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Revision of ModelMuse to support the use of PEST software with MODFLOW and SUTRA models

Executive Summary ModelMuse is a graphical user interface for several groundwater modeling programs. ModelMuse was updated to generate the input files for the parameter estimation software suite PEST. The software is used with MODFLOW or SUTRA models to run PEST-based parameter estimation and display the updated model inputs after parameter estimation. The PEST input files can also be used with the PEST++ version 5 software suite. Parameter estimation typically requires defining the parameters being adjusted during calibration and observations for assessing calibration quality. After a parameter is defined in ModelMuse, it can be applied to all or part of a model dataset. Pilot points—a parameterization device that facilitates higher levels of parameterization—can be used to assign spatially variable distributions of model inputs. Parameters can be applied to temporally varying features, such as boundary conditions, by either applying them to all the values in a series in one step or by applying separate parameters to individual members of a series. ModelMuse allows the definition of many observation types from various model output files. For MODFLOW 6 and SUTRA models, new options were added to ModelMuse to allow it to display the changed input after parameter estimation is complete. For MODFLOW–2005 and MODFLOW–NWT models, ModelMuse can import an entire model for visualization. An example illustrates the use of PEST with a MODFLOW 6 model in ModelMuse.

Techniques and Methods↗

Occurrence and temporal variability of methyl tert -butyl ether (MTBE) and other volatile organic compounds in select sources of drinking water : results of the focused survey

The large-scale use of the gasoline oxygenate methyl tert -butyl ether (MTBE), and its high solubility, low soil adsorption, and low biodegradability, has resulted in its detection in ground water and surface water in many places throughout the United States. Studies by numerous researchers, as well as many State and local environmental agencies, have discovered high levels of MTBE in soils and ground water at leaking underground gasoline-storage-tank sites and frequent occurrence of low to intermediate levels of MTBE in reservoirs used for both public water supply and recreational boating. In response to these findings, the American Water Works Association Research Foundation sponsored an investigation of MTBE and other volatile organic compounds (VOCs) in the Nation's sources of drinking water. The goal of the investigation was to provide additional information on the frequency of occurrence, concentration, and temporal variability of MTBE and other VOCs in source water used by community water systems (CWSs). The investigation was completed in two stages: (1) reviews of available literature and (2) the collection of new data. Two surveys were associated with the collection of new data. The first, termed the Random Survey, employed a statistically stratified design for sampling source water from 954 randomly selected CWSs. The second, which is the focus of this report, is termed the Focused Survey, which included samples collected from 134 CWS source waters, including ground water, reservoirs, lakes, rivers, and streams, that were suspected or known to contain MTBE. The general intent of the Focused Survey was to compare results with the Random Survey and provide an improved understanding of the occurrence, concentration, temporal variability, and anthropogenic factors associated with frequently detected VOCs. Each sample collected was analyzed for 66 VOCs, including MTBE and three other ether gasoline oxygenates (hereafter termed gasoline oxygenates). As part of the Focused Survey, 451 source-water samples and 744 field quality-control (QC) samples were collected from 78 ground-water, 39 reservoir and (or) lake, and 17 river and (or) stream source waters at fixed intervals for a period of 1 year. Using a common assessment level of 0.2 μg/L (micrograms per liter) (2.0 μg/L for methyl ethyl ketone), 37 of the 66 VOCs analyzed were detected in both surveys. However, VOCs, especially MTBE and other gasoline oxygenates, were detected more frequently in the Focused Survey than in the Random Survey. MTBE was detected in 55.5 percent of the CWSs sampled in the Focused Survey and in 8.7 percent of those sampled in the Random Survey. Little difference in occurrence, however, was observed for trihalomethanes (THMs), which were detected in 16.4 and 14.8 percent of Focused Survey and Random Survey CWSs, respectively. This may indicate a pervasive occurrence of THMs in several source-water types, regardless of CWS size or geographic location. Using data at or above the method detection limit to assess temporal variability and anthropogenic factors associated with frequent detection of select VOCs, concentrations in the Focused Survey in ground-water, reservoir, and river source waters were typically less than 1 μg/L. Also, at a 95-percent confidence interval, no statistically significant differences were observed in comparing concentrations in the first and second ground-water sample. A weak seasonal pattern was observed in samples collected from reservoirs and lakes where gasoline oxygenates and other gasoline compounds were detected more frequently during spring and summer, presumedly a result of increased use of motorized watercraft during these seasons. In contrast, seasonal patterns were not observed in samples collected from rivers and streams. The lack of seasonal differences in river and stream source waters sampled may indicate a common and continuous source of contamination. The most frequently detected VOC (MTBE) and the two most frequently occurring subgroups of VOCs (gasoline oxygenates and THMs) detected in CWS source waters were further characterized to evaluate some anthropogenic factors that may better explain their frequent occurrence. Gasoline oxygenates were detected in 73.9 percent of all CWSs sampled. The concentration of gasoline oxygenates was slightly correlated with watercraft use on reservoirs inside MTBE high-use areas (r2=0.3783) but not outside of these areas (r2=0.0242). In general, the concentration of gasoline oxygenates increased as watercraft use increased. THMs were detected in 47.8 percent of the CWSs supplied by surface water. The frequent occurrence of THMs in reservoir source waters was determined to be an artifact of disinfection and the recycling of chlorinated water to these reservoirs. All CWSs with frequent occurrence of THMs served by a reservoir indicated that chlorine was added to waters for various reasons and that the chlorinated water was then released back to, or upstream of, the reservoir or lake that was sampled.

Water-Resources Investigations Report↗

Geohydrology of the lowland lakes area, Anchorage, Alaska

Unconsolidated deposits, chiefly of glacial origin, make up the surficial geologic materials in the Anchorage lowland lakes area , the western part of the Anchorage glacial outwash plain. Postglacial accumulation of peat, commonly 5 to 10 feet thick, and the presence of ground water at or very near the surface combine to create the swamp-muskeg terrane of much of the area. Deeper, confined ground water is also present beneath thick silt and clay layers that underlie the surficial deposits. Domestic water supply for the lowland lakes area is provided largely by public-supply wells completed in the deep, confined aquifers. No large perennial streams traverse the area, thus streamflow is not a major parameter in the area 's natural water balance. The major uses of surface water are recreational, including fishing and boating at several of the larger lakes, and private and commercial aircraft operations at Hood-Spenard Lakes floatplane base. The hydrology and water balance of these lakes is complex. Water levels in some lakes appear to be closely related to adjacent ground-water levels. Other lakes are evidently perched above the local water table. The relation of lake level to adjacent ground-water level may vary along the shoreline of a single lake. The effect of residential development practices on lake basin water balance is not completely understood. At Sand Lake, the largest lake in this area of rapid urbanization, the water level has declined about 6 feet since the early 1960's. (Woodard-USGS)

Alaska↗

Multi-saline sample distillation apparatus for hydrogen isotope analyses: Design and accuracy

A distillation apparatus for saline water samples was designed and tested. Six samples may be distilled simultaneously. The temperature was maintained at 400 C to ensure complete dehydration of the precipitating salts. Consequently, the error in the measured ratio of stable hydrogen isotopes resulting from incomplete dehydration of hydrated salts during distillation was eliminated. (USGS)

Water-Resources Investigations Report↗

A digital model for streamflow routing by convolution methods

U.S. Geological Survey computer model, CONROUT, for routing streamflow by unit-response convolution flow-routing techniques from an upstream channel location to a downstream channel location has been developed and documented. Calibration and verification of the flow-routing model and subsequent use of the model for simulation is also documented. Three hypothetical examples and two field applications are presented to illustrate basic flow-routing concepts. Most of the discussion is limited to daily flow routing since, to date, all completed and current studies of this nature involve daily flow routing. However, the model is programmed to accept hourly flow-routing data. (USGS)

Water-Resources Investigations Report↗

Status of water levels in aquifers in the Nacatoch sand and Tokio Formation of southwestern Arkansas, 1996

Aquifers in the Nacatoch Sand and Tokio Formation in southwestern Arkansas are a source of water for industrial, public supply, domestic, and agricultural uses. Water-level measurements were made in 24 wells completed in the Nacatoch Sand and 18 wells completed in the Tokio Forma tion from August through October 1996 to pro duce potentiometric-surface maps. The direction of ground-water flow in aquifers in the Nacatoch Sand and Tokio Formation generally is to the south-southeast or southeast. Potentiometric highs for both aquifers are in the outcrop areas. The aquifer in the Tokio Formation has artesian flow in southeastern Pike, northeastern Hempstead, and northwestern Nevada Counties. One apparent cone of depression was evident within the study area in the aquifer in the Nacatoch Sand. Withdrawals from aquifers in the Nacatoch Sand and Tokio Formation increased from 1965 to 1980 and decreased from 1980 to 1995. Long-term hydrographs were prepared for seven wells in the study area. Changes in water levels in three wells completed in the aquifer in the Nacatoch Sand and one well completed in the aquifer in the Tokio Formation might be associated with decreased withdrawals. Evidence of an association between withdrawals and water levels in three wells is not apparent.

Water-Resources Investigations Report↗

Secondary mineralogy of core from geothermal drill hole CTGH-1, High Cascade Range, Oregon

Geothermal drill hole CTGH-1, located near Breitenbush Hot Springs in the Cascade Mountains of northwest Oregon, was drilled to a depth of 1463 m. The maximum reported temperature at the bottom of the drill hole was 96.4??C. The drill core consists predominantly of basalt to basaltic andesite lava flows, tuffs, and volcanic breccia. Red to orange iron-oxide stained tuffs are at least partly altered to smectite. Vesicles, fractures, and open spaces between breccia fragments are partly to completely filled by secondary minerals. All of the minerals are compatible with the present low-temperature conditions.

Conference Paper↗

Trichloroethylene and 1,1-dichloroethylene concentrations in ground water after temporary shutdown of the reclamation well field at Air Force Plant 44, Tucson, Arizona, 1999

Industrial activities beginning in the early 1940s resulted in extensive contamination of ground water near the Tucson International Airport, Tucson, Arizona, including an area around Air Force Plant 44, an industrial facility located on land owned by the U.S. Air Force and operated by a defense contractor. Principal ground-water contaminants are volatile organic compounds, primarily trichloroethylene (also called trichloroethene) and 1,1-dichloroethylene (also called 1,1-dichloroethene). A ground- water reclamation system was put into operation in 1987 to extract and treat contaminated ground water at Air Force Plant 44 and the downgradient area that is south of Los Reales Road. The ground- water reclamation system consists of 25 extraction wells, 22 recharge wells, and a water-treatment facility. Soil-vapor extraction techniques are being used to remove volatile organic compounds from the unsaturated zone. More than 120,000 pounds of volatile organic compounds have been removed from the regional aquifer and overlying unsaturated zone at Air Force Plant 44 and adjacent downgradient areas south of Los Reales Road. Air Force Plant 44 and adjacent areas being remediated by the ground-water reclamation system are about 7 square miles. To assess ground-water cleanup progress at Air Force Plant 44 and surrounding areas south of Los Reales Road, and possibly to identify areas that are resistant to cleanup attempts, ground-water samples were collected and analyzed after water levels had returned to near-equilibrium conditions following a 3-week shutdown of extraction and recharge wells. Modifications of the standard ground-water sampling procedures used at the site also were tested. The modifications included tests of a reduced-flow purging and sampling method in six monitoring wells and vertical- profile sampling in five extraction wells at the reclamation well field. The water treatment facility and all extraction and recharge wells at the reclamation well field were shut down on April 15, 1999, and water levels were allowed to recover for about 3 weeks before samples of ground water were obtained from 102 wells at Air Force Plant 44 and surrounding areas. Concentrations of trichloroethylene and 1,1-dichloroethylene were determined for samples obtained during the sitewide sampling effort. Data for 101 wells sampled in February 1999 before shutdown were compared with data obtained for wells sampled in May 1999 after shutdown. Concentrations of trichloroethylene increased in 36 wells, remained the same in 32 wells, and decreased in 33 wells. Increases in concentrations of trichloroethylene of as much as 1,476 micrograms per liter and decreases of as much as 2,292 micrograms per liter were reported after shutdown. Concentrations of trichloroethylene remained the same for the two sampling periods in wells that had concentrations that were at, or close to, the lower reporting limit (0.5 micrograms per liter) before shutdown. Net change in concentrations of trichloroethylene after shutdown on a percentage basis ranged from an increase of 1,300 percent to a decrease of 100 percent. Increases in concentrations of 1,1-dichloroethylene after shutdown of the reclamation well field of as much as 66 micrograms per liter and decreases of as much as 411.6 micro- grams per liter were reported. Concentrations of 1,1-dichloroethylene remained the same for the two sampling periods in wells that had concentrations that were at, or close to, the lower reporting limit (0.5 micrograms per liter) before shutdown. Net change in concentrations of 1,1-dichloroethylene after shutdown on a percentage basis ranged from an increase of 660 percent to a decrease of 100 percent. Data obtained from the water samples indicate that the largest changes in concentrations of trichloroethylene and 1,1-dichloroethylene occurred in samples collected from wells completed in the upper zone of the regional aquifer, along the axis of the contaminant plume, in close proximity to previously identified historical disposal areas. Changes in contaminant concentrations observed after shutdown of the well field probably were the result of changes in ground-water flow directions under nonpumping conditions compared with those present when the extraction and recharge wells were operating. Minimal changes occurred at the perimeter of the plume, which suggests that operation of the reclamation well field has been successful at containing the spread of the plume. New contaminant-source areas were not identified within the perimeter of the plume. A modification of the standard sampling technique used at Air Force Plant 44 was tested in six wells. In these wells, greatly reduced flow rates were used for well purging and sampling. Results indicate no distinct pattern of change of contaminant concentrations compared with concentrations in samples subsequently obtained using the standard technique, and no advantage was evident for using this method in routine sampling of the monitoring wells at Air Force Plant 44. Temperature profiles obtained before vertical-profile sampling of selected wells indicate little temperature variation with depth. The temperature-profile information suggests that under nonpumping conditions, most of the water enters these wells near the top of the screened interval and moves downward in response to a hydraulic gradient in the regional aquifer. Samples at depths below the top of the screened interval probably do not accurately represent water from the adjacent sediments. Vertical-profile samples were obtained in five wells and analyzed for concentrations of trichloroethylene. None of the wells showed large enough variation of contaminant concentrations with depth to indicate that a major improvement in extraction efficiency could be obtained by pumping selectively from a restricted interval. The largest variation in concentrations of trichloroethylene with depth that was observed ranged from 62 micrograms per liter near the top of the screened interval to 42 micrograms per liter near the bottom of the screened interval of one of the wells. The lack of large variation is probably the result of downward water flow in the casing of these wells.

Arizona↗

Seventh progress report on the cooperative investigation of springs and streamflow in the Tecolote tunnel area of Santa Barbara County, California

This report is the seventh in a a continuing series of progress reports giving the results of discharge measurements made at selected springs and streams in the Tecolote Tunnel are area of the Santa Ynez Mountains. The mountains. The measurement program was begun on its present scale in the latter part of 1948 by the Geological Survey at the request of the Santa Barbara County Water Agency and is being continued under a cooperative agreement whereby each agency pays half the cost of the investigation. The purpose of the program is to obtain sufficient factual data to determine what effect, if any, the inflow of ground water into Tecolote Tunnel will have on the flow of springs and streams in the vicinity of the tunnel. The area involved in the study, shown by plate 1, was made large enough to include a number of springs and steams believe to be outside the zone of influence of the tunnel. Tecolote Tunnel, completed late in 1955, was built by the Bureau of Reclamation for the purpose of conveying water stored in Cachuma Reservoir to the city of Santa Barbara and adjacent coastal communities. The alinement of the tunnel is roughly north and south through the center of the arbitrarily chosen study area which extends from the Painted Cave area on the east to Refugio Pass on the west and from the Santa Ynez River on the North to the Pacific Ocean on the south. The purpose of this report is to make available the factual data obtained from July 1954 to June 1956, together with a brief presentation of precipitation, springflow, and tunnel outflow for the entire period of investigation.

California↗

Stratigraphy and structure of the western Kentucky fluorspar district

The western Kentucky fluorspar district is part of the larger Illinois-Kentucky fluorspar district, the largest producer of fluorspar in the United States. This report is based largely on data gathered from 1960 to 1974 during the U.S. Geological Survey-Kentucky Geological Survey cooperative geologic mapping program of Kentucky. It deals chiefly with the stratigraphy and structure of the district and, to a lesser extent, with the fluorspar-zinc-lead-barite deposits. Sedimentary rocks exposed in the district range in age from Early Mississippian (Osagean) to Quaternary. Most rocks exposed at the surface are Mississippian in age; two-thirds are marine fossiliferous limestones, and the remainder are shales, siltstones, and sandstones. Osagean deep-water marine silty limestone and chert are present at the surface in the southwestern corner of the district. Meramecian marine limestone is exposed at the surface in about half the area. Chesterian marine and fluvial to fluviodeltaic clastic sedimentary rocks and marine limestone underlie about one-third of the area. The total sequence of Mississippian rocks is about 3,000 ft thick. Pennsylvanian rocks are dominantly fluvial clastic sedimentary rocks that change upward into younger fluviodeltaic strata. Pennsylvanian strata of Morrowan and Atokan age are locally thicker than 600 ft along the eastern and southeastern margin and in the major grabens of the district where they have been preserved from erosion. Cretaceous and Tertiary sediments of the Mississippi embayment truncate Paleozoic formations in and near the southwestern corner of the district and are preserved mostly as erosional outliers. The deposits are Gulfian nonmarine gravels, sands, and clays as much as 170 ft thick and upper Pliocene fluvial continental deposits as thick as 45 ft. Pleistocene loess deposits mantle the upland surface of the district, and Quaternary fluvial and fluviolacustrine deposits are common and widespread along the Ohio and Cumberland Rivers and their major tributaries. Many mafic dikes and a few mafic sills are present. The mafic rocks are mostly altered mica peridotites or lamprophyres that are composed of carbonate minerals, serpentine, chlorite, and biotite and contain some hornblende, pyroxene, and olivine. Most of the dikes are in a north-north west-trending belt 6 to 8 mi wide and strike N. 20 0 -30 0 W. The dikes dip from 80 0 to 90 0 and are commonly 5 to 10 ft wide. Radioisotopic study indicates that the dikes are Early Permian in age. The district is just southeast of the intersection of the east-trending Rough Creek-Shawneetown and northeast-trending New Madrid fault systems. The district's principal structural features are a northwest-trending domal anticline, the Tolu Arch, and a series of steeply dipping to nearly vertical normal faults and fault zones that trend dominantly northeastward and divide the area into elongated northeast-trending grabens and horsts. Formation of these grabens and horsts was one of the major tectonic events in the district. Vertical displacement may be as much as 3,000 ft but commonly ranges from a few feet to a few hundred feet; no substantial horizontal movement is believed to have taken place. Many cross faults having only a few feet of displacement trend northwestward and are occupied at places by mafic dikes. Faulting was mostly post-Early Permian to pre-middle Cretaceous in age. Many theories have been advanced to explain the structural history of the district. A generally acceptable overall hypothesis that would account for all the structural complexities, however, is still lacking. Useful structural data, such as the structural differences between the grabens and the horsts, have been obtained, however, from the recently completed geologic mapping. Mapping also has more clearly shown the alinement of the Tolu Arch, the belt of dikes, and an unusually deep graben (the Griffith Bluff graben); this alinement suggests that possibl

Professional Paper↗

Yellowstone grizzly bear investigations: Annual report of the Interagency Grizzly Bear Study Team, 2003

The contents of this Annual Report summarize results of monitoring and research from the 2003 field season. The report also contains a summary of nuisance grizzly bear ( Ursus arctos horribilis ) management actions. The study team continues to work on issues associated with counts of unduplicated females with cubs-of-the-year (COY). These counts are used to establish a minimum population size, which is then used to establish mortality thresholds for the Recovery Plan (U.S. Fish and Wildlife Service [USFWS] 1993). A computer program that defines the rule set used by Knight et al. (1995) to differentiate unique family groups is currently under development. Once complete, we intend to use it to verify the accuracy of the rules using known bears and their telemetry locations in test runs. We hope to have this work complete by summer 2004. The grizzly bear recovery plan (USFWS 1993) established mortality quotas at 4% of the minimum population estimate derived from female with COY data and no more than 30% of the 4% (1.2%) could be female bears. Simulation modeling (Harris 1984) established sustainable mortality at around 6% of the population. We used the latest information on reproduction and survival to estimate population trajectory in the same simulation model originally used by Harris. A Wildlife Monograph has been drafted and submitted for consideration as a publication. We anticipate final word sometime during winter 2005. Our project addressing the potential application of stable isotopes and trace elements to quantify consumption rates of whitebark pine ( Pinus albicaulis ) and cutthroat trout ( Oncorhynchus clarki ) by grizzly bears was completed. Our manuscript on consumption rates of whitebark pine has been published (Canadian Journal of Zoology 81:763-770). A copy can be found on the Interagency Grizzly Bear Study Team (IGBST) website http://www.nrmsc.usgs.gov/research/igbst-home.htm. The manuscript on fish consumption is in final review and should be published in 2004. We began a new study in Grand Teton National Park evaluating habitat use both temporally and spatially between grizzly and black ( Ursus americanus ) bears. We will employ a new form of Global Positioning System (GPS) technology that incorporates a spread spectrum communication system. Spread spectrum allows for transfer of stored GPS locations from the collar to a remote receiving station. We tested 2 collars during the fall of 2003 and provide a summary of the results. We will attempt to deploy several of these collars during the 2004 field season. The annual reports of the IGBST summarize annual data collection. Because additional information can be obtained after publication, data summaries are subject to change. For that reason, data analyses and summaries presented in this report supersede all previously published data. The study area and sampling techniques are reported by Blanchard (1985), Mattson et al. (1991a), and Haroldson et al. (1998).

Montana↗

Water quality of the St. Clair River, Lake St. Clair, and their U.S. tributaries, 1946-2005

The St. Clair River/Lake St. Clair waterway forms an international boundary between the United States and Canada. The waters of the area are an important part of the cultural heritage of the area and serves as an important water-supply and power-generating resource; the waterway also supports an economy based largely on recreation, agriculture, and manufacturing. This report was undertaken as part of the Lake St. Clair Regional Monitoring Project for the purpose of providing a comprehensive assessment of the hydrological, chemical, and physical state of the surface water of Lake St. Clair and its tributaries. The data varied in focus and density over the period of compilation which in many cases this variation prevented the completion of statistical analyses because data did not meet minimum comparability or quality requirements for those tests. Comparison of water quality of the Belle, Black, Clinton, and Pine River Basins, as well as basins of minor rivers in the study area, showed that water quality in many of the tributaries, particularly the Clinton River and some of the minor rivers, was degraded compared to the water quality of the St. Clair River/Lake St. Clair waterway. Data analyses included comparison of nutrients, chloride, specific conductance, turbidity, biochemical oxygen demand (BOD), and pesticides among the basins and the St. Clair River. Median concentrations of total nitrate were well below the recommended USEPA total nitrogen ambient water-quality criterion of 0.54 mg/L as N for nutrient ecoregion VII for all study-area streams except the Clinton River. More than 93 percent of the phosphorus concentrations for the Belle, Black, Pine and minor river basins and 84 percent of the phosphorus concentrations for the Clinton River Basin are greater than the USEPA recommended ambient total phosphorus criterion of 0.033 mg/L for rivers and streams. Nine chloride concentrations exceeded the USEPA criterion maximum concentration (CMC) for chloride set at 860 mg/L for all study-area streams, with the six largest being in the Belle River Basin. Higher chloride concentrations were increasingly common from 2002 to 2005. The urban minor river basins had the highest median specific conductance, whereas the agricultural Pine River Basin had the lowest median specific conductance. The median values of BOD for the five basins in the study area ranged from 2.4 mg/L for the Pine River Basin to 3.2 mg/L for the Black and Clinton River Basins, whereas the median for the St. Clair River was 0.5 mg/L. In 1985, the highest concentrations of pesticides were found in samples from the mouth of the Clinton River; however, in 1996–98, the majority of high pesticide concentrations were found in samples from the Black River. Changing land-use patterns, specifically conversion of agricultural lands to urban/residential lands in the Clinton River Basin, may explain this difference. Trend analysis was done for four stream sites where adequate data were available. These analyses identified no significant water-quality changes at a stream site on the Black River, where land-use patterns have changed little in the past few decades. This stands in marked contrast to trend analysis for three stream sites in the Clinton River Basin, which has undergone significant land-use change. The changes at the Clinton River stream sites, ranging from 5 to 13 significant trends, were generally decreases in nutrients and increases in total dissolved solids (TDS) and chloride. The greater flow volume of the St. Clair River/Lake St. Clair waterway is able to assimilate incoming dissolved and suspended constituents from tributaries with little effect upon its overall water quality, although incomplete mixing may result in localized water-quality impairment downstream from tributary confluences. Mixing effects on Lake St. Clair water quality was also demonstrated in analysis of Escherichia coli ( E. coli ) data collected at paired nearshore/offshore sites, which reflected similarity in water quality among many paired sites.

Michigan↗

Long-term mercury loading and trapping dynamics in a Western North America reservoir

Study Region The Carson River including Lahontan Reservoir in Northwestern Nevada, USA Study Focus The discovery, mining, and processing of silver and gold from the Comstock Lode in northwestern Nevada heavily contaminated the Carson River system with mercury (Hg). The river now contains some of the highest recorded water column and bed sediment Hg concentrations reported in peer-reviewed literature. Acute Hg contamination in river and reservoir bed sediment has led to elevated methylmercury (MeHg) concentrations across all trophic levels of Lahontan Reservoir, culminating in significant health risks to humans. Lahontan Reservoir, located downstream from the mills that processed Comstock ore, has served as a Hg trap since the completion of the dam in 1915. Starting in 1997 and extending through 2021, the U.S. Geological Survey has collected and analyzed hundreds of discrete water samples entering and exiting Lahontan Reservoir for unfiltered total Hg (uf.THg), thereby providing a first-of-its-kind opportunity for studying long-term Hg trapping efficiencies within a western North American reservoir. Continuous time series of uf.THg concentration and flux above and below the reservoir were estimated using the weighted regressions on time, discharge, and season with the Kalman filtering (WRTDS-K) method employed with newly developed methods to account for non-natural (i.e., managed) hydrographs below a reservoir. New hydrological insights for the region An estimated 31,650 kg (34.89 US tons) of uf.THg entered Lahontan Reservoir during the 25 year period of analysis, accounting for approximately 0.5% of the total uf.THg estimated to have been released to the Carson River system [6.8 million kg (7500 US tons)] over a multi-decade mining boom. Moreover, approximately 92% of the estimated uf.THg entering Lahontan Reservoir was trapped. On an annual basis, however, trapping efficiencies range between 34% and 98%, and are closely related to the total annual discharge. Results also indicate that flow-normalized uf.THg concentrations and loads above and below the reservoir are trending down.

Nevada↗

Terrestrial mammal diversity at Hansen Dam (Los Angeles, California, USA): Flood control area acts as habitat in a human-dominated landscape

Urban expansion is a prominent threat to biodiversity, particularly for terrestrial mammals, which are significantly impacted by disruptions in habitat connectivity and loss. It can also lead to increased human‑wildlife conflicts that contribute to species decline. Urban public works projects, such as flood control areas, may coincidentally preserve significant habitat, but their potential for conservation remains understudied. Hansen Dam, located in the city of Los Angeles, California, USA, is one of these flood control areas, hosting some of the last remaining riparian habitat in the greater Los Angeles area. We deployed motion‑triggered camera traps at 36 stratified random locations and completed small mammal trapping at 20 sites at Hansen Dam. We detected a total of 15 species, not including domesticated animals, but there is potential that additional species inhabit the area. All species detected were common and expected but demonstrate that the Hansen Dam flood control basin has a terrestrial mammal community similar to that reported for other urban habitats. These results suggest incidental habitat conservation could play a significant role in future conservation planning efforts.

California↗

Sources of nonresponse to the Federal Waterfowl Hunter Questionnaire Survey

Response rates to the Federal Waterfowl Hunter Questionnaire Survey (WHQS) have declined since the 1950's, suggesting that harvest estimates may be biased. Consequently, we investigated reasons for WHQS nonresponse using surveys of waterfowl hunters in Arkansas, California, Louisiana, Minnesota, New Jersey, and Texas. Sampling frames were constructed using lists of buyers of state hunting licenses or state duck stamps. We mailed questionnaires to 16,452 randomly selected hunters, with 2 follow-up mailings at 3-week intervals. Questionnaires were completed by 8,812 respondents, and a further 587 interviews were conducted by telephone. Post offices accounted for between 53.7% (Minn.) and 92.8% (N.J.) of federal waterfowl duck stamp sales, and stores accounted for most other sales. Of hunters who bought a federal waterfowl stamp from sample post offices, between 16.7% (Minn.) and 40.0% (Ark.) reported receiving a WHQS contact card. Of those receiving contact cards, between 30.0% (N.J.) and 64.3% (La. and Tex.) reported returning them. Because survey coverage of the target population is poor, we recommend that a new sampling frame be developed for the WHQS.

Arkansas, California, Louisiana, Minnesota, New Je↗

Distribution and abundance of Least Bell’s Vireos ( Vireo bellii pusillus ), Southwestern Willow Flycatchers ( Empidonax traillii extimus ), and Coastal California Gnatcatchers ( Polioptila californica californica ) at the Carbon Canyon Dam, Orange County, California—2025 data summary

Executive Summary We surveyed for Least Bell’s Vireos ( Vireo bellii pusillus ; vireo), Southwestern Willow Flycatchers ( Empidonax traillii extimus ; flycatcher), and Coastal California Gnatcatchers ( Polioptila californica californica ; gnatcatcher) at the Carbon Canyon Dam study area near Brea, California, in 2025. Four gnatcatcher and vireo surveys were completed between April 22 and June 25, 2025, and three flycatcher surveys were completed between May 15 and June 25, 2025. We detected 14 territorial male vireos, 12 of which were paired. We also detected a transient vireo. Juvenile vireos were observed in two territories during surveys. Of the five vireo nests incidentally located during surveys, three were parasitized by Brown-headed Cowbirds ( Molothrus ater ). Vireos were reported in four habitat types: (1) mixed willow riparian, (2) riparian scrub, (3) upland, and (4) non-native vegetation. The dominant tree species in vireo territories was Goodding’s black willow ( Salix gooddingii ). Most vireo territories (12) were in habitat with greater than 50-percent native vegetation. The most common exotic species in vireo territories was poison hemlock ( Conium maculatum ). No flycatchers or gnatcatchers were observed during surveys.

California↗

Brackish groundwater and its potential as a resource in the southwestern United States

Secure, reliable, and sustainable water resources are fundamental to food production, energy independence, and the health of humans and ecosystems. But the large-scale development of fresh groundwater resources has stressed aquifers in some areas, causing declines in the amount of groundwater in storage and decreases in discharge to surface-water bodies like rivers and springs (Reilly and others, 2008). In some parts of the southwestern United States, the water supply is not adequate to meet demand without substantial effects on groundwater storage or surface discharge, and severe drought intensifies the stresses affecting water resources. In support of the national census of water resources, the U.S. Geological Survey (USGS) completed the national brackish groundwater assessment to provide information about brackish groundwater as a potential resource to augment or replace freshwater supplies (Stanton and others, 2017). The objectives of the brackish groundwater assessment were to consolidate available data into a comprehensive database of brackish groundwater resources in the United States and to produce a summary report about the distribution, physical and chemical characteristics, and use of brackish groundwater. This fact sheet summarizes the occurrence of brackish groundwater and factors affecting its usability in the southwestern United States (specifically the Southwest Basins region) reported for the national study. The map below (fig. 1) summarizes the brackish zones for the five largest principal aquifers within the southwestern United States, along with groundwater resources in the remaining part of the region (Reilly and others, 2008).

Fact Sheet↗

Trends in surface-water quality at selected National Stream Quality Accounting Network (NASQAN) stations, in Michigan

To demonstrate the value of long-term, water-quality monitoring, the Michigan Department of Environmental Quality (MDEQ), in cooperation with the U.S. Geological Survey (USGS), initiated a study to evaluate potential trends in water-quality constituents for selected National Stream Quality Accounting Network (NASQAN) stations in Michigan. The goal of this study is to assist the MDEQ in evaluating the effectiveness of water-pollution control efforts and the identification of water-quality concerns. The study included a total of nine NASQAN stations in Michigan. Approximately 28 constituents were analyzed for trend tests. Station selection was based on data availability, land-use characteristics, and station priority for the MDEQ Water Chemistry Monitoring Project. Trend analyses were completed using the uncensored Seasonal Kendall Test in the computer program Estimate Trend (ESTREND), a software program for the detection of trends in water-quality data. The parameters chosen for the trend test had (1) at least a 5-year period of record (2) about 5 percent of the observations censored at a single reporting limit, and (3) 40 percent of the values within the beginning one-fifth and ending one-fifth of the selected period. In this study, a negative trend indicates a decrease in concentration of a particular constituent, which generally means an improvement in water quality; whereas a positive trend means an increase in concentration and possible degradation of water quality. The results of the study show an overall improvement in water quality at the Clinton River at Mount Clemens, Manistee River at Manistee, and Pigeon River near Caseville. The detected trend for these stations show decreases in concentrations of various constituents such as nitrogen compounds, conductance, sulfate, fecal coliform bacteria, and fecal streptococci bacteria. The negative trend may indicate an overall improvement in agricultural practices, municipal and industrial wastewater-treatment processes, and effective regulations. Phosphorus data for most of the study stations could not be analyzed because of the data limitations for trend tests. The only station with a significant negative trend in total phosphorus concentration is the Clinton River at Mount Clemens. However, scatter-plot analyses of phosphorus data indicate decreasing concentrations with time for most of the study stations. Positive trends in concentration of nitrogen compounds were detected at the Kalamazoo River near Saugatuck and Muskegon River near Bridgeton. Positive trends in both fecal coliform and total fecal coliform were detected at the Tahquamenon River near Paradise. Various different point and nonpoint sources could produce such positive trends, but most commonly the increase in concentrations of nitrogen compounds and fecal coliform bacteria are associated with agricultural practices and sewage-plant discharges. The constituent with the most numerous and geographically widespread significant trend is pH. The pH levels increased at six out of nine stations on all the major rivers in Michigan, with no negative trend at any station. The cause of pH increase is difficult to determine, as it could be related to a combination of anthropogenic activities and natural processes occurring simultaneously in the environment. Trends in concentration of major ions, such as calcium, sodium, magnesium, sulfate, fluoride, chloride, and potassium, were detected at eight out of nine stations. A negative trend was detected only in sulfate and fluoride concentrations; a positive trend was detected only in calcium concentration. The major ions with the most widespread significant trends are sodium and chloride; three positive and two negative trends were detected for sodium, and three negative and two positive trends were detected for chloride. The negative trends in chloride concentrations outnumbered the positive trends. This result indicates a slight improvement in surface-water quality because chloride as a point source in natural water comes from deicing salt, sewage effluents, industrial wastes, and oil fields. For other major ions, such as magnesium and potassium, both positive and negative trends were detected. These changes in trends indicate changes in surface-water quality caused by a variety of point and non-point sources throughout Michigan, as well as natural changes in the environment.

Michigan↗