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At least 1,747 records · Page 97Linked to original sources

Small-mammal data on early and middle Holocene climates and biotic communities in the Bonneville Basin, USA

Archaeological investigations in Camels Back Cave, western Utah, recovered a series of small-mammal bone assemblages from stratified deposits dating between ca. 12,000 and 500 14C yr B.P. The cave's early Holocene fauna includes a number of species adapted to montane or mesic habitats containing grasses and/or sagebrush (e.g., Lepus townsendii, Marmota flaviventris, Reithrodontomys megalotis, and Brachylagus idahoensis) which suggest that the region was relatively cool and moist until after 8800 14C yr B.P. Between ca. 8600 and 8100 14C yr B.P. these mammals became locally extinct, taxonomic diversity declined, and there was an increase in species well-adapted to xeric, low-elevation habitats, including ground squirrels, Lepus californicus and Neotoma lepida. The early small-mammal record from Camels Back Cave is similar to the 11,300-6000 14C yr B.P. mammalian sequence from Homestead Cave, northwestern Utah, and provides corroborative data on Bonneville Basin paleoenvironments and mammalian responses to middle Holocene desertification. ?? 2002 University of Washington.

Quaternary Research↗

Upper Cretaceous tectonic activity on lineaments in western South Dakota

Lineaments mapped on satellite images in western South Dakota define a geometry of basement blocks, and paleotectonic activity on these lineament-bound blocks is recorded in sedimentary rocks. Mapping on seven Landsat images in an area of about 100,000 km 2 reveals that lineaments are best developed along azimuths of N. 60° E. to N. 90° E. and N. 30° W. to N. 60° W. Although their exact structural nature and origin are not known, these features are visualized as major zones of weakness that subdivide the crystalline Precambrian basement into discrete blocks. Several of the most prominent surface lineaments can be related to basement faults. The blocks bounded by these lineaments constitute low-relief uplifts that define the southern margin of the Williston Basin. During deposition of the Upper Cretaceous Pierre Shale, lineaments were the sites of tectonic activity. Members of the Pierre are relatively continuous throughout the area and are well dated by biostratigraphic zonation. The base of the Mobridge Member is the highest structural datum available for regional mapping. Northeast-trending surface lineaments near the White and Cheyenne Rivers have a clear expression on a subsurface structural map of this horizon. The Ardmore Bentonite Bed lies approximately 300 m (980 ft) below the Mobridge; subsurface structure contours on this datum show the active lineaments trending northwest. Isopach maps of two rock-stratigraphic units between the Ardmore and Mobridge reflect the shift in tectonic activity from early northwest sets of lineaments to later northeast trends.

South Dakota↗

Succession of rugose coral faunas in the Lower and Middle Devonian of eastern North America

Rocks of Early Devonian age are widely but sporadically distributed in the eastern half of North America and coral studies are based on a very incomplete record. Middle Devonian rocks are thicker and cover a greater area. Both Early and Middle Devonian corals are more similar to western European species than they are to presumably contemporary forms from western North America, although some of the eastern faunas contain a significant portion of endemic genera. The general outline of an eastern province was inherited from the Silurian, but disappeared by Late Devonian time when the worldwide Frasnian fauna invaded the area. A reef fauna of middle Helderberg age is known from the northeast part of the province and is composed of both endemic and widespread genera. Approximately contemporaneous off-reef deposits have few species, but these are common in argillaceous rocks of a somewhat larger area. Rocks of middle Onesquethaw (Schoharie) age, although thin and discintinuous, include the largest and most widespread Early-Devonian coral fauna. Endemic genera are numerous but other elements are widespread and some species are apparently ancestral to species in the succeeding Onondaga fauna. The late Onesquethaw (Onondaga) faunas are the largest and most widely distributed of all those under review. Succeeding faunas of the Cazenovia, Tioughnioga and Taghanic Stage (Hamilton-Tully sequence) are less widespread and are clearly derivatives of the late Onesquethaw fauna. The Taghanic fauna is the latest Middle Devonian rugose coral fauna in the area

Indiana, Kentucky, Maine, Maryland, New Brunswick,↗

Evaluating drivers of environmental change in a lake sediment core: Insights from spectroscopic metrics of water-extractable organic matter and stable carbon isotopes

Freshwater lakes play a critical role in the global carbon cycle by storing and transforming organic matter (OM) from both terrestrial and aquatic sources. Small lakes in northern temperate regions, despite their limited surface area, disproportionately influence regional carbon budgets. Buried sediments integrate OM inputs over time and archive ecosystem responses to natural and anthropogenic disturbances. However, the direction and magnitude of recent environmental changes on sediment carbon (C) dynamics remain poorly understood. A 23-cm core was collected from a small temperate lake in northeastern USA to evaluate sediment OM content and composition over timescales relevant to historical land-use change, damming, and recovery from acid deposition. Patterns in OM burial and source contributions were revealed via elemental and isotopic analyses of bulk OM and ultraviolet-visible spectrophotometry of water-extractable organic matter (WEOM). The optical metrics expanded observations of likely OM sources beyond the information gained from bulk carbon metrics (total carbon, δ 13 C). The aromaticity of WEOM increased downcore, which is consistent with a shift from increased terrestrial inputs during early logging and damming activity (pre ∼1920) to more microbial-derived OM in recent surficial sediments. Future applications of WEOM optical properties as complements to traditional geochemical metrics can enhance interpretations of lake ecosystem responses recorded in lake sediments to environmental perturbations in temperate lakes.

New York↗

U-Pb ages of secondary silica at Yucca Mountain, Nevada: Implications for the paleohydrology of the unsaturated zone

Uranium, Th and Pb isotopes were analyzed in layers of opal and chalcedony from individual mm- to cm-thick calcite and silica coatings at Yucca Mountain, Nevada, USA, a site that is being evaluated for a potential high-level nuclear waste repository. These calcite and silica coatings on fractures and in lithophysal cavities in Miocene-age tuffs in the unsaturated zone (UZ) precipitated from descending water and record a long history of percolation through the UZ. Opal and chalcedony have high concentrations of U (10 to 780 ppm) and low concentrations of common Pb as indicated by large values of 206Pb/204Pb (up to 53,806), thus making them suitable for U-Pb age determinations. Interpretations of U-Pb isotope systems in opal samples at Yucca Mountain are complicated by the incorporation of excess 234U at the time of mineral formation, resulting in reverse discordance of U-Pb ages. However, the 207PB/235U ages are much less affected by deviation from initial secular equilibrium and provide reliable ages of most silica deposits between 0.6 and 9.8 Ma. For chalcedony subsamples showing normal age discordance, these ages may represent minimum times of deposition. Typically, 207Pb/235U ages are consistent with the microstratigraphy in the mineral coating samples, such that the youngest ages are for subsamples from outer layers, intermediate ages are from inner layers, and oldest ages are from innermost layers. 234U and 230Th in most silica layers deeper in the coatings are in secular equilibrium with 238U, which is consistent with their old age and closed system behavior during the past -0.5 Ma. The ages for subsamples of silica layers from different microstratigraphic positions in individual calcite and silica coating samples collected from lithophysal cavities in the welded part of the Topopah Spring Tuff yield slow long-term average growth rates of 1 to 5 mm/Ma. These data imply that the deeper parts of the UZ at Yucca Mountain maintained long-term hydrologic stability over the past 10 Ma. despite significant climate variations. U-Pb ages for subsamples of silica layers from different microstratigraphic positions in individual calcite and silica coating samples collected from fractures in the shallower part of the UZ (welded part of the overlying Tiva Canyon Tuff) indicate larger long-term average growth rates up to 23 mm/Ma and an absence of recently deposited materials (ages of outermost layers are 3-5 Ma.). These differences between the characteristics of the coatings for samples from the shallower and deeper parts of the UZ may indicate that the nonwelded tuffs (PTn), located between the welded parts of the Tiva Canyon and Topopah Spring Tuffs, play an important role in moderating UZ flow.

Applied Geochemistry↗

Gas hydrates of the Peruvian outer continental margin

Gas hydrates were recovered during coring by Ocean Drilling Program (ODP) Leg 112 at Sites 685 and 688 on the Peruvian outer continental margin at latitudes of 9° and 11.5°S, where water depths are 5070 and 3820 m, respectively. In addition, nearby Sites 682 and 683 yielded compelling evidence that gas hydrates are present, but gas hydrates were not directly observed there. Anomalous acoustic reflectors, known as bottom-simulating reflectors (BSRs), on marine seismic profiles from the region also provided inferential evidence that gas hydrates are present. Geothermal gradients of about 43 and 49°C/km were calculated on the basis of relations between depths to BSRs, bottom-water temperatures, and the pressure-temperature stability field of gas hydrates. Geochemical studies revealed that methane concentrations increase rapidly with depth after pore-water sulfate concentrations have been depleted. The relationship between methane and sulfate suggests that microbial processes account for the generation of methane, and the relationship between the carbon isotopic composition of methane and dissolved carbon dioxide supports this suggestion. We believe that decreasing chlorinity in pore water from squeezed sediment at the four sites results mainly from the decomposition of gas hydrates and is a dilution artifact observed as a result of the squeezing procedure. Maximum chlorinity values at or near the surface result from excess salt that comes from the formation of gas hydrates composed of freshwater. Record alkalinity attests to the intensity of diagenetic processes and has significant effects on salinity profiles at these sites. Gas hydrates were recovered at 99 and 166 meters below the seafloor (mbsf) at Site 685, and at 141 mbsf at Site 688 in Pleistocene diatomaceous mud. Methane constitutes more than 99% of the hydrocarbon gas mixture in the gas hydrates. The volumetric ratio of methane to water in the sample from Site 685 is 100, indicating that the sampled gas hydrate is either undersaturated with respect to methane or had partially decomposed during core recovery or both. The discovery of gas hydrates in lower slope deposits of the Peruvian outer continental margin extends our knowledge of gas-hydrate formation and occurrence in the Circum-Pacific region.

ODP Leg 112↗

Mineral resources of Elko County, Nevada

Of the 66 named mining districts in Elko County, 56 have been productive of one or more of 19 different commodities: 11 metals--copper, gold, silver, lead, zinc, mercury, tungsten, manganese, iron, uranium, and antimony; 8 nonmetals--sand and gravel, stone, barite, diatomite, gems, oil shale, volcanic ash, and clay. In addition to the commodities produced, at least 5 others--beryllium, molybdenum, tin, phosphorite, and petroleum, occur in amounts sufficient to warrant exploration. The other districts have been explored, but no production has been recorded. Total value-when-sold of production recorded through 1969 was nearly $91 million; actual production was considerably greater, especially if sand and gravel, barite, and other nonmetallic products before 1953 are included. In value of metals produced, the five highest districts are Mountain City ($26 million), Tuscarora ($11 million), Jarbidge ($10 million), Aura ($6 million), and Railroad (nearly $5 million). The Rio Tinto copper mine in the Mountain City district yielded $21 million. Of the 17 districts that produced nonmetallic minerals, Bootstrap .is the largest producer, containing the Rossi mine, one of the two largest barite mines in the United States. Most of /he metals produced name from veins and replacement deposits in limestone or dolomite near granitic stocks; exceptions are manganese and mercury, which are not associated with known or inferred stocks; mercury is further excepted because it occurs in volcanic rocks, as do a few deposits of the major metals. The largest deposit--the Rio Tinto lode--was a combination of fissure filling and replacement along a bedding plane shear zone 150 ft wide and 1,200 ft long in carbonaceous shale of the Valmy Formation; this deposit is apparently older than the Mountain City stock and its mineralization may be related to Paleozoic mafic volcanism later than a major thrust fault, inferred to underlie the area at a depth of about 5,000 ft. Most of the nonmetallic minerals mined were sedimentary bedded deposits, but mica was mined from pegmatite deposits, and turquoise from both placer and hydrothermal deposits. The largest known reserves of metals (1973) are of porphyry copper in the Dolly Varden district and gold in the Bootstrap district. Reserves of barite also are presumed to be large. The greatest potential for future production of metals, notably copper and gold, appears to be in the known districts or extensions of them and peripheral to deposits that are related to known or concealed plutons and thrust faults. Potential resources in deposits too low in grade to be worked profitably at the present time include all commodities that have been produced and, in addition, known, deposits of beryllium, molybdenum, tin, and phosphorite. Speculative resources in undiscovered deposits may reasonably be predicted to include all known commodities as well as others that are unsuspected. Petroleum may yet be produced from the Elko Formation and geothermal energy from the Ruby Valley and Elko areas.

Open-File Report↗

Integrated surface and borehole strong-motion, soil-response arrays in San Francisco, California: Empirical measurements of low-strain site coefficients at site class E and D soil sites

An integrated set of four borehole arrays and ten surface installations is installed in the city of San Francisco, California to measure the response of soft-soil deposits to strong earthquake ground motions. The borehole arrays extend through thick layers of soft water-saturated soils of Holocene age and older more consolidated soils of Pleistocene age into bedrock at depths up to 90 m. The surface installations are configured in pairs to provide simultaneous comparative surface measurements of soft soils and nearby rock. The rock locations also permit comparative measurements of rock as observed at the surface and in nearby boreholes. The arrays are designed to address a wide variety of scientific and engineering issues, and especially the issue of anelastic and nonlinear soil response at high strain levels as might be recorded during a large regional earthquake. Recordings of ground motions from the largest regional earthquakes which have occurred since the installation of the arrays show marked evidence of amplification as measured on the borehole and surface arrays. Implications of the results for low-strain site coefficients in present U.S. building codes are discussed.

Calfornia↗

Detrital U-Pb zircon dating of lower Ordovician syn-arc-continent collision conglomerates in the Irish Caledonides

The Early Ordovician Grampian Orogeny in the British Isles represents a classic example of collision between an oceanic island arc and a passive continental margin, starting around 480 Ma. The South Mayo Trough in western Ireland preserves a complete and well-dated sedimentary record of arc collision. We sampled sandstones and conglomerates from the Rosroe, Maumtrasna and Derryveeny Formations in order to assess erosion rates and patterns during and after arc collision. U–Pb dating of zircons reveals a provenance dominated by erosion from the upper levels of the Dalradian Supergroup (Southern Highland and Argyll Groups), with up to 20% influx from the colliding arc into the Rosroe Formation, but only 6% in the Maumtrasna Formation (~ 465 Ma). The dominant source regions lay to the northeast (e.g. in the vicinity of the Ox Mountains, 50 km distant, along strike). The older portions of the North Mayo Dalradian and its depositional basement (the Annagh Gneiss Complex) do not appear to have been important sources, while the Connemara Dalradian only plays a part after 460 Ma, when it supplies the Derryveeny Formation. By this time all erosion from the arc had effectively ceased and exhumation rates had slowed greatly. The Irish Grampian Orogeny parallels the modern Taiwan collision in showing little role for the colliding arc in the production of sediment. Negligible volumes of arc crust are lost because of erosion during accretion to the continental margin.

British Isles↗

Macrotidal subarctic environment of Turnagain and Knik Arms, Upper Cook Inlet, Alaska: sedimentology of the intertidal zone

An extensive sheet of silty sand crossed by tidal channels is exposed at low tide in Turnagain and Knik Arms, Alaska. Transportation and deposition of sediment composing this sheet is the result of strong tidal currents due to the maximum spring tidal range of approximately 11.4 m. In Turnagain and Knik Arms, the initiation of the floodtide is accompanied by the occurrence of a tidal bore that travels at a speed of 4 m/sec or more up the tidal channels. In intertidal environments in many parts of the world, physical processes of sedimentation are typically influenced by surface fauna; sedimentary structures in some zones are altered or obliterated by the activities of the infauna. However, in Turnagain and Knik Arms, virtually no macrofauna exist, and so the area provides an opportunity to study depositional processes and sedimentary structures without the masking effects of bioturbation. Suspended-sediment values for Turnagain and Knik Arms are greatest in the summer months and nearest low-tide stages. Ice floes form during winter months and, in combination with the freezing of intertidal sediment to several meters of depth, have a significant effect on sediment dispersal and on the deepening and increased stability of the tidal channels. The intertidal sediment is mainly very well sorted, medium to very fine sand and coarse silt, with a notable paucity of gravel, coarse sand, and clay. Sediment accumulates in sandbars oriented parallel to the axis of the estuary. Textural and facies patterns reflect decreasing current energy, first, as a function of distance from the mouth of the estuary and, second, as a function of topographic elevation on the sandbars. The intertidal deposits in Turnagain Arm contain a transitional upward-fining sequence which is analogous to point-bar and channel-bar successions described by other workers. The base of the sequence contains parallel-laminated sand that is overlain by mixed parallel- and cross-laminated silty sand overlain by cross-laminated silty sand. At the top of the sequence is a unit of organically rich parallel-laminated silt and sandy silt. This suite of sedimentary features and textures indicates changing current velocities and directions as bars emerge or are modified during ebb tide, and the vertical sequences could potentially be used to record intertidal bar erosion and aggradation by point- and channel-bar migration, a process carried out primarily by bed-load currents.

Journal of Sedimentary Petrology↗

Hydrologic processes controlling sulfate mobility in a small forested watershed

Hydrologic controls on sulfate mobility were investigated in a forested catchment in the Georgia Piedmont using a watershed mass balance approach. Variations in annual sulfate export were governed primarily by differences in runoff rather than by differences in sulfate deposition or in total annual precipitation. However, 2 years with similar total runoff had substantially different sulfate export. A residual analysis indicated that a shift in the concentration‐discharge relationship accounted for 72% of the difference in sulfate export and that a change in the pattern of discharge accounted for the remainder of the difference. Stream water sulfate concentrations reflected past hydrologic conditions. Concentrations at the same discharge were higher following an extended dry period than following average periods. The elevation in stream water sulfate concentrations following dry periods persisted for several months. The influence of rainfall patterns on sulfate export underscores the need for long‐term records to adequately characterize the acidification status of the watershed and to understand trends in water quality.

Georgia↗

Coal investigations on the southern margin of the Homer district, Kenai coal field, Alaska, in 1947-48

The presence of coal in the Tertiary Kenai formation of western Kenai Peninsula has been known since 1880, chiefly as exposed along the north shore of Kachemak Bay and the adjoining east shore of Cook Inlet (fig. 1). Several early attempts were made to develop a commercial mine in this area in the period 1888-1902 but none progressed beyond the prospecting stage and little coal was produced. In 1915 the mining of coal-was started at the Bluff Point mine, 1 1/2 miles west of Homer. Available records indicate that this mine produced between 20,000 and 25,000 tons of coal before closing in 1324. No further attempt at mining was made until 1946, when the Homer Coal Corporation began development near the site of the old Bluff Point mine. Development work during 1946 and 1947 included construction of a truck-loading bunker, mess hail, bunkhouse, and an incline end hoist for raising coal from the tunnel in the face of the beach bluff. Only a small amount of underground work was done in 1946 and 1947, and practically none in 1948. A preliminary step toward more extended investigation of the coal deposits of the Homer district was made by the writer, accompanied by T. J. Jolley of the U. S. Bureau of Mines, in the summer of 1946. Several days were spent in examining the principal coal exposures near Homer and collecting samples to determine the desirability of more detailed investigation. Detailed examination of the coal deposits of the Homer district was started by the Geological Survey in 1947. The period July 17 to September 14 was spent by the writer, assisted by H. C. Wagner, geologist, and L. A. Hale, field assistant, in reconnaissance of isolated coal exposures in an area extending several miles north of Homer, and in measuring detailed stratigraphic sections in the bluffs just north of Homer between Coal (Bidarki) and Fritz Creeks.

Alaska↗

Geology and mineral deposits of the Snow Camp-Saxapahaw area, central North Carolina

The Snow Camp-Saxapahaw study area, in the Carolina slate belt in the Southeastern United States, is notable for large zones of high-sulfidation alteration in arc-related metavolcanic rocks. The area has potential for additional significant pyrophyllite and related aluminosilicate refractory mineral deposits and may have potential for small- to medium-size gold deposits also associated with the high-sulfidation hydrothermal systems. The Carolina slate belt is an elongate zone of mostly low-grade metamorphic rocks of Neoproterozoic to early Paleozoic age that extends from northeastern Georgia to southern Virginia. It is dominated by volcanic rocks but locally consists of fine-grained epiclastic sedimentary rocks. Plutons and subvolcanic bodies have intruded the rocks of the Carolina slate belt in many places and have been important in controlling the metamorphism and in localizing hydrothermal alteration. The Snow Camp-Saxapahaw area is mostly underlain by volcanic and volcaniclastic rocks and lesser amounts of intrusive shallow plutons. The volcanic rocks range in composition from basalt to rhyolite; however andesites, dacites, and rhyodacites are the most abundant. The intrusive bodies are largely granite and quartz monzonite; gabbroic bodies also are common. It was possible to establish the relative ages of only part of these rocks. Two northeast-trending fault zones and fractures divide the map area into three structural blocks; the central block was tilted down to the southwest to form a grabenlike structure. Most of the hydrothermally altered rocks and all of the intensely altered zones are confined to the downdropped block, which we think may have been calderalike in origin. A major volcanic unit, the Reedy Branch Tuff, is limited to the southwestern part of the graben and may be the youngest volcanic rock in the area. Layered rocks record one or more strong folding events, but the diversity of rock types, lack of recognizable stratigraphic markers, and uneven distribution of outcrops prevented comprehensive structural studies. Except for a few late plutons and dikes, all of the rocks of the area have been metamorphosed in middle to upper greenschist facies, and contact aureoles were recognized around some of the plutons. Several relatively small bodies of granitic rock contain plagioclase grains in which primary oscillatory zoning was unaffected by metamorphism. These were interpreted to be post-metamorphic. We think that there were three separate stages of hydrothermal alteration in the complex volcanic terrane in the area. The oldest, an area of at least 8.5 square miles (22 square kilometers), was subjected to an intense hydrothermal alteration, ranging from peripheral zones of quartz-sericite-paragonite through a patchy marginal zone of pyrophyllite, andalusite, and other high-alumina minerals, to almost totally silicified core zones. The second event resulted in large areas of weak to moderate sericitic and propylitic alteration recognizable only in the Reedy Branch Tuff. The last event was related to post-metamorphic plutons. All of the pyrophyllite-andalusite deposits and perhaps most of the gold and silver mineralization can be related to the first period of hydrothermal alteration. The subsequent metamorphism did not produce significant changes in mineral species in the zones of most intense hydrothermal alteration. Gold- and silver-bearing sulfide minerals in fracture zones along the southeastern margin of the graben may also have been deposited during this earliest alteration stage. No metallic mineralization appears to have occurred during the second event. A group of molybdenum-bearing greisenlike bodies formed during the emplacement of the youngest plutons during the post-metamorphic event. One gold-bearing sulfide zone occurs in the exocontact of one such porphyritic stock.

North Carolina↗

100 Myr record of sequences, sedimentary facies and sea level change from Ocean Drilling Program onshore coreholes, US Mid-Atlantic coastal plain

We analyzed the latest Early Cretaceous to Miocene sections (???110-7Ma) in 11 New Jersey and Delaware onshore coreholes (Ocean Drilling Program Legs 150X and 174AX). Fifteen to seventeen Late Cretaceous and 39-40 Cenozoic sequence boundaries were identified on the basis of physical and temporal breaks. Within-sequence changes follow predictable patterns with thin transgressive and thick regressive highstand systems tracts. The few lowstands encountered provide critical constraints on the range of sea-level fall. We estimated paleowater depths by integrating lithofacies and biofacies analyses and determined ages using integrated biostratigraphy and strontium isotopic stratigraphy. These datasets were backstripped to provide a sea-level estimate for the past ???100 Myr. Large river systems affected New Jersey during the Cretaceous and latest Oligocene-Miocene. Facies evolved through eight depositional phases controlled by changes in accommodation, long-term sea level, and sediment supply: (1) the Barremian-earliest Cenomanian consisted of anastomosing riverine environments associated with warm climates, high sediment supply, and high accommodation; (2) the Cenomanian-early Turonian was dominated by marine sediments with minor deltaic influence associated with long-term (107 year) sea-level rise; (3) the late Turonian through Coniacian was dominated by alluvial and delta plain systems associated with long-term sea-level fall; (4) the Santonian-Campanian consisted of marine deposition under the influence of a wave-dominated delta associated with a long-term sea-level rise and increased sediment supply; (5) Maastrichtian-Eocene deposition consisted primarily of starved siliciclastic, carbonate ramp shelf environments associated with very high long-term sea level and low sediment supply; (6) the late Eocene-Oligocene was a starved siliciclastic shelf associated with moderately high sea-level and low sediment supply; (7) late early-middle Miocene consisted of a prograding shelf under a strong wave-dominated deltaic influence associated with major increase in sediment supply and accommodation due to local sediment loading; and (8) over the past 10 Myr, low accommodation and eroded coastal systems were associated with low long-term sea level and low rates of sediment supply due to bypassing. ?? 2008 The Authors. Journal compilation ?? 2008 Blackwell Publishing.

Basin Research↗

Stable isotope geochemistry of sphalerite and other mineral matter in coal beds of the Illinois and Forest City basins

Cleat and clastic dikes of Middle Pennsylvanian-age coal beds of the Illinois and Forest City basins of Illinois, Iowa, Missouri, and Kansas locally contain appreciable amounts of sphalerite within a kaolinite-pyrite-sphalerite (+ or - pyrite)-calcite paragenetic sequence. The sphalerite and associated minerals are of interest as a partial record of the history of fluids in the sedimentary basin and as possible indicators of Mississippi Valley-type mineralization. Moreover, zinc from the sphalerite may represent an exploitable by-product of coal mining and combustion.Pyrite is abundant in these coals both as fine-grained disseminated framboids that formed during early diagenesis and as coarser grained cleat fillings, etc., that formed much later. The delta 34 S values of this later pyrite, the sphalerite, and the coal organic matter range from -12 to 19 per mil. Within individual samples, however, pyrite, sphalerite, and organic matter sulfur delta 34 S values are nearly identical. This similarity strongly suggests related origins. The delta 34 S values of pyrite, sphalerite, and organic matter from coals of the Illinois basin and the central and southern Forest City basin range from -12 to 0 per mil. This range is not unique to the sphalerite-bearing coals; pyrite and organic matter from sphalerite-free high sulfur coals have similar delta 34 S values (Price and Shieh, 1979). We believe that sulfur produced by the breakdown of organosulfur compounds in the coal is incorporated into the epigenetic sulfides. In the northern Forest City basin, however, many samples have delta 34 S values between 8 and 19 per mil. These are similar to the delta 34 S values of sphalerite and pyrite from the Upper Mississippi Valley Zn-Pb district which lies northeast of the Forest City basin and north of the Illinois basin. This similarity suggests input from a Mississippi Valley-type hydrothermal system.Cleat kaolinite has delta D values of -36 to -24 per mil and delta 18 O values of 19.2 to 20.2 per mil. Assuming that clearing postdated the lignite rank of coalification implies that kaolinite was deposited between 40 degrees and 100 degrees C. At the lower temperatures, the kaolinite fluid would have had an isotopic composition similar to seawater; at the higher temperatures, it would have had a composition similar to the sphalerite-depositing fluid. Sphalerite was deposited from a fluid that was chemically and isotopically similar to the fluids responsible for the main-stage ores of the Upper Mississippi Valley Zn-Pb district (75 degrees -113 degrees C, approximately 21 equiv wt % NaCl, delta D = -65 to -3ppm, and delta 18 O = -0.9-9.9ppm). The isotopic compositions (delta 13 C = -12.4 to -2.7ppm and delta 18 O = 21.1-25.8ppm) and paragenetic positions of the cleat calcite samples are similar to those of the late-stage calcite of the Upper Mississippi Valley Zn-Pb and Illinois-Kentucky fluorspar districts. Calcite inclusion fluids had delta D (sub H 2 O) values of -80 and -58 per mil, implying a meteoric water source. At probable temperatures of 15 degrees to 75 degrees C, this calcite formed from fluids having calculated delta 18 O (sub H 2 O) values of -9 to 1 per mil, implying slight to moderate exchange with sedimentary rocks. The diagenetic-epigenetic history of fluids recorded by the cleat minerals probably began with a slightly evolved seawater, followed by a metal-bearing deep basin brine, and concluded with a cooler, slightly evolved, meteoric-water fluid.

Economic Geology↗

Preliminary evaluation of the coal resources for part of the Wilcox Group (Paleocene through Eocene), central Texas

The Wilcox Group of central Texas contains shallow (<500 ft) coal deposits that are mined for use in mine-mouth electric power generating plants. These coal deposits range in apparent rank from lignite to sub-bituminous (Tewalt, 1986), and are similar in rank and composition to shallow coal deposits in the northeast and south Texas areas (fig. 1). The coal zones and associated strata in the central Texas study area generally dip to the southeast toward the Gulf of Mexico coastline and basin center. The central Texas resource assessment area includes parts of eight counties (fig. 2). The assessment area was selected to encompass current mining areas and because of the availability of subsurface stratigraphic data in the area. The assessment area is roughly 160 miles long and 5 to 25 miles wide and generally follows the outcrop of the Paleocene - Eocene Wilcox Group in central Texas (figs. 1 and 2). Approximately 1,800 subsurface stratigraphic records from rotary and core drill holes were used to assess the resources of the central Texas assessment area. Of the 1,800 drill holes, only 168 are public data points and are primarily located in the areas that have been permitted for surface mining (fig. 2; Appendix 1). The remaining 1632 drill holes, which are distributed throughout the assessment area, were provided to the U.S. Geological Survey (USGS) on a confidential basis by various coal companies for use in regional studies. Nine coal zones were identified and assessed in the central Texas assessment area. Several other coal zones (as many as 9 unassessed zones) were identified but were not assessed due to the thinness of the coal beds or the lack of deep stratigraphic data (fig. 3). A total of 7.7 billion short tons of coal was identified in this assessment that excluded the resources within current coal mine lease areas (fig. 2). Corresponding maps were constructed to show the overburden, structure contour of the top of the coal zone, and cumulative coal-zone thickness for each of the nine coal zones. Warwick and Crowley (1995) offer a discussion of the general geologic setting and stratigraphy of the central Texas study area, and Tewalt (1986) presents a discussion of the coal quality aspects of the central Texas study area.

Open-File Report↗

An assessment of Kootenai River channel migration and riparian habitat encroachment

The lower reach of the Kootenai River in northern Idaho is dominated by large and actively migrating meander bends. Flow conditions, altered by both upstream flow reductions and by downstream backwater effects, are believed to be important geomorphological drivers throughout the reach. For example, Trout Creek Peninsula, located in an area of active meander migration, is undergoing continued bank erosion that has the potential to capture South Fork Trout Creek and result in an alteration of the Kootenai River active channel. Although chute-cutoffs are natural and common in meandering channels and can increase habitat diversity, avulsion events on regulated rivers with heavily used floodplains can also lead to loss of land and habitat. A chute-cutoff at Trout Creek Peninsula would create an island and potentially result in large volumes of erosion and deposition on private and tribal land. This could result in decreased riparian habitat and private land access along Trout Creek. To address landowner risk we refine estimates of bank erosion rates and the potential timeline for the capture of Trout Creek to inform stakeholder decisions about monitoring or managing bank erosion processes. Historical imagery, airborne and boat-mounted LiDAR, and repeat bathymetric surveys suggest that localized areas of high short-term bank erosion rates have increased to about 15 ft/yr near South Fork Trout Creek and the possibility of a chute cutoff event by 2043. Changes in bank erosion rates over time were compared to flow records to better understand how the complex flow regulation in this reach might be impacting geomorphic processes.

Idaho↗

Holocene climate on the Modoc Plateau, northern California, USA: The view from Medicine Lake

Medicine Lake is a small (165 ha), relatively shallow (average 7.3 m), intermediate elevation (2,036 m) lake located within the summit caldera of Medicine Lake volcano, Siskiyou County, California, USA. Sediment cores and high-resolution bathymetric and seismic reflection data were collected from the lake during the fall of 1999 and 2000. Sediments were analyzed for diatoms, pollen, density, grain size (sand/mud ratio), total organic carbon (TOC), and micro-scale fabric analysis. Using both 14 C (AMS) dating and tephrochronology, the basal sediments were estimated to have been deposited about 11,400 cal year BP, thus yielding an estimated average sedimentation rate of about 20.66 cm/1,000 year. The lowermost part of the core (11,400–10,300 cal year BP) contains the transition from glacial to interglacial conditions. From about 11,000–5,500 cal year BP, Medicine Lake consisted of two small, steep-sided lakes or one lake with two steep-sided basins connected by a shallow shelf. During this time, both the pollen ( Abies / Artemisia ratio) and the diatom ( Cyclotella / Navicula ratio) evidences indicate that the effective moisture increased, leading to a deeper lake. Over the past 5,500 years, the pollen record shows that effective moisture continued to increase, and the diatom record indicates fluctuations in the lake level. The change in the lake level pattern from one of the increasing depths prior to about 6,000 cal year BP to one of the variable depths may be related to changes in the morphology of the Medicine Lake caldera associated with the movement of magma and the eruption of the Medicine Lake Glass Flow about 5,120 cal year BP. These changes in basin morphology caused Medicine Lake to flood the shallow shelf which surrounds the deeper part of the lake. During this period, the Cyclotella / Navicula ratio and the percent abundance of Isoetes vary, suggesting that the level of the lake fluctuated, resulting in changes in the shelf area available for colonization by benthic diatoms and Isoetes . These fluctuations are not typical of the small number of low-elevation Holocene lake records in the region, and probably reflect the hydrologic conditions unique to Medicine Lake.

Hydrobiologia↗