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At least 1,765 records · Page 98Linked to original sources
USGS1985

Low-temperature molar heat capacities and entropies of MnO2 (pyrolusite), Mn3O4 (hausmanite), and Mn2O3 (bixbyite)

Pyrolusite (MnO2), hausmanite (Mn3O4), and bixbyite (Mn2O3), are important ore minerals of manganese and accurate values for their thermodynamic properties are desirable to understand better the {p(O2), T} conditions of their formation. To provide accurate values for the entropies of these important manganese minerals, we have measured their heat capacities between approximately 5 and 380 K using a fully automatic adiabatically-shielded calorimeter. All three minerals are paramagnetic above 100 K and become antiferromagnetic or ferrimagnetic at lower temperatures. This transition is expressed by a sharp ??-type anomaly in Cpmo for each compound with Ne??el temperatures TN of (92.2??0.2), (43.1??0.2), and (79.45??0.05) K for MnO2, Mn3O4, and Mn2O3, respectively. In addition, at T ??? 308 K, Mn2O3 undergoes a crystallographic transition, from orthorhombic (at low temperatures) to cubic. A significant thermal effect is associated with this change. Hausmanite is ferrimagnetic below TN and in addition to the normal ??-shape of the heat-capacity maxima in MnO2 and Mn2O3, it has a second rounded maximum at 40.5 K. The origin of this subsidiary bump in the heat capacity is unknown but may be related to a similar "anomalous bump" in the curve of magnetization against temperature at about 39 K observed by Dwight and Menyuk.(1) At 298.15 K the standard molar entropies of MnO2, Mn3O4, and Mn2O3, are (52.75??0.07), (164.1??0.2), and (113.7??0.2) J??K-1??mol-1, respectively. Our value for Mn3O4 is greater than that adopted in the National Bureau of Standards tables(2) by 14 per cent. ?? 1985.

Journal of Chemical Thermodynamics↗
USGS1984

Transport and concentration controls for chloride, strontium, potassium and lead in Uvas Creek, a small cobble-bed stream in Santa Clara County, California, U.S.A.: 2. Mathematical modeling

Three models describing solute transport of conservative ion species and another describing transport of species which adsorb linearly and reversibly on bed sediments are developed and tested. The conservative models are based on three different conceptual models of the transient storage of solute in the bed. One model assumes the bed to be a well-mixed zone with flux of solute into the bed proportional to the difference between stream concentration and bed concentration. The second model assumes solute in the bed is transported by a vertical diffusion process described by Fick's law. The third model assumes that convection occurs in a selected portion of the bed while the mechanism of the first model functions everywhere. The model for adsorbing species assumes that the bed consists of particles of uniform size with the rate of uptake controlled by an intraparticle diffusion process. All models are tested using data collected before, during and after a 24-hr. pulse injection of chloride, strontium, potassium and lead ions into Uvas Creek near Morgan Hill, California, U.S.A. All three conservative models accurately predict chloride ion concentrations in the stream. The model employing the diffusion mechanism for bed transport predicts better than the others. The adsorption model predicts both strontium and potassium ion concentrations well during the injection of the pulse but somewhat overestimates the observed concentrations after the injection ceases. The overestimation may be due to the convection of solute deep into the bed where it is retained longer than the 3-week post-injection observation period. The model, when calibrated for strontium, predicts potassium equally well when the adsorption equilibrium constant for strontium is replaced by that for potassium.

California↗
USGS1984

Laboratory analysis and airborne detection of materials stimulated to luminesce by the sun

The Fraunhofer line discriminator (FLD) is an airborne electro-optical device used to image materials which have been stimulated to luminesce by the Sun. Such materials include uranium-bearing sandstone, sedimentary phosphate rock, marine oil seeps, and stressed vegetation. Prior to conducting an airborne survey, a fluorescence spectrometer may be used in the laboratory to determine the spectral region where samples of the target material exhibit maximum luminescence, and to select the optimum Fraunhofer line.

Journal of Luminescence↗
USGS1980

Geophysical investigations in deep horizontal holes drilled ahead of tunnelling

Deep horizontal drill holes have been used since 1967 by the Defense Nuclear Agency as a primary exploration tool for siting nuclear events in tunnels at the Nevada Test Site. The U.S. Geological Survey had developed geophysical logging techniques for obtaining resistivity and velocity in these holes, and to date 33 horizontal drill holes in excess of 300 m in depth have been successfully logged. The deepest hole was drilled to a horizontal depth of 1125 m. The purposes of the logging measurements are to define clay zones, because of the unstable ground conditions such zones can present to tunnelling, and to define zones of partially saturated rock, because of the attenuating effects such zones have on the shock wave generated by the nuclear detonation. Excessive attenuation is undesirable because the shock wave is used as a tunnel closure mechanism to contain debris and other undesirable explosion products. Measurements are made by pumping resistivity, sonic and geophone probes down the drill string and out of the bit into the open hole. Clay zones are defined by the electrical resistivity technique based on empirical data relating the magnitude of the resistivity measurement to qualitative clay content. Rock exhibiting resistivity of less than 20 ??-m is considered potentially unstable, and resistivities less than 10 ??-m indicate appreciable amounts of clay are present in the rock. Partially saturated rock zones are defined by the measurement of the rock sound speed. Zones in the rock which exhibit velocities less than 2450 m/sec are considered of potential concern. ?? 1980.

International Journal of Rock Mechanics and Mining↗
USGS1993

Borehole techniques identifying subsurface chimney heights in loose ground-some experiences above underground nuclear explosions

The location of the subsurface top of the chimney formed by the collapse of the cavity resulting from an underground nuclear explosion is examined at five sites at the Nevada Test Site. The chimneys were investigated by drilling, coring, geophysical logging (density, gamma-ray, caliper), and seismic velocity surveys. The identification of the top of the chimney can be complicated by chimney termination in friable volcanic rock of relatively high porosity. The presence of an apical void in three of the five cases is confirmed as the chimney horizon by coincidence with anomalies observed in coring, caliper and gamma-ray logging (two cases), seismic velocity, and drilling. In the two cases where an apical void is not present, several of these techniques yield anomalies at identical horizons, however, the exact depth of chimney penetration is subject to some degree of uncertainty. This is due chiefly to the extent to which core recovery and seismic velocity may be affected by perturbations in the tuff above the chimney due to the explosion and collapse. The data suggest, however, that the depth uncertainty may be only of the order of 10 m if several indicators are available. Of all indicators, core recovery and seismic velocity indicate anomalous horizons in every case. Because radiation products associated with the explosion are contained within the immediate vicinity of the cavity, gamma-ray logs are generally not diagnostic of chimney penetration. In no case is the denisty log indicative of the presence of the chimney. ?? 1993.

International Journal of Rock Mechanics and Mining↗
USGS1994

Disruption of Drift glacier and origin of floods during the 1989-1990 eruptions of Redoubt Volcano, Alaska

Melting of snow and glacier ice during the 1989–1990 eruption of Redoubt Volcano caused winter flooding of the Drift River. Drift glacier was beheaded when 113 to 121 × 10 6 m 3 of perennial snow and ice were mechanically entrained in hot-rock avalanches and pyroclastic flows initiated by the four largest eruptions between 14 December 1989 and 14 March 1990. The disruption of Drift glacier was dominated by mechanical disaggregation and entrainment of snow and glacier ice. Hot-rock avalanches, debris flows, and pyroclastic flows incised deep canyons in the glacier ice thereby maintaining a large ice-surface area available for scour by subsequent flows. Downvalley flow rheologies were transformed by the melting of snow and ice entrained along the upper and middle reaches of the glacier and by seasonal snowpack incorporated from the surface of the lower glacier and from the river valley. The seasonal snowpack in the Drift River valley contributed to lahars and floods a cumulative volume equivalent to about 35 × 10 6 m 3 of water, which amounts to nearly 30% of the cumulative flow volume 22 km downstream from the volcano. The absence of high-water marks in depressions and of ice-collapse features in the glacier indicated that no large quantities of meltwater that could potentially generate lahars were stored on or under the glacier; the water that generated the lahars that swept Drift River valley was produced from the proximal, eruption-induced volcaniclastic flows by melting of snow and ice.

Alaska↗
USGS2009

The Tiptop coal-mine fire, Kentucky: Preliminary investigation of the measurement of mercury and other hazardous gases from coal-fire gas vents

The Tiptop underground coal-mine fire in the Skyline coalbed of the Middle Pennsylvanian Breathitt Formation was investigated in rural northern Breathitt County, Kentucky, in May 2008 and January 2009, for the purpose of determining the concentrations of carbon dioxide (CO2), carbon monoxide (CO), and mercury (Hg) in the vent and for measuring gas-vent temperatures. At the time of our visits, concentrations of CO2 peaked at 2.0% and > 6.0% (v/v) and CO at 600 ppm and > 700 ppm during field analysis in May 2008 and January 2009, respectively. For comparison, these concentrations exceed the U.S. Occupational Safety & Health Administration (OSHA) eight-hour safe exposure limits (0.5% CO2 and 50 ppm CO), although the site is not currently mined. Mercury, as Hg0, in excess of 500 and 2100 μg/m3, in May and January, respectively, in the field, also exceeded the OSHA eight-hour exposure limit (50 μg/m3). Carbonyl sulfide, dimethyl sulfide, carbon disulfide, and a suite of organic compounds were determined at two vents for the first sampling event. All gases are diluted by air as they exit and migrate away from a gas vent, but temperature inversions and other meteorological conditions could lead to unhealthy concentrations in the nearby towns. Variation in gas temperatures, nearly 300 °C during the January visit to the fire versus < 50 °C in May, demonstrates the large temporal variability in fire intensity at the Tiptop mine. These preliminary results suggest that emissions from coal fires may be important, but additional data are required that address the reasons for significant variations in the composition, flow, and temperature of vent gases.

Kentucky↗
USGS2010

Coalbed methane resources of the Appalachian Basin, eastern USA

In 2002, the U.S. Geological Survey (USGS) assessed the technically recoverable, undiscovered coalbed-gas resources in the Appalachian basin and Black Warrior basin Assessment Provinces as about 15.5 trillion cubic feet. Although these resources are almost equally divided between the two areas, most of the production occurs within relatively small areas within these Provinces, where local geological and geochemical attributes have resulted in the generation and retention of large amounts of methane within the coal beds and have enhanced the producibility of the gas from the coal. In the Appalachian basin, coalbed methane (CBM) tests are commonly commercial where the cumulative coal thickness completed in wells is greater than three meters (10 ft), the depth of burial of the coal beds is greater than 100 m (350 ft), and the coal is in the thermogenic gas window. In addition to the ubiquitous cleating within the coal beds, commercial production may be enhanced by secondary fracture porosity related to supplemental fracture systems within the coal beds. In order to release the methane from microporus coal matrix, most wells are dewatered prior to commercial production of gas. Two Total Petroleum Systems (TPS) were defined by the USGS during the assessment: the Pottsville Coal-bed gas TPS in Alabama, and the Carboniferous Coal-bed Gas TPS in Pennsylvania, Ohio, West Virginia, eastern Kentucky, Virginia, Tennessee, and Alabama. These were divided into seven assessment units, of which three had sufficient data to be assessed. Production rates are higher in most horizontal wells drilled into relatively thick coal beds, than in vertical wells; recovery per unit area is greater, and potential adverse environmental impact is decreased.

Alabama, Georgia, Kentucky, Maryland, North Caroli↗
USGS2016

Potential effects of climate change on streamflow for seven watersheds in eastern and central Montana

Study region Eastern and central Montana. Study focus Fish in Northern Great Plains streams tolerate extreme conditions including heat, cold, floods, and drought; however changes in streamflow associated with long-term climate change may render some prairie streams uninhabitable for current fish species. To better understand future hydrology of these prairie streams, the Precipitation-Runoff Modeling System model and output from the RegCM3 Regional Climate model were used to simulate streamflow for seven watersheds in eastern and central Montana, for a baseline period (water years 1982–1999) and three future periods: water years 2021–2038 (2030 period), 2046–2063 (2055 period), and 2071–2088 (2080 period). New hydrological insights for the region Projected changes in mean annual and mean monthly streamflow vary by the RegCM3 model selected, by watershed, and by future period. Mean annual streamflows for all future periods are projected to increase (11–21%) for two of the four central Montana watersheds: Middle Musselshell River and Cottonwood Creek. Mean annual streamflows for all future periods are projected to decrease (changes of −24 to −75%) for Redwater River watershed in eastern Montana. Mean annual streamflows are projected to increase slightly (2–15%) for the 2030 period and decrease (changes of −16 to −44%) for the 2080 period for the four remaining watersheds.

Montana↗
USGS2017

Soil microbial community composition is correlated to soil carbon processing along a boreal wetland formation gradient

Climate change is modifying global biogeochemical cycles. Microbial communities play an integral role in soil biogeochemical cycles; knowledge about microbial composition helps provide a mechanistic understanding of these ecosystem-level phenomena. Next generation sequencing approaches were used to investigate changes in microbial functional groups during ecosystem development, in response to climate change, in northern boreal wetlands. A gradient of wetlands that developed following permafrost degradation was used to characterize changes in the soil microbial communities that mediate C cycling: a bog representing an “undisturbed” system with intact permafrost, and a younger bog and an older bog that formed following the disturbance of permafrost thaw. Reference 16S rRNA databases and several diversity indices were used to assess structural differences among these communities, to assess relationships between soil microbial community composition and various environmental variables including redox potential and pH. Rates of potential CO2 and CH4 gas production were quantified to correlate sequence data with gas flux. The abundance of organic C degraders was highest in the youngest bog, suggesting higher rates of microbial processes, including potential CH4 production. In addition, alpha diversity was also highest in the youngest bog, which seemed to be related to a more neutral pH and a lower redox potential. These results could potentially be driven by increased niche differentiation in anaerobic soils. These results suggest that ecosystem structure, which was largely driven by changes in edaphic and plant community characteristics between the “undisturbed” permafrost bog and the two bogs formed following permafrost thaw, strongly influenced microbial function.

European Journal of Soil Biology↗
USGS2016

Haemosporidian parasite infections in grouse and ptarmigan: Prevalence and genetic diversity of blood parasites in resident Alaskan birds

Projections related to future climate warming indicate the potential for an increase in the distribution and prevalence of blood parasites in northern regions. However, baseline data are lacking for resident avian host species in Alaska. Grouse and ptarmigan occupy a diverse range of habitat types throughout the northern hemisphere and are among the most well-known and important native game birds in North America. Information regarding the prevalence and diversity of haemosporidian parasites in tetraonid species is limited, with few recent studies and an almost complete lack of genetic data. To better understand the genetic diversity of haemosporidian parasites in Alaskan tetraonids and to determine current patterns of geographic range and host specificity, we used molecular methods to screen 459 tissue samples collected from grouse and ptarmigan species across multiple regions of Alaska for infection by Leucocytozoon, Haemoproteus, and Plasmodium blood parasites. Infections were detected in 342 individuals, with overall apparent prevalence of 53% for Leucocytozoon , 21% for Haemoproteus , and 9% for Plasmodium . Parasite prevalence varied by region, with different patterns observed between species groups (grouse versus ptarmigan). Leucocytozoon was more common in ptarmigan, whereas Haemoproteus was more common in grouse. We detected Plasmodium infections in grouse only. Analysis of haemosporidian mitochondrial DNA cytochrome b sequences revealed 23 unique parasite haplotypes, several of which were identical to lineages previously detected in other avian hosts. Phylogenetic analysis showed close relationships between haplotypes from our study and those identified in Alaskan waterfowl for Haemoproteus and Plasmodium parasites. In contrast, Leucocytozoon lineages were structured strongly by host family. Our results provide some of the first genetic data for haemosporidians in grouse and ptarmigan species, and provide an initial baseline on the prevalence and diversity of blood parasites in a group of northern host species.

Alaska↗
USGS2012

Estimating aboveground biomass in interior Alaska with Landsat data and field measurements

Terrestrial plant biomass is a key biophysical parameter required for understanding ecological systems in Alaska. An accurate estimation of biomass at a regional scale provides an important data input for ecological modeling in this region. In this study, we created an aboveground biomass (AGB) map at 30-m resolution for the Yukon Flats ecoregion of interior Alaska using Landsat data and field measurements. Tree, shrub, and herbaceous AGB data in both live and dead forms were collected in summers and autumns of 2009 and 2010. Using the Landsat-derived spectral variables and the field AGB data, we generated a regression model and applied this model to map AGB for the ecoregion. A 3-fold cross-validation indicated that the AGB estimates had a mean absolute error of 21.8 Mg/ha and a mean bias error of 5.2 Mg/ha. Additionally, we validated the mapping results using an airborne lidar dataset acquired for a portion of the ecoregion. We found a significant relationship between the lidar-derived canopy height and the Landsat-derived AGB (R 2 = 0.40). The AGB map showed that 90% of the ecoregion had AGB values ranging from 10 Mg/ha to 134 Mg/ha. Vegetation types and fires were the primary factors controlling the spatial AGB patterns in this ecoregion.

Alaska↗
USGS2014

Mummy Lake: An unroofed ceremonial structure within a large-scale ritual landscape

The structure at Mesa Verde National Park known historically as Mummy Lake and more recently as Far View Reservoir is not part of a water collection, impoundment, or redistribution system. We offer an alternative explanation for the function of Mummy Lake. We suggest that it is an unroofed ceremonial structure, and that it serves as an essential component of a Chacoan ritual landscape. A wide constructed avenue articulates Mummy Lake with Far View House and Pipe Shrine House. The avenue continues southward for approximately 6 km where it apparently divides connecting with Spruce Tree House and Sun Temple/Cliff Palace. The avenue has previously been interpreted as an irrigation ditch fed by water impounded at Mummy Lake; however, it conforms in every respect to alignments described as Chacoan roads. Tree-ring dates indicate that the construction of Spruce Tree House and Cliff Palace began about A.D. 1225, roughly coincident with the abandonment of the Far View community. This pattern of periodically relocating the focus of an Anasazi community by retiring existing ritual structures and linking them to newly constructed facilities by means of broad avenues was first documented by Fowler and Stein (1992) in Manuelito Canyon, New Mexico. Periods of intense drought appear to have contributed to the relocation of prehistoric Native Americans from the Far View group to Cliff Palace/Spruce Tree House in the mid-13th century and eventually to the abandonment of all Anasazi communities in southwestern Colorado in the late-13th century.

Journal of Archaeological Science↗
USGS2019

Stormwater-quality performance of line permeable pavement systems

Three permeable pavements were evaluated for their ability to improve the quality of stormwater runoff over a 22-month period in Madison, Wisconsin. Using a lined system with no internal water storage, permeable interlocking concrete pavers (PICP), pervious concrete (PC), and porous asphalt (PA) were able to significantly remove sediment and sediment-bound pollutant loads from runoff originating from an asphalt parking lot five times larger than the receiving permeable pavement area. Reductions in total suspended solids were similar for all three surfaces at approximately 60 percent. Clogging occurred after approximately one year, primarily due to winter sand application that led to high sediment load in spring runoff. Winter road salt application resulted in high chloride load that was initially attenuated in all three permeable pavements but later released during subsequent spring runoff events. Total phosphorus load was reduced by nearly 20 percent for PICP and PA, and 43 percent for PC. These values were likely tempered by the export of dissolved phosphorus observed in PICP and PA, but not PC. Average removal efficiencies for metals were 40, 42, and 49 percent in PA, PICP, and PC, respectively. A median pH of 10.2 in PC effluent could explain elevated removal efficiency of phosphorus and select metals in PC over PICP and PA (median = 7.5 and 7.8, respectfully) through enhanced precipitation. Elevated pH values in PC may also have led to higher removal efficiencies for select metals than PICP or PA. The environmental benefits as well as potential unintended consequences of stormwater practices like permeable pavement that utilize infiltration as a form of treatment warrant consideration in management of urban runoff.

Wisconsin↗
USGS2021

Distribution, abundance and spatial variability of microplastic pollution on the surface of Lake Superior

In 2014, 94 paired neuston net samples (0.5 mm mesh) were collected from the surface waters of Lake Superior. These samples comprise the most comprehensive surface water survey for microplastics of any of the Great Lakes to date, and the first to employ double net trawls. Microplastic abundance estimates showed wide variability, ranging between 4000 to more than 100,000 particles/km 2 with most locations having abundances between 20,000 to 50,000 particles/km 2 . The average abundance in Lake Superior was ~30,000 particles/km 2 which was similar to previous estimates within this Laurentian Great Lake and suggests a total count of more than 2.4 billion (1.7 to 3.3 billion, 95% confidence interval) particles across the lake’s surface. Distributions of plastic particles, characterized by size fraction and type, differed between nearshore and offshore samples, and between samples collected in the eastern versus western portion of the lake. Most of the particles found were fibers (67%), and most (62%) were contained in the smallest classified size fraction (0.50–1 mm). The most common type of polymer found was polyethylene (51%), followed by polypropylene (19%). This is consistent with global plastics production and results obtained from other studies. No statistically significant difference was detected between the paired net samples, indicating that single net sampling should produce a representative estimate of microplastic particle abundance and distribution within a body of water.

Lake Superior↗
USGS2023

Does hatchery rearing of lake trout affect their reproductive behavior in the wild?

Stocking of hatchery-reared fishes has been used with variable success as a management action to promote the recovery of populations and species. The practice has been controversial for several reasons, including uncertainty about whether the hatchery rearing experience may affect reproduction after release. Fine-scale acoustic telemetry was used during three spawning seasons to test whether hatchery rearing affects the reproductive behavior of lake trout using a spawning shoal complex in northern Lake Huron. Within sex, wild- and hatchery-reared fish behaved similarly, but significant behavioral differences occurred between sexes. Lake trout of both sexes moved synchronously onto the spawning shoals at the completion of autumn thermal turnover and occupied the same spawning sites (confirmed visually by presence of fertilized eggs) on the shoals. Male lake trout tended to congregate directly on spawning sites, with duration of occupancy varying greatly among years. Female lake trout spent less time on spawning shoals than males and congregated less at spawning sites on shoals. Most fish visited multiple spawning sites among shoals per season, with many making multiple transits among individual spawning sites. We found no evidence to support the hypothesis that hatchery rearing impairs spawning behavior of lake trout and, therefore, conclude that behavior deficiencies on the spawning ground are likely not an impediment to rehabilitation of lake trout in northern Lake Huron. Our study narrows the field of possible impediments to lake trout rehabilitation in the Great Lakes and provides insights that expand the conceptual model of lake trout spawning behavior.

Michigan↗
USGS2008

Estimating groundwater recharge in Hebei Plain, China under varying land use practices using tritium and bromide tracers

Tritium and bromide were used as applied tracers to determine groundwater recharge in Hebei Plain, North China, to evaluate the impacts of different soil types, land use, irrigation, and crop cultivation practice on recharge. Additional objectives were to evaluate temporal variability of recharge and the effect on results of the particular tracer used. Thirty-nine profiles at representative locations were chosen for investigation. Average recharge rates and recharge coefficient determined by tritium and bromide tracing for different sites were 0.00-1.05 mm/d and 0.0-42.5%, respectively. The results showed relative recharge rates for the following paired influences (items within each pair are listed with the influence producing greater recharge first): flood-irrigated cropland and non-irrigated non-cultivation land, flood irrigation (0.42-0.58 mm/d) and sprinkling irrigation (0.17-0.23 mm/d), no stalk mulch (0.56-0.80 mm/d) and stalk mulch (0.44-0.60 mm/d), vegetable (e.g. Chinese cabbage and garlic, 0.70 mm/d) and wheat-maize (0.38 mm/d), peanut (0.51 mm/d) and peach (0.43 mm/d). The results also showed greater recharge for the first year of tracer travel than for the second. Because total precipitation and irrigation were greater in the first year than in the second, this may reflect temporal variability of recharge. The method may not be applicable where the water table is shallow (less than 3 m). A comparison of the near-ideal tritium tracer with the more common but less ideal bromide showed that bromide moved approximately 23% faster than tritiated water, perhaps because of anion exclusion. ?? 2008 Elsevier B.V.

Journal of Hydrology↗