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Coal geology of the Paleocene-Eocene Calvert Bluff Formation (Wilcox Group) and the Eocene Manning Formation (Jackson Group) in east-central Texas: Field trip guidebook for the Society for Organic Petrology, Twelfth Annual Meeting, The Woodlands, Texas, August 30, 1995

The Jackson and Wilcox Groups of eastern Texas (fig. 1) are the major lignite producing intervals in the Gulf Region. Within these groups, the major lignite-producing formations are the Paleocene-Eocene Calvert Bluff Formation (Wilcox) and the Eocene Manning Formation (Jackson). According to the Keystone Coal Industry Manual (Maclean Hunter Publishing Company, 1994), the Gulf Coast basin produces about 57 million short tons of lignite annually. The state of Texas ranks number 6 in coal production in the United States. Most of the lignite is used for electric power generation in mine-mouth power plant facilities. In recent years, particular interest has been given to lignite quality and the distribution and concentration of about a dozen trace elements that have been identified as potential hazardous air pollutants (HAPs) by the 1990 Clean Air Act Amendments. As pointed out by Oman and Finkelman (1994), Gulf Coast lignite deposits have elevated concentrations of many of the HAPs elements (Be, Cd, Co, Cr, Hg, Mn, Se, U) on a as-received gm/mmBtu basis when compared to other United States coal deposits used for fuel in thermo-electric power plants. Although regulations have not yet been established for acceptable emissions of the HAPs elements during coal burning, considerable research effort has been given to the characterization of these elements in coal feed stocks. The general purpose of the present field trip and of the accompanying collection of papers is to investigate how various aspects of east Texas lignite geology might collectively influence the quality of the lignite fuel. We hope that this collection of papers will help future researchers understand the complex, multifaceted interrelations of coal geology, petrology, palynology and coal quality, and that this introduction to the geology of the lignite deposits of east Texas might serve as a stimulus for new ideas to be applied to other coal basins in the U.S. and abroad.

Texas↗

Low flows from drought and water use reduced total dissolved solids fluxes in the Lower Colorado River Basin between 1976 to 2008

Study area: We evaluated the Virgin, Verde, Salt, and Gila Rivers in the Lower Colorado River Basin. The watersheds have extents in Arizona, Utah, New Mexico, US and Sonora, MX. Study focus: We calculated trends in total dissolved solids (TDS) concentrations and fluxes with the Weighted Regressions on Time, Discharge and Season model. The modeling framework leverages daily streamflow and discrete water quality observations at specific monitoring sites. We evaluated trends for a common period (1976–2008) and the whole period of record at each monitoring site in terms of climate and anthropogenic controls. New hydrologic insights for the region: Three rivers had persistent TDS concentrations exceeding the EPA secondary drinking water standard. All were associated with a geologic source of TDS. We observed increases and decreases in TDS concentrations at our monitoring sites, contrasting with global freshwater salinization and declining TDS concentrations in the Upper Colorado River Basin (UCRB). We attributed concentration variability to wintertime hydroclimatic forcing, with secondary influences of human water use. Reservoirs may decrease TDS concentrations by 50%. Efficiency improvements in irrigation and mining water uses may decrease TDS concentrations, while municipal growth increases TDS concentrations. We observed TDS flux declines at most monitoring sites. We attributed up to 85% of the TDS flux trend to changes in streamflow arising from drought and groundwater use. This study informs salinity dynamics in arid and aridifying locations, including the UCRB.

Lower Colorado River Basin↗

The World Coal Quality Inventory: South America

Executive Summary-Introduction: The concepts of a global environment and economy are strongly and irrevocably linked to global energy issues. Worldwide coal production and international coal trade are projected to increase during the next several decades in an international energy mix that is still strongly dependent on fossil fuels. Therefore, worldwide coal use will play an increasingly visible role in global environmental, economic, and energy forums. Policy makers require information on coal, including coal quality data, to make informed decisions regarding domestic coal resource allocation, import needs and export opportunities, foreign policy objectives, technology transfer policies, foreign investment prospects, environmental and health assessments, and byproduct use and disposal issues. The development of a worldwide, reliable, coal quality database would help ensure the most economically and environmentally efficient global use of coal. The U.S. Geological Survey (USGS), in cooperation with many agencies and scientists from the world's coal producing countries, originally undertook a project to obtain representative samples of coal from most of the world's producing coal provinces during a limited period of time (roughly 1998-2005), which is called the World Coal Quality Inventory (WoCQI). The multitude of producing coal mines, coal occurrences, or limited accessibility to sites in some countries can preclude collecting more than a single sample from a mine. In some areas, a single sample may represent an entire coal mining region or basin. Despite these limitations in sampling and uneven distribution of sample collection, the analytical results can still provide a general overview of world coal quality. The USGS intends to present the WoCQI data in reports and, when possible, in Geographic Information System (GIS) products that cover important coal bearing and producing regions.

Open-File Report↗

Analysis of the deconstruction of Dyke Marsh, George Washington Memorial Parkway, Virginia-Progression, geologic and manmade causes, and effective restoration scenarios

This report is a synthesis of the latest findings from an ongoing study of Dyke Marsh, an eroding freshwater tidal wetland that is scheduled for federal restoration. Its purpose is to provide an accurate and up-to-date temporal and geological framework for the marsh, of which most is new information (plus a compilation of historical and recent information), that is directly relevant to the restoration effort and also is relevant to short-term and long-term land management decisions regarding this natural resource. Analysis of field evidence, aerial photography, and published maps has revealed an accelerating rate of erosion and marsh loss at Dyke Marsh, which now appears to put at risk the short term survivability of this marsh. The destabilization of Dyke Marsh is outlined here, spanning an approximately 70-year time interval (1940-2010). This freshwater tidal marsh has shifted from a semi-stable net depositional environment (1864-1937) into a strongly erosional one, during a time when it currently is in early-phase planning for comprehensive restoration. The marsh has been deconstructed over the past 70 years by a combination of manmade and natural causes. The marsh initially experienced a strong destabilizing period between 1940 and 1972 by direct dredge mining of the marsh surface. By 1976 the marsh had entered a net destructive phase, where it remains at present. Photoanalysis of time-sequence aerial photographs of Dyke Marsh enabled us to calculate shoreline erosion estimates for this marsh over 19 years (1987-2006), as well as to quantify overall marsh acreage for 6 calendar years spanning an ~70 year interval (1937-2006). Photo overlay of a historic map enabled us to extend our whole-marsh acreage calculations back to 1883. Both sets of analyses were part of a geologic framework study in support of current efforts by the National Park Service (NPS) to restore this urban wetland. Two time intervals were selected for our shoreline erosion analyses, based on image quality and availability: 1987 to 2002, and 2002 to 2006. The more recent time interval shows a marked increase in erosion in the southern part of Dyke Marsh, following a wave-induced breach of a small peninsula that had protected its southern shoreline. Field observations and analyses of annual aerial imagery between 1987 and 2006 revealed a progressive increase in wave-induced erosion that presently is deconstructing Hog Island Gut, the last significant tidal creek network within the Dyke Marsh. These photo analyses documented an overall average westward shoreline loss of 6.0 to 7.8 linear feet per year along the Potomac River during this 19-year time interval. Additionally, photographic evidence documented that lateral erosion now is capturing existing higher order tributaries in the Hog Island Gut. Wave-driven stream piracy is fragmenting the remaining marsh habitat, and therefore its connectivity, relatively rapidly, causing the effective mouth of the Hog Island Gut tidal network to retreat headward visibly over the past several decades. Based on our estimates of total marsh area in the Dyke Marsh derived from 1987 aerial imagery, as much as 12 percent of the central part of the marsh has eroded in the 19 year period we studied (or ~7.5 percent of the original ~78.8 acres of 1987 marshland). Shoreline loss estimates for marsh parcels north and south of our study area have not yet been analyzed, although annual aerial photos from 1987 to 2002 confirm visible progressive shoreline loss in those areas over this same time interval.

Open-File Report↗

Reactivity of As and U co-occurring in mine wastes in northeastern Arizona

The reactivity of co-occurring arsenic (As) and uranium (U) in mine wastes was investigated using batch reactors, microscopy, spectroscopy, and aqueous chemistry. Analyses of field samples collected in proximity to mine wastes in northeastern Arizona confirm the presence of As and U in soils and surrounding waters, as reported in a previous study from our research group. In this study, we measured As (<0.500 to 7.77 μg/L) and U (0.950 to 165 μg/L) in waters, as well as mine wastes (<20.0 to 40.0 mg/kg As and <60.0 to 110 mg/kg U) and background solids (<20.0 mg/kg As and <60.0 mg/kg U). Analysis with X-ray fluorescence (XRF) and electron microprobe show the co-occurrence of As and U with iron (Fe) and vanadium (V). These field conditions served as a foundation for additional laboratory experiments to assess the reactivity of metals in these mine wastes. Results from laboratory experiments indicate that labile and exchangeable As(V) was released to solution when solids were sequentially reacted with water and magnesium chloride (MgCl 2 ), while limited U was released to solution with the same reactants. The predominance of As(V) in mine waste solids was confirmed by X-ray absorption near edge (XANES) analysis. Both As and U were released to solution after reaction of solids in batch experiments with HCO 3 − . Both X-ray photoelectron spectroscopy (XPS) and XANES analysis determined the predominance of Fe(III) in the solids. Mössbauer spectroscopy detected the presence of nano-crystalline goethite, Fe(II) and Fe(III) in (phyllo)silicates, and an unidentified mineral with parameters consistent with arsenopyrite or jarosite in the mine waste solids. Our results suggest that As and U can be released under environmentally relevant conditions in mine waste, which is applicable to risk and exposure assessment.

Arizona↗

Indiana and Landsat

Natural resources have always been a strength for Indiana. Once largely covered by forest, the State now includes a mix of forest, farmland, wetlands, and small lakes. In fact, farms and forested areas make up more than 80 percent of the land. The Ohio River forms the southern border, and the south shore of Lake Michigan contrasts with urban development in the northwestern corner. Indiana Dunes National and State Parks reside just east of the Chicago metropolitan area. Agriculture adds more than $30 billion to the economy in Indiana, which placed eighth in the country for agricultural exports at $4.6 billion in 2017. Indiana ranks in the top five States nationally for the production of corn and soybeans. The “Hoosier State” also grows sizable crops of popcorn, spearmint, peppermint, pumpkins, tomatoes, and watermelon. Additionally, hogs, cattle, dairy, and poultry contribute to the agricultural economy. Other industries important to Indiana include manufacturing, medicine, energy, and mining. Mineral sources vary from coal, building stone, and gypsum to sand, gravel, and shale. Landsat can help monitor the condition of natural resources and the effects of extreme weather events. Here are several ways Landsat has benefited Indiana.

Indiana↗

Preliminary assessment of channel stability and bed-material transport in the Coquille River basin, southwestern Oregon

This report summarizes a preliminary study of bed-material transport, vertical and lateral channel changes, and existing datasets for the Coquille River basin, which encompasses 2,745 km 2 (square kilometers) of the southwestern Oregon coast. This study, conducted to inform permitting decisions regarding instream gravel mining, revealed that: The 115.4-km-long study area on the South Fork and mainstem Coquille River can be divided into four reaches on the basis of topography and hydrology. In the fluvial (nontidal, or dominated by riverine processes) reaches on the South Fork Coquille River, the channel consists of bedrock and alluvium in the Powers Reach and mostly alluvium in the Broadbent Reach. In both fluvial reaches, the channel alternates between confined and unconfined segments and contains gravel bars. In the tidally affected Myrtle Point and Bandon Reaches, the channel consists of alluvial deposits and contains sparse gravel and sand bars as well as expansive mud flats and tidal marshes near the Coquille River mouth. The 15.4- and 14.6-km-long study areas on the Middle and North Forks of the Coquille River, respectively, were treated as distinct reaches. The channel beds consist of mixed bedrock and alluvium in the Bridge Reach on the Middle Fork Coquille River and alluvium in the Gravelford Reach on the North Fork Coquille River. Both of these reaches contain fewer bars than the Powers and Broadbent Reaches on the South Fork Coquille River and are predominately fluvial. Channel condition, bed-material transport, and the distribution and area of bars have likely been influenced by logging and splash damming, dredging and wood removal for navigation, historical and ongoing instream gravel mining, gold mining, fires, and mass movements. These anthropogenic and natural disturbances likely have varying effects on channel condition and sediment flux throughout the study area and over time. Available data include at least eight sets of aerial and orthophotographs that were taken of the study area from 1939 to 2011 that are available for assessing long-term changes in channel condition, bar area, and vegetation establishment patterns. Additionally, a high-resolution Light Detection And Ranging (LiDAR) survey conducted in 2008 for nearly the entire study area would be useful in future quantitative analyses of channel morphology and bed-material transport. Previous studies found (1) substantial bank erosion in the Broadbent Reach, resulting in banks with near vertical profiles and heights exceeding 7.6 m, (2) erosion of over 40,000 square meters of riparian land from 1939 to 1992, (3) incision along the South Fork Coquille River, and (4) potential for lateral channel migration at several locations along the mainstem and South Fork Coquille River. A review of deposited and mined bed-material estimates derived largely from repeat surveys at instream mining sites on the South Fork Coquille River indicates that bed material transported by the river tends to rebuild mined bar surfaces in most years. Reported annual deposition volumes for 1996–2009 indicate average transport of over 34,700 cubic meters per year (m 3 /yr) of bed material into the South Fork Coquille River study area. The spatial variation in the number and area of gravel bars is controlled by factors such as valley confinement, channel slope, basin geology, and tidal extent. The Powers and Broadbent Reaches of the South Fork Coquille River have the greatest abundance of gravel bars, likely owing to a substantial area of the South Fork Coquille River basin draining the gravel-producing Klamath Mountains geologic province. From 1939 to 2009, the fluvial reaches all had a net loss in bar area, ranging from 24 percent in the Powers Reach to 56 percent in the Bridge Reach. In the Powers and Broadbent Reaches, the declines in active bar area were associated primarily with vegetation establishment on bar surfaces and lateral bar erosion. The reductions in active bar area were attributed to vegetation establishment in the Bridge and Gravelford Reaches as well as some lateral bar erosion in the Bridge Reach. In contrast, the tidal Myrtle Point and Bandon Reaches had a net increase in bar area (28 and 29 percent, respectively) from 1939 to 2009. In the Myrtle Point Reach, these increases in bar area were primarily attributed to lateral channel migration that led to the deposition of bed material at newly formed bars. In the Bandon Reach, bar area increased primarily in the lower 5.4 km of the reach owing possibly to factors such as tide differences between the photographs and sediment deposition. Analyses of multiple channel cross sections along the South Fork Coquille River as well as historical stage-discharge data collected by the U.S. Geological Survey (USGS) at Powers, Oregon, indicate that the bed of the South Fork Coquille River has locally lowered, as much as 1.9 m from 1994 to 2008 for one site in the Broadbent Reach. Stage-discharge data indicate persistent incision at the Powers site since 1939 (with a net incision of about 0.3 m) that has been interrupted by episodic aggradation apparently corresponding with large floods. For the Bridge and Gravelford Reaches on the Middle and North Forks of the Coquille River, channel cross sections indicate a mix of aggradation and incision as well as bank erosion and deposition from 1992 to 2010 and 2000 to 2009, respectively. Cross sections in the tidal reaches indicate local incision of 0.4 m in at one site in the Myrtle Point Reach from 2004 to 2008 and 0.5 m at one site in in the Bandon Reach from 2000 to 2010. On the South Fork Coquille River, the median diameter of surface particles varied from 78.0 mm (millimeters) at China Flat Bar slightly upstream of the study area to 48.8 mm at Seals Bar in the Broadbent Reach. The armoring ratio (or ratio of the median grain sizes of the surface and subsurface layers) for Seals Bar was 3.5, indicating that the river’s transport capacity likely exceeds sediment supply at this site. Most fluvial reaches in the Coquille River study area are likely supply-limited, meaning that the river’s transport capacity exceeds the supply of bed-material, as indicated by the intermittent bedrock outcrops in the Powers and Bridge Reaches and the paucity of bars in the Bridge and Gravelford Reaches. The Broadbent Reach of the South Fork Coquille River may be presently and probably was historically transport-limited, meaning that bed-material transport is primarily a function of local transport capacity. However, the locally coarse bed texture, high armoring ratio measured at Seals Bar, and recent channel incision indicate that sediment supply has likely diminished relative to transport capacity in recent decades. Because of exceedingly low gradients, the tidal Myrtle Point and Bandon Reaches are transport limited. Bed material in these reaches is primarily sand and finer grain-size material, much of which is probably transported as suspended load from upstream reaches. The tidal reaches will be most susceptible to watershed conditions affecting the supply and transport of fine sediment. Compared to the nearby Chetco and Rogue Rivers and Hunter Creek on the southwestern Oregon coast, the Coquille River likely has lower overall transport of gravel bed material. While the conclusion of lower bed-material transport in the Coquille River is tentative in the absence of actual transport measurements or transport capacity calculations, empirical evidence including the much lower area and frequency of bars for most of the Coquille River study area and the head of tide reaching to RKM (river kilometer) 63.2 on the South Fork Coquille River supports this conclusion. More detailed investigations of bed-material transport rates and channel morphology would support assessments of lateral and vertical channel condition and longitudinal trends in bed material. Such assessments would be most practical for the Powers and Broadbent Reaches and relevant to several ongoing management and ecological issues pertaining to sand and gravel transport. The tidal Bandon and Myrtle Point Reaches may also be logical subjects for in-depth analyses of fine sediment deposition and transport (and associated channel and riparian conditions and processes) rather than coarse bed material.

Oregon↗

Under the Golden Gate Bridge — Views of the sea floor near the entrance to San Francisco Bay, California

San Francisco Bay in Northern California is one of the largest and most altered estuaries within the United States. The sea floor within the bay as well as at its entrance is constantly changing due to strong tidal currents, aggregate mining, dredge disposal, and the creation of new land using artificial fill. Understanding this dynamic sea floor is critical for addressing local environmental issues, which include defining pollution transport pathways, deciphering tectonics, and identifying benthic habitats. Mapping commercial interests such as safe ship navigation and dredge disposal is also significantly aided by such understanding. Over the past decade, the U.S. Geological Survey (USGS), the National Oceanic and Atmospheric Administration (NOAA), and California State University, Monterey Bay (CSUMB) in cooperation with the U.S. Army Corps of Engineers (USACOE) and the Center for Integrative Coastal Observation, Research and Education (CICORE) have partnered to map central San Francisco Bay and its entrance under the Golden Gate Bridge using multibeam echosounders. These sonar systems can continuously map to produce 100 percent coverage of the sea floor at meter-scale resolution and thus produce an unprecedented view of the floor of the bay. This poster shows views of the sea floor in west-central San Francisco Bay around Alcatraz and Angel Islands, underneath the Golden Gate Bridge, and through its entrance from the Pacific Ocean. The sea floor is portrayed as a shaded relief surface generated from the multibeam data color-coded for depth from light blues for the shallowest values to purples for the deepest. The land regions are portrayed by USGS digital orthophotographs (DOQs) overlaid on USGS digital elevation models (DEMs). The water depths have a 4x vertical exaggeration while the land areas have a 2x vertical exaggeration.

California↗

Assessment of undiscovered copper resources associated with the Permian Kupferschiefer, Southern Permian Basin, Europe

This study synthesizes available information and estimates the location and quantity of undiscovered copper associated with a late Permian bituminous shale, the Kupferschiefer, of the Southern Permian Basin in Europe. The purpose of this study is to (1) delineate permissive areas (tracts) where undiscovered reduced-facies sediment-hosted stratabound copper deposits could occur within 2.5 kilometers of the surface, (2) provide a database of known reduced-facies-type sediment-hosted stratabound copper deposits and significant prospects, and (3) provide probabilistic estimates of amounts of undiscovered copper that could be present within each tract. This assessment is a contribution to a global assessment conducted by the U.S. Geological Survey (USGS). Permissive tracts are delineated by mapping the extent of the Kupferschiefer that overlies reservoir-facies red beds of the lower Permian Rotliegend Group. More than 78 million metric tons (Mt) of copper have been produced or delineated as resources in the assessed tracts, with more than 90 percent of the known mineral endowment located in Poland. Mines in Poland are developing the deposit at depths ranging from about 500 to 1,400 meters. Two approaches are used to estimate in-situ amounts of undiscovered copper. The three-part form of assessment was applied to the entire study area. In this approach, numbers of undiscovered deposits are estimated and combined with tonnage-grade models to probabilistically forecast the amount of undiscovered copper. For Poland, drill-hole data were available, and Gaussian geostatistical simulation techniques were used to probabilistically estimate the amount of undiscovered copper. The assessment was done in September 2010 using a three-part form of mineral resource assessment and in January 2012 using Gaussian geostatistical simulation. Using the three-part form of assessment, a mean of 126 Mt of undiscovered copper is predicted in 4 assessed permissive tracts. Seventy-five percent of the mean amount of undiscovered copper (96 Mt) is associated with a tract in southwest Poland. For this same permissive tract in Poland, Gaussian geostatistical simulation techniques indicate a mean of 62 Mt of copper based on copper surface-density data from drill holes.

Scientific Investigations Report↗

Geologic map of the eastern half of the Vail 30' x 60' quadrangle, Eagle, Summit, and Grand Counties, Colorado

Recent mapping and geochronologic studies for the eastern half of the Vail 1:100,000-scale quadrangle have significantly improved our understanding of (1) Paleoproterozoic history of the basement rocks of the Gore Range and Williams Fork Mountains (western margin of the Front Range), (2) the Late Paleozoic history of the Gore fault system, (3) Laramide contractional tectonism, including deformation along the Gore fault and Williams Range thrust, (4) Oligocene and younger extensional history of the Blue River half graben (The northern extent of the Rio Grande rift), and (5) late Neogene and Quaternary surficial history. The recently active Gilman mining district, a major producer of zinc and lead, is in the southwestern corner of the map area. Marine sediments and mafic to felsic volcanic rocks deposited between about 1,740 and 1,780 m.y. were generally metamorphosed to amphibolite grade and intruded and deformed by mostly calc-alkalic granitic rocks during an orogenic episode that lasted about 110 m.y. The distribution of well-studied Upper Cambrian to thick Upper Cretaceous platform sediments is now greatly improved, which allows a better definition of the late Paleozoic uplift, erosion, and flanking sedimentation of the ancestral Front Range. Detailed mapping has also better defined the geometry of Late Cretaceous to early Tertiary Laramide deformation along both the Gore fault system and Williams Range thrust, as well as increased understanding of the details of mostly Neogene extension along the Blue River normal fault system (the western margin of the Blue River half graben). Scarps along the latter fault system indicate movement may be as young as Holocene. Detailed mapping of surficial deposits has defined and described (1) six ages of terrace alluvium, (2) three general ages of landslides, (3) glacial and periglacial deposits, and (4) fan, pediment, talus, and debris-flow deposits. The map is intended as a database for a variety of land-use and scientific purposes, including (1) assessment of geologically stable building sites, (2) planning for road and highway construction, (3) assessment of groundwater resources, (4) assessment of mineral resources, (5) determining geologic-hazard potential (flooding, landslide, rockfall, and seismic risk), (6) evaluating the structure of the northern Rio Grande rift in the Blue River valley, (7) improvement in understanding of the sedimentary section, which spans the period from the Cambrian to the Holocene, and (8) new insights into the geologic history of the Proterozoic basement rocks, including a number of new radiometric dates.

Scientific Investigations Map↗

Mercury bioaccumulation in fish in a region affected by historic gold mining: The South Yuba River, Deer Creek, and Bear River watersheds, California, 1999

Mercury that was used historically for gold recovery in mining areas of the Sierra Nevada continues to enter local and downstream water bodies, including the Sacramento Delta and the San Francisco Bay of northern California. Methylmercury is of particular concern because it is the most prevalent form of mercury in fish and is a potent neurotoxin that bioaccumulates at successive trophic levels within food webs. In April 1999, the U.S. Geological Survey, in cooperation with several other agencies the Forest Service (U.S. Department of Agriculture), the Bureau of Land Management, the U.S. Environmental Protection Agency, the California State Water Resources Control Board, and the Nevada County Resource Conservation District began a pilot investigation to characterize the occurrence and distribution of mercury in water, sediment, and biota in the South Yuba River, Deer Creek, and Bear River watersheds of California. Biological samples consisted of semi-aquatic and aquatic insects, amphibians, bird eggs, and fish. Fish were collected from 5 reservoirs and 14 stream sites during August through October 1999 to assess the distribution of mercury in these watersheds. Fish that were collected from reservoirs included top trophic level predators (black basses, Micropterus spp.) intermediate trophic level predators [sunfish (blue gill, Lepomis macrochirus; green sunfish, Lepomis cyanellus; and black crappie, Poxomis nigromaculatus)] and benthic omnivores (channel catfish, Ictularus punctatus). At stream sites, the species collected were upper trophic level salmonids (brown trout, Salmo trutta) and upper-to-intermediate trophic level salmonids (rainbow trout, Oncorhynchus mykiss). Boneless and skinless fillet portions from 161 fish were analyzed for total mercury; 131 samples were individual fish, and the remaining 30 fish were combined into 10 composite samples of three fish each of the same species and size class. Mercury concentrations in samples of black basses (Micropterus spp.), including largemouth, smallmouth, and spotted bass, ranged from 0.20 to 1.5 parts per million (ppm), wet basis. Mercury concentrations in sunfish ranged from less than 0.10 to 0.41 ppm (wet). Channel catfish had mercury concentrations from 0.16 to 0.75 ppm (wet). The range of mercury concentrations observed in rainbow trout was from 0.06 to 0.38 ppm (wet), and in brown trout was from 0.02 to 0.43 ppm (wet). Mercury concentrations in trout were greater than 0.3 ppm in samples from three of 14 stream sites. Mercury at elevated concentrations may pose a health risk to piscivorous wildlife and to humans who eat fish on a regular basis. Data presented in this report may be useful to local, state, and federal agencies responsible for assessing the potential risks associated with elevated levels of mercury in fish in the South Yuba River, Deer Creek, and Bear River watersheds.

California↗

Results of core drilling for coal at Lakhra Anticline, Pakistan, from December 1961 to May 1965

High-quality lignite has been mined in small quantity from rocks of early Tertiary age in the Lakhra anticline area for at least 20 years, but because coal outcrops are poor or nonexistent, the extent of the field was not known. However, between 1953 and 1958, five oil test holes penetrated the coal and revealed that coal underlies a large part of the Lakhra anticline. The Geological Survey of Pakistan began core drilling in 1961 to determine the extent and thickness of the shallower coal beds. By May 19630 25 borings had been completed. The Lailian coal bed was penetrated in borings over a distance of 5 miles from east to west and 11 miles from north to south, commonly at depths of less than 150 feet. The Lailian bed ranges in thickness from 2.6 to 8.4 feet; total reserves are estimated to be 130,000,000 tons. Coal below the Lailian bed appears to be lenticular, although present information is fragmentary.

Open-File Report↗

Uranium and trace elements in stream sediments as an exploration tool

More than 45 trace elements have been reported in anomalous amounts in the uranium ores. The specific suite of elements associated with any one uranium deposit varies according to deposit type and geologic province. The primary geochemical halo of uranium and associated trace elements in the host rock, together with secondary dispersion halo in soils and alluvium, offers a potential geochemical exploration target. Sediment from streams near low-grade uranium occurrences in arkosic sandstone of the Denver basin, Colorado, and sediment from streams in the igneous and metamorphic terrace near the Midnite mine of eastern Washington have been analyzed for acid-extractable U, Cu,Pb, Zn, Ni, Co, Fe, Mn, Mo, Cd, Cr, Ag, V, and Se, and for total Fe, Mn, Hg, As, and organic C. The -80 mesh fraction of the alluvium downstream from a small uraniferous limonite occurrence in the Denver basin shows anomalous concentrations of U, Pb, As, Ni, Mo, V, Zn, and Se. Anomalous concentrations of U persist farther downstream (as much as 1,000 m) than any of the trace elements. In another stream system southeast of Denver, above-background levels of U, Pb, As, Zn, V, Fe, and Mn occur near a uranium anomaly (defined by other methods) which has no surface mineralization. In the Midnite mine area, sediments of streams draining prospect areas showed anomalous concentrations of uranium (as much as 10 times background), but no accompanying anomalous trace-element concentrations, although analyses of Midnite mine ores show that a broad suite of trace elements are associated with uranium.

Open-File Report↗

Estimation of baseline daily mean streamflows for ungaged locations on Pennsylvania streams, water years 1960-2008

Water-resource managers use daily mean streamflows to generate streamflow statistics and analyze streamflow conditions. An in-depth evaluation of flow regimes to promote instream ecological health often requires streamflow information obtainable only from a time series hydrograph. Historically, it has been difficult to estimate daily mean streamflow for an ungaged location. The U.S. Geological Survey (USGS), in cooperation with the Pennsylvania Department of Environmental Protection, Susquehanna River Basin Commission, and The Nature Conservancy, has developed the Ba seline S treamflow E stimator (BaSE) to estimate baseline streamflow at a daily time scale for ungaged streams in Pennsylvania using data collected during water years 1960&ndash;2008. Baseline streamflow is minimally altered by regulation, diversion, or mining, and other anthropogenic activities. Daily mean streamflow is estimated in BaSE using a methodology that equates streamflow as a percentile from a flow duration curve for a particular day at an ungaged location with streamflow as a percentile from the flow duration curve for the same day at a reference streamgage that is considered to be hydrologically similar to the ungaged location. An appropriate reference streamgage is selected using map correlation, in which variogram models are developed that correlate streamflow at one streamgage with streamflows at all other streamgages. The percentiles from a flow duration curve for the ungaged location are converted to streamflow through the use of regression equations. Regression equations used to predict 17 flow-duration exceedance probabilities were developed for Pennsylvania using geographic information system-derived basin characteristics. The standard error of prediction for the regression equations ranged from 11 percent to 92 percent with the mean of 31 percent. The map correlation method for estimating streamflow was tested at locations within two pilot basins, the Upper Delaware River Basin and the Lower Susquehanna River Basin, before being applied statewide. Reference streamgages within the pilot basins were used as ungaged locations for analyzing the map correlation method. Correlation using Spearman&rsquo;s rho and centroid distance performed as well as, or better than, the method using the closest streamgage as a reference streamgage. Map correlation using the correlation metrics identified in the pilot basins was applied to 156 streamgages in and near Pennsylvania. BaSE uses the map correlation method and flow-duration exceedance probability regression equations to estimate baseline daily mean streamflow for an ungaged location. The output from BaSE is a Microsoft Excel&reg; report file that summarizes the reference streamgage and ungaged location information, including basin characteristics, percent difference in basin characteristics between the two locations, any warning associated with the basin characteristics, mean and median streamflow for the ungaged location, and a daily hydrograph of streamflow for water years 1960&ndash;2008 for the ungaged location. The daily mean streamflow for the ungaged location can be exported as a text file to be used as input into other statistical software packages. BaSE estimates daily mean streamflow for baseline conditions only, and any alterations to streamflow from regulation, large water use, or substantial mining are not reflected in the estimated streamflow.

Pennsylvania↗

Investigation of water quality in the Great Sand Dunes National Monument and Preserve, Saguache County, Colorado, February 1999 through September 2000: Qualifying for outstanding waters designation

Great Sand Dunes National Monument and Preserve is located on the eastern side of the San Luis Valley in south-central Colorado. The monument covers 60.4 square miles in Saguache and Alamosa Counties and lies at the base of the Sangre de Cristo Mountains, where a unique combination of climate, topography, and hydrology has created and maintained the Nation?s tallest inland sand dunes. The Sangre de Cristo Mountains, which rise to more than 14,000 feet to the north and east of the dunes, are the source of several streams that flow around the dunes and eventually recharge the aquifer beneath the valley. Sand Creek and Medano Creeks are the largest of the streams in the monument that originate in the Sangre de Cristo Mountains; several ephemeral streams flow into Sand Creek and Medano Creek. Maintaining the high surface-water quality in the Great Sand Dunes National Monument and Preserve is identified as a critical issue by the National Park Service. Additionally, the National Park Service has indicated a desire to pursue an Outstanding Waters Designation, which offers the highest level of water-quality protection available under the Clean Water Act and Colorado regulations. This designation is designed to prevent any degradation from existing conditions (Chatman and others, 1997). Assessment is needed to evaluate whether the water quality of the streams in the monument meets the requirements for an Outstanding Waters Designation. Historically, prospecting and mining activities have occurred in the watersheds of Sand and Medano Creeks; currently, however, there is no mining activity in those watersheds. In addition, the camping and recreation that occur upstream from the monument on national preserve lands and water activities that occur in Medano Creek during the summer are a potential source of human-waste contamination. Figure 1. Location of study area, sampling sites, and indication of sites that meet or exceed instream standards. The U.S. Geological Survey (USGS), in cooperation with the National Park Service, investigated the water quality at 15 sites (fig. 1) from February 1999 through September 2000 to identify baseline water-quality conditions and to determine if the water met standards to qualify for the Outstanding Waters Designation. This report describes current water-quality conditions in streams in the monument and compares the water-quality data to Colorado instream standards to assist the State of Colorado Water Quality Control Commission in the determination of qualification for Outstanding Waters Designation.

Water-Resources Investigations Report↗

Environmental Setting and Implications on Water Quality, Upper Colorado River Basin, Colorado and Utah

The Upper Colorado River Basin in Colorado and Utah is 1 of 60 study units selected for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment program, which began full implementation in 1991. Understanding the environmental setting of the Upper Colorado River Basin study unit is important in evaluating water-quality issues in the basin. Natural and human factors that affect water quality in the basin are presented, including an overview of the physiography, climatic conditions, general geology and soils, ecoregions, population, land use, water management and use, hydrologic characteristics, and to the extent possible aquatic biology. These factors have substantial implications on water-quality conditions in the basin. For example, high concentrations of dissolved solids and selenium are present in the natural background water conditions of surface and ground water in parts ofthe basin. In addition, mining, urban, and agricultural land and water uses result in the presence of certain constituents in the surface and ground water of the basin that can detrimentally affect water quality. The environmental setting of the study unit provides a framework of the basin characteristics, which is important in the design of integrated studies of surface water, ground water, and biology.

Water-Resources Investigations Report↗

Lithologic mapping using Landsat thematic mapper data

The Landsat-4 Thematic Mapper (TM), with its new near infrared bands centered at 1.65 μm and 2.20 μm and spatial resolution of 30 m has been used to distinguish rocks containing minerals having ferric-iron absorption bands in the visible and near-infrared and Al-O- and CO 3 absorption bands in the 2.1-2.4 μm regions. On the basis of characteristic absorption bands, digitally processed TM data were used to differentiate vegetated from non-vegetated areas, limonitic from nonlimonitic rocks, rocks containing minerals having absorption bands in the near-infrared region from rocks lacking infrared absorption bands. Specific minerals were detected in both the humid eastern and semi-arid western United States. The absorption bands in the near-infrared region were used to detect kaolinite in open-pit exposures of a kaolin mining district near Macon, Georgia; calcium carbonate in the back sands along the east coast of Floridia; and kaolinite, alunite, jarosite, sericite and gypsum in natural exposures near Boulder City, Nevada. These results show that the additional spectral bands in the near-infrared region and increased spatial resolution of the Thematic Mapper provide a valuable tool for distinguishing several significant geologic materials not distinguishable from space using previous imaging systems. They also show that TM data can be successfully used in a variety of geologic environments.

Pecora VIII Symposium↗

Concentration, distribution, and comparison of selected trace elements in bed sediment and fish tissue in the South Platte River Basin, USA, 1992- 1993

During August–November 1992 and August 1993, bed sediment and fish liver were sampled in the South Platte River Basin and analyzed for 45 elements in bed sediment and 19 elements in fish liver. The results for aluminum, arsenic, cadmium, chromium, copper, iron, lead, manganese, selenium, silver, uranium, and zinc are presented here. All 12 trace elements were detected in bed sediment, but not all were detected in fish liver or in all species of fish. A background concentration of trace elements in bed sediment was calculated using the cumulative frequency curves of trace element concentrations at all sites. Arsenic, cadmium, copper, lead, manganese, silver, uranium, and zinc concentrations were greater than background concentrations at sites in mining areas or at sites that have natural sources of these elements. Trace element concentrations in fish liver generally did not follow the same patterns as concentrations in bed sediment, although concentrations of aluminum and cadmium were higher in fish liver collected at mountain sites that had been disturbed by mining. Concentrations of aluminum, arsenic, cadmium, chromium, copper, iron, lead, silver, and zinc increased in bed sediments in urban areas. Iron, silver, and zinc concentrations in fish liver also increased in urban areas. Concentrations of cadmium, copper, silver, and zinc in fish liver increased in the agricultural areas of the basin. Downstream changes in trace element concentrations may be the result of geological changes in addition to changes in land use along the river.

Archives of Environmental Contamination and Toxico↗