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Hydrogeology and ground-water flow at Levee 31N, Miami-Dade County, Florida, July 2003 to May 2004: As part of the Comprehensive Everglades Restoration Plan

Introduction The Levee 31N Seepage Management Pilot Project began in 2001, as part of the Comprehensive Everglades Restoration Plan (CERP). The pilot project seeks to determine the appropriate technology needed to control seepage from Everglades National Park (ENP), and provide the appropriate amount of ground-water flow to minimize potential impacts to the West Well Field and Biscayne Bay. To meet these needs, a levee cut-off wall (vertical subsurface barrier) has been proposed along Levee 31N in Miami-Dade County to reduce seepage flow from ENP. During the wet season, ground water would be captured by wells adjacent to Levee 31N and diverted into a buffer area adjacent to ENP where sheetflow would be reestablished. An integrated, multidisciplinary investigation of ground-water flow is currently in progress by the South Florida Water Management District (SFWMD) and U.S. Army Corps of Engineers as part of the Levee 31N Seepage Management Pilot Project. Pre-seepage pilot wall ground-water flow patterns are being assessed through use of in situ heat-pulse flowmeter measurements, monitoring the vertical changes in hydraulic head and temperature, ground-water age dating, and measurement of the vertical change in ambient ground-water quality. A high-resolution hydrogeologic framework is needed as part of this effort. In 2003, the U.S. Geological Survey (USGS) initiated a study to characterize the surficial aquifer system in detail to a depth of about 100 feet below ground level in the Levee 31N study area, and to delineate karst preferential ground-water flow zones. This study was part of a cooperative agreement between the USGS and the SFWMD (USGS Joint Funding Agreement No. 04E0FL208011 and SFWMD Agreement No. CPO40324), and funded through CERP.

Florida↗

Ground-water resources of coastal Citrus, Hernando, and southwestern Levy counties, Florida

Ground water in the coastal parts of Citrus, Hernando, and Levy Counties is obtained almost entirely from the Floridan aquifer. The aquifer is unconfined near the coast and semiconfined in the ridge area. Transmissivity ranges from 20,000 feet squared per day in the ridge area to greater than 2,000,000 feet squared per day near major springs. Changes in the potentiometric surface of the aquifer are small between the wet and dry seasons. Water quality within the study area is generally very good except immediately adjacent to the coast where saltwater from the Gulf of Mexico poses a threat to freshwater supply. This threat can be compensated for by placing well fields a sufficient distance away from the zone of transition from saltwater to freshwater so as not to reduce or reverse the hydraulic gradient in that zone. Computer models are presently available to help predict the extent of influence of ground-water withdrawals in an area. These may be used as management tools in planning ground-water development of the area. (USGS)

Water-Resources Investigations Report↗

Aquifer composition and the tendency toward scale-deposit formation during reverse osmosis desalination - Examples from saline ground water in New Mexico, USA

Desalination is expected to make a substantial contribution to water supply in the United States by 2020. Currently, reverse osmosis is one of the most cost effective and widely used desalination technologies. The tendency to form scale deposits during reverse osmosis is an important factor in determining the suitability of input waters for use in desalination. The tendency toward scale formation of samples of saline ground water from selected geologic units in New Mexico was assessed using simulated evaporation. All saline water samples showed a strong tendency to form CaCO3 scale deposits. Saline ground water samples from the Yeso Formation and the San Andres Limestone showed relatively stronger tendencies to form CaSO4 2H2O scale deposits and relatively weaker tendencies to form SiO2(a) scale deposits than saline ground water samples from the Rio Grande alluvium. Tendencies toward scale formation in saline ground water samples from the Dockum Group were highly variable. The tendencies toward scale formation of saline waters from the Yeso Formation, San Andres Limestone, and Rio Grande alluvium appear to correlate with the mineralogical composition of the geologic units, suggesting that scale-forming tendencies are governed by aquifer composition and water-rock interaction. ?? 2006 Elsevier B.V. All rights reserved.

Desalination↗

Summary appraisals of the nation's ground-water resources – Lower Mississippi region

The Lower Mississippi Region comprises an area of 102,400 square miles (265,200 square kilometers). Almost all this area is in the physiographic province known as the Gulf Coastal Plain. Three small areas on the northwest boundary of the region are in the Interior Highlands. The Lower Mississippi Region has an abundance of ground water. The geologic structure in that part of the region within the Coastal Plain is an elongated trough which has been filled with permeable materials, resulting in vast subsurface reservoirs. Except in local areas where continued large withdrawals have caused significant water-level declines, these reservoirs are full. Recharge to the region's aquifers is primarily from rainfall. Annual rainfall in most of the region is well distributed throughout the year and is sufficient to satisfy evapotranspiration requirements and still provide recharge to the aquifers. An estimated 844 billion cubic feet (24 billion cubic meters) of fresh ground water is available for withdrawal annually in the region. Only about one-third of this quantity is being utilized. Therefore, on this basis alone, the region still has much potential for ground-water development. The Coastal Plain aquifers within the Lower Mississippi Region contain large reserves of saltwater in the downdip limits of the aquifers. The quantity of saltwater in the region is several times that of freshwater. As desalinization techniques are developed and as more uses are found for saltwater, this reserve could become an important source of water for the region. At present (1976), the most productive and potentially productive aquifers or aquifer systems in the region are the Mississippi River valley alluvial aquifer of Quaternary age and the Sparta Sand and the Memphis aquifer (Memphis Sand in Tennessee) of Tertiary age. The Sparta Sand and the Memphis aquifer are heavily utilized and have shown significant water-level declines. However, selected well hydrographs indicate that water levels may be stabilizing under present pumping conditions. The Mississippi River valley alluvial aquifer is the most extensive high-yielding aquifer in the region; yields of several thousand gallons per minute may be obtained at depths of less than 200 feet (61 meters). To obtain maximum benefit from the vast quantities of ground water in the region, adequate attention must be given to the effects of proposed development upon the ground-water regime. Knowledge of the geologic structure and hydraulic properties of the aquifer systems is essential to an evaluation of the effects of such development. Some studies have been made in sufficient detail to provide this knowledge, but additional studies are needed. Activities that could cause significant changes in the groundwater regime should be undertaken only after all available information has been considered. Failure to seek out and use such information may result in inefficient development of the groundwater resource and, in some instances, degradation of the quality of the resource. Some changes always result from ground-water development. The possible changes can be grouped into three categories: hydraulic, water quality, and those affecting the physical framework of the aquifers. Generally, they are small in magnitude and areal extent. Because these changes occur below the ground surface, they are unknown to the ground-water user unless they noticeably affect the quantity or quality of water produced or cause obvious physical effects, such as land subsidence. Great advances have been made in hydrologic technology in recent years. Predictive models have been developed that make it possible for the hydroiogist to simulate aquifer responses to proposed development or other stresses. These models would be invaluable tools in progressive water-resources planning and management.

Arkansas, Kentucky, Louisiana, Mississippi, Missou↗

Simulation of ground-water flow and evaluation of water-management alternatives in the upper Charles River basin, eastern Massachusetts

Ground water is the primary source of drinking water for towns in the upper Charles River Basin, an area of 105 square miles in eastern Massachusetts that is undergoing rapid growth. The stratified-glacial aquifers in the basin are high yield, but also are thin, discontinuous, and in close hydraulic connection with streams, ponds, and wetlands. Water withdrawals averaged 10.1 million gallons per day in 1989?98 and are likely to increase in response to rapid growth. These withdrawals deplete streamflow and lower pond levels. A study was conducted to develop tools for evaluating water-management alternatives at the regional scale in the basin. Geologic and hydrologic data were compiled and collected to characterize the ground- and surface-water systems. Numerical flow modeling techniques were applied to evaluate the effects of increased withdrawals and altered recharge on ground-water levels, pond levels, and stream base flow. Simulation-optimization methods also were applied to test their efficacy for management of multiple water-supply and water-resource needs. Steady-state and transient ground-water-flow models were developed using the numerical modeling code MODFLOW-2000. The models were calibrated to 1989?98 average annual conditions of water withdrawals, water levels, and stream base flow. Model recharge rates were varied spatially, by land use, surficial geology, and septic-tank return flow. Recharge was changed during model calibration by means of parameter-estimation techniques to better match the estimated average annual base flow; area-weighted rates averaged 22.5 inches per year for the basin. Water withdrawals accounted for about 7 percent of total simulated flows through the stream-aquifer system and were about equal in magnitude to model-calculated rates of ground-water evapotranspiration from wetlands and ponds in aquifer areas. Water withdrawals as percentages of total flow varied spatially and temporally within an average year; maximum values were 12 to 13 percent of total annual flow in some subbasins and of total monthly flow throughout the basin in summer and early fall. Water-management alternatives were evaluated by simulating hypothetical scenarios of increased withdrawals and altered recharge for average 1989?98 conditions with the flow models. Increased withdrawals to maximum State-permitted levels would result in withdrawals of about 15 million gallons per day, or about 50 percent more than current withdrawals. Model-calculated effects of these increased withdrawals included reductions in stream base flow that were greatest (as a percentage of total flow) in late summer and early fall. These reductions ranged from less than 5 percent to more than 60 percent of model-calculated 1989?98 base flow along reaches of the Charles River and major tributaries during low-flow periods. Reductions in base flow generally were comparable to upstream increases in withdrawals, but were slightly less than upstream withdrawals in areas where septic-system return flow was simulated. Increased withdrawals also increased the proportion of wastewater in the Charles River downstream of treatment facilities. The wastewater component increased downstream from a treatment facility in Milford from 80 percent of September base flow under 1989?98 conditions to 90 percent of base flow, and from 18 to 27 percent of September base flow downstream of a treatment facility in Medway. In another set of hypothetical scenarios, additional recharge equal to the transfer of water out of a typical subbasin by sewers was found to increase model-calculated base flows by about 12 percent of model-calculated base flows. Addition of recharge equal to that available from artificial recharge of residential rooftop runoff had smaller effects, augmenting simulated September base flow by about 3 percent. Simulation-optimization methods were applied to an area near Populatic Pond and the confluence of the Mill and Charles Rivers in Franklin,

Massachusetts↗

Nitrate behavior in ground waters of the southeastern USA

Principal components analysis (PCA) was performed with water-quality data from studies conducted during 1993 to 1995 to explore potential nitrate- attenuation processes in ground waters of the southeastern USA. Nitrate reduction is an important attenuation process in selected areas of the Southeast. A nitrate-reduction component explains 23% of the total variance in the data and indicates that nitrate and dissolved oxygen (DO) are inversely related to ammonium, iron, manganese, and dissolved organic carbon (DOC). Additional components extracted by PCA include calcite dissolution (18% of variance explained) and phosphate dissolution (9% of variance explained). Reducing conditions in ground waters of the region influence nitrate behavior through bacterially mediated reduction in the presence of organic matter, and by inhibition of nitrate formation in anoxic ground water beneath forested areas. Component scores are consistent with observed water- quality conditions in the region. For example, median nitrate concentration in ground-water samples from the Albemarle-Pamlico Drainage Basin (ALBE) Coastal Plain is <0.05 mg L-1, median DOC concentration is 4.2 mg L-1, and median DO concentration is 2.1 mg L-1, consistent with denitrification. Nitrate reduction does not occur uniformly throughout the Southeast. Median DO concentrations in ground-water samples from the Apalachicola- Chattahoochee-Flint River Basin (ACFB) are 6.2 to 7.1 mg L-1, and median nitrate concentrations are 0.61 to 2.2 mg L-1, inconsistent with denitrification. Similarly, median DO concentration in samples from the Georgia-Florida Coastal Plain (GAFL) is 6.0 mg L-1 and median nitrate concentration is 5.8 mg L-1.

Journal of Environmental Quality↗

Ground-water quality in the Santa Ana Watershed, California: Overview and data summary

Water-quality samples were collected from 207 wells in the Santa Ana Basin in the Coastal Range Province of southern California to assess the occurrence and distribution of dissolved constituents in ground water as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. These wells were sampled during eight studies from 1999 to 2001 that were designed to sample the used water resource at different scales: (1) three studies characterized water quality at a regional scale; (2) two studies focused on spatial and temporal variations in water quality along flow paths; (3) a land-use study focused on evaluation of water quality in shallow ground water; and (4) two studies assessed aquifer susceptibility to contamination. The Santa Ana Basin is divided into the Coastal Basin, the Inland Basin, and the San Jacinto Basin. The Coastal Basin includes a relatively small unconfined recharge area and a relatively large confined area where ground-water pumping is the primary source of discharge. Land use is almost entirely urban. The Inland Basin is predominantly unconfined and land use is urban and agricultural. The San Jacinto Basin is largely unconfined and land use is mostly agricultural. Water-quality data discussed in this report are compared with U.S. Environmental Protection Agency (EPA) drinking-water standards, both primary and secondary. Most exceedances of maximum contaminant levels (MCLs) occurred in the shallow, coastal monitoring wells that tap ground water not used for water supply. Water from several irrigation wells in the Inland and San Jacinto basins exceeded the 10 mg/L (milligrams per liter) MCL for nitrate. Water from some wells exceeded secondary MCLs for manganese (50 ?g/L [micrograms per liter]) and iron (300 ?g/L) and (or) proposed MCLs for arsenic (10 ?g/L) and uranium (30 ?g/L). Of the 94 production wells sampled for trace elements, 3 irrigation wells in the Coastal Basin produced water that exceeded the secondary MCL for manganese. Water from production wells sampled in all three subbasins exceeded the proposed MCL for radon (300 pCi/L [picocuries per liter]). Pesticides were detected above the laboratory reporting limit (LRL) in 50 percent of the production and monitoring wells sampled in the Santa Ana Basin. Deethylatrazine, simazine, atrazine, tebuthiuron, and prometon were the five most commonly detected pesticides in the current USGS studies. All pesticide concentrations detected in these studies were below MCLs established by the EPA. Volatile organic compounds (VOCs) were detected in 115 wells (56 percent) of the 207 wells sampled. Of the 38 VOCs detected, only 13 were detected in more than five wells. The most commonly detected VOCs, in order of detection frequency, were chloroform; trichloroethlyene, TCE; 1,1,1-trichloroethane, TCA; trichlorofluoromethane, CFC 11; 1,1,2-trichloro-1,2,2-trifluoroethane, CFC 113; tetrachloroethylene, PCE; bromodichloromethane; methyl tert-butyl ether, MTBE; 1,1-dichloroethene, 1-1-DCE; and 1,2- dichloroethene, 1,2-DCE. The only exceedances of EPA MCLs for VOCs occurred in six irrigation wells and in two deep monitoring wells sampled in the Inland Basin.

California↗

Effects of uranium-mining releases on ground-water quality in the Puerco River Basin, Arizona and New Mexico

Shallow ground water beneath the Puerco River of Arizona and New Mexico was studied to determine the effects of uranium-mining releases on water quality. Ground-water samples collected from 1989 to 1991 indicate that concentrations of dissolved uranium have decreased. Most samples from the alluvial aquifer downstream from Gallup, New Mexico, met with U.S. Environmental Protection Agency's maximum contaminant levels for gross alpha, gross beta, and radium and the proposed maximum contaminant level for uranium.

Water Supply Paper↗

Geology and ground-water resources of the island of Oahu, Hawaii

Oahu, one of the islands of the Hawaiian group, lies in the Mid-Pacific 2,100 miles southwest of San Francisco. The principal city is Honolulu. The Koolau Range makes up the eastern part of the island, and the Waianae Range the western part. Both are extinct basaltic volcanoes deeply dissected by erosion. The Koolau Volcano was the later to become extinct. The Waianae Range is made up of three groups of lavas erupted in Tertiary and possibly in early Pleistocene time. The exposed part of the older lava is nearly 2,000 feet thick and consists largely of thin-bedded pahoehoe. It is separated in most places from the middle lavas by an angular unconformity and talus breccia and in a few places by an erosional unconformity. The middle basalts are about 2,000 feet thick and closely resemble the lower ones except that they contain more aa. The upper lavas reach a thickness of about 2,300 feet and are mostly massive aa flows. The last eruptions produced large cinder cones and some nephelite basalts. The Waianae Volcano, like other Hawaiian volcanoes, produced only small amounts of ash, and the lavas were largely extruded from fissures a few feet wide, now occupied by dikes. The center of activity was near Kolekole Pass, at the head of Lualualei Valley. The Koolau Volcano is made up of two groups of lavas extruded in Tertiary and early Pleistocene (?) time. The older group, the Kailua volcanic series, is greatly altered by hydrothermal action and was extruded from fissures near Lanikai. The flows of the younger group, the Koolau volcanic series, were extruded from fissures about a mile south of the Kailua rift and have an exposed thickness of about 3,000 feet. The Koolau Volcano produced even less ash than the Waianae Volcano, and its flows are thin-bedded pahoehoe and aa. The eruptive center of the Koolau Volcano lies between Kaneohe and Waimanalo. Great amounts of both the Waianae and Koolau Ranges were removed by fluvial and marine erosion during the Pleistocene. The master streams are characterized by deep amphitheater-headed valleys. After this erosion cycle the island was submerged more than 1,200 feet, and these great valleys were drowned and alluviated. Besides this submergence, several strand lines, preserved up to 100 feet above present sea level occur, which may be due to world-wide changes in sea level in response to the withdrawal and restoration of water concurrent with the advances and recessions of the polar ice caps and to accompanying changes in the ocean floor. During this time of shifting ocean levels spasmodic eruptions occurred on the southeast end of the Koolau Range, producing numerous lava flows and tuff cones, most of which are nephelite basalt. The last of these eruptions occurred in Recent time. A description of the climate, rates of run-off, and results of experiments to determine evaporation and transpiration in the areas of high rainfall are given. It was found that the consumptive use decreases materially and becomes a very small percentage of the rainfall in the areas of high precipitation. The lava rocks of the island are very permeable and, because of a rainfall reaching a maximum of 300 inches a year, carry large amounts of ground water, confined and unconfined, basal and perched. The basal ground water floats on salt water because of its lower specific gravity. Consequently for each foot the water table stands above sea level, salt water lies about 42 feet below sea level, in accordance with the sea along the coast as basal ground water. In most places the lava rocks along the shore are overlain by an impermeable or nearly impermeable caprock consisting of submerged lateritic soils and marine noncalcareous sediments. These deposits retard the escape of basal ground water into the sea and give rise to artesian water, but unlike most other artesian systems, this one has no lower restraining formation. The artesian water is the principal source of domestic, municipal, and irrigation supplies. The average annual quantity pumped for the period 1928 to 1933 amounted to about 105,000,000,000 gallons, nearly 90 percent of which came from Koolau hasalt and the remainder from Waianae basalt. There are ten artesian areas in the Koolau Range and two in the Waianae Range. Hydraulic gradients in these basins were found to range from 1.2 to 3 feet to the mile. Because of these extremely flat gradients and the high permeability of the aquifers it is possible to reverse the hydraulic gradients by draft and make the water flow from one artesian area to another. The artesian water levels fluctuate in response to seasonal variations in draft and recharge and in a lesser way to tidal, barometric, and seismic pressures. The water, as shown by chemical analysis, is of excellent quality except where it is contaminated with sea water. Methods have been devised for freshening wells that have gone salty, for detecting leaks, for sealing leaky and defective wells, and for recharging the artesian basins. Owing to the danger of the wells becoming brackish with increased draft, it is believed that further large developments will be more successful if shafts are sunk to sea level in the basalt as far inland as practicable, and tunnels are driven from the bottom of the shafts near the top of the saturated zone. Favorable places for such development exist in Honolulu. In addition to the basal water in the volcanic rocks, water is found in the recent gravel, beach, and dune deposits, and the emerged reef limestone. This water has been recovered by wells and tunnels, and there are favorable localities for developing additional water of this type. The island contains two types of basal springs&mdash;those like the Pearl Harbor Springs, which issue from basalt and are supplied by overflow and leakage from the artesian basin, and those which issue from the coastal-plain sediments and are mainly return irrigation water. The total quantity of basal ground water issuing as springs is estimated to be 100,000,000 gallons a day. Ground water occurs at high levels, confined by dikes and perched on tuff, alluvium, and soil beds. These structures give rise to innumerable high-level springs. In the Koolau Range 60 tunnels yield about 33,000,000 gallons daily, of which about 95 percent is obtained from tunnels penetrating the dike complex of the Koolau volcanic series, about 2 percent from tunnels entering post-Koolau ash or tuff deposits, and the remainder from tunnels whose geologic relations are not certainly known. The average daily yield of the tunnels that recover dike water is 2,330 gallons a foot, but the average daily yield of the tunnels in post-Koolau tuff is 450 gallons a foot, and that of the tunnels in alluvium or soil is only 23 gallons a foot. Owing largely to the much lower rainfall on the Waianac Range, its 35 tunnels (not including two new tunnels under construction) yield only about 2,400,000 gallons daily, about 94 percent of which is believed to be obtained from dike systems. The average daily yield of the tunnels in this range that are supplied by dike systems is 581 gallons a foot, as compared to 5 gallons a foot from tunnels in ash or tuff. An extensive tunnel system is proposed to develop a large supply of high-level water for Honolulu from the dike complex of the Koolau series, and high-level water can be recovered by tunnels at many other places. The average daily discharge of all high-level springs in the Koolau Range is about 58,000,000 gallons, of which about 94 percent comes from the Koolau dike complex and about 6 percent from post-Koolau volcanic rocks. The average daily discharge of all high-level springs in the Waianae Range is about 500,000 gallons of which about 81 percent issues from the dike complex.

Hawaii↗

The value of long-term monitoring in the development of ground-water-flow models

As environmental issues have come to the forefront of public concern, so has the awareness of the importance of ground water in the overall water cycle and as a source of the Nation&rsquo;s drinking water. Heightened interest has spawned a host of scientific enterprises (Taylor and Alley, 2001). Some activities are directed toward collection of water-level data and related information to monitor the physical and chemical state of the resource. Other activities are directed at interpretive studies undertaken, for example, to optimize the location of new water-supply wells or to protect rivers and lakes fed by ground water. An important type of interpretive study is the computer ground-water-flow model that inte- grates field data in a mathematical framework. Long-term, systematic collection of hydro- logic data is crucial to the construction and testing of ground-water models so that they can reproduce the evolution of flow systems and forecast future conditions.

Wisconsin↗

Ground-water hydrology and water quality of Irwin Basin at Fort Irwin National Training Center, California

Geohydrologic data were collected from Irwin Basin at Fort Irwin National Training Center in the Mojave Desert of southern California by the U.S. Geological Survey during 199296 to deter mine the quantity and quality of ground water available in this basin. In addition to data collected from existing wells and test holes, 17 monitoring sites were constructed in Irwin Basin to provide data on subsurface geology, ground-water levels, and ground-water quality. Eleven of these sites were multiple-well monitoring sites that were constructed to provide depth-dependent geohydrologic data in the aquifer system. The aquifer system of Irwin Basin, defined on the basis of hydrologic data collected from wells in Irwin Basin, consists of an upper and a lower aquifer. A 1994 water-table contour map shows that a cone of depression beneath Irwin Basin well field has developed as a result of ground-water development. Water-quality samples collected from Irwin Basin wells to determine potential sources of ground-water degradation indicate that water in three areas in the basin contains high nitrate and dissolved-solids concentrations. The stable isotopes of oxygen and hydrogen indicate that present-day precipitation is not a major source of recharge in this basin. Tritium and carbon-14 data indicate that most of the basin was recharged before 1953 and that this water may be more than 14,000 years old.

Calfornia↗

Hydrogeology and water quality of the Pepacton Reservoir Watershed in Southeastern New York. Part 2. Hydrogeology, stream base flow, and ground-water recharge

The hydrogeology of the 372-square-mile Pepacton Reservoir watershed (herein called the East Branch Delaware River Basin) in the southwestern Catskill Mountain region of Southeastern New York is described and depicted in a detailed surficial geologic map and two geologic sections. An analysis of stream discharge records and estimates of mean annual ground-water recharge and stream base flow for eight subbasins in the basin are included. Analysis of surficial geologic data indicates that the most widespread geologic unit within the basin is till, which occurs as masses of ablation till in major stream valleys and as thick deposits of lodgment till that fill upland basins. Till covers about 91.5 percent of the Pepacton Reservoir watershed, whereas stratified drift (alluvium, outwash, and ice-contact deposits) accounts for 6.3 percent. The Pepacton Reservoir occupies about 2.3 percent of the basin area. Large outwash and ice-contact deposits occupy the valleys of the upper East Branch Delaware River, the Tremper Kill, the Platte Kill, the Bush Kill, and Dry Brook. These deposits form stratified-drift aquifers that range in thickness from 90 feet in parts of the upper East Branch Delaware River Valley to less than 30 feet in the Dry Brook valley, and average about 50 feet in the main East Branch Delaware River Valley near Margaretville. An analysis of daily mean stream discharge for the six eastern subbasins for 1998–2001, and for two western subbasins for 1945–52, was performed using three computer programs to obtain estimates of mean annual base flow and mean annual ground-water recharge for the eight subbasins. Mean annual base flow ranged from 15.3 inches per year for the Tremper Kill subbasin to 22.3 inches per year for the Mill Brook subbasin; the latter reflects the highest mean annual precipitation of all the subbasins studied. Estimated mean annual ground-water recharge ranged from 24.3 inches per year for Mill Brook to 15.8 inches per year for the Tremper Kill. The base flow index, which is the mean annual base flow expressed as a percentage of mean annual streamflow, ranged from 69.1 percent for Coles Clove Kill to 75.6 percent for the upper East Branch Delaware River; most subbasin indices were greater than 70 percent. These high base flow indices indicate that because stratified drift covers only a small percentage of subbasin areas (generally 5 to 7 percent), most of the base flow is derived from the fractured sandstone bedrock that underlies the basin.

Scientific Investigations Report↗

Geochemical comparison of ground water in areas of New England, New York, and Pennsylvania

In New England, the ground-water geochemistry results mainly from the reaction of CO2-charged water with feldspar and other primary silicates. Water in the New England bedrock is more highly evolved geochemically than water in the drift, presumably as a result of its longer residence time. In the New York area, the geochemistry of water in both types of aquifers results mainly from carbonate-mineral dissolution. Water in most glacial drift and bedrock is saturated with respect to calcite. In some parts of New York, the dissolution of evaporite minerals has a marked effect on the water chemistry of the bedrock. In most of the Pennsylvania area, the geochemistry of water in both types of aquifers indicates that, although carbonate minerals are the principal reactants, their influence on water chemistry is less than in New York. In parts of Pennsylvania, chemical differences between ground water from drift and ground water from bedrock are attributed to a higher proportion of reactive minerals in the drift than in the local bedrock as a result of glacial transport. -from Author

Groundwater↗

Simulation of ground-water flow in glaciofluvial aquifers in the Grand Rapids area, Minnesota

A calibrated steady-state, finite-difference, ground-waterflow model was constructed to simulate ground-water flow in three glaciofluvial aquifers, defined in this report as the upper, middle, and lower aquifers, in an area of about 114 mi2 surrounding the city of Grand Rapids in north-central Minnesota. The calibrated model will be used by Minnesota Department of Health and communities in the Grand Rapids area in the development of wellhead protection plans for their water supplies. The model was calibrated through comparison of simulated ground-water levels to measured static water levels in 351 wells, and comparison of simulated base-flow rates to estimated base-flow rates for reaches of the Mississippi and Prairie Rivers. Model statistics indicate that the model tends to overestimate ground-water levels. The root mean square errors ranged from +12.83 ft in wells completed in the upper aquifer to +19.10 ft in wells completed in the middle aquifer. Mean absolute differences between simulated and measured water levels ranged from +4.43 ft for wells completed in the upper aquifer to +9.25 ft for wells completed in the middle aquifer. Mean algebraic differences ranged from +9.35 ft for wells completed in the upper aquifer to +14.44 ft for wells completed in the middle aquifer, with the positive differences indicating that the simulated water levels were higher than the measured water levels. Percentage errors between simulated and estimated base-flow rates for the three monitored reaches all were less than 10 percent, indicating good agreement. Simulated ground-water levels were most sensitive to changes in general-head boundary conductance, indicating that this characteristic is the predominant model input variable controlling steady-state water-level conditions. Simulated groundwater flow to stream reaches was most sensitive to changes in horizontal hydraulic conductivity, indicating that this characteristic is the predominant model input variable controlling steady-state flow conditions.

Minnesota↗

Management of ground water and evolving hydrogeologic studies in New Jersey : a heavily urbanized and industrialized state in the northeastern United States

New Jersey is the most densely populated and one of the most industrialized states in the United States. An abundance of freshwater and proximity to major northeastern metropolitan centers has facilitated this development. Pumpage of freshwater from all aquifers in the State in 1980 was 730 million gallons per day (2.76 million cubic meters per day). Management and efficient development of the ground-water resources of the State are the responsibility of the New Jersey Department of Environmental Protection. Laws have been enacted and updated by the State legislature to manage water allocation and to control the disposal of hazardous wastes. Present resource management is guided by the New Jersey Water-Supply Master Plan of 1981. Funding for management activities is partially derived from the sale of state-approved bonds. Effective planning and regional management require accurate and up-to-date hydrologic information and analyses. The U.S. Geological Survey, in cooperation with the New Jersey Geological Survey, is conducting three intensive ground-water studies involving the collection and interpretation of hydrologic data to meet the urgent water-management needs of New Jersey. These studies are part of a long-term cooperative program and are funded through the Water-Supply Bond Act of 1981. They began in 1983 and are scheduled to be completed in 1988. The project areas are situated in the New Jersey part of the Atlantic Coastal Plain in and near Atlantic City, Camden, and South River. They range in size from 400 to 1,200 mil (1,040 to 3,120 km2). The studies are designed to define the geology, hydrology, and geochemistry of the local ground-water systems. The results of these studies will enable the State to address more effectively major problems in these areas such as declining water levels, overpumping, saltwater intrusion, and ground-water contamination resulting from the improper disposal of hazardous wastes. Specific objectives of these studies by the U.S. Geological Survey are to (1) develop an accurate and up-to-date hydrogeologic data base, (2) design and implement a data-collection program and establish a computerized information management system, (3) refine the conceptualization of the ground-water flow system, and (4) define the geochemistry of the aquifer system by conducting a water-quality appraisal. The objectives are accomplished by standard hydrogeologic methods. Information concerning hydrogeologic framework, ground-water levels, water use, hydraulic characteristics, and water quality in the study areas is compiled from all available sources. Additional data needed are collected through well inventories, surface geophysical surveys, water-quality samplings, water-level measurements, and a well-drilling program. Interpretation of the flow system is based on the use of standard analytical techniques and digital flow modeling. Calibrated flow models will provide ground-water managers with a mechanism to develop and test regional water-supply strategies. Definition of the geochemistry of the aquifer system is accomplished through a variety of methods which depend on the problems and available data in the particular study area. The approach includes statistical analysis of water-quality data, reaction-path modeling, and determination of the movement of chemical constituents using analytical and numerical modeling techniques. A combined staff of 25 to 30 professionals and technicians from the New Jersey District office of the U.S. Geological Survey is committed to the three studies. The staff has specialists in geohydrology, numerical modeling, geochemistry, geophysics, and computer science. The findings of these studies will be published in data reports, interpretive reports, instructional manuals and journal articles.

New Jersey↗

Ground-Water Quality in the St. Lawrence River Basin, New York, 2005-06

The Federal Clean Water Act requires that States monitor and report on the quality of ground water and surface water. To satisfy part of these requirements, the U.S. Geological Survey and New York State Department of Environmental Conservation have developed a program in which ground-water quality is assessed in 2 to 3 of New York State's 14 major river basins each year. To characterize the quality of ground water in the St. Lawrence River Basin in northern New York, water samples were collected from 14 domestic and 11 production wells between August 2005 and January 2006. Eight of the wells were finished in sand and gravel and 17 wells were finished in bedrock. Ground-water samples were collected and processed using standard U.S. Geological Survey procedures and were analyzed for 229 constituents and physical properties, including inorganic constituents, nutrients, trace elements, radon-222, pesticides and pesticide degradates, volatile organic compounds, and bacteria. Sixty-six constituents were detected above laboratory reporting levels. Concentrations of most compounds at most sites were within drinking water standards established by the U.S. Environmental Protection Agency and New York State Department of Health, but a few compounds exceeded drinking water standards at some sites. Water in the basin is generally hard to very hard (hardness equal to 121 mg/L as CaCO3 or greater); hardness and alkalinity were generally higher in the St. Lawrence Valley than in the Adirondack Mountains. The cation with the highest median concentration was calcium; the anion with the highest median concentration was bicarbonate. The concentration of chloride in one sample exceeded the 250 milligrams per liter U.S. Environmental Protection Agency Secondary Drinking Water Standard; the concentration of sulfate in one sample also exceeded the 250 milligrams per liter U.S. Environmental Protection Agency Secondary Drinking Water Standard. Nitrate was the predominant nutrient detected but no sample exceeded the 10 mg/L U.S. Environmental Protection Agency Maximum Contaminant Level. The trace elements detected with the highest median concentrations were strontium, barium, and iron. Concentration of trace elements in several samples exceeded U.S. Environmental Protection Agency Secondary Drinking Water Standards, including aluminum (50 micrograms per liter, 4 samples), iron (300 micrograms per liter, 5 samples), and manganese (50 micrograms per liter, 4 samples). The concentration of uranium in one sample from a domestic well finished in crystalline bedrock was three times the U.S. Environmental Protection Agency Maximum Contaminant Level of 30 micrograms per liter. The median concentration of radon-222 was 600 picoCuries per liter, but concentrations as high as 18,800 picoCuries per liter were detected; two wells with high radon concentrations also had high uranium concentrations. Radon-222 is not currently regulated, but the U.S. Environmental Protection Agency has proposed a Maximum Contaminant Level of 300 picoCuries per liter along with an Alternative Maximum Contaminant Level of 4,000 picoCuries per liter, to be in effect in states that have programs to address radon in indoor air. Concentrations of radon-222 exceeded the proposed Maximum Contaminant Level in 60 percent of samples and exceeded the proposed Alternative Maximum Contaminant Level in 8 percent of samples. Six pesticides and pesticide degradates were detected; all were amide or triazine herbicides or degradates. Five volatile organic compounds were detected, including disinfection byproducts such as trichloromethane and gasoline components or additives such as methyl tert-butyl ether. No pesticides, pesticide degradates, or volatile organic compounds were detected above established limits. Coliform bacteria, including Escherichia coli, were detected in three wells finished in carbonate bedrock.

Open-File Report↗

Digital model simulation of the hydrologic flow system, with emphasis on ground water in Spokane Valley, Washington and Idaho

A digital-computer model of the hydrologic flow system, with emphasis on ground water, was developed for Spokane Valley, Washington and Idaho. The current rate of ground-water pumping in Spokane Valley has little effect on water levels in the Spokane aquifer, although short-term water-level declines occur locally. The model was used to show the effects of increased ground-water pumpage on aquifer heads and streamflow. A simulated pumping rate twice that of actual 1977 pumping rates of 227 cubic feet per second lowered water levels in the Spokane aquifer less than 3 feet during a 1-year simulation period. This doubling of the ground water pumpage caused a decrease in discharge of the Spokane River, as measured at Spokane, of about 150 cubic feet per second during the summer months and about 50 cubic feet per second during the rest of the year. Leakage from the aquifer to the Little Spokane River was decreased by less than 10 cubic feet per second.

Idaho, Washington↗

Ground water available in the Davenport area, Oklahoma

This memorandum describes the ground-water resources in the vicinity of Davenport, Lincoln County, Oklahoma. It is based on a one-day trip to Davenport made by the writer on February 11, 1948, to obtain information in addition to that in the ground-water files in Norman on the availability of ground water for public supply or other uses in the Davenport area. Davenport is a town of about 1,000 in east-central Lincoln County, Oklahoma, on U.S. Highway 66, about half way between Oklahoma City and Tulsa. It is in an area of undulating to gently rolling topography underlain by rocks of Pennsylvanian age. The area is drained into Deep Fork of the Canadian River, by Dry Creek and its tributary, Chuckaho Creek.

Oklahoma↗