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At least 1,783 records · Page 99Linked to original sources
USGS1965

Ground-water data of selected test holes and wells along the Arkansas River in LeFlore and Haskell Counties, Oklahoma

The data in this report were collected during the period 1958-64 by the U.S. Geological Survey in cooperation with the U.S. Army, Corps of Engineers, as part of a comprehensive study of the ground-water resources of the alluvium along the Arkansas and Verdigris Rivers between Moffett and Catoosa, Oklahoma (fig. 1). The purpose of this report is to make the hydrologic data obtained during the study of ground water in the alluvium along the Arkansas River in Le Flore and Haskell Counties readily available to the public. The data in this report should be useful in predicting geologic and hydrologic conditions when drilling new wells. Table 1 gives information on the sizes, depths, yields, and other characteristics of wells in the area. The table also provides a key to the additional information for each well site given in tables 2 through 6. Table 2 gives logs for the materials penetrated at test holes and wells in the report area; table 3 gives depths to water measured in wells; table 4 includes chemical analyses of water from wells; table 5 gives laboratory determinations of particle-size distribution of earth samples collected from test holes and wells; and table 6 gives coefficients of permeability and other hydrologic properties of earth samples from the selected test holes. Similar data for Sequoyah County, Muskogee County, and Wagoner-Rogers Counties are available in other open-file reports. An interpretive report, 'Hydrology of the alluvium of the Arkansas River, Muskogee, Oklahoma, to Fort Smith, Arkansas,' by Harry H. Tanaka and Jerrald R. Hollowell will be published as U.S. Geological Survey Water-Supply Paper 1809-T.

Open-File Report↗
USGS2014

Geochemistry of groundwater in the Beaver and Camas Creek drainage basins, eastern Idaho

The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, is studying the fate and transport of waste solutes in the eastern Snake River Plain (ESRP) aquifer at the Idaho National Laboratory (INL) in eastern Idaho. This effort requires an understanding of the natural and anthropogenic geochemistry of groundwater at the INL and of the important physical and chemical processes controlling the geochemistry. In this study, the USGS applied geochemical modeling to investigate the geochemistry of groundwater in the Beaver and Camas Creek drainage basins, which provide groundwater recharge to the ESRP aquifer underlying the northeastern part of the INL. Data used in this study include petrology and mineralogy from 2 sediment and 3 rock samples, and water-quality analyses from 4 surface-water and 18 groundwater samples. The mineralogy of the sediment and rock samples was analyzed with X-ray diffraction, and the mineralogy and petrology of the rock samples were examined in thin sections. The water samples were analyzed for field parameters, major ions, silica, nutrients, dissolved organic carbon, trace elements, tritium, and the stable isotope ratios of hydrogen, oxygen, carbon, sulfur, and nitrogen. Groundwater geochemistry was influenced by reactions with rocks of the geologic terranes—carbonate rocks, rhyolite, basalt, evaporite deposits, and sediment comprised of all of these rocks. Agricultural practices near and south of Dubois and application of road anti-icing liquids on U.S. Interstate Highway 15 were likely sources of nitrate, chloride, calcium, and magnesium to groundwater. Groundwater geochemistry was successfully modeled in the alluvial aquifer in Camas Meadows and the ESRP fractured basalt aquifer using the geochemical modeling code PHREEQC. The primary geochemical processes appear to be precipitation or dissolution of calcite and dissolution of silicate minerals. Dissolution of evaporite minerals, associated with Pleistocene Lake Terreton, is an important contributor of solutes in the Mud Lake-Dubois area. Oxidation-reduction reactions are important influences on the chemistry of groundwater at Camas Meadows and the Camas National Wildlife Refuge. In addition, mixing of different groundwaters or surface water with groundwater appears to be an important physical process influencing groundwater geochemistry in much of the study area, and evaporation may be an important physical process influencing the groundwater geochemistry of the Camas National Wildlife Refuge. The mass-balance modeling results from this study provide an explanation of the natural geochemistry of groundwater in the ESRP aquifer northeast of the INL, and thus provide a starting point for evaluating the natural and anthropogenic geochemistry of groundwater at the INL.

Idaho↗
USGS1965

Ground-water data of selected test holes and wells along the Arkansas river in Muskogee County, Oklahoma

The data in this report were collected during the period 1958-64 by the U.S. Geological Survey in cooperation with the U.S. Army, Corps of Engineers, as part of a comprehensive study of the ground-water resources of the alluvium along the Arkansas and Verdigris Rivers between Moffett and Catoosa, Oklahoma (fig. 1). The purpose of this report is to make the hydrologic data obtained during the study of ground water in the alluvium along the Arkansas River in Muskogee County readily available to the public. The data in this report should be useful in predicting geologic and hydrologic conditions when drilling new wells. Table 1 gives information on the sizes, depths, yields, and other characteristics of wells in the area. The table also provides a key to the additional information for each well site given in tables 2 through 6. Table 2 gives logs for the materials penetrated at test holes and wells in the report area; table 3 gives depths to water measured in wells; table 4 includes chemical analyses of water from wells; table 5 gives laboratory determinations of particle-size distribution of earth samples collected from test holes and wells; and table 6 gives coefficients of permeability and other hydrologic properties of earth samples from the selected test holes. Similar data for Sequoyah County, LeFlore-Haskell Counties, and Wagoner-Rogers Counties are available in other open-file reports. An interpretive report, 'Hydrology of the alluvium of the Arkansas River, Muskogee, Oklahoma, to Fort Smith, Arkansas,' by Harry H. Tanaka and Jerrald R. Hollowell will be published as U.S. Geological Survey Water-Supply Paper 1809-T.

Open-File Report↗
USGS1965

Ground-water data of selected test holes and wells along the Arkansas River in Sequoyah County, Oklahoma

The data in this report were collected during the period 1958-64 by the U.S. Geological Survey in cooperation with the U.S. Army, Corps of Engineers, as part of a comprehensive study of the ground-water resources of the alluvium along the Arkansas and Verdigris Rivers between Moffett and Catoosa, Oklahoma (fig. 1). The purpose of this report is to make the hydrologic data obtained during the study of ground water in the alluvium along the Arkansas River in Sequoyah County readily available to the public. The data in this report should be useful in predicting geologic and hydrologic conditions when drilling new wells. Table 1 gives information on the sizes, depths, yields, and other characteristics of wells in the area. The table also provides a key to the additional information for each well site given in tables 2 through 6. Table 2 gives logs for the materials penetrated at test holes and wells in the report area; table 3 gives depths to water measured in wells; table 4 includes chemical analyses of water from wells; table 5 gives laboratory determinations of particle-size distribution of earth samples collected from test holes and wells; and table 6 gives coefficients of permeability and other hydrologic properties of earth samples from the selected test holes. Similar data for LeFlore-Haskell Counties, Muskogee County, and Wagoner-Rogers Counties are available in other open-file reports. An interpretive report, 'Hydrology of the alluvium of the Arkansas River, Muskogee, Oklahoma, to Fort Smith, Arkansas,' by Harry H. Tanaka and Jerrald R. Hollowell will be published as U.S. Geological Survey Water-Supply Paper 1809-T.

Open-File Report↗
USGS1973

Developing a state water plan: Ground-water conditions in Utah, spring of 1973

This report is the tenth in a series of annual reports that describe ground-water conditions in Utah. Reports in this series are prepared cooperatively by the U.S. Geological Survey and the Utah Division of Water Resources and are designed to provide data to enable interested parties such as legislators, administrators, and planners to keep abreast of changing ground-water conditions. This report, like the others (see references, p. 25), contains information on well construction, ground-water withdrawals, water-level changes, and related changes in precipitation and streamflow. Supplementary data such as graphs showing chemical quality of water and maps showing water-table configuration are included in reports of this series only for those years or areas for which applicable data are available and are important to a discussion of changing ground-water conditions. The report includes individual discussions of the most important areas of ground-water withdrawal in the State for the calendar year 1972 and for the 10-year period 1963-72. Water-level fluctuations, however, are described for the periods spring 1972 to spring 1973 and spring 1963 to spring 1973. Many of the data used in the report were collected by the Geological Survey in cooperation with the Division of Water Rights, Utah Department of Natural Resources.

Utah↗
USGS2001

Determination of variables in the prediction of strontium distribution coefficients for selected sediments

Idaho State University and the US Geological Survey, in cooperation with the US Department of Energy, conducted a study to determine and evaluate strontium distribution coefficients (Kds) of subsurface materials at the Idaho National Engineering and Environmental Laboratory (INEEL). The Kds were determined to aid in assessing the variability of strontium Kds and their effects on chemical transport of strontium-90 in the Snake River Plain aquifer system. Data from batch experiments done to determine strontium Kds of five sediment-infill samples and six standard reference material samples were analyzed by using multiple linear regression analysis and the stepwise variable-selection method in the statistical program, Statistical Product and Service Solutions, to derive an equation of variables that can be used to predict strontium Kds of sediment-infill samples. The sediment-infill samples were from basalt vesicles and fractures from a selected core at the INEEL; strontium Kds ranged from ???201 to 356 ml g-1. The standard material samples consisted of clay minerals and calcite. The statistical analyses of the batch-experiment results showed that the amount of strontium in the initial solution, the amount of manganese oxide in the sample material, and the amount of potassium in the initial solution are the most important variables in predicting strontium Kds of sediment-infill samples.

Environmental Geology↗
USGS1963

The peg claims spodumene pegmatites, Maine

The Peg Claims pegmatites are located southwest of Rockland in the towns of Warren and Cushing, Knox County, Maine . These pegmatites are representative of a group of zoned, granitic, lithium-bearing pegmatites in which spodumene is present nearly from wall to wall. The pegmatites are discordant, steeply dipping, tabular bodies in the Penobscot quartz-mica schist near the Waldoboro granite. A narrow quartz-tourmaline-muscovite-apatite aureole is commonly developed around each of the pegmatites and around inclusions of country rock in the pegmatites . The pegmatites are zoned, and each may be subdivided into: (1) a narrow quartz-muscovite border zone; (2) a narrow albite-quartz-muscovite wall zone; (3) and an albite-quartz- spodumene -perthite core that constitutes most of the pegmatite . Cross-cutting, fine-grained, quartz-albite- spodumene -muscovite lenses are found within pegmatite cores. The bulk mineralogy and variations in the mineralogy from zone to zone of the largest body (Dike 1) were determined by megascopic mineral point-counts. There is a decrease of albite, quartz, and muscovite and an increase of spodumene and perthite from the border and wall zones into the core. The alkali contents of Dike 1 and of each of its zones were determined by flame photometer and X-ray fluorescence analyses. The amount of Na20 decreases and the amounts of K 2 O, Li 2 0, Rb 2 0, and CS 2 O increase from the border and wall zones into the core. Estimated bulk compositions of Dike 1 and of each of its zones were computed. It is concluded that the distribution, structural features, bulk chemistry, and the mineralogical, chemical, and textural zoning of the pegmatites are consistent with development by fractional crystallization of a pegma-titic fluid in a restricted system.

Maine↗
USGS1972

Ground-water resources of Benson and Pierce Counties, north-central North Dakota

The purpose of this investigation is to provide information about the ground-water resources in Benson and Pierce Counties that is sufficient for planning the safe and intelligent development of water supplies for irrigation, domestic, stock, industrial, and municipal purposes. The investigation is part of a statewide program to determine the location and extent of ground-water aquifers; to evaluate the occurrence and movement of ground water within the aquifers, including sources of recharge and discharge; to determine potential yields to wells developed in the aquifers; and to determine the chemical quality of ground water. Benson and Pierce Counties cover an area of 2,512 square miles in north-central North Dakota. This study, which began in July 1967 and was completed in June 1971, was made cooperatively by the U.S. Geological Survey, the North Dakota State Water Commission, the North Dakota Geological Survey, and the Benson and Pierce Counties Water Management Districts. This interim report presents only the major conclusions of the study.

North Dakota↗
USGS2000

Quaternary geologic map of the Winnipeg 4° x 6° quadrangle, United States and Canada

The Quaternary Geologic Map of the Winnipeg 4° x 6° quadrangle, United States and Canada, is a component of the U.S. Geological Survey Quaternary Geologic Atlas of the United States map series (Miscellaneous Investigations Series I-1420), an effort to produce 4° x 6° Quaternary geologic maps, at 1:1 million scale, of the entire conterminous United States and adjacent Canada. The map and the accompanying text and supplemental illustrations provide a regional overview of the areal distributions and characteristics of surficial deposits and materials of Quaternary age (~1.8 Ma to present) in parts of North Dakota, Minnesota, Manitoba, and Saskatchewan. The map is not a map of soils as soils are recognized in agriculture. Rather, it is a map of soils as recognized in engineering geology, or of substrata or parent materials in which agricultural soils are formed. The map units are distinguished chiefly on the basis of (1)genesis (processes of origin) or environments of deposition: for example, sediments deposited primarily by glacial ice (glacial deposits or till), sediments deposited in lakes (lacustrine deposits), or sediments deposited by wind (eolian deposits); (2) age: for example, how long ago the deposits accumulated; (3) texture (grain size)of the deposits or materials; (4) composition (particle lithology) of the deposits or materials; (5) thickness; and (6) other physical, chemical, and engineering properties. Supplemental illustrations show (1) temporal correlation of the map units, (2) the areal relationships of late Wisconsin glacial ice lobes and sublobes, (3) temporal and spatial correlation of late Wisconsin glacial phases, readvance limits, and ice margin stillstands, (4) temporal and stratigraphic correlation of surface and subsurface glacial deposits in the Winnipeg quadrangle and in adjacent 4° x 6° quadrangles, and (5) responsibility for state and province compilations. The database provides information related to geologic hazards (for example, materials that are characterized by expansive clay minerals; landslide deposits or landslide-prone deposits), natural resources (for example, sources of aggregate, peat, and clay; potential shallow sources of groundwater), and areas of environmental concern (for example, areas that are potentially suitable for specific ecosystem habitats; areas of potential soil and groundwater contamination). All of these aspects of the database relate directly to land use, management, and policy. The map, text, and accompanying illustrations provide a database of regional scope related to geologic history, climatic changes, the stratigraphic and chronologic frameworks of surface and subsurface deposits and materials of Quaternary age, and other problems and concerns.

Manitoba, Minnesota, Saskatchewan↗
USGS2001

Water-Chemistry and On-Site Sulfur-Speciation Data for Selected Springs in Yellowstone National Park, Wyoming, 1996-1998

Fifty-eight water analyses are reported for samples collected from 19 hot springs and their overflow drainages and one ambient-temperature acid stream in Yellowstone National Park (YNP) during 1996-98. These water samples were collected and analyzed as part of research investigations on microbially mediated sulfur oxidation in stream waters and sulfur redox speciation in hot springs in YNP and chemical changes in overflow drainages that affect major ions, redox species, and trace elements. The research on sulfur redox speciation in hot springs is a collaboration with the State University of New York at Stony Brook, Northern Arizona University, and the U.S. Geological Survey (USGS). One ambient-temperature acidic stream system, Alluvium Creek and its tributaries in Brimstone Basin, was studied in detail. Analyses were performed adjacent to the sampling site, in an on-site mobile laboratory truck, or later in a USGS laboratory, depending on stability and preservability of the constituent. Water temperature, specific conductance, pH, Eh, dissolved oxygen (D.O.), and dissolved H2S were determined on-site at the time of sampling. Alkalinity and F were determined within a few days of sample collection by titration and by ion-selective electrode, respectively. Concentrations of S2O3 and SxO6 were determined as soon as possible (minutes to hours later) by ion chromatography (IC). Concentrations of Cl, SO4, and Br were determined by IC within a few days of sample collection. Concentrations of Fe(II) and Fe(total) were determined by ultraviolet/visible spectrophotometry within a few days of sample collection. Densities were determined later in the USGS laboratory. Concentrations of Li, Na, and K were determined by flame atomic absorption (Li) and emission (Na, K) spectrometry. Concentrations of Al, As(total), B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe(total), Mg, Mn, Ni, Pb, Si, Sr, V, and Zn were determined by inductively-coupled plasma optical emission spectrometry. Trace concentrations of Cd, Se, As(total), Ni, and Pb were determined by Zeeman-corrected graphite-furnace atomic-absorption spectrometry. Trace concentrations of As(total) and As(III) were determined by hydride generation using a flow-injection analysis system.

Open-File Report↗
USGS2001

Analytical data for waters of the Harvard Open Pit, Jamestown Mine, Tuolumne County, California, March 1998-September 1999

The Jamestown mine is located in the Jamestown mining district in western Tuolumne County, California (see Fig. 1). This district is one of many located on or near the Melones fault zone, a major regional suture in the Sierra Nevada foothills. The districts along the Melones fault comprise the Mother Lode gold belt (Clark, 1970). The Harvard pit is the largest of several open pits mined at the Jamestown site by Sonora Mining Corporation between 1986 and 1994 (Fig. 2; Algood, 1990). It is at the site of an historical mine named the Harvard that produced about 100,000 troy ounces of gold, mainly between 1906 and 1916 (Julihn and Horton, 1940). Sonora Mining mined and processed about 17,000,000 short tons of ore, with an overall stripping ratio of about 4.5:1, yielding about 660,000 troy ounces of gold (Nelson and Leicht, 1994). Most of this material came from the Harvard pit, which attained dimensions of about 2700 ft (830 m) in length, 1500 ft (460 m) in width, and 600 ft (185 m) in depth. The bottom of the pit is at an elevation of 870 ft (265 m). Since mining operations ceased in mid-1994, the open pit has been filling with water. As of November, 2000, lake level had reached an elevation of about 1170 ft (357 m). Water quality monitoring data gathered after mine closure showed rising levels of arsenic, sulfate, and other components in the lake, with particularly notable increases accompanying a period of rapid filling in 1995 (County of Tuolumne, 1998). The largest potential source for arsenic in the vicinity of the Harvard pit is arsenian pyrite, the most abundant sulfide mineral related to gold mineralization. A previous study of weathering of arsenian pyrite in similarly mineralized rocks at the Clio mine, in the nearby Jacksonville mining district, showed that arsenic released by weathering of arsenian pyrite is effectively attenuated by adsorption on goethite or coprecipitation with jarosite, depending upon the buffering capacity of the pyrite-bearing rock (Savage and others, 2000). Although jarosite would be expected to dissolve in water having the composition of the developing pit lake, iron oxyhydroxide species (ferrihydrite and goethite) would be stable, and strong partitioning of arsenic onto suspended particles or bottom sediments containing these iron phases would be expected. Arsenic release to the lake would not be expected until stratification develops, producing a reducing, non-circulating hypolimnion in which the iron phases would be destroyed by dissolution. The fact that arsenic concentrations increased rapidly before the pit lake was deep enough to stratify shows that arsenic may not be attenuated in the ways that the earlier Clio mine area study indicated, and suggested that our understanding of release and transport of arsenic in this environment is incomplete. Therefore, in 1997 we decided to study the chemical evolution of the Harvard pit lake as part of a project on environmental impacts of gold mining in the Sierra Nevada, and in early 1998 we developed a cooperative study with several of the investigators in the Stanford University Department of Geological and Environmental Sciences who had done the Clio study. The U.S. Geological Survey portion of the project has been funded by the Mineral Resources Program. It is anticipated that a better understanding of the release and transport of arsenic into the Harvard pit lake and its accumulation there will contribute to more accurate predictions of arsenic release from weathering of sulfide-bearing rocks exposed by mining or other activities or events, and to better forecasts of pit lake evolution in this and similar environments, leading to more effective monitoring and mitigation strategies. An accurate predictive model is needed for the Harvard pit lake to forecast trends in metal concentrations, particularly arsenic, and also concentrations of major cations and anions. As the lake approaches pre-mining groundwater levels the lake water could move down the hydrologic gradient to the southeast into domestic wells, and could also affect the surface water of Woods Creek (see Figures 1-3). This report presents data for water samples collected from March, 1998 through September, 1999. Selected preliminary data for the pit lake for the 1998 calendar year have been reported (Savage and others, 2000).

California↗
USGS2025

Gas chemistry and isotope data for volcano monitoring at the Lassen Volcanic Center, Lassen Volcanic National Park

This report presents chemical and isotopic compositions of volcanic gases collected from thermal areas within Lassen Volcanic National Park in northern California from 1974 through 2019. As the southernmost volcano in the Cascade Range and designated a very-high-threat volcano by the U.S. Geological Survey, the Lassen Volcanic Center (LVC) requires consistent monitoring to assess potential volcanic hazards. In 2014, the California Volcano Observatory established a gas geochemical monitoring program at LVC to provide baseline data to evaluate future changes.</p> Results demonstrate consistent spatial patterns in bulk gas chemistry that support a two-circulation-cell hydrothermal model previously established for LVC. Gas samples from circulation cell 1 thermal areas have higher helium isotope ratios (6.59–7.50 times the air value) than those from circulation cell 2 (5.86–6.52 times the air value), indicating a stronger magmatic signature. The Sulphur Works and Pilot Pinnacle thermal areas within circulation cell 1 consistently emit gases with the highest magmatic helium contents, suggesting gas at these areas best represents conditions in the underlying volcanic system. A slight decrease in helium isotope values since 1974 may indicate progressive dilution of magmatic helium-3 (3He) by radiogenic helium-4 (4He) in the absence of recent magma intrusion. Carbon isotope compositions of carbon dioxide across all thermal areas are relatively uniform (−9.7–−7.3 per mil), falling within the range observed at other Cascade Range volcanoes. Based on gas geochemical characteristics and site accessibility, the Sulphur Works and Pilot Pinnacle thermal areas represent optimal targets for continued monitoring of the LVC magmatic-hydrothermal system. This study includes the most comprehensive helium isotope dataset collected at LVC currently available and establishes critical baseline data for future volcanic monitoring efforts.</p>

Open-File Report↗
USGS1982

The evaluation of selected one-dimensional stream water quality models with field data

The U.S. Geological Survey One-Dimensional Stream Water-Quality Model, QUAL II Stream Water-Quality Routing Model, the U.S. Army corps of Engineers Water Quality for River Reservoir Systems Model, and the M.I.T. Transient Water Quality Network were evaluated and compared using actual water-quality data collected by the U.S. Geological Survey. The field data were taken from steady-state studies of the Chattahoochee River in Georgia, the Willamette River in Oregon, and the Arkansas River in Colorado. The data used to evaluate the models covered a wide range of physical, chemical, and biological conditions. The Willamette River is a large sluggish stream, whereas the Arkansas River is a small dynamic stream. The Chattahoochee River is of moderate size. Each stream has unique water-quality characteristics that test a wide range of model options. (USGS)

Open-File Report↗
USGS1994

Surface-water-quality assessment of the Yakima River basin in Washington: major-and minor-element data for sediment, water, and aquatic biota, 1987-91

Major- and minor-element concentrations are presented for streambed and suspended sediment, filtered- and unfiltered-water, and aquatic-biota samples collected during 1987-91 from the Yakima River Basin in south-central Washington. The samples were collected as part of the U.S. Geological Survey's National Water-quality Assessment (NAWQA) program which is designed to provide results that are useful in understanding and managing the Nation's water resources. This report includes the sampling approach, field collection and processing techniques, and methods of chemical analysis, as well as a compilation of chemical data, statistical summaries, and quality- control data. These data may be used by scientists and resource managers to describe (1) spatial distribution of selected major and minor elements in sediment, water, and aquatic biota of the Yakima River Basin; (2) temporal variation for element concentrations in filtered water and in suspended sediment at selected sites; (3) suita- bility of surface water for preservation of aquatic life and protection of human health; and (4) major natural and anthropogenic sources of major and minor elements in the Yakima River Basin that affect observed water-quality conditions. Streambed-sediment samples were collected once from 27 sites in the basin during 1987-91. Suspended-sediment and filtered-water samples were collected monthly and during hydrologic events (including snowmelt and winter rainstorms) at seven sites, and filtered-water samples were collected at least once at an additional 37 sites during synoptic samplings. Unfiltered-water samples were collected at seven sites on a quarterly basis during 1987 only. Samples of aquatic plants were collected once in 1989, and aquatic insects, fish, and clams were collected from 34 sites three times during 1989-90.

Washington↗
USGS2006

Occurrence and distribution of mercury in the surficial aquifer, Long Neck Peninsula, Sussex County, Delaware, 2003–04

In January 2001, mercury (Hg) was detected (500 nanograms per liter, ng/L, or greater) in the distribution system of the Long Neck Water Company (LNWC), Pot Nets, Delaware. By April 2001, two LNWC production wells had been taken off-line because discharge concentrations of total mercury (HgT) either had exceeded or approached the Federal limit of 2,000 ng/L. From October 2003 through January 2005, the U.S. Geological Survey, Delaware Geological Survey, and Delaware Department of Natural Resources and Environmental Control conducted a cooperative study to (a) determine if the Hg contamination was widespread, (b) identify possible forms of Hg in ground water, and (c) examine Hg occurrence in relation to (geo)chemical conditions and characteristics of ground water and sediment in the surficial aquifer on the Long Neck Peninsula, Sussex County, Delaware. An initial water-quality survey conducted with samples from 22 production wells revealed that concentrations of HgT in ground water in the surficial aquifer ranged from 0.11 to 1,820 ng/L. Shallow ground water (less than 120 feet below land surface) throughout most of the peninsula, including that which contained elevated concentrations of HgT (exceeding 100 ng/L), appeared to be affected by human activities. All samples contained volatile organic compounds (VOCs) and elevated nitrate-nitrogen (NO3-N, exceeding 0.4 milligrams per liter, mg/L). Most (16 of 22) samples had elevated specific conductance (SC, in excess of 100 microsiemens per centimeter at 25 degrees Celsius). Elevated concentrations of HgT, however, only occurred in five production wells in the Pot Nets Bayside and Lakeside communities. The vertical distribution of HgT in shallow ground water (less than 80 feet below land surface) was determined with samples collected at 5 to 6 vertical-nest short-screened (2 - 5-foot length) monitoring wells installed near Bayside and Lakeside production wells with the highest HgT concentrations (exceeding 1,000 ng/L). Elevated concentrations ofHgT (100-6,380 ng/L) occurred in the shallow aquifer near each well at different depths. Chemical analyses of selected soil, fill, and aquifer sediment samples, obtained during the installation of nested wells, indicated that little HgT occurred in soil or fill at either site (40 micrograms per kilogram, ?g/kg, or less). No HgT was detected (less than 20 ?g/kg) in aquifer sediment samples. These low HgT concentrations imply that neither the soil, fill, nor aquifer sediment was a likely source of the elevated Hg in ground water. Given Hg occurrence appeared to be a ground-water transport phenomenon, the forms of Hg in transport were investigated. Differences in HgT concentrations between raw and filtered (0.1- and (or) 0.4-absolute micrometer pore size) samples from nested wells were random in sign and similar in magnitude to the variability in measuring HgT attributed to field and laboratory methods (? 5-10 percent, for HgT concentrations exceeding 100 ng/L). Thus, Hg transport likely occurred in a dissolved or fine-colloidal nonparticulate phase. Methyl mercury (HgMe) only was detected at low concentrations (0.06 ng/L or less) in nested-well samples with low to moderate concentrations of HgT (less than 366 ng/L). Whether HgMe occurred at similar concentrations in samples with high HgT concentrations was unresolved due to a sample-matrix interference problem. Potential complex forms of Hg were investigated in relation to the occurrence of selected ligands (organic carbon, sulfide, and chloride concentrations) and geochemical conditions (for example, pH and dissolved oxygen concentrations). Only dissolved organic carbon (DOC) appeared directly related to Hg occurrence. Elevated concentrations of HgT and DOC co-occurred in ground water at both Pot Nets sites. The average concentration of DOC was about four times greater in samples from the Pot Nets wells with the highest HgT concentrations (exceeding 1,000 ng/L) than in most Pot Nets o

Delaware↗
USGS2010

Characterization of water quality and biological communities, Fish Creek, Teton County, Wyoming, 2007-08

Fish Creek, a tributary to the Snake River, is about 25 river kilometers long and is located in Teton County in western Wyoming near the town of Wilson. Public concern about nuisance growths of aquatic plants in Fish Creek have been increasing in recent years. To address this concern, the U.S. Geological Survey conducted a study in cooperation with the Teton Conservation District to characterize the water quality and biological communities in Fish Creek. Water-quality samples were collected for analyses of physical properties and water chemistry (nutrients, nitrate isotopes, and wastewater chemicals) between March 2007 and October 2008 from seven surface-water sites and three groundwater wells. During this same period, aquatic plant and macroinvertebrate samples were collected and habitat characteristics were measured at the surface-water sites. The main objectives of this study were to (1) evaluate nutrient concentrations (that influence biological indicators of eutrophication) and potential sources of nutrients by using stable isotope analysis and other indicator chemicals (such as caffeine and disinfectants) that could provide evidence of anthropogenic sources, such as wastewater or septic tank contamination in Fish Creek and adjacent groundwater, and (2) characterize the algal, macrophyte, and macroinvertebrate communities and habitat of Fish Creek. Nitrate was the dominant species of dissolved nitrogen present in all samples and was the only bioavailable species detected at concentrations greater than the laboratory reporting level in all surface-water samples. Average concentrations of dissolved nitrate in surface water were largest in samples collected from the two sites with seasonal flow near Teton Village and decreased downstream; the smallest concentration was at downstream site A-Wck. Concentrations of dissolved nitrate in groundwater were consistently greater than concentrations in corresponding surface-water sites during the same sampling event. Orthophosphate was the primary dissolved species of phosphorus present in all surface-water and groundwater samples. The average concentration of dissolved orthophosphate in surface water was largest in samples collected from near Teton Village; samples from all other sites had similar average concentrations. Concentrations of dissolved orthophosphate in groundwater also were typically greater than concentrations in corresponding surface-water sites during the same sampling event. The aquatic plant communities in Fish Creek typically were composed of a mixture of macrophytes, macroalgae, microalgae, and moss. The composition of the aquatic plant community in Fish Creek appeared to shift in the downstream direction in 2007. On average, the proportion of macrophytes ranged from about 1 percent at site A-R1U, the most upstream site, to 54 percent of the plant community at site A-R6D, the farthest downstream site sampled during 2007. The downstream increase in macrophytes was accompanied by a downstream decrease in microalgae. The average proportion of microalgae ranged from 80 percent at site A-R1U to 24 percent at site A-R6D. The proportion of the macroalgae Cladophora in the aquatic plant community was relatively high at sites A-Wck and A-R3D in both 2007 and 2008.

Scientific Investigations Report↗
USGS2022

Groundwater-level altitudes and groundwater-flow direction and nature and extent of volatile and semivolatile organic compounds at Petro-Chemical Systems, Inc. (Turtle Bayou), Superfund site, Liberty County, Texas, 2020

The Petro-Chemical Systems, Inc. (Turtle Bayou), Superfund site is 15 miles southeast of Liberty, Texas, in Liberty County. Improper disposal of waste oils led to contamination of soil and groundwater at the site. In cooperation with the U.S. Environmental Protection Agency, the U.S. Geological Survey collected water-quality samples from 11 monitoring wells at the site, in particular the area near well MW-109A (the MW-109 area), in August and September 2020 and compared the water-quality results to the results from previous water-quality sampling events at the site in June 2016 and August 2018 with a focus on benzene concentrations. Contours of groundwater-level altitudes in the MW-109 area indicate that groundwater-flow direction is south-southeasterly in the eastern part and south-southwesterly in the western part. Of the 51 volatile organic compounds analyzed, 13 were detected in groundwater samples from 1 or more wells. In all but 1 well, MW-109A, concentrations of these compounds were less than 100 micrograms per liter. Benzene is still the principal contaminant of concern, as it persists at concentrations exceeding 53,000 micrograms per liter, although naphthalene also appears to be a contaminant of concern, as it was detected at the greatest concentration of any semivolatile organic compound analyte (1,100 micrograms per liter in the sample from well MW-109A).

Texas↗
USGS1991

Use of sediment-trace element geochemical models for the identification of local fluvial baseline concentrations

Studies have demonstrated the utility of fluvial bed sediment chemical data in assesing local water-quality conditions. However, establishing local background trace element levels can be difficult. Reference to published average concentrations or the use of dated cores are often of little use in small areas of diverse local petrology, geology, land use, or hydrology. An alternative approach entails the construction of a series of sediment-trace element predictive models based on data from environmentally diverse but unaffected areas. Predicted values could provide a measure of local background concentrations and comparison with actual measured concentrations could identify elevated trace elements and affected sites. Such a model set was developed from surface bed sediments collected nationwide in the United States. Tests of the models in a small Louisiana basin indicated that they could be used to establish local trace element background levels, but required recalibration to account for local geochemical conditions outside the range of samples used to generate the nationwide models.

Conference Paper↗