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The geochemistry of pesticides
The mid-1970s marked a major turning point in human history, for it was at that moment that the ability of the Earth’s ecosystems to absorb most of the biological impacts of human activities appears to have been exceeded by the magnitude of those impacts. This conclusion is based partly upon estimates of the rate of carbon dioxide emission during the combustion of fossil fuels, relative to the rate of its uptake by terrestrial ecosystems ( Loh, 2002 ). A very different threshold, however, had already been crossed several decades earlier with the birth of the modern chemical industry, which produced novel substances for which no such natural assimilative capacity existed. Among these new chemical compounds, none has posed a greater challenge to the planet’s ecosystems than synthetic pesticides, compounds that have been intentionally released into the hydrologic system in vast quantities—several hundred million pounds of active ingredient (a.i.) per year in the United States alone ( Donaldson et al. , 2002 )—for many decades. To gauge the extent to which we are currently able to assess the environmental implications of this new development in the Earth’s history, this chapter presents an overview of current understanding regarding the sources, transport, fate, and biological effects of pesticides, their transformation products, and selected adjuvants in the hydrologic system. (Adjuvants are the so-called inert ingredients included in commercial pesticide formulations to enhance the effectiveness of the active ingredients.)
Extinctions of marine mammals
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Gas hydrates in the ocean environment
A GAS HYDRATE, also known as a gas clathrate, is a gas-bearing, icelike material. It occurs in abundance in marine sediments and stores immense amounts of methane, with major implications for future energy resources and global climate change. Furthermore, gas hydrate controls some of the physical properties of sedimentary deposits and thereby influences seafloor stability.
Pliocene environments
The Pliocene spans the interval of Earth history from ca. 5.3 to 1.8 million years ago (Ma). Although details are still debated there is much evidence from continental and oceanic locations indicating that conditions from 5.3 to about 3.0 Ma were often warmer than in modern times in mid- and high latitudes and that climate variability was subdued compared to the Pleistocene. Millennial-scale early Pliocene climate records are dominated by 19–21 thousand years ago (ka) oscillations. Starting at about 3.0 Ma, a long-term trend toward climate cooling and the ice ages of the Pleistocene accelerated. Significant build-up of Northern Hemisphere ice sheets began around 2.9 Ma and climate variability as measured by the oxygen isotope record in deep-sea carbonate microfossils increased. Distinct glacial–interglacial cycles developed in the late Pliocene between 2.9 and 2.7 Ma.
Dune fields: mid-latitudes
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Loess deposits, origins and properties
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Loess records: North America
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Paleosols and wind-blown sediments: overview
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Effects of external applications of fuel oil on hatchability of mallard eggs
An experiment was performed to determine the toxicity of oil to incubating eggs. Number 2 fuel oil, a mixture of 9 paraffin compounds, and propylene glycol were applied to the surface of artificially incubated mallard ( Anas platyrhynchos ) eggs. Seven groups of 50 eggs each were treated with 1, 5, 10, 20, and 50 μl of fuel oil, 50 μ1 of the paraffin mixture, and 50 μl of propylene glycol. Fifty untreated eggs served as a control. Microliter syringes were used to apply the liquid around the air cell end of the egg on the 8th day of incubation. Embryonic mortality was significantly greater (P ≤ 0.01) in all oil treated groups and the paraffin mixture group than in the control group. Most of the embryonic mortality for the oiled eggs occurred within 72 hours of treatment. Hatching and post-hatching (4 weeks) weights of the ducklings in all treatment groups were not significantly different (P > 0.01) from the control. Thus, the transfer of even small quantities of oil to the egg surface is sufficient to reduce hatchability.
Effects of external applications of No. 2 fuel oil on common eider eggs
Because eggs of marine birds may be exposed to oil adhering to the feathers of adult birds, a study was undertaken to determine the effects of oil contamination. Two hundred common eider eggs were divided into four experimental sets of 50 each. Two sets were treated with No. 2 fuel oil in amounts of 5 microliters to 20 microliters; a third with 20 microliters of propylene glycol, a neutral blocking agent. The fourth set served as a control. Hatching success was 96 percent for the eggs treated with 20 microliters propylene glycol, 96 percent for the controls and 92 percent for the eggs treated with 5 microliters oil hatched. Only 69 percent of the eggs treated with 20 microliters of oil survived - a significant reduction in hatchability (P 0.05). Mean Hatching weights for all sets were statistically equal. Thus, oil pollution may significantly increase embryonic mortality in marine birds.
Program to prepare standard figures for grade-tonnage models on a Macintosh
Grade-tonnage models are frequency distributions of deposit tonnage and grades of mineral deposits of a specific type. The program described here allows users to prepare standard figures of grade and tonnage distributions and display the deposit name associated with any of the data points. Titles and scales appropriate for most deposit types are plotted automatically for tonnage, Cu, Ni, Sn, Nb, W, Au, Hg, Mo, Zn, Pb, Ag, Co, Pt, Pd, Sb, Fe, Cr, Mn, and Ba.