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USGS2001

Surface-water, water-quality, and ground-water assessment of the Municipio of Comerio, Puerto Rico, 1997-99

To meet the increasing need for a safe and adequate supply of water in the municipio of Comerio, an integrated surface-water, water-quality, and ground-water assessment of the area was conducted. The major results of this study and other important hydrologic and water-quality features were compiled in a Geographic Information System, and are presented in two 1:30,000-scale map plates to facilitate interpretation and use of the diverse water-resource data. Because the supply of safe drinking water was a critical issue during recent dry periods, the surface-water assessment portion of this study focused on analysis of low-flow characteristics in local streams and rivers. Low-flow characteristics were evaluated at one continuous-record gaging station based on graphical curve-fitting techniques and log-Pearson Type III frequency curves. Estimates of low-flow characteristics for 13 partial-record stations were generated using graphical-correlation techniques. Flow-duration characteristics for the continuous- and partial-record stations were estimated using the relation curves developed for the low-flow study. Stream low-flow statistics document the general hydrology under current land- and water-use conditions. A sanitary quality survey of streams utilized 24 sampling stations to evaluate about 84 miles of stream channels with drainage to or within the municipio of Comerio. River and stream samples for fecal coliform and fecal streptococcus analyses were collected on two occasions at base-flow conditions to evaluate the sanitary quality of streams. Bacteriological analyses indicate that about 27 miles of stream reaches within the municipio of Comerio may have fecal coliform bacteria concentrations above the water-quality goal established by the Puerto Rico Environmental Quality Board (Junta de Calidad Ambiental de Puerto Rico) for inland surface waters. Sources of fecal contamination may include illegal discharge of sewage to storm-water drains, malfunction of sanitary sewer ejectors, clogged and leaking sewage pipes, septic tank leakage, unfenced livestock, runoff from livestock pens, and seepage from pits containing animal wastes. Long-term fecal coliform data at two sampling stations on the Rio de la Plata indicate that since 1984, the geometric mean of five consecutive samples commonly has been at or below 2,000 colonies per 100 milliliters (established as the sanitary quality goal in Puerto Rico for Class SD type waters). At the sampling station upstream of Comerio, the geometric mean concentration has been near 500 colonies per 100 milliliters; downstream of the town of Comerio, the geometric mean concentration has been near 2,000 colonies per 100 milliliters concentration. The data at these stations also indicate that fecal coliform concentrations increase commonly above 2,000 colonies per 100 milliliters during storm-runoff events, ranging from 1,000 to 100,000 colonies per 100 milliliters at both stations. Geologic, topographic, soil, hydrogeologic, and streamflow data were used to divide the municipio of Comerio into five hydrogeologic terranes. The integrated database was then used to evaluate the ground-water development potential of each hydrogeologic terrane. Analysis suggests that areas with slopes greater than 15 degrees have relatively low ground-water development potential. Fractures may be important locally in enhancing the water-bearing properties in the hydrogeologic terranes containing igneous rocks. The integrated hydrogeologic approach used in this study can serve as an important tool for regulatory agencies of Puerto Rico and the municipio of Comerio to evaluate the ground-water resource development potential, examine ground- and surface-water interaction, and determine the effect of land-use practices on ground-water quantity and quality. Stream low-flow statistics document the general hydrology under current land and water uses. Low-flow characteristics may substantially change as a re

Water-Resources Investigations Report↗
USGS2001

Reconnaissance of Stream Geomorphology, Low Streamflow, and Stream Temperature in the Mountaintop Coal-Mining Region, Southern West Virginia, 1999-2000

The effects of mountaintop removal coal mining and the valley fills created by this mining method in southern West Virginia were investigated by comparing data collected at valley-fill, mined, and unmined sites. Bed material downstream of valley-fill sites had a greater number of particles less than 2 millimeters and a smaller median particle size than the mined and unmined sites. At the 84th percentile of sampled data, however, bed material at each site type had about the same size particles. Bankfull cross-sectional areas at a riffle section were approximately equal at valley-fill and unmined sites, but not enough time has passed and insufficient streamflows since the land was disturbed may have prevented the stream channel at valley-fill sites from reaching equilibrium. The 90-percent flow durations at valley-fill sites generally were 6-7 times greater than at unmined sites. Some valley-fill sites, however, exhibited streamflows similar to unmined sites, and some unmined sites exhibited streamflows similar to valley-fill sites. Daily streamflows from valley-fill sites generally are greater than daily streamflows from unmined sites during periods of low streamflow. Valley-fill sites have a greater percentage of base-flow and a lower percentage of flow from storm runoff than unmined sites. Water temperatures from a valley-fill site exhibited lower daily fluctuations and seasonal variations than water temperatures from an unmined site.

Water-Resources Investigations Report↗
USGS2001

Low-Flow Characteristics and Discharge Profiles for Selected Streams in the Cape Fear River Basin, North Carolina, Through 1998

An understanding of the magnitude and frequency of low-flow discharges is an important part of evaluating surface-water resources and planning for municipal and industrial economic expansion. Low-flow characteristics are summarized in this report for 67 continuous-record gaging stations and 121 partial-record measuring sites in the Cape Fear River Basin of North Carolina. Records of discharge collected through the 1998 water year were used in the analyses. Flow characteristics included in the summary are (1) average annual unit flow; (2) 7Q10 low-flow discharge, the minimum average discharge for a 7-consecutive-day period occurring, on average, once in 10 years; (3) 30Q2 low-flow discharge; (4) W7Q10 low-flow discharge, similar to 7Q10 discharge except that only flow during November through March is considered; and (5) 7Q2 low-flow discharge. Low-flow characteristics in the Cape Fear River Basin vary widely in response to changes in geology and soil types. The area of the basin with the lowest potentials for sustained base flows is underlain by the Triassic basin in parts of Durham, Wake, and Chatham Counties. Typically, these soils are derived from basalt and fine-grained sedimentary rocks that allow very little infiltration of water into the shallow aquifers for storage and later release to streams during periods of base flow. The area of the basin with the highest base flows is the Sand Hills region in parts of Moore, Harnett, Hoke, and Cumberland Counties. Streams in the Sand Hills have the highest unit low flows in the study area as well as in much of North Carolina. Well-drained sandy soils in combination with higher topographic relief relative to other areas in the Coastal Plain contribute to the occurrence of high potentials for sustained base flows. A number of sites in the upper part of the Cape Fear River Basin underlain by the Carolina Slate Belt and Triassic basin, as well many sites in lower areas of the Coastal Plain (particularly the Northeast Cape Fear River Basin), have zero or minimal (defined as less than 0.05 cubic foot per second) 7Q10 discharges. In this area, the poorly sustained base flows are reflective of either (1) thin soils that have very little storage of water to sustain streams during base-flow periods (Carolina Slate Belt), or (2) soils having very low infiltration rates (Triassic basin). As a result, there is insufficient water stored in the surficial aquifers for release to streams during extended dry periods. Within the part of the study area underlain by the Carolina Slate Belt, streams draining basins 5 square miles or less may have zero or minimal 7Q10 discharges. The part of the study area underlain by the Triassic basin has a higher drainage-area threshold at 35 square miles, below which streams will likely have zero or minimal 7Q10 discharges. Occurrences of zero or minimal 7Q10 discharges in the Coastal Plain were noted, though on a more widespread basis. In this area, low flows are more likely affected by the presence of poorly drained soils in combination with very low topographic relief relative to other areas in the Coastal Plain, particularly the Sand Hills. In eastern Harnett County and northeastern Cumberland County, basins with less than 3 square miles may be prone to having zero or minimal 7Q10 discharges. Soils in this area have been described as a mixture of sandy and clay soils. In the Northeast Cape Fear River Basin, particularly on the western side of the river, streams draining less than 8 square miles may have zero or minimal 7Q10 discharges. The poorly drained clay soils along with very little topographic relief results in the low potential for sustained base flows in this part of the study area. Drainage area and low-flow discharge profiles are presented for 13 streams in the Cape Fear River Basin; these profiles reflect a wide range in basin size, characteristics, and streamflow conditions. In addition to the Haw River and Cape Fear River main stem, pro

North Carolina↗
USGS2001

Isotopic and chemical composition of inorganic and organic water-quality samples from the Mississippi River Basin, 1997-98

Nitrate (NO 3 ) and other nutrients discharged by the Mississippi River combined with seasonal stratification of the water column are known to cause a zone of depleted dissolved oxygen (hypoxic zone) in the Gulf of Mexico each summer. About 120 water and suspended sediment samples collected in 1997 and 1998 from 24 locations in the Mississippi River Basin were analyzed for the isotope ratios δ 15 N and δ 18 O of dissolved NO 3 , and δ 15 N and δ 13 C of suspended particulate organic material (POM). Sampling stations include both large rivers (drainage areas more than 30,000 square kilometers) that integrate the effects of many land uses, and smaller streams (drainage areas less than 2,500 square kilometers) that have relatively uniform land use within their drainage areas. The data are used to determine sources and transformations of NO 3 in the Mississippi River. Results of this study demonstrate that much of the NO 3 in the Mississippi River originates in the agriculturally dominated basins of the upper midwestern United States and is transported without significant transformation or other loss to the Gulf of Mexico. Results from major tributaries that drain into the Mississippi River suggest that NO 3 is not significantly altered by denitrification in its journey, ultimately, to the Gulf of Mexico. The spatial variability of isotope ratios among the smaller streams appears to be related to the dominant nitrogen source in the basins. There are some distinct isotope differences among land-use types. For example, for both NO 3 and POM, the majority of δ 15 N isotope ratio values from basins dominated by urban and undeveloped land are less than +5 per mil, whereas the majority of values from basins dominated by row crops and row crops and/or livestock production are greater than +5 per mil. Also, the median δ 18 O of NO 3 isotope ratio value (+14.0 per mil) from undeveloped basins is more than 6 per mil higher than the median value (+7.3 per mil) from the row crop dominated basins and 5 per mil higher than the median value (+9.0 per mil) from the row crop and/or livestock production dominated basins. The median δ 18 O of NO 3 isotope ratio value (+21.5 per mil) from urban basins is 6.5 per mil higher than the median value (+14.0 per mil) from the undeveloped basins. The majority of NO 3 concentrations are greater than 3 milligrams per liter (mg/L) in basins dominated by row crops and row crops and/or livestock production, whereas all NO 3 concentrations are less than 2 mg/L in basins dominated by urban and undeveloped land.

Mississippi River basin↗
USGS2001

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory - Determination of moderate-use pesticides and selected degradates in water by C-18 solid-phase extraction and gas chromatography/mass spectrometry

A method for the isolation and analysis of 21 parent pesticides and 20 pesticide degradates in natural-water samples is described. Water samples are filtered to remove suspended particulate matter and then are pumped through disposable solid-phase-extraction columns that contain octadecyl-bonded porous silica to extract the analytes. The columns are dried by using nitrogen gas, and adsorbed analytes are eluted with ethyl acetate. Extracted analytes are determined by capillary-column gas chromatography/mass spectrometry with selected-ion monitoring of three characteristic ions. The upper concentration limit is 2 micrograms per liter (µg/L) for most analytes. Single-operator method detection limits in reagent-water samples range from 0.00 1 to 0.057 µg/L. Validation data also are presented for 14 parent pesticides and 20 degradates that were determined to have greater bias or variability, or shorter holding times than the other compounds. The estimated maximum holding time for analytes in pesticide-grade water before extraction was 4 days. The estimated maximum holding time for analytes after extraction on the dry solid-phase-extraction columns was 7 days. An optional on-site extraction procedure allows for samples to be collected and processed at remote sites where it is difficult to ship samples to the laboratory within the recommended pre-extraction holding time. The method complements existing U.S. Geological Survey Method O-1126-95 (NWQL Schedules 2001 and 2010) by using identical sample preparation and comparable instrument analytical conditions so that sample extracts can be analyzed by either method to expand the range of analytes determined from one water sample.

Water-Resources Investigations Report↗
USGS2000

Stream Discharge Measurements From Cableways

Cableways have been used for decades as a platform for making stream discharge measurements. Use of cableways eliminates the need to expose personnel to hazards associated with working from highway bridges. In addition, cableways allow sites to be selected that offer the best possible hydraulic characteristics for measuring stream discharge. This training presentation describes methods currently used by the U.S. Geological Survey to make stream discharge measurements from cableways.

Water-Resources Investigations Report↗
USGS2001

Effects of land use and travel time on the distribution of nitrate in the Kirkwood-Cohansey aquifer system in southern New Jersey

Residents of the southern New Jersey Coastal Plain are increasingly reliant on the unconfined Kirkwood-Cohansey aquifer system for public water supply as a result of increasing population and restrictions on withdrawals from the deeper, confined aquifers. Elevated nitrate concentrations above background levels have been found in wells in the surficial aquifer system in agricultural and urban parts of this area. A three-dimensional steady-state ground-water-flow model of a 400-square-mile study area near Glassboro, New Jersey, was used in conjunction with particle tracking to examine the effects of land use and travel time on the distribution of nitrate in ground and surface water in southern New Jersey. Contributing areas and ground-water ages, or travel times, of water at ground-water discharge points (streams and wells) in the study area were simulated. Concentrations of nitrate were computed by linking land use and age-dependent nitrate concentrations in recharge to the discharge points. Median concentrations of nitrate in water samples collected during 1996 from shallow monitoring wells in different land-use areas were used to represent the concentration of nitrate in aquifer recharge since 1990. On the basis of upward trends in the use of nitrogen fertilizer, the concentrations of nitrate in aquifer recharge in agricultural and urban areas were assumed to have increased linearly from the background value in 1940 (0.07 mg/L as N) to the 1990 (2.5-14 mg/L as N) concentrations. Model performance was evaluated by comparing the simulation results to measured nitrate concentrations and apparent ground-water ages. Apparent ground-water ages at 32 monitoring wells in the study area determined from tritium/helium-3 ratios and sulfur hexafluoride concentrations favorably matched simulated travel times to these wells. Simulated nitrate concentrations were comparable to concentrations measured in 27 water-supply wells in the study area. A time series (1987-98) of nitrate concentrations at base-flow conditions in three streams that drain basins of various sizes and with various land uses was compared to simulated concentrations in these streams. In all three of the streams, a reasonable fit to the measured concentrations was achieved by multiplying the simulated concentration by 0.6. Because nitrate appeared to move conservatively (not degraded or adsorbed) in ground water to wells, the apparent non-conservative behavior in streams indicates that about 40 percent of the nitrate in aquifer recharge is removed by denitrification in the aquifer near the streams and (or) by in-stream processes. The model was used to evaluate the effects of various nitrate management options on the concentration of nitrate in streams and water-supply wells. Nitrate concentrations were simulated under the following management alternatives: an immediate ban on nitrate input, reduction of input at a constant rate, and fixed input at the current (2000) level. The time required for water to move through the aquifer results in a time lag between the reduction of nitrate input in recharge and the reduction of nitrate concentration in streams and wells. In the gradual-reduction alternative, nitrate concentrations in streams and wells continued to increase for several years after the reduction was enacted. In both the immediate-ban and gradual-reduction alternatives, nitrate concentrations remained elevated above background concentrations long after nitrate input ceased. In the fixed-use alternative, concentrations in streams and wells continued to increase for 30 to 40 years before reaching a constant level. The spatial distributions of simulated nitrate concentrations in streams in 2000 and 2050 were examined with the assumption of no change in land use, nitrate concentration in recharge, or ground-water withdrawals. As expected, nitrate concentrations were highest in agricultural areas and lowest in largely undeveloped areas.

New Jersey↗
USGS2002

Occurrence and distribution of pesticides and volatile organic compounds in ground water and surface water in Central Arizona Basins, 1996-98, and their relation to land use

Samples of ground water and surface water from the Sierra Vista subbasin, the Upper Santa Cruz Basin, and the West Salt River Valley were collected and analyzed to determine the occurrence and distribution of pesticides and volatile organic compounds in central Arizona. The study was done during 1996-98 within the Central Arizona Basins study unit of the National Water-Quality Assessment program. This study included 121 wells and 4 surface-water sites in the 3 basins and the analyses of samples from 4 sites along the Santa Cruz River that were part of a separate study. Samples were collected from 121 wells and 3 surface-water sites for pesticide analyses, and samples were collected from 109 wells and 3 surface-water sites for volatile organic compound analyses. Certain pesticides detected in ground water and surface water can be related specifically to agricultural or urban uses; others can be related to multiple land uses. Effects from historical agriculture are made evident by detections of DDE in ground-water and surface-water samples collected in the West Salt River Valley and detections of atrazine and deethylatrazine in the ground water in the Upper Santa Cruz Basin. Effects from present agriculture are evident in the seasonal variability in concentrations of pre-emergent pesticides in surface-water samples from the West Salt River Valley. Several detections of DDE and dieldrin in surface water were higher than established water-quality limits. Effects of urban land use are made evident by detections of volatile organic compounds in ground water and surface water from the West Salt River Valley. Detections of volatile organic compounds in surface water from the Santa Cruz River near Nogales, Arizona, also are indications of the effects of urban land use. One detection of tetrachloroethene in ground water was higher than established water-quality limits. Water reuse is an important conservation technique in the Southwest; however, the reuse of water provides a transport mechanism for pesticides and volatile organic compounds to reach areas that are not normally affected by manmade compounds from specific land-use activities. The most complex mixture of pesticides and volatile organic compounds is in the West Salt River Valley and is the result of water-management practices and the combination of land uses in this basin throughout history.

Arizona↗
USGS2001

Water quality and occurrence of methyl-tert butyl ether (MTBE) and other fuel related compounds in lakes and ground water at lakeside communities in Sussex and Morris Counties, New Jersey, 1998-1999

Densely populated communities surround many of the larger lakes in northwestern New Jersey. These communities derive most of their water supply from wells. The lakes can be navigated by gasoline-powered watercraft, can be in various stages of eutrophication, may contain pathogens associated with bathing and waterfowl, and are periodically subjected to chemical applications to control aquatic plant growth. Another feature that contributes to water-quality concerns in lakeside communities is the widespread use of septic tanks. Concentrations of methyl tert-butyl ether (MTBE), a gasoline oxygenate, in samples from Cranberry Lake and Lake Lackawanna ranged from 20 to 30 ug/L (micrograms per liter) and 5 to 14 ug/L during the summers of 1998 and 1999, respectively. These levels were persistent throughout the depth of the lakes when mixing conditions were present. MTBE concentrations in samples from the top 20 feet of Lake Hopatcong during summer 1999 were about 10 ug/L and about 2 to 3 ug/L in samples below 20 feet. The source of the MTBE in the lakes was determined to be gasoline-powered watercraft. Other constituents of gasoline--tertiary amyl methyl ether (TAME) and benzene, toluene, ethylbenzene, and xylenes (BTEX)--were detected in the lakes but at much lower concentrations than MTBE. Ambient ground-water quality at Cranberry Lake and Lake Lackawanna appears to be affected by the use of gasoline-powered watercraft. MTBE was detected in water samples from 13 of the 14 wells sampled at Cranberry Lake in fall 1998 and summer 1999. The wells were selected to monitor ambient ground-water quality and had no history of contamination. In ground-water samples collected during fall 1998, MTBE concentrations ranged from 0.12 to 19.8 ug/L, and the median concentration was 0.43 ug/L. In samples from summer 1999, MTBE concentrations ranged from 0.14 to 13.2 ug/L, and the median concentration was 0.38 ug/L. MTBE was detected in samples from four of the five wells at Lake Lackawanna in summer 1999;concentrations ranged from 0.05 to 0.19 ug/L. Lake/ground water interaction is a feasible explanation for the nearly ubiquitous presence of MTBE in ground water. The movement of water from lakes to wells is feasible because many static water levels and essentially all pumped water levels in the wells were below lake levels. Furthermore, diatom fragments were present in samples from the wells. Ambient ground water at Cranberry Lake also may be affected by septic-tank effluent, as indicated by the relation among concentrations of nitrate, boron, and chloroform. This result indicates potential vulnerability of the water supply to contamination by other chemicals and pathogens. Radon in ambient ground water is a concern throughout northern New Jersey. In particular, the median radon concentrations in ground-water samples collected from 14 wells at Cranberry Lake in 1998 and 1999 were 1,282 and 1,046 pCi/L, respectively. The median radon concentration in five ground-water samples collected at Lake Lackawanna in 1999 was 340 pCi/L. Although these values exceed regulatory levels, they are not high relative to radon concentrations measured in northwestern New Jersey. Eight wells in a neighborhood of Cranberry Lake with known MTBE contamination were sampled by the U.S. Geological Survey in summer 1998. MTBE was detected at concentrations greater than or equal to 40 ug/L in five of the wells. Concentrations of TAME, another gasoline oxygenate, were highly correlated with concentrations of MTBE; MTBE concentrations were about 10 times the TAME concentrations. In all samples, however, the concentrations of the BTEX compounds were less than 0.05 ug/L, and the sample from the most highly contaminated well, where the MTBE concentration was 900 ug/L, had no detectable BTEX.

New Jersey↗
USGS2001

Flood frequency estimates and documented and potential extreme peak discharges in Oklahoma

Knowledge of the magnitude and frequency of floods is required for the safe and economical design of highway bridges, culverts, dams, levees, and other structures on or near streams; and for flood plain management programs. Flood frequency estimates for gaged streamflow sites were updated, documented extreme peak discharges for gaged and miscellaneous measurement sites were tabulated, and potential extreme peak discharges for Oklahoma streamflow sites were estimated. Potential extreme peak discharges, derived from the relation between documented extreme peak discharges and contributing drainage areas, can provide valuable information concerning the maximum peak discharge that could be expected at a stream site. Potential extreme peak discharge is useful in conjunction with flood frequency analysis to give the best evaluation of flood risk at a site. Peak discharge and flood frequency for selected recurrence intervals from 2 to 500 years were estimated for 352 gaged streamflow sites. Data through 1999 water year were used from streamflow-gaging stations with at least 8 years of record within Oklahoma or about 25 kilometers into the bordering states of Arkansas, Kansas, Missouri, New Mexico, and Texas. These sites were in unregulated basins, and basins affected by regulation, urbanization, and irrigation. Documented extreme peak discharges and associated data were compiled for 514 sites in and near Oklahoma, 352 with streamflow-gaging stations and 162 at miscellaneous measurements sites or streamflow-gaging stations with short record, with a total of 671 measurements.The sites are fairly well distributed statewide, however many streams, large and small, have never been monitored. Potential extreme peak-discharge curves were developed for streamflow sites in hydrologic regions of the state based on documented extreme peak discharges and the contributing drainage areas. Two hydrologic regions, east and west, were defined using 98 degrees 15 minutes longitude as the dividing line.

Oklahoma↗
USGS2001

Evaluation of the Effects of Development on Peak-Flow Hydrographs for Collyer Brook, Maine

The development of former agricultural or forested lands creates more impervious areas and drainage improvements that can increase the volume of runoff and decrease infiltration and ground-water recharge in a watershed. Drainage improvements also can improve the conveyance of runoff, decreasing the time of rise to peak flow between the start of a rainfall event and the peak surface-water runoff, and likewise decreasing the duration of the peak-flow event. The watershed of Collyer Brook in southern Maine was studied to evaluate the effect of land-use changes on peakflow hydrographs because of the known development in the area during the past 35 years and the availability of aerial photos and streamflow data for this time period. Although aerial photography indicates that suburban development has increased in the watershed between 1964 and 1999, the overall effect of suburbanization on rainfall-runoff processes in the watershed did not produce a statistically detectable change in the peak-flow hydrographs for Collyer Brook.

Water-Resources Investigations Report↗
USGS2002

Feasibility of Acoustic Doppler Velocity Meters for the Production of Discharge Records from U.S. Geological Survey Streamflow-Gaging Stations

It is feasible to use acoustic Doppler velocity meters (ADVM's) installed at U.S. Geological Survey (USGS) streamflow-gaging stations to compute records of river discharge. ADVM's are small acoustic current meters that use the Doppler principle to measure water velocities in a two-dimensional plane. Records of river discharge can be computed from stage and ADVM velocity data using the 'index velocity' method. The ADVM-measured velocities are used as an estimator or 'index' of the mean velocity in the channel. In evaluations of ADVM's for the computation of records of river discharge, the USGS installed ADVM's at three streamflow-gaging stations in Indiana: Kankakee River at Davis, Fall Creek at Millersville, and Iroquois River near Foresman. The ADVM evaluation study period was from June 1999 to February 2001. Discharge records were computed, using ADVM data from each station. Discharge records also were computed using conventional stage-discharge methods of the USGS. The records produced from ADVM and conventional methods were compared with discharge record hydrographs and statistics. Overall, the records compared closely from the Kankakee River and Fall Creek stations. For the Iroquois River station, variable backwater was present and affected the comparison; because the ADVM record compensates for backwater, the ADVM record may be superior to the conventional record. For the three stations, the ADVM records were judged to be of a quality acceptable to USGS standards for publications and near realtime ADVM-computed discharges are served on USGS real-time data World Wide Web pages.

Indiana↗
USGS2001

Assessment of habitat, fish communities, and streamflow requirements for habitat protection, Ipswich River, Massachusetts, 1998-99

The relations among stream habitat, fish communities, and hydrologic conditions were investigated in the Ipswich River Basin in northeastern Massachusetts. Data were assessed from 27 sites on the mainstem of the Ipswich River from July to September 1998 and from 10 sites on 5 major tributaries in July and August 1999. Habitat assessments made in 1998 determined that in a year with sustained streamflow for most of the summer, the Ipswich River contains diverse, high-quality aquatic habitat. Channel types are predominantly low gradient glides, pools, and impoundments, with a sandy streambed and a forest or shrub riparian zone. Features that provide fish habitat are located mostly along stream margins; these features include overhanging brush, undercut banks, exposed roots, and woody debris. These habitat features decrease in availability to aquatic communities with declining streamflows and generally become unavailable after streamflows drop to the point where the edge of water recedes from the stream banks. The mainstem and tributaries were sampled to determine fish species composition, relative abundance, and length frequency. Fish sampling indicates that the fish community in the Ipswich River is currently a warm-water fish community dominated by pond-type fish. However, historical temperature data, and survival of stocked trout in the mainstem Ipswich into late summer of 1998, indicate that the Ipswich River potentially could support cold-water fish species if adequate flows are maintained. Dominant fish species sampled in the mainstem Ipswich River were redfin pickerel ( Esox americanus ), American eel ( Anguilla rostrata ), and pumpkinseed ( Lepomis gibbosus ), which together represented 41, 22, and 10 percent, respectively, of 4,745 fish sampled. The fish communities of the mainstem and tributaries contained few fluvial-dependent or fluvial-specialist species (requiring flow), and were dominated by macrohabitat generalists (tolerant of low-flow, warm-water, and ponded conditions). In comparison to a nearby river (Lamprey River, N.H.), and a reference fish community developed for inland New England streams, the Ipswich fish community would be expected to have appreciably higher percentages of fluvial-dependent and fluvial-specialist species were streamflows restored. Four riffle sites on the mainstem of the Ipswich River were identified as critical habitat areas because they are among the first sites to exhibit fish-passage problems or to dry during low flows. A watershed-scale precipitation-runoff model previously developed for the Ipswich River was used to simulate streamflows at these four sites for the period 1961­95 under no withdrawals (for water supply) and 1991 land use to evaluate habitat suitability under conditions that approximate the natural flow conditions. These simulated flows were used to calculate streamflow requirements by the Tennant and New England Aquatic-Base-Flow methods. Stream channels were surveyed at the critical riffle sites, and Water Surface Profile models were used to simulate streamflows and hydraulic characteristics needed for determining streamflow requirements by use of the Wetted-Perimeter and R2Cross methods. Normalized by drainage area to units of cubic feet per second per square mile, these methods yielded the following streamflow requirements: 0.50 cubic feet per second per square mile for the Tennant 30-percent Q MA method, 0.42 cubic feet per second per square mile for the wetted-perimeter value necessary to maintain wetted perimeter at three altered riffle sites, 0.42 cubic feet per second per square mile for the R2Cross value required to maintain R2Cross hydraulic criteria at a natural riffle site, and 0.34 cubic feet per second per square mile for the aquatic-base-flow median of monthly mean flows for August for the simulated 1961­95 period under no withdrawals and 1991 land use. The mean streamflow requirement determined from these four methods is 0.42 cubic feet per second per square mile. This flow would represent an average flow-exceedence value for the six study sites of about 77 percent under simulated flows with no withdrawals. For these flows, the 70-, 80-, and 90-percent exceedence flows averaged 0.59, 0.37, and 0.21 cubic feet per second per square mile, respectively, and the 7-day, 10-year low flow statistic at the two gaged sites averaged 0.08 cubic feet per second per square mile. Simulated flows under no withdrawals were used to determine monthly mean flows and other flow statistics used in the Range of Variability Approach to define a flow regime that mimics the river's natural flow regime.

Massachusetts↗
USGS2002

Simulation of Transient Ground-Water Flow in the Valley-Fill Aquifers of the Upper Rockaway River Basin, Morris County, New Jersey

More than 90 percent of the public water supply in the upper Rockaway River Valley in Morris County, New Jersey, is obtained from ground-water withdrawals from the valley-fill aquifers. During 1997, an average of 9.6 million gallons per day of ground water was withdrawn from these aquifers. The aquifer system consists of an unconfined aquifer (upper aquifer) and a locally confined aquifer (lower aquifer), which are composed of sands and gravels. These aquifers are separated by a discontinuous confining unit that consists mostly of silt and clay. Increases in ground-water withdrawals can induce movement of water from streams to wells, increase flow from the upper aquifer to the lower aquifer, and reduce base flow in the Rockaway River downstream. A ground-water-flow model was used to simulate and quantify the effects of current withdrawals on the valley-fill aquifer system under transient monthly conditions. Recharge over the model area varies both spatially and temporally. Part of model calibration consisted of adjusting percentages of monthly precipitation that recharges the valley-fill aquifer system. More recharge occurs during winter and spring than during summer and fall. This seasonal variation affects ground-water discharge to the Rockaway River. Ground-water withdrawals from the valleyfill aquifers also affect ground-water discharge to the Rockaway River. Three scenarios were simulated to observe the effects of ground-water withdrawals on ground-water discharge to the Rockaway River and to determine the extent to which variations in rates of withdrawals correspond to variations in rates of streamflow depletion. Streamflow depletion was estimated by comparing model-computed ground-water discharge for the three scenarios with the modelcomputed ground-water discharge under transient conditions. In scenario 1, all pumpage was removed from the model. In scenarios 2 and 3, 1 million gallons per day of ground-water withdrawals in excess of the current pumpage was withdrawn from the valley-fill aquifers. In scenario 2, the additional 1 million gallons per day of withdrawals were made from a hypothetical well located in the upper aquifer about 250 feet from the river. In scenario 3, the additional withdrawals were made from a hypothetical well located in the lower aquifer about 1,750 feet from the river. Results of scenario 1 indicated that the difference between the streamflow depletion and withdrawals is small; increases in ground-water withdrawals from the valley-fill aquifers correspond to decreases in ground-water discharge to the Rockaway River of approximately the same amount. Results of scenario 2 and 3 indicated that a lag time could occur between the introduction of withdrawals and the full magnitude of the effects of the withdrawals on streamflow depletion. A lag time of about seven months occurred for scenario 2 with the well placed in the upper aquifer. A longer lag time of more than 1.5 years occurred with the well placed in the lower aquifer and separated from the upper aquifer by a confining unit (scenario 3). Extreme low flow in the Rockaway River is mostly base flow. A flow-duration analysis of the Rockaway River at the surface-water gaging station upstream from the Boonton Reservoir during the drought of 1961-66 indicated that streamflow from the upper Rockaway River Basin alone might not be sufficient to meet the minimum passing flow of 7 million gallons per day during a drought. Under similar drought conditions today, during 3.2 percent of the drought time, streamflow at this station upstream from the reservoir would be less than the minimum passing flow requirement downstream from the reservoir.

Water-Resources Investigations Report↗
USGS2001

Simulated Effects of Alternative Pumping Strategies on Ground-Water-Flow Patterns and Areas Contributing Recharge to Selected Wells near Kenvil, Morris County, New Jersey

Ground-water-flow patterns and areas contributing recharge to supply wells change in response to new or altered pumping stresses. An understanding of these potential changes is essential for the effective evaluation of possible future water-supply alternatives, especially if the supply wells may be vulnerable to contamination from the land surface. Demand for water from a valley-fill and carbonate-rock aquifer system in the study area near Kenvil in Morris County, New Jersey, is expected to increase as the population of communities grows in and near the area. As withdrawals increase and new supplies are developed over time, ground-water-flow patterns and areas contributing recharge to supply wells in the area are expected to change. Flow patterns and areas contributing recharge to selected supply wells in the aquifer system in the study area, under a variety of hypothetical withdrawal conditions, were evaluated by use of numerical modeling techniques. Under the four alternative scenarios evaluated, withdrawals from selected wells are increased by a total of 1.3 to 2.4 million gallons per day, or 32 to 56 percent over the recent (1991-95) total withdrawals from the study area. The scenarios were incorporated in simulations of ground-water flow that were conducted by use of a previously developed three-dimensional numerical model. Flow-path comparisons indicate that ground-water-flow patterns change in response to changes in pumping rates and (or) new pumping stresses. Under the scenarios represented in the simulations, water levels (hydraulic heads) in the study area decline from 0 to as much as 63 ft. Under most of the scenarios evaluated, downward leakage of ground water increases and upward discharge to streams decreases. In some scenarios, supply wells intercept additional local flow, whereas in other scenarios additional regional flow is intercepted. Areas contributing recharge to wells also change or develop. Changes in flow patterns and in the location, size, and shape of areas contributing recharge to supply wells depend on the location and magnitude of the change in withdrawal stress and on other hydrogeologic factors, such as the configuration of aquifer boundaries and differences in aquifer properties.

Water-Resources Investigations Report↗
USGS2002

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory--Determination of wastewater compounds by polystyrene-divinylbenzene solid-phase extraction and capillary-column gas chromatography/mass spectrometry

A method for the determination of 67 compounds typically found in domestic and industrial wastewater is described. The method was developed in response to increasing concern over the impact of endocrine-disrupting chemicals in wastewater on aquatic organisms. This method also may be useful for evaluating the impact of combined sanitary and storm-sewer overflow on the water quality of urban streams. The method focuses on the determination of compounds that are an indicator of wastewater or that have been chosen on the basis of their endocrine-disrupting potential or toxicity. These compounds include the alkylphenol ethoxylate nonionic surfactants and their degradates, food additives, fragrances, antioxidants, flame retardants, plasticizers, industrial solvents, disinfectants, fecal sterols, polycyclicaromatic hydrocarbons, and high-use domestic pesticides. Water samples are filtered to remove suspended particulate matter and then are extracted by vacuum through disposable solid-phase cartridges that contain polystyrene-divinylbenzene resin. Cartridges are dried with nitrogen gas, and then sorbed compounds are eluted with dichloromethane-diethyl ether (4:1) and determined by capillary-column gas chromatography/mass spectrometry. Recoveries in reagent-water samples fortified at 4 micrograms per liter averaged 74 percent ? 7 percent relative standard deviation for all method compounds. Initial method detection limits for single-component compounds (excluding hormones and sterols) averaged 0.15 microgram per liter. Samples are preserved by filtration, the addition of 60 grams NaCl, and storage at 4 degrees Celsius. The laboratory has established a sample-holding time (prior to sample extraction) of 14 days from the date of sample collection until a statistically accepted method can be used to determine the effectiveness of these sample-preservation procedures.

Water-Resources Investigations Report↗
USGS2001

Low-Level Volatile Organic Compounds in Active Public Supply Wells as Ground-Water Tracers in the Los Angeles Physiographic Basin, California, 2000

Data were collected to evaluate the use of low-level volatile organic compounds (VOC) to assess the vulnerability of public supply wells in the Los Angeles physiographic basin. Samples of untreated ground water from 178 active public supply wells in the Los Angeles physiographic basin show that VOCs were detected in 61 percent of the ground-water samples; most of these detections were low, with only 29 percent above 1 mg/L (microgram per liter). Thirty-nine of the 86 VOCs analyzed were detected in at least one sample, and 11 VOCs were detected in 7 percent or more of the samples. The six most frequently detected VOCs were trichloromethane (chloroform) (46 percent); trichloroethene (TCE) (28 percent); tetrachloro-ethene (PCE) (19 percent); methyl tert-butyl ether (MTBE) (14 percent); 1,1-dichloroethane (11 percent); and 1,1,1-trichloroethane (TCA) (11 percent). These VOCs were also the most frequently detected VOCs in ground water representative of a wide range of hydrologically conditions in urban areas nationwide. Only two VOCs (TCE and PCE) exceeded state and federal primary maximum contaminant levels (MCL) for drinking water in a total of seven samples. Because samples were collected prior to water treatment, sample concentrations do not represent the concentrations entering the drinking-water system.Ground water containing VOCs may be considered to be a tracer of postindustrial-aged water-water that was recharged after the onset of intense urban development. The overall distribution of VOC detections is related to the hydrological and the engineered recharge facilities in the Coastal Los Angeles Basin and the Coastal Santa Ana Basin that comprise the Los Angeles physiographic basin. Most of the ground-water recharge occurs at engineered recharge facilities in the generally coarse-grained northeastern parts of the study area (forebay areas). Ground-water recharge from the land surface is minimal in the southwestern part of the basins, distal from the recharge facilities, where clay layers impede the vertical migration of ground water (pressure areas).VOCs are not uniformly distributed over the study area. Most of the wells with multiple VOC detections, which also have the highest concentrations, are in the forebay areas and are clustered proximal to the recharge facilities. In addition, the number of VOC detections and VOC concentrations decrease beyond about 10-15 kilometers from the recharge facilities. The distribution of individual VOCs is also related to their history of use. MTBE traces ground water recharged during about the last decade and is detected almost exclusively in the forebay areas. Chloroform, which has been used since the 1920s, is more widely distributed and is detected at the greatest distances from the recharge facilities.Downward migration of VOCs from the land surface may be a viable process for VOCs to reach aquifers in parts of the forebay areas, but there is little indication that the same process is active in the pressure area. The lack of contrast in the number of VOC detections between wells of different depths over most of the study area suggests that the downward migration from the land surface is not a dominant pathway for VOCs to travel to the capture zones of public supply wells. Isolated occurrences of multiple VOC detections and high concentrations of VOCs in individual wells may indicate rapid vertical transport from a localized source. Stable isotope data indicate that ground water containing VOCs is a mixture of local precipitation and runoff with water that is isotopically lighter (more negative) than the local sources. The isotopically lighter water could either be Colorado River water or State Water Project water, both of which are imported to the basin and used as a source of recharge to the ground-water flow system. The stable isotope data support the interpretation that VOCs in ground water are associated with the engineered recharge facilities.Two of the most frequently detecte

Water-Resources Investigations Report↗
USGS2001

Water-quality characteristics in the Black Hills area, South Dakota

This report summarizes the water-quality characteristics of ground-water and surface-water in the Black Hills area. Differences in groundwater quality by aquifer and differences in surfacewater quality by water source are presented. Ground-water characteristics are discussed individually for each of the major aquifers in the Black Hills area, referred to herein as the Precambrian, Deadwood, Madison, Minnelusa, Minnekahta, and Inyan Kara aquifers. Characteristics for minor aquifers also are discussed briefly. Surface-water characteristics are discussed for hydrogeologic settings including headwater springs, crystalline core sites, artesian springs, and exterior sites. To characterize the water quality of aquifers and streams in the Black Hills area, data from the U.S. Geological Survey National Water Information System water-quality database were examined. This included samples collected as part of the Black Hills Hydrology Study as well as for other studies within the time frame of October 1, 1930, to September 30, 1998. Tables of individual results are not presented in this report, only summaries. Constituents summarized and discussed include physical properties, common ions, nutrients, trace elements, and radionuclides. Comparisons of concentration levels are made to drinking-water standards as well as beneficial-use and aquatic-life criteria. Ground water within the Black Hills and surrounding area generally is fresh and hard to very hard. Concentrations exceeding various Secondary and Maximum Contaminant Levels may affect the use of the water in some areas for many aquifers within the study area. Concentrations that exceed Secondary Maximum Contaminant Levels (SMCL's) generally affect the water only aesthetically. Radionuclide concentrations may be especially high in some of the major aquifers used within the study area and preclude the use of water in some areas. The sodiumadsorption ratio and specific conductance may affect irrigation use for some wells. High concentrations of iron and manganese are the only concentrations that may hamper the use of water from Precambrian aquifers. The principal deterrents to use of water from the Deadwood aquifer are the high concentrations of radionuclides as well as iron and manganese. Iron, manganese, and hardness may deter use of water from the Madison aquifer as well as dissolved solids and sulfate in downgradient wells (generally deeper than 2,000 feet). Iron, manganese, and hardness may also deter use of the Minnelusa aquifer. Water from the Minnekahta aquifer generally is suitable for all water uses although it is hard to very hard. High concentrations of dissolved solids, iron, sulfate, and manganese may hamper the use of water from the Inyan Kara aquifer. In the southern Black Hills, radium-226 and uranium concentrations also may preclude use of water from the Inyan Kara aquifer. Suitability for irrigation may be affected by high specific conductance and sodium-adsorption ratio for the Inyan Kara. Surface-water quality within the Black Hills and surrounding area generally is very good but the water is hard to very hard. Concentrations of some constituents in the study area tend to be higher exterior to the Black Hills, primarily due to influences from the Cretaceous-age marine shales, including dissolved solids, sodium, sulfate, selenium, and uranium. Headwater springs have relatively constant discharge, specific conductance, dissolved solids, and concentrations of most other constituents. Concentrations at crystalline core sites are very similar to those found in samples from Precambrian aquifers. Some high nitrate concentrations greater than the Maximum Contaminant Level (MCL) of 10 mg/L (milligrams per liter) have occurred at Annie Creek near Lead, which have been attributed to mining impacts. Trace elements generally are low with the exception of arsenic, for which 60 percent of samples exceed the proposed MCL of 10 ug/L (micrograms per liter) and one sample

Water-Resources Investigations Report↗