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At least 1,693 records · Page 94Linked to original sources
USGS2007

Occurrence of radium-224, radium-226 and radium-228 in water from the Vincentown and Wenonah-Mount Laurel aquifers, the Englishtown aquifer system, and the Hornerstown and Red Bank Sands, southwestern and south-central New Jersey

This investigation is the first regionally focused study of the presence of natural radioactivity in water from the Vincentown and Wenonah-Mount Laurel aquifers, Englishtown aquifer system, and the Hornerstown and Red Bank Sands. Geologic materials composing the Vincentown and Wenonah-Mount Laurel aquifers and the Hornerstown and Red Bank Sands previously have been reported to contain radioactive (uranium-enriched) phosphatic strata, which is common in deposits from some moderate-depth coastal marine environments. The decay of uranium and thorium gives rise to natural radioactivity and numerous radioactive progeny, including isotopes of radium. Naturally occurring radioactive isotopes, especially those of radium, are of concern because radium is a known human carcinogen and ingestion (especially in water used for drinking) can present appreciable health risks. A regional network in southwestern and south-central New Jersey of 39 wells completed in the Vincentown and Wenonah-Mount Laurel aquifers, the Englishtown aquifer system, and the Hornerstown and Red Bank Sands was sampled for determination of gross alpha-particle activity; concentrations of radium radionuclides, major ions, and selected trace elements; and physical properties. Concentrations of radium-224, radium-226, and radium-228 were determined for water from 28 of the 39 wells, whereas gross alpha-particle activity was determined for all 39. The alpha spectroscopic technique was used to determine concentrations of radium-224, which ranged from less than 0.5 to 2.7 pCi/L with a median concentration of less than 0.5pCi/L, and of radium-226, which ranged from less than 0.5 to 3.2 pCi/L with a median concentration of less than 0.5 pCi/L. The beta-counting technique was used to determine concentrations of radium-228. The concentration of radium-228 ranged from less than 0.5 to 4.3 pCi/L with a median of less than 0.5. Radium-228, when quantifiable, had the greatest concentration of the three radium radioisotopes in 9 of the 12 samples (75 percent). The concentration of radium-224 exceeded that of radium-226 in five of the six (83 percent) samples when both were quantifiable. The radium concentration distribution differed by aquifer, with the highest Ra-228 concentrations present in the Englishtown aquifer system and the highest Ra-226 concentrations present in the Wenonah-Mount Laurel aquifer. Radium-224 generally contributed a considerable amount of gross alpha-particle activity to water produced from all the sampled aquifers, but was not the dominant radionuclide as it is in water from the Kirkwood-Cohansey aquifer system, nor were concentrations greater than 1 pCi/L of radium-224 widespread. Gross alpha-particle activity was found to exceed the U.S Environmental Protection Agency (USEPA) Maximum Contaminant Level (MCL) of 15 pCi/L in one sample (16 pCi/L) from the Vincentown aquifer. A greater part of the gross alpha-particle activity in water from the Wenonah-Mount Laurel aquifer resulted from the decay of Ra-226 than did the gross alpha-particle activity in the other sampled aquifers; this relation is consistent with the concentration distribution of the Ra-226 itself. Concentrations of radium-224 correlate strongly with those of both radium-226 and radium-228 (Spearman correlation coefficients, r, +0.86 and +0.66, respectively). The greatest concentrations of radium-224, radium-226, and radium-228 were present in the most acidic ground water. All radium-224, radium-226, and radium-228 concentrations greater than 2.5 pCi/L were present in ground-water samples with a pH less than 5.0. The presence of combined radium-226 and radium-228 concentrations greater than 5 pCi/L in samples from the Vincentown and Wenonah-Mount Laurel aquifers and the Englishtown aquifer system was not nearly as common as in samples from the Kirkwood-Cohansey aquifer system, likely because of the slightly higher pH of water from these aquifers relative to that of Kirkwood-Cohansey aqu

New Jersey↗
USGS2004

Sediment quality in the north coastal basin of Massachusetts, 2003

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, completed a reconnaissance-level study of bottom-sediment quality in selected lakes, rivers, and estuaries in the North Coastal Basin of Massachusetts. Bottom-sediment grab samples were collected from 20 sites in the North River, Lake Quannapowitt, Saugus River, Mill River, Shute Brook, Sea Plane Basin, Pines River, and Bear Creek. The samples were tested for various types of potentially harmful contaminants? including 33 elements, 17 polyaromatic hydrocarbons (PAHs), 22 organochlorine pesticides, and 7 polychlorinated biphenyl (PCB) mixtures (Aroclors)?to benthic organisms (bottom-dwelling) and humans. The results were compared among sampling sites, to background concentrations, and to concen-trations measured in other urban rivers, and sediment-quality guidelines were used to predict toxicity at the sampling sites to benthic organisms and humans. Because there are no standards for human toxicity for aquatic sediment, standards for contaminated upland soil were used. Contaminant concentrations measured in sediment collected from the North Coastal Basin generally were equal to or greater than concentrations in sediment from uncontaminated rivers throughout New England. Contaminants in North Coastal Basin sediment with elevated concentrations (above back-ground levels) included arsenic, chromium, copper, lead, nickel, and zinc, some of the PAHs, dichlorodiphenyltrichloro-ethane (DDT) and its metabolites, and dieldrin. No PCBs were measured above the detection limits. Measured concentrations of arsenic, chromium, and lead were also generally greater than those measured in other urban rivers throughout the conter-minous United States. With one exception (arsenic), local con-centrations measured in sediment samples collected from the North Coastal Basin were lower than concentrations measured in sediment collected from two of three urban rivers draining to Boston Harbor. The probable toxicity to benthic organisms ranged from about 33 to 91 percent across the study area. Of the elements analyzed, antimony, arsenic, beryllium, and lead exceeded the soil standards for risk to human health. Of the PAHs analyzed, four also exceeded soil standards. Organochlorine pesticide concentrations, however, were not high enough relative to the soil standards to pose a risk to human health. Some trace element and some organic compound concentrations in bottom sediment may be toxic to aquatic organisms and may pose a risk to human health.

Scientific Investigations Report↗
USGS2024

Prioritizing river basins for nutrient studies

Increases in fluxes of nitrogen (N) and phosphorus (P) in the environment have led to negative impacts affecting drinking water, eutrophication, harmful algal blooms, climate change, and biodiversity loss. Because of the importance, scale, and complexity of these issues, it may be useful to consider methods for prioritizing nutrient research in representative drainage basins within a regional or national context. Two systematic, quantitative approaches were developed to (1) identify basins that geospatial data suggest are most impacted by nutrients and (2) identify basins that have the most variability in factors affecting nutrient sources and transport in order to prioritize basins for studies that seek to understand the key drivers of nutrient impacts. The “impact” approach relied on geospatial variables representing surface-water and groundwater nutrient concentrations, sources of N and P, and potential impacts on receptors (i.e., ecosystems and human health). The “variability” approach relied on geospatial variables representing surface-water nutrient concentrations, factors affecting sources and transport of nutrients, model accuracy, and potential receptor impacts. One hundred and sixty-three drainage basins throughout the contiguous United States were ranked nationally and within 18 hydrologic regions. Nationally, the top-ranked basins from the impact approach were concentrated in the Midwest, while those from the variability approach were dispersed across the nation. Regionally, the top-ranked basin selected by the two approaches differed in 15 of the 18 regions, with top-ranked basins selected by the variability approach having lower minimum concentrations and larger ranges in concentrations than top-ranked basins selected by the impact approach. The highest ranked basins identified using the variability approach may have advantages for exploring how landscape factors affect surface-water quality and how surface-water quality may affect ecosystems. In contrast, the impact approach prioritized basins in terms of human development and nutrient concentrations in both surface water and groundwater, thereby targeting areas where actions to reduce nutrient concentrations could have the largest effect on improving water availability and reducing ecosystem impacts.

Environmental Monitoring and Assessment↗
USGS1996

Detailed study of selenium and other constituents in water, bottom sediment, soil, alfalfa, and biota associated with irrigation drainage in the Uncompahgre Project area and in the Grand Valley, west-central Colorado, 1991-93

In 1985, the U.S. Department of the Interior began a program to study the effects of irrigation drainage in the Western United States. These studies were done to determine whether irrigation drainage was causing problems related to human health, water quality, and fish and wildlife resources. Results of a study in 1991-93 of irrigation drainage associated with the Uncompahgre Project area, located in the lower Gunnison River Basin, and of the Grand Valley, located along the Colorado River, are described in this report. The focus of the report is on the sources, distribution, movement, and fate of selenium in the hydrologic and biological systems and the effects on biota. Generally, other trace- constituent concentrations in water and biota were not elevated or were not at levels of concern. Soils in the Uncompahgre Project area that primarily were derived from Mancos Shale contained the highest concentrations of total and watrer-extractable selenium. Only 5 of 128 alfalfa samples had selenium concentrations that exceeded a recommended dietary limit for livestock. Selenium data for soil and alfalfa indicate that irrigation might be mobilizing and redistributing selenium in the Uncompahgre Project area. Distribution of dissolved selenium in ground water is affected by the aqueous geochemical environment of the shallow ground- water system. Selenium concentrations were as high as 1,300 micrograms per liter in water from shallow wells. The highest concentrations of dissolved selenium were in water from wells completed in alluvium overlying the Mancos Shale of Cretaceous age; selenium concentrations were lower in water from wells completed in Mancos Shale residuum. Selenium in the study area could be mobilized by oxidation of reduced selenium, desorption from aquifer sediments, ion exchange, and dissolution. Infiltration of irrigation water and, perhaps nitrate, provide oxidizing conditions for mobilization of selenium from alluvium and shale residuum and for transport to streams and irrigation drains that are tributary to the Gunnison, Uncompahgre, and Colorado Rivers. Selenium concentrations in about 64 percent of water samples collected from the lower Gunnison River and about 50 percent of samples from the Colorado River near the Colorado-Utah State line exceeded the U.S. Environmental Protection Agency criterion of 5 micrograms per liter for protection of aquatic life. Almost all selenium concentrations in samples collected during the nonirrigation season from Mancos Shale areas exceeded the aquatic-life criterion. The maximum selenium concentrations in surface-water samples were 600 micrograms per liter in the Uncompahgre Project area and 380 micrograms per liter in the Grand Valley. Irrigation drainage from the Uncompahgre Project and the Grand Valley might account for as much as 75 percent of the selenium load in the Colorado River near the Colorado-Utah State line. The primary source areas of selenium were the eastern side of the Uncompahgre Project and the western one-half of the Grand Valley, where there is extensive irrigation on soils derived from Mancos Shale. The largest mean selenium loads from tributary drainages were 14.0 pounds per day from Loutsenhizer Arroyo in the Uncompahgre Project and 12.8 pounds per day from Reed Wash in the Grand Valley. Positive correlations between selenium loads and dissolved-solids loads could indicate that salinity-control projects designed to decrease dissolved-solids loads also could decrease selenium loads from the irrigated areas. Selenium concentrations in irrigation drainage in the Grand Valley were much higher than concentrations predicted by simple evaporative concentration of irrigation source water. Selenium probably is removed from pond water by chemical and biological processes and incorporated into bottom sediment. The maximum selenium concentration in bottom sediment was 47 micrograms per gram from a pond on the eastern side of the Uncompahgre Project.

Water-Resources Investigations Report↗
USGS2010

The quality of our Nation’s waters: Quality of water from public-supply wells in the United States, 1993–2007: Overview of major findings

Summary of Major Findings and Implications About 105 million people in the United States-more than one-third of the Nation's population-receive their drinking water from about 140,000 public water systems that use groundwater as their source. Although the quality of finished drinking water (after treatment and before distribution) from these public water systems is regulated by the U.S. Environmental Protection Agency (USEPA) under the Safe Drinking Water Act (SDWA), long-term protection and management of groundwater, a vital source of drinking water, requires an understanding of the occurrence of contaminants in untreated source water. Sources of drinking water are potentially vulnerable to a wide range of man-made and naturally occurring contaminants, including many that are not regulated in drinking water under the SDWA. In this study by the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey (USGS), chemical water-quality conditions were assessed in source (untreated) groundwater from 932 public-supply wells, hereafter referred to as public wells, and in source and finished water from a subset of 94 wells. The public wells are located in selected parts of 41 states and withdraw water from parts of 30 regionally extensive water-supply aquifers, which constitute about one-half of the principal aquifers in the United States. Although the wells sampled in this study represent less than 1 percent of all groundwater-supplied public water systems in the United States, they are widely distributed nationally and were randomly selected within the sampled hydrogeologic settings to represent typical aquifer conditions. All source-water samples were collected prior to any treatment or blending that potentially could alter contaminant concentrations. As a result, the sampled groundwater represents the quality of the source water and not necessarily the quality of finished water ingested by the people served by these public wells. A greater number of chemical contaminants-as many as 337-both naturally occurring and man-made, were assessed in this study than in any previous national study of public wells (Appendixes 1 and 2). Consistent with the terminology used in the SDWA, all constituents analyzed in water samples in this study are referred to as 'contaminants,' regardless of their source, concentration, or potential for health effects (see sidebar on page 3). Eighty-three percent (279) of the contaminants analyzed in this study are not regulated in drinking water under the SDWA. The USEPA uses USGS data on the occurrence of unregulated contaminants to fulfill part of the SDWA requirements for determining whether specific contaminants should be regulated in drinking water in the future. By focusing primarily on source-water quality, and by analyzing many contaminants that are not regulated in drinking water by USEPA, this study complements the extensive sampling of public water systems that is routinely conducted for the purposes of regulatory compliance monitoring by federal, state, and local drinking-water programs. The objectives of this study were to evaluate (1) the occurrence of contaminants in source water from public wells and their potential significance to human health, (2) whether contaminants that occur in source water also occur in finished water after treatment, and (3) the occurrence and characteristics of contaminant mixtures. To evaluate the potential significance of contaminant occurrence to human health, contaminant concentrations were compared to regulatory Maximum Contaminant Levels (MCLs) or non-regulatory Health-Based Screening Levels (HBSLs)-collectively referred to as human-health benchmarks in this study (see sidebars on pages 4 and 19). The major findings and implications of this study are summarized below and the results are described in greater detail in the remainder of the report. These findings build upon water-quality data from previous public-well studies and

Circular↗
USGS2018

Common hydraulic fracturing fluid additives alter the structure and function of anaerobic microbial communities

The development of unconventional oil and gas (UOG) resources results in the production of large volumes of wastewater containing a complex mixture of hydraulic fracturing chemical additives and components from the formation. The release of these wastewaters into the environment poses potential risks that are poorly understood. Microbial communities in stream sediments form the base of the food chain and may serve as sentinels for changes in stream health. Iron-reducing organisms have been shown to play a role in the biodegradation of a wide range of organic compounds, and so to evaluate their response to UOG wastewater, we enriched anaerobic microbial communities from sediments collected upstream (background) and downstream (impacted) of an UOG wastewater injection disposal facility in the presence of hydraulic fracturing fluid (HFF) additives: guar gum, ethylene glycol, and two biocides, 2,2-dibromo-3-nitrilopropionamide (DBNPA) and bronopol (C 3 H 6 BrNO 4 ). Iron reduction was significantly inhibited early in the incubations with the addition of biocides, whereas amendment with guar gum and ethylene glycol stimulated iron reduction relative to levels in the unamended controls. Changes in the microbial community structure were observed across all treatments, indicating the potential for even small amounts of UOG wastewater components to influence natural microbial processes. The microbial community structure differed between enrichments with background and impacted sediments, suggesting that impacted sediments may have been preconditioned by exposure to wastewater. These experiments demonstrated the potential for biocides to significantly decrease iron reduction rates immediately following a spill and demonstrated how microbial communities previously exposed to UOG wastewater may be more resilient to additional spills.

Applied and Environmental Microbiology↗
USGS2022

The thermal landscape of the Willamette River—Patterns and controls on stream temperature and implications for flow management and cold-water salmonids

Water temperature is a primary control on the health, diversity, abundance, and distribution of aquatic species, but thermal degradation resulting from anthropogenic influences on rivers is a challenge to threatened species worldwide. In the Willamette River Basin, northwestern Oregon, spring-run Chinook salmon ( Oncorhynchus tshawytscha ) and winter-run steelhead ( O. mykiss ) are formerly abundant cold-water-adapted species that are now protected under the Endangered Species Act. Among the challenges to the health of cold-water salmonids in the Willamette River Basin, disruptions in the seasonal patterns of stream temperature imposed by 13 large, multipurpose dams on tributaries to the Willamette River, as well as temperatures routinely in excess of regulatory limits in the Willamette River Basin, are contributing factors. To better understand controls on stream temperature, the sensitivity of stream temperature to flow augmentation as a management tool for suppressing high temperatures, and the implications for threatened salmonids, this study used a two-dimensional hydrodynamic and water-quality model (CE-QUAL-W2) to investigate spatial and temporal patterns of stream temperature in the Willamette River Basin. This study focused on the upper 160.4 river miles of the Willamette River from the confluence of the Middle Fork and Coast Fork Willamette Rivers (river mile 187.2) to Willamette Falls (river mile 26.8), three representative climate years (2011, a cool and wet year; 2015, an extremely hot and dry year; and 2016, a moderately hot and dry year), and a series of flow-augmentation scenarios. Model results show that the Willamette River upstream from Willamette Falls is divisible into four characteristic “thermal reaches” with similar thermal patterns, depending on tributary input, warming rate, and the timing of thermal response. In general, the Willamette River warms downstream during spring and summer, but patterns are complex, influenced by tributary inflows, and seasonally variable. Except in cool wet years (as illustrated by 2011), modeling suggests that adversely warm conditions for spring-run Chinook salmon are extensive from June or July through August. The thermal influence of flow augmentation from dam storage on four tributaries with U.S. Army Corps of Engineers dams varies spatially along the Willamette River, seasonally, and in magnitude, depending on a range of factors like distance from the Willamette River, the temperature of dam outflow, and the thermal template of tributary reaches controlling stream temperature adjustment to environmental heat fluxes. Modeling suggests that targeted flow management (via augmentation from dam storage) can reduce the extent and duration of thermally stressful conditions for Chinook salmon for short periods, but modeling suggests that flow augmentation is limited in its ability to fundamentally alter the “thermal landscape” (the entire range of temperature variation in a river system over space and time) of the Willamette River. While this research provides general insights into the thermal landscape of the Willamette River and its sensitivity to flow management, additional investigation into the thermal landscape of tributaries downstream from U.S. Army Corps of Engineers dams, as well as the thermal management of reservoirs, storage availability, and dam outflows, would be necessary to target specific management actions for supporting specified rearing or migration conditions for spring-run Chinook salmon and other cold-water-adapted species in the Willamette River Basin.

Oregon↗
USGS2025

Avian influenza spillover into poultry: Environmental influences and biosecurity protections

With the continued spread of highly pathogenic avian influenza (HPAI), understanding the complex dynamics of virus transfer at the wild – agriculture interface is paramount. Spillover events (i.e., virus transfer from wild birds into poultry) are related to proximity to infected wild bird populations and environmental conditions. By accounting for such dynamics, we can take a combined approach to assess the impacts of biosecurity measures implemented at poultry farms while simultaneously accounting for their local risk levels. We implemented a Bayesian joint-likelihood logistic regression for the Continental U.S. comparing models of spatiotemporal risk according to land use, weather, and predicted waterfowl distributions followed by integrating a farm-level case-control questionnaire dataset focused on identifying trends in HPAI spillover risk associated with a farm's biosecurity practices. We found that estimates of waterfowl abundance, along with mean precipitation and temperature during winter, were most correlated with spatiotemporal HPAI risk. Additionally, we identified multiple biosecurity practices associated with reduced risk to HPAI, where the strongest relationships were related to litter decontamination treatments, vehicle wash stations, and avoiding shared dead-bird disposal sites with other farms. This model broadly guides surveillance of HPAI in wild and domestic populations, identifying when and where we are most likely to see increased instances of the virus while also providing insights into how poultry farms can better protect themselves from risk.

contiguous United States↗
USGS2002

Effects of depleted uranium on the health and survival of Ceriodaphnia dubia and Hyalella azteca

Depleted uranium (DU) has been used as a substitute for the fissionable enriched uranium component of atomic weapons tested at Los Alamos National Laboratory (LANL) (Los Alamos, NM, USA) since the early 1950s, resulting in considerable concentrations of DU in the soils within the test sites. Although the movement of DU into major aquatic systems has been shown to be minimal, there are many small-order ephemeral streams and areas of standing water in canyons throughout LANL that may be affected by inputs of DU via runoff, erosion, and leaching. Ninety-six-hour acute and 7-d chronic toxicity assays were conducted to measure the toxicity of DU on survival and reproduction of Ceriodaphnia dubia. A 14-d water-only assay was conducted to measure survival and growth of Hyalella azteca. The estimated median lethal concentration (LC50) to produce 50% mortality of the test population for the 96-h Ceriodaphnia dubia assay was 10.50 mg/L. Reproductive effects occurred at a lowest-observable-effect concentration ≥ 3.91 mg/L with a no-observable-effect concentration of 1.97 mg/L. The estimated 14-d LC50 for the Hyalella azteca assay was 1.52 mg/L No significant relationship was detected between growth and DU concentrations. Concentrations at which toxicity effects were observed in this study for both invertebrates exceeded concentrations of total uranium observed in runoff from LANL lands. Thus, it is likely that current runoff levels of uranium do not pose a threat to these types of aquatic invertebrates.

New Mexico↗
USGS2006

Modeling the transport and inactivation of E. coli and enterococci in the near-shore region of Lake Michigan

To investigate the transport and fate of fecal pollution at Great Lakes beaches and the health risks associated with swimming, the near-shore waters of Lake Michigan and two tributaries discharging into it were examined for bacterial indicators of human fecal pollution. The enterococcus human fecal pollution marker, which targets a putative virulence factor the enterococcal surface protein (esp) in Enterococcus faecium , was detected in 2/28 samples (7%) in the tributaries draining into Lake Michigan and in 6/30 samples (20%) in Lake Michigan beaches. This was indicative of human fecal pollution being transported in the tributaries and occurrence at Lake Michigan beaches. To understand the relative importance of different processes influencing pollution transport and inactivation, a finite-element model of surf-zone hydrodynamics (coupled with models for temperature, E. coli and enterococci) was used. Enterococci appear to survive longer than E. coli , which was described using an overall first-order inactivation coefficient in the range 0.5−2.0 per day. Our analysis suggests that the majority of fecal indicator bacteria variation can be explained based on loadings from the tributaries. Sunlight is a major contributor to inactivation in the surf-zone and the formulation based on sunlight, temperature and sedimentation is preferred over the first-order inactivation formulation.

Environmental Science & Technology↗
USGS2025

Tapwater exposures, residential risk, and mitigation in a PFAS-impacted-groundwater community

Tapwater (TW) safety and sustainability are priorities in the United States. Per/polyfluoroalkyl substance(s) (PFAS) contamination is a growing public-health concern due to prolific use, widespread TW exposures, and mounting human-health concerns. Historically-rural, actively-urbanizing communities that rely on surficial-aquifer private wells incur elevated risks of unrecognized TW exposures, including PFAS, due to limited private-well monitoring and contaminant-source proliferation in urbanizing landscapes. Here, a broad-analytical-scope TW-assessment was conducted in a hydrologically-vulnerable, Mississippi River alluvial-island community, where PFAS contamination of the shallow-alluvial drinking-water aquifer has been documented, but more comprehensive contaminant characterization to inform decision-making is currently lacking. In 2021, we analyzed 510 organics, 34 inorganics, and 3 microbial groups in 11 residential and community locations to assess (1) TW risks beyond recognized PFAS issues, (2) day-to-day and year-to-year risk variability, and (3) suitability of the underlying sandstone aquifer as an alternative source to mitigate TW-PFAS exposures. Seventy-six organics and 25 inorganics were detected. Potential human-health risks of detected TW exposures were explored based on cumulative benchmark-based toxicity quotients ( ∑ TQ ). Elevated risks ( ∑ TQ ≥ 1) from organic and inorganic contaminants were observed in all alluvial-aquifer-sourced synoptic samples but not in sandstone-aquifer-sourced samples. Repeated sampling at 3 sites over 52–55 h indicated limited variability in risk over the short-term. Comparable PFAS-specific ∑ TQ for spatial-synoptic, short-term (3 days) temporal, and long-term (3 years quarterly) temporal samples indicated that synoptic results provided useful insight into the risks of TW-PFAS exposures at French Island over the long-term. No PFAS detections in sandstone-aquifer-sourced samples over a 3 year period indicated no PFAS-associated risk and supported the sandstone aquifer as an alternative drinking-water source to mitigate community TW-PFAS exposures. This study illustrated the importance of expanded contaminant monitoring of private-well TW, beyond known concerns (in this case, PFAS), to reduce the risks of a range of unrecognized contaminant exposures.

Wisconsin↗
USGS2012

Willamette Valley Ecoregion: Chapter 3 in Status and trends of land change in the Western United States--1973 to 2000

The Willamette Valley Ecoregion (as defined by Omernik, 1987; U.S. Environmental Protection Agency, 1997) covers approximately 14,458 km² (5,582 mi 2 ), making it one of the smallest ecoregions in the conterminous United States. The long, alluvial Willamette Valley, which stretches north to south more than 193 km and ranges from 32 to 64 km wide, is nestled between the sedimentary and metamorphic Coast Ranges (Coast Range Ecoregion) to the west and the basaltic Cascade Range (Cascades Ecoregion) to the east (fig. 1). The Lewis and Columbia Rivers converge at the ecoregion’s northern boundary in Washington state; however, the majority of the ecoregion falls within northwestern Oregon. Interstate 5 runs the length of the valley to its southern boundary with the Klamath Mountains Ecoregion. Topography here is relatively flat, with elevations ranging from sea level to 122 m. This even terrain, coupled with mild, wet winters, warm, dry summers, and nutrient-rich soil, makes the Willamette Valley the most important agricultural region in Oregon. Population centers are concentrated along the valley floor. According to estimates from the Oregon Department of Fish and Wildlife (2006), over 2.3 million people lived in Willamette Valley in 2000. Portland, Oregon, is the largest city, with 529,121 residents (U.S. Census Bureau, 2000). Other sizable cities include Eugene, Oregon; Salem (Oregon’s state capital); and Vancouver, Washington. Despite the large urban areas dotting the length of the Willamette Valley Ecoregion, agriculture and forestry products are its economic foundation (figs. 2,3). The valley is a major producer of grass seed, ornamental plants, fruits, nuts, vegetables, and grains, as well as poultry, beef, and dairy products. The forestry and logging industries also are primary employers of the valley’s rural residents (Rooney, 2008). These activities have affected the watershed significantly, with forestry and agricultural runoff contributing to river sedimentation and decreased water quality in the Willamette River and its tributary streams (Oregon Department of Fish and Wildlife, 2006). Recent years have seen a marked decline in forest health related to the increased frequency of multiyear droughts. Insect damage and other diseases also are present; however, drought- related water stress is the primary factor in coniferous-tree mortality (Oregon Department of Forestry, 2008). Trees most at risk include Douglas-fir ( Pseudotsuga menziesii ), grand fir ( Abies grandis ), and western red cedar ( Thuja plicata ). Overstocking by timber companies and planting on sites with poor conditions increase susceptibility. Over time, these problems may lead to changes in planting practices and the use of more drought-tolerant species such as ponderosa pine ( Pinus ponderosa ).

Oregon↗
USGS2001

Use of radium isotopes to determine the age and origin of radioactive barite at oil-field production sites

Radium-bearing barite (radiobarite) is a common constituent of scale and sludge deposits that form in oil-field production equipment. The barite forms as a precipitate from radium-bearing, saline formation water that is pumped to the surface along with oil. Radioactivity levels in some oil-field equipment and in soils contaminated by scale and sludge can be sufficiently high to pose a potential health threat. Accurate determinations of radium isotopes (226Ra+228Ra) in soils are required to establish the level of soil contamination and the volume of soil that may exceed regulatory limits for total radium content. In this study the radium isotopic data are used to provide estimates of the age of formation of the radiobarite contaminant. Age estimates require that highly insoluble radiobarite approximates a chemically closed system from the time of its formation. Age estimates are based on the decay of short-lived 228Ra (half-life=5.76 years) compared to 226Ra (half-life=1600 years). Present activity ratios of 228Ra/226Ra in radiobarite-rich scale or highly contaminated soil are compared to initial ratios at the time of radiobarite precipitation. Initial ratios are estimated by measurements of saline water or recent barite precipitates at the site or by considering a range of probable initial ratios based on reported values in modern oil-field brines. At sites that contain two distinct radiobarite sources of different age, the soils containing mixtures of sources can be identified, and mixing proportions quantified using radium concentration and isotopic data. These uses of radium isotope data provide more description of contamination history and can possibly address liability issues. Copyright ?? 2000 .

Environmental Pollution↗
USGS2013

Comparison of filters for concentrating microbial indicators and pathogens in lake-water samples

Bacterial indicators are used to indicate increased health risk from pathogens and to make beach closure and advisory decisions; however, beaches are seldom monitored for the pathogens themselves. Studies of sources and types of pathogens at beaches are needed to improve estimates of swimming-associated health risks. It would be advantageous and cost-effective, especially for studies conducted on a regional scale, to use a method that can simultaneously filter and concentrate all classes of pathogens from the large volumes of water needed to detect pathogens. In seven recovery experiments, stock cultures of viruses and protozoa were seeded into 10-liter lake water samples, and concentrations of naturally occurring bacterial indicators were used to determine recoveries. For the five filtration methods tested, the highest median recoveries were as follows: glass wool for adenovirus (4.7%); NanoCeram for enterovirus (14.5%) and MS2 coliphage (84%); continuous-flow centrifugation (CFC) plus Virocap (CFC+ViroCap) for Escherichia coli (68.3%) and Cryptosporidium (54%); automatic ultrafiltration (UF) for norovirus GII (2.4%); and dead-end UF for Enterococcus faecalis (80.5%), avian influenza virus (0.02%), and Giardia (57%). In evaluating filter performance in terms of both recovery and variability, the automatic UF resulted in the highest recovery while maintaining low variability for all nine microorganisms. The automatic UF was used to demonstrate that filtration can be scaled up to field deployment and the collection of 200-liter lake water samples.

Michigan, New York, Ohio, Wisconsin↗
USGS2009

Reproductive health of bass in the potomac, USA, drainage: Part 2. Seasonal occurrence of persistent and emerging organic contaminants

The seasonal occurrence of organic contaminants, many of which are potential endocrine disruptors, entering the Potomac River, USA, watershed was investigated using a two-pronged approach during the fall of 2005 and spring of 2006. Passive samplers (semipermeable membrane device and polar organic chemical integrative sampler [POCIS]) were deployed in tandem at sites above and below wastewater treatment plant discharges within the watershed. Analysis of the samplers resulted in detection of 84 of 138 targeted chemicals. The agricultural pesticides atrazine and metolachlor had the greatest seasonal changes in water concentrations, with a 3.1 - to 91 -fold increase in the spring compared with the level in the previous fall. Coinciding with the elevated concentrations of atrazine in the spring were increasing concentrations of the atrazine degradation products desethylatrazine and desisopropylatrazine in the fall following spring and summer application of the parent compound. Other targeted chemicals (organochlorine pesticides, polycyclic aromatic hydrocarbons, and organic wastewater chemicals) did not indicate seasonal changes in occurrence or concentration; however, the overall concentrations and number of chemicals present were greater at the sites downstream of wastewater treatment plant discharges. Several fragrances and flame retardants were identified in these downstream sites, which are characteristic of wastewater effluent and human activities. The bioluminescent yeast estrogen screen in vitro assay of the POCIS extracts indicated the presence of chemicals that were capable of producing an estrogenic response at all sampling sites. ?? 2009 SETA.

Environmental Toxicology and Chemistry↗
USGS2013

MODIS phenology image service ArcMap toolbox

Seasonal change is important to consider when managing conservation areas at landscape scales. The study of such patterns throughout the year is referred to as phenology. Recurring life-cycle events that are initiated and driven by environmental factors include animal migration and plant flowering. Phenological events capture public attention, such as fall color change in deciduous forests, the first flowering in spring, and for those with allergies, the start of the pollen season. These events can affect our daily lives, provide clues to help understand and manage ecosystems, and provide evidence of how climate variability can affect the natural cycle of plants and animals. Phenological observations can be gathered at a range of scales, from plots smaller than an acre to landscapes of hundreds to thousands of acres. Linking these observations to diverse disciplines such as evolutionary biology or climate sciences can help further research in species and ecosystem responses to climate change scenarios at appropriate scales. A cooperative study between the National Park Service (NPS), the U.S. Geological Survey (USGS), and the National Aeronautics and Space Administration (NASA) has been exploring how satellite information can be used to summarize phenological patterns observed at the park or landscape scale and how those summaries can be presented to both park managers and visitors. This study specifically addressed seasonal changes in plants, including the onset of growth, photosynthesis in the spring, and the senescence of deciduous vegetation in the fall. The primary objective of the work is to demonstrate that seasonality even in protected areas changes considerably across years. A major challenge is to decouple natural variability from possible trends—directional change that can lead to a permanent and radically different ecosystem state. Trends can be either a gradual degradation of the landscape (often from external influences) or steady improvement (by implementing long-term conservation plans). In either case, it is important to first grasp the magnitude of natural variation so that it is not confused with actual trends. This work used existing and freely available remote sensing data, specifically the NASA-funded 250-meter (m) spatial resolution land-surface phenology product for North America. This product is calculated from an annual record of vegetation health observed by NASA’s Moderate Resolution Imaging Spectroradiometer (MODIS) instrument. The land-surface phenology product is, in essence, a method to summarize all the observations throughout a year into a few key, ecologically relevant “metrics”.

Open-File Report↗
USGS1976

Recycling ground water in Waushara County, Wisconsin : resource management for cold-water fish hatcheries

Recycling water within the local ground-water system can increase the quantity of water available for use, control or avoid environmental pollution, and control temperature of the water supply. Pumped ground water supplied a fish-rearing facility for 15 months, and the waste water recharged the local ground-water system through an infiltration pond. Eighty-three percent of the recharged water returned to the well (recycled). Make-up water from the ground-water system provided the remaining 17 percent. Pumping 300 gallons per minute (20 litres per second), combined with recycling, resulted in water-level declines equivalent to a pumping rate of approximately 50 gallons per minute (3 litres per second). Using this effective pumping rate in the Theis nonequilibrium equation resulted in predicted drawdowns within 0.5 foot (0.2 metres) of those observed throughout the 15-month period. The concentration of nitrate in the water supply increased only slightly during the 15 months of recycling. Nitrate levels in a closed recycling system (100 percent recycling efficiency) would have reached 9 milligrams per litre, but observed levels did not exceed 4 milligrams per litre, and at the end of the recycling period they were lower than the initial levels. Mass-balance equations relate observed nitrate levels to the loading imposed on the system, the pumping rate, the volume of ground water affected by recycling, and the recycling efficiency. The equations predict nitrate concentrations (or other ions not attenuated by movement through the unsaturated part of the aquifer) within 1 milligram per litre of observed concentrations except during periods when nutrients are used in plant growth. The method does not account for nutrients utilized by aquatic vegetation in the infiltration pond, so that observed levels would usually be even lower than predicted. The predicted response of the local groundwater system to a nutrient loading equivalent to that generated by a hatchery producing approximately 100,000 pounds (50,000 kilograms) of trout and salmon per year indicates that maximum nitrate levels would remain significantly below the limit established by the State of Wisconsin (and the U.S. Public Health Service, 1962) for drinking water. The water-supply temperature can be maintained within the optimum range for trout and salmon rearing (10.0° to 15.5°C or 50° to 60°F) during recycling. Continuous recycling during the study period resulted in watersupply temperatures ranging between 7.0° and 14.0°C (45° and 57°F). Longterm continuous recycling would result in water-supply temperatures ranging between 7.0° and 14.5°C (45° and 58°F). Selective recycling (recycling water for only 8 months of the year) would provide water-supply temperatures ranging from 9.5° to 15.5°C (49° to 60°F). A permanent recharge pond with supplementary ponds would fulfill the needs of a hatchery development at the Greenwood Wildlife Refuge site, Waushara County, Wisconsin, and insure protection of the ground-water system. Eighty percent or more of the water pumped could be recycled by recharging waste water near the supply well. Selective recycling (recharging water to the ground-water system outside the zone of recycling during approximately 4 months of each year) could maintain optimum water-supply temperatures, reduce water-level declines by 50 percent (compared to no recycling), maintain nitrate levels in the water supply below limits established for drinking water supplies, and minimize the effect of water-supply development on the regional ground-water system. Other recharge-recycling schemes can also be evaluated. Estimating the recycling efficiency (of recharge ponds, trenches, spreading areas, or irrigated fields) provides a basis for predicting water-level declines, the concentration of conservative ions (conservative in the sense that no reaction other than mixing occurs to change the character of the ion being considered) in the water supply and in the regional ground-water system, and the temperature of the water supply. Hatchery development and management schemes can be chosen to optimize hatchery productivity or minimize operation costs while protecting the ground-water system.

Wisconsin↗
USGS2024

Considerations and challenges in support of science and communication of fish consumption advisories for per- and polyfluoroalkyl substances

Federal, state, tribal, or local entities in the United States issue fish consumption advisories (FCAs) as guidance for safer consumption of locally caught fish containing contaminants. Fish consumption advisories have been developed for commonly detected compounds such as mercury and polychlorinated biphenyls. The existing national guidance does not specifically address the unique challenges associated with bioaccumulation and consumption risk related to per- and polyfluoroalkyl substances (PFAS). As a result, several states have derived their own PFAS-related consumption guidelines, many of which focus on one frequently detected PFAS, known as perfluorooctane sulfonic acid (PFOS). However, there can be significant variation between tissue concentrations or trigger concentrations (TCs) of PFOS that support the individual state-issued FCAs. This variation in TCs can create challenges for risk assessors and risk communicators in their efforts to protect public health. The objective of this article is to review existing challenges, knowledge gaps, and needs related to issuing PFAS-related FCAs and to provide key considerations for the development of protective fish consumption guidance. The current state of the science and variability in FCA derivation, considerations for sampling and analytical methodologies, risk management, risk communication, and policy challenges are discussed. How to best address PFAS mixtures in the development of FCAs, in risk assessment, and establishment of effect thresholds remains a major challenge, as well as a source of uncertainty and scrutiny. This includes developments better elucidating toxicity factors, exposures to PFAS mixtures, community fish consumption behaviors, and evolving technology and analytical instrumentation, methods, and the associated detection limits. Given the evolving science and public interests informing PFAS-related FCAs, continued review and revision of FCA approaches and best practices are vital. Nonetheless, consistent, widely applicable, PFAS-specific approaches informing methods, critical concentration thresholds, and priority compounds may assist practitioners in PFAS-related FCA development and possibly reduce variability between states and jurisdictions. Integr Environ Assess Manag 2024;00:1–20. © 2024 SETAC

Integrated Environmental Assessment and Management↗