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USGS2016

Groundwater level trends and drivers in two northern New England glacial aquifers

We evaluated long-term trends and predictors of groundwater levels by month from two well-studied northern New England forested headwater glacial aquifers: Sleepers River, Vermont, 44 wells, 1992-2013; and Hubbard Brook, New Hampshire, 15 wells, 1979-2004. Based on Kendall Tau tests with Sen slope determination, a surprising number of well-month combinations had negative trends (decreasing water levels) over the respective periods. Sleepers River had slightly more positive than negative trends overall, but among the significant trends ( p < 0.1), negative trends dominated 67 to 40. At Hubbard Brook, negative trends outnumbered positive trends by a nearly 2:1 margin and all seven of the significant trends were negative. The negative trends occurred despite generally increasing trends in monthly and annual precipitation. This counterintuitive pattern may be a result of increased precipitation intensity causing higher runoff at the expense of recharge, such that evapotranspiration demand draws down groundwater storage. We evaluated predictors of month-end water levels by multiple regression of 18 variables related to climate, streamflow, snowpack, and prior month water level. Monthly flow and prior month water level were the two strongest predictors for most months at both sites. The predictive power and ready availability of streamflow data can be exploited as a proxy to extend limited groundwater level records over longer time periods.

New Hampshire, Vermont↗

USGS2011

Field verification of stable perched groundwater in layered bedrock uplands

Data substantiating perched conditions in layered bedrock uplands are rare and have not been widely reported. Field observations in layered sedimentary bedrock in southwestern Wisconsin, USA, provide evidence of a stable, laterally extensive perched aquifer. Data from a densely instrumented field site show a perched aquifer in shallow dolomite, underlain by a shale‐and‐dolomite aquitard approximately 25 m thick, which is in turn underlain by sandstone containing a 30‐m‐thick unsaturated zone above a regional aquifer. Heads in water supply wells indicate that perched conditions extend at least several kilometers into hillsides, which is consistent with published modeling studies. Observations of unsaturated conditions in the sandstone over a 4‐year period, historical development of the perched aquifer, and perennial flow from upland springs emanating from the shallow dolomite suggest that perched groundwater is a stable hydrogeologic feature under current climate conditions. Water‐table hydrographs exhibit apparent differences in the amount and timing of recharge to the perched and regional flow systems; steep hydraulic gradients and tritium and chloride concentrations suggest there is limited hydraulic connection between the two. Recognition and characterization of perched flow systems have practical importance because their groundwater flow and transport pathways may differ significantly from those in underlying flow systems. Construction of multi‐aquifer wells and groundwater withdrawal in perched systems can further alter such pathways.

Wisconsin↗

USGS2012

Assessing the relative bioavailability of DOC in regional groundwater systems

It has been hypothesized that the degree to which a hyperbolic relationship exists between concentrations of dissolved organic carbon (DOC) and dissolved oxygen (DO) in groundwater may indicate the relative bioavailability of DOC. This hypothesis was examined for 73 different regional aquifers of the United States using 7745 analyses of groundwater compiled by the National Water Assessment (NAWQA) program of the U.S. Geological Survey. The relative reaction quotient (RRQ), a measure of the curvature of DOC concentrations plotted versus DO concentrations and regressed to a decaying hyperbolic equation, was used to assess the relative bioavailability of DOC. For the basalt aquifer of Oahu, Hawaii, RRQ values were low (0.0013 mM −2 ), reflecting a nearly random relationship between DOC and DO concentrations. In contrast, on the island of Maui, treated sewage effluent injected into a portion of the basalt aquifer resulted in pronounced hyperbolic DOC-DO behavior and a higher RRQ (142 mM −2 ). RRQ values for the 73 aquifers correlated positively with mean concentrations of ammonia, dissolved iron, and manganese, and correlated negatively with mean pH. This indicates that greater RRQ values are associated with greater concentrations of the final products of microbial reduction reactions. RRQ values and DOC concentrations were negatively correlated with the thickness of the unsaturated zone (UNST) and depth to the top of the screened interval. Finally, RRQ values were positively correlated with mean annual precipitation (MAP), and the highest observed RRQ values were associated with aquifers receiving MAP rates ranging between 900 and 1300 mm/year. These results are uniformly consistent with the hypothesis that the hyperbolic behavior of DOC-DO plots, as quantified by the RRQ metric, can be an indicator of relative DOC bioavailability in groundwater systems.

Ground Water↗

USGS2011

Application of a new vertical profiling tool (ESASS) for sampling groundwater quality during hollow-stem auger drilling

A new tool called ESASS (Enhanced Screen Auger Sampling System) was developed by the U.S. Geological Survey. The use of ESASS, because of its unique U.S. patent design (U.S. patent no. 7,631,705 B1), allows for the collection of representative, depth-specific groundwater samples (vertical profiling) in a quick and efficient manner using a 0.305-m long screen auger during hollow-stem auger drilling. With ESASS, the water column in the flights above the screen auger is separated from the water in the screen auger by a specially designed removable plug and collar. The tool fits inside an auger of standard inner diameter (82.55 mm). The novel design of the system constituted by the plug, collar, and A-rod allows the plug to be retrieved using conventional drilling A-rods. After retrieval, standard-diameter (50.8 mm) observation wells can be installed within the hollow-stem augers. Testing of ESASS was conducted at one waste-disposal site with tetrachloroethylene (PCE) contamination and at two reference sites with no known waste-disposal history. All three sites have similar geology and are underlain by glacial, stratified-drift deposits. For the applications tested, ESASS proved to be a useful tool in vertical profiling of groundwater quality. At the waste site, PCE concentrations measured with ESASS profiling at several depths were comparable (relative percent difference <25%) to PCE concentrations sampled from wells. Vertical profiling with ESASS at the reference sites illustrated the vertical resolution achievable in the profile system; shallow groundwater quality varied by a factor of five in concentration of some constituents (nitrate and nitrite) over short (0.61 m) distances.

Ground Water Monitoring and Remediation↗

USGS2012

Estimating contributions of nitrate and herbicides from groundwater to headwater streams, northern Atlantic Coastal Plain, USA

Groundwater transport often complicates understanding of surface-water contamination. We estimated the regional flux of nitrate and selected herbicides from groundwater to nontidal headwater streams of the Atlantic Coastal Plain (New Jersey through North Carolina) based on late-winter or spring base-flow samples from 174 streams. Sampled streams were selected randomly, and flux estimates are based on resulting population estimates rather than on empirical models, which have been used previously for similar estimates. Base-flow flux in the estimated 8,834 headwater streams of the study area are an estimated 21,200 kg/day of nitrate (as N) and 5.83, 0.565, and 20.7 kg/day of alachlor, atrazine, and metolachlor (and selected degradates), respectively. Base-flow flux of alachlor and metolachlor is <3% of the total base-flow flux of those compounds plus degradates. Base-flow flux of nitrate and herbicides as a percentage of applications is typically highest in well-drained areas and lowest in areas with abundant poor drainage and anoxic conditions. In Coastal Plain watersheds of Albemarle and Pamlico Sounds, <2% of applied nitrogen reaches headwater streams as base flow. On the Delmarva Peninsula part of the Chesapeake Bay watershed, however, more than 10% of such applications are transported through groundwater to streams, and base-flow nitrate flux represents 70% of total nitrogen flux in headwater streams.

Northern Atlantic Coastal Plain↗

USGS2002

Flow and storage in groundwater systems

The dynamic nature of groundwater is not readily apparent, except where discharge is focused at springs or where recharge enters sinkholes. Yet groundwater flow and storage are continually changing in response to human and climatic stresses. Wise development of groundwater resources requires a more complete understanding of these changes in flow and storage and of their effects on the terrestrial environment and on numerous surface-water features and their biota.

Science↗

USGS1995

Transport behavior of groundwater protozoa and protozoan-sized microspheres in sandy aquifer sediments

Transport behaviors of unidentified flagellated protozoa (flagellates) and flagellate-sized carboxylated microspheres in sandy, organically contaminated aquifer sediments were investigated in a small-scale (1 to 4-m travel distance) natural-gradient tracer test on Cape Cod and in flow-through columns packed with sieved (0.5-to 1.0-mm grain size) aquifer sediments. The minute (average in situ cell size, 2 to 3 μ m) flagellates, which are relatively abundant in the Cape Cod aquifer, were isolated from core samples, grown in a grass extract medium, labeled with hydroethidine (a vital eukaryotic stain), and coinjected into aquifer sediments along with bromide, a conservative tracer. The 2- μ m flagellates appeared to be near the optimal size for transport, judging from flowthrough column experiments involving a polydispersed (0.7 to 6.2 μ m in diameter) suspension of carboxylated microspheres. However, immobilization within the aquifer sediments accounted for a log unit reduction over the first meter of travel compared with a log unit reduction over the first 10 m of travel for indigenous, free-living groundwater bacteria in earlier tests. High rates of flagellate immobilization in the presence of aquifer sediments also was observed in the laboratory. However, immobilization rates for the laboratory-grown flagellates (initially 4 to 5 μ m) injected into the aquifer were not constant and decreased noticeably with increasing time and distance of travel. The decrease in propensity for grain surfaces was accompanied by a decrease in cell size, as the flagellates presumably readapted to aquifer conditions. Retardation and apparent dispersion were generally at least twofold greater than those observed earlier for indigenous groundwater bacteria but were much closer to those observed for highly surface active carboxylated latex microspheres. Field and laboratory results suggest that 2- μ m carboxylated microspheres may be useful as analogs in investigating several abiotic aspects of flagellate transport behavior in groundwater.

Massachusetts↗

USGS2008

Assessing deep-seated landslide susceptibility using 3-D groundwater and slope-stability analyses, southwestern Seattle, Washington

In Seattle, Washington, deep-seated landslides on bluffs along Puget Sound have historically caused extensive damage to land and structures. These large failures are controlled by three-dimensional (3-D) variations in strength and pore-water pressures. We assess the slope stability of part of southwestern Seattle using a 3-D limit-equilibrium analysis coupled with a 3-D groundwater flow model. Our analyses use a high-resolution digital elevation model (DEM) combined with assignment of strength and hydraulic properties based on geologic units. The hydrogeology of the Seattle area consists of a layer of permeable glacial outwash sand that overlies less permeable glacial lacustrine silty clay. Using a 3-D groundwater model, MODFLOW-2000, we simulate a water table above the less permeable units and calibrate the model to observed conditions. The simulated pore-pressure distribution is then used in a 3-D slope-stability analysis, SCOOPS, to quantify the stability of the coastal bluffs. For wet winter conditions, our analyses predict that the least stable areas are steep hillslopes above Puget Sound, where pore pressures are elevated in the outwash sand. Groundwater flow converges in coastal reentrants, resulting in elevated pore pressures and destabilization of slopes. Regions predicted to be least stable include the areas in or adjacent to three mapped historically active deep-seated landslides. The results of our 3-D analyses differ significantly from a slope map or results from one-dimensional (1-D) analyses.

Washington↗

USGS2013

Groundwater–surface-water exchange and the geologic setting of northern Minnesota's lakes, wetlands, and streams—Modern-day relevance of Tom Winter's legacy

Tom Winter spent nearly 50 years conducting research in earth science, and he specialized in the exchange between groundwater and surface water. Tom's highly productive career began in Minnesota. This fi eld trip revisits many of the places where Tom conducted his early research and demonstrates the continuing relevance of that research. Stops and topics include the groundwater infl uence on the record low stage of White Bear Lake, the contribution of groundwater to continually rising water levels in an abandoned open-pit iron mine, hydrogeology of the Shingobee headwaters aquatic ecosystem research site, hydrogeology of Lake Sallie, geology associated with the Pillager water gap, and the hydrogeology of Little Rock Lake.

GSA Field Guides↗

USGS2015

Widespread groundwater-level offsets caused by the M w 5.8 Mineral, Virginia, earthquake of 23 August 2011

Groundwater levels were offset in bedrock observation wells, measured by the U.S. Geological Survey or others, as far as 553 km from the M w 5.8 Mineral, Virginia (USA), earthquake on 23 August 2011. Water levels dropped as much as 0.47 m in 34 wells and rose as much as 0.15 m in 12 others. In some wells, which are as much as 213 m deep, the water levels recovered from these deviations in hours to days, but in others the water-level offset may have persisted. The groundwater-level offsets occurred in locations where the earthquake was at least weakly felt, and the maximum water-level excursion increased with felt intensity, independent of epicentral distance. Coseismic static strain from the earthquake was too small and localized to have contributed significantly to the groundwater-level offsets. The relation with intensity is consistent with ground motion from seismic waves leading to the water-level offsets. Examination of the hydrographs indicates that short-period ground motion most likely affected the permeability of the bedrock aquifers monitored by the wells.

GSA Special Papers↗

USGS2018

Concentrations of pharmaceuticals and other micropollutants in groundwater downgradient from large on-site wastewater discharges

Large subsurface treatment systems (LSTS) and rapid infiltration basins (RIB) are preferred onsite wastewater treatments compared to direct discharge of treated wastewater to streams and adjacent facilities. Discharge of these wastewater treatments may result in contaminant loading to aquifers that also serve as drinking water sources downgradient from the discharge site. Until recently, few studies have characterized the contribution of micropollutants (e.g. pharmaceuticals, fragrances, flame retardants, etc.) to receiving aquifers. We conducted a pilot project to characterize the occurrence of micropollutants in groundwater downgradient from 7 on-site treatment systems in Minnesota, USA: 5 community LSTS and 2 municipal RIB. One downgradient monitoring well was sampled three times at each facility over one year. Of 223 micropollutants analyzed, 35 were detected. Total sample concentrations ranged from 90 to 4,039 ng/L. Sulfamethoxazole (antibiotic) was detected in all samples at concentrations from 7 to 965 ng/L. Other pharmaceuticals (0.12–1,000 ng/L), organophosphorus flame retardants (10–500 ng/L), and other anthropogenic chemicals (4–775 ng/L) were also detected. The numbers and concentrations of micropollutants detected were inversely related to dissolved oxygen and depth to water. Ratios of pharmaceutical concentrations to human-health screening values were <0.10 for most samples. However, concentrations of carbamazepine and sulfamethoxazole exceeded screening values at two sites. Study results illustrate that large on-site wastewater systems designed to discharge to permeable soil or shallow groundwater effectively deliver pharmaceuticals and other micropollutants to groundwater aquifers and could contribute micropollutants to drinking water via water supply wells.

Minnesota↗

USGS2004

Mapping saline groundwater beneath the Sea Galilee and its vicinity using time domain electromagnetic (TDEM) geophysical technique

An extensive time domain electromagnetic (TDEM) survey covering the Sea of Galilee with a dense grid of points has been recently carried out. A total of 269 offshore and 33 supplementary onshore TDEM soundings were performed along six N-S and ten W-E profiles and at selected points both offshore and onshore along the whole coastal line. The interpreted resistivities were calibrated with the direct salinity measurements in the Haon-2 borehole and relatively deep (5 m) cores taken from the lake bottom. It was found that resistivities below 1 ohm-m are solely indicative of groundwater salinity exceeding 10,000 mg Cl/l. Such low resistivities (high salinities) were detected at depths greater than 15 m below almost the entire bottom of the lake. At some parts of the lake, particularly in the south, the saline water was detected at shallower depths, sometimes at a few meters below the bottom. Relatively high resistivity (fresh groundwater) was found along the margins of the lake down to roughly 100 m, the maximum exploration depth of the system. The detected sharp lateral contrasts at the lake margin between high and low resistivities coincide with the faults separating the carbonate and clastic units, respectively. The geometry of the fresh/saline groundwater interface below the central part of the lake is very similar to the shape of the lake bottom, probably due to the diffusive salt transport from the bottom sediments to the lake water. The above geophysical observations suggest differentsalt transport mechanisms from the sediments to the central part of the lake (diffusion) and from regional aquifers to the margins of the lake (advection). ?? 2004 Science From Israel/LPPLtd.

Israel Journal of Earth Sciences↗

USGS2024

Self-guided decision support groundwater modelling with Python

The GMDSI tutorial notebooks repository provides learners with a comprehensive set of tutorials for self-guided training on decision-support groundwater modelling using Python-based tools. Although targeted at groundwater modelling, they are based around model-agnostic tools and readily transferable to other environmental modelling workflows. The tutorials are divided into three parts. The first covers fundamental theoretical concepts. These are intended as background reading for reference on an as-needed basis. Tutorials in the second part introduce learners to some of the core concepts parameter estimation in a groundwater modelling context, as well as providing a gentle introduction to the PEST, PEST++ and pyEMU software. Lastly, the third part demonstrates how to implement highly-parameterized applied decision-support modelling workflows. The tutorials aim to provide examples of both “how to use” the software as well as “how to think” about using the software. A key advantage to using notebooks in this context is that the workflows described run the same code as practitioners would run on a large-scale real- world application. Using a small synthetic model facilitates rapid progression through the workflow.

Journal of Open Source Education↗

USGS2005

Using multiple chemical indicators to assess sources of nitrate and age of groundwater in a karstic spring basin

Human health and ecological concerns have arisen due to a steady increase in nitrate-N concentrations during the past 40 years in Fannin Springs (0.3-4.7 mg/L), a regional discharge point with an average flow of >2.8 m3/second (>100 ft3/second) for water from the karstic Upper Floridan aquifer (UFA). Multiple chemical indicators (major dissolved species, 15N and 18O of nitrate, dissolved gases, 78 pesticides and degradates, and 67 organic compounds typically found in domestic and industrial wastewater) and transient tracers (3H/3He, chlorofluorocarbons [CFCs], sulfur hexafluoride [SF6]) were analyzed in water samples from nine wells along three transects and in spring water to assess groundwater age and potential contaminant sources. Land use is predominantly agricultural (52 percent) and forest (31 percent) in the 320 km2 (124 mi2) spring basin, which was delineated from a potentiometric-surface map of the UFA using high-resolution water-level data. Nitrate-N concentrations were highly variable in the oxic UFA and ranged from <0.02 to 4.7 mg/L. ?? 15N-NO3 values (3.4-9.9 per mil) indicated that nitrate contamination originated from inorganic sources (synthetic fertilizer) and organic sources (manure spreading or waste disposal). Higher nitrate concentrations and the younger age of spring water relative to water from upgradient wells indicate better communication with N sources at the surface. Apparent ages of groundwater correlated positively with well depth (P < 0.05) and were younger in water from wells nearer to the spring (<8 years) compared with other wells (10-50 years). Most transient tracer concentrations were consistent with binary mixing curves representing mixtures of water recharged during the past 10 years and older water (recharged before 1940). Young water mixing fractions ranged from 0.07 to 0.90. Trace levels of herbicides found in groundwater and spring water were indicative of applications for vegetative control in agricultural and other land-use types.

Environmental & Engineering Geoscience↗

USGS2015

Ground-truthing electrical resistivity methods in support of submarine groundwater discharge studies: Examples from Hawaii, Washington, and California

Submarine groundwater discharge (SGD) is an important conduit that links terrestrial and marine environments. SGD conveys both water and water-borne constituents into coastal waters, where these inflows may impact near-shore ecosystem health and sustainability. Multichannel electrical resistivity techniques have proven to be a powerful tool to examine scales and dynamics of SGD and SGD forcings. However, there are uncertainties both in data aquisition and data processing that must be addressed to maximize the effectiveness of this tool in estuarine or marine environments. These issues most often relate to discerning subtle nuances in the flow of electricity through variably saturated media that can also be highly conductive ( i.e., seawater). Three contrasting field sites were examined for this study to assess the effectiveness of electrical resistivity techniques in varying coastal settings by comparing resistivity data to direct salinity and resistivity observations, quantifying changes in lithology and beach geomorphology, and fine-tuning inversion protocols. The three study sites all have substantial (up to 85 cm day −1 ) submarine groundwater discharge rates, but the hydrologic, oceanographic, and geologic characteristics of the sites are all very different. At a site in Pelekane Bay on the Big Island of Hawaii, seasonal flooding introduces very high concentrations of fine to coarse sediment into the bay. Near-shore circulation is limited in Pelekane Bay, so this newly introduced sediment can become deposited in the bay where it accumulates over time. At a site in Hood Canal, a fjord within Puget Sound, Washington, SGD rates can be high because of the large tidal range, abundant recharge, and steep hydrologic gradients. At Younger Lagoon in northern California, the flow of groundwater towards the coast is much more parsimonious, but here marine processes, including recirculated seawater, are important in controlling the flow of material towards the coast. Rigorous ground-truthing at each field site showed that multi-channel electrcial resistivity techniques can reproduce the scales and dynamics of a seepage field when such data are correctly collected, and when the model inversions are tuned to field site characteristics. Such information can provide a unique perspective on the scales and dynamics of exchange processes within a coastal aquifer—information essential to scientists and resource managers alike.

California, Hawaii, Washington↗

USGS1996

Uncertainty of groundwater vulnerability assessments for agricultural regions in Hawaii: Review

There are important challenges associated with assessing potential groundwater vulnerability hazards that may result from regional scale applications of agrochemicals. The increasing availability of Geographic Information System (GIS) software to those involved in assisting with landuse decisions has resulted in the widespread production of multicolored risk management maps for many environmentally sensitive issues. Soil-based GIS's have recently been coupled to various solute-leaching models to make near-surface groundwater vulnerability assessments for guidance in pesticide regulation in several states. In general, these assessments rest on soil, climatic, and chemical data that are extremely sparse and contain considerable uncertainty. It is also important to acknowledge the uncertainty associated with the transport/fate processes that are not accounted for by the modeling approach used to make the assessment. In this paper, we review the results from a series of papers that have focused on characterization of uncertainty in pesticide mobility estimates, using the attenuation and retardation indices (AF and RF), for the Pearl Harbor Basin on the Hawaiian island of Oahu. Relative to data error uncertainties, we discuss the impacts of: (i) soil, climatic, and chemical data base uncertainties, (ii) reductions in data base uncertainties, (iii) extrapolation of soil data base information based on soil taxonomy and soil survey, and (iv) importing information from outside the region of interest. Relative to model error uncertainties, we compare pesticide leaching estimates from the simple AF and RF mobility indices with simulations from the EPA's Pesticide Root Zone Model (PRZM) and field observations. Finally, we outline a Regional Integrated Risk Assessment approach for characterizing regional scale groundwater vulnerability for near-surface nonpoint sources.

Hawaii↗

USGS2014

A screening tool for delineating subregions of steady recharge within groundwater models

We have developed a screening method for simplifying groundwater models by delineating areas within the domain that can be represented using steady-state groundwater recharge. The screening method is based on an analytical solution for the damping of sinusoidal infiltration variations in homogeneous soils in the vadose zone. The damping depth is defined as the depth at which the flux variation damps to 5% of the variation at the land surface. Groundwater recharge may be considered steady where the damping depth is above the depth of the water table. The analytical solution approximates the vadose zone diffusivity as constant, and we evaluated when this approximation is reasonable. We evaluated the analytical solution through comparison of the damping depth computed by the analytic solution with the damping depth simulated by a numerical model that allows variable diffusivity. This comparison showed that the screening method conservatively identifies areas of steady recharge and is more accurate when water content and diffusivity are nearly constant. Nomograms of the damping factor (the ratio of the flux amplitude at any depth to the amplitude at the land surface) and the damping depth were constructed for clay and sand for periodic variations between 1 and 365 d and flux means and amplitudes from nearly 0 to 1 × 10 −3 m d −1 . We applied the screening tool to Central Valley, California, to identify areas of steady recharge. A MATLAB script was developed to compute the damping factor for any soil and any sinusoidal flux variation.

California↗

USGS2015

Groundwater data network interoperability

Water data networks are increasingly being integrated to answer complex scientific questions that often span large geographical areas and cross political borders. Data heterogeneity is a major obstacle that impedes interoperability within and between such networks. It is resolved here for groundwater data at five levels of interoperability, within a Spatial Data Infrastructure architecture. The result is a pair of distinct national groundwater data networks for the United States and Canada, and a combined data network in which they are interoperable. This combined data network enables, for the first time, transparent public access to harmonized groundwater data from both sides of the shared international border.

Journal of Hydroinformatics↗