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At least 1,711 records · Page 95Linked to original sources

Simulation of water-management scenarios for the Mississippi Delta

To compare the effectiveness of proposed alternative water-supply scenarios on future water availability in the Mississippi Delta, the U.S. Geological Survey and the Mississippi Department of Environmental Quality are collaborating on the update and enhancement of an existing regional groundwater-flow model of the area. Through this collaboration, the model has been updated to include boundary conditions through March 2014 with the most recent water-use data, precipitation and recharge data, and streamflow and water-level observation data. The updated model has been used to evaluate selected alternative water-supply scenarios to determine relative effects on the Mississippi River Valley alluvial aquifer. Alternative water-supply options evaluated in this report include: (1) irrigation efficiency, (2) on-farm storage and tailwater recovery, (3) instream weirs to increase surface-water availability, (4) intrabasin transfer of surface water, and (5) groundwater transfer and injection. A relative comparison approach was used to calculate the simulated water-level response caused by each scenario. Water-level response is the difference between water levels simulated by the alternative water-supply scenario and those simulated by a base or “no action” scenario. Water-level response in the alluvial aquifer varied for each scenario based on the location, magnitude, and (or) adoption rates of the simulated alternative water-supply option. The groundwater transfer and injection scenario showed the largest water-level response.

Arkansas, Louisiana, Mississippi, Missouri↗

Reconnaissance for radioactive deposits in the Fairbanks and Livengood Quadrangles, east-central Alaska, 1949

Several mines and prospects in the Fairbanks and Livengood quadrangles, east-central Alaska, were examined for the possible presence of radioactive materials in the summer of 1949. Also tested were pre-Cambrian and Paleozoic metamorphic and sedimentary rocks crossed by the Elliott Highway, which extends from Fox, near Fairbanks, northward about 70 miles to the town of Livengood. None of the lodes tested exhibited radioactivity in excess of 0.003 percent equivalent uranium, although nuggets consisting chiefly of native bismuth and containing as much as 0.1 percent equivalent uranium had been found previously in a placer on Fish Creek several miles below the reported bismuth-bearing lode on Melba Creek. The greatest radioactivity found in the rocks along the Elliott Highway was in an iron-stained schist of pre-Cambrian age and in carbonaceous shale of Middle Devonian or Carboniferous age. Respective samples of these rocks contain 0.003 and 0.004 percent equivalent uranium. A possible local bedrock source for a euxenite-polycrase mineral found in a placer concentrate containing about 0.04 percent equivalent uranium was sought in the watershed of Goodluck Creek, near Livengood. The bedrock source of this mineral could not be located; it is believed that the source could be outside of the Goodluck watershed, as drainage changes in the area during Quaternary time might well have introduced gravels from nearby areas.

Alaska↗

Computation of rapidly varied unsteady, free-surface flow

Many unsteady flows in hydraulics occur with relatively large gradients in free surface profiles. The assumption of hydrostatic pressure distribution with depth is no longer valid. These are rapidly-varied unsteady flows (RVF) of classical hydraulics and also encompass short wave propagation of coastal hydraulics. The purpose of this report is to present an introductory review of the Boussinnesq-type differential equations that describe these flows and to discuss methods for their numerical integration. On variable slopes and for large scale (finite-amplitude) disturbances, three independent derivational methods all gave differences in the motion equation for higher order terms. The importance of these higher-order terms for riverine applications must be determined by numerical experiments. Care must be taken in selection of the appropriate finite-difference scheme to minimize truncation error effects and the possibility of diverging (double mode) numerical solutions. It is recommended that practical hydraulics cases be established and tested numerically to demonstrate the order of differences in solution with those obtained from the long wave equations of St. Venant. (USGS)

Water-Resources Investigations Report↗

Water resources of Soledad, Poway, and Moosa basins, San Diego County, California

Reclaimed water is being considered as as supplemental water supply in the Soledad, Poway, and Moosa basins, San Diego County. This report describes the geology, soils, hydrology, and cultural factors in each of the basins as they relate to use of reclaimed water. Imported water is currently the major water-supply source in the basins. Groundwater supplies are used to a limited extent for both agricultural and domestic needs. Surface water flows are intermittent and, therefore, have not been developed for use in the basins. All three of the basins have the potential for use of reclaimed water, but only the Moosa basin is currently implementing a plan for such use. Concentrations of dissolved solids, chloride, and sulfate in both ground and surface water commonly exceed local basin objectives. As of 1985, plans for use of reclaimed water are oriented toward improving the quality of the groundwater.

California↗

Description and effects of 1988 drought on ground-water levels, streamflow, and reservoir levels in Indiana

Documentation of the 1988 drought in Indiana was undertaken to aid water-management agencies and planners concerned with periods of below-normal precipitation and their effect on commercial, agricultural, and residential water use. Precipitation, temperature, Palmer Drought Severity Indices, and ground- and surface-water levels from water years 1988 and 1989 were compared to the historical record to evaluate severity, extent, and duration of the 1988 drought in Indiana. Three types of drought-climatological, hydrologic, and agricultural--occurred in most of Indiana during water years 1988 and 1989. The drought began toward the end of calendar year 1987 as annual precipitation decreased to 4.6 inches below the long term mean. By the end of September 1988, statewide precipitation deficits had increased to almost 8 inches below normal. High temperatures during the summer months increased the stress on crops, livestock, and people. Northwest Indiana experienced the second warmest June-August on record. Palmer Drought Severity Indices indicated that a moderate-to-severe drought had occurred in Indiana during most of 1988. Ground-water levels were affected substantially in many areas of the State. Record low-water levels were observed at 12 of the 20 monitoring wells included in this report. A go-day ground-water emergency was declared in parts of northwestern Indiana. Streamflow throughout the State was affected to varying degrees by the drought. Annual mean discharge in some rivers was only slightly less than the mean annual discharge, while others flowed at less than half that value. The effects of low streamflows were felt by many as electric power plants reduced or ceased production and public-water utilities requested conservation measures by their customers. Major reservoirs in the State approached or reached record low levels, causing water supplies as well as recreational activities to be diminished. Most major crops produced in Indiana were affected by the dry conditions. Average yields in 1988 ranged from 50 to 86 percent of 1987 yields.

Indiana↗

Fishes of the White River basin, Indiana

Since 1875, researchers have reported 158 species of fish belonging to 25 families in the White River Basin. Of these species, 6 have not been reported since 1900 and 10 have not been reported since 1943. Since the 1820's, fish communities in the White River Basin have been affected by the alteration of stream habitat, overfishing, the introduction of non-native species, agriculture, and urbanization. Erosion resulting from conversion of forest land to cropland in the 1800's led to siltation of streambeds and resulted in the loss of some silt-sensitive species. In the early 1900's, the water quality of the White River was seriously degraded for 100 miles by untreated sewage from the City of Indianapolis. During the last 25 years, water quality in the basin has improved because of efforts to control water pollution. Fish communities in the basin have responded favorably to the improved water quality.

Indiana↗

A demonstration of the instream flow incremental methodology, Shenandoah River, Virginia

Current and projected demands on the water resources of the Shenandoah River have increased concerns for the potential effect of these demands on the natural integrity of the Shenandoah River system. The Instream Flow Incremental Method (IFIM) process attempts to integrate concepts of water-supply planning, analytical hydraulic engineering models, and empirically derived habitat versus flow functions to address water-use and instream-flow issues and questions concerning life-stage specific effects on selected species and the general well being of aquatic biological populations. The demonstration project also sets the stage for the identification and compilation of the major instream-flow issues in the Shenandoah River Basin, development of the required multidisciplinary technical team to conduct more detailed studies, and development of basin specific habitat and flow requirements for fish species, species assemblages, and various water uses in the Shenandoah River Basin. This report presents the results of an IFIM demonstration project, conducted on the main stem Shenandoah River in Virginia, during 1996 and 1997, using the Physical Habitat Simulation System (PHABSIM) model. Output from PHABSIM is used to address the general flow requirements for water supply and recreation and habitat for selected life stages of several fish species. The model output is only a small part of the information necessary for effective decision making and management of river resources. The information by itself is usually insufficient for formulation of recommendations regarding instream-flow requirements. Additional information, for example, can be obtained by analysis of habitat time-series data, habitat duration data, and habitat bottlenecks. Alternative-flow analysis and habitat-duration curves are presented.

Virginia↗

Water-use trends in the desert southwest: 1950-2000

The population of the Desert Southwest is among the fastest growing in the country. In this area, ground-water supplies have been developed, surface-water resources have been fully appropriated, and conservation and conjunctive water-use measures are being used to meet water-resource needs. Complex networks of water-distribution systems have been developed to deliver surface-water supplies, and interstate agreements, such as the Colorado River Compact of 1922, help manage the distribution of water among many States in the Western United States, including Arizona, California, Nevada, New Mexico, and Utah. The Colorado River, which lies on the borders of Arizona, California, and Nevada, plays an important role in supplying water to the Southwest. Water from the Colorado River is used to irrigate extensive farmland in the southern California deserts and is delivered to southern and central Arizona through the Central Arizona Project canal for domestic and agricultural uses. It is also the source of much of the water used for domestic purposes in southern Nevada. Estimated water-withdrawal and related data were compiled from various sources to identify trends in Arizona, California, Nevada, New Mexico, and Utah. More water is used for agriculture than domestic and industrial use in these five States. From 1950 to 2000, however, the percentage increase in withdrawal for domestic water use exceeded that for agricultural use. The estimated amount of water withdrawn for domestic, agricultural, and industrial purposes in Arizona, California, Nevada, New Mexico, and Utah increased 58 percent, from 39.6 to 62.8 million acre-feet, from 1950 to 2000. During this period withdrawals for domestic water use, which included self-supplied domestic and public supply (all deliveries to residential, commercial, and some industrial users), increased 410 percent from 2.0 million to 10.2 million acre-feet and the population in these five Southwestern States increased 250 percent. From 1965 to 2000, water withdrawals for agriculture, which were primarily for irrigation of crops and livestock uses, increased 14 percent in the five States, from 44.0 to 50.2 million acre-feet, while irrigated acreage increased 12 percent from 12.6 to 14.1 million acres. Water-use trends in the Southwest are dominated by water use in California where crop acreage is more than twice as large as the combined crop acreages in Arizona, Nevada, New Mexico, and Utah, and the population in 2000 was more than three times larger than the combined population of these States. Withdrawals for agriculture in California accounted for 62 percent of the water withdrawals for agriculture in the five States in 1950 and 68 percent in 2000. Water withdrawals for domestic-water use in California declined from 82 percent of the total domestic-water withdrawals in all five States in 1950 to 70 percent in 2000, indicating that the need for domestic withdrawals increased more in Arizona, Nevada, New Mexico, and Utah combined than in California. The population of California is larger than the combined population of Arizona, New Mexico, Nevada, and Utah, but the combined population of these smaller States grew faster than the population of California. From 1950 to 2000 the California population increased 220 percent, but the combined population of the four other States increased 390 percent. From 1960 to 2000, public supply per-capita use increased in Arizona, New Mexico, and California, and decreased in Nevada and Utah. Crop-application rates (water withdrawal for irrigation of crops divided by the irrigated crop acreage) from 1965 to 2000 ranged from 2.32 acre-feet per acre in Utah in 1975 to 6.21 acre-feet per acre in Arizona in 2000. More water is used per acre of irrigated land in Arizona than in the other four States. This could be due to several reasons, including differences in climate, conveyance losses, length of growing season, and type of crops grown. Trends in water withdrawals for industrial use are difficult to identify because of differences in data reporting from year to year. From 1950 to 2000, withdrawal for industrial use in the five States was generally less than 6 percent of the total withdrawal. Withdrawal for industrial use was less than 4 percent of the total withdrawal in Arizona, except in 1990; industrial withdrawal was less than 6 percent in California and less than 7 percent in Nevada, New Mexico, and Utah, except in 1980 when in Utah it was almost 12 percent of the total withdrawal. From 1950 to 2000, ground-water withdrawals increased 324 percent in Nevada, 147 percent in New Mexico, 208 percent in Utah, and 52 percent in California. Ground-water withdrawal decreased 15 percent in Arizona. For all five States, ground-water withdrawals increased 62 percent.

Scientific Investigations Report↗

Conceptual model to assess water use associated with the life cycle of unconventional oil and gas development

As the demand for energy increases in the United States, so does the demand for water used to produce many forms of that energy. Technological advances, limited access to conventional oil and gas accumulations, and the rise of oil and gas prices resulted in increased development of unconventional oil and gas (UOG) accumulations. Unconventional oil and gas is developed using a method that combines directional drilling and hydraulic fracturing techniques, allowing for greater oil and gas production from previously unrecoverable reservoirs. Quantification of the water resources required for UOG development and production is difficult because of disparate data sources, variable reporting requirements across boundaries (local, State, and national), and incomplete or proprietary datasets. A topical study was started in 2015 under the U.S. Geological Survey’s Water Availability and Use Science Program, as part of the directive in the Secure Water Act for the U.S. Geological Survey to conduct a National Water Census, to better understand the relation between production of UOG resources for energy and the amount of water needed to produce and sustain this type of energy development in the United States. The Water Availability and Use Science Program goal for this topical study is to develop and apply a statistical model to better estimate the water use associated with UOG development, regardless of the location and target geologic formation. As a first step, a conceptual model has been developed to characterize the life cycle of water use in areas of UOG development. Categories of water use and the way water-use data are collected might change over time; therefore, a generic approach was used in developing the conceptual model to allow for greater flexibility in adapting to future changes or newly available data. UOG development can be summarized into four stages: predrilling construction, drilling, hydraulic fracturing, and ongoing production. The water used in UOG production can be categorized further as direct, indirect, or ancillary water use. Direct water use is defined as the water used for drilling and hydraulic fracturing a well and for maintaining the well during ongoing production. Indirect water use is defined as the water used at or near a well pad. The water used for dust abatement also is considered an indirect use but may be applied away from the well pad. Ancillary water use is defined as the additional local or regional water use resulting from a change (for example, population) directly related to UOG development throughout the life cycle that is not used directly in the well or indirectly for any other purpose at the well pad. The conceptual model presented in this report consists of five elements: (1) input data, (2) processes, (3) decisions, (4) output data, and (5) outcomes. The input data requirements for estimating water use associated with UOG development are somewhat onerous, and obtaining suitable datasets can be challenging because local, State, and Federal agencies do not collect data similarly. The quality of a water-use assessment that uses the conceptual model presented in this report is dependent on the quality and quantity of data that are available for a UOG play. The conceptual model can be used for an assessment with sparse data; however, having sparse data likely will result in greater uncertainty in the water-use estimates. The conceptual model presented in this report is designed to be robust to characterize and simulate the data processing to estimate water use associated with UOG development. Although the results of an analysis that includes missing data have greater uncertainty, the analysis still can be insightful because it can establish a baseline estimate of UOG water use that may be refined further as more data become available. Analysis of models that include missing data also could aid in identifying the data most needed for future water-use estimates. Characterizing individual model limitations is important because the conceptual model can be used in future water-use studies to facilitate data compiling, data processing, estimating, and assessing UOG activities regardless of location.

Scientific Investigations Report↗

Automated construction of Streamflow-Routing networks for MODFLOW—Application in the Mississippi Embayment region

In humid regions with dense stream networks, surface water exerts a fundamental control on the water levels and flow directions of shallow groundwater. Understanding interactions between groundwater and surface water is critical for managing groundwater resources and groundwater-dependent ecosystems. Representing streams in groundwater models has historically been arduous and error prone. In recent years, however, all the information needed to numerically describe stream boundary conditions for a model area has become readily available online, as have robust open-source software tools for translating that information to a model grid. The SFRmaker Python package leverages geospatial capabilities in the scientific Python ecosystem to robustly automate the production of input to the Streamflow-Routing (SFR) Package of MODFLOW from the National Hydrography Dataset Plus or other hydrography data. This report documents an application of SFRmaker to automate production of SFR Package input for groundwater models within the Mississippi Embayment Regional Aquifer Study area. SFR Package input was developed in three steps: (1) preprocessing to develop a single set of grid-independent flowlines from National Hydrography Dataset Plus version 2 data; (2) setting up the SFR package from the preprocessed flowlines, and (3) correcting streambed top elevations after an initial model run. Separating the hydrography preprocessing from the construction of SFR Package input was advantageous in that it minimized the need to repeat computationally expensive geoprocessing (thereby speeding model construction) and also allowed for the curation of a single set of grid-independent SFR input data that can be used for any MODFLOW model within the study area.

Mississippi Embayment Region↗

Application of nonlinear least-squares regression to ground-water flow modeling, west-central Florida

A nonlinear least-squares regression technique for estimation of ground-water flow model parameters was applied to an existing model of the regional aquifer system underlying west-central Florida. The regression technique minimizes the differences between measured and simulated water levels. Regression statistics, including parameter sensitivities and correlations, were calculated for reported parameter values in the existing model. Optimal parameter values for selected hydrologic variables of interest are estimated by nonlinear regression. Optimal estimates of parameter values are about 140 times greater than and about 0.01 times less than reported values. Independently estimating all parameters by nonlinear regression was impossible, given the existing zonation structure and number of observations, because of parameter insensitivity and correlation. Although the model yields parameter values similar to those estimated by other methods and reproduces the measured water levels reasonably accurately, a simpler parameter structure should be considered. Some possible ways of improving model calibration are to: (1) modify the defined parameter-zonation structure by omitting and/or combining parameters to be estimated; (2) carefully eliminate observation data based on evidence that they are likely to be biased; (3) collect additional water-level data; (4) assign values to insensitive parameters, and (5) estimate the most sensitive parameters first, then, using the optimized values for these parameters, estimate the entire data set.

Florida↗

Organochlorine compounds and trace elements in fish tissue and streambed sediment in the Mobile River Basin, Alabama, Mississippi, and Georgia, 1998

During the summer of 1998, as part of the National Water-Quality Assessment Program, a survey was conducted to determine which organochlorine compounds and trace elements occur in fish tissues and streambed sediments in the Mobile River Basin, which includes parts of Alabama, Mississippi, Georgia, and Tennessee. The data collected were compared to guidelines related to wildlife, land use, and to 1991 and 1994 National Water-Quality Assessment Program Study-Unit data. Twenty-one sites were sampled in subbasins of the Mobile River Basin. The subbasins ranged in size from about 9 to 22,000 square miles and were dominated by either a single land use or a combination of land uses. The major land-use categories were urban, agriculture, and forest. Organochlorine compounds were widespread spatially in the Mobile River Basin. At least one organochlorine compound was reported at the majority of sampling sites (84 percent) and in a majority of whole-fish (80 percent) and streambed-sediment (52 percent) samples. Multiple organochlorine compounds were reported at 75 percent of the sites where fish tissues were collected and were reported at many of the streambed-sediment sampling sites (45 percent). The majority of concentrations reported, however, were less than 5 micrograms per kilogram in fish-tissue samples and less than 1 microgram per kilogram in streambed-sediment samples. The majority of trace elements analyzed in fish-liver tissue (86 percent) and streambed-sediment (98 percent) samples were reported during this study. Multiple trace elements were reported in all samples and at all sites. Based on comparisons of concentrations of organochlorine compounds and trace elements in fish-tissue and streambed-sediment samples in relation to National Academy of Science and National Academy of Engineering and Canadian tissue guidelines, probable-effects concentrations, and mean probable-effects concentration quotients for streambed sediment, the potential exists for adverse effects to wildlife at 15 (72 percent) of the sites sampled. The potential for adverse effects at these sites is because of the presence of residues or breakdown products related to polychlorinated biphenyls (PCB’s), chlordane, dichlorodiphenyltrichloroethane (DDT), chromium, lead, and zinc. The majority of compounds reported (65 percent) were chlordane, DDT, and PCB’s, or their breakdown products. Concentrations of chlordane and heptachlor epoxide in whole-fish tissue were positively correlated to the amount of urban land use in a basin. Total DDT concentrations in whole-fish tissues were positively correlated to agriculture. The relation of trace elements to land use is not as clear as the relation of organochlorine compounds to land use. This lack of clarity may be due to the possibility of geologic sources of trace elements in the Mobile River Basin and to the ubiquitous nature of many of these trace elements. However, there may be a correlation between the amount of urban land use and concentrations of antimony, cadmium, lead, and zinc in streambed-sediment samples from the Mobile River Basin. Fewer organochlorine compounds and trace elements were reported in samples from the Mobile River Basin than in samples collected during the 1991 and 1994 National Water-Quality Assessment Program studies. Of the organochlorine compounds analyzed nationally, 57 percent were reported in whole-fish tissue samples collected locally and 41 percent were reported in streambed-sediment samples collected locally, whereas 96 percent and 86 percent, respectively, were reported nationally. Of trace elements analyzed nationally, 86 percent were reported in fish-liver tissue locally and 95 percent were reported in streambed-sediment samples locally, whereas 95 percent and 98 percent, respectively, were reported nationally. In general, concentrations of organochlorine compounds and trace elements and the frequency with which they were reported in the Mobile River Basin are similar to or less than those reported by 1991 and 1994 Study Units; however, exceptions do exist to this generality. Exceptions are the higher reporting frequency of heptachlor epoxide, p,p' -DDT, and PCB’s in whole-fish samples, higher quartile concentrations of heptachlor epoxide and p,p' -DDT in whole-fish samples, the higher maximum concentration of heptachlor epoxide in whole-fish samples, and the higher maximum concentration and reporting frequency of trans -chlordane in streambed-sediment samples in the Mobile River Basin. In addition, aluminum, barium, chromium, cobalt, nickel, and strontium were reported more frequently in fish-liver samples locally than nationally, boron concentrations were consistently higher in fish-liver samples locally than nationally, and mercury, silver, and ytterbium were reported more frequently in streambed-sediment samples from the Mobile River Basin than nationally. The higher reporting frequencies and concentrations of heptachlor epoxide, p,p' -DDT, and trans-chlordane in samples from the Mobile River Basin are probably due to the greater use of these compounds locally than nationally. The reason for the higher reporting frequency of PCB’s is less clear, but may be due to the production of these compounds within the basin. The higher frequency with which some trace elements were reported in fish-liver tissue and streambed-sediment samples in the Mobile River Basin may be due to geology or anthropomorphic activities. Higher boron concentrations locally are probably due to anthropomorphic activities, because there are no major geological sources for boron in the Mobile River Basin. Potential sources locally for most of these trace elements include irrigation drain water (mercury), coal combustion (mercury and nickel), metallurgy (barium, boron, chromium, and nickel), soaps (boron), and the wood and pulp industry (barium and chromium). Other sources that could enrich samples from the Mobile River Basin are the Black Warrior coal fields (aluminum and mercury) in the northwestern quarter of the basin, which are known to have elevated levels of mercury, and barite deposits (barium) in east-central Alabama.

Alabama, Georgia, Mississippi, Tennessee↗

Flood characteristics of Alaskan streams

Peak discharge data for Alaskan streams are summarized and analyzed. Multiple-regression equations relating peak discharge magnitude and frequency to climatic and physical characteristics of 260 gaged basins were determined in order to estimate average recurrence interval of floods at ungaged sites. These equations are for 1.25-, 2-, 5-, 10-, 25-, and 50-year average recurrence intervals. In this report, Alaska was divided into two regions, one having a maritime climate with fall and winter rains and floods, the other having spring and summer floods of a variety or combinations of causes. Average standard errors of the six multiple-regression equations for these two regions were 48 and 74 percent, respectively. Maximum recorded floods at more than 400 sites throughout Alaska are tabulated. Maps showing lines of equal intensity of the principal climatic variables found to be significant (mean annual precipitation and mean minimum January temperature), and location of the 260 sites used in the multiple-regression analyses are included. Little flood data have been collected in western and arctic Alaska, and the predictive equations are therefore less reliable for those areas. (Woodard-USGS)

Alaska↗

Selected elements and organic chemicals in bed sediment and fish tissue of the Tualatin River basin, Oregon, 1992-96

A variety of elements and organic compounds have entered the environment as a result of human activities. Such substances find their way to aquatic sediments from direct discharges to waterways, atmospheric emissions, and runoff. Some of these chemicals are known to harm fish or wildlife, either by direct toxicity, by reducing viability, or by limiting reproductive success. In aquatic systems, sediments become the eventual sink for most of these chemicals. Analyzing the sediments provides a first step in a chemical inventory that can lead to an assessment of potential biological impacts (Kennicutt and others, 1994). Many elements (iron, aluminum, calcium, and others) enter the environment from the natural weathering of rock. Additional amounts of elements have been contributed by human activities such as mining, metals production and processing, fossil fuel combustion, municipal waste incineration, and transportationrelated sources. The environmental presence of some elements, such as lead and mercury, is almost entirely due to human activity. Lead is often associated with the use of leaded gasoline and from the manufacture and disposal of lead storage batteries. Mercury was used historically in a variety of industrial processes and as a pesticide. Nriagu and Pacyna (1998) concluded that human activity is the “most important element in the global biogeochemical cycling of the trace metals.” The number of organic compounds in existence and their total production has more than tripled in the last century. Many of these compounds enter the environment directly as pesticides; others are inadvertently discharged. Some organic compounds have natural sources. Three general classes of organic compounds will be discussed: organochlorine compounds, polyaromatic hydrocarbons, and phthalates. Almost all organochlorine compounds are manmade. Many are pesticides that were used widely in the 1950s–60s (DDT and chlordanes, for example). Use of most organochlorine pesticides was restricted or banned in the United States in the 1970s–80s. Polychlorinated biphenyls (PCBs) are also organochlorine compounds; they were used for a variety of applications, but most commonly as insulators in electrical transformers and other equipment. In general, organochlorine compounds degrade very slowly in the environment and therefore, are routinely found in environmental samples, despite the fact that they are no longer used in the United States. They are hydrophobic that is they do not dissolve readily in water and, in aquatic systems, are almost exclusively associated with sediments or tissue. Because these compounds cause a variety of adverse health effects in wildlife, the U.S. Environmental Protection Agency (USEPA) has listed many as priority pollutants. Organochlorine compounds also have been implicated as endocrine disrupters— chemicals that can interfere with the normal function of hormones. Polyaromatic hydrocarbons (PAHs) are found in sediments throughout the world (Hites and others, 1980). Their presence is thought to be primarily anthropogenic. PAHs occur naturally in petroleum products and also are produced during combustion. They enter the environment from fuel spills, tar coatings, coal and other fossil fuel usage, road dust, and from the atmospheric deposition of combustion products (Prahl and others, 1984; Wakeham and others, 1980). Urban areas often have high concentrations of PAHs because of transportation-related sources (vehicle exhaust, paving materials, and releases of fuel or oil). Natural sources, such as forest fires, may contribute small amounts of PAHs. Several PAHs are known carcinogens (benzo[a]pyrene, for example); 16 are listed as USEPA priority pollutants. Phthalate compounds are often associated with urban areas. They are used in a wide variety of industrial applications and in inks, adhesives, resins, and as plasticizers (chemicals that increase the flexibility of plastics). In aquatic systems, phthalates are found mostly in sediments where they degrade very slowly. Phthalates are thought to be endocrine disrupters; Jobling and others (1995) found that some phthalates were weakly estrogenic. USEPA considers some phthalates to be possible carcinogens. This report describes the results of a reconnaissance survey of elements and organic compounds found in bed sediment and fish tissue in streams of the Tualatin River Basin. The basin is in northwestern Oregon to the west of the Portland metropolitan area (fig. 1). The Tualatin River flows for about 80 miles, draining an area of about 712 square miles, before it enters the Willamette River. Land use in the basin changes from mostly forested in the headwaters, to mixed forest and agriculture, to predominately urban. The basin supports a growing population of more than 350,000 people, most of whom live in lower parts of the basin. Water quality in the Tualatin River and its tributaries is expected to be affected by the increasing urbanization of the basin.

Oregon↗

Conceptual hydrogeologic framework and groundwater budget near the southeastern part of Puget Sound, Washington

More than 1 million people live within the active model area (AMA) in the southeastern part of the lowlands surrounding Puget Sound, or Puget Lowland, Washington, and groundwater is the source for approximately one-half of their public, domestic, and irrigation water demands. The 887-square-mile AMA, located in King and Pierce Counties, represents the area of analysis for the conceptual hydrogeologic framework and numerical groundwater-flow models within the study area and includes the Puyallup River and Chambers-Clover Creek watersheds. To assess the potential hydrologic and anthropogenic impacts to groundwater and the connected surface-water resources, conceptual and numerical groundwater-flow models of groundwater flow were developed by the U.S. Geological Survey Washington Water Science Center in close cooperation with 18 water-resource agencies and stakeholders. This report presents information used to characterize the groundwater-flow system and the development of a numerical model in the AMA. Included are descriptions of the geology and conceptual hydrogeologic framework, groundwater levels and flow directions, groundwater recharge and discharge, numerical groundwater-flow model construction and results, and model limitations. The study area encompasses the western part of Pierce County and the southwestern part of King County, Washington. The study area extends south to the Nisqually River, southwest to Tanwax Creek, northeast to the Green River, and north through the valley near Auburn and adjacent uplands. It is bounded on the east by foothills of the Cascade Range, and on the northwest by Puget Sound.

Washington↗

The Tuscaloosa Aquifer system in Mississippi

A three-sheet map report describes the Tuscaloosa aquifer system in Mississippi. The Tuscaloosa aquifer system, of Cretaceous age , is in the interconnected irregular sand and gravel beds in the Coker and Gordo Formations. The aquifer contains freshwater in an area of about 9,000 sq mi in northeastern Mississippi. Water produced from the aquifer by about 90 water systems and numerous industries in 1975 averaged about 47 Mgal/d. Regional water level declines have averaged less than two feet per year and the aquifer has a large potential for future development. The aquifer is used in some areas where the dissolved-solids concentration is more than 500 mg/L and where wells exceed 2,000 ft in depth. The most common problems in water supplies are excessive chloride and iron. (Woodard-USGS)

Mississippi↗

Water-quality assessment of the Connecticut, Housatonic, and Thames River Basins study unit: Analysis of available data on nutrients, suspended sediments, and pesticides, 1972-92

This retrospective report examines available nutrient, suspended sediment, and pesticide data in surface and ground water in the Connecticut, Housatonic and Thames Rivers Study Unit of the National Water-Quality Assessment Program. The purpose of this study is to improve the understanding of natural and anthropogenic factors affecting water quality in the study unit. Waterquality data were acquired from various sources, primarily, the U.S. Geological Survey and the U.S. Environmental Protection Agency. The report examines data for water years 1972-92, focusing on 1980-92, although it also includes additional data from as early as 1905. The study unit lies within the New England Physiographic Province and altitudes range from sea level in coastal Connecticut to 6,288 feet above sea level at Mount Washington, New Hampshire. Two major aquifer types underlie the study unit unconsolidated glacial deposits and fractured bedrock. The climate generally is temperate and humid, with four distinct seasons. Average annual precipitation ranges from 34 to 65 inches. The study unit has a population of about 4.5 million, which is most highly concentrated in southwestern Connecticut and along the south-central region of the Connecticut River Valley. Surface-water-quality data were screened to provide information about sites with adequate numbers of analyses (50) over sufficiently long periods (1980-90) to enable valid statistical analyses. In order to compare effects of different types of land use on surface-water quality, examination of data required application of several statistical and graphical techniques, including mapping, histograms, boxplots, concentration-discharge plots, trend analysis, and load estimation. Spatial and temporal analysis of surface-water-quality data indicated that, with a single exception, only stations in the Connecticut water-quality network had sufficient data collected over adequately long time periods to use in detailed analyses. Ground-water nutrient and pesticide data were compiled from several Federal and State agencies, primarily the U.S. Geological Survey, U.S. Environmental Protection Agency, and Connecticut Department of Health Services. Nutrient data were available for several thousand wells; nitrite plus nitrate as nitrogen was the most commonly reported constituent. Most wells with nutrient data are in Massachusetts and Connecticut. Relative to nutrient data in ground and surface water, pesticide data are less common. Pesticide data were available for slightly more than 200 surface-water sites and less than 500 wells; about 95 percent of the wells are completed in stratified-drift or till aquifers. Data for 81 pesticide compounds were available in various data bases. 2,4-D and silvex were the most commonly detected herbicides in surface water and dieldrin and diazinon were the most commonly detected insecticides. Most surface-water pesticide samples and detections are from bed sediment, but much of the data are not recent. Ethylene dibromide (EDB), a soil fumigant used in tobacco farming was detected in 268 wells in a 50 square-mile area of north-central Connecticut; EDB contamination also was detected in wells in Massachusetts. Atrazine, an herbicide commonly used in corn farming, commonly was detected in wells installed in tilled agricultural fields. Corn herbicides were commonly detected in the northern part of the study unit, although the sampling has been less frequent than in the southern part of the study unit. Pesticides were seldom detected in public-supply wells in Connecticut. Urban sites with relatively high population densities and high concentrations of dischargers were characterized by having the highest nutrient concentrations and loads when adjusted for differences in drainage area or population. Particularly, the Pequabuck, Naugatuck, and Quinnipiac River Basins were characterized by high nutrient concentrations median total nitrogen concentrations ranged from 3.3 to 4.2 mg/L (milligrams per liter) and median total phosphorus concentrations ranged from 0.42 to 0.8 mg/L. In contrast, the predominantly forested and low density residential land-use sites, such as Saugatuck and Salmon River Basins, were characterized by low nutrient concentrations median total nitrogen ranged from 0.50 to 0.60 mg/L and median total phosphorus concentrations ranged from 0.01 to 0.02 mg/L. Estimated total nitrogen loadings in median discharge years ranged from 940 kilograms per square mile at the Salmon River near East Hampton, Conn., to 5,800 kilograms per square mile at the Naugatuck River at Beacon Falls, Conn. Water quality, in terms of nutrient concentrations and areally adjusted loadings, for sites with large drainage basins integrating a wide variety of land-use categories fell between the extremes of the urban and forested sites total nitrogen was 1,400 kilograms per square mile per year at the Connecticut River at Thompsonville, Conn. Nitrate concentrations in ground water occasionally exceeded the safe drinking-water standard of 10 mg/L as nitrogen. The greatest number of detections exceeding the standard, however, were not in public-water supplies but in shallow observation wells in agricultural settings (the most frequently sampled type of well). None of the public-supply wells in Massachusetts exceeded the standard. Although nitrate concentrations for Vermont and New Hampshire generally were low, few data were available and those were seldom reported on the basis of drainage basin, making analysis difficult. Trend analysis indicated that flow-adjusted concentrations of total and dissolved phosphorus generally decreased during the period of analysis, however, total nitrogen did not change substantially. Decreases in ammonia concentrations with time were usually accompanied by increases in nitrate, suggesting improvements in sewage treatment. The lack of adequate data from more or less exclusively agricultural areas points to the need for further study of the effects of fanning on surface-water quality in the study unit. Furthermore, additional information is needed on the rates, transformations, and movements of nutrients and other materials through and between the aquatic and terrestrial components of the study unit.

Connecticut, Massachusetts, New Hampshire, Quebec,↗

Hydrogeologic and geochemical characterization and evaluation of two arroyos for managed aquifer recharge by surface infiltration in the Pojoaque River Basin, Santa Fe County, New Mexico, 2014–15

In order to provide long-term storage of diverted surface water from the Rio Grande as part of the Aamodt water rights settlement, managed aquifer recharge by surface infiltration in Pojoaque River Basin arroyos was proposed as an option. The initial hydrogeologic and geochemical characterization of two arroyos located within the Pojoaque River Basin was performed in 2014 and 2015 in cooperation with the Bureau of Reclamation to evaluate the potential suitability of these two arroyos as sites for managed aquifer recharge through surface infiltration. The selected reaches were high-gradient (average 3.0–3.5 percent) braided channels filled with unconsolidated sand and gravel-sized deposits that were generally 30–50 feet thick. Saturation was not observed in the unconsolidated channel sands in four subsurface borings but was found at 7–60 feet below the contact between the unconsolidated channel sands and the bedrock. The poorly to well-cemented alluvial deposits that make up the bedrock underlying the unconsolidated channel material is the Tesuque Formation. The individual beds of the Tesuque Formation are reported to be highly heterogeneous and anisotropic, and the bedrock at the site was observed to have variable moisture and large changes in lithology. Surface electrical-resistivity geophysical survey methods showed a sharp contrast between the electrically resistive unconsolidated channel sands and the highly conductive bedrock; however, because of the high conductivity, the resistivity methods were not able to image the water table or preferential flow paths (if they existed) in the bedrock. Infiltration rates measured by double-ring and bulk infiltration tests on a variety of channel morphologies in the study reaches were extremely large (9.7–94.5 feet per day), indicating that the channels could potentially accommodate as much as 6.6 cubic feet per second of applied water without generating surface runoff out of the reach; however, the small volume available for storage in the unconsolidated channel sands (about 410 acre-feet in the east arroyo and about 190 acre-feet in the west arroyo) and the potential for the infiltrating water to preferentially flow over the bedrock contact and out of the reach present a challenge for storing water. Although a detailed assessment of the infiltration rate of the Tesuque Formation is beyond the scope of this investigation, one double-ring infiltrometer test was conducted on an outcrop, resulting in an estimated infiltration rate of about 4 feet per day. The shallow groundwater observed in this investigation was determined to be recharged locally on the basis of groundwater elevations and geochemical and isotopic signatures. The channel sands and shallow bedrock were observed to be weathered, indicating contact with oxic groundwater following deposition. This observation was supported by whole-rock elemental analysis and mineralogy of several core samples. The downward groundwater gradient between the shallow wells and those wells screened at greater depths suggests that the shallow groundwater is recharged by local precipitation and has the potential to migrate to the deeper aquifer units. The two age-dating tracers measured in this investigation, however, demonstrate that the shallow groundwater flow paths are very slow and that the deeper flow paths are likely part of a larger regional system. The composition of the shallow, native groundwater suggests that storing water diverted from the Rio Grande is not likely to leach constituents of concern that would cause the stored water to exceed health-based U.S. Environmental Protection Agency Maximum Contaminant Levels.

New Mexico↗