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USGS2014

Delivering climate science about the Nation's fish, wildlife, and ecosystems: the U.S. Geological Survey National Climate Change and Wildlife Science Center

Changes to the Earth’s climate—temperature, precipitation, and other climate variables—pose significant challenges to our Nation’s natural resources. Managers of land, water, and living resources require an understanding of the impacts of climate change—which exacerbate ongoing stresses such as habitat alteration and invasive species—in order to design effective response strategies. In 2008, Congress created the National Climate Change and Wildlife Science Center (NCCWSC) within the U.S. Geological Survey (USGS). The center was formed to address environmental challenges resulting from climate and land-use change and to provide natural resource managers with rigorous scientific information and effective tools for decision making. Located at the USGS National Headquarters in Reston, Virginia, the NCCWSC has established eight regional Department of the Interior (DOI) Climate Science Centers (CSCs) and has invested over $93 million (through fiscal year 2013) in cutting-edge climate change research.

Fact Sheet↗

USGS2026

High and dry: The persistence of diverse coastal marsh communities depends on available upland area and connection to surrounding waters

Sea-level-rise and alterations to natural hydrology have contributed to coastal land loss. To combat coastal land loss and maintain the ecosystem services provided by marshes, marsh creation has been broadly implemented. Marsh creation projects can be performed in conjunction with the construction of elevated terrestrial ridges that seek to mimic historic delta-formed distributary ridges. Ridges and similar elevated structures, such as those surrounding created marshes, offer the opportunity to sample the ecotones between low marsh and upland areas within a small area. We sampled marsh assemblages on elevation gradients at eight sites in the Louisiana coastal zone. We identified nine marsh communities based on co-occurrence of taxa and abiotic conditions (soil salinity, percent time inundated, soil percent moisture, soil bulk density, and soil pH) with a two-step process of hierarchical clustering and random forest classification. Inundation time and salinity were identified as the most important conditions related to community composition. We used future estimates of coastal elevations based on local relative sea-level-rise estimates to make predictions of community change up to 50 years into the future. Our predictions, meant to serve as generalizations for the coastal region, indicate a near total loss of high-elevation salt marsh communities at the sites sampled. Elevation variation supports diverse marsh communities when water is allowed to flow as in a natural marsh. Hydrology regulates inundation, and by extension, salinity. Evaluating hydrologic exchange can be incorporated into decisions regarding future marsh creation to support marsh health and persistence.

Louisiana↗

USGS2014

Concentrations of selected constituents in surface-water and streambed-sediment samples collected from streams in and near an area of oil and natural-gas development, south-central Texas, 2011-13

During 2011–13, the U.S. Geological Survey, in cooperation with the San Antonio River Authority and the Guadalupe-Blanco River Authority, analyzed surface-water and streambed-sediment samples collected from 10 sites in the San Antonio River Basin to provide data for a broad range of constituents that might be associated with hydraulic fracturing and the produced waters that are a consequence of hydraulic fracturing. Among surface-water samples, all sulfide concentrations were less than the method detection limit of 0.79 milligrams per liter. Four glycols—diethylene glycol, ethylene glycol, propylene glycol, and triethylene glycol—were analyzed for in surface-water samples collected for this study, and none were detected. Of the 91 semivolatile organic compounds analyzed for this study, there were six detections, all but one of which were in storm-runoff samples. The base-flow sample collected at the San Antonio River at Goliad, Tex. (SAR Goliad), site contained bis(2-ethylhexyl) phthalate, a plasticizer in polyvinyl chloride and a constituent in hydraulic fracturing fluids. The storm-runoff samples collected at the San Antonio River near Elmendorf, Tex. (SAR Elmendorf), and Ecleto Creek at County Road 326 near Runge, Tex. (Ecleto 2), sites also contained bis(2-ethylhexyl) phthalate. The storm-runoff sample collected at the SAR Elmendorf site contained the plasticizer diethyl phthalate. Both storm-runoff samples collected at the Ecleto Creek near Runge, Tex. (Ecleto 1), and Ecleto 2 sites contained benzyl alcohol, a solvent commonly used in paints. Of the 67 volatile organic compounds analyzed in this study, there were a total of six detections, all of which were in base-flow samples. The surface-water sample collected at the SAR Elmendorf site contained bromodichloromethane, dibromochloromethane, and trichloromethane, all of which are disinfection byproducts associated with the chlorination of municipal water supplies and of treated municipal wastewater. The sample collected at the Cibolo Creek near Saint Hedwig, Tex. (Cibolo St. Hedwig), site contained toluene, a fuel additive, solvent, and industrial feedstock used to produce benzene and a constituent associated with produced waters. The Cibolo St. Hedwig site is upstream from current (2014) oil and natural-gas production areas. Dichloromethane, an industrial solvent with multiple uses, was detected in surface-water samples at both the San Antonio River at State Highway 72 near Runge, Tex. (SAR 72), and SAR Goliad sites. In streambed-sediment samples, concentrations of total saturated hydrocarbons (TSH) ranged from an estimated 260 micrograms per kilogram (μg/kg) in the less than (<) 2-millimeter (mm) size-fraction sample collected at the SAR Goliad site to 11,000 μg/kg in the <2-mm size-fraction sample collected at the Ecleto 1 site. TSH concentrations were greater in the <63-micrometer (μm) size-fraction samples than in the <2-mm size-fraction samples in streambed-sediment samples collected from 5 of the 9 sites. Total polycyclic aromatic hydrocarbons (PAHs) were calculated as the sum of the individual PAHs and alkylated PAHs. Total PAH concentrations ranged from less than the method detection limit in the <2-mm size-fraction samples collected from multiple sites to 1,600 μg/kg in the <2-mm size-fraction sample collected from the San Antonio River near McFaddin, Tex. (SAR McFaddin), site. Total PAH concentrations were greater in the <63-μm size-fraction samples than in the <2-mm size-fraction samples at 7 of the 9 sites. During collection of streambed-sediment samples, additional samples from a subset of three sites (the SAR Elmendorf, SAR 72, and SAR McFaddin sites) were processed by using a 63-µm sieve on one aliquot and a 2-mm sieve on a second aliquot for PAH and n -alkane analyses. The purpose of analyzing PAHs and n -alkanes on a sample containing sand, silt, and clay versus a sample containing only silt and clay was to provide data that could be used to determine if these organic constituents had a greater affinity for silt- and clay-sized particles relative to sand-sized particles. The greater concentrations of PAHs in the <63-μm size-fraction samples at all three of these sites are consistent with a greater percentage of binding sites associated with fine-grained (<63 μm) sediment versus coarse-grained (<2 mm) sediment. The larger difference in total PAHs between the <2-mm and <63-μm size-fraction samples at the SAR Elmendorf site might be related to the large percentage of sand in the <2-mm size-fraction sample which was absent in the <63-μm size-fraction sample. In contrast, the <2-mm size-fraction sample collected from the SAR McFaddin site contained very little sand and was similar in particle-size composition to the <63-μm size-fraction sample.

Texas↗

USGS2015

Interactions of water quality and integrated groundwater management: Examples from the United States and Europe

Groundwater is available in many parts of the world, but the quality of the water may limit its use. Contaminants can limit the use of groundwater through concerns associated with human health, aquatic health, economic costs, or even societal perception. Given this broad range of concerns, this chapter focuses on examples of how water quality issues influence integrated groundwater management. One example evaluates the importance of a naturally occurring contaminant Arsenic (As) for drinking water supply, one explores issues resulting from agricultural activities on the land surface and factors that influence related groundwater management, and the last examines unique issues that result from human-introduced viral pathogens for groundwater-derived drinking water vulnerability. The examples underscore how integrated groundwater management lies at the intersections of environmental characterization, engineering constraints, societal needs, and human perception of acceptable water quality. As such, water quality factors can be a key driver for societal decision making.

Book chapter↗

USGS1983

Analysis of spurious oscillation modes for the shallow water and Navier-Stokes equations

The origin and nature of spurious oscillation modes that appear in mixed finite element methods are examined. In particular, the shallow water equations are considered and a modal analysis for the one-dimensional problem is developed. From the resulting dispersion relations we find that the spurious modes in elevation are associated with zero frequency and large wave number (wavelengths of the order of the nodal spacing) and consequently are zero-velocity modes. The spurious modal behavior is the result of the finite spatial discretization. By means of an artificial compressibility and limiting argument we are able to resolve the similar problem for the Navier-Stokes equations. The relationship of this simpler analysis to alternative consistency arguments is explained. This modal approach provides an explanation of the phenomenon in question and permits us to deduce the cause of the very complex behavior of spurious modes observed in numerical experiments with the shallow water equations and Navier-Stokes equations. Furthermore, this analysis is not limited to finite element formulations, but is also applicable to finite difference formulations.

Computers and Fluids↗

USGS2004

Potentiometric surfaces in the Cockfield and Wilcox aquifers of southern and northeastern Arkansas, 2003

This report presents the results of water-level measurements made at wells in the Cockfield Formation and Wilcox Group of southern and northeastern Arkansas during 2003, and the water levels are displayed in potentiometric-surface maps and hydrographs. During March and April 2003, the water level was measured at 55 wells completed in the Cockfield aquifer, 13 wells completed in the Wilcox aquifer of southern Arkansas, and 43 wells completed in the Wilcox aquifer of northeastern Arkansas. The Cockfield Formation generally consists of discontinuous sand units interbedded with silt, clay, and lignite in southeastern Arkansas. Sand beds near the base of the Cockfield Formation constitute most of the Cockfield aquifer. Withdrawals from the Cockfield aquifer in the study area during 2000 totaled about 9 million gallons per day. The potentiometric surface of the Cockfield aquifer constructed from the 2003 water levels shows that regional direction of ground-water flow generally is towards the east and southeast, away from the outcrop, except in areas of intense ground-water withdrawals. Some local ground-water flow in the outcrop area is toward rivers that have eroded into the Cockfield Formation and deposited alluvium in south Bradley and Calhoun Counties (Ouachita River), and in north Dallas County (Saline River). An evaluation of 20 wells with water-level data from 1983 to 2003 shows that water levels in 15 wells have declined at a rate of -0.04 to -0.97 feet per year, and water levels in 5 wells have risen at a rate of 0.07 to 0.32 feet per year. An evaluation of the same 20 wells from 2000 to 2003 shows that water levels have declined in only 8 wells, and water levels have risen in 12 wells. The Wilcox Group is distributed throughout most of southern and eastern Arkansas. There are two study areas in southern and northeastern Arkansas. The Wilcox Group of the southern study area consists of interbedded clay, sandy clay, sand, and lignite. Thin discontinuous sand units constitute the Wilcox aquifer in the southern study area. Withdrawals from the aquifer in the southern study area were about 1 million gallons per day during 2000. The potentiometric surface of the Wilcox aquifer in the southern study area shows that regional ground-water flow generally is south and east, except in Clark County where flow is towards the Ouachita River. The Wilcox Group in the northeastern study area consists of thin interbedded lignitic sand and clays. A sand bed of about 200 feet thick in the middle to lower part of the Wilcox Group constitutes the major producing unit of the Wilcox aquifer in the northeastern study area. Withdrawals from the aquifer in the northeastern study area were about 23 million gallons per day during 2000. The potentiometric surface of the Wilcox aquifer in the northeastern study area shows that ground-water flow generally is south and east, except where ground-water withdrawals may have altered the natural direction of flow near the centers of pumping at Paragould and West Memphis. An evaluation of 27 wells with water-level data from 1983 to 2003 in the northeastern study area shows that water levels in all 27 wells have been declining at a rate of -0.17 to -1.73 feet per year. An evaluation of the same 27 wells from 2000 to 2003 shows that water levels in 18 wells have risen and in 9 wells have declined.

Scientific Investigations Report↗

USGS2008

Simulations of Ground-Water Flow, Transport, Age, and Particle Tracking near York, Nebraska, for a Study of Transport of Anthropogenic and Natural Contaminants (TANC) to Public-Supply Wells

Contamination of public-supply wells has resulted in public-health threats and negative economic effects for communities that must treat contaminated water or find alternative water supplies. To investigate factors controlling vulnerability of public-supply wells to anthropogenic and natural contaminants using consistent and systematic data collected in a variety of principal aquifer settings in the United States, a study of Transport of Anthropogenic and Natural Contaminants to public-supply wells was begun in 2001 as part of the U.S. Geological Survey National Water-Quality Assessment Program. The area simulated by the ground-water flow model described in this report was selected for a study of processes influencing contaminant distribution and transport along the direction of ground-water flow towards a public-supply well in southeastern York, Nebraska. Ground-water flow is simulated for a 60-year period from September 1, 1944, to August 31, 2004. Steady-state conditions are simulated prior to September 1, 1944, and represent conditions prior to use of ground water for irrigation. Irrigation, municipal, and industrial wells were simulated using the Multi-Node Well package of the modular three-dimensional ground-water flow model code, MODFLOW-2000, which allows simulation of flow and solutes through wells that are simulated in multiple nodes or layers. Ground-water flow, age, and transport of selected tracers were simulated using the Ground-Water Transport process of MODFLOW-2000. Simulated ground-water age was compared to interpreted ground-water age in six monitoring wells in the unconfined aquifer. The tracer chlorofluorocarbon-11 was simulated directly using Ground-Water Transport for comparison with concentrations measured in six monitoring wells and one public supply well screened in the upper confined aquifer. Three alternative model simulations indicate that simulation results are highly sensitive to the distribution of multilayer well bores where leakage can occur and that the calibrated model resulted in smaller differences than the alternative models between simulated and interpreted ages and measured tracer concentrations in most, but not all, wells. Results of the first alternative model indicate that the distribution of young water in the upper confined aquifer is substantially different when well-bore leakage at known abandoned wells and test holes is removed from the model. In the second alternative model, simulated age near the bottom of the unconfined aquifer was younger than interpreted ages and simulated chlorofluorocarbon-11 concentrations in the upper confined aquifer were zero in five out of six wells because the conventional Well Package fails to account for flow between model layers though well bores. The third alternative model produced differences between simulated and interpreted ground-water ages and measured chlorofluorocarbon-11 concentrations that were comparable to the calibrated model. However, simulated hydraulic heads deviated from measured hydraulic heads by a greater amount than for the calibrated model. Even so, because the third alternative model simulates steady-state flow, additional analysis was possible using steady-state particle tracking to assess the contributing recharge area to a public supply well selected for analysis of factors contributing to well vulnerability. Results from particle-tracking software (MODPATH) using the third alternative model indicates that the contributing recharge area of the study public-supply well is a composite of elongated, seemingly isolated areas associated with wells that are screened in multiple aquifers. The simulated age distribution of particles at the study public-supply well indicates that all water younger than 58 years travels through well bores of wells screened in multiple aquifers. The age distribution from the steady-state model using MODPATH estimates the youngest 7 percent of the water to have a flow-weighted mean age

Scientific Investigations Report↗

USGS2010

A Compilation of Spatial Datasets and Surface-Water and Ground-Water Data from the U.S. Geological Survey and Other Federal and Oklahoma State Agencies for the Kickapoo Tribe of Oklahoma

This report contains spatial datasets of natural and anthropogenic features and spatial datasets detailing surface-water, ground-water, and other types of environmental information collected in and surrounding Kickapoo Tribal Lands. Spatial datasets were compiled from Federal and Oklahoma State agencies. Surface-water, ground-water, and other types of environmental information of natural and anthropogenic features were compiled from USGS National Water Information System database, Oklahoma Department of Environmental Quality online Geographic Information System data viewer, Oklahoma Water Resources Board online Water Information Mapping System, and U.S. Environmental Protection Agency online Modernized STORET database. These spatial datasets were compiled from many different sources with varying quality. Because of the different sources, features common to multiple layers may not overlay exactly. Users should check the metadata to determine proper use of these data. These data were not checked for accuracy or completeness. Should a question of accuracy or completeness arise, the user should contact the originator cited in the metadata.

Data Series↗

USGS1989

Yield and quality of ground water from stratified-drift aquifers, Taunton River basin, Massachusetts : executive summary

Water shortages are a chronic problem in parts of the Taunton River basin and are caused by a combination of factors. Water use in this part of the Boston metropolitan area is likely to increase during the next decade. The Massachusetts Division of Water Resources projects that about 50% of the cities and towns within and on the perimeter of the basin may have water supply deficits by 1990 if water management projects are not pursued throughout the 1980s. Estimates of the long-term yield of the 26 regional aquifers indicate that the yields of the two most productive aquifers equal or exceed 11.9 and 11.3 cu ft/sec, 90% of the time, respectively, if minimum stream discharge is maintained at 99.5% flow duration. Eighteen of the 26 aquifers were pumped for public water supply during 1983. Further analysis of the yield characteristics of these 18 aquifers indicates that the 1983 pumping rate of each of these 18 aquifers can be sustained at least 70% of the time. Selected physical properties and concentrations of major chemical constituents in groundwater from the stratified-drift aquifers at 80 sampling sites were used to characterize general water quality in aquifers throughout the basin. The pH of the groundwater ranged from 5.4 to 7.0. Natural elevated concentrations of Fe and Mn in water in the stratified-drift aquifers are present locally in the basin. Natural concentrations of these two metals commonly exceed the limits of 0.3 mg/L for Fe and 0.05 mg/L for Mn recommended for drinking water. Fifty-one analyses of selected trace metals in groundwater samples from stratified-drift aquifers throughout the basin were used to characterize trace metal concentrations in the groundwater. Of the 10 constituents sampled that have US EPA limits recommended for drinking water, only the Pb concentration in water at one site (60 micrograms/L) exceeded the recommended limit of 50 micrograms/L. Analyses of selected organic compounds in water in the stratified-drift aquifers at 74 locations revealed that 13 of the sample contained one or more of the following compounds: chloroform; carbon tetrachloride; dichloroethane; dichloroethylene; tetrachloroethylene; and, toluene. (Lantz-PTT)

Water-Resources Investigations Report↗

USGS2002

Simulated pond-aquifer interactions under natural and stressed conditions near Snake Pond, Cape Cod, Massachusetts

A numerical model was used to simulate pond-aquifer interactions under natural and stressed conditions near Snake Pond, Cape Cod, Massachusetts. Simulation results show that pond-bottom hydraulic conductivity, which represents the degree of hydraulic connection between the pond and the aquifer, is an important control on these interactions. As this parameter was incrementally increased from 10 to 350 feet per day, the rate of ground-water inflow into the pond under natural conditions increased by about 250 percent, the associated residence times of water in the pond decreased by about 50 percent, and ground-water inflow to the pond shifted closer to the pond shore. Most ground-water inflow (90 to 98 percent) was in the upper model layer, which corresponded to shallow, near-shore areas of the pond, over the entire range of pond-bottom hydraulic conductivity. Ground-water flow paths into the pond became more vertical, the contributing area to the pond became larger, and the pond captured water from greater depths in the aquifer as the hydraulic conductivity of the pond bottom was increased. The pond level, however, remained nearly constant, and regional ground-water levels and gradients differed little over the range of pond-bottom hydraulic conductivity, indicating that calibrated models with similar head solutions can have different pond-aquifer interaction characteristics. Hydrologic stresses caused by a simulated plume-containment system that specifies the extraction and injection of large volumes of ground water near the pond increased the pond level by about 0.4 foot and ground-water inflow rates into the pond by about 25 percent. Several factors related to the operation of the simulated containment system are affected by the hydraulic conductivity of the pond bottom. With increasing pond-bottom hydraulic conductivity, the amount of injected water that flows into Snake Pond increased and the amount of water recirculated between extraction and injection wells decreased. Comparison of simulations in which pond-bottom hydraulic conductivity was varied throughout the pond and simulations in which hydraulic conductivity was varied only in areas corresponding to shallow, near-shore areas of the pond indicate that the simulated hydraulic conductivity of the pond bottom in deeper parts of the pond had little effect on pond-aquifer interactions under both natural and stressed conditions.

Massachusetts↗

USGS1988

Simulation of ground-water flow in aquifers along the Susquehanna River in Columbia County, Pennsylvania

A numerical model of groundwater flow was developed for a 10.3 sq mi area along the Susquehanna River in Columbia County, east central Pennsylvania. Groundwater in the model area primarily is in secondary openings in the carbonate--and clastic-rock aquifers and primary openings in the glacial-outwash aquifer that discontinuously overlies bedrock. The groundwater flow model was calibrated under average steady-state conditions for 1981. The simulated 1981 water budget indicates an average inflow rate of 7.24 cu ft/sec. Of this, 93% is recharge from precipitation and 6.6% is boundary flow. 62% of the outflow is leakage to streams, 21% to pumpage, and 17% to evapotranspiration. The model was calibrated under transient conditions for December 22, 1980 through April 21, 1982. Water level fluctuations caused by natural stresses were more successfully simulated than those caused by pumping stresses. Three 10-year, hypothetical stress periods were simulated with the calibrated, transient model. The general impact of three pumping schemes under hypothetical drought and drought-recovery conditions were simulated. (USGS)

Pennyslvania↗

USGS1994

Ground-water quality and geochemistry, Carson Desert, western Nevada

Aquifers in the Carson Desert are the primary source of drinking water, which is highly variable in chemical composition. In the shallow basin-fill aquifers, water chemistyr varies from a dilute calcium bicarbonate-dominated water beneath the irrigated areas to a saline sodium chloride- dominated water beneath unirrigated areas. Water samples from the shallow aquifers commonly have dissolved solids, chloride, magnesium, sulfate, arsenic, and manganese concentrations that exceed State of Nevada drinking-water standards. Water in the intermediante basin-fill aquifers is a dilute sodium bicarbonate type in the Fallon area and a distinctly more saline sodium chloride type in the Soda Lake-Upsal Hogback area. Dissolved solids, chloride, arsenic, fluoride, and manganese concen- trations commonly exceed drinking-water standards. The basalt aquifer contains a dilute sodium bicarbonate chloride water. Arsenic concentrations exceed standards in all sampled wells. The concen- trations of major constituents in ground water beneath the southern Carson Desert are the result of evapotranspiration and natural geochemical reactions with minerals derived mostly from igneous rocks. Water with higher concentrations of iron and manganese is near thermodynamic equilibrium with siderite and rhodochrosite and indicates that these elements may be limited by the solubility of their respective carbonate minerals. Naturally occurring radionuclides (uranium and radon-222) are present in ground water from the Carson Desert in concen- tratons higher than proposed drinking-water standards. High uranium concentrations in the shallow aquifers may be caused by evaporative concentration and the release of uranium during dissolution of iron and manganese oxides or the oxidation of sedimentary organic matter that typically has elevated uranium concentrations. Ground water in the Carson Desert does not appear to have be contaminated by synthetic organic chemicals.

Open-File Report↗

USGS2022

Hydrology of the Yucaipa groundwater subbasin: Characterization and integrated numerical model, San Bernardino and Riverside Counties, California

Executive Summary Water management in the Santa Ana River watershed in San Bernardino and Riverside Counties in southern California is a complex task with various water purveyors navigating geographic, geologic, hydrologic, and political challenges to provide a reliable water supply to stakeholders. As the population has increased throughout southern California, so has the demand for water. The Yucaipa groundwater subbasin (hereafter referred to as “Yucaipa subbasin”), one of nine groundwater subbasins in what the California Department of Water Resources (DWR) refers to as the Upper Santa Ana Valley groundwater basin (California Department of Water Resources, 2016; the DWR naming convention is used within this report), is no exception; steady population growth since the 1940s and changes in water use has forced local water purveyors to regularly adapt their water infrastructure to meet demand. Groundwater has historically been the dominant source of water in the Yucaipa subbasin although recently, imported water via the California State Water Project has augmented the total water supply. Despite the influx of imported water, overall demand for groundwater continues to rise, and there is concern by local water managers that groundwater levels may adversely impact water supply and (or) decline to a point where it will be uneconomical to produce water, severely limiting the ability of local agencies to meet water-supply demand. To better understand the hydrogeology and water resources in the Yucaipa subbasin, the U.S. Geological Survey (USGS) and the San Bernardino Valley Municipal Water District initiated a cooperative study to understand the hydrogeologic system of the Yucaipa subbasin and in the encompassing Yucaipa Valley watershed (YVW). A three-dimensional hydrogeologic framework model was constructed to quantify the structure and extent of hydrogeologic units. Historical and present-day groundwater conditions were characterized to evaluate the groundwater-flow system. Lastly, the Yucaipa Integrated Hydrological Model (YIHM) was developed to simulate the integrated surface-water and groundwater systems, including natural and anthropogenic (that is, human influenced) recharge and discharge throughout the study area from 1947 to 2014. The Yucaipa subbasin is an inland groundwater basin located about 12 miles (mi) southeast of the City of San Bernardino and about 75 mi east of Los Angeles, California. The subbasin encompasses about 39 square miles (mi 2 ), including the City of Yucaipa. The geographic extent of the Yucaipa subbasin was established by the California Department of Water Resources, who defined the boundaries of the subbasin based on hydrogeologic transitions between crystalline rock and basin-fill sediments, active fault strands, surface-water drainage divides, and a portion of an adjudicated groundwater management boundary. Two groundwater subbasins of the Upper Santa Ana Valley groundwater basin are adjacent to the Yucaipa subbasin, the San Bernardino groundwater subbasin to the west and the San Timoteo groundwater subbasin to the south. The Yucaipa subbasin is encompassed by the YVW, which is in turn comprised of three sub-watersheds that represent surface-water flow across and within the Yucaipa subbasin. Although the Yucaipa subbasin is the specific area of interest for this study, the entire YVW was considered for the purposes of characterizing the hydrogeology of the Yucaipa subbasin and for development of the YIHM. The purposes of this report are to (1) describe the hydrologic and hydrogeologic settings of the Yucaipa subbasin and aquifer system, (2) describe the construction and calibration of the fully coupled groundwater and surface-water flow model for the Yucaipa subbasin and the encompassing YVW, referred to as the YIHM, and (3) present numerical results, including water budgets and hydraulic heads, and the effect of pumping and climate stresses (precipitation and temperature) on water-budget components.

California↗

USGS2013

An isotope-dilution standard GC/MS/MS method for steroid hormones in water

An isotope-dilution quantification method was developed for 20 natural and synthetic steroid hormones and additional compounds in filtered and unfiltered water. Deuterium- or carbon-13-labeled isotope-dilution standards (IDSs) are added to the water sample, which is passed through an octadecylsilyl solid-phase extraction (SPE) disk. Following extract cleanup using Florisil SPE, method compounds are converted to trimethylsilyl derivatives and analyzed by gas chromatography with tandem mass spectrometry. Validation matrices included reagent water, wastewater-affected surface water, and primary (no biological treatment) and secondary wastewater effluent. Overall method recovery for all analytes in these matrices averaged 100%; with overall relative standard deviation of 28%. Mean recoveries of the 20 individual analytes for spiked reagent-water samples prepared along with field samples analyzed in 2009–2010 ranged from 84–104%, with relative standard deviations of 6–36%. Detection levels estimated using ASTM International’s D6091–07 procedure range from 0.4 to 4 ng/L for 17 analytes. Higher censoring levels of 100 ng/L for bisphenol A and 200 ng/L for cholesterol and 3-beta-coprostanol are used to prevent bias and false positives associated with the presence of these analytes in blanks. Absolute method recoveries of the IDSs provide sample-specific performance information and guide data reporting. Careful selection of labeled compounds for use as IDSs is important because both inexact IDS-analyte matches and deuterium label loss affect an IDS’s ability to emulate analyte performance. Six IDS compounds initially tested and applied in this method exhibited deuterium loss and are not used in the final method.

Book chapter↗

USGS2025

Arsenic accumulation in Sonora Mud Turtles (Kinosternon sonoriense) in an unusual freshwater food web

Montezuma Well is an unusual fishless, spring-fed, desert wetland in central Arizona. Water in the wetland is naturally enriched with > 100 µg/l dissolved geogenic arsenic (As) and supports a simple aquatic food web dominated by a small number of endemic invertebrate species that achieve high abundances. Previous studies of As among various environmental compartments and organisms in Montezuma Well did not include omnivorous Sonora Mud turtles ( Kinosternon sonoriense ) despite their potential importance in the As cycle by virtue of their substantial biomass and role as top predators. We measured As concentrations in water, sediment, and organisms (macrophytes, amphipods, insects, leeches, and turtles) representing a range of trophic levels in order to document the importance of turtles at the apex of the Montezuma Well food web and in the As cycle. Concentrations of As in turtles varied according to tissue type. The greatest values (up to 26.77 mg/kg dry weight) were in the scutes of 1 of our oldest turtles (31.5 yrs). These elevated concentrations may be due to the affinity of As to react with sulfur in the keratin of scutes, and therefore might reflect duration of exposure in long-lived turtles. Although As concentrations generally tend to decrease when moving up to higher trophic levels in a food web, our results were different. Relatively elevated concentrations reported in sediments by us and a previous study declined in plant samples as expected. Amphipod concentrations increased but then decreased again in 3 of their invertebrate predators. Arsenic concentrations in endemic leeches were extremely elevated with a mean value of 72.2 mg/kg. The mean concentration of As in turtles was 7.08 mg/kg across tissue types and was greater than the plants or invertebrates they eat, with the notable exception of leeches, which have been proposed to be part of their diet.

Arizona↗

USGS2022

Quality of surface water in Missouri, water year 2020

The U.S. Geological Survey, in cooperation with the Missouri Department of Natural Resources, monitors stations designed for the Ambient Water-Quality Monitoring Network, a collection of stations that monitor streams and springs in Missouri. During water year 2020 (October 1, 2019, through September 30, 2020), the U.S. Geological Survey collected water-quality data at 72 stations: 70 Ambient Water-Quality Monitoring stations and 2 U.S. Geological Survey National Water Quality Network stations. Among the stations in this report, four stations have data from additional sampling completed in cooperation with the U.S. Army Corps of Engineers. Water-quality analyses are provided for dissolved oxygen, specific conductance, water temperature, suspended solids, suspended sediment, Escherichia coli bacteria, fecal coliform bacteria, dissolved nitrate plus nitrite as nitrogen, total phosphorus, dissolved and total recoverable lead and zinc, and selected pesticide compounds. Monitoring stations have been classified based on the physiographic province or primary land use in the watershed or based on the unique hydrologic characteristics of the waterbodies (springs, large rivers) monitored. A summary of hydrologic conditions including peak streamflows, monthly mean streamflows, and 7-day low flows also are provided for representative streamgages in the State.

Missouri↗

USGS2012

Dissolved methane in New York groundwater, 1999-2011

New York State is underlain by numerous bedrock formations of Cambrian to Devonian age that produce natural gas and to a lesser extent oil. The first commercial gas well in the United States was dug in the early 1820s in Fredonia, south of Buffalo, New York, and produced methane from Devonian-age black shale. Methane naturally discharges to the land surface at some locations in New York. At Chestnut Ridge County Park in Erie County, just south of Buffalo, N.Y., several surface seeps of natural gas occur from Devonian black shale, including one behind a waterfall. Methane occurs locally in the groundwater of New York; as a result, it may be present in drinking-water wells, in the water produced from those wells, and in the associated water-supply systems (Eltschlager and others, 2001). The natural gas in low-permeability bedrock formations has not been accessible by traditional extraction techniques, which have been used to tap more permeable sandstone and carbonate bedrock reservoirs. However, newly developed techniques involving horizontal drilling and high-volume hydraulic fracturing have made it possible to extract previously inaccessible natural gas from low-permeability bedrock such as the Marcellus and Utica Shales. The use of hydraulic fracturing to release natural gas from these shale formations has raised concerns with water-well owners and water-resource managers across the Marcellus and Utica Shale region (West Virginia, Pennsylvania, New York and parts of several other adjoining States). Molofsky and others (2011) documented the widespread natural occurrence of methane in drinking-water wells in Susquehanna County, Pennsylvania. In the same county, Osborn and others (2011) identified elevated methane concentrations in selected drinking-water wells in the vicinity of Marcellus gas-development activities, although pre-development samples were not available for comparison. In order to manage water resources in areas of gas-well drilling and hydraulic fracturing in New York, the natural occurrence of methane in the State's aquifers needs to be documented. This brief report presents a compilation of data on dissolved methane concentrations in the groundwater of New York available from the U.S. Geological Survey (USGS) National Water Information System (NWIS) (http://waterdata.usgs.gov/nwis).

New York↗

USGS1972

Trends in ground-water levels in Wisconsin, 1967-1971

This report supplements the Wisconsin Geological and Natural History Survey, Information Circular No.9, "Trends in Ground-Water Levels in Wisconsin through 1966". It describes, by hydrographs, the ground-water level trends in Wisconsin for the period 1967-1971. All current observation wells with more than three years of record are included; records of observation wells discontinued since 1967 and records of wells with less than three years of record are not included. Explanatory and interpretive material is in Circular 9.

Wisconsin↗