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A pressure-packer system for conducting rising head tests in water table wells

The pressure system developed for fully-saturated well screens has been modified for conducting rising head tests in water table wells installed in highly permeable aquifers. The pressure system consists of a compressed air source and 1 inch diameter PVC piping with a packer attached at the end. The pressure system was evaluated in a series of rising head tests conducted in a well at a Superfund site in New England. The well was tested with slugs and with the pressure system. Within each technique, estimates of hydraulic conductivity showed no difference. Comparison of hydraulic conductivity estimates between techniques (slug test vs. pressure test) showed differences due to stratigraphy. The interval tested using slug tests crossed two stratigraphic units; the pressure system tested only one of these units. We conclude that the pressure system may be used to characterize the vertical hydraulic conductivity distribution in a series of successive tests by changing the packer position and the screened interval tested.

Journal of Hydrology↗

Small anthropogenic landforms from past charcoal production control moisture dynamics and chemistry in northcentral Appalachian soils

Throughout the northeastern United States (U.S.) and Europe, relict charcoal hearths (RCHs) are regularly being discovered in proximity to furnaces once used for the extraction of metal from ore or quick-lime production; charcoal produced in hearths was used as a furnace fuel. Given previous research has shown that topographic and subsurface disturbance can be great when a hearth is constructed, we hypothesize that hearth construction alters surface hydrology and soil chemistry in environments in and near hearths. We used a landscape classification process to identify 6,758 hearths near furnaces at Greenwood and Pine Grove Furnace State Park, central and southcentral Pennsylvania, U.S. Two types of digital elevation model wetness indexes were used to quantify surface hydrology effects in and around hearths. Modeled wetness conditions were compared to field soil volumetric water content in RCHs near Greenwood Furnace State Park. Modeled wetness indexes indicate that RCH interiors are significantly wetter than RCH rim areas; RCHs are acting as a landscape moisture sink. Results also indicate that RCHs on slopes result in downslope drier conditions below RCHs. Field measured volumetric water content indicates that as distance from the center of the hearth increases, soil moisture significantly decreases. Geomorphic position was found to not be related to RCH wetness. Soil from RCHs, compared to nearby native soils, has significantly higher total C, a lower Mehlich 3 extractable acidity, higher Ca and P. No trend was evident with RCH soil chemistry and geomorphic position. The high frequency of RCH occurrence, in proximity to the furnace’s RCHs supported, suggests that RCHs today could locally be an important niche for understory flora and fauna. Further research could explore how RCHs might be affecting surrounding plant populations and how within RCH patterns, especially on hillslopes, might represent a distinctly different scale of physical and chemical variability.

Pennsylvania↗

Estimating formation properties from early-time oscillatory water levels in a pumped well

Hydrologists often attempt to estimate formation properties from aquifer tests for which only the hydraulic responses in a pumped well are available. Borehole storage, turbulent head losses, and borehole skin, however, can mask the hydraulic behavior of the formation inferred from the water level in the pumped well. Also, in highly permeable formations or in formations at significant depth below land surface, where there is a long column of water in the well casing, oscillatory water levels may arise during the onset of pumping to further mask formation responses in the pumped well. Usually borehole phenomena are confined to the early stages of pumping or recovery, and late-time hydraulic data can be used to estimate formation properties. In many instances, however, early-time hydraulic data provide valuable information about the formation, especially if there are interferences in the late-time data. A mathematical model and its Laplace transform solution that account for inertial influences and turbulent head losses during pumping is developed for the coupled response between the pumped borehole and the formation. The formation is assumed to be homogeneous, isotropic, of infinite areal extent, and uniform thickness, with leakage from an overlying aquifer, and the screened or open interval of the pumped well is assumed to fully penetrate the pumped aquifer. Other mathematical models of aquifer flow can also be coupled with the equations describing turbulent head losses and the inertial effects on the water column in the pumped well. The mathematical model developed in this paper is sufficiently general to consider both underdamped conditions for which oscillations arise, and overdamped conditions for which there are no oscillations. Through numerical inversion of the Laplace transform solution, type curves from the mathematical model are developed to estimate formation properties through comparison with the measured hydraulic response in the pumped well. The mathematical model is applied to estimate formation properties from a singlewell test conducted near Waialua, Oahu, Hawaii. At this site, both the drawdown and recovery showed oscillatory water levels in the pumped well, and a step-drawdown test showed that approximately 86% of the drawdown is attributed to turbulent head losses. Analyses at this site using late-time drawdown data were confounded by the noise present in the measured water levels due primarily to nearby irrigation wells and ocean tides. By analyzing the early-time oscillatory recovery data at the Waialua site, upper and lower bounds were placed on the transmissivity, T, storage coefficient, S, and the leakance of the confining unit, K′/B′. The upper and lower bounds on T differ by a factor of 2. Upper and lower bounds on S and K′/B′ are much larger, because drawdown stabilized relatively quickly after the onset of pumping.

Journal of Hydrology↗

Tracking the sources of metals to the San Juan River, Four Corners Region, USA: An introduction to the thematic issue

Surface water quantity and quality is important for arid and semi-arid regions where many people, including underserved and Indigenous communities, rely on a scarce resource for drinking water, irrigation, livestock and ceremonial uses. The southwestern United States, and specifically the Four Corners Region (Colorado, Arizona, New Mexico and Utah), is an example of this situation. Elevated concentrations of metals including aluminium, arsenic and lead were identified in previous studies and this study in the San Juan River from below the Navajo Dam, through the Navajo Nation to Mexican Hat, Utah. An interdisciplinary team applied approaches and principles of geology, geochemistry, geomorphology, hydrology and statistics to gain a better understanding of the tributaries supplying the source(s) of metals to the San Juan River. This introductory paper provides an overview of the ‘Metal geochemical fingerprinting to identify sub-watershed source contributions to surface water at a regional arid watershed scale, Four Corners Region, USA’ thematic collection . An overview of sampling sites, techniques and potential sources of metals is provided. Approaches used in this study could be applied to investigations in similar systems globally.

Four Corners region↗

Geologic map of the north polar region of Mars

The north polar region of Mars occurs within the central and lowest part of the vast northern plains of Mars and is dominated by the roughly circular north polar plateau, Planum Boreum. The northern plains formed very early in Martian time and have collected volcanic flows and sedimentary materials shed from highland sources. Planum Boreum has resulted from the accumulation of water ice and dust particles. Extensive, uncratered dune fields adjacent to Planum Boreum attest to the active and recent transport and accumulation of sand. Our geologic map of Planum Boreum is the first to record its entire observable stratigraphic record using the various post-Viking image and topography datasets released before 2009. We also provide much more detail in the map than previously published, including some substantial revisions based on new data and observations. The available data have increased and improved immensely in quantity, resolution, coverage, positional accuracy, and spectral range, enabling us to resolve previously unrecognized geomorphic features, stratigraphic relations, and compositional information. We also employ more carefully prescribed and effective mapping methodologies and digital techniques, as well as formatting guidelines. The foremost aspect to our mapping approach is how geologic units are discriminated based primarily on their temporal relations with other units as expressed in unit contacts by unconformities or by gradational relations. Whereas timing constraints of such activity in the north polar region are now better defined stratigraphically, they remain poorly constrained chronologically. The end result is a new reconstruction of the sedimentary, erosional, and structural histories of the north polar region and how they may have been driven by climate conditions, available geologic materials, and eolian, periglacial, impact, magmatic, hydrologic, and tectonic activity.

Scientific Investigations Map↗

Methodology for hydrologic evaluation of a potential surface mine: Loblolly Branch basin, Tuscaloosa County, Alabama

Methodology for evaluating premining hydrology and postmining effects of mining and reclamation on the hydrology of an area is presented for a potential mine-permit area of 1,680 acres in the Warrior Coal Field, northwestern Alabama. Information is included on climate, geology, soil-water relations, vegetation, surface water, ground water, and quality of water. Estimation techniques are used to develop data for reconstructed topography, soil-water relations, vegetation cover, peak flows, flow volumes, soil losses, and sediment yields. Streamflow response of the basin is described by the variable-source-area concept; nearly all water moving from slopes flows through coarse-textured soils and unconsolidated sand and gravel deposits that are underlain by an impermeable clay zone. The resultant peak discharges per unit area are small to moderate, and there is very little erosion of slopes or channels. Susceptibility of the soils to compaction by heavy machines and the effects of compaction on soil-water relations are demonstrated. Regression and empirical methods for evaluating streamflow characteristics are compared. Estimates of peak discharges made with four methods are divergent, particularly for recurrence intervals of 2, 5, and 10 years; divergence is less for 25-, 50-, and 100-year discharges. The Universal Soil Loss Equation (USLE) and sediment-delivery ratios are used to estimate sediment yields for various land and cover conditions from premining until 20 years after reclamation would begin. A premining estimate of sediment yield made with the Universal Soil Loss Equation and a sediment-delivery ratio is about 2.5 times larger than an estimate made with the sediment rating curve-flow duration method. Research and data needs are discussed regarding: (1) An improved understanding of the hydrology of small, very ,permeable, upland basins; (2) alternative methods for estimating streamflow and sediment yield of such basins; (3) field evaluation of permeability and erodibility of soils on reclaimed areas; and (4) better understanding of ground-water hydrology and geochemistry of the coal-bearing Pottsville Formation before and after mining.

Alabama↗

Genetic and grade and tonnage models for sandstone-hosted roll-type uranium deposits, Texas Coastal Plain, USA

The coincidence of a number of geologic and climatic factors combined to create conditions favorable for the development of mineable concentrations of uranium hosted by Eocene through Pliocene sandstones in the Texas Coastal Plain. Here 254 uranium occurrences, including 169 deposits, 73 prospects, 6 showings and 4 anomalies, have been identified. About 80 million pounds of U 3 O 8 have been produced and about 60 million pounds of identified producible U 3 O 8 remain in place. The development of economic roll-type uranium deposits requires a source, large-scale transport of uranium in groundwater, and deposition in reducing zones within a sedimentary sequence. The weight of the evidence supports a source from thick sequences of volcanic ash and volcaniclastic sediment derived mostly from the Trans-Pecos volcanic field and Sierra Madre Occidental that lie west of the region. The thickest accumulations of source material were deposited and preserved south and west of the San Marcos arch in the Catahoula Formation. By the early Oligocene, a formerly uniformly subtropical climate along the Gulf Coast transitioned to a zoned climate in which the southwestern portion of Texas Coastal Plain was dry, and the eastern portion humid. The more arid climate in the southwestern area supported weathering of volcanic ash source rocks during pedogenesis and early diagenesis, concentration of uranium in groundwater and movement through host sediments. During the middle Tertiary Era, abundant clastic sediments were deposited in thick sequences by bed-load dominated fluvial systems in long-lived channel complexes that provided transmissive conduits favoring transport of uranium-rich groundwater. Groundwater transported uranium through permeable sandstones that were hydrologically connected with source rocks, commonly across formation boundaries driven by isostatic loading and eustatic sea level changes. Uranium roll fronts formed as a result of the interaction of uranium-rich groundwater with either (1) organic-rich debris adjacent to large long-lived fluvial channels and barrier–bar sequences or (2) extrinsic reductants entrained in formation water or discrete gas that migrated into host units via faults and along the flanks of salt domes and shale diapirs. The southwestern portion of the region, the Rio Grande embayment, contains all the necessary factors required for roll-type uranium deposits. However, the eastern portion of the region, the Houston embayment, is challenged by a humid environment and a lack of source rock and transmissive units, which may combine to preclude the deposition of economic deposits. A grade and tonnage model for the Texas Coastal Plain shows that the Texas deposits represent a lower tonnage subset of roll-type deposits that occur around the world, and required aggregation of production centers into deposits based on geologic interpretation for the purpose of conducting a quantitative mineral resource assessment.

Texas↗

Chester County ground-water atlas, Chester County, Pennsylvania

Chester County encompasses 760 square miles in southeastern Pennsylvania. Groundwater-quality studies have been conducted in the county over several decades to address specific hydrologic issues. This report compiles and describes water-quality data collected during studies conducted mostly after 1990 and summarizes the data in a county-wide perspective. In this report, water-quality constituents are described in regard to what they are, why the constituents are important, and where constituent concentrations vary relative to geology or land use. Water-quality constituents are grouped into logical units to aid presentation: water-quality constituents measured in the field (pH, alkalinity, specific conductance, and dissolved oxygen), common ions, metals, radionuclides, bacteria, nutrients, pesticides, and volatile organic compounds. Water-quality constituents measured in the field, common ions (except chloride), metals, and radionuclides are discussed relative to geology. Bacteria, nutrients, pesticides, and volatile organic compounds are discussed relative to land use. If the U.S. Environmental Protection Agency (USEPA) or Chester County Health Department has drinking water standards for a constituent, the standards are included. Tables and maps are included to assist Chester County residents in understanding the water-quality constituents and their distribution in the county. Ground water in Chester County generally is of good quality and is mostly acidic except in the carbonate rocks and serpentinite, where it is neutral to strongly basic. Calcium carbonate and magnesium carbonate are major constituents of these rocks. Both compounds have high solubility, and, as such, both are major contributors to elevated pH, alkalinity, specific conductance, and the common ions. Elevated pH and alkalinity in carbonate rocks and serpentinite can indicate a potential for scaling in water heaters and household plumbing. Low pH and low alkalinity in the schist, quartzite, and gneiss rocks can indicate a potential for corrosive water. The only constituent measured in the field that has a USEPA Secondary Maximum Contaminant Level (SMCL) is pH. The SMCL for pH is 6.5-8.5; 64 percent of samples analyzed for pH were acidic (below pH 6.5). Only 1 percent of samples were basic (above pH 8.5). Of the common ions, the USEPA has SMCLs for chloride, sulfate, and total dissolved solids. The USEPA has a SMCL and a Primary Maximum Contaminant Level (PMCL) for fluoride. Chloride is more closely related to land use than geology. In Chester County, chloride exceeded the SMCL (250 mg/L) only in 5 percent of the services (commercial services, community services, and military) land-use areas. No samples analyzed for sulfate exceeded the SMCL (250 mg/L). Only 3 percent of samples analyzed for total dissolved solids exceeded the SMCL (500 milligrams per liter) (mg/L). No samples analyzed for fluoride equaled or exceeded the SMCL (2.0 mg/L) or PMCL (4.0 mg/L). Iron concentrations exceeded the USEPA SMCL in 11 percent of samples and were highest in schist (14 percent) and gneiss (13 percent). Manganese concentrations exceeded the SMCL in 19 percent of samples and were highest in quartzite and schist (both 28 percent). Lead and arsenic were present in low concentrations: the highest concentrations of lead occurred in water from quartzite (8 percent exceeded the USEPA Action Level), and arsenic was detected mostly in Triassic sedimentary rocks (9 percent exceeded the USEPA PMCL). The highest concentrations of copper occurred more frequently in quartzite rocks, and to a lesser extent were evenly distributed between ground water in gneiss, schist, and Triassic sedimentary rocks. Elevated concentrations of radon-222 and the combined radium-226/radium-228 radionuclides were common in water from quartzite and schist. Gross alpha and gross beta particle activities were elevated in water from quartzite and carbonate rocks. In contrast, elevated concentrations of uranium primarily were measured in water from Triassic sedimentary and carbonate rocks. Despite a sampling bias towards agricultural land use, only two samples indicated the presence of fecal coliforms. Samples analyzed for nutrients generally exhibited low concentrations, but about 11 percent of samples collected for nitrate exceeded the USEPA PMCL. Only one nitrite sample (less than 1 percent) exceeded the respective USEPA PMCL. Approximately 190 samples were collected for each of the three pesticides in this report: lindane, dieldrin, and diazinon. Sampling was biased towards agricultural, low-medium density residential, and wooded land uses. Approximately 95 percent of samples for each pesticide were below minimum reporting levels (MRL). Only lindane has a USEPA PMCL, and only one sample exceeded the standard. Results for dieldrin and diazinon were similar, except results for two diazinon samples where concentrations were 57.0 and 490 micrograms per liter (μg/L). Volatile organic compounds in this report were analyzed in water from 198 samples. Sampling was biased towards agricultural, low-medium density residential, and wooded land uses. Two percent of samples analyzed for trichloroethylene and less than 1 percent of samples analyzed for tetrachloroethylene exceeded their respective USEPA PMCLs (each 5.0 μg/L). No samples analyzed for 1,1,1-trichloroethane exceeded the USEPA PMCL (200 μg/L). No samples analyzed for methyl tert-butyl ether exceeded the USEPA Drinking Water Advisory (20μg/L).

Open-File Report↗

Simulated changes in salinity in the York and Chickahominy Rivers from projected sea-level rise in Chesapeake Bay

As a result of climate change and variability, sea level is rising throughout the world, but the rate along the east coast of the United States is higher than the global mean rate. The U.S. Geological Survey, in cooperation with the City of Newport News, Virginia, conducted a study to evaluate the effects of possible future sea-level rise on the salinity front in two tributaries to Chesapeake Bay, the York River, and the Chickahominy/James River estuaries. Numerical modeling was used to represent sea-level rise and the resulting hydrologic effects. Estuarine models for the two tributaries were developed and model simulations were made by use of the Three-Dimensional Hydrodynamic-Eutrophication Model (HEM-3D), developed by the Virginia Institute of Marine Science. HEM-3D was used to simulate tides, tidal currents, and salinity for Chesapeake Bay, the York River and the Chickahominy/James River. The three sea-level rise scenarios that were evaluated showed an increase of 30, 50, and 100 centimeters (cm). Model results for both estuaries indicated that high freshwater river flow was effective in pushing the salinity back toward Chesapeake Bay. Model results indicated that increases in mean salinity will greatly alter the existing water-quality gradients between brackish water and freshwater. This will be particularly important for the freshwater part of the Chickahominy River, where a drinking-water-supply intake for the City of Newport News is located. Significant changes in the salinity gradients for the York River and Chickahominy/James River estuaries were predicted for the three sea-level rise scenarios. When a 50-cm sea-level rise scenario on the York River during a typical year (2005) was used, the model simulation showed a salinity of 15 parts per thousand (ppt) at river kilometer (km) 39. During a dry year (2002), the same salinity (15 ppt) was simulated at river km 45, which means that saltwater was shown to migrate 6 km farther upstream during a dry year than a typical year. The same was true of the Chickahominy River for a 50-cm sea-level rise scenario but to a greater extent; a salinity of 4 ppt was simulated at river km 13 during a typical year and at river km 28 during a dry year, indicating that saltwater migrated 15 km farther upstream during a dry year. Near a drinking-water intake on the Chickahominy River, for a dry year, salinity is predicted to more than double for all three sea-level rise scenarios, relative to a typical year. During a typical year at this location, salinity is predicted to increase to 0.006, 0.07, and more than 2 ppt for the 30-, 50-, and 100-cm rise scenarios, respectively.

Virginia↗

Streamflow and estimated loads of phosphorus and dissolved and suspended solids from selected tributaries to Lake Ontario, New York, water years 2012–14

This report presents results of the evaluation and interpretation of hydrologic and water-quality data collected as part of a cooperative program between the U.S. Geological Survey and the U.S. Environmental Protection Agency. Streamflow, phosphorus, and solids dissolved and suspended in stream water were the focus of monitoring by the U.S. Geological Survey at 10 sites on 9 selected tributaries to Lake Ontario during the period from October 2011 through September 2014. Streamflow yields (flow per unit area) were the highest from the Salmon River Basin due to sustained yields from the Tug Hill aquifer. The Eighteenmile Creek streamflow yields also were high as a result of sustained base flow contributions from a dam just upstream of the U.S. Geological Survey monitoring station at Burt. The lowest streamflow yields were measured in the Honeoye Creek Basin, which reflects a decrease in flow because of withdrawals from Canadice and Hemlock Lakes for the water supply of the City of Rochester. The Eighteenmile Creek and Oak Orchard Creek Basins had relatively high yields due in part to groundwater contributions from the Niagara Escarpment and seasonal releases from the New York State Barge Canal. Annual constituent yields (load per unit area) of suspended solids, phosphorus, orthophosphate, and dissolved solids were computed to assess the relative contributions and allow direct comparison of loads among the monitored basins. High yields of total suspended solids were attributed to agricultural land use in highly erodible soils at all sites. The Genesee River, Irondequoit Creek, and Honeoye Creek had the highest concentrations and largest mean yields of total suspended solids (165 short tons per square mile [t/mi 2 ], 184 t/mi 2 , and 89.7 t/mi 2 , respectively) of the study sites. Samples from Eighteenmile Creek, Oak Orchard Creek at Kenyonville, and Irondequoit Creek had the highest concentrations and largest mean yields of phosphorus (0.27 t/mi 2 , 0.26 t/mi 2 , and 0.20 t/mi 2 , respectively) and orthophosphate (0.17 t/mi 2 , 0.13 t/mi 2 , and 0.04 t/mi 2 , respectively) of the study sites. These results were attributed to a combination of sources, including discharges from wastewater treatment plants, diversions from the New York State Barge Canal, and manure and fertilizers applied to agricultural land. Yields of phosphorus also were high in the Genesee River Basin (0.17 t/mi 2 ) and were presumably associated with nutrient and sediment transport from agricultural land and from streambank erosion. The Salmon and Black Rivers, which drain a substantial amount of forested land and are influenced by large groundwater discharges, had the lowest concentrations and yields of phosphorus and orthophosphate of the study sites. Mean annual yields of dissolved solids were the highest in Irondequoit Creek due to a high percentage of urbanized area in the basin and in Oak Orchard Creek at Kenyonville and in Eighteenmile Creek due to groundwater contributions from the Niagara Escarpment. High yields of dissolved solids of 840 t/mi 2 , 829 t/mi 2 , and 715 t/mi 2 , respectively, from these basins can be attributed to seasonal chloride yields associated with use of road deicing salts. The Niagara Escarpment can produce large amounts of dissolved solids from the dissolution of minerals (a continual process reflected in base flow samples). Groundwater inflows in the Salmon River have very low concentrations of dissolved solids due to minimal bedrock interaction along the Tug Hill Plateau and discharge from the Tug Hill sand and gravel aquifer, which has minimal mineralization.

New York↗

Preliminary United States-Mexico border watershed analysis, twin cities area of Nogales, Arizona and Nogales, Sonora

The United States - Mexico border area faces the challenge of integrating aspects of its binational physical boundaries to form a unified or, at least, compatible natural resource management plan. Specified geospatial components such as stream drainages, mineral occurrences, vegetation, wildlife, and land-use can be analyzed in terms of their overlapping impacts upon one another. Watersheds have been utilized as a basic unit in resource analysis because they contain components that are interrelated and can be viewed as a single interactive ecological system. In developing and analyzing critical regional natural resource databases, the Environmental Protection Agency (EPA) and other federal and non-governmental agencies have adopted a ?watershed by watershed? approach to dealing with such complicated issues as ecosystem health, natural resource use, urban growth, and pollutant transport within hydrologic systems. These watersheds can facilitate the delineation of both large scale and locally important hydrologic systems and urban management parameters necessary for sustainable, diversified land-use. The twin border cities area of Nogales, Sonora and Nogales, Arizona, provide the ideal setting to demonstrate the utility and application of a complete, cross-border, geographic information systems (GIS) based, watershed analysis in the characterization of a wide range of natural resource as well as urban features and their interactions. In addition to the delineation of a unified, cross-border watershed, the database contains sewer/water line locations and status, well locations, geology, hydrology, topography, soils, geomorphology, and vegetation data, as well as remotely sensed imagery. This report is preliminary and part of an ongoing project to develop a GIS database that will be widely accessible to the general public, researchers, and the local land management community with a broad range of application and utility.

Arizona, Sonora↗

Design and methods of the Southeast Stream Quality Assessment (SESQA), 2014

During 2014, the U.S. Geological Survey (USGS) National Water-Quality Assessment Program (NAWQA) assessed stream quality across the Piedmont and southern Appalachian Mountain regions of the southeastern United States. This Southeast Stream Quality Assessment (SESQA) simultaneously characterized watershed and stream-reach water-quality stressors along with instream biological conditions, in order to better understand regional stressor-effects relations. The goal of SESQA is to provide communities and policymakers with information about those human and environmental factors that have the greatest impact on stream quality across the region. The SESQA design focused on hydrologic alteration and urbanization because of their importance as ecological stressors of particular concern to Southeast region resource managers. Streamflow and land-use data were used to identify and select sites representing gradients in urbanization and streamflow alteration across the region. One hundred fifteen sites were selected and sampled for as many as 10 weeks during April, May, and June 2014 for contaminants, nutrients, and sediment. This water-quality “index” period culminated with an ecological survey of habitat, periphyton, benthic macroinvertebrates, and fish at all sites. Sediment was collected during the ecological survey for analysis of sediment chemistry and toxicity testing. Of the 115 sites, 59 were on streams in watersheds with varying degrees of urban land use, 5 were on streams with multiple confined animal feeding operations, and 13 were reference sites with little or no development in their watersheds. The remaining 38 “hydro” sites were on streams in watersheds with relatively little agricultural or urban development but with hydrologic alteration, such as a dam or reservoir. This report provides a detailed description of the SESQA study components, including surveys of ecological conditions, routine water sampling, deployment of passive polar organic compound integrative samplers for pesticides and contaminants of emerging concern, and synoptic sediment sampling and toxicity testing at all urban, confined animal feeding operation, and reference sites. Continuous water-quality monitoring and daily pesticide sampling efforts conducted at a subset of urban sites are also described.

Alabama, Georgia, North Carolina, South Carolina, ↗

Preliminary hydrogeologic assessment of a ground-water contamination area in Wolcott, Connecticut

Contamination of ground water by volatile organic compounds and inorganic constituents has been identified at a number of industrial sites in the Town of Wolcott, Connecticut. Contamination is also present at a municipal landfill in the City of Waterbury that is upgradient from the industrial sites in the local ground-water-flow system. The study area, which lies in the Western Highlands of Connecticut, is in the Mad River Valley, a tributary to the Naugatuck River. Geohydrologic units (aquifer materials) include unconsolidated glacial sediments (surficial materials) and fractured crystalline (metamorphic) bedrock. Surficial materials include glacial till, coarse-grained andfine-grained glacial stratified deposits, and postglacial floodplain alluvium and swamp deposits. The ground-water-flow system in the surficial aquifer is complex because the hydraulic properties of the surficial materials are highly variable. In the bedrock aquifer, ground water moves exclusively through fractures. Hydrologic characteristics of the crystalline bedrock-degree of confinement, hydraulic conductivity, storativity, and porosity-are poorly defined in the study area. Further study is needed to adequately assess ground-water flow and contaminant migration under current or past hydrologic conditions. All known water-supply wells in the study area obtain water from the bedrock aquifer. Twenty households in a hillside residential area on Tosun Road currently obtain drinking water from private wells tapping the bedrock aquifer. The extent of contamination in the bedrock aquifer and the potential for future contamination from known sources of contamination in the surficial aquifer is of concern to regulatory agencies. Previous investigations have identified ground-water contamination by volatile organic compounds at the Nutmeg Valley Road site area. Contamination has been associated with on-site disposal of heavy metals, chlorinated and non-chlorinated volatile organic compounds, and cyanide. Concentrations of volatile organic compounds detected in water samples collected from bedrock wells during 1981-95 at the Nutmeg Valley Road site area show a general downward trend through time. Water samples collected from wells completed in surficial materials were not collected systematically, and a trend in concentration cannot be identified.

Open-File Report↗

Delineation of recharge areas for selected wells in the St. Peter-Prairie du Chien-Jordan aquifer, Rochester, Minnesota

Accurate delineation of recharge areas for wells is an important requisite to protecting ground-water quality. Zones of transport and zones of contribution are two types of recharge areas that can be delineated. Analytical-calculation, numerical-modeling, and hydrogeologic-mapping methods were used to delineate recharge areas for two high-capacity wells (greater than about 200 gallons per minute discharge) completed in a karstic aquifer in the city of Rochester, in southeastern Minnesota. One well is less than 1,000 feet from a river in an area where the aquifer is unconfined, whereas the other well is more than 2,000 feet from a stream in an area where a bedrock confining unit is present. Ground-water travel times from points along the top of the aquifer to a pumped well are identified by use of a constructed map showing lines of equal advective travel time. A zone of transport, therefore, is defined by the area bounded by lines of equal travel time. Zones of transport are delineated by analytical models (calculations) and by numerical models that account for hydrologic factors. Analytical models that were used include fixed-radius (Theis drawdown, Theis time-of-travel, and volumetric equation) and variable shape. Numerical modeling was done with the U.S. Geological Survey three-dimensional ground-water-flow model MODFLOW and particle-tracking code MODPATH. The zone-of-transport areas for each of the two wells calculated by the various analytical models were very similar. The Theis-drawdown method yielded results that compared least favorably with results from the other analytical methods. The zone-of-transport areas computed by use of the numerical model were generally larger than areas computed by use of analytical models. Hydrogeologic mapping and numerical modeling were used to delineate zones of contribution to wells, defined as all parts of a ground-water-flow system that could supply water to a well. The zones of contribution delineated by use of numerical modeling have similar orientation (parallel to regional flow directions) but significantly different areas than the zones of contribution delineated by use of hydrogeologic mapping. Differences in computed areas of recharge are attributed to the capability of the numerical model to more accurately represent (1) the three-dimensional flow system, (2) hydrologic boundaries such as streams, (3) variable recharge, and (4) the influence of nearby pumped wells, compared to the analytical models.

Minnesota↗

Hydrogeologic framework and groundwater/surface-water interactions of the South Fork Nooksack River Basin, northwestern Washington

A hydrogeologic framework of the South Fork (SF) Nooksack River Basin in northwestern Washington was developed and hydrologic data were collected to characterize the groundwater-flow system and its interaction with surface‑water features. In addition to domestic, agricultural, and commercial uses of groundwater within the SF Nooksack River Basin, groundwater has the potential to provide ecological benefits by maintaining late-summer streamflows and buffering stream temperatures. Cold-water refugia, created and maintained in part by groundwater, have been identified by water-resource managers as key elements to restore the health and viability of threatened salmonids in the SF Nooksack River. The SF Nooksack River drains a 183-square mile area of the North Cascades and the Puget Lowland underlain by unconsolidated glacial and alluvial sediments deposited over older sedimentary, metamorphic, and igneous bedrock. The primary aquifer that interacts with the SF Nooksack River was mapped within unconsolidated glacial outwash and alluvial sediment. The lower extent of this unit is bounded by bedrock and fine-grained, poorly sorted unconsolidated glaciomarine and glaciolacustrine sediments. In places, these deposits overlie and confine an aquifer within older glacial sediments. The extent and thickness of the hydrogeologic units were assembled from mapped geologic units and lithostratigraphic logs of field-inventoried wells. Generalized groundwater-flow directions within the surficial aquifer were interpreted from groundwater levels measured in August 2012; and groundwater seepage gains and losses to the SF Nooksack River were calculated from synoptic streamflow measurements made in the SF Nooksack River and its tributaries in September 2012. A subset of the field-inventoried wells was measured at a monthly interval to determine seasonal fluctuations in groundwater levels during water year 2013. Taken together, these data provide the foundation for a future groundwater-flow model of the SF Nooksack River Basin that may be used to investigate the potential effects of future climate change, land use, and groundwater pumping on water resources in the study area. Site-specific hydrologic data, including time series of longitudinal temperature profiles measured with a fiber-optic distributed temperature sensor and continuous monitoring of stream stage and water levels measured in wells in adjacent wetlands and aquifers, also were measured to characterize the interaction among the SF Nooksack River, surficial aquifers, and riparian wetlands.

Washington↗

Hydrogeology and ground-water flow in the Edwards-Trinity aquifer-system, west-central, Texas

Two finite-element ground-water flow models were developed for the Edwards–Trinity aquifer system, west-central Texas, to gain a better understanding of the flow system; one ground-water flow model was developed at a large scale to simulate the regional system and contiguous, hydraulically connected units, and one model was constructed at a smaller more detailed scale to simulate the most active areas of the system. The study area is divided into four geographic subareas: the Trans-Pecos (9,750 square miles), the Edwards Plateau (23,750 square miles), the Hill Country (5,500 square miles), and the Balcones fault zone (3,000 square miles). The major aquifers within the study area are the Edwards–Trinity aquifer underlying the Trans-Pecos and Edwards Plateau, the Trinity aquifer underlying the Hill Country, and the Edwards aquifer in the Balcones fault zone. Hydraulically connected aquifers include the High Plains aquifer north of the Edwards Plateau, and the Cenozoic Pecos alluvium aquifer adjacent to both the Trans-Pecos and the Edwards Plateau along the Pecos River. Minor contiguous aquifers include the Dockum, Ellenburger– San Saba, Marble Falls, Hickory, and Lipan, which is adjacent to the Colorado River in Tom Green and Concho Counties, Texas. The ground-water flow equations solved by the finite-element method are based on conservation of mass and energy. The equation for ground-water flow assumes laminar flow through a porous media. In places, the Edwards–Trinity aquifer system is a fractured karst system in which ground water flows through caverns and other features of secondary porosity development. The regional and subregional models were constructed to synthesize the known hydrologic boundaries and geologic structures into a heterogeneous continuum model of the karst ground-water flow system, rather than simulate the flow through specific fractures and caverns. A heterogeneous continuum or equivalent porous media approach uses an effective transmissivity and anisotropy for each element of the models. The models are calibrated both on water levels (representing potential energy) and estimates of recharge and discharge (for a realistic mass balance). A two-dimensional one-layer large-scale model (55,600 square miles) was developed for the Edwards–Trinity aquifer system and contiguous, hydraulically connected units, in westcentral Texas. A quasi-three-dimensional, multilayer more detailed scale ground-water flow model (12,300 square miles) was applied to the major aquifers of the Edwards–Trinity aquifer system in the Hill Country and the Balcones fault zone, and in part of the Edwards Plateau. The ground-water flow system in most of the study area within the Trans-Pecos and Edwards Plateau can be approximated with a one-layer regional model under steady-state conditions. Regionally, the Edwards–Trinity aquifer system in the Trans-Pecos and Edwards Plateau has been relatively static. Potentiometric maps from predevelopment and postdevelopment (winter 1974–75) indicate small differences in water levels. In local areas in the Trans-Pecos (in Pecos and Reeves Counties), ground-water withdrawals have exceeded recharge resulting in more than 300 feet of drawdown. Measurable differences between the 1974 and predevelopment potentiometric surfaces have been observed in small areas in the Trans-Pecos and in the northwestern part of the Edwards Plateau. The largest water-level declines in the Trans-Pecos have been observed in Pecos and Reeves Counties, and declines greater than 300 feet have been measured in Reeves County. Comparison of pre- and postdevelopment water budgets for the regional model indicates that the increase in groundwater withdrawals has captured 20 percent of the water that would have naturally discharged to streams, and 30 percent of the natural discharge to springs after ground-water development. Induced recharge from streams to the ground-water system increased by 12 percent in the postdevelopment simulation compared to the predevelopment simulation.

Texas↗

National water summary 1990-91: Hydrologic events and stream water quality

National Water Summary 1990-91 Hydrologic Events and Stream Water Quality was planned to complement existing Federal-State water-quality reporting to the U.S. Congress that is required by the Clean Water Act of 1972. This act, formally known as the Federal Water Pollution Control Act Amendments of 1972 (Public Law 92-500), and its amendments in 1977,1979,1980,1981,1983, and 1987, is the principal basis for Federal-State cooperation on maintaining and reporting on water quality in the United States. Under section 305(b) of the Clean Water Act, the States must designate uses for waterbodies, biennially assess whether the waterbodies meet designated uses, and report to the U.S. Environmental Protection Agency (EPA), which in turn summarizes the findings of the State assessments in a biennial National Water Quality Inventory report to the Congress. This volume of the National Water Summary uses a nationally consistent data base and methods of statistical analysis to document stream water quality in the United States, Puerto Rico, and the Western Pacific Islands. As a basis for preparation of this report, the U.S. Geological Survey (uses) created a data base of waterquality data from about 2,900 stream water-quality monitoring stations in the United States (Lanfear, 1993). These data, which were extracted primarily from the uses National Water Information System (NWIS) and supplemented with data from the EPA national data base known as STORET, consisted mostly of water-chemistry and physical-sediment data. About 1,400 of these stations met a criterion, used in this volume for trends analysis of data, of having a period of record that began before water year 1980. (A water year is the period from October 1 through September 30 and is identified by the calendar year at the end of the period.) Inasmuch as the determination of trends requires about 10 years of data, few biological data were suitable for trends analysis because biological indicators of water quality were not being collected extensively by water year 1980. Also, because of the lack of long-term data, an assessment of the water quality of lakes and reservoirs is not included in this National Water Summary . Constituent and waterproperty data were selected from this data base and analyzed with statistical techniques that have been used extensively by the uses to summarize conditions and trends in water quality. (Throughout the remainder of this article, the term "constituent" is used also to represent water properties, such as pH and alkalinity.) Selected results from this analysis are presented graphically, both by State and nationally, in this volume. The data base created for preparation of this volume and the resulting nationally consistent statistical analysis of these data provide a unique opportunity to compare and contrast stream water-quality conditions and trends nationally and State by State. Because of the complexity of water quality and the natural seasonal and diurnal variations in the concentrations of waterquality constituents, the determination of trends in water quality requires a relatively long period of record. Trends in constituent concentrations in the State summaries in this volume were calculated for one or more of four periods water years 1970-89,1975-89,1980- 89, and 1982-89. Unfortunately, few water-quality monitoring stations have periods of record of more than 10 or 15 years, and therefore most analyses in the State summaries were done for 8- or 10-year periods. Although interest in water quality has continued to heighten since passage of the Clean Water Act, funds for support of data-collection programs are limited and data records of many of the constituents now of current concern, especially organic constituents, do not exist or are less than 10-years long; consequently only a modest number of organic constituents are presented in this volume. Discussion of conditions and trends in water quality in this National Water Summary also draw upon information about land use, population, water use, application of agricultural chemicals in rural areas, the siting of industrial facilities, and other ancillary information. Because the results of analysis of a restricted number of constituents are presented in this volume, State 305(b) reports also are cited in the discussion of water quality in each State. The following discussion is an overview of the three parts of this 1990-91 National Water Summary - "Hydrologic Conditions and Water-Related Events, Water Years 1990-91," "Hydrologic Perspectives on Water Issues," and "State Summaries of Stream Water Quality."

Water Supply Paper↗

Geology and hydrology of the Claiborne Group in western Tennessee

The area of western Tennessee underlain by the Claiborne Group is about 7,200 square miles and lies on the east flank of the syncline that forms the Mississippi embayment. It includes the Mississippi Alluvial Plain and part of a dissected upland plateau. The Claiborne Group dips to the northwest at 10-25 feet per mile and ranges in altitude from 600 feet above mean sea level in the outcrop area to 900 feet below mean sea level near the embayment axis. The Claiborne Group is tentatively subdivided into five units including, in ascending order, the Meridian Sand Member of the Tallahatta Formation, the Basic City Shale Member of the Tallahatta Formation, the Sparta Sand, an unnamed clay unit, and an unnamed sand unit. The two major aquifers in the Claiborne Group are the '500-foot' sand and the unnamed sand unit. The top of the '500-foot' sand is correlated with the top of the Sparta Sand; and the base, with the base of the Claiborne Group. The '500-foot' sand ranges in thickness from 200 to 750 feet and consists mainly of very fine to coarse sand or gravel. It also contains layers of white to blue, pink, gray, or brown clay, which constitute only a small percentage of the total thickness. The unnamed sand unit ranges from 0 to 210 feet in thickness and consists mostly of white, gray, or brown fine-grained lignitic sand. An estimated 75 percent of the ground water withdrawn in western Tennessee (west of the northward-flowing segment of the Tennessee River) is taken from the '500-foot' sand and the unnamed sand unit. The quantities of water available to wells from the '500-foot' sand are currently adequate for all municipal and industrial needs. The permeability of this aquifer is about 570 gallons per day per square foot. An estimated 155 mgd (million gallons per day) is pumped from the '500-foot' sand, about 140 mgd is discharged from the aquifer as the base flow of surface streams, and about 40 mgd is discharged from the report area as underflow. Water from the '500-foot' sand contains objectionable quantities of iron in the western half of the report area. Otherwise the quality of the water is suitable for most needs. Quantities of water adequate for domestic use and for small municipal systems can be obtained from the unnamed sand unit in most of the report area. The field permeability of this aquifer is probably about 270 gallons per day per square foot. About 8 mgd is discharged into adjacent formations, and about 2 mgd is withdrawn by pumping. Water from the unnamed sand unit contains objectionable quantities of iron in the western half of the report area. Otherwise the water from this aquifer is of good quality. Ground-water supplies in both the '500-foot' sand and the unnamed sand unit will be adequate for the predicted rate of municipal growth and economic development for many years to come. If the hydraulic gradient in the '500-foot' sand were increased to 19 feet per mile, the average dip of the top of the aquifer, about 578 mgd would be transmitted downdip. Similarly, the unnamed sand unit would transmit about 34 mgd downdip under a hydraulic gradient of 10 feet per mile. Furthermore, additional amounts of water could be induced into the report area as underflow from adjacent States. The anticipated effects of additional large scale development are (1) a drop in local and regional water levels in proportion to the increase in pumpage, (2) an increase in the net inflow of ground water from adjacent States, and (3) an increase of recharge to the aquifers at the expense of streamflow.

Water Supply Paper↗