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Sustainability trade-offs across modeled floating solar waterscapes of the Northeastern United States

Expansion of floating photovoltaic (FPV) solar systems provides a low-conflict renewable energy option to help mitigate climate change while sparing land, but potential sustainability trade-offs remain unquantified. We compare the technical potential of maximum FPV deployment to address the climate crisis with FPV-buildout scenarios that prioritize biodiversity and social values across waterscapes. FPV deployment on all technically suitable waterbodies (3.5% of available sites) in the Northeastern US could generate nearly a quarter of the region’s solar energy while offsetting all the land required for solar by 2050, but trade-offs, including maintenance of freshwater biodiversity and recreational benefits, exist. Avoidance of socioenvironmental interactions yields FPV-electricity generation potential equal to a 5% increase in regional solar generation while sparing water for biodiversity and social values, though opportunities for co-location make this a conservative estimate. Our framework extends technical potential assessments to holistically inform FPV siting and support diverse Sustainable Development Goals.

Connecticut, Delaware, Maine, Maryland, Massachuse

A fire-use decision model to improve the United States’ wildfire management and support climate change adaptation

The US faces multiple challenges in facilitating the safe, effective, and proactive use of fire as a landscape management tool. This intentional fire use exposes deeply ingrained communication challenges and distinct but overlapping strategies of prescribed fire, cultural burning, and managed wildfire. We argue for a new conceptual model that is organized around ecological conditions, capacity to act, and motivation to use fire and can integrate and expand intentional fire use as a tool. This result emerges from more considered collaboration and communication of values and needs to address the negative consequences of contemporary fire use. When applied as a communication and translation tool, there is potential to lower barriers to faster and more successful collaboration among stakeholders. Such improvements are a vital part of strategies to address climate adaptation, wildfire mitigation, and the well-being of ecosystems.

Cell Reports Sustainability

Rising sea level reduces carbon sequestration and CO2 and N2O fluxes while promoting CH4 flux from mangroves

Sea-level rise (SLR) may reduce mangrove carbon sequestration by increasing greenhouse gas (GHG) emissions—a key factor in forecasting the trajectory of blue carbon reserves. Nonetheless, predictions of future GHG fluxes under SLR remain uncertain. Unlike prior studies limited to controlled or single-site settings, we deploy cross-latitude “marsh-organ” designs in China to access GHG fluxes in mangroves and neighboring mudflats. Our findings show that SLR-stimulated CH 4 emissions in mangroves could increase by 10% under RCP 4.5 and by 22% under RCP 8.5, relative to current sea level by 2100. Conversely, SLR decreases ecosystem respiration and N 2 O emissions by 35%–51% and 28%–36%, respectively, while net ecosystem productivity decreases by 12%–28% as SLR increases. Overall, our results forecast a 17%–30% decline in mangroves’ climate mitigation efficiency. We recommend focusing on non-CO 2 GHG emissions from mangroves, as they may significantly offset climate mitigation capacity under climate change.

Cell Reports Sustainability

Ichthyophonus-induced cardiac damage: a mechanism for reduced swimming stamina in salmonids

Swimming stamina, measured as time-to-fatigue, was reduced by approximately two-thirds in rainbow trout experimentally infected with Ichthyophonus. Intensity of Ichthyophonus infection was most severe in cardiac muscle but multiple organs were infected to a lesser extent. The mean heart weight of infected fish was 40% greater than that of uninfected fish, the result of parasite biomass, infiltration of immune cells and fibrotic (granuloma) tissue surrounding the parasite. Diminished swimming stamina is hypothesized to be due to cardiac failure resulting from the combination of parasite-damaged heart muscle and low myocardial oxygen supply during sustained aerobic exercise. Loss of stamina in Ichthyophonus-infected salmonids could explain the poor performance previously reported for wild Chinook and sockeye salmon stocks during their spawning migration. ?? 2006 Blackwell Publishing Ltd.

Journal of Fish Diseases

Observing systems, modeling, and forecasting

Predicting harmful algal blooms (HABs) requires integrating physical, chemical, and biological data collected from observing networks and then assimilating these data into models, which are used to generate forecasts. In 2005, the Harmful Algal Research and Response: A National Environmental Science Strategy 2005-2015 (HARRNESS, 2005) made recommendations on how to improve HAB modeling and forecasting over the next decade. Key HARRNESS recommendations related to sensing, networking, and modeling HABs included: ● Support the development and validation of new and improved technologies for remote cell and toxin detection, and for modeling and forecasting, ● Improve coordination of monitoring/ and modeling efforts, both at national and regional levels, ● Improve the use of networking technologies for monitoring and modeling efforts, ● Conduct sustained time series measurements of the biotic, chemical, and physical environments impacted by HABs, ● Develop food web models on the ecosystem fate and effects of toxins, ● Develop and improve species-specific models that link to physical-biological models. Here we review HAB observing, modeling, and forecasting advances and technologies and recommend research and management priorities for the next decade and beyond. Our report encompasses sensing technologies, sensor networking and data management, models and forecasts, and the paths to operationalize forecasts. Continued improvements of deployable sensors are foundational to improving early warning indicators, models, and forecasts, which are only as good as the underlying data. Sensing technology has advanced considerably in the last decade; for example, more capable fluorometric pigment sensors can track changes in bloom biomass in real-time. Additionally, automated imaging/classifying systems to identify and quantify key harmful algal (HA) taxa are being routinely deployed. However, deployable toxin sensors are available for only some HAB toxins and continue to be identified as a critical need by researchers and managers. As more and improved sensors and technologies become available, the data quality associated with each sensor needs to be assessed. Data quality encompasses the reliability, accuracy, and uncertainty associated with sensor-generated data. These data need to be of known quality so that researchers, managers, and end-users can reliably determine if the information is appropriate for their intended applications. Many of the data quality recommendations from HARRNESS (2005) are still relevant and have been reiterated within the management community. Understanding and documenting data quality, and when applicable, standardizing best practices for sensor use, continue to be recommended.

Report

Response of seismicity to Coulomb stress triggers and shadows of the 1999 Mw=7.6 Chi-Chi, Taiwan, earthquake

The correlation between static Coulomb stress increases and aftershocks has thus far provided the strongest evidence that stress changes promote seismicity, a correlation that the Chi-Chi earthquake well exhibits. Several studies have deepened the argument by resolving stress changes on aftershock focal mechanisms, which removes the assumption that the aftershocks are optimally oriented for failure. Here one compares the percentage of planes on which failure is promoted after the main shock relative to the percentage beforehand. For Chi-Chi we find a 28% increase for thrust and an 18% increase for strike-slip mechanisms, commensurate with increases reported for other large main shocks. However, perhaps the chief criticism of static stress triggering is the difficulty in observing predicted seismicity rate decreases in the stress shadows, or sites of Coulomb stress decrease. Detection of sustained drops in seismicity rate demands a long catalog with a low magnitude of completeness and a high seismicity rate, conditions that are met at Chi-Chi. We find four lobes with statistically significant seismicity rate declines of 40-90% for 50 months, and they coincide with the stress shadows calculated for strike-slip faults, the dominant faulting mechanism. The rate drops are evident in uniform cell calculations, 100-month time series, and by visual inspection of the M ??? 3 seismicity. An additional reason why detection of such declines has proven so rare emerges from this study: there is a widespread increase in seismicity rate during the first 3 months after Chi-Chi, and perhaps many other main shocks, that might be associated with a different mechanism. Copyright 2005 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth

The effects of using ground water to maintain water levels of Cedar Lake, Wisconsin

Cedar Lake, a kettle lake with no surface inlet or outlet, was studied to evaluate the feasibility of maintaining water levels of lakes in the glaciated kettle moraine area of eastern Wisconsin by pumping ground water into them. The general hydrogeology of the area around the lake was defined and the hydrology of the lake was studied in detail. There are two aquifer systems in the Cedar Lake area, and in general, throughout eastern Wisconsin. The shallow aquifer system is composed of unconsolidated glacial drift of Quaternary age and consolidated bedrock of Silurian age. Cedar Lake is located in a local recharge area within this system. The saturated thicknesses of the glacial drift and Silurian dolomite beneath the lake are approximately 100 feet and 500 feet, respectively. This aquifer system is separated from an underlying aquifer system by a layer of shale approximately '200 feet thick that forms an effective barrier to water movement. The deep aquifer system is composed of dolomites and sandstones of Ordovician and Cambrian age whose composite thickness is 600 to 650 feet. A water budget was prepared to quantify the components of the hydrologic system of Cedar Lake. Inflow to the lake averaged approximately ^5 inches per water year for the 2-year period October 197^ through September 1976. Inflow consisted of precipitation on the lake surface (28 inches), groundwater seepage to the lake (2 inches), and overland flow (15 inches) to the lake. Outflow averaged approximately U9 inches per year for the same 2- year period. Outflow consisted of evaporation (31 inches) from the lake surface and ground-water seepage from the lake (18 inches). A volume of water equivalent to that needed to raise the lake level 1*7 inches was pumped from the shallow aquifer system into Cedar Lake between February 1 and September 30, 1977. The water budget for the lake during this period indicated that approximately 90 percent of pumped water was either recycled from the lake to the well or otherwise lost as seepage from the lake. Selected physical and chemical characteristics of the lake water were measured periodically between October 197^ and September 1977- The water temperature ranged between 26°C in August to approximately 2°C in December during each year of the study. The dissolved-oxygen concentration of the water ranged from 13 milligrams per liter at the time ice cover first developed in December to h milligrams per liter at the time ice cover broke up the following April. The total nitrogen concentration of the water varied from 1.0 milligrams per liter during winter to 0.5 milligrams per liter during summer. The total phosphorus concentration of the water was fairly uniform throughout the year, averaging 0.01 milligrams per liter. The phytoplankton population was sampled periodically. The total phytoplankton count was small during winter, generally less than 250 cells per milliliter. These phytoplankton were composed of euglenoids, diatoms, green algae, and blue-green algae. The count increased to 50,000 to 100,000 cells per milliliter during summer. One or two species of blue-green algae dominated during these times. There were no identifiable changes in measured physical and chemical characteristics of lake water during sustained pumping of ground water into the lake, nor were there identifiable changes in the number or makeup of the phytoplankton community. Differences in physical and chemical characteristics of lake water and ground water added to the lake probably were not great enough to cause changes within the lake.

Wisconsin

Widespread episodic thiamine deficiency in Northern Hemisphere wildlife

Many wildlife populations are declining at rates higher than can be explained by known threats to biodiversity. Recently, thiamine (vitamin B 1 ) deficiency has emerged as a possible contributing cause. Here, thiamine status was systematically investigated in three animal classes: bivalves, ray-finned fishes, and birds. Thiamine diphosphate is required as a cofactor in at least five life-sustaining enzymes that are required for basic cellular metabolism. Analysis of different phosphorylated forms of thiamine, as well as of activities and amount of holoenzyme and apoenzyme forms of thiamine-dependent enzymes, revealed episodically occurring thiamine deficiency in all three animal classes. These biochemical effects were also linked to secondary effects on growth, condition, liver size, blood chemistry and composition, histopathology, swimming behaviour and endurance, parasite infestation, and reproduction. It is unlikely that the thiamine deficiency is caused by impaired phosphorylation within the cells. Rather, the results point towards insufficient amounts of thiamine in the food. By investigating a large geographic area, by extending the focus from lethal to sublethal thiamine deficiency, and by linking biochemical alterations to secondary effects, we demonstrate that the problem of thiamine deficiency is considerably more widespread and severe than previously reported.

Scientific Reports

A framework for assessing the sustainability of monitored natural attenuation

The sustainability of monitored natural attenuation (MNA) over time depends upon (1) the presence of chemical/biochemical processes that transform wastes to innocuous byproducts, and (2) the availability of energy to drive these processes to completion. The presence or absence of contaminant-transforming chemical/biochemical processes can be determined by observing contaminant mass loss over time and space (mass balance). The energy available to drive these processes to completion can be assessed by measuring the pool of metabolizable organic carbon available in a system, and by tracing the flow of this energy to available electron acceptors (energy balance). For the special case of chlorinated ethenes in ground-water systems, for which a variety of contaminant-transforming biochemical processes exist, natural attenuation is sustainable when the pool of bioavailable organic carbon is large relative to the carbon flux needed to drive biodegradation to completion. These principles are illustrated by assessing the sustainability of MNA at a chlorinated ethene-contaminated site in Kings Bay, Georgia. Approximately 1,000 kilograms of perchloroethene (PCE) was released to a municipal landfill in the 1978-1980 timeframe, and the resulting plume of chlorinated ethenes migrated toward a nearby housing development. A numerical model, built using the sequential electron acceptor model code (SEAM3D), was used to quantify mass and energy balance in this system. The model considered the dissolution of non-aqueous phase liquid (NAPL) as the source of the PCE, and was designed to trace energy flow from dissolved organic carbon to available electron acceptors in the sequence oxygen > chlorinated ethenes > ferric iron > sulfate > carbon dioxide. The model was constrained by (1) comparing simulated and measured rates of ground-water flow, (2) reproducing the observed distribution of electron-accepting processes in the aquifer, (3) comparing observed and measured concentrations of chlorinated ethenes, and (4) reproducing the observed production and subsequent dilution of dissolved chloride, a final degradation product of chloroethene biodegradation. Simulations using the constrained model indicated that an average flux of 5 milligrams per liter per day of organic carbon (CH2O) per model cell (25 square meters) is required to support the short-term sustainability of MNA. Because this flux is small relative to the pool of renewable organic carbon (about 4.7 x 107 milligrams [mg] per model cell) present in the soil zone and non-renewable carbon (about 6.9 x 108 mg per model cell) in an organic-rich sediment layer overlying the aquifer, the long-term sustainability of MNA is similarly large. This study illustrates that the short- and long-term sustainability of MNA can be assessed by: 1. Estimating the time required for contaminants to dissolve/disperse/degrade under ambient hydrologic conditions (time of remediation). 2. Quantifying the organic carbon flux to the system needed to consume competing electron acceptors (oxygen) and direct electron flow toward chloroethene degradation (short-term sustainability). 3. Comparing the required flux of organic carbon to the pool of renewable and non-renewable organic carbon given the estimated time of remediation (long-term sustainability). These are general principles that can be used to assess the sustainability of MNA in any hydrologic system.

Circular

Enumeration of viruses and prokaryotes in deep-sea sediments and cold seeps of the Gulf of Mexico

Little is known about the distribution and abundance of viruses in deep-sea cold-seep environments. Like hydrothermal vents, seeps support communities of macrofauna that are sustained by chemosynthetic bacteria. Sediments close to these communities are hypothesized to be more microbiologically active and therefore to host higher numbers of viruses than non-seep areas. Push cores were taken at five types of Gulf of Mexico habitats at water depths below 1000 m using a remotely operated vehicle (ROV). The habitats included non-seep reference sediment, brine seeps, a microbial mat, an urchin field, and a pogonophoran worm community. Samples were processed immediately for enumeration of viruses and prokaryotes without the addition of a preservative. Prokaryote counts were an order of magnitude lower in sediments directly in contact with macrofauna (urchins, pogonophorans) compared to all other samples (10 7 vs. 10 8 cells g -1 dry weight) and were highest in areas of elevated salinity (brine seeps). Viral-Like Particle (VLP) counts were lowest in the reference sediments and pogonophoran cores (10 8 VLP g -1 dry wt), higher in brine seeps (10 9 VLP g -1 dry wt), and highest in the microbial mats (10 10 VLP g -1 dry wt). Virus-prokaryote ratios (VPR) ranged from <5 in the reference sediment to >30 in the microbial mats and >60 in the urchin field. VLP counts and VPR were all significantly greater than those reported from sediments in the deep Mediterranean Sea and in most cases were higher than recent data from a cold-seep site near Japan. The high VPR suggest that greater microbial activity in or near cold-seep environments results in greater viral production and therefore higher numbers of viruses.

Gulf Of Mexico;Green Canyon;Atwater Valley;Alamino

Effects of Land-Use Changes and Ground-Water Withdrawals on Stream Base Flow, Pocono Creek Watershed, Monroe County, Pennsylvania

The Pocono Creek watershed drains 46.5 square miles in eastern Monroe County, Pa. Between 2000 and 2020, the population of Monroe County is expected to increase by 70 percent, which will result in substantial changes in land-use patterns. An evaluation of the effect of reduced recharge from land-use changes and additional ground-water withdrawals on stream base flow was done by the U.S. Geological Survey (USGS) in cooperation with the U.S. Environmental Protection Agency (USEPA) and the Delaware River Basin Commission as part of the USEPA?s Framework for Sustainable Watershed Management Initiative. Two models were used. A Soil and Water Assessment Tool (SWAT) model developed by the USEPA provided areal recharge values for 2000 land use and projected full buildout land use. The USGS MODFLOW-2000 ground-water-flow model was used to estimate the effect of reduced recharge from changes in land use and additional ground-water withdrawals on stream base flow. This report describes the ground-water-flow-model simulations. The Pocono Creek watershed is underlain by sedimentary rock of Devonian age, which is overlain by a veneer of glacial deposits. All water-supply wells are cased into and derive water from the bedrock. In the ground-water-flow model, the surficial geologic units were grouped into six categories: (1) moraine deposits, (2) stratified drift, (3) lake deposits, (4) outwash, (5) swamp deposits, and (6) undifferentiated deposits. The unconsolidated surficial deposits are not used as a source of water. The ground-water and surface-water systems are well connected in the Pocono Creek watershed. Base flow measured on October 13, 2004, at 27 sites for model calibration showed that streams gained water between all sites measured except in the lower reach of Pocono Creek. The ground-water-flow model included the entire Pocono Creek watershed. Horizontally, the modeled area was divided into a 53 by 155 cell grid with 6,060 active cells. Vertically, the modeled area was discretized into four layers. Layers 1 and 2 represented the unconsolidated surficial deposits where they are present and bedrock where the surficial deposits are absent. Layer 3 represented shallow bedrock and was 200 ft (feet) thick. Layer 4 represented deep bedrock and was 300 ft thick. A total of 873 cells representing streams were assigned to layer 1. Recharge rates for model calibration were provided by the USEPA SWAT model for 2000 land-use conditions. Recharge rates for 2000 for the 29 subwatersheds in the SWAT model ranged from 6.11 to 22.66 inches per year. Because the ground-water-flow model was calibrated to base-flow data collected on October 13, 2004, the 2000 recharge rates were multiplied by 1.18 so the volume of recharge was equal to the volume of streamflow measured at the mouth of Pocono Creek. During model calibration, adjustments were made to aquifer hydraulic conductivity and streambed conductance. Simulated base flows and hydraulic heads were compared to measured base flows and hydraulic heads using the root mean squared error (RMSE) between measured and simulated values. The RMSE of the calibrated model for base flow was 4.7 cubic feet per second for 27 locations, and the RMSE for hydraulic heads for 15 locations was 35 ft. The USEPA SWAT model was used to provide areal recharge values for 2000 and full buildout land-use conditions. The change in recharge ranged from an increase of 37.8 percent to a decrease of 60.8 percent. The ground-water-flow model was used to simulate base flow for 2000 and full buildout land-use conditions using steady-state simulations. The decrease in simulated base flow ranged from 3.8 to 63 percent at the streamflow-measurement sites. Simulated base flow at streamflow-gaging station Pocono Creek above Wigwam Run near Stroudsburg, Pa. (01441495), decreased 25 percent. This is in general agreement with the SWAT model, which estimated a 30.6-percent loss in base flow at the streamflow-gaging station.

Scientific Investigations Report

Groundwater-flow model of the Treasure Valley, southwestern Idaho, 1986–2015

Most of the population of the Treasure Valley and the surrounding area of southwestern Idaho and easternmost Oregon depends on groundwater for domestic supply, either from domestic or municipal-supply wells. Current and projected rapid population growth in the area has caused concern about the long-term sustainability of the groundwater resource. In 2016, the U.S. Geological Survey, in cooperation with the Idaho Water Resource Board and the Idaho Department of Water Resources, began a project to construct a numerical groundwater-flow model of the westernmost portion of the western Snake River Plain aquifer system, called the Treasure Valley. The development of the model was guided by several objectives, including: to improve the understanding of groundwater and surface water interactions; to facilitate conjunctive water management; to provide a tool for water resources planning; and to provide a tool for water allocation. The model was constructed with a spatial scale and level of detail that aimed to meet these objectives while balancing the sometimes-competing goals of fast runtimes, numerical stability, usability, and parsimony. The Treasure Valley Groundwater Flow Model (TVGWFM) is a three-dimensional finite-difference numerical model constructed using MODFLOW 6 (Langevin and others, 2017, Documentation for the MODFLOW 6 Groundwater Flow Model: U.S. Geological Survey Techniques and Methods, book 6, chap. A55, 197 p., https://doi.org/10.3133/tm6A55 ). The model covers the westernmost portion of the western Snake River Plain and is discretized into a regular grid of 64 by 65 cells with a side length of 1 mile and 6 layers of varying depth and active area. A historical model period was developed consisting of 360 month-long stress periods for 1986–2015. The model builds upon previous modeling efforts by adding a transient period, incorporating new head and discharge observations to constrain parameters, incorporating information from the hydrogeologic framework model (HFM) of Bartolino (2019, Hydrogeologic framework of the Treasure Valley and surrounding area, Idaho and Oregon: U.S. Geological Survey Scientific Investigations Report 2019–5138, https://doi.org/10.3133/sir20195138 ) and incorporating refined estimates of evapotranspiration and irrigation classification of lands in the study area. The TVGWFM includes all significant components of recharge to and discharge from the aquifer. Inflows include canal seepage, irrigation and precipitation recharge, mountain-front recharge, rivers and stream seepage, and seepage from Lake Lowell. Outflows include discharge to agricultural drainage ditches, discharge to rivers and streams, pumping, and discharge to Lake Lowell. Each recharge or discharge component is represented separately using individual MODFLOW 6 packages. Parameter values were derived with a combination of trial-and-error steps and automated parameter estimation using PEST software (Doherty, J.E., 2005, PEST, model-independent parameter estimation–User manual: Watermark Numerical Computing, https://pesthomepage.org/documentation ). Parameter estimates were constrained with several types of observation data, including water levels, water level changes, vertical water level differences, drain discharges, change in drain discharges, river seepage, seepage from Lake Lowell, and change in seepage from Lake Lowell. Material properties from the hydrogeologic framework were also used to assign the minimum and maximum values of some parameters. A final parameter realization was reached that minimized residuals between the observed and modelled values for the various observation groups. Mean residuals for the observation groups were 15.4 feet (ft) for water levels, 0.2 ft for water level changes, 19.4 ft for vertical water level differences, −3.9 cubic feet per second (ft 3 /s) for drain discharges, 0.0 ft 3 /s for changes in drain discharge, 45.0 ft 3 /s for river seepage, −40.1 ft 3 /s for Lake Lowell seepage, and 126.3 ft 3 /s for changes in Lake Lowell seepage. The quality of the model’s fit to observations varied spatially, with notable areas of under- or over-simulation of water levels present to the northwest and southwest of Lake Lowell, in the foothills along the eastern model boundary, and near the City of Eagle. Trends were observed in the residuals of many of the observation groups, indicating that the model is missing or not fully reproducing some phenomena that are observed in the system. The TVGWFM can be used as a tool for water resource planning, for understanding the interactions of groundwater and surface water at a basin scale, and for facilitating conjunctive management, but may lack the precision needed for water rights administration at a local scale. Additional sources of uncertainty or limitations of the model are noted. The quantity and spatial distribution of canal seepage and infiltration of irrigation water recharge, the largest sources of recharge to the system, are unknown and approximated indirectly. There is poor understanding of how canal seepage and incidental recharge change as land is converted from agricultural (irrigated) to suburban (semi-irrigated). These uncertainties will affect any scenarios that investigate changes to land use or irrigation practices. Finally, the model has relatively high water-level residuals around and to the southwest of Lake Lowell and should not be used to estimate water level effects in that region. The model was built with multiple, broadly expressed objectives and did not optimize performance for specific uses. However, the model and the tools included in an associated data release provide ample flexibility to improve the model for future uses. Adjustments and improvements could be made by refining the model in an area of interest, collecting additional calibration data, applying more rigorous boundary conditions, or re-estimating model parameters to optimize model performance for a specific model forecast.

Idaho

Nutrient enrichment, phytoplankton algal growth, and estimated rates of instream metabolic processes in the Quinebaug River Basin, Connecticut, 2000-2001

A consistent and pervasive pattern of nutrient enrichment was substantiated by water-quality sampling in the Quinebaug River and its tributaries in eastern Connecticut during water years 2000 and 2001. Median total nitrogen and total phosphorus concentrations exceeded the U.S. Environmental Protection Agency?s recently recommended regional ambient water-qual-ity criteria for streams (0.71 and 0.031 milligrams per liter, respectively). Maximum total phosphorus concentrations exceeded 0.1 milligrams per liter at nearly half the sampled locations in the Quinebaug River Basin. Elevated total nitrogen and total phosphorus concentrations were measured at all stations on the mainstem of the Quinebaug River, the French River, and the Little River. Nutrient enrichment was related to municipal wastewater point sources at the sites on the mainstem of the Quinebaug River and French River, and to agricultural nonpoint nutrient sources in the Little River Basin. Nutrient enrichment and favorable physical factors have resulted in excessive, nuisance algal blooms during summer months, particularly in the numerous impoundments in the Quinebaug River system. Phytoplankton algal density as high as 85,000 cells per milliliter was measured during such nuisance blooms in water years 2000 and 2001. Different hydrologic conditions during the summers of 2000 and 2001 produced very different seston algal populations. Larger amounts of precipitation sustained higher streamflows in the summer of 2000 (than in 2001), which resulted in lower total algal abundance and inhibited the typical algal succession from diatoms to cyanobacteria. Despite this, nearly half of all seston chlorophyll-a concentrations measured during this study exceeded the recommended regional ambient stream-water-quality criterion (3.75 micrograms per liter), and seston chlorophyll-a concentrations as large as 42 micrograms per liter were observed in wastewa-ter-receiving reaches of the Quinebaug River. Estimates of primary productivity and respiration obtained from diel dissolved oxygen monitoring and from light- and dark-bottle dissolved oxygen measurements demonstrated that instream metabolic processes are consistent with a seston-algae dominant system. The highest estimated maximum primary productivity rate was 1.72 grams of oxygen per cubic meter per hour at the Quinebaug River at Jewett City during September 2001. The observed extremes in diel dissolved oxygen concentrations (less than 5 milligrams per liter) and pH (greater than 9) may periodically stress aquatic organisms in the Quinebaug River Basin.

Scientific Investigations Report

An inset groundwater-flow model to evaluate the effects of layering configuration on model calibration and assess managed aquifer recharge near Shellmound, Mississippi

The U.S. Geological Survey has developed a high-resolution inset groundwater-flow model in the Mississippi Delta as part of an interdisciplinary collaboration coordinated by the Mississippi Alluvial Plain project to provide a tool that stakeholders can use to support water-resource management decisions. Groundwater withdrawals from the Mississippi River Valley alluvial (MRVA) aquifer have been vital to support agricultural production in the region, but substantial groundwater-level declines near Shellmound, Mississippi, have caused concerns for long-term sustainability of the aquifer. To better understand the subsurface and try to mitigate the long-term groundwater-level declines, stakeholders have undertaken actions including a Groundwater Transfer and Injection Pilot (GTIP) project using a riverbank filtration-based managed aquifer recharge approach. The pilot project consisted of extracting groundwater near the Tallahatchie River and reinjecting it into the aquifer 3 kilometers west where water levels have substantially declined. A high-resolution airborne electromagnetic (AEM) survey was also completed to collect electrical resistivity data to support the GTIP project and the development of the groundwater model. The inset groundwater-flow model was developed to (1) integrate the AEM data into the optimal layering configuration of the MRVA aquifer that the available observation data can support through calibration, and (2) assess the potential effect of the GTIP project on the groundwater levels. The AEM data were processed into three different layering configurations leading to the development of model A (18 layers), model B (16 layers), and model C (8 layers), all at a 100- x 100-meter cell spatial resolution using the U.S. Geological Survey modular finite-difference flow model 6 code with Newton-Raphson formulation. The model development process integrated recent advances in modeling, such as the incorporation of AEM data, the use of outputs from the soil-water-balance (SWB) model, and the Aquaculture and Irrigation Water-Use Model, and was facilitated by robust automation using the open-source python packages Modflow-setup and SFRmaker. Using Parameter Estimation ++ Iterative Ensemble Smoother, the three numerical groundwater-flow models (models A, B, and C) were calibrated against a set of observations, which included aquifer groundwater levels, streamflows, stream stage, and aquifer transmissivity. Results indicate that the detailed representation of MRVA aquifer layers in model A produced the best calibrated model by history matching, and the integration of data representing surficial connectivity played a key role in improving groundwater recharge and enhancing the ability of the model to match groundwater levels in the cone of depression. A forecast model simulated the managed aquifer recharge approach, and the results indicated that, given average irrigation and recharge conditions (2010–15), the GTIP project has the potential to induce groundwater-level increases of as much as 3 meters around the injection site, but a sustained increase would require repetition in subsequent years of water transfer at 2022 rates or above.

Mississippi

Moderate-resolution sea surface temperature data and seasonal pattern analysis for the Arctic Ocean ecoregions

Sea surface temperature (SST) is an important environmental characteristic in determining the suitability and sustainability of habitats for marine organisms. In particular, the fate of the Arctic Ocean, which provides critical habitat to commercially important fish, is in question. This poses an intriguing problem for future research of Arctic environments - one that will require examination of long-term SST records. This publication describes and provides access to an easy-to-use Arctic SST dataset for ecologists, biogeographers, oceanographers, and other scientists conducting research on habitats and/or processes in the Arctic Ocean. The data cover the Arctic ecoregions as defined by the "Marine Ecoregions of the World" (MEOW) biogeographic schema developed by The Nature Conservancy as well as the region to the north from approximately 46&deg;N to about 88&deg;N (constrained by the season and data coverage). The data span a 29-year period from September 1981 to December 2009. These SST data were derived from Advanced Very High Resolution Radiometer (AVHRR) instrument measurements that had been compiled into monthly means at 4-kilometer grid cell spatial resolution. The processed data files are available in ArcGIS geospatial datasets (raster and point shapefiles) and also are provided in text (.csv) format. All data except the raster files include attributes identifying latitude/longitude coordinates, and realm, province, and ecoregion as defined by the MEOW classification schema. A seasonal analysis of these Arctic ecoregions reveals a wide range of SSTs experienced throughout the Arctic, both over the course of an annual cycle and within each month of that cycle. Sea ice distribution plays a major role in SST regulation in all Arctic ecoregions.

Open-File Report

Conjunctive-use optimization model of the Mississippi River Valley alluvial aquifer of Southeastern Arkansas

The Mississippi River Valley alluvial aquifer is a water-bearing assemblage of gravels and sands that underlies about 32,000 square miles of Missouri, Kentucky, Tennessee, Mississippi, Louisiana, and Arkansas. Because of the heavy demands placed on the aquifer, several large cones of depression have formed in the potentiometric surface, resulting in lower well yields and degraded water quality in some areas. A ground-water flow model of the alluvial aquifer was previously developed for an area covering 3,826 square miles, extending south from the Arkansas River into the southeastern corner of Arkansas, parts of northeastern Louisiana, and western Mississippi. The flow-model results indicated that continued ground-water withdrawals at rates commensurate with those of 1997 could not be sustained indefinitely without causing water levels to decline below half the original saturated thickness of the aquifer. Conjunctive-use optimization modeling was applied to the flow model of the alluvial aquifer to develop withdrawal rates that could be sustained relative to the constraints of critical ground-water area designation. These withdrawal rates form the basis for estimates of sustainable yield from the alluvial aquifer and from rivers specified within the alluvial aquifer model. A management problem was formulated as one of maximizing the sustainable yield from all ground-water and surface-water withdrawal cells within limits imposed by plausible withdrawal rates, and within specified constraints involving hydraulic head and streamflow. Steady-state conditions were selected because the maximized withdrawals are intended to represent sustainable yield of the system (a rate that can be maintained indefinitely).One point along the Arkansas River and one point along Bayou Bartholomew were specified for obtaining surface-water sustainable-yield estimates within the optimization model. Streamflow constraints were specified at two river cells based on average 7-day low flows with 10-year recurrence intervals. Sustainable-yield estimates were affected by the allowable upper limit on withdrawals from wells specified in the optimization model. Withdrawal rates were allowed to increase to 200 percent of the withdrawal rate in 1997. As the overall upper limit is increased, the sustainable yield generally increases. Tests with the optimization model show that without limits on pumping, wells adjacent to sources of water, such as large rivers, would have optimal withdrawal rates that were orders of magnitude larger than rates corresponding to those of 1997. Specifying an upper withdrawal limit of 100 percent of the 1997 withdrawal rate, the sustainable yield from ground water for the entire study area is 70.3 million cubic feet per day, which is about 96 percent of the amount withdrawn in 1997 (73.5 million cubic feet per day). If the upper withdrawal limit is increased to 150 percent of the 1997 withdrawal rate, the sustainable yield from ground water for the entire study area is 80.6 million cubic feet per day, which is about 110 percent of the amount withdrawn in 1997. If the upper withdrawal limit is increased to 200 percent of the 1997 withdrawal rate, the sustainable yield from ground water for the entire study area is 110.2 million cubic feet per day, which is about 150 percent of the amount withdrawn in 1997. Total sustainable yield from the Arkansas River and Bayou Bartholomew is about 4,900 million cubic feet per day, or about 6,700 percent of the amount of ground-water withdrawn in 1997. The large, sustainable yields from surface water represent a potential source of water that could supplement ground water and meet the total water demand. Unmet demand (defined as the difference between the optimized withdrawal rate or sustainable yield, and the anticipated demand) was calculated using different demand rates based on multiples of the 1997-withdrawal rate. Assuming that demand is the 1997 withdrawal rate, and that sustainable-

Water-Resources Investigations Report

Demonstration optimization analyses of pumping from selected Arapahoe aquifer municipal wells in the west-central Denver Basin, Colorado, 2010–2109

Declining water levels caused by withdrawals of water from wells in the west-central part of the Denver Basin bedrock-aquifer system have raised concerns with respect to the ability of the aquifer system to sustain production. The Arapahoe aquifer in particular is heavily used in this area. Two optimization analyses were conducted to demonstrate approaches that could be used to evaluate possible future pumping scenarios intended to prolong the productivity of the aquifer and to delay excessive loss of saturated thickness. These analyses were designed as demonstrations only, and were not intended as a comprehensive optimization study. Optimization analyses were based on a groundwater-flow model of the Denver Basin developed as part of a recently published U.S. Geological Survey groundwater-availability study. For each analysis an optimization problem was set up to maximize total withdrawal rate, subject to withdrawal-rate and hydraulic-head constraints, for 119 selected municipal water-supply wells located in 96 model cells. The optimization analyses were based on 50- and 100-year simulations of groundwater withdrawals. The optimized total withdrawal rate for all selected wells for a 50-year simulation time was about 58.8 cubic feet per second. For an analysis in which the simulation time and head-constraint time were extended to 100 years, the optimized total withdrawal rate for all selected wells was about 53.0 cubic feet per second, demonstrating that a reduction in withdrawal rate of about 10 percent may extend the time before the hydraulic-head constraints are violated by 50 years, provided that pumping rates are optimally distributed. Analysis of simulation results showed that initially, the pumping produces water primarily by release of water from storage in the Arapahoe aquifer. However, because confining layers between the Denver and Arapahoe aquifers are thin, in less than 5 years, most of the water removed by managed-flows pumping likely would be supplied by depleting overlying hydrogeologic units, substantially increasing the rate of decline of hydraulic heads in parts of the overlying Denver aquifer.

Colorado

Simulation of potential groundwater recharge for the glacial aquifer system east of the Rocky Mountains, 1980–2011, using the Soil-Water-Balance Model

An understanding of the spatial and temporal extent of groundwater recharge is critical for many types of hydrologic assessments involving water quality, contaminant transport, ecosystem health, and sustainable use of groundwater. Annual potential groundwater recharge was simulated at a 1-kilometer resolution with the Soil-Water-Balance (SWB) model for the glacial aquifer system east of the Rocky Mountains, from central Montana east to Maine, for calendar years 1980–2011. The SWB model used high resolution meteorological, land cover, and soil hydrology datasets that are nationally consistent and publicly available. The SWB model computed daily potential groundwater recharge as precipitation in excess of interception, runoff, evapotranspiration, and soil-water storage capacity. Daily potential recharge values within each year of the simulation were summed to produce annual potential recharge rates. Potential recharge as described in this report is water that infiltrates vertically below the plant rooting zone and is assumed to reach the water table. The calibrated SWB model in this report is called the glacial SWB model. Model calibration assumed that the area contributing to groundwater discharge equaled the surface watershed. The model was calibrated to stream base flows from 39 watersheds throughout the model domain that had hydrologic conditions appropriate for hydrograph separation. Base flows were calculated from daily streamflow records with the HYSEP local minimum hydrograph separation method The glacial SWB model reproduced the mean annual base-flow calibration targets well; the Nash-Sutcliffe efficiency coefficient was 0.94, and the root mean squared error was 1.28 inches per year. The glacial SWB model provides insight into the spatial and temporal variability in potential annual recharge across the glacial aquifer system. About 20 percent of the active model area had an average potential recharge rate of less than 1 inch per year. Total precipitation, total recharge, and recharge as a percentage of precipitation increased from west to east. A substantial amount of the recharge water (39 percent) entering the glacial aquifer system travels through developed (urbanized) and agricultural landscapes, which are known to cause water-quality impairments. Regional climatic events, such as the 1988 to 1989 drought, are apparent in the potential recharge time series. Potential recharge generally increased across the glacial aquifer system between 2001 and 2011. A comparison of the potential recharge from the glacial SWB model to previous broad-scale recharge estimates reveals several important considerations for future SWB modeling applications. Shifts in the overall distribution of potential recharge between separate models can be explained by methods used to generate base-flow calibration target datasets. Spatial patterns in potential recharge simulated by SWB models are strongly dependent on the data and assumptions used to assign model cells to hydrologic soil groups. A review of several SWB models used to estimate groundwater recharge (and not surface runoff) revealed that model results are most sensitive to input climatic data, followed by surface runoff (curve number) and root-zone depth parameters.

Scientific Investigations Report