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Antipodal hotspots and bipolar catastrophes: Were oceanic large-body impacts the cause?

One aspect of the hotspot distribution that has received little attention is its antipodal character. Of 45 ‘primary’ hotspots found in most hotspot compilations 22 (49%) form antipodal pairs within observed hotspot drift limits (≤ 20 mm/yr). In addition, the available ages, or possible age ranges, for both hotspots of an antipodal pair tend to be similar (≤ 10 Myr difference) or overlap. Monte Carlo simulations indicate that the antipodal primary hotspots' locations and ages are not due to chance at the > 99% confidence level ( p < 0.01). All hotspot pairs include at least one oceanic hotspot, and these are consistently opposite those hotspots related to large igneous provinces (LIPs) and continental volcanism. A mechanism of formation is considered in which minor hotspot volcanism is induced at, and flood basalt volcanism is triggered by seismic energy focused antipodal to, oceanic large-body impact sites. Because continental impacts are expected to have lower seismic efficiencies, continents possibly acted as shields to the formation of antipodal hotspot pairs. Published numerical models indicate that large oceanic impacts (10-km-diameter bolide) generate megatsunami capable of altering coastal depositional environments on a global scale. Past impact-generated megatsunami, consequently, could have left widespread stratigraphic records, possibly misinterpreted as indicating large rapid changes in eustatic sea level, and widely disrupted continental and marine sediment reservoirs responsible for abrupt changes in the isotopic composition of seawater. Phanerozoic mass extinction events, therefore, might have resulted primarily from catastrophic megatsunami in a dominantly oceanic hemisphere and the near contemporaneous effusion of vast quantities of noxious gases from flood basalt eruptions in a dominantly continental one.

Earth and Planetary Science Letters↗

Optical resolution of rotenoids

Optical resolution of selected rotenoids containing 1-3 asymmetric centers in dihydrobenzopyranofuroben-zopyranone and dihydrobisbenzopyranopyranone series has been achieved on two chiral high-performance liquid chromatographic (hplc) stationary phases. In most cases, the absolute stereochemistry at the cis -B/C ring junction of the rotenoidal antipodes can be related to their elution order. Generally, the 6a&alpha;,12a&alpha;-enantiomers were more strongly retained by the chiral substrate than their corresponding optical antipodes. The elution-configuration relationship provides potential utility for predicting the absolute configuration of related rotenoidal compounds. Chiral phase hplc on amino-acid-bonded-silica yielded results explicable in terms of Pirkle's bonding schemes for chiral recognition. Resolution data for 12a-hydroxy-, 12a-methoxy-, and 12-hydroxyiminorotenoids further corroborate the mechanistic rationale, and demonstrate that nonpolar &pi;-&pi; interactions appeared to be important for enantiomeric separation on helic poly-triphenylmethylacryl-ate-silica (CPOT). In the latter system, steric effects and conformational factors in association with the modification of E-ring structures might play significant roles in the chiral separation process in view of the reversal to the elution order observed for all methoxylated rotenoids and elliptone derivatives including the parent deguelin. The unique separability (&alpha; = 1.44) of 12a-hydroxyelliptone on CPOT was suggestive of structural effects of the 5-side chain on the resolution of the rotenoids having a five-membered-E-ring. The results obtained with two different types of chiral phases are complementary and useful for optical resolution of a wide variety of natural and synthetic rotenoidal compounds.

Journal of Heterocyclic Chemistry↗

Large impact features on Europa: Results of the Galileo Nominal Mission

The Galileo Orbiter examined several impact features on Europa at considerably better resolution than was possible from Voyager. The new data allow us to describe the morphology and infer the geology of the largest impact features on Europa, which are probes into the crust. We observe two basic types of large impact features: (1) “classic” impact craters that grossly resemble well-preserved lunar craters of similar size but are more topographically subdued (e.g., Pwyll) and (2) very flat circular features that lack the basic topographic structures of impact craters such as raised rims, a central depression, or central peaks, and which largely owe their identification as impact features to the field of secondary craters radially sprayed about them (e.g., Callanish). Our interpretation is that the classic craters (all <30 km diameter) formed entirely within a solid target at least 5 to 10 km thick that exhibited brittle behavior on time scales of the impact events. Some of the classic craters have a more subdued topography than fresh craters of similar size on other icy bodies such as Ganymede and Callisto, probably due to the enhanced viscous relaxation produced by a steeper thermal gradient on Europa. Pedestal ejecta facies on Europa (and Ganymede) may be produced by the relief-flattening movement of plastically deforming but otherwise solid ice that was warm at the time of emplacement. Callanish and Tyre do not appear to be larger and even more viscously relaxed versions of the classic craters; rather they display totally different morphologies such as distinctive textures and a series of large concentric structural rings cutting impact-feature-related materials. Impact simulations suggest that the distinctive morphologies would not be produced by impact into a solid ice target, but may be explained by impact into an ice layer ∼10 to 15 km thick overlying a low-viscosity material such as water. The very wide (near antipodal) separation of Callanish and Tyre imply that ∼10–15 km may have been the global average thickness of the rigid crust of Europa when these impacts occurred. The absence of detectable craters superposed on the interior deposits of Callanish suggests that it is geologically young (<10 8 years). Hence, it seems likely that our preliminary conclusions about the subsurface structure of Europa apply to the current day.

Icarus↗

Magnetostratigraphic correlations of Permian-Triassic marine-to-terrestrial sections from China

We have studied three Permian–Triassic (PT) localities from China as part of a combined magnetostratigraphic, 40 Ar/ 39 Ar and U–Pb radioisotopic, and biostratigraphic study aimed at resolving the temporal relations between terrestrial and marine records across the Permo-Triassic boundary, as well as the rate of the biotic recovery in the Early Triassic. The studied sections from Shangsi (Sichuan Province), Langdai (Guihzou Province), and the Junggar basin (Xinjiang Province), span marine, paralic, and terrestrial PT environments, respectively. Each of these sections was logged in detail in order to place geochronologic, paleomagnetic, geochemical, conodont and palynologic samples within a common stratigraphic context. Here we present rock-magnetic, paleomagnetic and magnetostratigraphic results from the three localities. At Shangsi, northern Sichuan Province, we sampled three sections spanning Permo-Triassic marine carbonates. Magnetostratigraphic results from the three sections indicate that the composite section contains at least eight polarity chrons and that the PT boundary occurs within a normal polarity chron a short distance above the mass extinction level and a reversed-to-normal (R-N) polarity reversal. Furthermore, the onset of the Illawarra mixed interval lies below the sampled section indicating that the uppermost Permian Changhsingian and at least part of the Wuchiapingian stages postdate the end of the Kiaman Permo-Carboniferous Reversed Superchron. At Langdai, Guizhou Province, we studied magnetostratigraphy of PT paralic mudstone and carbonate sediments in two sections. The composite section spans an R-N polarity sequence. Section-mean directions pass a fold test at the 95% confidence level, and the section-mean poles are close to the mean PT pole for the South China block. Based on biostratigraphic constraints, the R-N transition recorded at Langdai is consistent with that at Shangsi and demonstrates that the PT boundary occurred within a normal polarity chron a short distance above the mass extinction level. In the southern Junggar basin, Xinjiang Province, in northwest China, we determined the magnetostratigraphy of three sections of a terrestrial sequence. Normal and reversed polarity directions are roughly antipodal, and magnetostratigraphies from the three sections are highly consistent. Combined bio- and magneto-stratigraphy used to correlate this sequence to other PT sequences suggests that the previously-proposed biostratigraphic PT boundary in the Junggar sections was most likely misplaced by earlier workers suggesting that further work is necessary to confidently place the PT boundary there.

Journal of Asian Earth Sciences↗

Paleomagnetism of Proterozoic mafic dikes from the Tobacco Root Mountains, southwest Montana

Paleomagnetic data from Proterozoic mafic dikes in southwestern Montana provides evidence for two distinct episodes of subparallel dike emplacement at ca. 1450 and 780 Ma. Published geochemical data from dikes in the southern Tobacco Root Mountains has identified three distinct compositional groups, termed groups A, B, and C. Geochronological data from the group A dikes yielded a Sm-Nd age of 1448 ?? 49 Ma. Emplacement of these dikes is thought to reflect mafic magmatism associated with extension accompanying development of the adjacent Mesoproterozoic Belt Basin. Paleomagnetic results from these dikes and a group C dike yield antipodal magnetizations with a group-mean direction of D = 225.0??, I = 61.8?? (k = 27.9, ??95 = 7.7??, N = 14 independent means/24 sites). The average paleomagnetic pole (8.7??N, 216.1??E, A95 = 10.3??) is considered to be primary on the basis of positive baked contact tests and similarity to poles of ca. 1.45-1.4 Ga from intrusions elsewhere in North America, but is discordant with respect to poles from age equivalent sedimentary rocks of the Meosoproterozoic Belt Supergroup. 40Ar/39Ar dates from geochemical group B dikes are consistent with published U-Pb dates that demonstrate dike emplacement at 780 Ma as part of the regional Gunbarrel magmatic event. Hornblende concentrates from the group B dikes yield 40Ar/39Ar apparent ages of 778-772 Ma, whereas biotite from a baked contact zone yielded a plateau date of 788 Ma. Paleomagnetic results from the group B dikes yield a mean direction of D = 301.5??, I = -17.1?? (k = 65.7, ??95 = 4.0??, N = 12 independent means/23 sites) with a paleomagnetic pole at 14.6??N, 127.0??E (A95 = 3.2??). The combination of geochronologic data, results of a baked contact test, and spatial agreement of the paleomagnetic poles with poles of similar age elsewhere in North America indicates that this is also a primary magnetization associated with dike emplacement. Paleomagnetic data from some of the Tobacco Root Mountains dikes provide evidence that they were partially to completely remagnetized during latest Cretaceous to early Tertiary time, perhaps due to thermal affects associated with emplacement of the Late Cretaceous Tobacco Root Batholith. The overall agreement of paleomagnetic poles from the Proterozoic dikes with those of age equivalent rocks elsewhere in North America and agreement of the secondary magnetization with expected directions for the latest Cretaceous/early Tertiary indicate that the rocks of the Tobacco Root Mountains have not experienced significant tilting or vertical axis rotation since the Mesoproterozoic. The new paleomagnetic poles from this study thus provide key data for refining Meso- and Neoproterozoic parts of the North American APW path. ?? 2008 Elsevier B.V. All rights reserved.

Precambrian Research↗

Chiral-phase high-performance liquid chromatography of rotenoid racemates

The high-performance liquid chromatograhic (HPLC) behavior of parent rotenoids (type I) and the hydroxyl-analogues (type II) on three different chiral stationary phases (CSPs) was studied. Separations of optical isomers were achieved in various degrees depending largely upon the rotenoidal structures and the CSP types employed. Enantiomers of all but elliptone compounds were separable on &beta;-cyclodextrin-bonded silica (CDS). Without exception, the 12a-hydroxyrotenoid antipodes were resolved on Pirkle's phenylglycine-bonded silica (PGS) despite unsuccessful attenmpts to resolve the type I rotenoidal racemates. Conversely, optical resolution of the latter rotenoids was accomplished by using a helical polytriphenylmethylacrylate-coated silica (TPS) column and the observed separation factors (&alpha; values) ranged from 1.14 to 1.90. The results from HPLC of type II rotenoids on TPS (&alpha; = 1.00&ndash;1.63) suggested that variations in E-ring structures had profound influence on the resolution outcome. Conjugated double bonds on the E-ring and the desisopropylation of the five-membered E-ring ot type II rotenoids appeared to be important structural features for chiral recognition involving the TPS substrate. In both reversed-phase (CDS) and normal-pahse (PGS and TPS) HPLC modes, the less polar enantiomers were the 6a&beta;,12a&beta;-rotenoids as observed in most cases, though this relationship was reversed in the cases of deguelin and hydroxyelliptone probably due to conformational effects of rotenoidal ring systems.

Journal of Chromatography↗

Paleomagnetism and 40Ar/39Ar ages from volcanics extruded during the Matuyama and Brunhes Chrons near McMurdo Sound, Antarctica

Maps of virtual geomagnetic poles derived from international geomagnetic reference field models show large lobes with significant departures from the spin axis. These lobes persist in field models for the last few millenia. The anomalous lobes are associated with observation sites at extreme southerly latitudes. To determine whether these features persist for millions of years, paleomagnetic vector data from the continent of Antarctica are essential. We present here new paleomagnetic vector data and 40 Ar/ 39 Ar ages from lava flows spanning the Brunhes and Matuyama Chrons from the vicinity of McMurdo Sound, Antarctica. Oriented paleomagnetic samples were collected from 50 lava flows by E. Mankinen and A. Cox in the 1965–1966 austral summer season. Preliminary data based largely on the natural remanent magnetization (NRM) directions were published by Mankinen and Cox [1988]. We have performed detailed paleomagnetic investigations of 37 sites with multiple fully oriented core samples to investigate the reliability of results from this unique sample collection. Of these, only one site fails to meet our acceptance criteria for directional data. Seven sites are reversely magnetized. The mean normal and reverse directions are antipodal. The combined mean direction has = 12, = −86, α = 4, κ = 37 and is indistinguishable from that expected from a GAD field. We obtained reproducible absolute paleointensity estimates from 15 lava flows with a mean dipole moment of 49 ZAm 2 and a standard deviation of 28 ZAm 2 . 40 Ar/ 39 Ar age determinations were successfully carried out on samples from 18 of the flows. Our new isotopic ages and paleomagnetic polarities are consistent with the currently accepted geomagnetic reversal timescales.

Geochemistry, Geophysics, Geosystems↗

Paleomagnetic study of late Miocene through Pleistocene igneous rocks from the southwestern USA: Results from the historic collections of the U.S. Geological Survey Menlo Park laboratory

Seventy sites from the southwestern United States provide paleomagnetic results that meet certain minimum criteria and can be considered for the Time‐Averaged Field Initiative (TAFI). The virtual geomagnetic poles for these 70 units are circularly distributed, and their mean is nearly coincident with the rotational axis. When other published data for the southwestern United States are included (N = 146), the virtual geomagnetic poles are again circularly distributed, but their mean is significantly displaced from the rotational axis. Whichever of these data sets is used, the mean poles for normal‐ and reversed‐polarity data differ by ∼170° and are not antipodal at greater than 95% confidence. When the data are separated into specific age groups, the 95% confidence limits about the mean poles for the Brunhes, Matuyama, combined Gauss/Gilbert, and late Miocene intervals all include the rotational axis. Angular dispersion about these four mean poles increases systematically with increasing age and is consistent with paleosecular variation Model “G.”

Geochemistry, Geophysics, Geosystems↗

Global primary and secondary microseism multi-decade geographic variation, secular intensification, and period lengthening

Earth's long-period background seismic wavefield is dominated by two distinct processes that couple ocean wave energy to a global microseism wavefield. We assess global microseism intensity in the secondary (4–10 s) and primary (14–20 s) bands, and across eight 2 s-wide period bands between 4 and 20 s. Robustly estimated primary and secondary secular amplitude trends are estimated at 73 globally distributed seismic station sites with continuous recording spanning at least 20 years, from as early as the late 1980s through October 2025. These trends are positive at 3⁢𝜎 significance for 61 (84%) and 46 (63%) stations with global average rates for vertical-component acceleration of 0.17 ± 0.04 and 0.11 ± 0.05%/yr, for the primary and secondary bands, respectively, with corresponding rates of energy increase of 0.27 ± 0.08 and 0.15 ± 0.09%/yr. Secular intensification is also observed within all 2 s period bands between 4 and 20 s. Amplitude histories for the longest primary microseism periods (18–20 s) correlate to near-antipodal distances, reflecting long-range teleconnections attributed to large-fetch storm systems, long-range swell and Rayleigh wave propagation, and geographically correlated El Niño Southern Oscillation and other geographically extensive atmospheric influences on storms and waves. The lower average rates of intensification for the secondary microseism suggest that crossing wave systems in remote regions are either under-observed or are intensifying more slowly than the primary microseism, possibly due to increasing swell unidirectionality. Secular intensification is greatest at the longest primary microseism periods. This is consistent with a broadening of the global ocean wave spectrum by approximately 0.01%/yr which may reflect an increasing occurrence of large storm systems.

JGR Solid Earth↗

Paleomagnetic evidence that the central block of Salinia (California) is not a far-traveled terrane

New paleomagnetic results from Late Cretaceous (75–85 m.y.) red beds on the central block of Salinia indicate that Salinia was located within 6° (in latitude) of its current cratonal North American position during the Late Cretaceous (after correction for Neogene San Andreas Fault transport). The red beds formed as alluvial-fan overbank deposits with hematite cement deposited directly on Salinian granites in the La Panza Range. Paleomagnetic analysis shows two components of magnetization in the red beds, a low-blocking-temperature present-day overprint residing in goethite and a high-blocking-temperature (>600°) component residing in hematite. The hematite magnetization is a chemical remanent magnetization which formed soon after deposition during pedogenesis. The bedding-corrected hematite remanence contains a magnetic polarity stratigraphy with antipodal normal and reversed directions. Twenty-three Class I sites (α 95 < 20°) have an average hematite direction with inclination =54.4° and declination = 18.2° (α 95 = 6.1°) after structural correction. These paleomagnetic data suggest that Salinia resided at about 35°N latitude during the Late Cretaceous, within 6° of its current location adjacent to cratonal North America. By contrast, a summary of paleomagnetic data from the Peninsular Ranges terrane and the Sur-Obispo terrane, which are currently outboard of Salinia, shows northward transport of these terranes of 12° to 22° relative to their current locations in North America since the Cretaceous. The offsets increase systematically away from the craton with the most outboard Sur-Obispo terrane (which is composed of accretionary prism and distal forearc material) showing the largest degree of northward translation.

California↗

Brunhes chron excursion/polarity episode recorded during the late pleistocene, Albuquerque Volcanoes, New Mexico, USA

All basaltic lava flows of the Albuquerque Volcanoes (lat.: 35.2°N, long.: 253.2°E), Albuquerque-Belen Basin, New Mexico, record a short excursion/polarity episode. K-Ar isotopic age determinations (weighted average: 155 ± 47 ka) and evaluation of soil profiles on flow surfaces suggest the late Pleistocene ( circa between 250 and 80 ka) as the time of extrusion. Results from 63 sites in a minimum of eight flows yield a mean direction of D = 101.1°, I = -36.1°, α 95 = 1.2° (α 1 95 = 0.7, α 2 95 = 1.2), k = 2219 ( N = 8 flows) and a corresponding virtual geomagnetic pole position (VGP) of 354.1°E, 20.2°S, dp = 0.8°, dm = 1.4° ( A 1 95 = 0.5, A 2 95 = 1.4), and VGP angular standard deviation (ASD) = 1.8°. The unusual magnetization in flows of the Albuquerque Volcanoes is carried by fine-grained [single-domain (SD) and/or pseudo-single-domain (PSD)] low-Ti magnetite and is apparently not a function of complex sub-solidus alteration of magnetic phases. Underlying baked soils contain a relatively low coercivity magnetization with directions comprising two groups. One is roughly antipodal to the lava remanence; the other intermediate between the lava remanence and present field direction. Because all flows yield statistically indistinguishable directions, a field directional path clearly cannot be defined. At the precision level of our age determinations, the Albuquerque feature may correlate with other short polarity episodes or excursions of late Pleistocene age (e.g., Blake or Jamaica). Though characteristically limited in directional morphology, well-dated polarity episodes (i.e. sub-chrons) and excursions recorded in volcanic rocks may provide information on the frequency of significant dynamo instabilities.

New Mexico↗

Atmospheric waves and global seismoacoustic observations of the January 2022 Hunga eruption, Tonga

The 15 January 2022 climactic eruption of Hunga volcano, Tonga, produced an explosion in the atmosphere of a size that has not been documented in the modern geophysical record. The event generated a broad range of atmospheric waves observed globally by various ground-based and spaceborne instrumentation networks. Most prominent was the surface-guided Lamb wave (≲0.01 hertz), which we observed propagating for four (plus three antipodal) passages around Earth over 6 days. As measured by the Lamb wave amplitudes, the climactic Hunga explosion was comparable in size to that of the 1883 Krakatau eruption. The Hunga eruption produced remarkable globally detected infrasound (0.01 to 20 hertz), long-range (~10,000 kilometers) audible sound, and ionospheric perturbations. Seismometers worldwide recorded pure seismic and air-to-ground coupled waves. Air-to-sea coupling likely contributed to fast-arriving tsunamis. Here, we highlight exceptional observations of the atmospheric waves.

Hunga volcano↗

Evidence for a global seismic-moment release sequence

Temporal clustering of the larger earthquakes (foreshock-mainshock-aftershock) followed by relative quiescence (stress shadow) are characteristic of seismic cycles along plate boundaries. A global seismic-moment release history, based on a little more than 100 years of instrumental earthquake data in an extended version of the catalog of Pacheco and Sykes (1992), illustrates similar behavior for Earth as a whole. Although the largest earthquakes have occurred in the circum-Pacific region, an analysis of moment release in the hemisphere antipodal to the Pacific plate shows a very similar pattern. Monte Carlo simulations confirm that the global temporal clustering of great shallow earthquakes during 1952-1964 at M ??? 9.0 is highly significant (4% random probability) as is the clustering of the events of M ??? 8.6 (0.2% random probability) during 1950-1965. We have extended the Pacheco and Sykes (1992) catalog from 1989 through 2001 using Harvard moment centroid data. Immediately after the 1950-1965 cluster, significant quiescence at and above M 8.4 begins and continues until 2001 (0.5% random probability). In alternative catalogs derived by correcting for possible random errors in magnitude estimates in the extended Pacheco-Sykes catalog, the clustering of M ??? 9 persists at a significant level. These observations indicate that, for great earthquakes, Earth behaves as a coherent seismotectonic system. A very-large-scale mechanism for global earthquake triggering and/or stress transfer is implied. There are several candidates, but so far only viscoelastic relaxation has been modeled on a global scale.

Bulletin of the Seismological Society of America↗