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The GIS weasel - An interface for the development of spatial information in modeling

The GIS Weasel is a map and Graphical User Interface (GUI) driven tool that has been developed as an aid to modelers in the delineation, characterization of geographic features, and their parameterization for use in distributed or lumped parameter physical process models. The interface does not require user expertise in geographic information systems (GIS). The user does need knowledge of how the model will use the output from the GIS Weasel. The GIS Weasel uses Workstation ArcInfo and its the Grid extension. The GIS Weasel will run on all platforms that Workstation ArcInfo runs (i.e. numerous flavors of Unix and Microsoft Windows).The GIS Weasel requires an input ArcInfo grid of some topographical description of the Area of Interest (AOI). This is normally a digital elevation model, but can be the surface of a ground water table or any other data that flow direction can be resolved from. The user may define the AOI as a custom drainage area based on an interactively specified watershed outlet point, or use a previously created map. The user is then able to use any combination of the GIS Weasel's tool set to create one or more maps for depicting different kinds of geographic features. Once the spatial feature maps have been prepared, then the GIS Weasel s many parameterization routines can be used to create descriptions of each element in each of the user s created maps. Over 200 parameterization routines currently exist, generating information about shape, area, and topological association with other features of the same or different maps, as well many types of information based on ancillary data layers such as soil and vegetation properties. These tools easily integrate other similarly formatted data sets.

Conference Paper↗

Nitrogen fluxes and retention in urban watershed ecosystems

Although the watershed approach has long been used to study whole-ecosystem function, it has seldom been applied to study human-dominated systems, especially those dominated by urban and suburban land uses. Here we present 3 years of data on nitrogen (N) losses from one completely forested, one agricultural, and six urban/suburban watersheds, and input-output N budgets for suburban, forested, and agricultural watersheds. The work is a product of the Baltimore Ecosystem Study, a long-term study of urban and suburban ecosystems, and a component of the US National Science Foundation's long-term ecological research (LTER) network. As expected, urban and suburban watersheds had much higher N losses than did the completely forested watershed, with N yields ranging from 2.9 to 7.9 kg N ha −1 y −1 in the urban and suburban watersheds compared with less than 1 kg N ha −1 y −1 in the completely forested watershed. Yields from urban and suburban watersheds were lower than those from an agricultural watershed (13-19.8 kg N ha −1 y −1 ). Retention of N in the suburban watershed was surprisingly high, 75% of inputs, which were dominated by home lawn fertilizer (14.4 kg N ha −1 y −1 ) and atmospheric deposition (11.2 kg N ha −1 y −1 ). Detailed analysis of mechanisms of N retention, which must occur in the significant amounts of pervious surface present in urban and suburban watersheds, and which include storage in soils and vegetation and gaseous loss, is clearly warranted.

Maryland↗

Multielement geochemical dataset of surficial materials for the northern Great Basin

This report presents geochemical data generated during mineral and environmental assessments for the Bureau of Land Management in northern Nevada, northeastern California, southeastern Oregon, and southwestern Idaho, along with metadata and map representations of selected elements. The dataset presented here is a compilation of chemical analyses of over 10,200 stream-sediment and soil samples originally collected during the National Uranium Resource Evaluation's (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program of the Department of Energy and its predecessors and reanalyzed to support a series of mineral-resource assessments by the U.S. Geological Survey (USGS). The dataset also includes the analyses of additional samples collected by the USGS in 1992. The sample sites are in southeastern Oregon, southwestern Idaho, northeastern California, and, primarily, in northern Nevada. These samples were collected from 1977 to 1983, before the development of most of the present-day large-scale mining infrastructure in northern Nevada. As such, these data may serve as an important baseline for current and future geoenvironmental studies. Largely because of the very diverse analytical methods used by the NURE HSSR program, the original NURE analyses in this area yielded little useful geochemical information. The Humboldt, Malheur-Jordan-Andrews, and Winnemucca-Surprise studies were designed to provide useful geochemical data via improved analytical methods (lower detection levels and higher precision) and, in the Malheur-Jordan-Andrews and Winnemucca Surprise areas, to collect additional stream-sediment samples to increase sampling coverage. The data are provided in *.xls (Microsoft Excel) and *.csv (comma-separated-value) format. We also present graphically 35 elements, interpolated ("gridded") in a geographic information system (GIS) and overlain by major geologic trends, so that users may view the variation in elemental concentrations over the landscape and reach their own conclusions regarding correlation among geochemistry, geologic features, and known mineral deposits. Quality-control issues are discussed for the grids and data.

California; Nevada; Oregon↗

Quality of Shallow Groundwater and Drinking Water in the Mississippi Embayment-Texas Coastal Uplands Aquifer System and the Mississippi River Valley Alluvial Aquifer, South-Central United States, 1994-2004

The Mississippi embayment-Texas coastal uplands aquifer system is an important source of drinking water, providing about 724 million gallons per day to about 8.9 million people in Texas, Louisiana, Mississippi, Arkansas, Missouri, Tennessee, Kentucky, Illinois, and Alabama. The Mississippi River Valley alluvial aquifer ranks third in the Nation for total withdrawals of which more than 98 percent is used for irrigation. From 1994 through 2004, water-quality samples were collected from 169 domestic, monitoring, irrigation, and public-supply wells in the Mississippi embayment-Texas coastal uplands aquifer system and the Mississippi River Valley alluvial aquifer in various land-use settings and of varying well capacities as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Groundwater samples were analyzed for physical properties and about 200 water-quality constituents, including total dissolved solids, major inorganic ions, trace elements, radon, nutrients, dissolved organic carbon, pesticides, pesticide degradates, and volatile organic compounds. The occurrence of nutrients and pesticides differed among four groups of the 114 shallow wells (less than or equal to 200 feet deep) in the study area. Tritium concentrations in samples from the Holocene alluvium, Pleistocene valley trains, and shallow Tertiary wells indicated a smaller component of recent groundwater than samples from the Pleistocene terrace deposits. Although the amount of agricultural land overlying the Mississippi River Valley alluvial aquifer was considerably greater than areas overlying parts of the shallow Tertiary and Pleistocene terrace deposits wells, nitrate was rarely detected and the number of pesticides detected was lower than other shallow wells. Nearly all samples from the Holocene alluvium and Pleistocene valley trains were anoxic, and the reducing conditions in these aquifers likely result in denitrification of nitrate. In contrast, most samples from the Pleistocene terrace deposits in Memphis, Tennessee, were oxic, and the maximum nitrate concentration measured was 6.2 milligrams per liter. Additionally, soils overlying the Holocene alluvium and Pleistocene valley trains, generally in areas near the wells, had lower infiltration rates and higher percentages of clay than soils overlying the shallow Tertiary and Pleistocene terrace deposits wells. Differences in these soil properties were associated with differences in the occurrence of pesticides. Pesticides were most commonly detected in samples from wells in the Pleistocene terrace deposits, which generally had the highest infiltration rates and lowest clay content. Median dissolved phosphorus concentrations were 0.07, 0.11, and 0.65 milligram per liter in samples from the shallow Tertiary, Pleistocene valley trains, and Holocene alluvium, respectively. The widespread occurrence of dissolved phosphorus at concentrations greater than 0.02 milligram per liter suggests either a natural source in the soils or aquifer sediments, or nonpoint sources such as fertilizer and animal waste or a combination of natural and human sources. Although phosphorus concentrations in samples from the Holocene alluvium were weakly correlated to concentrations of several inorganic constituents, elevated concentrations of phosphorus could not be attributed to a specific source. Phosphorus concentrations generally were highest where samples indicated anoxic and reducing conditions in the aquifers. Elevated dissolved phosphorus concentrations in base-flow samples from two streams in the study area suggest that transport of phosphorus with groundwater is a potential source contributing to high yields of phosphorus in the lower Mississippi River basin. Water from 55 deep wells (greater than 200 feet deep) completed in regional aquifers of Tertiary age represent a sample of the principal aquifers used for drinking-water supply in the study area. The wells were screened in both confined and

Scientific Investigations Report↗

Atlas of ground-water resources in Puerto Rico and the U.S. Virgin Islands

This atlas presents an overview of the ground-water resources of the main island of Puerto Rico; two of its larger offshore islands, Isla de Culebra and Isla de Vieques; and the three principal islands of the U.S. Virgin Islands, St. Thomas, St. John, and St. Croix. The atlas presents the most important ground-water information available for these islands, and is written for water managers and the general public. It describes, through the use of maps, graphs, and hydrogeologic sections, the most important aspects of the geohydrology, ground-water flow system, and groundwater withdrawals for the principal aquifers in these islands. Most of the information presented in the atlas is from published reports, although unpublished data from ongoing studies by the U.S. Geological Survey were used to prepare parts of the atlas. This report provides a useful compilation of information concerning major aquifers in Puerto Rico and the U.S. Virgin Islands and provides a first step in gaining a general knowledge of these aquifers. More detailed information is available from the primary sources referenced in the report. The atlas contains an introductory section and 15 sections describing the ground-water resources of 12 regions within the 7 ground-water areas of the main island of Puerto Rico, Isla de Culebra and Isla de Vieques (described in a single section of the atlas), and the U.S. Virgin Islands (St. Thomas and St. John are described in one section of the atlas and St. Croix in another), and a concluding section describing present and potential problems related to the development of ground-water resources. Information presented in each of 15 descriptive sections of the atlas include the (1) location and major geographic features of the area covered by that section, (2) population and estimated (4) hydrogeology of the area, (5) ground-water levels and movements, and (6) a description of soil permeabilities.

Water-Resources Investigations Report↗

The role of environmental gradients in non-native plant invasion into burnt areas of Yosemite National Park, California

Fire is known to facilitate the invasion of many non-native plant species, but how invasion into burnt areas varies along environmental gradients is not well-understood. We used two pre-existing data sets to analyse patterns of invasion by non-native plant species into burnt areas along gradients of topography, soil and vegetation structure in Yosemite National Park, California, USA. A total of 46 non-native species (all herbaceous) were recorded in the two data sets. They occurred in all seven of the major plant formations in the park, but were least common in subalpine and upper montane conifer forests. There was no significant difference in species richness or cover of non-natives between burnt and unburnt areas for either data set, and environmental gradients had a stronger effect on patterns of non-native species distribution, abundance and species composition than burning. Cover and species richness of non-natives had significant positive correlations with slope (steepness) and herbaceous cover, while species richness had significant negative correlations with elevation, the number of years post-burn, and cover of woody vegetation. Non-native species comprised a relatively minor component of the vegetation in both burnt and unburnt areas in Yosemite (percentage species Combining double low line 4%, mean cover < 6.0%), and those species that did occur in burnt areas tended not to persist over time. The results indicate that in many western montane ecosystems, fire alone will not necessarily result in increased rates of invasion into burnt areas. However, it would be premature to conclude that non-native species could not affect post-fire succession patterns in these systems. Short fire-return intervals and high fire severity coupled with increased propagule pressure from areas used heavily by humans could still lead to high rates of invasion, establishment and spread even in highly protected areas such as Yosemite. ?? 2006 Blackwell Publishing Ltd.

Diversity and Distributions↗

Volcanic gas monitoring

Introduction As magma rises through the crust, decreasing pressure conditions allow volatiles to exsolve from the magma. These volatiles then migrate upward through the crust, where they can be stored at shallower levels or escape to the atmosphere. Rising magma also heats rock masses beneath volcanic centers, causing water in shallow aquifers and hydrothermal systems to boil and release additional gases and steam (see chapter F , this volume; Ingebritsen and Hurwitz, 2024). The chemistry and quantity of gases that reach the surface during periods of quiescence or volcanic unrest can reveal that gas-rich magma is ascending, crystallizing, or alternatively stalling, with important implications for volcanic hazard (for example, Sutton and others, 1992; Aiuppa and others, 2007, 2021; Werner and others, 2009, 2011, 2012; Moretti and others, 2013; de Moor and others, 2016; Lewicki and others, 2019; Edmonds and others, 2022; Kern and others, 2022; Kunrat and others, 2022). Most volcanoes in Alaska and the western United States are characterized by weak degassing, with one or more low-temperature fumaroles (typically near the local boiling temperature of water) and connect to a deeper and sometimes extensive hydrothermal system (for example, McGee and others, 2001; Symonds and others, 2003a, b). Hydrothermal systems will affect the chemistry of rising gases exsolved from deeper magma (Symonds and others, 2001), including sulfur dioxide (SO 2 ), hydrogen chloride (HCl), and water vapor (for example, Doukas and Gerlach, 1995; Gerlach and others, 1998, 2008; Symonds and others, 2001; Werner and others, 2013). As an example, depending on factors such as temperature, pressure, and oxidation state, rising SO 2 will react with groundwater to form hydrogen sulfide (H 2 S) gas, dissolved sulfate (SO 4 2− ), or elemental sulfur (Christenson, 2000; Symonds and others, 2001; Werner and others, 2008). The reaction and dissolution of SO 2 into shallow groundwater is commonly referred to as scrubbing, and can reduce the likelihood that ascending, degassing magma can be detected. Carbon dioxide, however, in addition to exsolving from magma early in the ascent process, is not easily removed by hydrothermal fluids (Lowenstern, 2001). As scrubbing and other processes take place, the SO 2 /H 2 S, CO 2 /SO 2 , and CO 2 /H 2 S ratios may change. High rates of SO 2 emission indicate that magma has moved to relatively shallow levels in the volcano and that the system has heated up enough to establish dry pathways from depth to the surface. Monitoring multiple gas species and the total output of those species is thereby useful for volcano monitoring during both periods of quiescence, to establish background degassing conditions, and during unrest, when gas geochemistry and emission rates can provide information on changing conditions, such as magma ascent. To provide context for multidisciplinary volcano forecasts, we focus on the following two key required capabilities: (1) characterizing baseline geochemistry and gas discharge from volcanoes and volcanic regions and (2) monitoring changes in gas geochemistry and discharge to inform forecasts of volcanic eruptions and their effects. Sufficient baseline data must be collected to identify and interpret anomalous degassing associated with volcanic unrest (for example, Sorey and others, 1998; Rouwet and others, 2014). Differences in volcano type, baseline degassing rates, local hydrology, and geography (for example, high versus low latitude) will result in a different baseline for each volcano. Volcanoes of any threat level that exhibit one or more degassing phenomena would ideally be monitored by techniques needed to establish baseline degassing data, with the sampling frequency of baseline data dictated by the threat level (table E1). Additional monitoring techniques become necessary during periods of unrest. In general, three of the most important techniques for gas monitoring are (1) direct sampling of fumarole, spring, and soil gases for laboratory geochemical measurements, (2) measurements of the chemical composition of the volcanic plume and emission rates of major gas species (for example, H 2 O, CO 2 , SO 2 , and H 2 S) by satellite, airborne, or ground-based techniques, and (3) measurements of diffuse emissions of CO 2 and other gases through soils. Various methods and instruments may be useful both for baseline studies and during unrest.

Scientific Investigations Report↗

Daily fluctuating flows affect riparian plant species distributions from local to regional scales

Aims The number of hydropower dams has grown globally over recent decades, with significant impacts on downstream riparian plant communities. Many of these dams generate daily fluctuating flows known as hydropeaking to meet sub-daily variation in energy demands. Hydropeaking can significantly impact riparian plant communities, with obligate riparian species tending to experience the greatest negative effects on habitat suitability. Whether this pattern holds in arid biomes where daily soil moisture enhancements could benefit some plants is an open question. Location Colorado River, Grand Canyon, Western USA. Methods We used occurrence records to model species responses to variation in daily flow fluctuations across 32 689 river segments in the Western United States. We then applied estimates of hydropeaking responses derived from those models to understanding the abundance and fine scale hydrologic niches of riparian plant species in the Colorado River ecosystem downstream of Glen Canyon Dam, which has experienced vegetation expansion attributed to river regulation, including hydropeaking that began in 1964. Results At the regional scale, species with greater wetland dependence exhibited increasingly negative responses to hydropeaking across 1 496 species, consistent with previous studies at smaller scales. At the local scale of the Colorado River, we found that species inhabiting near-channel habitat characterized by daily inundation and exposure had positive modeled responses to hydropeaking, consistent with a long history of selection for species tolerant of hydropeaking. In contrast, species inhabiting the zone immediately above peak daily river stage had negative modeled responses to hydropeaking, suggesting that they are being excluded from otherwise suitable habitat nearer the channel. Conclusions These results demonstrate that hydropeaking can impact species distributions from local to regional scales by excluding obligate wetland species and reducing habitat suitability for some facultative wetland species. These results from an arid river system are consistent with those reported from other biomes.

Arizona↗

Effects of farming systems on ground-water quality at the management systems evaluation area near Princeton, Minnesota, 1991-95

Ground-water quality in an unconfined sand and gravel aquifer was monitored during 1991-95 at the Minnesota Management Systems Evaluation Area (MSEA) near Princeton, Minnesota. The objectives of the study were to: (1) describe the effects of three farming systems on groundwater quality, and (2) evaluate the factors affecting ground-water quality and transport of agricultural chemicals at the site. Concentrations of nitrate nitrogen (nitrate-N) in the upper 1 meter (m) of the saturated zone were greatest beneath the two cropped areas having a potato-sweet corn annual rotation (median concentrations of 23 and 22 mg/L). Concentrations of nitrate-N were least beneath a cropped area having a field cornsoybean annual rotation (median of 14 mg/L); another cropped area having the field corn-soybean rotation had similar nitrate-N concentrations to those beneath a cropped area having field corn in consecutive years (continuous corn)(medians of 17 mg/L). Concentrations of atrazine plus metabolites de-ethylatrazine (DEA) and de-isopropylatrazine (DIA), atrazine plus metabolites, were significantly greater during 1994-95 than during 1992- 93 beneath all cropped areas in the upper 1 m of the saturated zone. Concentrations of atrazine plus metabolites during 1994-95 were greatest beneath the continuous corn (median of 1.07 ( &mu; g/L), intermediate beneath one cropped area with the potato-sweet corn rotation (median of 0.37 &mu; g/L), and least beneath the other cropped area with the potato-sweet corn rotation, the field corn-soybean rotation, and background areas (medians ranging from 0.11 to 0.21 &mu; g/L), for which concentrations were not significantly different. Concentrations of atrazine plus metabolites during 1992-93 were mostly similar beneath the different cropped areas and background areas. DEA was the predominant atrazine-metabolite detected in ground water; the average DEA to atrazine ratio was 8.0. The herbicides metribuzin, alachlor, and metolachlor were rarely detected in ground water at trace levels and could not be linked to the MSEA farming systems, with the exception of metribuzin detections during 1993-94 at concentrations of 0.14-1.24 ( &mu; g/L beneath one cropped area where metribuzin was applied to potatoes. Peak concentrations of chloride and bromide tracers were usually detected in the upper 2 m of the saturated zone 11 to 19 months after application. Peak concentrations of nitrate-N and atrazine plus metabolites were usually detected about 13 to 27 months and 2 years after application, respectively. The estimated proportion of applied nitrogen that reached ground water ranged from about 13 to 50 percent with an average of 30 percent. Differences in the concentrations of nitrate-N in ground water between different cropped areas were related to varying nitrogen application rates, timing of nitrogen application, timing of recharge in relation to crop rotation, and differences in nitrogen uptake by crops. In order of importance, plant uptake and leaching to ground water likely account for most of the nitrogen applied. Denitrification likely is an important mechanism affecting nitrate-N concentrations at depths greater than 2 m below the water table. The proportion of applied atrazine in ground water, detected as atrazine or its metabolites, ranged from 0 to about 1 percent with an average of 0.37 percent. The small proportion of applied atrazine detected in ground water indicates that atrazine was predominantly affected by processes occurring in the soil such as adsorption and degradation. Concentrations of atrazine plus metabolites were related to application rates.

Minnesota↗

Covariance of bacterioplankton composition and environmental variables in a temperate delta system

We examined seasonal and spatial variation in bacterioplankton composition in the Sacramento-San Joaquin River Delta (CA) using terminal restriction fragment length polymorphism (T-RFLP) analysis. Cloned 16S rRNA genes from this system were used for putative identification of taxa dominating the T-RFLP profiles. Both cloning and T-RFLP analysis indicated that Actinobacteria , Verrucomicrobia , Cytophaga-Flavobacterium and Proteobacteria were the most abundant bacterioplankton groups in the Delta. Despite the broad variety of sampled habitats (deep water channels, lakes, marshes, agricultural drains, freshwater and brackish areas), and the spatial and temporal differences in hydrology, temperature and water chemistry among the sampling campaigns, T-RFLP electropherograms from all samples were similar, indicating that the same bacterioplankton phylotypes dominated in the various habitats of the Delta throughout the year. However, principal component analysis (PCA) and partial least-squares regression (PLS) of T-RFLP profiles revealed consistent grouping of samples on a seasonal, but not a spatial, basis. b- Proteobacteria related to Ralstonia , Actinobacteria related to Microthrix , and b- Proteobacteria identical to the environmental Clone LD12 had the highest relative abundance in summer/fall T-RFLP profiles and were associated with low river flow, high pH, and a number of optical and chemical characteristics of dissolved organic carbon (DOC) indicative of an increased proportion of phytoplankton-produced organic material as opposed to allochthonous, terrestrially derived organic material. On the other hand, Geobacter -related b- Proteobacteria showed a relative increase in abundance in T-RFLP analysis during winter/spring, and probably were washed out from watershed soils or sediment. Various phylotypes associated with the same phylogenetic division, based on tentative identification of T-RFLP fragments, exhibited diverse seasonal patterns, suggesting that ecological roles of Delta bacterioplankton were partitioned at the genus or species level.

Aquatic Microbial Ecology↗

Evapotranspiration Rates of Riparian Forests, Platte River, Nebraska, 2002-06

Evapotranspiration (ET) in riparian areas is a poorly understood component of the regional water balance in the Platte River Basin, where competing demands have resulted in water shortages in the ground-water/surface-water system. From April 2002 through March 2006, the U.S. Geological Survey, Nebraska Platte River Cooperative Hydrology Study Group, and Central Platte Natural Resources District conducted a micrometeorological study of water and energy balances at two sites in central Nebraska near Odessa and Gothenburg to improve understanding of ET rates and factors affecting them in Platte River riparian forests. A secondary objective of the study was to constrain estimates of ground-water use by riparian vegetation to satisfy ET consumptive demands, a useful input to regional ground-water flow models. Both study sites are located on large islands within the Platte River characterized by a cottonwood-dominated forest canopy on primarily sandy alluvium. Although both sites are typical of riparian forests along the Platte River in Nebraska, the Odessa understory is dominated by deciduous shrubs, whereas the Gothenburg understory is dominated by eastern redcedars. Additionally, seasonal ground-water levels fluctuated more at Odessa than at Gothenburg. The study period of April 2002 through March 2006 encompassed precipitation conditions ranging from dry to wet. This study characterized the components of the water balance in the riparian zone of each site. ET was evaluated from eddy-covariance sensors installed on towers above the forest canopy at a height of 26.1 meters. Precipitation was measured both above and below the forest canopy. A series of sensors measured soil-moisture availability within the unsaturated zone in two different vertical profiles at each site. Changes in ground-water altitude were evaluated from piezometers. The areal footprint represented in the water balance extended up to 800 meters from each tower. During the study, ET was less variable than precipitation. Annual ET fluctuated about 7 percent from the 4-year mean, ranging from about 514 to 586 millimeters per year (551 on average) at the Odessa site and 535 to 616 millimeters per year (575 on average) at the Gothenburg site. Conversely, annual precipitation fluctuated by about 35 percent from the 4-year mean, ranging from 429 to 844 millimeters per year at Odessa and 359 to 791 millimeters per year at Gothenburg. Of this precipitation, 14 to 15 percent was intercepted by the forest canopy before it could infiltrate into the soil. For the 4-year period, annual ground-water recharge from the riparian measurement zone averaged 76 and 13 millimeters at Odessa and Gothenburg, respectively, to satisfy the water balance at each site. This indicates that, from an annual perspective, ground-water reductions caused by ET may be minimal. This effect varied somewhat and primarily was affected by fluctuations in precipitation. Ground-water discharge occurred during the driest study year (2002), whereas ground-water recharge occurred from 2003 to 2005. These results do not exclude ground water as an important source of water to riparian vegetation - especially to phreatophytes that have the capability of directly using water from the saturated zone - during periods of high ET in the summer, particularly during periods of lower than normal precipitation. However, the calculations indicate that, on an annual (or longer) net-flux basis, ground-water use by riparian forests is likely to be balanced by periods of recharge from excess precipitation at other times of the year. In contrast to more arid settings, where scientific literature indicates that ground water may supply a large fraction of the water used for ET by riparian vegetation, precipitation along the Platte River of Nebraska was great enough - and generally greater than ET - that most or all of the annual ET demand was satisfied by available precipitation. Crop coefficients developed for 15-

Scientific Investigations Report↗

Wide-area estimates of evapotranspiration by red gum ( Eucalyptus camaldulensis ) and associated vegetation in the Murray-Darling River Basin, Australia

Floodplain red gum forests ( Eucalyptus camaldulensis plus associated grasses, reeds and sedges) are sites of high biodiversity in otherwise arid regions of southeastern Australia. They depend on periodic floods from rivers, but dams and diversions have reduced flood frequencies and volumes, leading to deterioration of trees and associated biota. There is a need to determine their water requirements so environmental flows can be administered to maintain or restore the forests. Their water requirements include the frequency and extent of overbank flooding, which recharges the floodplain soils with water, as well as the actual amount of water consumed in evapotranspiration (ET). We estimated the flooding requirements and ET for a 38&thinsp;134&thinsp;ha area of red gum forest fed by the Murrumbidgee River in Yanga National Park, New South Wales. ET was estimated by three methods: sap flux sensors placed in individual trees; a remote sensing method based on the Enhanced Vegetation Index from MODIS satellite imagery and a water balance method based on differences between river flows into and out of the forest. The methods gave comparable estimates yet covered different spatial and temporal scales. We estimated flood frequency and volume requirements by comparing Normalized Difference Vegetation Index values from Landsat images with flood history from 1995 to 2014, which included both wet periods and dry periods. ET during wet years is about 50% of potential ET but is much less in dry years because of the trees' ability to control stomatal conductance. Based on our analyses plus other studies, red gum trees at this location require environmental flows of 2000&thinsp;GL&thinsp;yr &minus;1 every other year, with peak flows of 20&thinsp;000&thinsp;ML&thinsp;d &minus;1 , to produce flooding sufficient to keep them in good condition. However, only about 120&ndash;200&thinsp;GL&thinsp;yr &minus;1 of river water is consumed in ET, with the remainder flowing out of the forest where it enters the Murray River system.

Murray-Darling River Basin↗

Detailed description of oil shale organic and mineralogical heterogeneity via fourier transform infrared mircoscopy

Mineralogical and geochemical information on reservoir and source rocks is necessary to assess and produce from petroleum systems. The standard methods in the petroleum industry for obtaining these properties are bulk measurements on homogenized, generally crushed, and pulverized rock samples and can take from hours to days to perform. New methods using Fourier transform infrared (FTIR) spectroscopy have been developed to more rapidly obtain information on mineralogy and geochemistry. However, these methods are also typically performed on bulk, homogenized samples. We present a new approach to rock sample characterization incorporating multivariate analysis and FTIR microscopy to provide non-destructive, spatially resolved mineralogy and geochemistry on whole rock samples. We are able to predict bulk mineralogy and organic carbon content within the same margin of error as standard characterization techniques, including X-ray diffraction (XRD) and total organic carbon (TOC) analysis. Validation of the method was performed using two oil shale samples from the Green River Formation in the Piceance Basin with differing sedimentary structures. One sample represents laminated Green River oil shales, and the other is representative of oil shale breccia. The FTIR microscopy results on the oil shales agree with XRD and LECO TOC data from the homogenized samples but also give additional detail regarding sample heterogeneity by providing information on the distribution of mineral phases and organic content. While measurements for this study were performed on oil shales, the method could also be applied to other geological samples, such as other mudrocks, complex carbonates, and soils.

Energy & Fuels↗

Geochemical data for samples collected in 2007 near the concealed pebble porphyry Cu-Au-Mo deposit, southwest Alaska

In the summer of 2007, the U.S. Geological Survey (USGS) began an exploration geochemical research study over the Pebble porphyry copper-gold-molydenum (Cu-Au-Mo) deposit in southwest Alaska. The Pebble deposit is extremely large and is almost entirely concealed by tundra, glacial deposits, and post-Cretaceous volcanic and volcaniclastic rocks. The deposit is presently being explored by Northern Dynasty Minerals, Ltd., and Anglo-American LLC. The USGS undertakes unbiased, broad-scale mineral resource assessments of government lands to provide Congress and citizens with information on national mineral endowment. Research on known deposits is also done to refine and better constrain methods and deposit models for the mineral resource assessments. The Pebble deposit was chosen for this study because it is concealed by surficial cover rocks, it is relatively undisturbed (except for exploration company drill holes), it is a large mineral system, and it is fairly well constrained at depth by the drill hole geology and geochemistry. The goals of the USGS study are (1) to determine whether the concealed deposit can be detected with surface samples, (2) to better understand the processes of metal migration from the deposit to the surface, and (3) to test and develop methods for assessing mineral resources in similar concealed terrains. This report presents analytical results for geochemical samples collected in 2007 from the Pebble deposit and surrounding environs. The analytical data are presented digitally both as an integrated Microsoft 2003 Access? database and as Microsoft 2003 Excel? files. The Pebble deposit is located in southwestern Alaska on state lands about 30 km (18 mi) northwest of the village of Illiamna and 320 km (200 mi) southwest of Anchorage (fig. 1). Elevations in the Pebble area range from 287 m (940 ft) at Frying Pan Lake just south of the deposit to 1146 m (3760 ft) on Kaskanak Mountain about 5 km (5 mi) to the west. The deposit is in an area of relatively subdued topographic relief with an elevation of around 300 m (1000 ft). This portion of Alaska is part of the subarctic regime mountains division, Yukon intermontane plateaus-tayga-meadow province ecoregion, as defined by Bailey (U.S. Forest Service, 2007). Between June 28th and July 12th, 2007, scientists from the USGS collected soil, water, stream sediment, vegetation, heavy-mineral concentrate, till, and rock samples from the deposit area. This report contains analytical results for soil, water, stream sediment, and vegetation samples. Analyses for the heavy-mineral concentrate, till, and rock samples are still in progress. The sampling was undertaken during relatively dry and stable weather conditions. Only minor scattered rain showers occurred during the sampling period, so surface conditions were largely unaffected by weather. The predominant sample media collected were soils and surface waters. Soil and water (mostly from ponds and springs, some from small creeks) samples were collected along a single 7.8 km-long (4.8 mi) east-west traverse across the Pebble East and Pebble West zones and from more distal background areas around Koktuli and Kaskanak Mountains. Sample sites are shown on figure 2 and plate 1, and locality coordinates are provided in the accompanying Access and Excel files named FieldSite. Water samples were analyzed by USGS laboratories with one subset analyzed by Activation Laboratories (Actlabs), as indicated below. Soils and stream sediments were analyzed for their total content by SGS Minerals Services under a contract with the USGS. Soil samples were also leached by selected partial-extraction leaching procedures and then analyzed by several commercial laboratories, as described below. Vegetation samples were analyzed as indicated below.

Alaska↗

Microbiological and chemical quality of ground water used as a source of public supply in southern Missouri — Phase II, April–July, 1998

The protection of public health through quality public ground-water systems is the responsibility of the U. S. Environmental Protection Agency and the State of Missouri, through the Missouri Department of Natural Resources, Public Drinking Water Program. Approximately 95 percent of the public-water supplies in Missouri use ground water as their source of drinking water through more than 3,700 public wells. Karst terrain, intensive agricultural operations, extensive numbers of on-site sewage systems, and poor well construction can lead to chemical and microbiological contamination of the contributing aquifers. Sitespecific studies and routine regulatory monitoring have produced information on the overall quality and potability of the State's public-drinking-water supplies, but little is known about the presence of viruses. The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, sampled 109 public-water supplies to characterize the physical, chemical, bacterial, and viral conditions in southern Missouri. During April to July 1998, these wells were sampled for nutrients, total organic carbon, optical brighteners, indicator bacteria, enteric viruses, and ribonucleic acid and somatic coli phages. These constituents indicate possible surface contamination of the sampled aquifer. Selection of the wells to be sampled depended on the age of the well (pre-1970), land use, geohydrology, and well construction. None of the physical or chemical constituents measured or analyzed exceeded Missouri's Drinking Water Standards set by the Public Drinking Water Program of the Missouri Department of Natural Resources. The majority of ammonia plus organic nitrogen, nitrite, and phosphorus concentrations were below the laboratory's minimum reporting levels. There were a greater number of detects above the minimum reporting level with respect to the nitrite plus nitrate, ammonia, orthophosphate, and total organic carbon concentrations. Analyses included comparing and contrasting the data by grouping according to well age and construction, karst type, geohydrology, soil type, and land use. There was little variation in well construction between selected wells. The results indicated several groupings of similar and dissimilar concentrations, most expected because of hydrological, physical, or land use differences. Dissolved oxygen values indicated distinct variation in the different groupings. There were significant differences in dissolved oxygen values between the secondary and non-karst areas, the Ozark confined and Ozark unconfined geohydrologic groups, and between agricultural and other land uses. In groupings by soil and geohydrology, the Missouri bootheel region differed with respect to ammonia, total organic carbon, and phosphorus when compared with the other groups. Less than 10 percent of the wells sampled tested positive for bacterial contamination. E. coli was the most frequently detected bacterium. The public wells at Monett and West Plains, Missouri, had plates with colonies too numerous to count for all three indicator bacteria. Further analyses by rRNA (ribosomal RiboNucleic Acid) hybridization techniques detennined that much of the bacteria present were from ruminant and human sources. No enteric viruses were detected in the 109 samples. Both ribonucleic acid and somatic coliphage were detected at two wells. One additional well had ribonucleic acid coliphage and another had somatic coliphage for a total of four wells with coliphage selects.

Missouri↗

Prediction, time variance, and classification of hydraulic response to recharge in two karst aquifers

Many karst aquifers are rapidly filled and depleted and therefore are likely to be susceptible to changes in short-term climate variability. Here we explore methods that could be applied to model site-specific hydraulic responses, with the intent of simulating these responses to different climate scenarios from high-resolution climate models. We compare hydraulic responses (spring flow, groundwater level, stream base flow, and cave drip) at several sites in two karst aquifers: the Edwards aquifer (Texas, USA) and the Madison aquifer (South Dakota, USA). A lumped-parameter model simulates nonlinear soil moisture changes for estimation of recharge, and a time-variant convolution model simulates the aquifer response to this recharge. Model fit to data is 2.4% better for calibration periods than for validation periods according to the Nash–Sutcliffe coefficient of efficiency, which ranges from 0.53 to 0.94 for validation periods. We use metrics that describe the shapes of the impulse-response functions (IRFs) obtained from convolution modeling to make comparisons in the distribution of response times among sites and between aquifers. Time-variant IRFs were applied to 62% of the sites. Principal component analysis (PCA) of metrics describing the shapes of the IRFs indicates three principal components that together account for 84% of the variability in IRF shape: the first is related to IRF skewness and temporal spread and accounts for 51% of the variability; the second and third largely are related to time-variant properties and together account for 33% of the variability. Sites with IRFs that dominantly comprise exponential curves are separated geographically from those dominantly comprising lognormal curves in both aquifers as a result of spatial heterogeneity. The use of multiple IRF metrics in PCA is a novel method to characterize, compare, and classify the way in which different sites and aquifers respond to recharge. As convolution models are developed for additional aquifers, they could contribute to an IRF database and a general classification system for karst aquifers.

South Dakota, Texas↗

GPS in dynamic monitoring of long-period structures

Global Positioning System (GPS) technology with high sampling rates (??? 10 samples per second) allows scientifically justified and economically feasible dynamic measurements of relative displacements of long-period structures-otherwise difficult to measure directly by other means, such as the most commonly used accelerometers that require post-processing including double integration. We describe an experiment whereby the displacement responses of a simulated tall building are measured clearly and accurately in real-time. Such measurements can be used to assess average drift ratios and changes in dynamic characteristics, and therefore can be used by engineers and building owners or managers to assess the building performance during extreme motions caused by earthquakes and strong winds. By establishing threshold displacements or drift ratios and identifying changing dynamic characteristics, procedures can be developed to use such information to secure public safety and/or take steps to improve the performance of the building. Published by Elsevier Science Ltd.

Soil Dynamics and Earthquake Engineering↗

Changes in vegetation in northern Alaska under scenarios of climate change, 2003-2100: Implications for climate feedbacks

Assessing potential future changes in arctic and boreal plant species productivity, ecosystem composition, and canopy complexity is essential for understanding environmental responses under expected altered climate forcing. We examined potential changes in the dominant plant functional types (PFTs) of the sedge tundra, shrub tundra, and boreal forest ecosystems in ecotonal northern Alaska, USA, for the years 2003&ndash;2100. We compared energy feedbacks associated with increases in biomass to energy feedbacks associated with changes in the duration of the snow-free season. We based our simulations on nine input climate scenarios from the Intergovernmental Panel on Climate Change (IPCC) and a new version of the Terrestrial Ecosystem Model (TEM) that incorporates biogeochemistry, vegetation dynamics for multiple PFTs (e.g., trees, shrubs, grasses, sedges, mosses), multiple vegetation pools, and soil thermal regimes. We found mean increases in net primary productivity (NPP) in all PFTs. Most notably, birch ( Betula spp.) in the shrub tundra showed increases that were at least three times larger than any other PFT. Increases in NPP were positively related to increases in growing-season length in the sedge tundra, but PFTs in boreal forest and shrub tundra showed a significant response to changes in light availability as well as growing-season length. Significant NPP responses to changes in vegetation uptake of nitrogen by PFT indicated that some PFTs were better competitors for nitrogen than other PFTs. While NPP increased, heterotrophic respiration ( R H ) also increased, resulting in decreases or no change in net ecosystem carbon uptake. Greater aboveground biomass from increased NPP produced a decrease in summer albedo, greater regional heat absorption (0.34 &plusmn; 0.23 W&middot;m &minus;2 &middot;10 yr &minus;1 [mean &plusmn; SD]), and a positive feedback to climate warming. However, the decrease in albedo due to a shorter snow season (&minus;5.1 &plusmn; 1.6 d/10 yr) resulted in much greater regional heat absorption (3.3 &plusmn; 1.24 W&middot;m &minus;2 &middot;10 yr &minus;1 ) than that associated with increases in vegetation. Through quantifying feedbacks associated with changes in vegetation and those associated with changes in the snow season length, we can reach a more integrated understanding of the manner in which climate change may impact interactions between high-latitude ecosystems and the climate system.

Alaska↗