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At least 1,693 records · Page 94Linked to original sources

Integrating sea level rise scenarios into Everglades restoration planning

One of the largest and most expensive restoration efforts in the world is occurring in the Everglades, a sub-tropical freshwater wetland system located in southern Florida. This unique ecosystem supports several endangered species, provides flood control for Florida’s large urban population, and provides water for both agriculture and drinking supply within the state. The Comprehensive Everglades Restoration Plan (CERP), authorized by Congress in 2000, guides federal, state, and local efforts to build the infrastructure necessary to bring more water into the Everglades and restore its ecological integrity, while balancing other water-related needs such as water supply and flood protection in the human environment. The Everglades encompasses the southern coast of Florida and restoration efforts are likely to be impacted by climate-induced sea level rise. However, currently, many project planning studies do not formally incorporate the potential impacts of sea level rise when evaluating restoration plan outcomes. Resource managers and project planners require methods and tools to confidently incorporate scenarios of sea level rise into their evaluations. The U.S. Geological Survey (USGS) and partners from the University of Florida worked with project planners from multiple agencies to identify restoration questions for consideration when addressing sea level rise. In addition, our project team sought to understand the types of sea level rise decision-support tools that would be of interest, and then worked with Everglades restoration managers and project planners to develop those tools. The tools developed by this project can be used by project planners to inform their decision-making abilities when considering multiple restoration plans across the Everglades landscape. Specifically, the novel ways to visualize output information from ecological models that came of this project can help project planners compare alternative restoration plans that include potential sea level rise impacts. This effort demonstrates how incorporating sea level rise scenarios into Everglades restoration project planning can help managers decide whether projects will maintain or improve ecological integrity and evaluate water availability for wildlife and humans.

Final Report↗

Pesticide Occurrence and Distribution in the Lower Clackamas River Basin, Oregon, 2000-2005

Pesticide occurrence and distribution in the lower Clackamas River basin was evaluated in 2000?2005, when 119 water samples were analyzed for a suite of 86?198 dissolved pesticides. Sampling included the lower-basin tributaries and the Clackamas River mainstem, along with paired samples of pre- and post-treatment drinking water (source and finished water) from one of four drinking water-treatment plants that draw water from the lower river. Most of the sampling in the tributaries occurred during storms, whereas most of the source and finished water samples from the study drinking-water treatment plant were obtained at regular intervals, and targeted one storm event in 2005. In all, 63 pesticide compounds were detected, including 33 herbicides, 15 insecticides, 6 fungicides, and 9 pesticide degradation products. Atrazine and simazine were detected in about half of samples, and atrazine and one of its degradates (deethylatrazine) were detected together in 30 percent of samples. Other high-use herbicides such as glyphosate, triclopyr, 2,4-D, and metolachlor also were frequently detected, particularly in the lower-basin tributaries. Pesticides were detected in all eight of the lower-basin tributaries sampled, and were also frequently detected in the lower Clackamas River. Although pesticides were detected in all of the lower basin tributaries, the highest pesticide loads (amounts) were found in Deep and Rock Creeks. These medium-sized streams drain a mix of agricultural land (row crops and nurseries), pastureland, and rural residential areas. The highest pesticide loads were found in Rock Creek at 172nd Avenue and in two Deep Creek tributaries, North Fork Deep and Noyer Creeks, where 15?18 pesticides were detected. Pesticide yields (loads per unit area) were highest in Cow and Carli Creeks, two small streams that drain the highly urban and industrial northwestern part of the lower basin. Other sites having relatively high pesticide yields included middle Rock Creek and upper Noyer Creek, which drain basins having nurseries, pasture, and rural residential land. Some concentrations of insecticides (diazinon, chlorpyrifos, azinphos-methyl, and p,p?-DDE) exceeded U.S. Environmental Protection Agency (USEPA) aquatic-life benchmarks in Carli, Sieben, Rock, Noyer, Doane, and North Fork Deep Creeks. One azinphos-methyl concentration in Doane Creek (0.21 micrograms per liter [?g/L]) exceeded Federal and State of Oregon benchmarks for the protection of fish and benthic invertebrates. Concentrations of several other pesticide compounds exceeded non-USEPA benchmarks. Twenty-six pesticides or degradates were detected in the Clackamas River mainstem, typically at much lower concentrations than those detected in the lower-basin tributaries. At least 1 pesticide was detected in 65 percent of 34 samples collected from the Clackamas River, with an average of 2?3 pesticides per sample. Pesticides were detected in 9 (or 60 percent) of the 15 finished water samples collected from the study water-treatment plant during 2003?2005. These included 10 herbicides, 1 insecticide, 1 fungicide, 1 insect repellent, and 2 pesticide degradates. The herbicides diuron and simazine were the most frequently detected (four times each during the study), at concentrations far below human-health benchmarks?USEPA Maximum Contaminant Levels or U.S. Geological Survey human Health-Based Screening Levels (HBSLs). The highest pesticide concentration in finished drinking water was 0.18 ?g/L of diuron, which was 11 times lower than its low HBSL benchmark. Although 0?2 pesticides were detected in most finished water samples, 9 and 6 pesticides were detected in 2 storm-associated samples from May and September 2005, respectively. Three of the unregulated compounds detected in finished drinking water (diazinon-oxon, deethylatrazine [CIAT], and N, N-diethyl-m-toluamide [DEET]) do not have human-health benchmarks available for comparison. Although most of the 51 curren

Scientific Investigations Report↗

Analysis of selected benthic communities in Florida Everglades with reference to their physical and chemical environment

Species diversity and numbers of benthic macroinvertebrates were determined at 12 sites, both canals and marshes, in the Everglades of south Florida. The values calculated are used to indicate long-term trends in water quality and variations between study areas. Species diversity at all sites was generally in a range indicative of degraded water quality. The number of organisms per square metre of bottom surface was highly variable ranging from 43 to 8,200 organisms. Chemical analysis of water and bottom material indicated no gross contamination from sewage or agricultural runoff in any of the canals where benthic organisms were collected. Other physical factors such as depth, velocity of flow, substrate type, and water-level fluctuation were responsible for the low species diversities and variable numbers of organisms, rather than contamination from urban or agricultural areas.

Florida↗

Distance to human populations influences epidemiology of respiratory disease in desert tortoises

We explored variables likely to affect health of Agassiz's desert tortoises (Gopherus agassizii) in a 1,183-km2 study area in the central Mojave Desert of California between 2005 and 2008. We evaluated 1,004 tortoises for prevalence and spatial distribution of 2 pathogens, Mycoplasma agassizii and M. testudineum, that cause upper respiratory tract disease. We defined tortoises as test-positive if they were positive by culture and/or DNA identification or positive or suspect for specific antibody for either of the two pathogens. We used covariates of habitat (vegetation, elevation, slope, and aspect), tortoise size and sex, distance from another test-positive tortoise, and anthropogenic variables (distances to roads, agricultural areas, playas, urban areas, and centroids of human-populated census blocks). We used both logistic regression models and regression trees to evaluate the 2 species of Mycoplasma separately. The prevalence of test-positive tortoises was low: 1.49% (15/1,004) for M. agassizii and 2.89% (29/1,004) for M. testudineum. The spatial distributions of test-positive tortoises for the 2 Mycoplasma species showed little overlap; only 2 tortoises were test-positive for both diseases. However, the spatial distributions did not differ statistically between the 2 species. We consistently found higher prevalence of test-positive tortoises with shorter distances to centroids of human-populated census blocks. The relationship between distance to human-populated census blocks and tortoises that are test-positive for M. agassizii and potentially M. testudineum may be related to release or escape of captive tortoises because the prevalence of M. agassizii in captive tortoises is high. Our findings have application to other species of chelonians where both domestic captive and wild populations exist. Published 2014. This article is a U.S. Government work and is in the public domain in the USA.

Journal of Wildlife Management↗

Worldwide wetland loss and conservation of biodiversity and ecosystem services

Aim : Best strategies for future conservation and management to address global and regional trends in wetland loss and degradation are assessed in this article. Main concepts covered : Direct drivers of wetland loss and change include land drainage and filling, hydrologic alteration, degradation from pollutants and sediments, and conversion to agriculture, urban and industrial usage. Estimates of global wetland loss are as high as 87% since 1700 CE. All regions of the world have lost wetland area. The designation of wetland protected area reduces disturbance by humans and supports the conservation of biodiversity and habitat. Protected areas have been designated by local, state, or federal entities, NGOs (e.g., Nature Conservancy), and the Ramsar Convention on Wetlands. Protected wetlands have great value for human society. For example, wetlands such as peatland and swamp store carbon that would otherwise be released as greenhouse gases to the atmosphere. A case study of the Keoladeo National Park, Rajasthan, India underscores the importance of maintaining water supply to maintain aquatic vegetation in protected wetlands. Conclusion/outlook : Given the combined stresses of land-use and climate change to wetland protected areas, management of altered wetlands may improve their function. Beneficial management actions can include freshwater remediation of hydrologically-altered floodplains, improved wetland reserve design, assisted migration, and the softening of burning/cutting during drought. A better knowledge of potential of management actions to remediate land-use change will be helpful in addressing protected area management to promote conservation in the future.

Book chapter↗

Water-quality assessment of the upper Snake River Basin, Idaho and western Wyoming — Environmental setting, 1980-92

The 35,800-square-mile upper Snake River Basin is one of 20 areas studied as part of the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey. Objectives of NAWQA are to study ground- and surface-water quality, biology, and their relations to land-use activities. Major land and water uses that affect water quality in the basin are irrigated agriculture, grazing, aquaculture, food processing, and wastewater treatment. Data summarized in this report are used in companion reports to help define the relations among land use, water use, water quality, and biological conditions. The upper Snake River Basin is located in southeastern Idaho and northwestern Wyoming and includes small parts of Nevada and Utah. Total population in the basin was about 425,000 in 1990. Major urban areas are Idaho Falls, Pocatello, Rexburg, and Twin Falls, Idaho, which make up 10, 11,3, and 6 percent of the total population, respectively. Climate in the basin is mostly semiarid and mean annual precipitation ranges from 8 to more than 60 inches. The eastern Snake River Plain is the major geologic feature in the basin and is delineated mostly by Quaternary and Tertiary basalt flows. It is about 55 to 62 miles wide and 320 miles long and bisects the basin in a northeast-southwest direction. The Snake River is the dominant surface-water feature and flows about 453 miles from the southern border of Yellowstone National Park in Wyoming to King Hill, Idaho, where it leaves the basin. The Snake River flows through five reservoirs that provide a total storage capacity of more than 4 million acre-feet. Gravity-flow diversions are predominant in the upper part of the basin and totaled 8.8 million.acre-feet in 1980. Pumped diversions occur mainly in the lower part of the basin and totaled 408,500 acre-feet in 1980. The Snake River Plain aquifer is the predominant ground-water feature in the upper Snake River Basin and underlies the eastern Snake River Plain. The upper 500 feet of the aquifer may store 200 to 300 million acre-feet of water. Ground-water resources that supply agricultural lands are sustained by recharge from surface-water irrigation, precipitation, and tributary inflow. Major ground-water discharges are at springs and seeps or from ground-water pumpage for irrigation. Water use in the basin is dominated by irrigated agriculture, which is the largest consumptive water use in the basin. Major crops in the basin include potatoes, wheat, sugar beets, hay, and barley. Most irrigation needs are supplied from surface-water sources through a series of canals and laterals. In 1990, about 2.5 million acres were irrigated with more than 14.2 million acre-feet of surface and ground water. About 21 percent of the basin is agricultural land and 50 percent is rangeland. Idaho leads the Nation in trout production for commercial sale. Combined mean annual discharges from 12 aquacultural facilities in the basin (1985-90) were about 787,000 acre-feet. These facilities are clustered in a reach of the Snake River between Milner Dam and King Hill where ground-water discharge is from many seeps and springs that provide sufficient quantities of good-quality water. Other facilities that release effluent to the Snake River include 13 municipal wastewater treatment plants and 3 industrial facilities.

Idaho, Wyoming↗

Simulating the effects of frequent fire on southern california coastal shrublands

Fire disturbance is a primary agent of change in the mediterranean-climate chaparral shrublands of southern California, USA. However, fire frequency has been steadily increasing in coastal regions due to ignitions at the growing wildland-urban interface. Although chaparral is resilient to a range of fire frequencies, successively short intervals between fires can threaten the persistence of some species, and the effects may differ according to plant functional type. California shrublands support high levels of biological diversity, including many endangered and endemic species. Therefore, it is important to understand the long-term effects of altered fire regimes on these communities. A spatially explicit simulation model of landscape disturbance and succession (LANDIS) was used to predict the effects of frequent fire on the distribution of dominant plant functional types in a study area administered by the National Park Service. Shrubs dependent on fire-cued seed germination were most sensitive to frequent fire and lost substantial cover to other functional types, including drought-deciduous subshrubs that typify coastal sage scrub and nonnative annual grasses. Shrubs that resprout were favored by higher fire frequencies and gained in extent under these treatments. Due to this potential for vegetation change, caution is advised against the widespread use of prescribed fire in the region. ?? 2006 by the Ecological Society of America.

Ecological Applications↗

Drought and water management in ancient Maya society

Paleoclimate research in the Maya region of Mesoamerica provides compelling evidence of drought during key periods of cultural transition in Maya society. These include the transition from the Preclassic to the Classic, and from Classic to the Postclassic. Previous research emphasized a causal relationship between drought and cultural change, or so-called “collapse” in the Maya region. Recent advances in the range and precision of climate-sensitive proxies and the development of new archives have enabled quantitative reconstructions of past hydroclimate, as well as providing evidence of high impact, short-duration events, such as tropical cyclones. Simultaneously, archaeological research has unearthed widespread evidence of technologies used by the Maya to exert control over water resources in urban, rural, and agricultural settings. Evidence suggests that many of these water features were in use for multiple generations, possibly centuries, and many were constructed during the Terminal Preclassic and Terminal Classic periods. We suggest that, given the availability of new archaeological and paleoclimate records, these data can be combined to identify the full complexity of Maya adaptation to hydroclimate variability to emphasize adaptation and resilience to both water scarcity and over-abundance (e.g., flooding). Such syntheses, which can offer lessons for present-day efforts to grapple with regional climate change, will benefit from additional studies in data-poor zones of the Maya region, as well as public archiving of paleoclimate and archaeological data.

Progress in Physical Geography: Earth and Environm↗

Shallow faulting and folding beneath south‐central Seattle, Washington State, from land‐based high‐resolution seismic‐reflection imaging

The geologic framework of the Seattle fault zone (SFZ) has been extensively studied, but the structure and fault strand locations in the central portion of the fault zone through the city of Seattle have remained controversial. Much of what is known about the SFZ has come from light detection and ranging (lidar)‐topographic surveys and paleoseismic investigations of fault scarps primarily west of Puget Sound, regional gravity and aeromagnetic modeling, and multiscale marine seismic imaging in waters both west and east of Seattle. We analyze ∼24 km of land‐based P ‐wave seismic‐reflection data that fill in a critical gap in our understanding of the SFZ beneath the urban areas of West Seattle, south‐central Seattle, and Mercer Island. These data image deformed strata in the upper 1 km, including upwarped Tertiary rock and younger sediments. Collectively, these data provide evidence for multiple Quaternary‐active thrust faults, back thrusts, and sub‐basins within the SFZ beneath the city of Seattle. The results indicate that multiple and potentially active back thrusts in the upper ∼500 m extend across the length of the SFZ and the entire urban corridor that may be analogous to those on Bainbridge Island west of Puget Sound.

Washington↗

Declines of the California red-legged frog: Climate, UV-B, habitat, and pesticides hypotheses

The federally threatened California red-legged frog ( Rana aurora draytonii ) has disappeared from much of its range for unknown reasons. We mapped 237 historic locations for the species and determined their current population status. Using a geographic information system (GIS), we determined latitude, elevation, and land use attributes for all sites and analyzed the spatial pattern of declines. We then compared the observed patterns of decline to those predicted by the climate change, UV-B radiation, pesticides, and habitat alteration hypotheses for amphibian decline. Declines were not consistent with the climate change hypothesis but showed a strong positive association with elevation, percentage upwind agricultural land use, and local urbanization. These results apply to patterns of decline across the entire range of R. a. draytonii in California, as well as within geographic subregions. The elevational gradient in declines is consistent with the UV-B hypothesis, although the UV-B hypothesis also predicts a north-to-south gradient in declines, which we did not observe. The association of declines with the amount of upwind agricultural land use strongly suggests that wind-borne agrochemicals may be an important factor in declines. This association was most pronounced within the Central Valley–Sierra region, where other studies have documented both transport and deposition of pesticides to the Sierra Nevada and the presence of pesticide residues in the bodies of congeneric ( Rana muscosa ) and more distantly related ( Hyla regilla ) frog species.

California↗

Natural restoration basics for wetlands

Around the world, dams, diversions, and drainage systems reengineer rivers for navigation, farming, and urban development, and this has caused vast changes in the environmental conditions of the flood plains adjacent to these rivers (Middleton, 2002). Even though “flood pulses,” the periodic overflow of these rivers, were once the most important hydrological factor regulating all functions of the flood plain (Junk and others, 1986), now they have been reduced or eliminated along many of the world’s waterways (Sparks and others, 1998). These changes in river channels have created a hydrologic setting on flood plains that has not been conducive to restoration and nature conservation (Middleton, 2002). Consequently, USGS scientists are studying the long-term effects of hydrologic changes on flood plains, such as how the restoration of baldcypress (Taxodium distichum) swamps has been hindered because seeds cannot disperse or germinate without the seasonally driven high and low water levels associated with the flood pulse.

Fact Sheet↗

Organic waste compounds in streams: Occurrence and aquatic toxicity in different stream compartments, flow regimes, and land uses in southeast Wisconsin, 2006–9

An assessment of organic chemicals and aquatic toxicity in streams located near Milwaukee, Wisconsin, indicated high potential for adverse impacts on aquatic organisms that could be related to organic waste compounds (OWCs). OWCs used in agriculture, industry, and households make their way into surface waters through runoff, leaking septic-conveyance systems, regulated and unregulated discharges, and combined sewage overflows, among other sources. Many of these compounds are toxic at elevated concentrations and (or) known to have endocrine-disrupting potential, and often they occur as complex mixtures. There is still much to be learned about the chronic exposure effects of these compounds on aquatic populations. During 2006–9, the U.S. Geological Survey, in cooperation with the Milwaukee Metropolitan Sewerage District (MMSD), conducted a study to determine the occurrence and potential toxicity of OWCs in different stream compartments and flow regimes for streams in the Milwaukee area. Samples were collected at 17 sites and analyzed for a suite of 69 OWCs. Three types of stream compartments were represented: water column, streambed pore water, and streambed sediment. Water-column samples were subdivided by flow regime into stormflow and base-flow samples. One or more compounds were detected in all 196 samples collected, and 64 of the 69 compounds were detected at least once. Base-flow samples had the lowest detection rates, with a median of 12 compounds detected per sample. Median detection rates for stormflow, pore-water, and sediment samples were more than double that of base-flow samples. Compounds with the highest detection rates include polycyclic aromatic hydrocarbons (PAHs), insecticides, herbicides, and dyes/pigments. Elevated occurrence and concentrations of some compounds were detected in samples from urban sites, as compared with more rural sites, especially during stormflow conditions. These include the PAHs and the domestic waste-water-indicator compounds, among others. Urban runoff and storm-related leaks of sanitary sewers and (or) septic systems may be important sources of these and other compounds to the streams. The Kinnickinnic River, a highly urbanized site, had the highest detection rates and concentrations of compounds of all the sampled sites. The Milwaukee River near Cedarburg—one of the least urban sites—and the Outer Milwaukee Harbor site had the lowest detection rates and concentrations. Aquatic-toxicity benchmarks were exceeded for 12 of the 25 compounds with known benchmarks. The compounds with the greatest benchmark exceedances were the PAHs, both in terms of exceedance frequency (up to 93 percent for some compounds in sediment samples) and magnitude (concentrations up to 1,024 times greater than the benchmark value). Other compounds with toxicity-benchmark exceedances include Bis(2-ethylhexyl) phthalate (a plasticizer), 2-Methylnapthalene (a component of fuel and oil), phenol (an antimicrobial disinfectant with diverse uses), and 4-Nonylphenol (sum of all isomers; a detergent metabolite, among other uses). Analyzed as a mixture, the suite of PAH compounds were found to be potentially toxic for most non-base-flow samples. Bioassay tests were conducted on samples from 14 streams: Ceriodaphnia dubia in base-flow samples, Ceriodaphnia dubia and Hyallela azteca in pore-water samples, and Hyallela azteca and Chironomus tentans in sediment samples. The greatest adverse effect was observed in tests with Chironomus tentans from sediment samples. The weight of Chironomus tentans after exposure to sediments decreased with increased OWC concentrations. This was most evident in the relation between PAH results and Chironomus tentans bioassay results for the majority of samples; however, solvents and flame retardants appeared to be important for one site each. These results for PAHs were consistent with assessment of PAH potency factors for sediment, indicating that PAHs were likely to have adverse effects on aquatic organisms in many of the streams studied.

Wisconsin↗

Relations between pesticide use and riverine flux in the Mississippi River Basin

In an intensive subcontimental study of pesticides in surface waters of the United States, concentrations of 26 high-use pesticides were measured at nine sites in the Mississippi River basin from May 1991 through March 1992. Calculated total fluxes were combined with agricultural-use data to estimate the percentage of applied pesticide reaching the mouths of the Mississippi River and six major tributaries. For most pesticides, the riverine flux was less than 2% of the mass applied agriculturally. The insecticide diazinon was detected frequently in rivers draining the three basins with the highest population densities, apparently as a result of urban use.

Mississippi River basin↗

Organic Compounds in Running Gutter Brook Water Used for Public Supply near Hatfield, Massachusetts, 2003-05

The 258 organic compounds studied in this U.S. Geological Survey (USGS) assessment generally are man-made, including pesticides, solvents, gasoline hydrocarbons, personal-care and domestic-use products, and pavement and combustion-derived compounds. Of these 258 compounds, 26 (about 10 percent) were detected at least once among the 31 samples collected approximately monthly during 2003-05 at the intake of a flowthrough reservoir on Running Gutter Brook in Massachusetts, one of several community water systems on tributaries of the Connecticut River. About 81 percent of the watershed is forested, 14 percent is agricultural land, and 5 percent is urban land. In most source-water samples collected at Running Gutter Brook, fewer compounds were detected and their concentrations were low (less than 0.1 micrograms per liter) when compared with compounds detected at other stream sites across the country that drain watersheds that have a larger percentage of agricultural and urban areas. The relatively few compounds detected at low concentrations reflect the largely undeveloped land use at Running Gutter Brook. Despite the absence of wastewater discharge points on the stream, however, the compounds that were detected could indicate different sources and uses (point sources, precipitation, domestic, and agricultural) and different pathways to drinking-water supplies (overland runoff, groundwater discharge, leaking of treated water from distribution lines, and formation during treatment). Six of the 10 compounds detected most commonly (in at least 20 percent of the samples) in source water also were detected commonly in finished water (after treatment but prior to distribution). Concentrations in source and finished water generally were below 0.1 micrograms per liter and always less than humanhealth benchmarks, which are available for about one-half of the compounds detected. On the basis of this screening-level assessment, adverse effects to human health are expected to be negligible (subject to limitations of available humanhealth benchmarks).

Fact Sheet↗

Nutrient concentrations and loads in the northeastern United States - Status and trends, 1975-2003

The U.S. Geological Survey (USGS) National Water-Quality Assessment Program (NAWQA) began regional studies in 2003 to synthesize information on nutrient concentrations, trends, stream loads, and sources. In the northeastern United States, a study area that extends from Maine to central Virginia, nutrient data were evaluated for 130 USGS water-quality monitoring stations. Nutrient data were analyzed for trends in flow-adjusted concentrations, modeled instream (non-flow-adjusted) concentrations, and stream loads for 32 stations with 22 to 29 years of water-quality and daily mean streamflow record during 1975-2003 (termed the long-term period), and for 46 stations during 1993-2003 (termed the recent period), by using a coupled statistical model of streamflow and water quality developed by the USGS. Recent trends in flow-adjusted concentrations of one or more nutrients also were analyzed for 90 stations by using Tobit regression. Annual stream nutrient loads were estimated, and annual nutrient yields were calculated, for 47 stations for the long-term and recent periods, and for 37 additional stations that did not have a complete streamflow and water-quality record for 1993-2003. Nutrient yield information was incorporated for 9 drainage basins evaluated in a national NAWQA study, for a total of 93 stations evaluated for nutrient yields. Long-term downward trends in flow-adjusted concentrations of total nitrogen and total phosphorus (18 and 19 of 32 stations, respectively) indicate regional improvements in nutrient-related water-quality conditions. Most of the recent trends detected for total phosphorus were upward (17 of 83 stations), indicating possible reversals to the long-term improvements. Concentrations of nutrients in many streams persist at levels that are likely to affect aquatic habitat adversely and promote freshwater or coastal eutrophication. Recent trends for modeled instream concentrations, and modeled reference concentrations, were evaluated relative to ecoregion-based nutrient criteria proposed by the U.S. Environmental Protection Agency. Instream concentrations of total nitrogen and total phosphorus persist at levels higher than proposed criteria at more than one-third and about one-half, respectively, of the 46 stations analyzed. Long-term trends in nutrient loads were primarily downward, with downward trends in total nitrogen and total phosphorus loads detected at 12 and 17 of 32 stations, respectively. Upward trends were rare, with one upward trend for total nitrogen loads and none for total phosphorus. Trends in loads of nitrite-plus-nitrate nitrogen included 7 upward and 8 downward trends among 32 stations. Downward trends in loads of ammonia nitrogen and total Kjeldahl nitrogen were detected at all six stations evaluated. Long-term downward trends detected in four of the five largest drainage basins evaluated include: total nitrogen loads for the Connecticut, Delaware, and James Rivers; total Kjeldahl nitrogen and ammonia nitrogen loads for the Susquehanna River; ammonia nitrogen and nitrite-plus-nitrate nitrogen loads for the James River; and total phosphorus loads for the Connecticut and Delaware Rivers. No trends in load were detected for the Potomac River. Nutrient yields were evaluated relative to the extent of land development in 93 drainage basins. The undeveloped land-use category included forested drainage basins with undeveloped land ranging from 75 to 100 percent of basin area. Median total nitrogen yields for the 27 undeveloped drainage basins evaluated, including 9 basins evaluated in a national NAWQA study, ranged from 290 to 4,800 pounds per square mile per year (lb/mi 2 /yr). Total nitrogen yields even in the most pristine drainage basins may be elevated relative to natural conditions, because of high rates of atmospheric deposition of nitrogen in parts of the northeastern United States. Median total phosphorus yields ranged from 12 to 330 lb/mi 2 /yr for the 26 undeveloped basins evaluated. The undeveloped category includes some large drainage basins with point-source discharges and small percentages of developed land; in these basins, streamflow from undeveloped headwater areas dilutes streamflow in more urbanized reaches, and dampens but does not eliminate the point-source "signal" of higher nutrient loads. Median total nitrogen yields generally do not exceed 1,700 lb/mi 2 /yr, and median total phosphorus yields generally do not exceed 100 lb/mi 2 /yr, in the drainage basins that are least affected by human land-use and waste-disposal practices. Agricultural and urban land use has increased nutrient yields substantially relative to undeveloped drainage basins. Median total nitrogen yields for 24 agricultural basins ranged from 1,700 to 26,000 lb/mi 2 /yr, and median total phosphorus yields ranged from 94 to 1,000 lb/mi 2 /yr. The maximum estimated total nitrogen and total phosphorus yields, 32,000 and 16,000 lb/mi 2 /yr, respectively, for all stations in the region were in small (less than 50 square miles (mi 2 )) agricultural drainage basins. Median total nitrogen yields ranged from 1,400 to 17,000 lb/mi 2 /yr in 26 urbanized drainage basins, and median total phosphorus yields ranged from 43 to 1,900 lb/mi 2 /yr. Urbanized drainage basins with the highest nutrient yields are generally small (less than 300 mi2) and are drained by streams that receive major point-source discharges. Instream nutrient loads were evaluated relative to loads from point-source discharges in four drainage basins: the Quinebaug River Basin in Connecticut, Massachusetts, and Rhode Island; the Raritan River Basin in New Jersey; the Patuxent River Basin in Maryland; and the James River Basin in Virginia. Long-term downward trends in nutrient loads, coupled with similar trends in flow-adjusted nutrient concentrations, indicate long-term reductions in the delivery of most nutrients to these streams. However, the absence of recent downward trends in load for most nutrients, coupled with instream concentrations that exceed proposed nutrient criteria in several of these waste-receiving streams, indicates that challenges remain in reducing delivery of nutrients to streams from point sources. During dry years, the total nutrient load from point sources in some of the drainage basins approached or equaled the nutrient load transported by the stream.

Connecticut;Delaware;Maine;Maryl;Massachusetts;New↗

Lead exposure of red-shouldered hawks during the breeding season in the central Appalachians, USA

Lead is toxic to humans and wildlife. Most studies of lead exposure of raptors focus on the winter, non-breeding season when they scavenge heavily. We evaluated blood lead concentrations (BLCs) of red-shouldered hawks (Buteo lineatus) during the non-scavenging season in the eastern United States. BLCs of 53 of 70 hawks were above the limit of detection ( x¯ = 9.25 µg/dL ± 19.81; ± SD). Adult hawks had higher BLCs ( x¯ = 12.86 µg/dL ± 24.72) than did nestlings ( x¯ = 3.25 µg/dL ± 2.62; p ≤ 0.001, χ2 = 13.2). There was no difference in BLCs of adult hawks among physiographic provinces but there were differences between urban and non-urban settings (p = 0.04, χ2 = 4.2). Soils and invertebrate hawk prey also had quantifiable lead concentrations. Our work shows that red-shouldered hawks are exposed to lead when not scavenging, and suggests pathways by which these birds may be exposed.

Central Appalachians↗

Trophic structure and avian communities across a salinity gradient in evaporation ponds of the San Francisco Bay estuary

Commercial salt evaporation ponds comprise a large proportion of baylands adjacent to the San Francisco Bay, a highly urbanized estuary. In the past two centuries, more than 79% of the historic tidal wetlands in this estuary have been lost. Resource management agencies have acquired more than 10 000 ha of commercial salt ponds with plans to undertake one of the largest wetland restoration projects in North America. However, these plans have created debate about the ecological importance of salt ponds for migratory bird communities in western North America. Salt ponds are unique mesohaline (5–18 g l −1 ) to hyperhaline (> 40 g l −1 ) wetlands, but little is known of their ecological structure or value. Thus, we studied decommissioned salt ponds in the North Bay of the San Francisco Bay estuary from January 1999 through November 2001. We measured water quality parameters (salinity, DO, pH, temperature), nutrient concentrations, primary productivity, zooplankton, macroinvertebrates, fish, and birds across a range of salinities from 24 to 264 g l −1 . Our studies documented how unique limnological characteristics of salt ponds were related to nutrient levels, primary productivity rates, invertebrate biomass and taxa richness, prey fish, and avian predator numbers. Salt ponds were shown to have unique trophic and physical attributes that supported large numbers of migratory birds. Therefore, managers should carefully weigh the benefits of increasing habitat for native tidal marsh species with the costs of losing these unique hypersaline systems.

California↗

Cr(VI) occurrence and geochemistry in water from public-supply wells in California

Hexavalent chromium, Cr(VI), in 918 wells sampled throughout California between 2004 and 2012 by the Groundwater Ambient Monitoring and Assessment-Priority Basin Project (GAMA-PBP) ranged from less than the study reporting limit of 1 microgram per liter (μg/L) to 32 μg/L. Statewide, Cr(VI) was reported in 31 percent of wells and equaled or exceeded the recently established (2014) California Maximum Contaminant Level (MCL) for Cr(VI) of 10 μg/L in 4 percent of wells. Cr(VI) data collected for regulatory purposes overestimated Cr(VI) occurrence compared to spatially-distributed GAMA-PBP data. Ninety percent of chromium was present as Cr(VI), which was detected more frequently and at higher concentrations in alkaline (pH ≥ 8), oxic water; and more frequently in agricultural and urban land uses compared to native land uses. Chemical, isotopic (tritium and carbon-14), and noble-gas data show high Cr(VI) in water from wells in alluvial aquifers in the southern California deserts result from long groundwater-residence times and geochemical reactions such as silicate weathering that increase pH, while oxic conditions persist. High Cr(VI) in water from wells in alluvial aquifers along the west-side of the Central Valley results from high-chromium in source rock eroded to form those aquifers, and areal recharge processes (including irrigation return) that can mobilize chromium from the unsaturated zone. Cr(VI) co-occurred with oxyanions having similar chemistry, including vanadium, selenium, and uranium. Cr(VI) was positively correlated with nitrate, consistent with increased concentrations in areas of agricultural land use and mobilization of chromium from the unsaturated zone by irrigation return.

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