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At least 1,675 records · Page 93Linked to original sources
USGS2021

Spring types and contributing aquifers from water-chemistry and multivariate statistical analyses for seeps and springs in Theodore Roosevelt National Park, North Dakota, 2018

Water resources in Theodore Roosevelt National Park, North Dakota, support wildlife, visitors, and staff, and play a vital role in supporting the native ecology of the park. The U.S. Geological Survey, in cooperation with the National Park Service, completed field work in 2018 for a study to address concerns about water availability and possible sources of groundwater contamination for seeps and springs in Theodore Roosevelt National Park. The objective of the study was to improve hydrologic knowledge and determine the water composition of 11 seeps and springs in the park by collecting water-chemistry data at springs, streams, wells, and rain collectors. Water samples were collected at 26 sites at springs, streams, wells, and rain collectors in the North and South Units of Theodore Roosevelt National Park. Samples in the North Unit were collected at 5 springs, 1 stream, 2 wells, and 1 rain collector. Samples in the South Unit were collected at 6 springs, 2 streams, 8 wells, and 1 rain collector. Samples from springs, streams, and wells were collected in May, July, and September 2018. Samples from rain collectors were collected when enough daily precipitation accumulated in the collectors. Sampled precipitation events during the study period were in May, June, July, August, and September 2018. Physical properties of sampled water—temperature, pH, and specific conductance—were measured in the field. Water samples were analyzed for stable isotopes of oxygen and hydrogen and for chloride concentration. Recharge rates for aquifers supplying springs were determined using precipitation volume and chloride concentrations for a 12-day period before the sample-collection date. Multivariate statistical analysis methods used on water-chemistry data included principal component analysis, cluster analysis, and end-member mixing analysis. Water composition was used to determine the spring type and contributing aquifers for 11 springs in the North and South Units of Theodore Roosevelt National Park from analyses of water-chemistry data between May and September 2018. In the North Unit, Achenbach Spring was classified as a filtration spring with water from an unconfined part of the upper Fort Union aquifer and infiltration of precipitation. Hagen Spring, Mandal Spring, and Stevens Spring were classified as contact springs supplied by semiconfined parts of the upper Fort Union aquifer. Overlook Spring at one time may have been a natural spring or seep but now is a developed spring that behaves like a flowing artesian well completed in a confined part of the upper Fort Union aquifer. In the South Unit, six springs were classified into two spring types: filtration and contact springs. Boicourt Spring and Sheep Butte Spring were classified as filtration springs that have water supplied by unconfined parts of the upper Fort Union aquifer and infiltrated precipitation. Big Plateau Spring, Lone Tree Spring, Sheep Pasture Spring, and Southeast Corner Spring were classified as contact springs that receive waters from a semiconfined part of the upper Fort Union aquifer.

North Dakota↗
USGS1968

Analysis of water quality of the Mahoning River in Ohio

The Mahoning River drains the densely populated and industrialized Warren-Youngstown area in northeastern Ohio. Significant chemical constituents and physical properties generally regarded as important in establishing water-quality standards for the Mahoning River are evaluated on the basis of hydrologic conditions and water use. Most of the interpretations and the appraisal of water-quality conditions are based on data collected from January 1963 to December 1965. Generally, streamflow during this period was lower than during a selected long-term reference period ; however, extremely low flows that occurred in the reference period did not occur in the 3-year study period. Water temperatures of the Mahoning River at Pricetown and Leavittsburg were not affected by thermal loading. Water temperatures at those stations ranged from the freezing point to 78?F during the 1963-65 period. Downstream from Leavittsburg, the use of large quantities of water for industrial cooling caused critical thermal loading during periods of low streamflow. Maximum water temperatures were 108?F and 104?F at Struthers and Lowellville, respectively. Water temperatures of the Mahoning River were lower during high water discharges and increased with higher steel-production indices. Flow augmentation and modifications in industrial processes have improved the water-temperature conditions in recent years. A combination of oxygen-consuming materials and warmed water from industrial and municipal wastes discharged into the lower reaches of the Mahoning River frequently depleted the dissolved-oxygen content. At Lowellville, the river water had a dissolved-oxygen content of 5 ppm (parts per million) or less for 67 percent of the time and 3 ppm or less for 16 percent of the time during the study period. The percentage of saturation of dissolved oxygen followed a similar trend. Both the dissolved-oxygen concentration and the percentage of saturation were noticeably lower downstream from Leavittsburg during the warm months when water temperatures were high and streamflow was low. The dissolved-oxygen content in the Mahoning River at Leavittsburg and Pricetown was almost always at acceptable levels. The calculated dissolved-solids concentration of the Mahoning River ranged from 150 to 450 ppm at Leavittsburg and from 200 ppm to 650 ppm at Lowellville. Industrial use of the water caused an increase in the dissolved-solids concentration at Lowellville. During one steel-mill shutdown the average dissolved-solids concentration decreased from about 360 to about 280 ppm. Chloride concentrations in the Mahoning River ranged from 42 ppm at Pricetown to 108 ppm at Struthers. The chloride load at 50-percent flow duration was 9 and 69 tons per day at Pricetown and Lowellville, respectively. The chloride content of the Mahoning River was well within acceptable levels. Sulfate from wastes disposal and acid mine drainage made up the largest quantity of dissolved-solids load in the Mahoning River. The sulfate load at 50-percent flow duration increased from 38 tons per day at Pricetown to 300 tons per day at Lowellville. At Pricetown the sulfate load ranged from about 2 to 588 tons per day, while at Lowellville, downstream from the industrialized area, the range was from 106 to 2,420 tons per day. Comparison of sulfate loads during periods of steel production with periods of steel-mill shutdown indicated that during low flow about half the sulfate load at Lowellville was derived from steel-mill wastes when the production index was 100. The alkalinity load of the Mahoning River at 50-percent flow duration increased from Pricetown (23 tons per day) to Lowellville (41 tons per day). During steel production the alkalinity of the water showed a marked decrease from Leavittsburg downstream to Lowellville. However, during steel-mill shutdowns the chemical composition of the river at Youngstown and Lowellville was similar to that at Leavittsburg. Acid mine drainag

Water Supply Paper↗
USGS1979

Preliminary hydrogeologic investigation of the Maxey Flats radioactive waste burial site, Fleming County, Kentucky

Burial trenches at the Maxey Flats radioactive waste burial site , Fleming County, Ky., cover an area of about 0.03 square mile, and are located on a plateau, about 300 to 400 feet above surrounding valleys. Although surface-water characteristics are known, little information is available regarding the ground-water hydrology of the Maxey Flats area. If transport of radionuclides from the burial site were to occur, water would probably be the principal mechanism of transport by natural means. Most base flow in streams around the burial site is from valley alluvium, and from the mantle of regolith, colluvium, and soil partially covering adjacent hills. Very little base flow is due to ground-water flow from bedrock. Most water in springs is from the mantle, rather than from bedrock. Rock units underlying the Maxey Flats area are, in descending order, the Nancy and Farmers Members of the Borden Formation, Sunbury, Bedford, and Ohio Shales, and upper part of the Crab Orchard Formation. These units are mostly shales, except for the Farmers Member, which is mostly sandstone. Total thickness of the rocks is about 320 feet. All radioactive wastes are buried in the Nancy Member. Most ground-water movement in bedrock probably occurs in fractures. The ground-water system at Maxey Flats is probably unconfined, and recharge occurs by (a) infiltration of rainfall into the mantle, and (b) vertical, unsaturated flow from the saturated regolith on hilltops to saturated zones in the Farmers Member and Ohio Shale. Data are insufficient to determine if saturated zones exist in other rock units. The upper part of the Crab Orchard Formation is probably a hydrologic boundary, with little ground-water flow through the formation. (USGS)

Open-File Report↗
USGS1996

Hydrologic data at a wetland site, Millington, Shelby County, Tennessee, June 1993 through June 1994

Hydrologic data at a wetland site near Millington, Shelby County, Tennessee, were collected from June 1993 through June 1994. The data were collected to support the efforts of the Tennessee Department of Transportation to better understand hydrologic properties at the site prior to wetland restoration. Water levels were monitored in thirteen 8-inch- diameter wells, approximately 2 feet deep. The casing in each well was slotted and screened from land surface to a depth of about 2 feet. Water-level recorders provided continuous records of stage during periods of wetland inundation, and depth to water table during periods of noninundation. A continuous-stage recorder was installed in a pond. Precipitation data were obtained from the Naval Air Station-Memphis, Millington, Tennessee. Land surface at the wells was inundated from 0 to 56 percent of the study period. Additionally, water levels in the wells were not more than 1.5 feet below land surface for 16 to 68 percent of the study period.

Tennessee↗
USGS1982

Geohydrologic data from sandstone aquifers in southwestern Kansas

Data collected during a reconnaissance investigation of the geology and hydrology of sandstone aquifers provide useful information in the study of, and planning for, water-resources development in a 17,400 square-mile area in 26 counties of southwestern Kansas. The aquifers consist chiefly of saturated sandstones that occur in Upper Permian, Upper Jurassic, and Lower and Upper Cretaceous rocks. In parts of southwestern Kansas, the sandstone aquifers already serve as the principal or secondary source of ground water for irrigation and other uses. Data indicate that water may be available for development in sandstone aquifers in other parts of the study area. In still other areas, water from wells in sandstone aquifers may not be of a suitable quality for some purposes. The data provided include records of selected wells, lithologic logs of test holes and wells, selected formation surfaces and sandstone thicknesses , chemical analyses of water from selected wells, and water levels in observation wells. (USGS)

Open-File Report↗
USGS1995

State Soil Geographic (STATSGO) Data Base for the Conterminous United States

USSOILS is an Arc 7.0 coverage containing hydrology-relevant information for 10,498 map units covering the entire conterminous United States. The coverage was compiled from individual State coverages contained in the October 1994 State Soil Geographic (STATSGO) Data Base produced on CD-ROM. The geo-dataset USSOILS.PAT relates (on the basis of a map unit identifier) the 10,498 map units to 78,518 polygons. The scale of the geo-dataset is 1:250,000. The INFO attribute table USSOILS.MUID_ATTS contains selected variables from the STATSGO data set for 10,501 map units (an extra 3 map units are contained in the attribute table that are not in the geo-dataset - see the 'Procedures' section below), including: the map unit identifier, a 2-character state abbreviation, available water capacity of the soil, percent clay in the soil, the actual k-factor used in the water erosion component of the universal soil loss equation, the organic material in soil, soil permeability, cumulative thickness of all soil layers, hydrologic characteristics of the soil, quality of drainage, surface slope, liquid limit of the soil, share of a map unit having hydric soils, and the annual frequency of flooding. To facilitate mapping the attribute data, the narrative section below contains instructions for transferring the information contained in the attribute table USSOILS.MUID_ATTS to the polygon attribute table USSOILS.PAT. STATSGO United States Soil Water Capacity Clay Organic material Permeability Infiltration Drainage Hydric Flood frequency Slope

Open-File Report↗
USGS2006

Hydrologic bench marks to distinguish the effects of climate vs. man

There is a vital need for hydrologic data representing various environments that are free from the effects of man 's activities. Without such data hydrologists will be stymied in distinguishing hydrologic changes caused by man from those caused by climate . To provide this background information, the U. S. Geological Survey is planning a nationwide hydrologic bench ‐ mark program in which runoff, transport of sediment, precipitation, changes in vegetation, fluctuations in ground water, and other hydrologic events will be studied in locales unaffected by the works of man . The knowledge gained in operating these bench marks will be invaluable in statistical appraisals of hydrologic data wherein a part of the record is affected by man 's activities.

Groundwater↗
USGS1972

Radiochemical analyses of surface water from U.S. Geological Survey hydrologic bench-mark stations

The U.S. Geological Survey's program for collecting and analyzing surface-water samples for radiochemical constituents at hydrologic bench-mark stations is described. Analytical methods used during the study are described briefly and data obtained from 55 of the network stations in the United States during the period from 1967 to 1971 are given in tabular form. Concentration values are reported for dissolved uranium, radium, gross alpha and gross beta radioactivity. Values are also given for suspended gross alpha radioactivity in terms of natural uranium. Suspended gross beta radioactivity is expressed both as the equilibrium mixture of strontium-90/yttrium-90 and as cesium-137. Other physical parameters reported which describe the samples include the concentrations of dissolved and suspended solids, the water temperature and stream discharge at the time of the sample collection.

Open-File Report↗
USGS2011

Water budgets and groundwater volumes for abandoned underground mines in the Western Middle Anthracite Coalfield, Schuylkill, Columbia, and Northumberland Counties, Pennsylvania: Preliminary estimates with identification of data needs

This report, prepared in cooperation with the Pennsylvania Department of Environmental Protection (PaDEP), the Eastern Pennsylvania Coalition for Abandoned Mine Reclamation, and the Dauphin County Conservation District, provides estimates of water budgets and groundwater volumes stored in abandoned underground mines in the Western Middle Anthracite Coalfield, which encompasses an area of 120 square miles in eastern Pennsylvania. The estimates are based on preliminary simulations using a groundwater-flow model and an associated geographic information system that integrates data on the mining features, hydrogeology, and streamflow in the study area. The Mahanoy and Shamokin Creek Basins were the focus of the study because these basins exhibit extensive hydrologic effects and water-quality degradation from the abandoned mines in their headwaters in the Western Middle Anthracite Coalfield. Proposed groundwater withdrawals from the flooded parts of the mines and stream-channel modifications in selected areas have the potential for altering the distribution of groundwater and the interaction between the groundwater and streams in the area. Preliminary three-dimensional, steady-state simulations of groundwater flow by the use of MODFLOW are presented to summarize information on the exchange of groundwater among adjacent mines and to help guide the management of ongoing data collection, reclamation activities, and water-use planning. The conceptual model includes high-permeability mine voids that are connected vertically and horizontally within multicolliery units (MCUs). MCUs were identified on the basis of mine maps, locations of mine discharges, and groundwater levels in the mines measured by PaDEP. The locations and integrity of mine barriers were determined from mine maps and groundwater levels. The permeability of intact barriers is low, reflecting the hydraulic characteristics of unmined host rock and coal. A steady-state model was calibrated to measured groundwater levels and stream base flow, the latter at many locations composed primarily of discharge from mines. Automatic parameter estimation used MODFLOW-2000 with manual adjustments to constrain parameter values to realistic ranges. The calibrated model supports the conceptual model of high-permeability MCUs separated by low-permeability barriers and streamflow losses and gains associated with mine infiltration and discharge. The simulated groundwater levels illustrate low groundwater gradients within an MCU and abrupt changes in water levels between MCUs. The preliminary model results indicate that the primary result of increased pumping from the mine would be reduced discharge from the mine to streams near the pumping wells. The intact barriers limit the spatial extent of mine dewatering. Considering the simulated groundwater levels, depth of mining, and assumed bulk porosity of 11 or 40 percent for the mined seams, the water volume in storage in the mines of the Western Middle Anthracite Coalfield was estimated to range from 60 to 220 billion gallons, respectively. Details of the groundwater-level distribution and the rates of some mine discharges are not simulated well using the preliminary model. Use of the model results should be limited to evaluation of the conceptual model and its simulation using porous-media flow methods, overall water budgets for the Western Middle Anthracite Coalfield, and approximate storage volumes. Model results should not be considered accurate for detailed simulation of flow within a single MCU or individual flooded mine. Although improvements in the model calibration were possible by introducing spatial variability in permeability parameters and adjusting barrier properties, more detailed parameterizations have increased uncertainty because of the limited data set. The preliminary identification of data needs includes continuous streamflow, mine discharge rate, and groundwater levels in the mines and adjacent areas. Data collected whe

Pennsylvania↗
USGS2024

Correlation analysis of groundwater and hydrologic data, Kaloko-Honokōhau National Historical Park, Hawai‘i

Designated in 1978, Kaloko-Honokōhau National Historical Park is located on the west coast of the Island of Hawaiʻi. The Kaloko-Honokōhau National Historical Park encompasses about 1,200 acres of coastal land and nearshore ecosystems, which include wetlands, anchialine pools (landlocked bodies of brackish water with hydrologic connections to the ocean), fishponds, a fishtrap, and coral reefs. These nearshore ecosystems are dependent on groundwater discharge with a freshwater component and provide habitat for threatened and endangered, endemic species, such as the orangeblack Hawaiian damselfly ( Megalagrion xanthomelas ) and the Hawaiian coot (ʻAlae keʻokeʻo, Fulica alai ). The populations of these native species, however, are threatened because of habitat loss related to urban development and environmental changes. Kaloko-Honokōhau National Historical Park is within the Keauhou aquifer system and the North Kona District, which experienced a 52 percent resident-population increase between 2000 and 2020 and a 41 percent visitor increase between 2008 and 2019. To support the current water demand associated with this growing population, groundwater is the primary source of freshwater used in the North Kona District, with about 15 million gallons of groundwater withdrawn from the Keauhou aquifer system per day since 2009. With anticipated development, future (2015–35) groundwater withdrawal from the Keauhou aquifer system is projected to be about 55 percent greater than recent (2012–14) withdrawal. Because Kaloko-Honokōhau National Historical Park is located within a coastal aquifer, natural and human-induced changes can affect the quality and quantity of groundwater, which can threaten groundwater-dependent ecosystems. To improve understanding of recent groundwater conditions, the U.S. Geological Survey, in cooperation with the National Park Service, undertook this study to document correlations between hydrologic time-series datasets from sites in and near Kaloko-Honokōhau National Historical Park using the nonparametric (distribution-free) Kendall’s tau statistical test. For the statistical analyses, dependent variables representing the groundwater system include groundwater level, the groundwater-level difference between pairs of sites, and specific conductance, and independent variables include datasets of sea level, rainfall, and groundwater withdrawal. About 34 percent of the 140 non-time-lagged Kendall’s tau statistical tests evaluated in this report are statistically significant ( p -value ≤ 0.050) with generally weak (0.1 ≤ tau ≤ 0.2) to moderate (0.2 ≤ tau ≤ 0.3) correlations. Groundwater levels measured at monitoring sites have the strongest correlation with the multivariate El Niño–Southern Oscillation index and withdrawal from production wells at the nearby Kohanaiki Private Club Community. Specific conductance is not consistently and significantly correlated with the independent hydrologic variables investigated in this report. Because the relations between hydrologic variables are commonly not instantaneous, a second set of correlations was evaluated after applying a range of time lags to the independent variable datasets. Relative to the non-time-lagged case (the set of correlations that did not use time-lagged independent variables), some of the time-lagged independent variables improved correlations with some of the dependent variables. For a particular independent variable, similar time lags were expected between the independent variable and dependent variable at all four monitoring sites. However, different time lags among the four sites sometimes produced the strongest correlations. This study identified several correlations that are statistically significant and hydrologically plausible, but the correlations could indicate that multiple concurrent factors are controlling the observed groundwater-system response, which might be better addressed using multivariate analyses. This study only investigates bivariate correlations, which may not explain all the variance in the data. The correlations analyzed in this report are limited by the quantity of available hydrologic data in the area near Kaloko-Honokōhau National Historical Park and are based on 14 years of time-series data, which were aggregated to a relatively coarse monthly temporal resolution that represents the minimum resolution common to all datasets.

Hawaii↗
USGS2019

Potential for increased inundation in flood-prone regions of southeast Florida in response to climate and sea-level changes in Broward County, Florida, 2060–69

The U.S. Geological Survey, in cooperation with Broward County Environmental Planning and Resilience Division, has developed county-scale and local-scale groundwater/surface-water models to study the potential for increased inundation and flooding in eastern Broward County that are due to changes in future climate and sea-level rise. These models were constructed by using MODFLOW 2005, with the surface-water system represented by using the Surface-Water Routing process and a new Urban Runoff process. The local-scale model allowed the use of finer grid resolution in a selected area of the county, whereas the county-scale model provided boundary conditions for the local-scale model and insight into the hydrologic behavior of the larger system. The aquifer layering, properties, and boundaries relied heavily on a previous three-dimensional variable-density solute-transport model of the same area developed by the U.S. Geological Survey. The surface-water system within these new models actively simulates a part of the extensive canal network by using level-pool routing and active structure operations within the Surface-Water Routing process. These models were used to simulate a historical base-case period (1990–99) by using measured data and regional climate model rainfall and potential evapotranspiration output. The simulated flow and water-level results generally captured the behavior of the hydrologic system. A future period (2060–69) was simulated by using regional climate model rainfall and potential evapotranspiration output representing a wetter and drier future and low, intermediate, and high sea-level rise projections. The results were used to evaluate the potential effects on the surface-water drainage system, coastal-structure operation, and wet-season groundwater levels. Future period simulations using the county-scale model indicate that (1) the effects of the changing climate and sea level are much more evident in eastern and coastal areas of Broward County compared to western areas, with increases in groundwater level nearly equivalent to sea-level rise; (2) coastal groundwater-level increases are distributed farther inland in the wetter future scenarios than in the drier future scenarios; (3) water levels at the westernmost groundwater station locations exhibited little change caused by sea-level rise and showed more dependence on changes in precipitation; (4) there was a reduced west-to-east groundwater gradient with increasing sea-level rise; and (5) increased downstream tidal stage at the S–13 structure resulted in increased reliance on the pump to control upstream inland canal stages. Future simulations using the local-scale model indicate similar behavior as seen in the county-scale model: (1) the coastal areas exhibited the largest impacts in groundwater levels in the future scenarios; (2) the westernmost, interior areas exhibited little change during the future scenarios; and (3) there was an increased reliance on the pump at the S–13 coastal structure but to a lesser extent than indicated in the county-scale model because of the reduced temporal scale of the local-scale model. Possible adaptation and mitigation strategies were simulated to evaluate the county-scale and local-scale models’ ability to simulate hydrologic changes. Alterations to S–13 pump operations within the county-scale model were tested, and results indicate a reduced effect of sea-level rise inland of the control structure, but the affected area is spatially limited. The concept of using pumps to reduce the local groundwater levels in two neighborhood-sized areas was tested by using the local-scale model. The MODFLOW 2005 Drain package was used to remove groundwater by using drainage elevations set to zero, 1 foot, and 2 feet above average wet-season groundwater levels. Area 1 was well connected to coastal boundaries, and a high rate of groundwater removal was required, whereas the rate of groundwater removal required was greatly reduced in Area 2, which is less connected to tidal boundaries. Water for these scenarios was assumed to be pumped to tide with no downstream effects.

Florida↗
USGS2008

Statistical analysis of major ion and trace element geochemistry of water, 1986-2006, at seven wells transecting the freshwater/saline-water interface of the Edwards aquifer, San Antonio, Texas

This report by the U.S. Geological Survey, in cooperation with the San Antonio Water System, describes the results of a statistical analysis of major ion and trace element geochemistry of water at seven wells transecting the freshwater/saline-water interface of the Edwards aquifer in San Antonio, Texas, either over time or in response to variations in hydrologic conditions. The data used in this report were collected during 1986–2006. The seven monitoring wells are screened at different depths in the aquifer at three sites that form a generally north-to-south transect. The three wells of the southern site and the deeper of the two middle-site wells are open to the freshwater/saline-water transition zone, which contains saline water. The shallower well of the middle site and the two wells of the northern site are open to the freshwater zone. Mean specific conductance (SC) values were greater at transition-zone wells than at freshwater-zone wells, but SC did not vary systematically with depth. Concentrations of all major ions except bicarbonate were greater at transition-zone wells than at freshwater-zone wells, but concentrations tended to be more variable at freshwater-zone wells. Mean molar ratios of magnesium:calcium, sulfate:chloride, and sodium:chloride were similar at transition-zone wells and freshwater-zone wells. Concentrations of trace elements for many water samples at the seven transect wells were below the laboratory analytical reporting level. Detections of trace elements were more frequent at transition-zone wells, and mean concentrations of cadmium, chromium, copper, lead, and silver were elevated at transition-zone wells relative to freshwater-zone wells. All strong correlations between SC and major ions were positive, and in general there were more and stronger correlations between SC and major ions in the water from the freshwater-zone wells than from the transition-zone wells. Except for the shallowest transition-zone well, the transition-zone wells had relatively few strong correlations overall. The lack of a strong correlation indicates that much of the variability in the major ion concentrations at these wells might be a result of analytical variability caused by the multiple laboratory analytical methods used. In most cases, strong correlations between concentrations of trace elements were positive, and transition-zone wells and freshwater-zone wells had water with a similar number of significant correlations. Principal components analysis indicates dilution of ground water by low-ionic-strength meteoric water at the three freshwater-zone wells and at the shallowest transition-zone well. At the two deeper transition-zone wells at the southern site, principal components analysis indicates that there is no systematic variation in major ion concentrations. At three transition-zone wells, there was a general trend toward less salinity over the 21-year period of sampling. Trends in SC at the freshwater-zone wells were less consistent. There is no systematic change in the direction of trend in SC by water type (saline or fresh), between sites, or with depth. In general, trends in major ion concentrations corresponded to those in SC. For each trace element over the 21-year sampling period, there was either no trend or a downward trend. Relations between SC, major ions, and major ion molar ratios and hydrologic indicators (concurrent or prior time-averaged measures of water level and effective rainfall) were investigated. Correlations between geochemical variables and measures of water level in the freshwater-zone wells were much more frequent than correlations between geochemical variables and measures of water level in the transition-zone wells. There were correlations between SC and all measures of water level at the two freshwater-zone wells at the northern site, but there were no correlations between SC and any measures of water level at any transition-zone wells. SC was correlated with effective rainfall at all freshwater-zone wells and at one transition-zone well. The statistical analyses taken together indicate that the geochemistry at the freshwater-zone wells is more variable than that at the transition-zone wells. The geochemical variability at the freshwater-zone wells might result from dilution of ground water by meteoric water. This is indicated by relatively constant major ion molar ratios; a preponderance of positive correlations between SC, major ions, and trace elements; and a principal components analysis in which the major ions are strongly loaded on the first principal component. Much of the variability at three of the four transition-zone wells might result from the use of different laboratory analytical methods or reporting procedures during the period of sampling. This is reflected by a lack of correlation between SC and major ion concentrations at the transition-zone wells and by a principal components analysis in which the variability is fairly evenly distributed across several principal components. The statistical analyses further indicate that, although the transition-zone wells are less well connected to surficial hydrologic conditions than the freshwater-zone wells, there is some connection but the response time is longer.

Texas↗
USGS1984

Hydrologic data: South Branch Casselman River, Garrett County, and Marsh Run, Washington County, Maryland

This report is a compilation of well construction data, lithologic and geophysical logs, and water level and water quality data for selected wells and springs in the South Branch Casselman River and Marsh Run drainage basins, Garrett and Washington Counties, Maryland. The report contains, for the two areas combined, records of 202 wells and 57 springs; periodic water level measurements and field determinations of specific conductance, pH, and water temperature for 33 wells and 7 springs; geophysical logs for 1 well and lithologic logs for 113 wells; and multi-year water-level data for 9 observation wells. (USGS)

Maryland↗
USGS1997

Hydrogeologic and water-quality data used to evaluate the effects of focused recharge on ground-water quality near Princeton, Minnesota, 1991-95

This study was part of the Management Systems Evaluation Area (MSEA) Program, a multi-scale, inter-agency initiative to evaluate the effects of agricultural systems on water quality in the midwest corn belt. The research was part of the U.S. Geological Survey Toxics Substances Hydrology Program. The research area was located in the Anoka Sand Plain about 5 kilometers southwest of Princeton, Minnesota. This report presents temperature, precipitation, soil-moisture, water-quality, and other data collected during 1991-95 to evaluate the effects of focused recharge on ground-water quality at the Princeton MSEA.

Minnesota↗
USGS2026

Post-wildfire water quality and aquatic ecosystem response in the U.S. Pacific Northwest: science and monitoring gaps

An increase in the occurrence of large, high severity wildfires in the western Pacific Northwest (PNW), USA, has created an urgent need for science to better inform forest management and policy decisions to maintain source water quality in the region. The western PNW faces similar challenges to other regions with shifting wildfire regimes and large population centers reliant on surface water from forested catchments. However, the uniquely wet and highly seasonal climate of the western PNW suggests that findings from other, more frequently burned regions may not be directly applicable. To identify science, monitoring, and management gaps and opportunities in the western PNW, this review was collaboratively undertaken by academics, non-government and industry representatives, and local, state, and federal government entities who have been working together since the 2020 Labor Day fires in Oregon. Focusing on Oregon and Washington, we found that monitoring networks for continuous water quantity and quality cover much of the state with greater representation in western U.S. ecoregions, but few studies have analyzed and published these data to capture and communicate the post-wildfire response. Approximately half of the streamgages in Oregon and Washington record major water quality parameters, and hundreds of sites in the area have discrete sampling for a wide range of water quality constituents. Still, numerous gaps exist in understanding the short- and long-term impacts of wildfire on hydrology, water chemistry, including pH and dissolved oxygen, mobilization of metals, aquatic ecosystems, and downstream drinking water treatment. Collective action to further collect, analyze, interpret, and publish the key data could help improve our understanding of post-wildfire water quality impacts in this and other increasingly wildfire-affected regions.

Oregon, Washington↗
USGS2018

Watershed ‘chemical cocktails’: forming novel elemental combinations in Anthropocene fresh waters

In the Anthropocene, watershed chemical transport is increasingly dominated by novel combinations of elements, which are hydrologically linked together as ‘chemical cocktails.’ Chemical cocktails are novel because human activities greatly enhance elemental concentrations and their probability for biogeochemical interactions and shared transport along hydrologic flowpaths. A new chemical cocktail approach advances our ability to: trace contaminant mixtures in watersheds, develop chemical proxies with high-resolution sensor data, and manage multiple water quality problems. We explore the following questions: (1) Can we classify elemental transport in watersheds as chemical cocktails using a new approach? (2) What is the role of climate and land use in enhancing the formation and transport of chemical cocktails in watersheds? To address these questions, we first analyze trends in concentrations of carbon, nutrients, metals, and salts in fresh waters over 100 years. Next, we explore how climate and land use enhance the probability of formation of chemical cocktails of carbon, nutrients, metals, and salts. Ultimately, we classify transport of chemical cocktails based on solubility, mobility, reactivity, and dominant phases: (1) sieved chemical cocktails (e.g., particulate forms of nutrients, metals and organic matter); (2) filtered chemical cocktails (e.g., dissolved organic matter and associated metal complexes); (3) chromatographic chemical cocktails (e.g., ions eluted from soil exchange sites); and (4) reactive chemical cocktails (e.g., limiting nutrients and redox sensitive elements). Typically, contaminants are regulated and managed one element at a time, even though combinations of elements interact to influence many water quality problems such as toxicity to life, eutrophication, infrastructure corrosion, and water treatment. A chemical cocktail approach significantly expands evaluations of water quality signatures and impacts beyond single elements to mixtures. High-frequency sensor data (pH, specific conductance, turbidity, etc.) can serve as proxies for chemical cocktails and improve real-time analyses of water quality violations, identify regulatory needs, and track water quality recovery following storms and extreme climate events. Ultimately, a watershed chemical cocktail approach is necessary for effectively co-managing groups of contaminants and provides a more holistic approach for studying, monitoring, and managing water quality in the Anthropocene.

Biogeochemistry↗
USGS2011

Simulating daily water temperatures of the Klamath River under dam removal and climate change scenarios

A one-dimensional daily averaged water temperature model was used to simulate Klamath River temperatures for two management alternatives under historical climate conditions and six future climate scenarios. The analysis was conducted for the Secretarial Determination on removal of four hydroelectric dams on the Klamath River. In 2012, the Secretary of the Interior will determine if dam removal and implementation of the Klamath Basin Restoration Agreement (KBRA) (Klamath Basin Restoration Agreement, 2010) will advance restoration of salmonid fisheries and is in the public interest. If the Secretary decides dam removal is appropriate, then the four dams are scheduled for removal in 2020. Water temperature simulations were conducted to compare the effect of two management alternatives: the no-action alternative where dams remain in place, and the action alternative where dam removal occurs in 2020 along with habitat restoration. Each management alternative was simulated under historical climate conditions (1961-2010) and six 50-year (2012-2061) climate scenarios. The model selected for the study, River Basin Model-10 (RBM10), was used to simulate water temperatures over a 253-mile reach of the Klamath River located in south-central Oregon and northern California. RBM10 uses a simple equilibrium flow model, assuming discharge in each river segment on each day is transmitted downstream instantaneously. The model uses a heat budget formulation to quantify heat flux at the air-water interface. Inputs for the heat budget were calculated from daily-mean meteorological data, including net shortwave solar radiation, net longwave atmospheric radiation, air temperature, wind speed, vapor pressure, and a psychrometric constant needed to calculate the Bowen ratio. The modeling domain was divided into nine reaches ranging in length from 10.8 to 42.4 miles, which were calibrated and validated separately with measured water temperature data collected irregularly from 1961 to 2010. Calibration root mean square errors of observed versus simulated water temperatures for the nine reaches ranged from 0.8 to 1.5 degrees C. Mean absolute errors ranged from 0.6 to 1.2 degrees C. For model validation, a k-fold cross-validation technique was used. Validation root mean square error and mean absolute error for the nine reaches ranged from 0.8 to 1.4 degrees C and 0.8 to 1.2 degrees C, respectively. Input data for the six future climate scenarios (2012-2061) were derived from historical hydrological and meteorological data and simulated meteorological output from five Global Circulation Models. Total Maximum Daily Loads or other regulatory processes that might reduce future water temperatures were not included in the simulations. Under the current climate conditions scenario, impacts of dam removal on water temperatures were greatest near Iron Gate Dam (near Yreka, California) and were attenuated in the lower reaches of the Klamath River. May and October simulated mean water temperatures increased and decreased by approximately 1-2 degrees C and 2-4 degrees C, respectively, downstream of Iron Gate Dam after dam removal. Dam removal also resulted in an earlier annual temperature cycle shift of 18 days, 5 days, and 2 days, near Iron Gate Dam, Scott River, and Trinity River, respectively. Although the magnitude of precipitation and air temperature change predicted by the five Global Circulation Models varied, all five models resulted in progressive incremental increases in water temperatures with each decade from 2012 to 2061. However, dam removal under KBRA appeared to delay the effects of climate change to some extent near Iron Gate Dam. With dam removal under KBRA, annual-mean water temperatures exceeded the 49-year historical mean temperature beginning in 2045; whereas with dams, annual-mean temperatures exceeded the historical mean beginning in 2025. Potential changes in seasonal water temperatures resulting from dam removal, with or without future climat

Open-File Report↗
USGS2019

Factors affecting the occurrence of lead and manganese in untreated drinking water from Atlantic and Gulf Coastal Plain aquifers, eastern United States—Dissolved oxygen and pH framework for evaluating risk of elevated concentrations

Groundwater samples collected during 2012 and 2013 from public-supply wells screened in the Atlantic and Gulf Coastal Plain aquifers of the eastern and southeastern U.S. rarely contained lead or manganese concentrations that exceeded drinking-water limits, despite having corrosive characteristics. Data indicate that the occurrence of dissolved lead and manganese in sampled groundwater, prior to its distribution or treatment, was related to several explanatory factors including the presence of source minerals, hydrologic position along the flow path, water-rock interactions, and associated geochemical conditions such as pH and dissolved oxygen (DO) concentrations. Elevated concentrations of lead compared to health-based benchmarks were associated with groundwater that is acidic (pH ≤ 6.5), oxygenated (DO ≥ 2 mg/L), and closer to recharge zones (relatively young water). Elevated concentrations of manganese were associated with groundwater that is acidic to neutral (pH ≤ 7.5), has low DO (<2 mg/L), and further from recharge zones (relatively old). Under these geochemical conditions, minerals that could sequester lead or manganese tended to be undersaturated, and adsorption by hydrous ferric oxide was limited. Under neutral to alkaline pH conditions, precipitation of impure calcium carbonate or phosphate compounds containing traces of lead or manganese (solid solutions) could maintain low concentrations of the trace elements. Additionally, adsorption of lead or manganese cations by hydrous ferric oxides (HFO) could be another attenuating factor where conditions are oxidizing and dissolved inorganic carbon concentrations are relatively low. A DO/pH framework was developed as a screening tool for evaluating risk of elevated lead or manganese, based on the occurrence of elevated lead and manganese concentrations and the corresponding distributions of DO and pH in the Atlantic and Gulf Coastal Plain aquifers. Validation of the DO/pH framework was accomplished using an independent national dataset that showed consistent results for elevated lead (pH ≤ 6.5; DO ≥ 2 mg/L) and manganese (pH ≤ 7.5; DO < 2 mg/L).

Atlantic and Gulf Coastal Plain aquifers↗