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Geologic framework for the national assessment of carbon dioxide storage resources—Atlantic Coastal Plain and Eastern Mesozoic Rift Basins

This chapter presents information pertinent to the geologic carbon dioxide (CO 2 ) sequestration potential within saline aquifers located in the Atlantic Coastal Plain and Eastern Mesozoic Rift Basins of the Eastern United States. The Atlantic Coastal Plain is underlain by a Jurassic to Quaternary succession of sedimentary strata that onlap westward onto strata of the Appalachian Piedmont physiographic province and generally thicken eastward toward the present-day Atlantic coastline and onto the present-day continental shelf. Although no significant petroleum discoveries have been made on the coastal plain, the deep saline aquifers of the region appear to contain porous strata (potential reservoirs, or “storage formations”) that are overlain by fine-grained, laterally continuous strata (potential seals), which are prospective CO 2 sequestration targets. For the Atlantic Coastal Plain, we identify two storage assessment units (SAUs), both of which consist of Cretaceous strata. The two SAUs are the Lower Cretaceous Composite SAU C50700101 and the Upper Cretaceous Composite SAU C50700102. The Eastern Mesozoic Rift Basins are a chain of generally southwest- to northeast-trending, elongate sedimentary basins that either underlie the Atlantic Coastal Plain or crop out within adjacent geologic provinces to the west. Similar to the Atlantic Coastal Plain, there has been no significant oil and gas production from any of the basins, although there is a proven petroleum system in several of them. At least three of these basins appear to contain potential storage formations overlain by potential seal units. Most of the other basins were not assessed because a storage and (or) seal formation could not be established in the timeframe of the assessment, often because of the paucity of subsurface data for these basins in comparison to other petroliferous basins of the United States. Thus, we present information supporting one quantitative assessment in the Newark basin, as well as information supporting two nonquantitative assessments, one for strata in the Gettysburg basin and the other for strata in the Culpeper basin. We briefly discuss six other basins within the Eastern Mesozoic Rift Basins that were not assessed. For all SAUs, we discuss the areal distribution of suitable CO 2 reservoir rock. We also describe the overlying sealing unit and the geologic characteristics that influence the potential CO 2 storage volume and reservoir characteristics. These characteristics include storage formation depth, gross thickness, net thickness, porosity, permeability, and groundwater salinity. Case-by-case strategies for estimating the pore volume existing within structurally and (or) stratigraphically closed traps are presented. Although assessment results are not contained in this chapter, the geologic information included herein was used to calculate the potential storage space in the SAUs.

Atlantic Coastal Plain and Eastern Mesozoic Rift B↗

Geochemistry of Florida Bay sediments: Nutrient history at five sites in eastern and central Florida Bay

Recent seagrass dieoff and massive microalgal blooms have focused attention on the health of the Florida Bay ecosystem. Changes in nutrient input and the nutrient dynamics of Florida Bay are hypothesized to be linked to these problems, but crucial baseline information is still lacking. Efforts to restore Florida Bay to its natural condition will require information on the nutrient history of the bay. The purpose of this study was to examine distributions of organic C, total N, and total P in carbonate sediments from sites of continuous and known sedimentation rate (210Pb and 137Cs dated), in eastern and central Florida Bay. These sediments provide a record of historical changes in the C, N, and P load to the eastern and central bay. Analyses were conducted on sediments from cores collected at five sites, and on buried seagrass fragments at two sites. At three of the sites, sediments from seagrass-covered and adjacent barren areas were examined to determine differences in sedimentary geochemistry. Stable isotope analyses (??13C and ??15N) of sedimentary organic C and total N and of buried seagrass fragments were also carried out at two sites to examine possible changes in nutrient sources to the estuary. Results were consistent with recent increases in N and P in eastern Florida Bay, beginning in the early to mid 1980's. The timing of the increase in nutrient load observed in the sediment data directly preceded the first observations of massive microalgal blooms and seagrass dieoff in Florida Bay in 1987. The observed nutrification was greater for P than N, and was most pronounced at the most northeasterly site sampled (Pass Key). Isotope data (??15N) suggested that an increase in algal production accompanied the increase in N load at the Pass Key site. Along record of organic C, total N, and total P distributions from Whipray Basin in central Florida Bay showed historical peaks (mid 1700's and late 1800's) in organic C and total N, but not total P; these enrichments were nearly equivalent to recent inputs to the estuary. Barren areas were observed to have generally lower concentrations of organic C, total N, and total P in near surface sediments compared to seagrass-covered areas, but had generally similar concentrations in deeper sediments. This suggested that barren areas adjacent to seagrass-covered sites were places where relict sediment was physically transported and covered seagrass beds. This dataset provides an historical view of changes in nutrient inputs to Florida Bay, and baseline information needed for nutrient modeling of the bay.

Journal of Coastal Research↗

Assessing vulnerability to invasion by nonnative plant species at multiple spatial scales

Basic information on where nonnative plant species have successfully invaded is lacking. We assessed the vulnerability of 22 vegetation types (25 sets of four plots in nine study areas) to nonnative plant invasions in the north–central United States. In general, habitats with high native species richness were more heavily invaded than species-poor habitats, low-elevation areas were more invaded than high-elevation areas, and riparian zones were more invaded than nearby upland sites. For the 100 1000-m 2 plots (across all vegetation types), 50% of the variation in nonnative species richness was explained by longitude, latitude, native plant species richness, soil total percentage nitrogen, and mean maximum July temperature ( n = 100 plots; P < 0.001 ). At the vegetation-type scale ( n = 25 sets of four 1000-m 2 plots/type), 64% of the variation in nonnative species richness was explained by native plant species richness, elevation, and October to June precipitation ( P < 0.001 ). The foliar cover of nonnative species (log) was strongly positively correlated with the nonnative species richness at the plot scale ( r = 0.77 , P < 0.001 ) and vegetation-type scale ( r = 0.83 , P < 0.001 ). We concluded that, at the vegetation-type and regional scales in the north–central United States, (1) vegetation types rich in native species are often highly vulnerable to invasion by nonnative plant species; (2) where several nonnative species become established, nonnative species cover can substantially increase; (3) the attributes that maintain high native plant species richness (high light, water, nitrogen, and temperatures) also help maintain nonnative plant species richness; and (4) more care must be taken to preserve native species diversity in highly vulnerable habitats.

Environmental Management↗

Measuring urban water conservation policies: Toward a comprehensive index

This article (1) discusses existing efforts to measure water conservation policies (WCPs) in the United States (U.S.); (2) suggests general methodological guidelines for creating robust water conservation indices (WCIs); (3) presents a comprehensive template for coding WCPs; (4) introduces a summary index, the Vanderbilt Water Conservation Index (VWCI), which is derived from 79 WCP observations for 197 cities for the year 2015; and (5) compares the VWCI to WCP data extracted from the 2010 American Water Works Association (AWWA) Water and Wastewater Rates survey. Existing approaches to measuring urban WCPs in U.S. cities are limited because they consider only a portion of WCPs or they are restricted geographically. The VWCI consists of a more comprehensive set of 79 observations classified as residential, commercial/industrial, billing structure, drought plan, or general. Our comparison of the VWCI and AWWA survey responses indicate reasonable agreement ( ρ = 0.76) between the two WCIs for 98 cities where the data overlap. The correlation suggests the AWWA survey responses can provide fairly robust longitudinal WCP information, but we argue the measurement of WCPs is still in its infancy, and our approach suggests strategies for improving existing methods.

Journal of the American Water Resources Associatio↗

A goodness-of-fit test for capture-recapture model Mt under closure

A new, fully efficient goodness-of-fit test for the time-specific closed-population capture-recapture model M t is presented. This test is based on the residual distribution of the capture history data given the maximum likelihood parameter estimates under model M t , is partitioned into informative components, and is based on chi-square statistics. Comparison of this test with Leslie's test (Leslie, 1958, Journal of Animal Ecology , 27 , 84–86) for model M t , using Monte Carlo simulations, shows the new test generally outperforms Leslie's test. The new test is frequently computable when Leslie's test is not, has Type I error rates that are closer to nominal error rates than Leslie's test, and is sensitive to behavioral variation and heterogeneity in capture Probabilities. Leslie's test is not sensitive to behavioral variation in capture probabilities but, when computable, has greater power to detect heterogeneity than the new test.

Biometrics↗

Mineral Facilities of Latin America and Canada

This data set consists of records for over 900 mineral facilities in Latin America and Canada. The mineral facilities include mines, plants, smelters, or refineries of aluminum, cement, coal, copper, diamond, gold, iron and steel, nickel, platinum-group metals, salt, and silver, among others. Records include attributes such as commodity, country, location, company name, facility type and capacity if applicable, and generalized coordinates. The data were compiled from multiple sources, including the 2003 and 2004 USGS Minerals Yearbooks (Latin America and Candada volume), data to be published in the 2005 Minerals Yearbook Latin America and Canada Volume, minerals statistics and information from the USGS minerals information Web site (minerals.usgs.gov/minerals), and data collected by USGS minerals information country specialists. Data reflect the most recent published table of industry structure for each country. Other sources include statistical publications of individual countries, annual reports and press releases of operating companies,and trade journals. Due to the sensitivity of some energy commodity data, the quality of these data should be evaluated on a country-by-country basis. Additional information and explanation is available from the country specialists.

Open-File Report↗

Flow-log analysis for hydraulic characterization of selected test wells at the Indian Point Energy Center, Buchanan, New York

Flow logs from 24 test wells were analyzed as part of the hydraulic characterization of the metamorphosed and fractured carbonate bedrock at the Indian Point Energy Center in Buchanan, New York. The flow logs were analyzed along with caliper, optical- and acoustic-televiewer, and fluid-resistivity and temperature logs to determine the character and distribution of fracture-flow zones and estimate their transmissivities and hydraulic heads. Many flow zones were associated with subhorizontal to shallow-dipping fractured zones, southeast-dipping bedding fractures, northwest-dipping conjugate fractures, or combinations of bedding and conjugate fractures. Flow-log analysis generally provided reasonable first-order estimates of flow-zone transmissivity and head differences compared with the results of conventional hydraulic-test analysis and measurements. Selected results of an aquifer test and a tracer test provided corroborating information in support of the flow-log analysis.

New York↗

Quality of Streams in Johnson County, Kansas, and Relations to Environmental Variables, 2003-07

The quality of streams and relations to environmental variables in Johnson County, northeastern Kansas, were evaluated using water, streambed sediment, land use, streamflow, habitat, algal periphyton (benthic algae), and benthic macroinvertebrate data. Water, streambed sediment, and macroinvertebrate samples were collected in March 2007 during base flow at 20 stream sites that represent 11 different watersheds in the county. In addition, algal periphyton samples were collected twice (spring and summer 2007) at one-half of the sites. Environmental data including water and streambed-sediment chemistry data (primarily nutrients, fecal-indicator bacteria, and organic wastewater compounds), land use, streamflow, and habitat data were used in statistical analyses to evaluate relations between biological conditions and variables that may affect them. This report includes an evaluation of water and streambed-sediment chemistry, assessment of habitat conditions, comparison of biological community attributes (such as composition, diversity, and abundance) among sampling sites, placement of sampling sites into impairment categories, evaluation of biological data relative to environmental variables, and evaluation of changes in biological communities and effects of urbanization. This evaluation is useful for understanding factors that affect stream quality, for improving water-quality management programs, and for documenting changing conditions over time. The information will become increasingly important for protecting streams in the future as urbanization continues. Results of this study indicate that the biological quality at nearly all biological sampling sites in Johnson County has some level of impairment. Periphyton taxa generally were indicative of somewhat degraded conditions with small to moderate amounts of organic enrichment. Camp Branch in the Blue River watershed was the only site that met State criteria for full support of aquatic life in 2007. Since 2003, biological quality improved at one rural sampling site, possibly because of changes in wastewater affecting the site, and declined at three urban sites possibly because of the combined effects of ongoing development. Rural streams in the western and southern parts of the county, with land-use conditions similar to those found at the State reference site (Captain Creek), continue to support some organisms normally associated with healthy streams. Several environmental factors contribute to biological indicators of stream quality. The primary factor explaining biological quality at sites in Johnson County was the amount of urbanization upstream in the watershed. Specific conductance of stream water, which is a measure of dissolved solids in water and is determined primarily by the amount of groundwater contributing to streamflow, the amount of urbanization, and discharges from wastewater and industrial sites, was strongly negatively correlated with biological stream quality as indicated by macroinvertebrate metrics. Concentration of polycyclic aromatic hydrocarbons (PAHs) in streambed sediment also was negatively correlated with biological stream quality. Individual habitat variables that most commonly were positively correlated with biological indicators included stream sinuosity, buffer length, and substrate cover diversity. Riffle substrate embeddedness and sediment deposition commonly were negatively correlated with favorable metric scores. Statistical analysis indicated that specific conductance, impervious surface area (a measure of urbanization), and stream sinuosity explained 85 percent of the variance in macroinvertebrate communities. Management practices affecting environmental variables that appear to be most important for Johnson County streams include protection of stream corridors, measures that reduce the effects of impervious surfaces associated with urbanization, reduction of dissolved solids in stream water, reduction of PAHs entering streams and

Scientific Investigations Report↗

Linking urbanization to the Biological Condition Gradient (BCG) for stream ecosystems in the Northeastern United States using a Bayesian network approach

Urban development alters important physical, chemical, and biological processes that define urban stream ecosystems. An approach was developed for quantifying the effects of these processes on aquatic biota, and then linking those effects to endpoints that can be used for environmental management. These complex, interacting systems are challenging to model from a scientific standpoint. A desirable model clearly shows the system, simulates the interactions, and ultimately predicts results of management actions. Traditional regression techniques that calculate empirical relations between pairs of environmental factors do not capture the interconnected web of multiple stressors, but urban development effects are not yet understood at the detailed scales required to make mechanistic modeling approaches feasible. Therefore, in contrast to a fully deterministic or fully statistical modeling approach, a Bayesian network model provides a hybrid approach that can be used to represent known general associations between variables while acknowledging uncertainty in predicted outcomes. It does so by quantifying an expert-elicited network of probabilistic relations between variables. Advantages of this modeling approach include (1) flexibility in accommodating many model specifications and information types; (2) efficiency in storing and manipulating complex information, and to parameterize; and (3) transparency in describing the relations using nodes and arrows and in describing uncertainties with discrete probability distributions for each variable. In realization of the aforementioned advantages, a Bayesian network model was constructed to characterize the effect of urban development on aquatic macroinvertebrate stream communities through three simultaneous, interacting ecological pathways affecting stream hydrology, habitat, and water quality across watersheds in the Northeastern United States. This model incorporates both empirical data and expert knowledge to calculate the probabilities of attaining desired aquatic ecosystem conditions under different urban stress levels, environmental conditions, and management options. Ecosystem conditions are characterized in terms of standardized Biological Condition Gradient (BCG) management endpoints. This approach to evaluating urban development-induced perturbations in watersheds integrates statistical and mechanistic perspectives, different information sources, and several ecological processes into a comprehensive description of the system that can be used to support decision making. The completed model can be used to infer which management actions would lead to the highest likelihood of desired BCG tier achievement. For example, if best management practices (BMP) were implemented in a highly urbanized watershed to reduce flashiness to medium levels and specific conductance to low levels, the stream would have a 70-percent chance of achieving BCG Tier 3 or better, relative to a 24-percent achievement likelihood for unmanaged high urban land cover. Results are reported probabilistically to account for modeling uncertainty that is inherent in sources such as natural variability and model simplification error.

Scientific Investigations Report↗

Distribution of indoor radon concentrations in Pennsylvania, 1990-2007

Results from 548,507 indoor radon tests from a database compiled by the Pennsylvania Department of Environmental Protection, Bureau of Radiation Protection, Radon Division, are evaluated in this report in an effort to determine areas where concentrations of radon are highest. Indoor radon concentrations were aggregated according to geologic unit and hydrogeologic setting for spatial analysis. Indoor radon concentrations greater than or equal to the U.S. Environmental Protection Agency (USEPA) action level of 4 picocuries per liter (pCi/L) were observed for 39 percent of the test results; the highest concentration was 1,866.4 pCi/L. When analyzed according to Pennsylvania&rsquo;s geologic units, 93 of the 188 (49.5 percent) geologic units with indoor radon concentrations had median concentrations greater than the USEPA action level of 4 pCi/L; most of these geologic units are located in the eastern part of the State and include metamorphic rocks, limestones, sandstones, shales, and glacial deposits. When analyzed according to Pennsylvania&rsquo;s hydrogeologic settings, 5 of the 20 (25 percent) settings had median indoor radon concentrations greater than the USEPA action level of 4 pCi/L; these settings are located mostly in the south-central part of the State. Median indoor radon concentrations aggregated according to geologic units and hydrogeologic settings are useful for drawing general conclusions about the occurrence of indoor radon in specific geologic units and hydrogeologic settings, but the associated data and maps have limitations. The aggregated indoor radon data have testing and spatial accuracy limitations due to lack of available information regarding testing conditions and the imprecision of geocoded test locations. In addition, the associated data describing geologic units and hydrogeologic settings have spatial and interpretation accuracy limitations, which are a result of using statewide data to define conditions at test locations and geologic data that represent a broad interpretation of geologic units across the State. As a result, indoor air radon concentration distributions are not proposed for use in predicting individual concentrations at specific sites nor for use as a decision-making tool for property owners to decide whether to test for indoor radon concentrations at specific property locations.

Pennsylvania↗

Ground-water resources of Saipan, Commonwealth of the Northern Mariana Islands

Saipan has an area of 48 mi 2 and is the largest of the 14 islands in the Commonwealth of the Northern Mariana Islands (CNMI). The island is formed by volcanic rocks overlain by younger limestones. The island is situated in the western Pacific Ocean at latitude 15 o 12'N and longitude 145 o 45'E, about 3,740 mi west-southwest of Honolulu and midway between Japan and New Guinea (fig. 1). The climate on Saipan is classified as tropical marine with an average temperature of 80 o F. The natural beauty of the island and surrounding waters are the basis for a growing tourist-based economy. The resulting rapid development and increases in resident and tourist populations have added stresses to the island's limited water supplies. Freshwater resources on Saipan are not readily observable because, aside from the abundant rainfall, most freshwater occurs as ground water. Fresh ground water is found in aquifers composed mainly of fragmental limestones. About 90 percent of the municipal water supply comes from 140 shallow wells that withdraw about 11 Mgal/d. The chloride concentration of water withdrawn from production wells ranges from less than 100 mg/L for wells in the Akgak and Capital Hill well fields, to over 2,000 mg/L from wells in the Puerto Rico, Maui IV, and Marpi Quarry well fields. The chloride concentrations and rates of ground-water production are not currently adequate for providing island residents with a potable 24-hour water supply and future demands are expected to be higher. To better understand the ground-water resources of the island, and water resources on tropical islands in general, the U.S. Geological Survey (USGS) entered into a cooperative program with the Commonwealth Utilities Corporation (CUC). The objective of the program, initiated in 1989, is to assess the ground-water resources of Saipan and to make hydrologic information available to the CUC in support of their ongoing efforts to improve the quality and quantity of the municipal water supply. This report presents some of the results of the program including descriptions of (1) the geography and geology, (2) the occurrence of fresh ground water in permeable limestones that extend to some distance below sea level where water-level elevation is affected by ocean tides (coastal aquifers) and in limestones that overlie volcanic basement rocks above sea level (high-level aquifers), (3) the water-table configuration and directions of ground-water flow, and (4) the rainfall, ground-water withdrawal, and chloride concentrations in well water. Also described is the relation of the changes in water-table elevations to changes in sea level, rainfall, and ground-water withdrawal.

Saipan↗

Baseline conditions and projected future hydro-climatic change in National Parks in the conterminous United States

The National Park Service (NPS) manages hundreds of parks in the United States, and many contain important aquatic ecosystems and/or threatened and endangered aquatic species vulnerable to hydro-climatic change. Effective management of park resources under future hydro-climatic uncertainty requires information on both baseline conditions and the range of projected future conditions. A monthly water balance model was used to assess baseline (1981-1999) conditions and a range of projected future hydro-climatic conditions in 374 NPS parks. General circulation model outputs representing 214 future climate simulations were used to drive the model. Projected future changes in temperature (T), precipitation (P), and runoff (R) are expressed as departures from historical baselines. Climate simulations indicate increasing T in 2030 for all parks with 50th percentile simulations projecting increases of 1.67 oC or more in 50% of parks. Departures in 2030 P indicate a mix of mostly increases and some decreases, with 50th percentile simulations projecting increases in P in more than 70% of parks. Departures in R for 2030 are mostly decreases , with the 50th percentile simulations projecting decreases in R in more than 50% of parks in all seasons except winter. Hence in many parks, R is projected to decrease even when P is projected to increase because of increasing T in all NPS parks. Projected changes in future hydro-climatic conditions can also be assessed for individual parks, and Rocky Mountain National Park and Congaree National Park are used as examples.

Water↗

California spotted owls

California spotted owls ( Strix occidentalis occidentalis ) are habitat specialists that are strongly associated with late-successional forests. For nesting and roosting, they require large trees and snags embedded in a stand with a complex forest structure (Blakesley et al. 2005, Gutiérrez et al. 1992, Verner et al. 1992b). In mixed-conifer forests of the Sierra Nevada, California spotted owls typically nest and roost in stands with high canopy closure (≥75 percent) [Note: when citing studies, we use terminology consistent with Jennings et al. (1999), however, not all studies properly distinguish between canopy cover and closure and often use the terms interchangeably (see chapter 14 for clarification)] and an abundance of large trees (>24 in (60 cm) diameter at breast height [d.b.h.]) (Bias and Gutiérrez 1992, Gutiérrez et al. 1992, LaHaye et al. 1997, Moen and Gutiérrez 1997, Verner et al. 1992a). The California spotted owl guidelines (Verner et al. 1992b) effectively summarized much of the information about nesting and roosting habitat. Since that report, research on the California spotted owl has continued with much of the new information concentrated in five areas: population trends, barred owl ( Strix varia ) invasion, climate effects, foraging habitat, and owl response to fire.

California↗

Flowing wells in Michigan, 1974

Flowing wells yielding fresh water occur in both the glacial drift and the bedrock in Michigan. Most known flowing wells are in the Lower Peninsula because the greater population in that part of the State has led to more frequent drilling. A comparison of flowing-well areas in 1900 with those in 1970 shows a probable decline in head in the glacial drift and the Marshall and Saginaw bedrock formations in the central and southern parts of the Lower Peninsula. Wells having the greatest reported flews are from the Marshall and Saginaw Formations; wells having the greatest heads are from the Cambrian, Ordovician, and Silurian rock units. Flowing wells in Michigan are largely used for domestic water supplies, although a few are used for municipal and industrial supplies. In general, water from most flowing wells is suitable for domestic use; however, high iron, chloride, and hardness impair water quality at some locations.

Michigan↗

Flood-frequency analyses from paleoflood investigations for Spring, Rapid, Boxelder, and Elk Creeks, Black Hills, western South Dakota

Flood-frequency analyses for the Black Hills area are important because of severe flooding of June 9-10, 1972, that was caused by a large mesoscale convective system and caused at least 238 deaths. Many 1972 peak flows are high outliers (by factors of 10 or more) in observed records that date to the early 1900s. An efficient means of reducing uncertainties for flood recurrence is to augment gaged records by using paleohydrologic techniques to determine ages and magnitudes of prior large floods (paleofloods). This report summarizes results of paleoflood investigations for Spring Creek, Rapid Creek (two reaches), Boxelder Creek (two subreaches), and Elk Creek. Stratigraphic records and resulting long-term flood chronologies, locally extending more than 2,000 years, were combined with observed and adjusted peak-flow values (gaged records) and historical flood information to derive flood-frequency estimates for the six study reaches. Results indicate that (1) floods as large as and even substantially larger than 1972 have affected most of the study reaches, and (2) incorporation of the paleohydrologic information substantially reduced uncertainties in estimating flood recurrence. Canyons within outcrops of Paleozoic rocks along the eastern flanks of the Black Hills provided excellent environments for (1) deposition and preservation of stratigraphic sequences of late-Holocene flood deposits, primarily in protected slack-water settings flanking the streams; and (2) hydraulic analyses for determination of associated flow magnitudes. The bedrock canyons ensure long-term stability of channel and valley geometry, thereby increasing confidence in hydraulic computations of ancient floods from modern channel geometry. Stratigraphic records of flood sequences, in combination with deposit dating by radiocarbon, optically stimulated luminescence, and cesium-137, provided paleoflood chronologies for 29 individual study sites. Flow magnitudes were estimated from elevations of flood deposits in conjunction with hydraulic calculations based on modern channel and valley geometry. Reach-scale paleoflood chronologies were interpreted for each study reach, which generally entailed correlation of flood evidence among multiple sites, chiefly based on relative position within stratigraphic sequences, unique textural characteristics, or results of age dating and flow estimation. The FLDFRQ3 and PeakfqSA analytical models (assuming log-Pearson Type III frequency distributions) were used for flood-frequency analyses for as many as four scenarios: (1) analysis of gaged records only; (2) gaged records with historical information; (3) all available data including gaged records, historical flows, paleofloods, and perception thresholds; and (4) the same as the third scenario, but ?top fitting? the distribution using only the largest 50 percent of gaged peak flows. The PeakfqSA model is most consistent with procedures adopted by most Federal agencies for flood-frequency analysis and thus was (1) used for comparisons among results for study reaches, and (2) considered by the authors as most appropriate for general applications of estimating low-probability flood recurrence. The detailed paleoflood investigations indicated that in the last 2,000 years all study reaches have had multiple large floods substantially larger than in gaged records. For Spring Creek, stratigraphic records preserved a chronology of at least five paleofloods in approximately (~) 1,000 years approaching or exceeding the 1972 flow of 21,800 cubic feet per second (ft 3 /s). The largest was ~700 years ago with a flow range of 29,300-58,600 ft 3 /s, which reflects the uncertainty regarding flood-magnitude estimates that was incorporated in the flood-frequency analyses. In the lower reach of Rapid Creek (downstream from Pactola Dam), two paleofloods in ~1,000 years exceeded the 1972 flow of 31,200 ft 3 /s. Those occurred ~440 and 1,000 years ago, with flows of 128,000-256,000 and 64,000-128,000 ft 3 /s, respectively. Five smaller paleofloods of 9,500-19,000 ft 3 /s occurred between ~200 and 400 years ago. In the upper reach of Rapid Creek (above Pactola Reservoir), the largest recorded floods are substantially smaller than for lower Rapid Creek and all other study reaches. Paleofloods of ~12,900 and 12,000 ft 3 /s occurred ~1,000 and 1,500 years ago. One additional paleoflood (~800 years ago) was similar in magnitude to the largest gaged flow of 2,460 ft 3 /s Boxelder Creek was treated as having two subreaches because of two tributaries that affect peak flows. During the last ~1,000 years, paleofloods of ~39,000-78,000 ft 3 /s and 40,000-80,000 ft 3 /s in the upstream subreach have exceeded the 1972 peak flow of 30,800 ft 3 /s. One other paleoflood was similar to the second largest gaged flow (16,400 ft 3 /s in 1907). For the downstream subreach, paleofloods of 61,300-123,000 ft 3 /s and 52,500-105,000 ft 3 /s in the last ~1,000 years have substantially exceeded the 1972 flood (50,500 ft 3 /s). Four additional paleofloods had flows between 14,200 and 33,800 ft 3 /s. The 1972 flow on Elk Creek (10,400 ft 3 /s) has been substantially exceeded at least five times in the last 1,900 years. The largest paleoflood (41,500-124,000 ft 3 /s) was ~900 years ago. Three other paleofloods between 37,500 and 120,000 ft 3 /s occurred between 1,100 and 1,800 years ago. A fifth paleoflood of 25,500-76,500 ft 3 /s was ~750 years ago. Considering analyses for all available data (PeakfqSA model) for all six study reaches, the 95-percent confidence intervals about the low-probability quantile estimates (100-, 200-, and 500-year recurrence intervals) were reduced by at least 78 percent relative to those for the gaged records only. In some cases, 95-percent uncertainty intervals were reduced by 99 percent or more. For all study reaches except the two Boxelder Creek subreaches, quantile estimates for these long-term analyses were larger than for the short-term analyses. The 1972 flow for the Spring Creek study reach (21,800 ft 3 /s) corresponds with a recurrence interval of ~400 years. Recurrence intervals are ~500 years for the 1972 flood magnitudes along the lower Rapid Creek reach and the upstream subreach of Boxelder Creek. For the downstream subreach of Boxelder Creek, the large 1972 flood magnitude (50,500 ft 3 /s) exceeds the 500-year quantile estimate by about 35 percent. The recurrence interval of ~100 years for 1972 flooding along the Elk Creek study reach is small relative to other study reaches along the eastern margin of the Black Hills. All of the paleofloods plot within the bounds of a national envelope curve, indicating that the national curve represents exceedingly rare floods for the Black Hills area. Elk Creek, lower Rapid Creek, and the downstream subreach of Boxelder Creek all have paleofloods that plot above a regional envelope curve; in the case of Elk Creek, by a factor of nearly two. The Black Hills paleofloods represent some of the largest known floods, relative to drainage area, for the United States. Many of the other largest known United States floods are in areas with physiographic and climatologic conditions broadly similar to the Black Hills-semiarid and rugged landscapes that intercept and focus heavy precipitation from convective storm systems. The 1972 precipitation and runoff patterns, previous analyses of peak-flow records, and the paleoflood investigations of this study support a hypothesis of distinct differences in flood generation within the central Black Hills study area. The eastern Black Hills are susceptible to intense orographic lifting associated with convective storm systems and also have high relief, thin soils, and narrow and steep canyons-factors favoring generation of exceptionally heavy rain-producing thunderstorms and promoting runoff and rapid concentration of flow into stream channels. In contrast, storm potential is smaller in and near the Limestone Plateau area, and storm runoff is further reduced by substantial infiltration into the limestone, gentle topography, and extensive floodplain storage. Results of the paleoflood investigations are directly applicable only to the specific study reaches and in the case of Rapid Creek, only to pre-regulation conditions. Thus, approaches for broader applications were developed from inferences of overall flood-generation processes, and appropriate domains for application of results were described. Example applications were provided by estimating flood quantiles for selected streamgages, which also allowed direct comparison with results of at-site flood-frequency analyses from a previous study. Several broad issues and uncertainties were examined, including potential biases associated with stratigraphic records that inherently are not always complete, uncertainties regarding statistical approaches, and the unknown applicability of paleoflood records to future watershed conditions. The results of the paleoflood investigations, however, provide much better physically based information on low-probability floods than has been available previously, substantially improving estimates of the magnitude and frequency of large floods in these basins and reducing associated uncertainty.

South Dakota↗

Communicating scientific findings to the general public

The Human Induced Land Transformation project (HILT), part of the U.S. Geological Survey Global Change Research Program, has generated considerable public interest during the first two phases of the project: the data assembly and visualization phase carried out for the San Francisco Bay area; and the model building and calibration phase. The third phase, now underway for the Washington/Baltimore region, is a large scale test of the model's portability to another urban area. The modeling community has been kept informed of progress and findings of the HILT project through conventional academic outlets such as conference and journal publications as well as through more popular outlets such as newspaper, television, and a World Wide Web site. The program, sample data and documentation of the model will be available for downloading to those with an Internet connection. While recognizing that not all research has the same degree of public appeal as this project, additional effort was invested to establish contacts, publicize, and distribute the historical visualizations and model predictions generated by this work in the media, publishing, and in education. In this paper, we will cover the lessons learned in publicizing HILT, the techniques used and the criteria evolved for successful involvement of the general public in the modeling of land cover transitions.

Conference Paper↗

Characterization and data-gap analysis of surface-water quality data in the Piceance study area, western Colorado, 1959–2009

The U.S. Geological Survey, in cooperation with Federal, State, county, and industry partners, developed a Web-accessible common data repository to provide access to historical and current (as of August 2009) water-quality information (available on the Internet at http://rmgsc.cr.usgs.gov/cwqdr/Piceance/index.shtml ). Surface-water-quality data from public and private sources were compiled for the period 1931 to 2009 and loaded into the common data repository for the Piceance Basin. A subset of surface-water-quality data for 1959 to 2009 from the repository were compiled, reviewed, and checked for quality assurance for this report. This report contains data summaries, comparisons to water-quality standards, trend analyses, a generalized spatial analysis, and a data-gap analysis for select water-quality properties and constituents. Summary statistics and a comparison to standards were provided for 347 sites for 33 constituents including field properties, nutrients, major ions, trace elements, suspended sediment, Escherichia coli, and BTEX (benzene, toluene, ethylbenzene, and xylene). When sufficient data were available, trends over time were analyzed and loads were calculated for those sites where there were also continuous streamflow data. The majority of sites had information on field properties. Water temperature data was available for 316 sites where data were collected between 1959 and 2009. The only trend that was detected in temperature was an upward trend at the Gunnison River near Grand Junction, Colorado. There were 326 values out of a total of 32,006 values in the study area that exceeded the aquatic-life standard for daily maximum water temperature. For the entire study area, 196 sites had dissolved-oxygen data collected between 1970 and 2009, and median dissolved-oxygen concentrations ranged from 6.8 to11.2 milligrams per liter (mg/L). There were 185 concentrations that exceeded the dissolved oxygen aquatic-life standard out of a total of 11,248 values. The pH data were available for 276 sites, and median pH values ranged from 7.5 to 9.0. There were 241 values that exceeded the high pH standard and 13 values that were less than the low pH standard of the 16,790 values in the study area. Nutrients within the study area were not well represented in each basin and were often not being sampled currently. For the entire study area, 62 sites had nitrate data collected between 1958 and 2009, and median nitrate concentrations ranged from less than detection to 3.72 mg/L as nitrogen. The maximum contaminant level for domestic water supply for nitrate is 10 mg/L and was exceeded once in 3,736 samples. Total phosphorus was collected at 113 sites between 1974 and 2009, and median total phosphorus concentrations ranged from less than detection to 5.04 mg/L. The U.S. Environmental Protection Agency recommendation for phosphorus is less than 0.1 mg/L, and 1,469 of 4,842 samples exceeded this recommended standard. An upward trend in both nitrate and total phosphorus was detected in the White River above Coal Creek near Meeker, Colo. Standards for major ions exist only for chloride and sulfate. For the entire study area, 118 sites had both chloride and sulfate concentration data collected between 1958 and 2009. Median chloride concentrations ranged from 0.085 mg/L to 280 mg/L. Median sulfate concentrations ranged from 4.57 mg/L to 15,000 mg/L. Both chloride and sulfate domestic water-supply standards are 250 mg/L. There were 120 chloride concentrations and 1,111 sulfate concentration samples that exceeded these standards. A downward trend in dissolved solids was detected at the Colorado River near the Colorado-Utah state border and could be a result of salinity control work near Grand Junction, Colo. Trace elements were relatively well represented both temporally and spatially in the study area though the number of trace element samples per site was not typically enough to compute trends or loads except for selenium. There were 127 sites that had dissolved iron concentration data collected between 1961 and 2009, and median iron concentrations ranged from less than detection to 1,100 micrograms per liter (µg/L). The 30-day drinking-water standard for iron is 300 µg/L, and 203 samples exceeded the standard. Selenium was the best represented trace element with selenium concentration data collected at 197 sites between 1973 and 2009, and median selenium concentrations range from less than detection to 181 µg/L. The chronic standard of 4.6 µg/L for selenium concentrations was exceeded in 899 samples, and the acute aquatic-life standard of 18.4 µg/ for selenium was exceeded in 629 samples. High concentrations of selenium are of concern in the Lower Gunnison River Basin because of the combination of geologic formations and land use. There were significant downward trends in selenium at both main-stem sites on the Gunnison River at Delta, Colo., and the Gunnison River near Grand Junction, Colo. High selenium concentrations correlate with high salinity concentrations; thus, when salinity control efforts are conducted in selenium-rich areas in the Lower Gunnison River Basin, both salinity and selenium have the potential to decrease. Spatial, temporal, and analytical data gaps were identified in the study area. The spatial coverage of sampling sites could be expanded in the White River Basin by adding more tributary sites. No water-quality data exist for tributary streams in the area north of Rangely, Colo., where extensive energy development has occurred in a complex geologic setting. Douglas Creek has a drainage area of 425 square miles and has limited historic water-quality and water-quantity data. Limited data were available for field properties, major ions, nutrients, and trace elements on the main stem of the Colorado River between Glenwood Springs and Cameo, Colo. Nutrient data were minimally collected upstream from Colorado River at the Colorado-Utah state border and on the Gunnison River (major tributary in the reach). Approximately 30 percent of the samples for total phosphorus in the Lower Gunnison River Basin exceeded the recommended standard, yet there were insufficient data to do trends analysis in the Lower Gunnison River Basin except at the Gunnison near Grand Junction site. There is limited trace element data except for selenium in the Lower Gunnison River Basin. Additional sampling is necessary to understand the occurrence, concentrations, and loads of these constituents.

Colorado↗

Uncertainty of groundwater vulnerability assessments for agricultural regions in Hawaii: Review

There are important challenges associated with assessing potential groundwater vulnerability hazards that may result from regional scale applications of agrochemicals. The increasing availability of Geographic Information System (GIS) software to those involved in assisting with landuse decisions has resulted in the widespread production of multicolored risk management maps for many environmentally sensitive issues. Soil-based GIS's have recently been coupled to various solute-leaching models to make near-surface groundwater vulnerability assessments for guidance in pesticide regulation in several states. In general, these assessments rest on soil, climatic, and chemical data that are extremely sparse and contain considerable uncertainty. It is also important to acknowledge the uncertainty associated with the transport/fate processes that are not accounted for by the modeling approach used to make the assessment. In this paper, we review the results from a series of papers that have focused on characterization of uncertainty in pesticide mobility estimates, using the attenuation and retardation indices (AF and RF), for the Pearl Harbor Basin on the Hawaiian island of Oahu. Relative to data error uncertainties, we discuss the impacts of: (i) soil, climatic, and chemical data base uncertainties, (ii) reductions in data base uncertainties, (iii) extrapolation of soil data base information based on soil taxonomy and soil survey, and (iv) importing information from outside the region of interest. Relative to model error uncertainties, we compare pesticide leaching estimates from the simple AF and RF mobility indices with simulations from the EPA's Pesticide Root Zone Model (PRZM) and field observations. Finally, we outline a Regional Integrated Risk Assessment approach for characterizing regional scale groundwater vulnerability for near-surface nonpoint sources.

Hawaii↗