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At least 1,675 records · Page 93Linked to original sources

Geothermal implications of a refined composition-age geologic map for the volcanic terrains of southeast Oregon, northeast California, and southwest Idaho, USA

Sufficient temperatures to generate steam likely exist under most of the dominantly volcanic terrains of southeast Oregon, northeast California, and southeast Idaho, USA, but finding sufficient permeability to allow efficient advective heat exchange is an outstanding challenge. A new thematic interpretation of existing state-level geologic maps provides an updated and refined distribution of the composition and age of geologic units for the purposes of assessing the implications for measurement and development of geothermal resources. This interpretation has been developed to better understand geothermal and hydrologic resources of the region. Comparison of the new geologic categories with available hydrologic data shows that younger volcanogenic terrains tend to have higher primary permeability than older terrains. Decrease in primary permeability with age is attributable to weathering and hydrothermal alteration of volcanogenic deposits to pore-filling clays and deposition of secondary deposits (e.g., zeolites). Spring density as a function of geology and precipitation can be used to infer groundwater flow path length within the upper aquifers. Beneath the upper aquifers, we postulate that, due to accelerated hydrothermal alteration at temperatures ~>30 °C, primary permeability at depths of geothermal interest will be limited, and that secondary permeability is a more viable target for hydrothermal fluid withdrawal. Because open fractures resulting from tensile stresses will affect all geologic layers, regions with a significant amount of groundwater flow through shallow, structurally controlled secondary permeability may overlay zones of deep secondary permeability. Regardless of whether the shallow permeability is connected with the deep permeability, shallow groundwater flow can mask the presence of deep hydrothermal flow, resulting in blind geothermal systems. Ideally, hydraulic connectivity between shallow and deep secondary permeability is limited, so that shallow groundwater does not cool potential geothermal reservoirs.

Conference Paper↗

Nonpoint-source agricultural chemicals in ground water in Nebraska; preliminary results for six areas of the High Plains Aquifer

The reconnaissance phase of a study to determine the occurrence of agricultural chemicals from nonpoint sources in groundwater in six areas, which represented the major provinces of the High Plains aquifer in Nebraska is described. In 1984, water from 82 wells in the 6 study areas was analyzed for nitrate, and water from 57 of the 82 wells was analyzed for triazine herbicides. Data for 9 of the 21 independent variables suspected of affecting concentrations of nitrate and triazine herbicides in groundwater were compiled from the 82 well sites. The variables and their ranges are: hydraulic gradient (XI), 0.006-0.0053; hydraulic conductivity (X2), 5-149 ft/day; specific discharge (X3), 0.0128-0.2998 ft/day; depth to water (X4), 3-239 ft; well depth (X5), 40-550 ft; annual precipitation (X6), 12.0-39.3 inches; soil permeability (X7), 0.76-9.0 inches; irrigation well density (X8), 0-8 irrigation wells/ sq mi; and annual nitrogen fertilizer use (X9), 0-260 lbs of nitrogen/acre. Nitrate concentrations ranged from < 0.1 to 45 mg/L as nitrogen. Triazine herbicide concentrations were detected in samples from five of the six study areas in concentrations ranging from < 0.1 to 2.3 mg/L. Statistical tests indicated that there were significant differences in nitrate concentrations among the six study areas, while no significant differences in triazine herbicide concentrations were found. Concentrations of nitrate and triazine herbicide were significantly larger in more intensively irrigated areas. Preliminary correlations with the independent variables and nitrate concentrations indicated significant relations at the 95% confidence level with variables X2, X5, and X8. Correlations with triazine herbicide concentrations indicated significant relations with variables X2 , X3, X5, X6, and X8, and with nitrate concentrations (X10). By using a simple multiple regression technique, variables X5, X8, and X9 explained about 51% of the variation in nitrate concentrations. Variables X3 and X5 explained about 60% of the variation in triazine herbicide concentrations. Adding nitrate concentration as an independent variable, two variables, X10 and X3, explained 84% of the total variation in triazine herbicide concentrations. (Author 's abstract)

Water-Resources Investigations Report↗

Use of NMR logging to obtain estimates of hydraulic conductivity in the High Plains aquifer, Nebraska, USA

Hydraulic conductivity (K) is one of the most important parameters of interest in groundwater applications because it quantifies the ease with which water can flow through an aquifer material. Hydraulic conductivity is typically measured by conducting aquifer tests or wellbore flow (WBF) logging. Of interest in our research is the use of proton nuclear magnetic resonance (NMR) logging to obtain information about water-filled porosity and pore space geometry, the combination of which can be used to estimate K. In this study, we acquired a suite of advanced geophysical logs, aquifer tests, WBF logs, and sidewall cores at the field site in Lexington, Nebraska, which is underlain by the High Plains aquifer. We first used two empirical equations developed for petroleum applications to predict K from NMR logging data: the Schlumberger Doll Research equation (K SDR ) and the Timur-Coates equation (K T-C ), with the standard empirical constants determined for consolidated materials. We upscaled our NMR-derived K estimates to the scale of the WBF-logging K(K WBF-logging ) estimates for comparison. All the upscaled K T-C estimates were within an order of magnitude of K WBF-logging and all of the upscaled K SDR estimates were within 2 orders of magnitude of K WBF-logging . We optimized the fit between the upscaled NMR-derived K and KWBF-logging estimates to determine a set of site-specific empirical constants for the unconsolidated materials at our field site. We conclude that reliable estimates of K can be obtained from NMR logging data, thus providing an alternate method for obtaining estimates of K at high levels of vertical resolution.

Nebraska↗

Trends in recent historical and projected climate data for the Colorado River Basin and potential effects on groundwater availability

Understanding recent historical and projected trends in precipitation and temperature in the Colorado River Basin, and estimating what the projected changes in these climate parameters may mean for groundwater resources in the region, is important for water managers and policymakers to sustainably manage water resources in the basin. Historical (1896–2019) precipitation and temperature data for the upper and lower Colorado River Basins were analyzed to better understand recent trends in climate data that may affect groundwater resources in the area. Historical data indicate multidecadal-scale cyclical patterns in precipitation in both the upper and lower basins. Although upper basin precipitation had no statistical trend over the recent historical period, the lower basin had a weak negative trend over this period. Multidecadal-scale cyclical patterns in temperature also are observed in historical climate data in both the upper and lower basins, at least until the early 1970s. Beginning at that time, both the upper and lower basins experienced strong, monotonic positive trends in temperature. Basic principles of hydrology indicate that periods of decreasing precipitation as well as increasing temperature would have a negative effect, that is, reduction in groundwater infiltration and hence, reduced recharge of aquifer systems. Projected climate data from 97 Coupled Model Intercomparison Project phase 5 (CMIP5) ensemble members across the full range of Representative Concentration Pathway (RCPs) from water years 1951 through 2099 were evaluated to understand what current global climate models are projecting about future conditions in the Colorado River Basin, and what this might mean for groundwater systems in the region. Precipitation in the upper basin is projected to increase throughout the rest of the century, rising to 6 percent above the 1951–2015 historical period by mid-century and to 9 percent above the historical period by the end of the century. Temperature in the upper basin also is projected to be above the recent historical median throughout the rest of the century, with steady warming in decadal average temperatures expected until the last quarter of this century. In contrast to projected precipitation in the upper basin, precipitation in the lower basin is projected to be the same as, or slightly less than, the historical period throughout most of the rest of this century. Like projected temperature in the upper basin, temperature in the lower basin also is projected to be above the recent historical median throughout the rest of the century. Comparing median projections for all future decades with median results from all historical decades, future precipitation is expected to be greater than that of the past in the upper basin, though no significant difference is projected for precipitation in the lower basin. Significant increases (p-value<0.05) are expected in temperature in both the upper and lower basins. To estimate the effects of projected precipitation and temperature on groundwater systems in the region, results from the 97 member CMIP5 climate projection ensemble were used as input in a Soil-Water Balance (SWB) groundwater infiltration model for the Colorado River Basin. SWB simulation results indicate that the upper Colorado River Basin is expected to experience decades of above-historical-average groundwater infiltration through the end of the century. For the lower Colorado River Basin, simulated groundwater infiltration is projected to be consistently less than the recent (1951–2015) historical period for most of the remaining century. A comparison of the distribution of all median simulated groundwater infiltration results between recent historical and future periods indicates projected groundwater infiltration in the upper basin is significantly (p-value<0.05) greater over the combined 2020–2099 future period than the recent (1951–2015) historical period. Moreover, in 41 of 71 (58 percent) possible future decades in this century, groundwater infiltration is projected to be greater than the 75th percentile of historical simulated groundwater infiltration. Projected groundwater infiltration in the lower Colorado River Basin across all future decades is significantly less than in the historical period. Of the 71 future decades in the century, projected groundwater infiltration in the lower basin is expected to be less than the 25th percentile of historical infiltration in 55 (77 percent) of the 10-year periods. Important differences in projected precipitation between the upper (increasing precipitation) and lower (decreasing precipitation) basins largely drive the different responses of simulated groundwater infiltration in the upper (increasing infiltration) and lower (decreasing infiltration) basins. It will be useful to revisit projections in groundwater infiltration in the Colorado River Basin when more up-to-date projections of precipitation become available from the next Coupled Model Intercomparison Project phases or by using climate input developments through Regional Climate Modeling efforts and stochastic weather generators.

Arizona, California, Colorado, Nevada, New Mexico,↗

Using a coupled groundwater/surfacewater model to predict climate-change impacts to lakes in the Trout Lake watershed, Northern Wisconsin

A major focus of the U.S. Geological Survey&rsquo;s Trout Lake Water, Energy, and Biogeochemical Budgets (WEBB) project is the development of a watershed model to allow predictions of hydrologic response to future conditions including land-use and climate change. The coupled groundwater/surface-water model GSFLOW was chosen for this purpose because it could easily incorporate an existing groundwater flow model and it provides for simulation of surface-water processes. The Trout Lake watershed in northern Wisconsin is underlain by a highly conductive outwash sand aquifer. In this area, streamflow is dominated by groundwater contributions; however, surface runoff occurs during intense rainfall periods and spring snowmelt. Surface runoff also occurs locally near stream/lake areas where the unsaturated zone is thin. A diverse data set, collected from 1992 to 2007 for the Trout Lake WEBB project and the co-located and NSF-funded North Temperate Lakes LTER project, includes snowpack, solar radiation, potential evapotranspiration, lake levels, groundwater levels, and streamflow. The timeseries processing software TSPROC (Doherty 2003) was used to distill the large time series data set to a smaller set of observations and summary statistics that captured the salient hydrologic information. The timeseries processing reduced hundreds of thousands of observations to less than 5,000. Model calibration included specific predictions for several lakes in the study area using the PEST parameter estimation suite of software (Doherty 2007). The calibrated model was used to simulate the hydrologic response in the study lakes to a variety of climate change scenarios culled from the IPCC Fourth Assessment Report of the Intergovernmental Panel on Climate Change (Solomon et al. 2007). Results from the simulations indicate climate change could result in substantial changes to the lake levels and components of the hydrologic budget of a seepage lake in the flow system. For a drainage lake lower in the flow system, the impacts of climate change are diminished.

Conference Paper↗

Aquifer storage change, 2018–2021, in the Big Chino Subbasin, Yavapai County, Arizona

This report updates groundwater-storage and groundwater-level trends presented in U.S. Geological Survey (USGS) Scientific Investigations Report 2019–5060, in the Big Chino Subbasin, Yavapai County, Arizona. This earlier geophysical investigation of groundwater-storage change in the Big Chino Subbasin was conducted by the U.S. Geological Survey, in cooperation with the City of Prescott, the Town of Prescott Valley, and the Salt River Project from 2010 to 2017 to understand groundwater-level and groundwater-storage changes. Conclusions were based on precipitation, streamflow, groundwater level, and repeat microgravity data; the latter is a direct measurement of groundwater-storage change. This report focuses on the southern part of the Big Chino Subbasin for water years 2018–2021. These more recent data show relatively small changes in groundwater storage, consistent with the earlier monitoring presented in U.S. Geological Survey Scientific Investigations Report 2019–5060. In the Big Chino Water Ranch area, water levels have increased gradually owing to discontinued pumping for irrigation during summer months, and an in-channel recharge event in summer 2021. In the Paulden, Arizona, area, gradual water level declines have continued a downward trend that started in the 1990s. Seasonal variation is present in the Paulden area, with higher water levels in the winter months when pumping for irrigation and agricultural use is reduced. Two wells showed groundwater-level increases consistent with in-channel recharge in 2018 and 2021, whereas groundwater levels in a well screened in the deeper, confined to semi-confined carbonate aquifer showed no such discrete recharge events. In the area west of Big Chino Wash and east of the Juniper Mountains and Santa Maria Mountains, groundwater levels continued long-term declines, but storage changes were minimal.

Arizona↗

Land subsidence along the Delta-Mendota Canal in the northern part of the San Joaquin Valley, California, 2003-10

Extensive groundwater withdrawal from the unconsolidated deposits in the San Joaquin Valley caused widespread aquifer-system compaction and resultant land subsidence from 1926 to 1970—locally exceeding 8.5 meters. The importation of surface water beginning in the early 1950s through the Delta-Mendota Canal and in the early 1970s through the California Aqueduct resulted in decreased pumping, initiation of water-level recovery, and a reduced rate of compaction in some areas of the San Joaquin Valley. However, drought conditions during 1976–77 and 1987–92, and drought conditions and regulatory reductions in surface-water deliveries during 2007–10, decreased surface-water availability, causing pumping to increase, water levels to decline, and renewed compaction. Land subsidence from this compaction has reduced freeboard and flow capacity of the Delta-Mendota Canal, the California Aqueduct, and other canals that deliver irrigation water and transport floodwater. The U.S. Geological Survey, in cooperation with the U.S. Bureau of Reclamation and the San Luis and Delta-Mendota Water Authority, assessed land subsidence in the vicinity of the Delta-Mendota Canal as part of an effort to minimize future subsidence-related damages to the canal. The location, magnitude, and stress regime of land-surface deformation during 2003–10 were determined by using extensometer, Global Positioning System (GPS), Interferometric Synthetic Aperture Radar (InSAR), spirit leveling, and groundwater-level data. Comparison of continuous GPS, shallow extensometer, and groundwater-level data, combined with results from a one-dimensional model, indicated the vast majority of the compaction took place beneath the Corcoran Clay, the primary regional confining unit. Land-surface deformation measurements indicated that much of the northern portion of the Delta-Mendota Canal (Clifton Court Forebay to Check 14) was fairly stable or minimally subsiding on an annual basis; some areas showed seasonal periods of subsidence and of uplift that resulted in little or no longer-term elevation loss. Many groundwater levels in this northern area did not reach historical lows during 2003–10, indicating that deformation in this region was primarily elastic. Although the northern portion of the Delta-Mendota Canal was relatively stable, land-surface deformation measurements indicated the southern portion of the Delta-Mendota Canal (Checks 15–21) subsided as part of a large subsidence feature centered about 15 kilometers northeast of the Delta-Mendota Canal, south of the town of El Nido. Results of InSAR analysis indicated at least 540 millimeters of subsidence near the San Joaquin River and the Eastside Bypass during 2008–10, which is part of a 3,200 square-kilometer area—including the southern part of the Delta-Mendota Canal—affected by 20 millimeters or more of subsidence during the same period. Calculations indicated that the subsidence rate doubled in 2008 in some areas. The GPS surveys done in 2008 and 2010 confirmed the high subsidence rate measured by using InSAR for the same period. Water levels in many shallow and deep wells in this area declined during 2007–10; water levels in many deep wells reached historical lows, indicating that subsidence measured during this period was largely inelastic. InSAR-derived subsidence maps for various periods during 2003–10 showed that the area of maximum active subsidence (that is, the largest rates of subsidence) shifted from its historical (1926–70) location southwest of Mendota to south of El Nido. Continued groundwater-level and land-subsidence monitoring in the San Joaquin Valley is important because (1) regulatory- and drought-related reductions in surface-water deliveries since 1976 have resulted in increased groundwater pumping and associated land subsidence, and (2) land use and associated groundwater pumping continue to change throughout the valley. The availability of surface water remains uncertain; even during record-setting precipitation years, such as 2010–11, water deliveries have fallen short of requests and groundwater pumping was required to meet the irrigation demand. Due to the expected continued demand for irrigation supply water and the limitations and uncertainty of surface-water supplies, groundwater pumping and associated land subsidence is likely to continue in the future. Spatially detailed information on land subsidence is needed to facilitate minimization of future subsidence-related damages to the Delta-Mendota Canal and other infrastructure in the San Joaquin Valley. The integration of subsidence, deformation, and water-level measurements—particularly continuous measurements—enables the analysis of aquifer-system response to increased groundwater pumping, which in turn, enables identification of the preconsolidation head and calculation of aquifer-system storage properties. This information can be used to improve numerical model simulations of groundwater flow and aquifer-system compaction and allow for consideration of land subsidence in the evaluation of water-resource management alternatives.

California↗

Infiltration and hydraulic connections from the Niagara River to a fractured-dolomite aquifer in Niagara Falls, New York

The spatial distribution of hydrogen and oxygen stable-isotope values in groundwater can be used to distinguish different sources of recharge and to trace groundwater flow directions from recharge boundaries. This method can be particularly useful in fractured-rock settings where multiple lines of evidence are required to delineate preferential flow paths that result from heterogeneity within fracture zones. Flow paths delineated with stable isotopes can be combined with hydraulic data to form a more complete picture of the groundwater flow system. In this study values of ??D and ??18O were used to delineate paths of river-water infiltration into the Lockport Group, a fractured dolomite aquifer, and to compute the percentage of fiver water in groundwater samples from shallow bedrock wells. Flow paths were correlated with areas of high hydraulic diffusivity in the shallow bedrock that were delineated from water-level fluctuations induced by diurnal stage fluctuations in man-made hydraulic structures. Flow paths delineated with the stable-isotope and hydraulic data suggest that fiver infiltration reaches an unlined storm sewer in the bedrock through a drainage system that surrounds aqueducts carrying river water to hydroelectric power plants. This finding is significant because the storm sewer is the discharge point for contaminated groundwater from several chemical waste-disposal sites and the cost of treating the storm sewer's discharge could be reduced if the volume of infiltration from the river were decreased.The spatial distribution of hydrogen and oxygen stable-isotope values in groundwater can be used to distinguish different sources of recharge and to trace groundwater flow directions from recharge boundaries. This method can be particularly useful in fractured-rock settings where multiple lines of evidence are required to delineate preferential flow paths that result from heterogeneity within fracture zones. Flow paths delineated with stable isotopes can be combined with hydraulic data to form a more complete picture of the groundwater flow system. In this study values of ??D and ??18O were used to delineate paths of river-water infiltration into the Lockport Group, a fractured dolomite aquifer, and to compute the percentage of river water in groundwater samples from shallow bedrock wells. Flow paths were correlated with areas of high hydraulic diffusivity in the shallow bedrock that were delineated from water-level fluctuations induced by diurnal stage fluctuations in man-made hydraulic structures. Flow paths delineated with the stable-isotope and hydraulic data suggest that river infiltration reaches an unlined storm sewer in the bedrock through a drainage system that surrounds aqueducts carrying river water to hydroelectric power plants. This finding is significant because the storm sewer is the discharge point for contaminated groundwater from several chemical waste-disposal sites and the cost of treating the storm sewer's discharge could be reduced if the volume of infiltration from the river were decreased.

Journal of Hydrology↗

Geologic history of the Black Hills caves, South Dakota

Cave development in the Madison aquifer of the Black Hills has taken place in several stages. Mississippian carbonates first underwent eogenetic (early diagenetic) reactions with interbedded sulfates to form breccias and solution voids. Later subaerial exposure allowed oxygenated meteoric water to replace sulfates with calcite and to form karst and small caves. All were later buried by ~2 km of Pennsylvanian&ndash;Cretaceous strata. Groundwater flow and speleogenesis in the Madison aquifer were renewed by erosional exposure during Laramide uplift. Post-Laramide speleogenesis enlarged paleokarst voids. Most interpretations of this process in the Black Hills invoke rising thermal water, but they fail to account for the cave patterns. Few passages extend downdip below the present water table or updip to outcrops. None reaches the base of the Madison Limestone, and few reach the top. Major caves underlie a thin cover of basal Pennsylvanian&ndash;Permian Minnelusa Formation (interbedded quartzarenite and carbonates). Water infiltrating through the Minnelusa Formation dissolves carbonates in a nearly closed system, producing low p CO 2 , while recharge directly into Madison outcrops has a much higher p CO 2 . Both are at or near calcite saturation when they enter caves, but their mixture is undersaturated. The caves reveal four phases of calcite deposition: eogenetic ferroan calcite (Mississippian replacement of sulfates); white scalenohedra in paleovoids deposited during deep post-Mississippian burial; palisade crusts formed during blockage of springs by Oligocene&ndash;Miocene continental sediments; and laminated crusts from late Pleistocene water-table fluctuations. The caves reveal more than 300 m.y. of geologic history and a close relationship to regional geologic events.

South Dakota, Wyoming↗

Effects of climate change and population growth on the transboundary Santa Cruz aquifer

The USA and Mexico have initiated comprehensive assessment of 4 of the 18 aquifers underlying their 3000 km border. Binational management of groundwater is not currently proposed. University and agency researchers plus USA and Mexican federal, state, and local agency staff have collaboratively identified key challenges facing the Santa Cruz River Valley Aquifer located between the states of Arizona and Sonora. The aquifer is subject to recharge variability, which is compounded by climate change, and is experiencing growing urban demand for groundwater. In this paper, we briefly review past, current, and projected pressures on Santa Cruz groundwater. We undertake first-order approximation of the relative magnitude of climate change and human demand drivers on the Santa Cruz water balance. Global circulation model output for emissions scenarios A1B, B1, and A2 present mixed trends, with annual precipitation projected to vary by ±20% over the 21st century. Results of our analysis indicate that urban water use will experience greater percentage change than climate-induced recharge (which remains the largest single component of the water balance). In the Mexican portion of the Santa Cruz, up to half of future total water demand will need to be met from non-aquifer sources. In the absence of water importation and with agricultural water use and rights increasingly appropriated for urban demand, wastewater is increasingly seen as a resource to meet urban demand. We consider decision making on both sides of the border and conclude by identifying short- and longer-term opportunities for further binational collaboration on transboundary aquifer assessment.

Santa Cruz Aquifer↗

Surficial geology and ground-water availability in the Allegheny River basin and part of the Lake Erie basin, New York

New York State 's need to develop a groundwater management program for protection of its aquifers led in 1985 to a cooperative program between the U.S. Geological Survey and the New York State Department of Environmental Conservation (through regional planning agencies) to publish data from previous studies. The two maps presented are from original compilations done in a 1967 study. Sheet 1 depicts the surficial geology as mapped in 1967; sheet 2 shows the groundwater availability (well yield) throughout the basin. These maps are presented at 1:250 ,000 scale for compatibility with published maps of adjacent river basins.

New York↗

Geochemical and geophysical examination of submarine groundwater discharge and associated nutrient loading estimates into Lynch Cove, Hood Canal, WA

Geochemical tracer data (i.e., 222 Rn and four naturally occurring Ra isotopes), electromagnetic (EM) seepage meter results, and high-resolution, stationary electrical resistivity images were used to examine the bi-directional (i.e., submarine groundwater discharge and recharge) exchange of a coastal aquifer with seawater. Our study site for these experiments was Lynch Cove, the terminus of Hood Canal, WA, where fjord-like conditions dramatically limit water column circulation that can lead to recurring summer-time hypoxic events. In such a system a precise nutrient budget may be particularly sensitive to groundwater-derived nutrient loading. Shore-perpendicular time-series subsurface resistivity profiles show clear, decimeter-scale tidal modulation of the coastal aquifer in response to large, regional hydraulic gradients, hydrologically transmissive glacial terrain, and large (4-5 m) tidal amplitudes. A 5-day 222 Rn time-series shows a strong inverse covariance between 222 Rn activities (0.5&minus;29 dpm L -1 ) and water level fluctuations, and provides compelling evidence for tidally modulated exchange of groundwater across the sediment/water interface. Mean Rn-derived submarine groundwater discharge (SGD) rates of 85 &plusmn; 84 cm d -1 agree closely in the timing and magnitude with EM seepage meter results that showed discharge during low tide and recharge during high tide events. To evaluate the importance of fresh versus saline SGD, Rn-derived SGD rates (as a proxy of total SGD) were compared to excess 226Ra-derived SGD rates (as a proxy for the saline contribution of SGD). The calculated SGD rates, which include a significant (>80%) component of recycled seawater, are used to estimate associated nutrient (NH 4+ , Si, PO 4 3- , NO 3 + NO 2 , TDN) loads to Lynch Cove. The dissolved inorganic nitrogen (DIN = NH 4 + NO 2 + NO 3 ) SGD loading estimate of 5.9 &times; 10 4 mol d -1 is 1&minus;2 orders of magnitude larger than similar estimates derived from atmospheric deposition and surface water runoff, respectively.

Washington↗

Water resources in the Cheyenne and Arapaho Tribal jurisdictional area, west-central Oklahoma, with an analysis of data gaps through 2015

This report provides an overview of existing hydrologic information describing the quality, quantity, and extent of the major surface-water and groundwater resources in the Cheyenne and Arapaho Tribal jurisdictional area, west-central Oklahoma. Hydrologic information is provided for five major river systems (Cimarron River, North Canadian River, Canadian River, Washita River, and North Fork Red River), two reservoirs (Foss Reservoir and Canton Lake), and eight aquifers consisting of the alluvial aquifers associated with each of the five major river systems and three major bedrock aquifers (Ogallala aquifer, Elk City aquifer, and Rush Springs aquifer). Types of information provided about rivers and reservoirs for the Cheyenne and Arapaho Tribal jurisdictional area include diversion sites and amounts of water allocated and diverted for permitted uses in 2015; treated wastewater discharge sites and amounts discharged in 2015; and characteristics describing water-quality field properties, major ions, nutrients, and selected trace elements. Major ions, nutrients, and selected trace elements are compared to secondary maximum contaminant levels and maximum contaminant levels for finished drinking water. Additionally, statistics are provided describing daily, monthly, and annual streamflow characteristics at 12 U.S. Geological Survey streamgages. Streamflow statistics include the magnitudes and frequencies of floods, base-flow characteristics, and long-term streamflow trends. Types of information provided about the aquifers include amounts of water allocated and pumped for permitted uses in 2015; characteristics of groundwater describing water-quality field properties, major ions, nitrate (measured as nitrogen), and selected trace elements with comparisons to secondary maximum contaminant levels and maximum contaminant levels for finished drinking water; groundwater levels and long-term changes in water levels; and ranges of hydraulic conductivity, aquifer recharge, specific yield, transmissivity, and well yields from reports and groundwater-flow models. Surface water is used primarily for irrigation and mining and other nonconsumptive uses in the Cheyenne and Arapaho Tribal jurisdictional area, except from the Washita and North Fork Red Rivers, where water is treated for use as a public-water supply. Large concentrations of dissolved solids are the primary limiting factor affecting the use of surface water. Median concentrations of dissolved solids in surface water range from less than 1,000 milligrams per liter (mg/L) in samples from the North Canadian River to greater than 9,000 mg/L in samples from the Cimarron River. Large dissolved solids concentrations are correlated with hard water. Median hardness as calcium carbonate concentrations in surface water ranges from 427 mg/L in samples from Canton Lake to 1,000 mg/L in samples from the Washita River. In 2015, groundwater was used at more than twice the rate of surface water in the Cheyenne and Arapaho Tribal jurisdictional area. Although the alluvial aquifers are considered reliably good sources of water in the Cheyenne and Arapaho Tribal jurisdictional area, concentrations of nitrate (measured as nitrogen) exceed the maximum contaminant level of 10 mg/L established by the U.S. Environmental Protection Agency for finished drinking water in parts of all of the alluvial aquifers. Water from the three major bedrock aquifers is used for irrigation, mining, public-water supply, and other uses; however, large concentrations of dissolved solids, nitrate (measured as nitrogen), and naturally occurring trace elements such as arsenic and uranium may limit the use of groundwater as a source of public-water supply in some areas. As of 2015, the depletion of groundwater from the major aquifers in west-central Oklahoma is a minor concern to the Oklahoma Water Resources Board. Groundwater levels and other hydrologic information show that recharge rates exceed the rates of water pumped from aquifers, except in areas that may be affected locally by groundwater depletions.

Oklahoma↗

Quantitative subsurface characterization illuminates the origin of the Quaternary Mississippi River Valley alluvial aquifer

The Mississippi River Valley alluvial aquifer (MRVA) is vital to U.S. food security and global agricultural supply. However, quantitative understanding of its Quaternary origin, architecture, and hydrologic function remains incomplete. Here we develop a three-dimensional hydrostratigraphic model to characterize the deposition of clay and silt, fine-medium sands, and graveliferous sands using lithologic data from 75,000 boreholes compiled across the Lower Mississippi Valley and a geostatistical method—interval kriging. We find that cyclic glacial entrenchments, evidenced by remnants of pre-Wisconsinan postglacial sediments, alongside geodynamic activities shaped the MRVA basal configuration. Stratal weakening from faulting and salt diapirism enhanced glacial incision and thereby produced abrupt aquifer thickening. We demarcate the top of graveliferous sands as the regional marker of the Pleistocene-Holocene transition. The MRVA hydrostratigraphy reveals hydrologic function and geologic controls on groundwater storage and quality, advancing the assessment of aquifer sustainability under a changing climate, with implications for alluvial aquifers globally.

Arkansas, Illinois, Kentucky, Louisiana, Mississip↗

Evidence of CFC degradation in groundwater under pyrite-oxidizing conditions

A detailed local-scale monitoring network was used to assess CFC distribution in an unconfined sand aquifer in southwestern Ontario where the zone of 1–5-year-old groundwater was known with certainty because of prior use of a bromide tracer. Groundwater ⩽5 years old was confined to an aerobic zone at ⩽5 m depth and had CFC concentrations consistent with modern atmospheric mixing ratios at recharge temperatures of 7–11 °C, as was observed in the 3-m thick vadose zone at the site. At depths below 6 m, the groundwater became progressively more reducing, however, with a denitrifying horizon at 6–7 m depth, and a Mn and Fe reducing zone below 7 m depth. In the anaerobic zone, 3 H/ 3 He ratios indicated that groundwater-age continued to increase uniformly with depth, to a maximum value of 27 years at 13 m depth. CFC concentrations, however, decreased abruptly within the denitrifying zone, leading to substantial age overestimation compared to the 3 H/ 3 He ages. Noble gas data indicated that the apparent CFC mass loss was not likely the result of gas stripping from possible bubble formation; thus, CFC degradation was indicated in the anoxic zone. The field data are consistent with first-order degradation rates of 0.3 yr −1 for CFC-12, 0.7 yr −1 for CFC-11, and 1.6 yr −1 for CFC-113. CFC attenuation at this site coincides with a zone where reduced S (pyrite) is actively oxidized by NO 3 and dissolved oxygen (DO). Similar behavior has been observed at other sites [Tesoriero, A.J., Liebscher, H., Cox, S.E., 2000. Mechanism and rate of denitrification in an agricultural watershed: electron and mass balance along groundwater flow path. Water Resour. Res. 36 (6), 1545–1559; Hinsby, K., Hojberg, A.L., Engesgaard, P., Jensen, K.H., Larsen, F., Plummer, L.N., Busenberg, E., Accepted for publication. Transport and degradation of chlorofluorocarbons (CFCs) in a pyritic aquifer, Rabis Creek, Denmark. Water Resour. Res.], further demonstrating that the use of CFCs for age-dating anaerobic groundwater should be approached with caution, particularly if the sediment contains pyrite.

Journal of Hydrology↗

Relations between well-field pumping and induced canal leakage in east-central Miami-Dade County, Florida, 2010-2011

An extensive canal and water management system exists in south Florida to prevent flooding, replenish groundwater, and impede saltwater intrusion. The unconfined Biscayne aquifer, which underlies southeast Florida and provides water for millions of residents, interacts with the canal system. The Biscayne aquifer is composed of a highly transmissive karst limestone; therefore, canal stage and flow may be affected by production well pumping, especially in locations where production wells and canals are in proximity. The U.S. Geological Survey developed a local-scale, transient, numerical groundwater flow model of a well field in Miami-Dade County to (1) quantify relations between well-field pumping and C-2 Canal (herein referred to as the Snapper Creek Canal) leakage, (2) determine primary controls on canal leakage variability, and (3) summarize results that could simplify characterization of canal/well-field interactions in other locations. In addition to the groundwater model development, stable isotope data from water-quality samples were used to characterize the relations between production well pumping and canal leakage. The results from the groundwater model and the isotope data were used to refine the conceptual flow model of the study area. The groundwater flow model MODFLOW-NWT was used for simulating groundwater flow and quantifying interactions between pumping from the well field and Snapper Creek Canal leakage. Input data for the groundwater model included precipitation, evapotranspiration, pumping, canal stage, and regional groundwater elevation. The inverse modeling tool UCODE and groundwater data from June 2010 to July 2011 were used to calibrate the model. Parameter sensitivity analyses were performed with UCODE. Model sensitivities to geologic heterogeneity, non-laminar flow, and changes in the regional flow boundary were evaluated. The groundwater model generally fits the calibration criteria well within estimated error ranges for groundwater elevations and canal leakage values. The mean average error for heads simulated with the model was 0.19 meter, and head residuals were generally randomly distributed. The model simulated groundwater flow under ambient conditions without production well pumping to establish background leakage. Groundwater flow also was simulated with production well pumping to estimate induced leakage from the Snapper Creek Canal that occurs in response to pumping. Canal leakage was quantified as a percentage of total canal leakage. The percentage of leakage during pumping increased non-linearly with pumping rate, indicating a decreasing sensitivity of canal leakage to pumping at relatively large pumping magnitudes. The results for Snapper Creek Canal may serve as an upper limit for well-field interaction with surface-water features in Miami-Dade County, given the proximity (about 50 meters) of the pumping wells in this study to the Snapper Creek Canal. The isotopic compositions of hydrogen (H) and oxygen (O) in groundwater samples were used to distinguish sources for groundwater within the study area and to assess the extent of natural mixing and pumping-induced mixing with water in the Snapper Creek Canal. Water-level data and water-quality samples were collected from monitoring well clusters, production wells, and the Snapper Creek Canal during discrete sampling events under ambient and pumping conditions. Trends in the isotope data generally follow the regional west-to-east hydraulic gradient across the study area. Data collected within the monitoring-well clusters in closest proximity to the canal indicate that groundwater/surface-water interactions are greatest within the shallow flow zone of the aquifer, especially during pumping conditions. The isotopic composition of samples collected within the study area indicates that the shallow, highly transmissive preferential flow zone receives substantial recharge from the canal. The isotope data from the production wells which are open to the deeper flow zone within the aquifer, indicate only traces of mixing with a 2 H- and 18 O-enriched source, suggesting little canal admixture with waters of the deeper flow zone. Results from the groundwater model and the stable isotope data analysis indicate the importance of considering geologic heterogeneity when investigating the relations between pumping and canal leakage, not only at this site, but also at other sites with similar heterogeneous geology. The model results were consistently sensitive to the hydrogeologic framework and changes in hydraulic conductivities. The model and the isotope data indicate that the majority of the groundwater/surface-water interactions occurred within the shallow flow zone. A relatively lower-permeability geologic layer occurring between the shallowest and deep preferential flow zones lessens the interactions between the production wells and the canal.

Florida↗

Perfluoroalkyl and polyfluoroalkyl substances in groundwater used as a source of drinking water in the eastern United States

In 2019, 254 samples were collected from five aquifer systems to evaluate per- and polyfluoroalkyl substance (PFAS) occurrence in groundwater used as a source of drinking water in the eastern United States. The samples were analyzed for 24 PFAS, major ions, nutrients, trace elements, dissolved organic carbon (DOC), volatile organic compounds (VOCs), pharmaceuticals, and tritium. Fourteen of the 24 PFAS were detected in groundwater, with 60% and 20% of public-supply and domestic wells, respectively, containing at least one PFAS detection. Concentrations of tritium, chloride, sulfate, DOC, and manganese+iron; percent urban land use within 500 m of the wells; and VOC and pharmaceutical detection frequencies were significantly higher in samples containing PFAS detections than in samples with no detections. Boosted Regression Tree models that consider 57 chemical and land-use variables show that tritium concentration, distance to the nearest fire-training area, percentage of urban land use, and DOC and VOC concentrations are the top five predictors of PFAS detections, consistent with hydrologic position, geochemistry, and land use being important controls on PFAS occurrence in groundwater. Model results indicate it may be possible to predict PFAS detections in groundwater using existing data sources.

Glacial aquifer, Mississippi Embayment aquifer, So↗

The dominance and growth of shallow groundwater resources in continuous permafrost environments

Water is a limited resource in Arctic watersheds with continuous permafrost because freezing conditions in winter and the impermeability of permafrost limit storage and connectivity between surface water and deep groundwater. However, groundwater can still be an important source of surface water in such settings, feeding springs and large aufeis fields that are abundant in cold regions and generating runoff when precipitation is rare. Whether groundwater is sourced from suprapermafrost taliks or deeper regional aquifers will impact water availability as the Arctic continues to warm and thaw. Previous research is ambiguous about the role of deep groundwater, leading to uncertainty regarding Arctic water availability and changing water resources. We analyzed chemistry and residence times of spring, stream, and river waters in the continuous permafrost zone of Alaska, spanning the mountains to the coastal plain. Water chemistry and age tracers show that surface waters are predominately sourced from recent precipitation and have short (<50 y) subsurface residence times. Remote sensing indicates trends in the areal extent of aufeis over the last 37 y, and correlations between aufeis extent and previous year summer temperature. Together, these data indicate that surface waters in continuous permafrost regions may be impacted by short flow paths and shallow suprapermafrost aquifers that are highly sensitive to climatic and hydrologic change over annual timescales. Despite the lack of connection to regional aquifers, continued warming and permafrost thaw may promote deepening of the shallow subsurface aquifers and creation of shallow taliks, providing some resilience to Arctic freshwater ecosystems.

Proceedings of the National Academy of Sciences↗