitors of the organic substance in the Green River oil shale could only have been microscopic algae, and other micro-organisms, that grew and accumulated in the central parts of large, shallow lakes that existed under a subtropical climate. The only nonlacustrine organic components were wind-blown, or water borne, pollens and waxy spores. These, however, made up a large and important part of the organic-rich sediment. The geology of the Green River Formation shows that as the algal and pollen-rich sediment was buried deeper and deeper, progressively more of its pore water and dissolved constituents were expressed. Static pressures may have reached as much as 210 kg cm −2 , and the ambient temperature rose, with depth, to somewhere within the range between 90° and 125° C. Beneath the ancient lakes a tectonically quiescent environment persisted for tens of millions of years after their organic sediments had been deeply buried. The organic material of the Green River oil shale can be divided into three fractions—a small bitumen fraction that is extractable with common organic solvents, a major fraction called koerogen that consists of insoluble pyrobitumens, and a somewhat smaller inert fraction that is neither soluble nor does it yield oil on pyrolysis. As all three fractions originated in the same algal, pollen-rich sediment, an explanation for their marked differences must be sought in their geochemical history or from a study of the modern analogues of their progenitors. The components of the bitumen fraction consisted of “biological markers” that were inherited from the Eocene plants and animals in which they originally formed. Diagenesis has changed these hydrogen-rich compounds, but not enough to obscure their provenance. Kerogen presumably became insoluble because its hydrogen-rich components polymerized. My speculation is that the inert fraction was derived from a polyphenolic substance produced in the original algal ooze by “non-enzymatic browning.” Only three Classes of non-marine algae need be considered as progenitors of the Green River oil shale; the Xanthophyceae, the Chlorophyceae, and the Cyanophyceae. Only the Cyanophyceae (the blue-green algae) meet the biologic and paleontologic requirements to have served as the dominant precursors of the Green River oil shale. Several other oil shales clearly were derived from the Xanthophyceae, specifically Botryococcus. The blue-green algal ooze now forming, and accumulating, in Mud Lake, Florida, has been studied biologically and chemically as a possible present-day analogue of the Green River oil shale precursor. In this small lake we have established the fact that a bacterial inhibitor is produced, which inhibits decay of the algae and thereby permits the accumulation of energy-rich organic compounds. We infer that a similar indigenous inhibitor must have acted in the Eocene lakes to permit them to become the huge energy sinks they were. Studies of the organic chemistry of living blue-green algae show that they contain appreciable percentages of fatty acids, hydrocarbons, and very large percentages of proteins. These promising, energy-rich compounds could serve as source materials for potential conversion into oil shale in the geologic future. Certain marine anaerobic bacteria convert fatty acids into aliphatic hydrocarbons. Fresh-water obligate anaerobes should be investigated to see if they also convert fatty acids into hydrocarbons. The part played by aquatic animals that live in, or on, freshwater algal ooze in synthesizing hydrocarbons has not been investigated, but deserves attention. Pollen grains, of course, must be considered an important precursor of hydrocarbons produced on pyrolysis. They contain far higher percentages of long chain hydrocarbons and alcohols than most plant materials. The major problem ahead is to account for the progressive hydrogenation and subsequent polymerization of the relatively oxygen-rich constituents of algae such as the polysaccharides, amino acids, ammo sugars, and fatty acids into the insoluble pyrobitumens that constitute, particularly, the kerogen fraction of the Green River oil shale.

Wyoming↗
USGS2002

Water quality, selected chemical characteristics, and toxicity of base flow and urban stormwater in the Pearson Creek and Wilsons Creek Basins, Greene County, Missouri, August 1999 to August 2000

The chemistry and toxicity of base flow and urban stormwater were characterized to determine if urban stormwater was degrading the water quality of the Pearson Creek and Wilsons Creek Basins in and near the city of Springfield, Greene County, Missouri. Potentially toxic components of stormwater (nutrients, trace metals, and organic compounds) were identified to help resource managers identify and minimize the sources of toxicants. Nutrient loading to the James River from these two basins (especially the Wilsons Creek Basin) is of some concern because of the potential to degrade downstream water quality. Toxicity related to dissolved trace metal constituents in stormwater does not appear to be a great concern in these two basins. Increased heterotrophic activity, the result of large densities of fecal indicator bacteria introduced into the streams after storm events, could lead to associated dissolved oxygen stress of native biota. Analysis of stormwater samples detected a greater number of polycyclic aromatic hydrocarbons (PAHs) and volatile organic compounds (VOCs) than were present in base-flow samples. The number and concentrations of pesticides detected in both the base-flow and stormwater samples were similar.Genotoxicity tests were performed to determine the bioavilability of chemical contaminants and determine the potential harmful effects on aquatic biota of Pearson Creek and Wilsons Creek. Genotoxicity was determined from dialysates from both long-term (approximately 30 days) and storm-event (3 to 5 days) semipermeable membrane device (SPMD) samples that were collected in each basin. Toxicity tests of SPMD samples indicated evidence of genotoxins in all SPMD samples. Hepatic activity assessment of one long-term SPMD sample indicated evidence of contaminant uptake in fish. Chemical analyses of the SPMD samples found that relatively few pesticides and pesticide metabolites had been sequestered in the lipid material of the SPMD; however, numerous PAHs and VOCs were detected in both the long-term and the storm-event exposures. It is suspected, based on the compounds detected in the SPMDs and the water samples, that the observed genotoxicity is largely the result of PAHs and VOCs that were probably derived from petroleum inputs or combustion sources. Therefore the water quality and thus the aquatic environments in the Pearson Creek and Wilsons Creek Basins are being degraded by urban derived contaminants.

Missouri↗
USGS2009

A Collection of Chemical, Mineralogical, and Stable Isotopic Compositional Data for Green River Oil Shale from Depositional Center Cores in Colorado, Utah, and Wyoming

For over half a century, the U.S. Geological Survey and collaborators have conducted stratigraphic and geochemical studies on the Eocene Green River Formation, which is known to contain large oil shale resources. Many of the studies were undertaken in the 1970s during the last oil shale boom. One such study analyzed the chemistry, mineralogy, and stable isotopy of the Green River Formation in the three major depositional basins: Piceance basin, Colo.; Uinta basin, Utah; and the Green River basin, Wyo. One depositional-center core from each basin was sampled and analyzed for major, minor, and trace chemistry; mineral composition and sulfide-mineral morphology; sulfur, nitrogen, and carbon forms; and stable isotopic composition (delta34S, delta15N, delta13C, and delta18O). Many of these data were published and used to support interpretative papers (see references herein). Some bulk-chemical and carbonate-isotopic data were never published and may be useful to studies that are currently exploring topics such as future oil shale development and the climate, geography, and weathering in the Eocene Epoch. These unpublished data, together with most of the U.S. Geological Survey data already published on these samples, are tabulated in this report.

Open-File Report↗
USGS2022

Geochemical studies of the Green River Formation in the Piceance Basin, Colorado: II. Chemofacies from hierarchical cluster analysis

Hierarchical cluster analysis (HCA) was applied to a geochemical dataset representing the Eocene Green River Formation in the Piceance Basin of Colorado to identify chemofacies in core and outcrop samples from the basin margin and the basin center. The input dataset consisted of inductively coupled plasma optical emission spectroscopy and mass spectrometry and total organic carbon (TOC) content analyses of 186 basin margin outcrop samples and 190 basin center core samples discussed in Part 1 of this study (this volume). TOC values and twenty-five major and trace elements were used as variables to define statistical clusters of samples for the overall dataset, for the two basin center cores, and for each separate core or outcrop dataset by HCA applying Euclidean distance and Ward’s method algorithms. For each dataset, five cluster-defined chemofacies were identified. The chemofacies for each dataset show chemical affinities with five informally defined rock types– mudstone, marlstone, carbonate-rich mudstone, siliciclastic-rich mudstone/siltstone/sandstone, and Na-rich (saline) mudstone, with each showing variations in TOC content and abundance of redox sensitive minor and trace elements. A close relationship between enrichment of redox sensitive elements, particularly As and Mo, and TOC is identified in the basin center. Whereas enrichment factors (relative to average shale) are relatively low for many Period IV (PIV) transition metals, as discussed in Part 1 of this study, their consistent coherence in enrichment or depletion in HCA-defined chemofacies demonstrates the expected relationship between redox state and organic richness. Enrichment in PIV transition metals also shows a correlation to enrichment in elements with affinity for siliciclastic sediment. Enrichment/depletion among several groups of redox indicators is not everywhere consistent, with some chemofacies showing, for example, enrichment of PIV transition metals and depletion of sulfur and arsenic. Early timing of saline conditions in the basin margin is clearly displayed in the chemofacies log display, consistent with observations based on geochemical interpretations of concentrations and elemental ratios discussed in Part 1. Overall, the chemofacies are consistent with major mineralogical units and lake history stages defined in previous work, but provide more detail on the fluctuations in lake chemistry that occurred during deposition of Green River oil shale in the Piceance Basin.

Colorado↗
USGS2023

Soil biotic and abiotic thresholds in sugar maple and American beech seedling establishment in forests of the northeastern United States

Aims Climate change is expected to shift climatic envelopes of temperate tree species into boreal forests where unsuitable soils may limit range expansion. We studied several edaphic thresholds (mycorrhizae, soil chemistry) that can limit seedling establishment of two major temperate tree species, sugar maple (arbuscular mycorrhizal, AM) and American beech (ectomycorrhizal, EM). Methods We integrate two field surveys of tree seedling density, mycorrhizal colonization, and soil chemistry in montane forests of the Adirondack and Green Mountains (Mtns) in the northeastern United States. We conducted correlation and linear breakpoint analyses to detect soil abiotic and biotic thresholds in seedling distributions across edaphic gradients. Results In the Green Mtns, sugar maple seedling importance (an index of species relative density and frequency, IV) declined sharply with low pH (< 3.74 in mineral soil) and low mycorrhizal colonization (< 27.5% root length colonized). Sugar maple importance was highly correlated with multiple aspects of soil chemistry, while beech was somewhat sensitive to pH only; beech mycorrhizal colonization did not differ across elevation. Mycorrhizal colonization of sugar maple was positively correlated with soil pH and conspecific overstory basal area. In the Adirondacks, sugar maple importance, but not beech, plateaued above thresholds in soil calcium (~ 2 meq/100 g) and magnesium (~ 0.3 meq/100 g). Conclusions The establishment of sugar maple, but not beech, was impeded by both biotic and abiotic soil components in montane conifer forests and by soil acidity in temperate deciduous forests. These differences in species sensitivity to edaphic thresholds will likely affect species success and future shifts in forest composition.

New York, Vermont↗
USGS2000

Stream chemistry modeling of two watersheds in the Front Range, Colorado

We investigated the hydrologic, geochemical, and biogeochemical controls on stream chemical composition on the Green Lakes Valley and Andrews Creek watersheds using the alpine hydrochemical model (AHM). Both sites had comparable data sets from 1994 and 1996, including high‐resolution spatial data and high‐frequency time series of hydrology, geochemistry, and meteorology. The model of each watershed consisted of three terrestrial subunits (soil, talus, and rock), with the routing between the subunits determined by spatial land cover data. Using 1994 data for model calibration and 1996 data for evaluation, AHM captured the dominant processes and successfully simulated daily stream chemical composition on both watersheds. These results confirm our procedure of using spatial and site‐specific field and laboratory data to generate an initial catchment model and then calibrating the model to calculate effective parameters for unmeasured processes. A net source of nitrogen was identified in the Andrews Creek watershed during the spring snowmelt period, whereas nitrogen was immobilized in the Green Lakes Valley. This difference was most likely due to the larger and more dominant area of talus in the Andrews Creek watershed. Our results also indicate that routing of snowmelt through either soil or talus material is sufficient for retention of H + and release of base cations but that N retention is more important on areas mapped as soil. Owing to the larger ionic pulse and larger fraction of surface runoff the Green Lakes Valley was more sensitive to a doubling of wet deposition chemistry than the Andrews Creek watershed.

Colorado↗
USGS2022

Geochemical studies of the Green River Formation in the Piceance Basin, Colorado: I. Major, minor, and trace elements

The Eocene Green River Formation contains the largest oil shale deposits in the world and is a welldocumented example of a lacustrine depositional system. In addition, mineral resources associated with oil shale in the Piceance Basin nahcolite [NaHCO3] and dawsonite [NaAl(CO3)(OH)2)] are of current and potential economic value, respectively. Detailed geochemical analysis across the basin can aid in the understanding of the depositional environment, sedimentary processes, and water-chemistry evolution in this system. Quantitative geochemical data for Green River oil shale from the Piceance Basin of Colorado were collected by inductively coupled plasma optical emission spectroscopy and mass spectrometry as part of this study. The basin margin is represented by samples from exposures at Douglas Pass (Garfield County) and the basin center area is characterized by core samples from two drilled wells: the Shell 23X-2 and John Savage 24-1 (Rio Blanco County). Major elements and groups of elements are used as proxies for clastic influx (Si, Al, K, Ti), carbonate deposition (Ca, Mg), salinity (Na), paleo-productivity (P), and redox state (Fe, S), respectively. Minor and trace elements reinforce observations based on major elements, including Rb, Zr, Nb for clastic influx and Mn, Sr for carbonate. Trace elements are used to characterize redox conditions (As, Mo, U, V, Co, Ni, Cu, Zn) and salinity (Rb/K, B/Ga). Chemical distinctions between the basin margin and the basin center, in terms of these components and total organic carbon concentrations, support the model of a permanently stratified lake through most of the depositional interval. A primary purpose of the study was to conduct more extensive sampling to confirm conclusions of a previous reconnaissance study. Geochemical data from this study indicates elevated Na around the basin margin occurring earlier than in the deeper basin. Early in the history of Lake Uinta, the salinity may have been elevated first in the shallower marginal waters, due to increased evaporation, which then led to elevated salinity in the basin center through transport of saline density currents. Other indicators of salinity (Rb/K, B/Ga) do not track Na content in intervals where clay minerals are absent due to diagenetic alteration under hypersaline conditions but may be used to indicate the salinities at which authigenic Na-bearing minerals begin to form. Most Na-rich samples show high proportions of clastic constituents (Si, Al, K, Ti) compared to conventional carbonate constituents (Ca, Mg). Redox-sensitive period IV transition metal elements (V, Co, Ni, Cu, Zn) show only local occurrence of significant enrichment relative to average shale abundances. Analysis of Fe/Al ratios for this dataset suggests that the depletion of these elements may be related to source rocks depleted in mafic constituents, with apparent redox-related enrichments subdued by this effect. The basin margin samples reflect generally oxic bottom waters, with some intervals deposited under more reducing, possibly dysoxic to anoxic conditions. The basin center results indicate more reducing conditions, with Mo and U enrichment factors suggesting operation of a particulate shuttle mechanism that scavenged Mo on Fe/Mn-oxyhydroxides that redissolved at depth, with Mo precipitating along with sulfides and/or organic matter at or near the sediment/water interface.

Colorado↗
USGS1991

Trondhjemitic, 1.35-1.31 Ga gneisses of the Mount Holly Complex of Vermont: evidence for an Elzevirian event in the Grenville Basement of the United States Appalachians

A newly recognized suite of trondhjemite–tonalite and dacitic gneiss forms a 10 km wide belt of rocks within the Mount Holly Complex in the central part of the Green Mountain massif of Vermont. Field relationships and chemistry indicate that these gneisses are calc-alkaline, volcanic, and hypabyssal plutonic rocks older than the Middle Proterozoic regional deformation that affected the Mount Holly Complex. U–Pb zircon dates indicate ages as great as 1.35 Ga for crystallization of the volcanic protoliths and for intrusion of crosscutting trondhjemite. Tonalitic plutonism continued until 1.31 Ga.Map-scale contacts between the trondhjemitic–tonalitic–dacitic gneisses and the paragneiss sequence of the Mount Holly Complex are sharp, suggesting that the volcanic rocks of the trondhjemite–tonalite suite underlie the paragneiss units and do not intrude them. These relationships suggest that the trondhjemite–tonalite suite is either considerably older than, and unconformable beneath, the paragneiss cover rocks or represents a volcanic edifice slightly older than the deposition of the sedimentary precursor to the paragneiss units. The paragneiss and tonalite–trondhjemite gneisses are both intruded by younger granitoids that were intruded at about 1.25 Ga during strong dynamothermal metamorphism.The trondhjemitic gneisses of the Mount Holly Complex of Vermont have high Al 2 O 3 and low Yb contents and light rare-earth element enrichment patterns that are more characteristic of continental than oceanic volcanic arcs. The Mount Holly intrusives and volcanics may have formed during 1.35–1.31 Ga ensialic volcanic-arc activity, contemporaneous with ensimatic arc activity during the early part of the Elzevirian phase of the Grenville orogeny. In Vermont, later deformation and granite intrusion at about 1.25 Ga coincide with the major pulse of the Elzevirian orogeny and associated trondhjemitic plutonism in the Central Metasedimentary Belt of eastern Canada.

Vermont↗
USGS2006

Characterization of the hydrology, water chemistry, and aquatic communities of selected springs in the St. Johns River Water Management District, Florida, 2004

The hydrology, water chemistry, and aquatic communities of Silver Springs, De Leon Spring, Gemini Springs, and Green Spring in the St. Johns River Water Management District, Florida, were studied in 2004 to provide a better understanding of each spring and to compile data of potential use in future water-management decisions. Ground water that discharges from these and other north-central Florida springs originates from the Upper Floridan aquifer of the Floridan aquifer system, a karstic limestone aquifer that extends throughout most of the State's peninsula. This report summarizes data about flow, water chemistry, and aquatic communities, including benthic invertebrates, fishes, algae, and aquatic macrophytes collected by the U.S. Geological Survey, the St. Johns River Water Management District, and the Florida Department of Environmental Protection during 2004, as well as some previously collected data. Differences in water chemistry among these springs reflect local differences in water chemistry in the Upper Floridan aquifer. The three major springs sampled at the Silver Springs group (the Main Spring, Blue Grotto, and the Abyss) have similar proportions of cations and anions but vary in nitrate and dissolved oxygen concentrations. Water from Gemini Springs and Green Spring has higher proportions of sodium and chloride than the Silver Springs group. Water from De Leon Spring also has higher proportions of sodium and chloride than the Silver Springs group but lower proportions of calcium and bicarbonate. Nitrate concentrations have increased over the period of record at all of the springs except Green Spring. Compounds commonly found in wastewater were found in all the springs sampled. The most commonly detected compound was the insect repellant N,N'-diethyl-methyl-toluamide (DEET), which was found in all the springs sampled except De Leon Spring. The pesticide atrazine and its degradate 2-chloro-4-isopropylamino-6-amino-s-triazine (CIAT) were detected in water from the Silver Springs group and in both boils at Gemini Springs. No pesticides were detected in water samples from De Leon Spring and Green Spring. Evidence of denitrification was indicated by the presence of excess nitrogen gas in water samples from most of the springs. Aquatic communities varied among the springs. Large floating mats of cyanobacteria (blue-green algae), identified as Lyngbya wollei, were observed in De Leon Spring during all sampling events in 2004. At Gemini Springs, the dominant periphyton was Rhizoclonium sp. Of the three springs sampled for benthic invertebrates, De Leon Spring had the highest overall species richness and most disturbance intolerant species (Florida Index = 4). Green Spring had the lowest species richness of the springs sampled. Based on qualitative comparisons, overall macroinvertebrate species richness seemed to be negatively related to magnesium, potassium, sodium, and specific conductance. Invertebrate abundance was greatest when dissolved oxygen and nitrate were high but phosphorus and potassium concentrations were low. Dipteran abundance seemed to be positively associated with specific conductance and total organic carbon but negatively associated with nitrate-N. Amphipods were the numerically dominant group collected in most (six of nine) collections. Shifts in amphipod abundance of the two species collected (Gammarus sp. and Hyalella azteca) varied by season among the three springs, but there were no trends evident in the variation. Fish populations were relatively species-rich at the Silver Springs group, De Leon Spring, and Gemini Springs, but not at Green Spring. Nonindigenous fish species were observed at all springs except Green Spring.

Open-File Report↗
USGS1981

Geochemistry of spring water, southeastern Uinta Basin, Utah and Colorado

The chemical quality of water in the southeastern Uinta Basin, Utah and Colorado, is important to the future development of the abundant oil-shale resources of the area. This report examines the observed changes in chemistry as water circulates in both shallow and deep ground-water systems. Mass-balance and mass- transfer calculations are used to define reactions that simulate the observed water chemistry in the mixed sandstone, siltstone, and carbonate lithology of the Green River Formation of Tertiary age. The mass-transfer calculations determine a reaction path particular to this system. The early dominance of calcite dissolution produces a calcium carbonate water. After calcite saturation, deeper circulation and further rock-water interaction cause the reprecipitation of calcite, the dissolution of dolomite and plagioclase, and the oxidation of pyrite; all combining to produce a calcium magnesium sodium bicarbonate sulfate water. The calculations suggest that silica concentrations are controlled by a kaolinite-Ca-montmorillonite phase boundary. Close agreement of mineral-saturation indices calculated by both an aqueous-equilibrium model and the mass-transfer model support the selection of reactions from the mass-transfer calculations.

Colorado, Utah↗
USGS2003

Surface-water quality of the Skokomish, Nooksack, and Green-Duwamish rivers and Thornton Creek, Puget Sound Basin, Washington, 1995-98

Streamflow and surface-water-quality data were collected from November 1995 through April 1998 (water years 1996-98) from a surface-water network in the Puget Sound Basin study unit of the U.S. Geological Survey National Water-Quality Assessment program. Water samples collected monthly and during storm runoff events were analyzed for nutrients, major ions, organic carbon, and suspended sediment, and at selected sites, samples were analyzed for pesticides and volatile organic compounds. Eleven sites were established in three major watersheds--two in the Skokomish River Basin, three in the Nooksack River Basin, five in the Green-Duwamish River Basin, and one site in Thornton Creek Basin, a small tributary to Lake Washington. The Skokomish River near Potlatch, Nooksack River at Brennan, and Duwamish River at Tukwila are integrators of mixed land uses with the sampling sites locally influenced by forestry practices, agriculture, and urbanization, respectively. The remaining eight sites are indicators of relatively homogeneous land use/land cover in their basins. The site on the North Fork Skokomish River is an indicator site chosen to measure reference or background conditions in the study unit. In the Nooksack River Basin, the site on Fishtrap Creek is an indicator of agriculture, and the Nooksack River at North Cedarville is an indicator site of forestry practices in the upper watershed. In the Green-Duwamish River Basin, Springbrook Creek is an urban indicator, Big Soos Creek is an indicator of a rapidly developing suburban basin; Newaukum Creek is an indicator of agriculture; and the Green River above Twin Camp Creek is an indicator of forestry practices. Thornton Creek is an indicator of high-density urban residential and commercial development. Conditions during the first 18 months of sampling were dominated by above-normal precipitation. For the Seattle-Tacoma area, water year 1997 was the wettest of the 3 years during the sample-collection period. Nearly 52 inches fell (about 14 inches above average) and monthly precipitation was often 200 percent of normal. The wet years kept streamflows generally above normal and contributed to high concentrations of pesticides, nutrients, suspended sediment, and organic carbon in samples. On the basis of chemical concentrations, dissolved oxygen concentrations, and water temperature, the relative quality of water among the 11 study sites ranged from exceptionally high in the North Fork Skokomish and the Green to fair in Springbrook and Thornton. Water in the large rivers (Skokomish, Nooksack, Green-Duwamish) and in two of the small streams in the Puget Sound Lowlands (Big Soos and Newaukum) was characterized by dilute water chemistry with dissolved solids concentrations less than 130 milligrams per liter. Water in three other small streams in the Lowlands (Fishtrap, Springbrook, and Thornton) had dissolved solids concentrations as high as 320 milligrams per liter. Nutrient and pesticide concentrations mostly were higher in the small streams than in the large rivers. Suspended-sediment concentrations, however, were highest in the large rivers, with averages ranging from 85 to 443 milligrams per liter. During storm and flood events, suspended-sediment concentrations in samples from the Nooksack were as much as 2,800 milligrams per liter, and from the Skokomish, 1,500 milligrams per liter. Out of 86 pesticides and 86 volatile organic compounds analyzed, a total of 35 pesticides and 11 volatile organic compounds were detected at concentrations above laboratory reporting levels in samples collected from the four intensively studied sites, the lower Nooksack River, Duwamish River, Fishtrap Creek, and Thornton Creek. Herbicides were detected more frequently than insecticides. The herbicide prometon was detected in 66 percent of all 124 samples collected, followed by simazine (65 percent), atrazine (64 percent), and the insecticide diazinon (50 percent). The detected volatile organic compounds belonged to one of three general classes--fuel-related, the trihalomethanes, or solvents. Water-quality standards and criteria for drinking water or for the protection of aquatic life were nearly always met, except on occasion by concentrations of dissolved oxygen, iron, and manganese in samples from Springbrook and Fishtrap, and concentrations of diazinon in Thornton and Fishtrap. Concentrations of three other insecticides (carbaryl, chlorpyrifos, and lindane) also did not meet criteria protecting aquatic life in a few samples (from 1 to 5) from Thornton and Fishtrap and from the Duwamish River. Water-quality conditions at the sampling sites resulted from natural characteristics of the watersheds and from human activities. In the Nooksack and Skokomish, natural conditions were probably important contributors to the large suspended-sediment concentrations observed during high streamflow events. However, logging and road building in the basins might also have contributed to the suspended-sediment loads. In the forested study basins, the water chemistry was more dilute, based on dissolved solids and nutrient concentrations. The North Fork Skokomish (indicator site of background conditions) and the Green (indicator site of forestry and natural conditions) were characterized by high-quality water with low concentrations of dissolved solids, nutrients, and sediment and by standards or criteria that were nearly always met. Unlike the high-quality water at the background and forestry sites, natural conditions appear to have adversely affected the quality of water in Springbrook. High concentrations of iron and manganese and low dissolved-oxygen concentrations were possibly the result of ground-water discharge at this site. Of all the sites, nutrient concentrations were highest in the agricultural streams (Fishtrap and Newaukum) and next highest in the urban streams, indicating that human activities affect the water quality of these streams. Of the three large rivers integrating a mix of land uses, the lower Nooksack, in an agricultural setting, on average had the highest total nitrogen and phosphorus concentrations, followed by the Duwamish in an urban setting, and the Skokomish in a forestry-practices setting. In both urban and agricultural settings, pesticides affected water quality at the four sites sampled for organic compounds. However, more types of pesticides were found at the agricultural sites than at the urban sites. The most pesticides were detected in Fishtrap. Many of these were pesticides applied for agricultural purposes, but several were pesticides applied in urban settings, such as those used in maintaining rights-of-way. In urban Thornton Creek, however, high application rates and retail availability of pesticides likely resulted in generally higher concentrations, the detections of certain pesticides in many samples year round, and the number of times insecticide concentrations did not meet chronic criteria for the protection of freshwater aquatic life. The two sites located in urban areas also had more detections of volatile organic compounds and at a higher detection frequency than the two sites in agricultural areas. The most compounds were detected in Thornton, and in the highest concentrations. Conversely, the least number of compounds was detected in the lower Nooksack, with only 2 percent urban land upstream. Methyl tert -butyl ether, an automotive fuel additive, was detected in a few samples from Fishtrap. Many solvents, such as trichloroethene and tetrachloroethene, were detected only in samples from the urban sites on the Duwamish River and Thornton Creek. The only volatile organic compound with a distinctly agricultural signature was 1,2-dichloropropane, detected only in Fishtrap Creek samples.

Washington↗
USGS1981

Location of a Caldera Source for the Soldier Meadow Tuff, Northwestern Nevada, Indicated by Gravity and Aeromagnetic Data

The Soldier Meadow Tuff in north-western Nevada is part of a sequence of peralkaline and subalkaline rhyolitic rocks of Miocene age that occupies an area of about 1,600 km 2 and has a volume of about 50 km 3 . The formation is mostly welded tuff containing abundant alkali feldspar and quartz phenocrysts in devitrified groundmass containing minute needles of blue-green alkali amphibole. The rhyolite of Badger Mountain is similar in mineralogy and chemistry, but textures suggest that it is a flow rhyolite. The underlying rhyolite of Catnip Mountain and tuff of Trough Mountain are phenocryst-poor but apparently also peralkaline. Gravity and aeromagnetic anomaly maps show 16- by 24-km anomalies near Badger Mountain. An analysis of these maps suggests that observed anomalies could be caused by a concealed caldera of 2,700-m thickness filled with rocks 0.2 g/cm 3 less dense and 0***002 emu/cm 3 lower magnetic susceptibility than the surrounding rocks. Distribution of the Soldier Meadow Tuff and the occurrence of numerous vents in the rhyolite of Badger Mountain suggest that the source for both units is associated with the indicated caldera. Possible alternative sources are other calderas whose locations are suggested by a 7- by 11-km gravity minimum near Rock Spring Table and a 12- by 24-km magnetic minimum west of Soldier Meadow.

Nevada↗
USGS2020

Biomarker similarities between the saline lacustrine Eocene Green River and the Paleoproterozoic Barney Creek Formations

The Paleoproterozoic Barney Creek Formation, which is currently interpreted as a restricted, deep marine paleoenvironment, plays a disproportionate role in our understanding of Proterozoic ocean chemistry and the rise of complex life. The Barney Creek Formation hosts several unusual biomarker features, specifically its methylhopane and carotenoid signatures. Herein, we demonstrate that the saline lacustrine Eocene Green River Formation shares a similar distribution of methylhopanes and carotenoids, which is characteristic of saline lacustrine organic matter more generally. These distinct methylhopane and carotenoid patterns are not observed together in marine organic matter of any geologic age. These results imply a saline lacustrine depositional environment for the Barney Creek Formation, which agrees with earlier but now abandoned depositional models of this formation. As a result, models of Proterozoic ocean chemistry and emergence of complex life that rely on a marine Barney Creek Formation should be re-examined. Alternatively, if Paleoproterozoic marine biomarker signatures resemble those of younger saline lacustrine systems, then this must be recognized to accurately interpret geologic biomarker and paleoenvironmental records.

Colorado, Utah↗