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At least 1,675 records · Page 93Linked to original sources

Hillslope hydrologic connectivity controls riparian groundwater turnover: Implications of catchment structure for riparian buffering and stream water sources

Hydrologic connectivity between catchment upland and near stream areas is essential for the transmission of water, solutes, and nutrients to streams. However, our current understanding of the role of riparian zones in mediating landscape hydrologic connectivity and the catchment scale export of water and solutes is limited. We tested the relationship between the duration of hillslope‐riparian‐stream (HRS) hydrologic connectivity and the rate and degree of riparian shallow groundwater turnover along four HRS well transects within a set of nested mountain catchments (Tenderfoot Creek Experimental Forest, MT). Transect HRS water table connectivity ranged from 9 to 123 days during the annual snowmelt hydrograph. Hillslope water was always characterized by low specific conductance (∼27 μ S cm −1 ). In transects with transient hillslope water tables, riparian groundwater specific conductance was elevated during base flow conditions (∼127 μ S cm −1 ) but shifted toward hillslope signatures once a HRS groundwater connection was established. The degree of riparian groundwater turnover was proportional to the duration of HRS connectivity and inversely related to the riparian: hillslope area ratios (buffer ratio; r 2 = 0.95). We applied this relationship to the stream network in seven subcatchments within the Tenderfoot Creek Experimental Forest and compared their turnover distributions to source water contributions measured at each catchment outlet. The amount of riparian groundwater exiting each of the seven catchments was linearly related ( r 2 = 0.92) to their median riparian turnover time. Our observations suggest that the size and spatial arrangement of hillslope and riparian zones along a stream network and the timing and duration of groundwater connectivity between them is a first‐order control on the magnitude and timing of water and solutes observed at the catchment outlet.

Water Resources Research↗

Urbanization and water management control stream water quality along a mountain to plains transition

Urbanization can have substantial effects on water quality due to altered hydrology and introduction of constituents to water bodies. In arid and semi-arid environments, streams are further stressed by dewatering as a result of diversions. We conducted a high-resolution synoptic survey of two streams in Colorado, USA that transition abruptly from granitic/metamorphic forested mountains to sedimentary urbanized plains and are both highly managed for water supply, yet differ in degree of urbanization. A synoptic mass balance approach developed for mine drainage applications was adapted to elucidate effects of urbanization, geology, and diversions on stream chemistry during baseflow conditions. Urbanization was a more important driver of stream concentrations than geology. The urban area was a strong source of bromide, calcium, chloride, and manganese, while lanthanum and dissolved organic carbon were primarily sourced from the mountains. A majority of streamflow was removed by diversions near the mountains/plains interface. Groundwater accounted for 31% of the subsequent flow increase to the urbanized stream, and delivered at least 33% of chloride loading. Constituents that were primarily urban-derived (bromide, calcium, chloride, and manganese) were 2–3 times higher in the urban region due to diversions; without diversions, stream water quality would have largely retained characteristics of forested streams through the urban reach. This study provides insights into processes that affect water quality in highly managed streams of the semi-arid western USA.

Colorado↗

Hydrogeology of the Old Faithful area, Yellowstone National Park, Wyoming, and its relevance to natural resources and infrastructure

A panel of leading experts (The Old Faithful Science Review Panel) was convened by Yellowstone National Park (YNP) to review and summarize the geological and hydrological understanding that can inform National Park Service management of the Upper Geyser Basin area. We give an overview of present geological and hydrological knowledge of the Old Faithful hydrothermal (hot water) system and related thermal areas in the Upper Geyser Basin. We prioritize avenues for improving our understanding of key knowledge gaps that limit informed decision-making regarding human use in this fragile natural landscape. Lastly, we offer guidelines to minimize impacts to the hydrothermal system that could be used to aid decisions by park management. Old Faithful sits within the Upper Geyser Basin, an area of abundant hydrothermal activity where boiling waters extend from the surface to significant depth within glacial sediments and underlying volcanic rocks. The geyser systems are directly fed by waters recharged decades to millennia ago, which are surrounded by colder, younger waters. Activity of the geysers is controlled by complex subsurface plumbing with fractures and conduits separated by regions of low permeability. Observations over the past century indicate that the thermal areas and their features are both fragile and highly dynamic. Although Old Faithful has erupted regularly for the past 150 years, it exhibits changes in eruptive behavior over time, and the average interval between eruptions has increased by about 50 percent over the past 50 years. It is clear that human activity has modified the hydrothermal system in the past; conversely, natural features pose ongoing hazards to humans and human infrastructure. Current (2014) long-term programs to measure heat discharge by chloride-flux monitoring, and more recently by thermal-infrared imaging, are crucial for assessing the status of the hydrothermal system. Complementary studies could include airborne resistivity, environmental tracers, numerical modeling, and greater emphasis on measuring the discharge of water during geyser eruptions. Such data are needed to better understand the subsurface plumbing systems that feed the geysers. Further understanding can be gained through installation of shallow groundwater observation wells, surface geophysical studies, and direct measurement of temperature gradients near the surface. It also is critical to archive existing data from all studies in a manner that will be readily accessible to scientists and decision makers. Monitoring and data collection can be achieved through the YNP geology program, by direct funding to other groups, or by encouraging and facilitating externally funded research. There are many documented examples at YNP and elsewhere where human infrastructure and natural thermal features have negatively affected each other. Unless action is taken, human conflicts with the Old Faithful hydrothermal system are likely to increase over the coming years. This is partly because of the increase in park visitation over the past decades, but also because the interval between eruptions of Old Faithful has increased, lengthening the time spent (and services needed) for each visitor at Old Faithful. To avoid an increase in visitor impacts, the National Park Service should consider 2 alternate strategies to accommodate people, vehicles, and services in the Upper Geyser Basin, such as shuttle services from staging (parking and dining) areas with little or no recent hydrothermal activity. We further suggest that YNP consider a zone system to guide maintenance and development of infrastructure in the immediate Old Faithful area. A “red” zone includes hydrothermally active land where new development is discouraged and existing infrastructure is modified with great care. An outer “green” zone represents areas where cooler temperatures and less hydrothermal flow are thought to exist, and where development and maintenance could proceed as occurs elsewhere in the park. An intermediate “yellow” zone would require preliminary assessment of subsurface temperatures and gas concentrations to assess suitability for infrastructure development. The panel recommends that YNP management follow the lead of the National Park System Advisory Board Science Committee (2012) by applying the “precautionary principle” when making decisions regarding the interaction of hydrothermal phenomena and park infrastructure in the Old Faithful area and other thermal areas within YNP.

Wyoming↗

Nitrate in watersheds: straight from soils to streams?

Human activities are rapidly increasing the global supply of reactive N and substantially altering the structure and hydrologic connectivity of managed ecosystems. There is long-standing recognition that N must be removed along hydrologic flowpaths from uplands to streams, yet it has proven difficult to assess the generality of this removal across ecosystem types, and whether these patterns are influenced by land-use change. To assess how well upland nitrate (NO 3 - ) loss is reflected in stream export, we gathered information from >50 watershed biogeochemical studies that reported nitrate concentrations ([NO 3 - ]) for stream water and for either upslope soil solution or groundwater NO 3 - to examine whether stream export of NO3- accurately reflects upland NO 3 - losses. In this dataset, soil solution and streamwater [NO 3 - ] were correlated across 40 undisturbed forest watersheds, with streamwater [NO 3 - ] typically half (median = 50%) soil solution [NO 3 - ]. A similar relationship was seen in 10 disturbed forest watersheds. However, for 12 watersheds with significant agricultural or urban development, the intercept and slope were both significantly higher than the relationship seen in forest watersheds. Differences in concentration between soil solution or groundwater and stream water may be attributed to biological uptake, microbial processes including denitrification, and/or preferential flow routing. The results of this synthesis are consistent with the hypotheses that undisturbed watersheds have a significant capacity to remove nitrate after it passes below the rooting zone and that land use changes tend to alter the efficiency or the length of watershed flowpaths, leading to reductions in nitrate removal and increased stream nitrate concentrations.

Journal of Geophysical Research G: Biogeosciences↗

Stream‐centric methods for determining groundwater contributions in karst mountain watersheds

Climate change influences on mountain hydrology are uncertain, but likely to be mediated through changes in subsurface hydrologic residence times and flowpaths. The heterogeneity of karst aquifers add complexity in assessing the resiliency of these water sources to perturbation, suggesting a clear need to quantify contributions from and losses to these aquifers. Here we develop a stream centric method that combines mass and flow balances to quantify net and gross gains and losses at different spatial scales. We then extend these methods to differentiate between karst conduit and matrix contributions from the aquifer. In the Logan River watershed in Northern Utah we found significant amounts of the river water repeatedly gained and then lost through a 35 km study reach. Further, the direction and amount of water exchanged varied over space, time, and discharge. Streamflow was dominated by discharge of karst conduit groundwater after runoff with increasing, yet still small, fractions of matrix water later in the summer. These findings were combined with geologic information, prior subsurface dye tracing, and chemical sampling to provide additional lines of evidence that repeated groundwater exchanges are likely occurring and river flows are highly dependent on karst aquifer recharge and discharge. Given the large population dependent on karst aquifers throughout the world, there is a continued need to develop simple methods, like those presented here, for determining the resiliency of karst groundwater resources.

Water Resources Research↗

Multispecies reactive tracer test in an aquifer with spatially variable chemical conditions, Cape Cod, Massachusetts: Dispersive transport of bromide and nickel

Dispersive transport of groundwater solutes was investigated as part of a multispecies reactive tracer test conducted under spatially variable chemical conditions in an unconfined, sewage‐contaminated sand and gravel aquifer on Cape Cod, Massachusetts. Transport of the nonreactive tracer bromide (Br) reflected physical and hydrologic processes. Transport of the reactive tracer nickel (Ni) complexed with an organic ligand (NiEDTA) varied in response to pH and other chemical conditions within the aquifer. A loss of about 14% of the Ni mass was calculated from the distribution of tracers through time. This loss is consistent with reversible adsorption of NiEDTA onto the iron and aluminum oxyhydroxide coatings on the aquifer sediments. The Ni consistently lagged behind Br with a calculated retardation coefficient of 1.2. Longitudinal dispersivities reached constant values of 2.2 and 1.1 m for Br and Ni, respectively, by at least 69 m of travel. The smaller dispersivity for Ni possibly was due to nonlinear or spatially variant adsorption of NiEDTA. In the upper, uncontaminated zone of the aquifer, longitudinal dispersion of Ni was greater than that of Br early in the test as a result of reversible adsorption of NiEDTA. In general, transverse dispersivities were much smaller (horizontal: 1.4–1.5 × 10 −2 m; vertical: 0.5–3.8 × 10 −3 m) than the longitudinal dispersivities. The Br results are similar to those from a test conducted eight years earlier, suggesting that transport parameters are spatially stationary within the aquifer at the scale of 300 m covered by the spatially overlapping tests. A significant difference between the two tests was the travel distance (69 and 26 m) needed to reach a constant longitudinal dispersivity.

Massachusetts↗

Hydrological mobilization of mercury and dissolved organic carbon in a snow-dominated, forested watershed: Conceptualization and modeling

The mobilization of mercury and dissolved organic carbon (DOC) during snowmelt often accounts for a major fraction of the annual loads. We studied the role of hydrological connectivity of riparian wetlands and upland/wetland transition zones to surface waters on the mobilization of Hg and DOC in Fishing Brook, a headwater of the Adirondack Mountains, New York. Stream water total mercury (THg) concentrations varied strongly (mean = 2.25 ± 0.5 ng L −1 ), and the two snowmelt seasons contributed 40% (2007) and 48% (2008) of the annual load. Methyl mercury (MeHg) concentrations ranged up to 0.26 ng L −1 , and showed an inverse log relationship with discharge. TOPMODEL‐simulated saturated area corresponded well with wetland areas, and the application of a flow algorithm based elevation‐above‐creek approach suggests that most wetlands become well connected during high flow. The dynamics of simulated saturated area and soil storage deficit were able to explain a large part of the variation of THg concentrations (r 2 = 0.53 to 0.72). In contrast, the simulations were not able to explain DOC variations and DOC and THg concentrations were not correlated. These results indicate that all three constituents, THg, MeHg, and DOC, follow different patterns at the outlet: (1) the mobilization of THg is primarily controlled by the saturation state of the catchment, (2) the dilution of MeHg suggests flushing from a supply limited pool, and (3) DOC dynamics follow a pattern different from THg dynamics, which likely results from differing gain and/or loss processes for THg and/or DOC within the Fishing Brook catchment.

New York↗

Hydrology of the North Cascades region, Washington: 1. Runoff, precipitation, and storage characteristics

The time and space distributions of measured precipitation and measured runoff and of spring storage, which is approximately equal to the subsequent summer runoff of snowmelt and stored groundwater, have been analyzed for the North Cascades region of Washington. Neither precipitation nor runoff shows a consistent relationship with altitude, chiefly because of precipitation-shadowing effects in this region of high relief. The relationship between mean annual precipitation and altitude is improved considerably when a topographic mean altitude is used instead of the actual altitude of the weather station. However, the improvement is not sufficient to explain a number of discrepancies that still occur. Some of the scatter in a precipitation-altitude plot appears to be due to a deficient precipitation catch by high-altitude gages. When the dependence of runoff on precipitation was examined on an annual, seasonal, and monthly basis, it was found that only a few low-altitude gages correlated well with basin runoff. In several instances, annual (water year) runoff could be better predicted from winter precipitation than from annual precipitation. Precipitation and runoff were tested for changes with time and both appeared to have been increasing slightly but not at a statistically significant level. When the summer (May–September) fraction of the total annual runoff is plotted against mean basin altitude, a consistent, physically reasonable, mildly curvilinear relationship is revealed. On the basis of this relationship, by using several drainages with diverse area-altitude profiles the spring storage versus altitude distribution can be estimated for each basin. The area-altitude distribution is used instead of the mean altitude in this calculation because of the apparent nonlinear relationship between runoff and altitude.

Washington↗

Using dissolved organic matter fluorescence to predict total mercury and methylmercury in forested headwater streams, Sleepers River, Vermont USA

Aqueous transport of mercury (Hg) across the landscape is closely linked to dissolved organic matter (DOM). Both quantity and quality of DOM affect Hg mobility, as well as the formation and transport of toxic methylmercury (MeHg), but only a limited number of field studies have investigated Hg and MeHg with respect to specific DOM components. We investigated these interactions at the 41-ha forested W-9 catchment at Sleepers River, Vermont, which has a long history of mercury and other biogeochemical research. We examined spatial and temporal patterns of filtered Hg fractions and dissolved organic carbon (DOC) concentration, DOM quality, and major solutes at 12 stream sites within W-9 and the downstream W-3 gage (837 ha) over five sampling campaigns including a large (79 mm) fall storm, spring snowmelt, and three seasonally contrasting base flow periods. Filtered total Hg (THg), MeHg, and DOC concentrations increased in order base flow < snowmelt < fall storm, except that MeHg remained at baseflow levels during snowmelt. Ranges of median concentrations across sites for the five campaigns were THg, <0.2–4.1 ng L −1 ; MeHg, <0.03–0.45 ng L −1 ; and DOC, 0.8–14.0 mg L −1 . Humic-like DOM fluorescence components, as determined by parallel factor analysis (PARAFAC), dominated the fluorescence across sites and sampling campaigns. THg correlated strongly ( r > 0.94) with these humic components, but even more strongly with bulk DOC and absorbance at 254 nm (UV 254 ; r > 0.96), and less strongly with protein-like DOM (0.7 < r < 0.9). MeHg correlated in the same order but less strongly with humic- (0.8 < r < 0.9) and protein-like (0.6 < r < 0.8) DOM. MeHg increased in summer, potentially in response to enhanced microbial production in warmer periods. MeHg formation may have been linked to protein-like DOM, but its transport was linked to humic-like DOM.

Vermont↗

Aggradation of gravels in tidally influenced fluvial systems: Upper Albian (Lower Cretaceous) on the cratonic margin of the North American Western Interior foreland basin

Alluvial conglomerates were widely distributed around the margin of the Early Cretaceous North American Cretaceous Western Interior Seaway (KWIS). Conglomerates, sandstones, and lesser amounts of mudstones of the upper Albian Nishnabotna Member of the Dakota Formation were deposited as fill-in valleys that were incised up to 80 m into upper Paleozoic strata. These paleovalleys extended southwestward across present-day northwestern Iowa into eastern Nebraska. Conglomerate samples from four localities in western Iowa and eastern Nebraska consist mostly of polycrystalline quartz with lesser amounts of microcrystalline (mostly chert), and monocrystalline quartz. Previous studies discovered that some chert pebbles contain Ordovician-Pennsylvanian invertebrate fossils. The chert clasts analyzed in this study were consistent with these findings. In addition, we found that non-chert clasts consist of metaquartzite, strained monocrystalline quartz and 'vein' quartz from probable Proterozic sources, indicating that parts of the fluvial system's sediment load must have travelled distances of 400-1200 km. The relative tectonic stability of this subcontinent dictated that stream gradients were relatively low with estimates ranging from 0.3 to 0.6 m/km. Considering the complex sedimentologic relationships that must have been involved, the ability of low-gradient easterly-sourced rivers to entrain gravel clasts was primarily a function of paleodischarge rather than a function of steep gradients. Oxygen isotopic evidence from Albian sphaerosiderite-bearing paleosols in the Dakota Formation and correlative units from Kansas to Alaska suggest that mid-latitude continental rainfall in the Albian was perhaps twice that of the modern climate system. Hydrologic fluxes may have been related to wet-dry climatic cycles on decade or longer scales that could account for the required water supply flux. Regardless of temporal scale, gravels were transported during 'high-energy' pulses, under humid climatic conditions in large catchment areas. An overall rising sea level during the late Albian created accommodation space for the gravelly lithofacies equivalent to the Kiowa-Skull Creek rocks. As Western Interior sea level rose, regional stream gradients were reduced, resulting in regional fluvial aggradation. The conglomeratic lower parts of the Nishnabotna Member of the Dakota Formation formed the transgressive systems tract within an upper Albian sequence that is defined by two unconformities that can be traced from marine Kiowa strata in western Kansas northeastward into western Iowa (Brenner et al., 2000). Mud-draped cross-bedded sandstone bodies, laminated mudstone intervals, and vertical burrows in the lower strata of the Nishnabotna Member indicate that estuarine conditions existed at the mouths of the river system, and tidal effects were transmitted at least 200 km inland from the interpreted late Albian coast. These observations suggest that estuarine conditions stepped up the incised valleys as fluvial sediments aggraded in response to regional transgression that continued through the Late Albian. ?? 2003 Elsevier Ltd. All rights reserved.

Cretaceous Research↗

El Niño increases high‐tide flooding in tidal wetlands along the U.S. Pacific coast.

Periodic oscillations between El Niño and La Niña conditions in the Pacific Basin affect oceanographic and meteorological phenomena globally, with impacts on the abundance and distribution of marine species. However, El Niño effects on estuarine hydrology and tidal wetland processes have seldom been examined rigorously. We used detailed wetland elevation and local inundation data from 10 tidal wetlands located along the Pacific coast of the United States to assess changes in flooding during the 2015–2016 El Niño and to determine decadal‐scale relationships between estuarine sea‐level anomalies and Pacific Basin climate indices for this region. During the 2015–2016 El Niño all sites experienced significant increases in high‐tide water levels exceeding those predicted by astronomical tides, and increased flooding frequency during at least one of the El Niño subperiods relative to pre‐El Niño conditions. The magnitude of positive sea‐level anomalies varied by site (4–15 cm), with local hot spots of high water in southern Oregon, northern California, and Pt. Mugu lagoon in the Southern California Bight. Furthermore, over the last three decades of historic tide records, there were positive relationships between high‐tide sea‐level anomalies and equatorial Pacific Basin sea surface temperature anomalies across the region, and negative relationships with the Northern Oscillation Index. Increases of 1 °C in equatorial sea surface temperature were associated with 3–5 cm of increased high‐tide flooding at the sites. Elevated estuarine flooding associated with future El Niños could impact important tidal wetland processes and could be an additive stressor for wetlands facing accelerating sea‐level rise.

California, Oregon, Washington↗

Stochastic watershed model ensembles for long-range planning: Verification and validation

Deterministic watershed models (DWMs) are used in nearly all hydrologic planning, design, and management activities, yet they cannot generate streamflow ensembles needed for hydrologic risk management (HRM). The stochastic component of DWMs is often ignored in practice, leading to a systematic bias in extreme events. Since traditional stochastic streamflow models used in HRM struggle to account for anthropogenic change, there is a need to convert DWMs into stochastic watershed models (SWMs) to generate ensembles for use in HRM. A DWM can be converted to an SWM using a post-processing (pp) approach to add error to the DWM predictions. Many pp methods advanced in the area of flood forecasting are useful in HRM and for correcting extreme event biases. Selecting a suitable error model for pp is challenging due to nonnormality, skewness, heteroscedasticity, and autocorrelation. We develop a parsimonious pp method based on an autoregressive (AR) model of the logarithm of the ratio of the observations and simulations, which leads to AR model residuals that are approximately symmetric and independent. We document the value of pp for improving flood and low flow frequency analysis and we reintroduce the concepts of verification and validation of stochastic streamflow ensembles to ensure that the SWM can reproduce both statistics it was and was not designed to reproduce, respectively. These concepts are illustrated on a Massachusetts basin using the USGS Precipitation Runoff Modeling System, with an additional analysis indicating the approach may be applicable to 1,225 other sites across the United States.

Massachusetts, New Hampshire↗

Flow reconstructions in the Upper Missouri River Basin using riparian tree rings

River flow reconstructions are typically developed using tree rings from montane conifers that cannot reflect flow regulation or hydrologic inputs from the lower portions of a watershed. Incorporating lowland riparian trees may improve the accuracy of flow reconstructions when these trees are physically linked to the alluvial water table. We used riparian plains cottonwoods ( Populus deltoides ssp. monilifera ) to reconstruct discharge for three neighboring rivers in the Upper Missouri River Basin: the Yellowstone ( n = 389 tree cores), Powder ( n = 408), and Little Missouri Rivers ( n = 643). We used the Regional Curve Standardization approach to reconstruct log-transformed discharge over the 4 months in early summer that most highly correlated to tree ring growth. The reconstructions explained at least 57% of the variance in historical discharge and extended back to 1742, 1729, and 1643. These are the first flow reconstructions for the Lower Yellowstone and Powder Rivers, and they are the furthest downstream among Rocky Mountain rivers in the Missouri River Basin. Although mostly free-flowing, the Yellowstone and Powder Rivers experienced a shift from early-summer to late-summer flows within the last century. This shift is concurrent with increasing irrigation and reservoir storage, and it corresponds to decreased cottonwood growth. Low-frequency flow patterns revealed wet conditions from 1870 to 1980, a period that includes the majority of the historical record. The 1816–1823 and 1861–1865 droughts were more severe than any recorded, revealing that drought risks are underestimated when using the instrumental record alone.

Water Resources Research↗

Performance mapping and weighting for the evapotranspiration models of the OpenET ensemble

Evapotranspiration (ET) accounts for the majority of water available from precipitation in the terrestrial water cycle, and improvements to the accuracy, resolution, and coverage of ET data can enhance hydrologic models and assessments. The OpenET collaboration of six remotely sensed ET modeling teams has demonstrated that an ensemble approach to ET estimation generally provides improved accuracy relative to individual ensemble members. The performance of individual models has been shown to vary by land cover type and climate zone, but a thorough study of the variables that influence model performance differences has not yet been conducted. In this paper, we model the performance of OpenET models relative to flux tower data as a function of variables such as land cover type and precipitation. These performance models are used to map estimated OpenET model performance across the conterminous United States. We develop relative weights based on these modeled performance metrics and show that a performance-weighted ensemble improves accuracy relative to the current OpenET ensemble method to varying degrees. The monthly mean absolute error of the weighted ensemble is reduced relative to the current method by 8% in agricultural settings, by 23% in shrublands and mixed forests, and by 5% in grasslands and evergreen forests. We produce weight maps that can be used to generate performance-weighted ensemble values for OpenET data. The results can be used to inform model selection and provide insight about the controls on model performance that could lead to model refinement.

Water Resources Research↗

The ecological condition of estuaries in the Gulf of Mexico

The Gulf of Mexico is a vast natural resource encompassing the coastal areas of western Florida, Alabama, Mississippi, Louisiana, and Texas, as well as a portion of Mexico. Many estuaries flow into the Gulf of Mexico and serve as nursery grounds for fish, habitat for a wide variety of wildlife, shipping routes, and a source of recreation. Estuarine-dependent species constitute more than 95 percent of the commercial fishery harvests from the Gulf of Mexico, and many important recreational fishery species depend on estuaries during some part of their life cycle. Gulf estuaries are diverse and productive ecosystems that provide a variety of valuable resources, including fish and shellfish, recreation, transportation, and water supply. Assessing the overall condition of Gulf of Mexico estuaries required incorporating data from other federal, state, and local monitoring programs to augment the information on ecological indicators collected by the U.S. Environmental Protection Agency’s (USEPA) Environmental Monitoring and Assessment Program (EMAP). The resulting document would provide a synthesis of the available knowledge about the condition of Gulf of Mexico estuaries. This document is intended for use by scientists and other citizens concerned with the ecological condition of estuaries, as well as by managers and lawmakers interested in the sustained use of estuaries for commercial and recreational purposes. It also addresses public concerns about the aesthetic quality of coastal areas vital to tourism and recreation. By producing this report on the ecological condition of estuaries in the Gulf of Mexico, we have taken one step in assessing the health of this environmental resource. We have produced an environmental “report card” to be used as a guide in the evaluation of management decisions and research directions. This report is organized in three parts: (1) an introduction that gives background information on the Gulf of Mexico, estuarine ecology, and the factors that impact estuaries in the gulf, (2) the main section on priority ecological indicators used to measure the condition of estuaries in the gulf and (3) an ecological report card that summarizes the data on ecological indicators and provides a rating of the condition of estuaries in each gulf state and for gulf estuaries overall. Many of the ratings were based on the percent area of estuaries in each state exhibiting degraded or adverse levels of an indicator. Eutrophication, a condition of high nutrients often resulting in low oxygen levels and other adverse effects, is an important water quality concern for estuaries along the gulf coast. The National Oceanic and Atmospheric Administration (NOAA) has compared the Gulf of Mexico to other coastal regions like the middle Atlantic and has ranked the Gulf of Mexico as having the highest number of point sources of nutrients and the highest percentage of land use devoted to agriculture. We evaluated monitoring data for nitrogen, chlorophyll, and dissolved oxygen as indicators of eutrophication. Although most of the estuaries exhibited high nitrogen or chlorophyll or low dissolved oxygen concentrations at least once during a survey, many times these conditions were observed in small rivers or bayous rather than in the entire estuary. Often, the percent area affected was low. The gulf estuaries had moderate conditions overall for nutrients and dissolved oxygen. Definite nutrient problems were observed in >25% of the estuarine area in Louisiana and Texas and definite dissolved oxygen problems were observed in Alabama. Contaminants in estuarine sediments provide evidence of the accumulation of chemicals from anthropogenic sources. We compared the concentrations of sediment contaminants to established guideline values to determine the proportion of estuarine area that could have potential adverse effects on living organisms. Although detectable levels of contaminants were measured in almost every estuary in the Gulf of Mexico, <25% of the estuarine area in all states had contaminant concentrations that exceeded these guidelines. Wetlands are integral parts of estuarine systems. Declining acreage means habitat loss that may be the result of commercial and residential development, hydrologic alterations, or dredge and fill operations. The Gulf of Mexico region contains more than 50% of the coastal wetland acreage in the U.S. and yet it also has the highest rate of coastal wetland loss. Nine of the top ten estuarine drainage areas ranked by total wetland area are in the Gulf of Mexico region. The most current estimates of total wetland loss over the past 200 years range from 41% to 54% for the gulf states. Although coastal wetlands continue to be altered or destroyed, some estimates indicate that the rate of loss has slowed. All gulf states were rated as having severe problems with wetland loss. The condition of benthic (bottom-dwelling) invertebrates, fish and shellfish, birds, and threatened and endangered species was used to evaluate the health of estuarine fauna. Degraded benthic communities inhabited <25% of the estuarine area in all gulf states except for Texas. Commercial fish and shellfish landings may be used as an indicator of population stability while fish biomarkers are used to measure the health of individuals in the population. Commercial landings of the top four fisheries (shrimp, menhaden, blue crab, and oyster) are stable in the gulf states while fish biomarkers indicate fair to poor fish health in Alabama and Texas and good fish health elsewhere. Coastal and marine bird populations appear to be in good condition throughout the gulf. Four threatened or endangered species inhabit coastal areas in the Gulf of Mexico: brown pelican, Gulf sturgeon, manatee, and Kemp’s ridley sea turtle. In general, populations of these species are in good to fair condition in the gulf states. Public health indicators include shellfish bed closures and chemicals found in edible fish tissue. Harvest of shellfish (primarily oyster in the Gulf of Mexico) is restricted or prohibited when concentrations of bacteria or other pathogens reach levels that could impair human health. The gulf states contain the most acreage of shellfish-growing waters in the U.S. but also have the most acreage restricted for harvest. All gulf states except Mississippi have >25% of their shellfish-growing waters restricted for harvest, mostly due to pollution from wastewater treatment plants or other upstream sources. Advisories may be issued that limit consumption when the concentrations of chemicals in fish tissue exceed levels known to be harmful to humans. Although seafood consumption advisories have been issued in all gulf states, the percent of the fish population with high concentrations of contaminants is relatively low in the gulf overall.

Alabama, Florida, Louisiana, Mississippi, Texas↗

Modeling thermal dynamics of active layer soils and near-surface permafrost using a fully coupled water and heat transport model

Thawing and freezing processes are key components in permafrost dynamics, and these processes play an important role in regulating the hydrological and carbon cycles in the northern high latitudes. In the present study, we apply a well-developed soil thermal model that fully couples heat and water transport, to simulate the thawing and freezing processes at daily time steps across multiple sites that vary with vegetation cover, disturbance history, and climate. The model performance was evaluated by comparing modeled and measured soil temperatures at different depths. We use the model to explore the influence of climate, fire disturbance, and topography (north- and south-facing slopes) on soil thermal dynamics. Modeled soil temperatures agree well with measured values for both boreal forest and tundra ecosystems at the site level. Combustion of organic-soil horizons during wildfire alters the surface energy balance and increases the downward heat flux through the soil profile, resulting in the warming and thawing of near-surface permafrost. A projection of 21st century permafrost dynamics indicates that as the climate warms, active layer thickness will likely increase to more than 3 meters in the boreal forest site and deeper than one meter in the tundra site. Results from this coupled heat-water modeling approach represent faster thaw rates than previously simulated in other studies. We conclude that the discussed soil thermal model is able to well simulate the permafrost dynamics and could be used as a tool to analyze the influence of climate change and wildfire disturbance on permafrost thawing.

Journal of Geophysical Research D: Atmospheres↗

Active neutron interrogation experiments and simulation verification using the SIngle-scintillator Neutron and Gamma-Ray spectrometer (SINGR) for geosciences

We present a new SIngle-scintillator Neutron and Gamma Ray spectrometer (SINGR) instrument for use with both passive and active measurement techniques. Here we discuss the application of SINGR for planetary exploration missions, however, hydrology, nuclear non-proliferation, and resource prospecting are all potential areas where the instrument could be applied. SINGR uses an elpasolite scintillator, Cs 2 YLiCl 6 :Ce (CLYC), that has been shown to have high neutron efficiency even at small volumes, with a gamma-ray energy resolution of approximately 4% full-width-at-half-maximum at 662 keV. Active gamma-ray and neutron (GRNS) measurements were performed with SINGR at the NASA Goddard Space Flight Center (GSFC) Goddard Geophysical and Astronomical Observatory (GGAO) outdoor test site using a pulsed neutron generator (PNG) to interrogate geologically relevant materials (basalt and granite monuments). These experimental results, combined with simulations, demonstrate that SINGR is capable of generating neutron die-away curves that can be used to reconstruct the bulk hydrogen abundance and the depth distribution of hydrogen within the monuments. We compare our experimental results with Monte Carlo N-Particle (MCNP) 6.1 transport simulations to constrain the uncertainties in depth and hydrogen abundance from the neutron die-away data generated by SINGR. For future planetary exploration missions, SINGR provides a single detector system for interrogating the shallow subsurface to characterize the presence and abundance of hydrated phases and to provide bulk elemental analysis.

Nuclear Instruments and Methods in Physics Researc↗

Seasonal ice and hydrologic controls on dissolved organic carbon and nitrogen concentrations in a boreal-rich fen

[1] Boreal wetland carbon cycling is vulnerable to climate change in part because hydrology and the extent of frozen ground have strong influences on plant and microbial functions. We examined the response of dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) across an experimental manipulation of water table position (both raised and lowered water table treatments) in a boreal-rich fen in interior Alaska. DOC and TDN responses to water table manipulation exhibited an interaction with seasonal ice dynamics. We observed consistently higher DOC and TDN concentrations in the lowered water table treatment (71.7 ± 6.5 and 3.0 ± 0.3 mg−L) than in both the control (55.6 ± 5.1 and 2.3 ± 0.2 mg−L) and raised (49.1 ± 4.3 and 1.9 ± 0.1 mg L−1, respectively) water table treatments. Across all plots, pore water DOC concentrations at 20 cm increased as the depth to water table increased (R2 = 0.43, p < 0.001). DOC concentrations also increased as the seasonal thaw depth increased, with solutes increasing most rapidly in the drained plot (R2 = 0.62, p < 0.001). About half of the TDN pool was composed of dissolved organic N (DON). Inorganic N and DON were both highly correlated with changes in DOC, and their respective constraints to mineralization are discussed. These results demonstrate that a declining water table position and dryer conditions affect thaw depth and peat temperatures, and interactions among these ecosystem properties will likely increase DOC and TDN loading and potential for export in these systems.

Alaska↗