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USGS2010

Methylmercury cycling, bioaccumulation, and export from agricultural and non-agricultural wetlands in the Yolo Bypass

This 18-month field study addresses the seasonal and spatial patterns and processes controlling methylmercury (MeHg) production, bioaccumulation, and export from natural and agricultural wetlands of the Yolo Bypass Wildlife Area (YBWA). The data were collected in conjuntion with a Proposition 40 grant from the State Water Resources Control Board in support of the development of Best Management Practices (BMP's) for reducing MeHg loading from agricultural lands in the wetland-dominated Yolo Bypass to the Sacramento-San Joaquin River Delta. The four managemenr-based questions addressed in this study were: 1. Is there a different among agricultural and managfed wetland types in terms of Me Hg dynamic (production, degradation, bioaccumulation, or export)? 2. Does water residence time influence MeHg dynamics? 3. Does the application of sulfate-based fertilizer impact MeHg production rates? 4. Does the presence (or absence) of vegetation influence MeHg production rates? Measurements of MeHg concentrations in sediment, water, and biota (plants, invertebrates, and fish) were made to assess management-level patterns in five wetland types, which included three type of shallowly-flooded agricultural wetlands (white rice, wild rice, and fallow) and two types of managed wetlands (permanently and seasonally flooded). To strengthen our understanding of the processes underlying the seasonal and spatial patterns of MeHg cycling, additional exploratory factors were measured including ancillary sediment and water quality parameters, stable isotope fractionation (oxygen, sulfur, carbon, and nitrogen), photodemethylation rates, and daily-integrated hydrologic budgets. Samples and field data were collected from May 2007 to July 2008, and nearly all sample analyses were completed by September 2008 as per the Quality Assurance Program Plan (QAPP) requirements. Although wetland type was a major factor that drove the study design, within-field hydrology also proved to be an important factor controlling aqueous MeHg and total mercury (THg) concentrations and export. Overall, agricultural wetlands exhibited higher MeHg concentrations in overlying water, sediment, and biota than did managed seasonal and permanent wetlands. This appears to be partly due to higher rates of sediment in microbial production of MeHg on agricultural wetlands during the fall through spring period. Both sulfate- and iron-reducing bacteria have been implicated in the MeHg production process, and both were demonstrably active in all wetlands studied; however, sulfate-reducing bacteria were not stimulated by the addition of sulfate-based fertilizer to agricultural wetlands, suggesting that easily-degraded (labile) organic matter, rather than sulfate, was limiting their activity in these field types. The data suggest that agriculturally-managed soils promoted MeHg production through 1) enhanced microbial activity via higher temperatures and larger pools of labile carbon, and 2) enhanced pools of microbially available inorganic divalent mercury (Hg(II)) resulting from a decrease in reduced-sulfur, solid-phase minerals under oxic or only mildly reducing conditions. MeHg mass balances were assessed by comparing filed-specific MeHg loads for inlets vs. outlet flows. The overall mass balance for MeHg in surface water during the summer irrigation period (June - September 2007) indicated little to no net MeHg export from the six agricultural wetlands taken as a whole. Of the six agricultural wetlands, there was net overall MeHg export from two fields (one fallow and one white rice) during August, and from four of the six fields (one fallow, one white rice, and two wild rice) during September) Over the entire summer irrigation period, two of the fields (one fallow and one wild rive) showed net MeHg export, and the other four fields showed wither net import or no significant change. Rates of measured photomethylation and exchange between sediment and water pools suggest that both processes may be responsible for the lack of MeHg export. Despite significant differences during winter months between fields in surface water concentrations of MeHg, MeHg loads were not calculated in mid-winter because flood waters had overtopped field boundaries and field fidelity could not be established. During the summer 2007 irrigation season, surface water out-flows from agricultural wetlands were 9%-36% of inlet flows, and evaporation rates explained most of this water loss, with infiltration likely accounting for the remainder. Unfiltered aqueous MeHg concentrations increased from <1 ng L -1 in source waters to up to 10 ng L -1 in agricultural wetland drains during the summer irrigation period. Increases in solute concentration caused by evapoconcentration were estimated by determining concentration factors (outflow/inflow) for chloride (a conservative dissolved constituent) and by measuring oxygen isotope ratios ( 18 O/ 16 O, expressed as δ 18 O) in water. Increases in MeHg concentration from inflows-to-outflows exceeded those caused by evapoconcentration on several fields during the summer irrigation season. This was especially true when initial surface water MeHg concentrations were low, as seen in the southern block of fields receiving irrigation water directly from the Toe Drain. The northern block of fields received irrigation water from Greens Lake, which included Toe Drain water plus recirculated drain water from other agricultural fields within the Yolo Bypass and west of the Yolo Bypass; as such, the northern fields showed a smaller percentage increase in MeHg concentration because initial MeHg concentrations in surface water inflows were greater than in inputs to the southern fields. Mercury concentrations in fish were greater in agricultural wetlands white rice and wild rice) than in the two permanently flooded wetlands. Additionally, Hg concentrations in biota showed a general increase from inlets to outlets withing agricultural wetlands, but not within permanent wetlands. This was particular evident in white rice fields where caged western mosquitofish at the outlets had Hg concentrations that were more than 4 times higher than in caged fish held at the inlets. Similar spatial patterns in Hg bioaccumulation in agricultural and permanent wetlands were seen for wild populations of western mosquitofish and Mississippi silversides. In contrast to fish, invertebrates, such as water-boatman (Corixidae) and back swimmers (Notonectidae), had greater Hg concentrations in permanent wetlands than in tempoarirly flooded agricultural wetlands, Fish THg concentrations were weakly correlated with water MeHg,a and not correlated with sediment MeHg. In contrast, invertebrate MeHg concentrations were more strongly correlated with sediment MeHg than with water MeHg concentrations. These results illustrate the complexity of MeHg bioaccumulation through food webs and indicate the importance of simultaneously using multiple biosentinels when monitoring MeHg production and bioaccumulation. Despite high sediment production rates and water concentrations in agricultural wetlands, MeHg export was physically limited by hydrologic export for all wetlands studied. We suggest that load reduction is maximized by limiting water throughout, but that on-site biota exposure is maximized by this loner water residence time. While field-specific hydrologic loads could not be fully quantified during flood conditions in February 2008, we suggest that the primary period of MeHg export from Yolo Bypass Wildlife Area is during those winter flooding periods when overall microbial activity and MeHg production in agricultural soils is fueled by the decomposition of rice straw, and when hydrologic flowthrough is maximal. Local stakeholders participated in two workshops related to this study, demonstrating an interest in understanding factors controlling MeHg production, export, and bioaccumulation. The results of this field study show that permanently flooded, naturally vegetated wetlands are unlikely to a large source of MeHg production within the YBWA, in contrast with agriculturally-managed wetlands. MeHg loading to Toe Drain waters of the Yolo Bypass may be reduced by lowering rated of hydrologic export from agricultural wetlands during the growing season and especially during rice harvest, However, under these water-holding conditions, biota living within agricultural wetlands may thus be exposed to higher MeHg concentrations in surface water, As observed in this study, rapid bioacculumaltion over a 2-month period led to MeHg concentrations in invertebrates and fish more than 6 and 11 times higher, respectively, than proposed TMDL target values to protect wildlife (0.03 ppm ww). The results of this field study, together with the information from YBWA stakeholders, provide a more definitive understanding of how MeHg cycling and bioaccumulation respond to habitat differences and specific management practices. These results directly address 4 core components of CBDA's Mercury Strategy for the Bay-Delta Ecosystem (Wiener et al., 2003a): a) Quantification and evaluation of THg and MeHg sources, b) Quantification of effects of ecosystem restoration on MeHg exposure, c) Assessment of ecological risk, and d) Identification and testing of potential management approaches for reducing MeHg contamination. In addition, the quantitative results reported here assess the effect of current land use practices in the Yolo Bypass MeHg production, bioaccumulation and export, and provide process-based advice towards achieving current goals of the RWQCB-CVR's Sacramento -- San Joaquin Delta Estuary TMDL for Methyl & Total Mercury (Wood et al., 2010b). Further work is necessary to evaluate biotic exposure in the Yolo Bypass Wildlife Area at higher trophic levels (e.g. birds), to quantify winter hydrologic flux of MeHg to the larger Delta ecosystem, and to evaluate rice straw management options to limit labile carbon supplies to surface sediment during winter months. In summary, agricultural management of rice fields -- specifically the periodic flooding and production of easily degraded organic matter -- promotes the production of MeHg beyond rates seen in naturally vegetated wetlands, whether seasonally or permanently flooded., The exported load from MeHg from these agricultural wetlands may be controlled by limiting hydrologic export from fields to enhance on-site MeHg removal processes, but the tradeoff is that this impoundement increases Me Hg exposure to resident organisms.

California↗

USGS2013

Potential Environmental and Environmental-Health Implications of the SAFRR Tsunami Scenario in California: Chapter F in The SAFRR (Science Application for Risk Reduction) Tsunami Scenario

The California Tsunami Scenario models the impacts of a hypothetical, yet plausible, tsunami caused by an earthquake offshore from the Alaska Peninsula. In this chapter, we interpret plausible tsunami-related contamination, environmental impacts, potential for human exposures to contaminants and hazardous materials, and implications for remediation and recovery. Inundation-related damages to major ports, boat yards, and many marinas could release complex debris, crude oil, various fuel types and other petroleum products, some liquid bulk cargo and dry bulk cargo, and diverse other pollutants into nearby coastal marine environments and onshore in the inundation zone. Tsunami-induced erosion of contaminated harbor bottom sediments could re-expose previously sequestered metal and organic pollutants (for example, organotin or DDT). Inundation-related damage to many older buildings could produce debris containing lead paint, asbestos, pesticides, and other legacy contaminants. Intermingled household debris and externally derived debris and sediments would be left in flooded buildings. Post tsunami, mold would likely develop in inundated houses, buildings, and debris piles. Tsunamigenic fires in spilled oil, debris, cargo, vehicles, vegetation, and residential, commercial, or industrial buildings and their contents would produce potentially toxic gases and smoke, airborne ash, and residual ash/debris containing caustic alkali solids, metal toxicants, asbestos, and various organic toxicants. Inundation of and damage to wastewater treatment plants in many coastal cities could release raw sewage containing fecal solids, pathogens, and waste chemicals, as well as chemicals used to treat wastewaters. Tsunami-related physical damages, debris, and contamination could have short- and longer-term impacts on the environment and the health of coastal marine and terrestrial ecosystems. Marine habitats in intertidal zones, marshes, sloughs, and lagoons could be damaged by erosion or sedimentation, and could receive an influx of debris, metal and organic contaminants, and sewage-related pathogens. Debris and re-exposed contaminated sediments would be a source of sea- or rain-water-leachable metal and organic contaminants that could pose chronic toxicity threats to ecosystems. If human populations are successfully evacuated prior to the tsunami arrival, there would be no or limited numbers of drownings, other casualties, or related injuries, wounds, and infections. Immediately after the tsunami, human populations away from the inundation zone could be transiently exposed to airborne gases, smoke, and ash from tsunamigenic fires. Cleanup and disposal, particularly of hazardous materials, would pose substantial logistical challenges and economic costs. Given the high value of the coastal residential and commercial properties in the inundation zone, it can be postulated that there would be substantial insurance claims for environmental restoration, mold mitigation, disposal of debris that contains hazardous materials, and costs of litigation related to environmental liability. Post-tsunami cleanup, if done with appropriate mitigation (for example, dust control), personal protection, and disposal measures, would help reduce the potential for cleanup-worker and resident exposures to toxicants and pathogens in harbor waters, debris, soils, ponded waters, and buildings. A number of other steps can be taken by governments, businesses, and residents to help reduce the environmental impacts of tsunamis and to recover more quickly from these environmental impacts. For example, development of State and local policies that foster rapid assessment of potential contamination, as well as rapid decision making for disposal options should hazardous debris or sediment be identified, would help enhance recovery by speeding cleanup.

California↗

USGS2016

Effects of climate and water balance across grasslands of varying C 3 and C 4 grass cover

Climate change in grassland ecosystems may lead to divergent shifts in the abundance and distribution of C 3 and C 4 grasses. Many studies relate mean climate conditions over relatively long time periods to plant cover, but there is still much uncertainty about how the balance of C 3 and C 4 species will be affected by climate at a finer temporal scale than season (individual events to months). We monitored cover at five grassland sites with co-dominant C 3 and C 4 grass species or only dominant C 3 grass species for 6 yr in national parks across the Colorado Plateau region to assess the influence of specific months of climate and water balance on changes in grass cover. C 4 grass cover increased and decreased to a larger degree than C 3 grass cover with extremely dry and wet consecutive years, but this response varied by ecological site. Climate and water balance explained 10–49% of the inter-annual variability of cover of C 3 and C 4 grasses at all sites. High precipitation in the spring and in previous year monsoon storms influenced changes in cover of C 4 grasses, with measures of water balance in the same months explaining additional variability. C 3 grasses in grasslands where they were dominant were influenced primarily by longer periods of climate, while C 3 grasses in grasslands where they were co-dominant with C 4 grasses were influenced little by climate anomalies at either short or long periods of time. Our results suggest that future changes in spring and summer climate and water balance are likely to affect cover of both C 3 and C 4 grasses, but cover of C 4 grasses may be affected more strongly, and the degree of change will depend on soils and topography where they are growing and the timing of the growing season.

Ecosphere↗

USGS2014

Assessment of ethylene dibromide, dibromochloropropane, other volatile organic compounds, radium isotopes, radon, and inorganic compounds in groundwater and spring water from the Crouch Branch and McQueen Branch aquifers near McBee, South Carolina, 2010-2012

Public-supply wells near the rural town of McBee, in southwestern Chesterfield County, South Carolina, have provided potable water to more than 35,000 residents throughout Chesterfield County since the early 1990s. Groundwater samples collected between 2002 and 2008 in the McBee area by South Carolina Department of Health and Environmental Control (DHEC) officials indicated that groundwater from two public-supply wells was characterized by the anthropogenic compounds ethylene dibromide (EDB) and dibromochloropropane (DBCP) at concentrations that exceeded their respective maximum contaminant levels (MCLs) established by the U.S. Environmental Protection Agency’s (EPA) National Primary Drinking Water Regulations (NPDWR). Groundwater samples from all public-supply wells in the McBee area were characterized by the naturally occurring isotopes of radium-226 and radium-228 at concentrations that approached, and in one well exceeded, the MCL for the combined isotopes. The local water utility installed granulated activated carbon filtration units at the two EDB- and DBCP-contaminated wells and has, since 2011, shut down these two wells. Groundwater pumped by the remaining public-supply wells is currently (2014) centrally treated at a water-filtration plant. To assess the occurrence, distribution, and potential sources of the anthropogenic and naturally occurring compounds detected in groundwater in the McBee area, samples of groundwater and spring water were collected from public-supply, domestic-supply, agricultural-supply, and monitoring wells and springs, respectively, between 2010 and 2012 by the U.S. Geological Survey. The water samples were analyzed for concentrations of EDB, DBCP, other volatile organic compounds (VOCs), radium-226 and radium-228, radon, and inorganic compounds. All wells sampled were screened in the shallow Crouch Branch aquifer, the deeper McQueen Branch aquifer, or, for most public-supply wells, both aquifers. In areas where no wells existed or wells could not be installed, passive samplers that adsorb EDB, DBCP, and various VOCs, were installed in the shallow subsurface. A representative groundwater flow pathway to each public supply well and selected other wells was determined by using a calibrated three-dimensional groundwater-flow model of the Atlantic Coastal Plain in Chesterfield County and particle-tracking analysis. The aerial extent of the groundwater flow pathway to public-supply wells was mapped by using chlorofluorocarbon-concentration based, apparent-age dates of the groundwater. The water-quality data collected between 2010 and 2012, in conjunction with groundwater flow pathways and historical aerial photographs of land uses near McBee, indicate an area where EDB-, DBCP-, 1,2-dichloropropane-, 1,3-dichloropropane-, and carbon disulfide-contaminated groundwater exists in the Crouch Branch aquifer in the Cedar Creek Basin and north of McBee and is most likely related to the past use of these compounds between the early 1900s and the 1980s as soil fumigants in predominately agricultural areas north of McBee. The highest EDB concentration detected (18.6 micrograms per liter) during the 3-year study was in a groundwater sample from an agricultural-supply well located north of McBee. Other VOCs, such as dichloromethane and 1,1,2-trichloroethane, also were detected in groundwater samples from this EDB-contaminated agricultural-supply well but are from unknown source(s). The fact that the agricultural area north of McBee is located in a recharge area for the Crouch Branch aquifer most likely facilitated the groundwater contamination in this area. DBCP-contaminated groundwater detected in three public-supply wells south of McBee in the deeper McQueen Branch aquifer appears to be related to past soil fumigation practices that used DBCP in agricultural areas located south of McBee. One of the three DBCP-contaminated public-supply wells also contained EDB, most likely present in groundwater due to the release of leaded gasolines that contained EDB as a fuel additive between the 1940s and 1970s. A gasoline-source of EDB, rather than a soil-fumigation source, is supported by the co-detection in groundwater from the well of 1,2-dichloroethane, a lead scavenger compound also added to leaded gasoline. Groundwater pumped from two public-supply wells located within and to the east of the McBee town limits and one domestic-supply well east of McBee was characterized by the detection of 1,1-dichloroethane, trichloroethylene, 1,1-dichloroethylene, and perchloroethylene. Groundwater flow pathways determined for these wells indicate that the potential source(s) of these compounds detected in one public-supply well and the domestic-supply well may be located within the McBee town limits, and that the potential source(s) of these compounds detected in the public-supply well to the east of McBee may be located in an area north of McBee formerly used for agriculture, but used for industry since at least the 1970s. Radium isotopes (defined in this study as the sum of radium-226 and radium-228 concentrations) and radon were detected in all wells sampled in the McBee area between 2010 and 2012. Wells characterized by radium isotope concentrations in groundwater that exceeded the MCL of 5.0 picocuries per liter were also characterized by specific conductance values greater than 30 microsiemens per centimeter and clustered north of McBee in a predominately agricultural area, and in agricultural and urban areas located within and east of McBee. The elevated specific conductance values measured in groundwater from these wells most likely are due to recharge by water mineralized by fertilizer application in agricultural areas, or due to the recharge by water mineralized by septic-tank drain-field effluent near urban areas. Radon was detected in groundwater from all wells sampled, and radon concentrations in groundwater from three monitoring wells exceeded the proposed MCL of 300 picocuries per liter. Concentrations of uranium in groundwater in the McBee area increased with increased groundwater-sample depth, most likely due to the proximity of the sample-collection location to basement rock that contains uranium-bearing minerals.

South Carolina↗

USGS2006

Effects of elevated CO2 on fine root dynamics in a Mojave Desert community: A FACE study

Fine roots (??? 1mm diameter) are critical in plant water and nutrient absorption, and it is important to understand how rising atmospheric CO2 will affect them as part of terrestrial ecosystem responses to global change. This study's objective was to determine effects of elevated CO2 on production, mortality, and standing crops of fine root length over 2 years in a free-air CO2 enrichment (FACE) facility in the Mojave Desert of southern Nevada, USA. Three replicate 25m diameter FACE rings were maintained at ambient (??? 370 ??mol mol-1) and elevated CO2 (??? 550 ??mol mol-1) atmospheric concentrations. Twenty-eight minirhizotron tubes were placed in each ring to sample three microsite locations: evergreen Larrea shrubs, drought-deciduous Ambrosia shrubs, and along systematic community transects (primarily in shrub interspaces which account for ??? 85% of the area). Seasonal dynamics were similar for ambient and elevated CO2: fine root production peaked in April-June, with peak standing crop occurring about 1 month later, and peak mortality occurring during the hot summer months, with higher values for all three measures in a wet year compared with a dry year. Fine root standing crop, production, and mortality were not significantly different between treatments except standing crop along community transects, where fine root length was significantly lower in elevated CO2. Fine root turnover (annual cumulative mortality/mean standing crop) ranged from 2.33 to 3.17 year-1, and was not significantly different among CO2 treatments, except for community transect tubes where it was significantly lower for elevated CO2. There were no differences in fine root responses to CO2 between evergreen (Larrea) and drought-deciduous (Ambrosia) shrubs. Combined with observations of increased leaf-level water-use efficiency and lack of soil moisture differences, these results suggest that under elevated CO2 conditions, reduced root systems (compared with ambient CO2) appear sufficient to provide resources for modest aboveground production increases across the community, but in more fertile shrub microsites, fine root systems of comparable size with those in ambient CO2 were required to support the greater aboveground production increases. For community transects, development of the difference in fine root standing crops occurred primarily through lower stimulation of fine root production in the elevated CO2 treatment during periods of high water availability. ?? 2005 Blackwell Publishing Ltd.

Global Change Biology↗

USGS1977

Distribution of injected wastewater in the saline-lava aquifer, Wailuku-Kahului wastewater treatment facility, Kahului, Maui, Hawaii

Field studies and digital modeling of a lava rock aquifer system near Kahului, Maui, Hawaii, were employed to define and describe the distribution of planned injected wastewater from a secondary treatment facility. The lava rock aquifer contains water that is almost as saline as seawater. The saline water is below a seaward-discharging freshwater lens, and separated from it by a transition zone of varying salinity. Injection of wastewater at an average rate of 6.2 cubic feet per second is planned through wells open only to the aquifer deep within the saline water zone. The lava rock aquifer is overlain by a sequence of residual soil, clay, coral reef deposits, and marine sand that form a low-permeability caprock which semiconfines the lava rock aquifer. A two-dimensional finite-difference model was used to describe initial conditions within the freshwater part of the aquifer, and to indicate response of the freshwater part of the system to injection of wastewater. Steady-state distribution of the wastewater within the saline and the freshwater parts of the lava rock aquifer was simulated by use of a three-dimensional finite-difference model. This model, using vertical-to-horizontal ratios of hydraulic conductivity of 1:10 and 1:100, shows that wastewater with a lesser density than that of either the saline or freshwater aquifer, will form a roughly cylindrical column around the injection well base and rise through the transition zones into the freshwater lens flow system. The column diameter varies with the ratio, and the column, or plume, widens progressively through the transition zone, then maintains virtually constant size through the freshwater part of the lava rock aquifer. Seaward flow within the freshwater lens tends to distort the plume seaward. Under conditions measured and assumed for the study, it is evident that wastewater injected at the planned rate will move upward, then seaward without significant change. After reaching a new steady state, the wastewater will discharge into and through the caprock sequence within an area measuring approximately 1,000 feet inland, 1,000 feet laterally on either side of the injection site, and about 2,000 feet seaward. Little, if any, of the injected wastewater may be expected to reach the upper part of the caprock flow system landward of the treatment plant facility.

Hawaii↗

USGS2004

Twentieth century demographic changes in cirio and cardón in Baja California, Mexico

Aim&ensp; Our purpose was to discern long-term large-scale patterns of survivorship and recruitment of two dominant, charismatic and useful desert plants, cirio [Fouquieriaceae; Fouquieria columnaris (Kell.) Kell. ex Curran] and cardón [Cactaceae; Pachycereus pringlei (S.Watson) Britton & Rose], and to evaluate the effects of physical and human factors. Location&ensp; The study included 77 sites distributed over c. 13,200 km 2 in the northern Vizcaíno Region of the Sonoran Desert, state of Baja California, México. Method&ensp; Censuses used identified individuals ( n = 3780 cirio and 2246 cardón) and were based on repeat photography. Time intervals between censuses ranged from 29 to 96 years, ending in 1996–2002. Earlier repetition (1963) of old photographs at 14 sites allowed analysis of temporal variation. The effect of elapsed time was modelled with Weibull functions for survivorship and linear functions for recruitment. To explain the residual variations, we tested categorical and continuous variables related to substrate, geomorphology, climate and geography. Human impacts were weighed with historical and quantitative analysis. Results&ensp; Elapsed time accounted for 45% of the variation of survivorship in cirio but only 35% in cardón. The fitted Weibull curves were used to estimate longevity: all-size cohorts of 1000 individuals would die out in 388 (cirio) and 723 years (cardón). Recruitment in cirio was linearly related to time ( r 2 = 0.71) and averaged < 0.003 year −1 but was less than mortality at 90% of the sites. For cardón, recruitment averaged > 0.005 year −1 , was linearly related to time ( r 2 = 0.66) and was less than mortality at only 33% of the sites. Vital rates were not strongly correlated between mid- and late-century but were mostly similar to the long-term regional rates. Removing the factor of elapsed time, the residual variations showed that survivorship was greater on sites protected from winds for cirio and was less on very coarse soils for cardón. Recruitment increased with latitude in cirio and was greater on southern exposures for both species. The residual variations were not clearly affected, at a regional scale, by other factors thought to be important, including elevation, distance to the Pacific Ocean, geology, slope gradient, soil stability, older vs. young alluvial soils, and soil Ca : Mg and Na : K ratios. Human impacts have been sporadic and heterogeneous but locally strong; our quantitative indices of accessibility did not show regionally significant effects. Blowdown by hurricanes is a sporadic cause of major mortality for cirio but not necessarily for cardón. Main conclusions&ensp; At our scales, effects of time outweigh those of substrate, and human impact was scant. Large patterns were pronounced: cirio experienced a prolonged, widespread decline in the 1900s, while cardón fluctuated in different directions and degree among local populations. Cirio was found to be inherently much shorter-lived than cardón. We also suggest that recruitment in cirio was low due to long periods with relatively dry winters that affected the entire region, while spatial heterogeneity of cardón recruitment seemed more related to the variation in summer rains.

Journal of Biogeography↗

USGS1975

Geochemical Exploration Techniques Applicable in the Search for Copper Deposits

Geochemical exploration is an important part of copper-resource evaluation. A large number of geochemical exploration techniques, both proved and untried, are available to the geochemist to use in the search for new copper deposits. Analyses of whole-rock samples have been used in both regional and local geochemical exploration surveys in the search for copper. Analyses of mineral separates, such as biotite, magnetite, and sulfides, have also been used. Analyses of soil samples are widely used in geochemical exploration, especially for localized surveys. It is important to distinguish between residual and transported soil types. Orientation studies should always be conducted prior to a geochemical investigation in a given area in order to determine the best soil horizon and the best size of soil material for sampling in that area. Silty frost boils, caliche, and desert varnish are specialized types of soil samples that might be useful sampling media. Soil gas is a new and potentially valuable geochemical sampling medium, especially in exploring for buried mineral deposits in arid regions. Gaseous products in samples of soil may be related to base-metal deposits and include mercury vapor, sulfur dioxide, hydrogen sulfide, carbon oxysulfide, carbon dioxide, hydrogen, oxygen, nitrogen, the noble gases, the halogens, and many hydrocarbon compounds. Transported materials that have been used in geochemical sampling programs include glacial float boulders, glacial till, esker gravels, stream sediments, stream-sediment concentrates, and lake sediments. Stream-sediment sampling is probably the most widely used and most successful geochemical exploration technique. Hydrogeochemical exploration programs have utilized hot- and cold-spring waters and their precipitates as well as waters from lakes, streams, and wells. Organic gel found in lakes and at stream mouths is an unproved sampling medium. Suspended material and dissolved gases in any type of water may also be useful media. Samples of ice and snow have been used for limited geochemical surveys. Both geobotanical and biogeochemical surveys have been successful in locating copper deposits in many parts of the world. Micro-organisms, including bacteria and algae, are other unproved media that should be studied. Animals can be used in geochemical-prospecting programs. Dogs have been used quite successfully to sniff out hidden and exposed sulfide minerals. Tennite mounds are commonly composed of subsurface material, but have not as yet proved to be useful in locating buried mineral deposits. Animal tissue and waste products are essentially unproved but potentially valuable sampling media. Knowledge of the location of areas where trace-element-associated diseases in animals and man are endemic as well as a better understanding of these diseases, may aid in identifying regions that are enriched in or depleted of various elements, including copper. Results of analyses of gases in the atmosphere are proving valuable in mineral-exploration surveys. Studies involving metallic compounds exhaled by plants into the atmosphere, and of particulate matter suspended in the atmosphere are reviewed these methods may become important in the future. Remote-sensing techniques are useful for making indirect measurements of geochemical responses. Two techniques applicable to geochemical exploration are neutron-activation analysis and gamma-ray spectrometry. Aerial photography is especially useful in vegetation surveys. Radar imagery is an unproved but potentially valuable method for use in studies of vegetation in perpetually clouded regions. With the advent of modern computers, many new techniques, such as correlation analysis, regression analysis, discriminant analysis, factor analysis, cluster analysis, trend-surface analysis, and moving-average analysis can be applied to geochemical data sets. Selective use of these techniques can provide new insights into the interpretatio

Professional Paper↗

USGS2013

Effect of long-term understory prescribed burning on standing and down dead woody material in dry upland oak forests

Dead woody material, long ignored or viewed as a nuisance for forest management, has gained appreciation for its many roles in the forest including wildlife habitat, nutrient storage and cycling, energy for trophic webs, protection of soil, fuel for fire and carbon storage. The growing interest in managing dead woody material has created strong demand for greater understanding of factors controlling amounts and turnover. Prescribed burning, an important management tool, may have strong effects of dead woody material given fire’s capacity to create and consume dead woody material. We determined effects of long-term understory prescribed burning on standing and down woody material in upland oak forests in south-central North America. We hypothesized that as frequency of fire increased in these stands the amount of deadwood would decrease and the fine woody material would decrease more rapidly than coarse woody material. The study was conducted in forests dominated by post oak ( Quercus stellata ) and blackjack oak ( Quercus marilandica ) in wildlife management areas where understory prescribed burning had been practiced for over 20 years and the range of burn frequencies was 0 (unburned) fires per decade (FPD) to 4.6 FPD. The amount of deadwood was low compared with more productive forests in southeastern North America. The biomass (24.7 Mg ha -1 ) and carbon stocks (11.7 Mg ha -1 ) were distributed among standing dead (22%), coarse woody debris (CWD, dia. > 7.5 cm., 12%), fine woody debris (FWD, dia. < 7.5 cm., 23%), and forest floor (43%). There was no evidence that understory prescribed burning influenced the amount and size distribution of standing and down dead woody material. There were two explanations for the lack of a detectable effect. First, a high incidence of severe weather including ice storms and strong winds that produce large amounts of deadwood intermittently in an irregular pattern across the landscape may preclude detecting a strong effect of understory prescribed burning. Second, fire suppression during the first one-half of the 20th Century may have led to encroachment of woody plants into forest gaps and savannas creating a patchwork of young and old stands that produced deadwood of different sizes and at different rates.

Forest Ecology and Management↗

USGS2004

Development of a geodatabase and conceptual model of the hydrogeologic units beneath air force plant 4 and Naval Air Station-Joint Reserve Base Carswell Field, Fort Worth, Texas

Air Force Plant 4 and adjacent Naval Air Station-Joint Reserve Base Carswell Field at Fort Worth, Texas, constitute a government-owned, contractor-operated facility that has been in operation since 1942. Contaminants from AFP4, primarily volatile organic compounds and metals, have entered the ground-water-flow system through leakage from waste-disposal sites and from manufacturing processes. The U.S. Geological Survey developed a comprehensive geodatabase of temporal and spatial environmental information associated with the hydrogeologic units (alluvial aquifer, Goodland-Walnut confining unit, and Paluxy aquifer) beneath the facility and a three-dimensional conceptual model of the hydrogeologic units integrally linked to the geodatabase. The geodatabase design uses a thematic layer approach to create layers of feature data using a geographic information system. The various features are separated into relational tables in the geodatabase on the basis of how they interact and correspond to one another. Using the geodatabase, geographic data at the site are manipulated to produce maps, allow interactive queries, and perform spatial analyses. The conceptual model for the study area comprises computer-generated, three-dimensional block diagrams of the hydrogeologic units. The conceptual model provides a platform for visualization of hydrogeologic-unit sections and surfaces and for subsurface environmental analyses. The conceptual model is based on three structural surfaces and two thickness configurations of the study area. The three structural surfaces depict the altitudes of the tops of the three hydrogeologic units. The two thickness configurations are those of the alluvial aquifer and the Goodland-Walnut confining unit. The surface of the alluvial aquifer was created using a U.S. Geological Survey 10-meter digital elevation model. The 2,130 point altitudes of the top of the Goodland-Walnut unit were compiled from lithologic logs from existing wells, available soil-boring logs, and previous studies. Data from 120 wells, primarily from existing reports, were used to create a map of the approximate altitude of the Paluxy aquifer.

Texas↗

USGS2020

Vegetation vs. anoxic controls on degradation of plant litter in a restored wetland

The ability of wetlands to accrete organic matter in response to rising sea level is a key to landscape resilience, especially in light of reduced sediment availability consequent to dam construction and channelization. This study examined the degradation of cattail ( Typha spp.) and tule ( Schoenoplectus acutus ) litters in restored wetlands through the lens of lignin, a major structural biopolymer in vascular plants with degradation characteristics very sensitive to oxic versus anoxic conditions. A series of litterbags were deployed during the first 10 years after flooding of Deep (55 cm) and Shallow (25 cm) restored wetlands. As emergent marsh vegetation spread through the maturing wetlands, anoxic conditions were more prevalent and overall degradation rates of litter in litterbags were lower. In later experiments in the maturing wetlands, lignin was progressively enriched in litter as evidenced by carbon-normalized yields (Λ 8 ) that increased in tule starting materials from 6.3 to 7.1 mg 100 mgOC –1 to as high as 9.9 mg 100 mgOC –1 , and in cattail starting materials from 5.9 to 7.0 mg 100 mgOC –1 to as high as 10.9 mg 100 mgOC –1 . However, in an experiment initiated soon after the restored wetlands were constructed, Λ 8 in tule litter decreased from 6.8 to 3.6 mg 100 mgOC –1 , highlighting the prevalence of initial oxic conditions. With the exception of the early oxic conditions for tule, there was an overall trend of decreasing lignin acid-to-aldehyde ratios with litter degradation, which runs counter to most studies in the literature. We hypothesize that this reflects the utilization of more oxygen-rich lignin components as electron acceptors in redox reactions. No consistent differences were observed in degradation patterns between the Shallow and Deep wetlands. There were distinct differences in lignin degradation in cattail (more resistant) versus tule (less resistant), which indicates that although anoxia may be the dominant control on organic matter accretion in wetlands, specific types of vegetation in restored or constructed wetlands affects organic matter preservation, and hence accretion. Thus, selective management of predominant species in wetlands may prove important for the ability of wetlands to maintain emergent vegetation during sea level rise and to preserve the overall stability of wetland soils.

California↗

USGS2006

Increases in desert shrub productivity under elevated carbon dioxide vary with water availability

Productivity of aridland plants is predicted to increase substantially with rising atmospheric carbon dioxide (CO2) concentrations due to enhancement in plant water-use efficiency (WUE). However, to date, there are few detailed analyses of how intact desert vegetation responds to elevated CO2. From 1998 to 2001, we examined aboveground production, photosynthesis, and water relations within three species exposed to ambient (around 38 Pa) or elevated (55 Pa) CO2 concentrations at the Nevada Desert Free-Air CO2 Enrichment (FACE) Facility in southern Nevada, USA. The functional types sampled - evergreen (Larrea tridentata), drought-deciduous (Ambrosia dumosa), and winter-deciduous shrubs (Krameria erecta) - represent potentially different responses to elevated CO2 in this ecosystem. We found elevated CO2 significantly increased aboveground production in all three species during an anomalously wet year (1998), with relative production ratios (elevated:ambient CO2) ranging from 1.59 (Krameria) to 2.31 (Larrea). In three below-average rainfall years (1999-2001), growth was much reduced in all species, with only Ambrosia in 2001 having significantly higher production under elevated CO2. Integrated photosynthesis (mol CO2 m-2 y-1) in the three species was 1.26-2.03-fold higher under elevated CO2 in the wet year (1998) and 1.32-1.43-fold higher after the third year of reduced rainfall (2001). Instantaneous WUE was also higher in shrubs grown under elevated CO2. The timing of peak canopy development did not change under elevated CO2; for example, there was no observed extension of leaf longevity into the dry season in the deciduous species. Similarly, seasonal patterns in CO2 assimilation did not change, except for Larrea. Therefore, phenological and physiological patterns that characterize Mojave Desert perennials - early-season lags in canopy development behind peak photosynthetic capacity, coupled with reductions in late-season photosynthetic capacity prior to reductions in leaf area - were not significantly affected by elevated CO2. Together, these findings suggest that elevated CO2 can enhance the productivity of Mojave Desert shrubs, but this effect is most pronounced during years with abundant rainfall when soil resources are most available. ?? 2006 Springer Science+Business Media, Inc.

Ecosystems↗

USGS2023

Selenium hazards in the Salton Sea environment—Summary of current knowledge to inform future wetland management

Quaternary marine and continental shales in the western United States are sources of selenium that can be loaded into the aquatic environment through mining, agricultural, and energy production processes. The mobilization of selenium from shales through agricultural irrigation has been recognized since the 1930s; however, discovery of deformities in birds and other wildlife using agricultural habitats during the 1980s spurred studies to determine the extent and effects of the contamination. Through these early studies, researchers determined that biota in the Salton Sea drainage basin was at risk from legacy selenium contamination in the Colorado River watershed. The Salton Sea and its surrounding managed and unmanaged wetlands provide vital inland habitat and trophic support for diverse assemblages of resident and migratory wildlife, and understanding regional selenium hazards for these trust species is a priority for many Federal and State agencies. The modern Salton Sea is a shallow, landlocked saline lake in Riverside and Imperial Counties (not shown) of California that is sustained by irrigation return and perennial river inflow. Changes in water transfer agreements under the 2003 Quantification Settlement Agreement (QSA) have resulted in reduced irrigation flow, declining lake levels, and the evolution of unmanaged wetlands in areas where drains and rivers no longer reach the Salton Sea. These wetlands provide additional habitat for some species of concern, but their potential to increase selenium hazards for trust species is largely unknown. From the 1980s to 2020, efforts to document selenium contamination and effects throughout the region have resulted in a considerable amount of selenium data from the Salton Sea and its surrounding drainage basin; however, no long-term (greater than 20 years), consistent sampling program has been established, and all data have been collected by different entities using a variety of protocols and analytical techniques. This lack of coordination has been previously documented in regional management plans and has led to difficulty in reliably assessing selenium hazards in the Salton Sea environment. This report provides a summary of the available disparate selenium information collected from water, sediment, and biota in the Salton Sea region since the 1980s and to identify data gaps that need to be filled to understand the potential effects of selenium on species of concern, including federally endangered desert pupfish ( Cyprinodon macularius ) and Yuma Ridgway’s Rail ( Rallus obsoletus yumanensis; formerly Yuma Clapper Rail, Rallus longirostris yumanensis ). Available data from the Salton Sea drainage basin show that water from the Colorado River has the lowest selenium concentration of all surface water sources. All other surface water flowing into the Salton Sea has elevated selenium concentrations due to evaporation and evapotranspiration that occurs in agricultural fields and associated water delivery infrastructure or leaching of selenium from irrigated farmland soils. The Salton Sea has lower selenium concentrations because of various biogeochemical processes that recycle selenium into the sediment or volatilize it to the atmosphere; however, these mechanisms are not well defined, and it is not clear if selenium cycling will change in response to possible changes in the oxidation state of the Salton Sea bottom waters as water levels decline. Agricultural drains have the highest average selenium concentrations, but few drains have been sampled since changes in irrigation practices have occurred (due to the 2003 QSA). Groundwater selenium concentrations are variable; some wells south of the Salton Sea have selenium concentrations as high as 300 micrograms per liter (µg/L), whereas selenium concentrations are below detection in other wells. Groundwater and surface-water geothermal discharge zones around the margins of the Salton Sea and in unmanaged wetlands have not been studied in detail, and published selenium measurements are not available for these surface features. Selenium concentrations in the sediment of the Salton Sea drainage basin are highest in wetland particulate organic matter and the Salton Sea lakebed, indicating that removal of selenium from the water to the sediment has been a primary mechanism for keeping selenium concentrations low in the water column. Sediment selenium concentrations in wetlands are lower than in the Salton Sea but higher than inflowing drains and rivers, indicating the lentic wetland sites also may be important sinks for selenium because of biogeochemical processes. Sediment selenium data have not been collected in agricultural drains since changes in irrigation practices occurred (due to the 2003 QSA), and it is unknown if selenium sequestration from the water column has changed in these systems. We divided biological data into broad taxonomic categories, including primary producers, invertebrates, herpetofauna, mammals, fishes, and birds to facilitate evaluation of selenium concentrations and spatiotemporal trends observed in the Salton Sea. Overall, selenium concentrations were substantially greater in algae samples compared to all vascular plant samples combined. Median selenium concentrations in several invertebrate taxa (Chironomidae, Formicidae, Corixidae, Corbiculidae and Nereididae, and Decapoda) exceeded the maximum suggested dietary threshold of 3.0–4.0 micrograms per gram (µg/g) dry weight (dw) for predators consuming invertebrates in aquatic food webs. The greatest number of samples were collected from fish, and selenium distributions among species and locations showed that the range for most samples was lower than the U.S. Environmental Protection Agency selenium criterion for aquatic life (8.5 µg/g dw whole body, 11.3 µg/g dw fillets). The median selenium concentrations for whole body fish were below the selenium criterion in most locations, except for bairdiella ( Bairdiella icistia ) from the Salton Sea and irrigation drains, a few individual tilapia spp. (family Cichlidae, including genera Tilapia, Oreochromis , and their hybrids) from the river and river outlets, and several western mosquitofish ( Gambusia affinis ) and sailfin molly ( Poecilia latipinna ) from irrigation drain outlets. For avian samples combined among years and locations, median selenium concentrations in livers from all families except waders and Ibis (family Threskiornithidae) were higher than levels expected to cause selenium toxicosis (10–20 µg/g dw), and all median egg concentrations were above or near 6.0 μg/g dw, which is a conservative threshold value for reproductive impairment. Most knowledge gaps we identified for water, sediment, and biota were interrelated, and the use of integrated approaches to address knowledge gaps can provide greater insight into the drivers behind selenium hazards. Integrated water, sediment, and biota studies could help identify cost-effective management solutions that serve multiple purposes. A comprehensive analysis of the hydrology, biogeochemistry, and food-web processes in wetlands and other habitats can inform predictive models to identify drivers of selenium bioavailability, uptake from the environment and subsequent trophic transfer, ultimately forming the basis for experimental habitat management manipulations to minimize selenium hazards to wildlife. Furthermore, a comprehensive, long-term sampling and analytical laboratory plan would enable comparison of data among different entities that are sampling at the Salton Sea. Such efforts are well suited to help fill knowledge gaps that preclude understanding of selenium hazards and future management options for biota using Salton Sea habitats, including newly formed wetlands throughout the region. All data compiled for this report are available in two U.S. Geological Survey data releases: Groover and others (2022) for water and sediment samples and De La Cruz and others (2022) for biological samples. The data releases include all publicly available data for selenium concentrations in water, sediment, and biological samples collected in and around the Salton Sea, including the Coachella and Imperial Valleys. The data releases also include previously unpublished data.

California↗

USGS2010

Holocene pollen and sediment record from the tangle lakes area, central Alaska

Pollen and sediments have been analyzed from a 5.5 meter‐length core of lacustrine sediments from Tangle Lakes, in the Gulkana Upland south of the Alaska Range (63 ° 01 ‘ 46”; N. latitude, 146° 03 ‘ 48 “ W. longitude). Radiocarbon ages indicate that the core spans the last 4700 years. The core sediments are sandy silt and silty clay; the core shows distinct rhythmic laminations in the lower 398 cm. The laminae appear to be normally graded; peat fibers and macerated plant debris are more abundant near the tops of the laminae. Six volcanic‐ash layers are present in the upper 110 cm of the core. Present‐day vegetation of the Tangle Lakes area is mesic shrub tundra and open spruce woodland, with scattered patches of shrub willow (Salix), balsam poplar (P. balsamifera), spruce (Picea), paper birch (Betula papyrifera), and alder (Alnus). Pollen analysis of 27 core samples suggests that this vegetation type has persisted throughout the past 4700 years, except for an apparently substantial increase in Picea beginning about 3500 years B.P. Percentages of Picea pollen are very low (generally 1–3 percent) in the lower 2 meters of core (ca. 4700 to 3500 years B.P.), but rise to 13–18 percent in the upper 3.4 meters (ca. 3500 years B.P. to present). Previously reported data from this area indicate that Picea trees initially arrived in the Tangle Lakes area about 9100 years B.P., at least 2.5 to 3 thousand years after deglaciation of the region. The present investigation suggests that Picea trees became locally scarce or died out sometime after about 9000 years B.P. but before 4700 years B.P., then reinvaded the area about 3500 years B.P. If this extrapolated age for the Picea reinvasion is accurate it suggests that local expansion of the Picea population coincides with the onset of a Neoglacial interval of cooler, moister climate. This is an unexpected result, because intervals of cooler climate generally coincide with lowering of the altitudinal limit of trees. In this case, improved moisture conditions may have promoted spruce growth and reproduction in spite of somewhat cooler temperatures. Previous pollen records from Alaska suggest that Artemisia pollen contributed little to the pollen rain of most taiga and tundra sites during Holocene time. The pollen record from Tangle Lakes, however shows rather high percentages (7–13 percent) of Artemisia deposited during the approximate time interval 4700 to 3500 years B.P. Local habitats that have well‐drained soils derived from glacial deposits support patches of Artemisia telesii and other Artemisia species. These local habitats may account for the source of Artemisia pollen deposited in the Tangle Lakes area during Holocene time.

Alaska↗

USGS2005

Bathymetry and vegetation in isolated marsh and cypress wetlands in the northern Tampa Bay Area, 2000-2004

Wetland bathymetry and vegetation mapping are two commonly used lines of evidence for assessing the hydrologic and ecologic status of expansive coastal and riverine wetlands. For small isolated freshwater wetlands, however, bathymetric data coupled with vegetation assessments are generally scarce, despite the prevalence of isolated wetlands in many regions of the United States and the recognized importance of topography as a control on inundation patterns and vegetation distribution. In the northern Tampa Bay area of west-central Florida, bathymetry was mapped and vegetation was assessed in five marsh and five cypress wetlands. These 10 isolated wetlands were grouped into three categories based on the effects of ground-water withdrawals from regional municipal well fields: natural (no effect), impaired (drier than natural), and augmented (wetlands with artificially augmented water levels). Delineation of the wetland perimeter was a critical component for estimating wetland-surface area and stored water volume. The wetland perimeter was delineated by the presence of Serenoa repens (the 'palmetto fringe') at 9 of the 10 sites. At the 10th site, where the palmetto fringe was absent, hydric-soils indicators were used to delineate the perimeter. Bathymetric data were collected using one or more techniques, depending on the physical characteristics of each wetland. Wetland stage was measured hourly using continuous stage recorders. Wetland vegetation was assessed semiannually for 2 1/2 years in fixed plots located at three distinct elevations. Vegetation assessments were used to determine the community composition and the relative abundance of obligate, facultative wet, and facultative species at each elevation. Bathymetry maps were generated, and stage-area and stage-volume relations were developed for all 10 wetlands. Bathymetric data sets containing a high density of data points collected at frequent and regular spatial intervals provided the most useful stage-area and stage-volume relations. Bathymetric maps of several wetlands also were generated using a low density of data points collected along transect lines or contour lines. In a comparative analysis of the three mapping approaches, stage-area and stage-volume relations based on transect data alone underestimated (by 50-100 percent over certain ranges of stage) the wetland area and volume compared to results using a high density of data points. Adding data points collected along one elevation contour below the wetland perimeter to the transect data set greatly improved the agreement of the resulting stage-area and stage-volume relations to the high-density mapping approach. Stage-area relations and routinely monitored stage data were used to compare and contrast the average flooded area in a natural marsh and an impaired marsh over a 2-year period. Vegetation assessments used together with flooded-area information provided the potential for extrapolating vegetation results from points or transects to wetlands as a whole. A comparison of the frequency of flooding of different areas of the wetland and the species composition in vegetation plots at different elevations indicated the dependence of vegetation on inundation frequency. Because of the broad tolerances of many wetlands plants to a range of inundation conditions, however, vegetation assessments alone provided less definitive evidence of the hydrologic differences between the two sites, and hydrologic changes occurring during the 2 years, than the flooded-area frequencies. Combining flooded-area frequencies with vegetation assessments could provide a more versatile and insightful approach for determining the ecological status of wetlands than using vegetation and stage data alone. Flooded-area frequencies may further provide a useful approach for assessing the ecological status of wetlands where historical vegetation surveys and stage data are lacking. Comparing the contemporary flooded-area frequencies a

Scientific Investigations Report↗

USGS1999

Effect of subalpine canopy removal on snowpack, soil solution, and nutrient export, Fraser Experimental Forest, CO

Research on the effects of vegetation manipulation on snowpack, soil water, and streamwater chemistry and flux has been underway at the Fraser Experimental Forest (FEF), CO, since 1982. Greater than 95% of FEF snowmelt passes through watersheds as subsurface flow where soil processes significantly alter meltwater chemistry. To better understand the mechanisms accounting for annual variation in watershed streamwater ion concentration and flux with snowmelt, we studied subsurface water flow, its ion concentration, and flux in conterminous forested and clear cut plots. Repetitive patterns in subsurface flow and chemistry were apparent. Control plot subsurface flow chemistry had the highest ion concentrations in late winter and fall. When shallow subsurface flow occurred, its Ca 2+ , SO 4 2− , and HCO 3 − concentrations were lower and K + higher than deep flow. The percentage of Ca 2+ , NO 3 − , SO 4 2− , and HCO 3 − flux in shallow depths was less and K + slightly greater than the percentage of total flow. Canopy removal increased precipitation reaching the forest floor by about 40%, increased peak snowpack water equivalent (SWE)>35%, increased the average snowpack Ca 2+ , NO 3 − , and NH 4 + content, reduced the snowpack K + content, and increased the runoff four-fold. Clear cutting doubled the percentage of subsurface flow at shallow depths, and increased K + concentration in shallow subsurface flow and NO 3 − concentrations in both shallow and deep flow. The percentage change in total Ca 2+ , SO 4 2− , and HCO 3 − flux in shallow depths was less than the change in water flux, while that of K + and NO 3 − flux was greater. Relative to the control, in the clear cut the percentage of total Ca 2+ flux at shallow depths increased from 5 to 12%, SO 4 2− 5·4 to 12%, HCO 3 − from 5·6 to 8·7%, K + from 6 to 35%, and NO 3 − from 2·7 to 17%. The increases in Ca 2+ and SO 4 2− flux were proportional to the increase in water flux, the flux of HCO 3 − increased proportionally less than water flux, and NO 3 − and K + were proportionally greater than water flux. Increased subsurface flow accounted for most of the increase in non-limiting nutrient loss. For limiting nutrients, loss of plant uptake and increased shallow subsurface flow accounted for the greater loss. Seasonal ion concentration patterns in streamwater and subsurface flow were similar .

Hydrological Processes↗

USGS1983

Effects of specific land uses on nonpoint sources of suspended sediment, nutrients, and herbicides, Pequea Creek basin, Pennsylvania, 1979-80

The Susquehanna River Basin Commission and the U.S. Environmental Protection Agency cooperated with the U.S. Geological Survey in a study to quantify nonpoint-source loadings from an agricultural area in Pennsylvania. Pequea Creek, a tributary to the Susquehanna River, drains a 154-square mile agricultural area in Lancaster County, Pennsylvania. Previous studies defined the Pequea Creek basin as a contributor of sediment, nutrients, and pesticides from nonpoint sources to the Susquehanna River. The purpose of this intensive watershed investigation was to determine the effects of various land uses on water quality of receiving streams. Streamflow was measured and monthly base-flow samples and water-weighted composite storm samples were analyzed for suspended sediment, nutrients, organic carbon, and triazine herbicides. Constituent loadings were calculated to quantify their discharge from the entire Pequea Creek basin and from four specific subbasins: forest, cornfield, rural residential, and pasture. Soil samples were analyzed for nutrients and selected herbicides, and land use and application data were collected to determine the source of loadings. Precipitation amounts and chemistry were also measured. Precipitation and streamflow were below average for much of the investigation period, May 1979 to December 1980. The annual precipitation for 1980 was 10 inches below normal, with drought conditions the last half of the year. During base flow, the highest concentrations of individual constituents generally observed were: 4.0 milligrams per liter total organic nitrogen and 1.4 milligrams per liter total phosphorus from the downstream pasture site; 24 milligrams per liter total nitrate nitrogen and 3.9 micrograms per liter total atrazine from the cornfield site; and 0.5 micrograms per liter total prometone, and 2.3 micrograms per liter total simazine from the residential site. Nearly all total nitrate nitrogen concentrations from the cornfield site during base flow were about double the U.S. Environmental Protection Agency (1977) criterion of 10 milligrams per liter. The highest constituent concentrations found in composite storm samples were nearly all in samples from the cornfield site. The highest concentrations found were: 16,000 milligrams per liter suspended sediment, 54 milligrams per liter total organic nitrogen, 41 milligrams per liter total nitrate nitrogen, 19 milligrams per liter total phosphorus, and 200 micrograms per liter total atrazine. The highest concentrations found in composite storm samples for total prometone was 6.4 micrograms per liter at the residential site and for total simazine was 4.8 micrograms per liter at the downstream pasture site. Generally, concentrations of all the constituents, except nitrate, were higher during storms than during base flow at all sites. Total concentrations of the constituents increase during storms predominantly due to increases in suspended concentrations. The highest storm concentrations of most constituents occurred at the cornfield site. Fertilizer and herbicide applications increase the available sources of nutrients and herbicides for transport to the stream. The highest phosphorus, atrazine, and suspended-sediment concentrations at the cornfield site occurred during intense storms soon after application and planting. Constituent yields (tons per square mile) from storms, about evenly distributed throughout the basin, were compared from the other specific land-use sites to the forest site, which represents a relatively undisturbed land use. During storms, yields for suspended sediment, total organic nitrogen, and total phosphorus were highest for the pasture and lowest for the forest site. Total nitrate-nitrogen yields were highest for the cornfield and about the same for the forest and residential sites. Yields of total organic carbon were about the same for the cornfield and residential sites, which were both slightly higher than the forest

Water-Resources Investigations Report↗

USGS2001

Late Quaternary vegetation history of Rough Canyon, south-central New Mexico, USA

South-central New Mexico, USA, at the junction of the Rocky Mountains, High Plains and Chihuahuan Desert, is one of the better known regions in the late Quaternary of North America. Plant macrofossils and pollen from a packrat midden series in Rough Canyon, New Mexico allows refinement of plant distributions and paleoclimates in this transitional area since full glacial times. From 17 000 to 12 000 14 C yr BP, Pinus edulis – Juniperus scopulorum woodlands dominated limestone substrates between 1800 and 1490 m, with Pseudotsuga menziesii and other mixed-conifer species restricted to shady, north-facing slopes. Juniperus deppeana , the dominant juniper today above 2000 m in southern New Mexico, is conspicuously absent from glacial middens and must have been displaced south of the US–Mexico border. The minimum climatic conditions for P. edulis – J. scopulorum woodlands are ca 20% wetter and 3.5–5°C cooler (July mean maximum temperatures) than the modern climate at Rough Canyon. Holocene warming/drying may have started as early as 12 000 14 C yr BP with the extirpation of J. scopulorum from Rough Canyon, and was completed by at least 10 540 14 C yr BP. The record for arrivals of some desert species is confounded by traces of pollen and macrofossils in some of the glacial middens, which could signify either earliest occurrence or temporal mixing (contamination) of assemblages. AMS 14 C dating can discriminate between early arrival and contamination in midden macrofossils but not in pollen. AMS dates show that Choisya dumosa , presently near its northern (cold) limits at Rough Canyon, endured late glacial winters, possibly as clonal populations. Some Larrea tridentata leaves and pollen occur in middens dominated by conifers and oaks no longer at the site; an AMS date of 3205 14 C yr BP on Larrea leaves from one midden indicates contamination. Evidence for some macrofossil contamination, however, does not rule out the possibility that pollen of desert elements (e.g. Larrea , Prosopis ) in late glacial–early Holocene middens indicates their presence in the Tularosa Basin, well ahead of their local appearance in Rough Canyon. Finally, the increasing dominance of desert elements after 5000 14 C yr BP in the Rough Canyon series and elsewhere in the northern Chihuahuan Desert could reflect slow, postglacial migration from the south and/or progressive encroachment with gradual stripping of soils formed during the last glacial period.

Palaeogeography, Palaeoclimatology, Palaeoecology↗