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At least 1,675 records · Page 93Linked to original sources
USGS1994

Uranium(VI) adsorption to ferrihydrite: Application of a surface complexation model

A study of U(VI) adsorption by ferrihydrite was conducted over a wide range of U(VI) concentrations, pH, and at two partial pressures of carbon dioxide. A two-site (strong- and weak-affinity sites, Fe s OH and Fe w OH, respectively) surface complexation model was able to describe the experimental data well over a wide range of conditions, with only one species formed with each site type: an inner-sphere, mononuclear, bidentate complex of the type (FeO 2 )UO 2 . The existence of such a surface species was supported by results of uranium EXAFS spectroscopy performed on two samples with U(VI) adsorption density in the upper range observed in this study (10 and 18% occupancy of total surface sites). Adsorption data in the alkaline pH range suggested the existence of a second surface species, modeled as a ternary surface complex with UO 2 CO 3 0 binding to a bidentate surface site. Previous surface complexation models for U(VI) adsorption have proposed surface species that are identical to the predominant aqueous species, e.g., multinuclear hydrolysis complexes or several U(VI)-carbonate complexes. The results demonstrate that the speciation of adsorbed U(VI) may be constrained by the coordination environment at the surface, giving rise to surface speciation for U(VI) that is significantly less complex than aqueous speciation.

Geochimica et Cosmochimica Acta↗
USGS1994

Cyclic variations of sulfur isotopes in Cambrian stratabound Ni-Mo-(PGE-Au) ores of southern China

Cyclic variations of δ 34 S values over a range of at least 48‰ in pyrite nodules from stratabound Ni-Mo-PGE(Au) ores of southern China are attributed to biogenic reduction of seawater sulfate in an anoxic, phosphogenic, and metallogenic basin. Cyclic introduction and mixing of normal seawater into typically stagnant basin waters led to extreme variations in δ 34 S values of aqueous sulfide species present at different times. Intermittent venting of metal-laden hydrothermal fluids into such a bacteriogenic sulfide-rich environment resulted in precipitation of metal sulfides as pseudomorphous replacements of organic debris and as sulfide sediments that record large δ 34 S CDT variations from −26 to +22‰. Apatite and silica dominated the replacement of the organic debris when metals were not being introduced into the basin. The combination of abundant organic debris, localized topographic basins for accumulation of the debris, bacterial production of sulfide species, and introduction of metal-bearing hydrothermal fluids provided the environment necessary to form these unusually rich Ni-Mo ores.

Geochimica et Cosmochimica Acta↗
USGS1963

Applications of geohydrologic concepts in geology

Subsurface water, an active agent in many geologic proceses, must be considered in interpreting geologic phenomena. Principles of the occurrence, distribution, and movement of subsurface waters are well established and readily applicable. In many interpretations in geologic literature, geohydrologic principles have been employed realistically, but in many others these principles have been either ignored or violated. Explanations of genesis of underclays and associated deposits afford some examples wherein principles of movement and activity of vadose and ground water have been ignored and others in which they have been used advantageously. Postulates stating that waters percolate downward from swamp areas do not allow for the usual movement of subsurface water in such environments. The idea that sediments were leached by vadose water after uplift satisfies the geohydrologic requirements. Weathering and solution form porous and permeable zones subjacent to unconformities in dense rocks such as carbonates and granites; this illustrates the geohydrologic and economic significance of unconformities. Examples are Mohawkian carbonate aquifers of northern Illinois and oil-bearing limestones of Mississippian age of eastern Montana. The flushing effects of meteoric water and other hydrodynamic factors active during erosion periods are important elements in the genesis and concentration of brines. Explanation of the origin and occurrence of brines must include consideration of the geohydrologic environments throughout their geologic history.

Journal of Hydrology↗
USGS1973

Karst hydrology: A review

Karst regions of the world are characterized by limestones and other soluble rocks at or near land surface that have been modified by solutional erosion. Such surface features as sinks, long dry valleys, sparse streams, and bare rock and such subsurface features as caverns, arterial solution openings leading to large springs, and a deep water table are typical of karst terranes. These features result in an uneven distribution of permeability in karst systems and surface and subsurface hydrologic conditions that require special hydrogeologic studies. Local high permeability at shallow depth in mature karst regions leads to an ecology associated with a soilless and water-scarce surface environment. Many practical problems result from this high permeability, including: (1) scarcity and poor predictability of groundwater supplies; (2) scarcity of surface-water supplies; (3) instability of the ground; (4) leakage of surface reservoirs; and (5) an unreliable waste-disposal environment. Interest in karst hydrology has increased greatly in the past decade; this interest has resulted in the international exchange of numerous published reports on local areas and on special topical karst problems. Many of these reports have been used by the authors in preparing this paper, which synthesizes results of many workers and focuses attention on: (1) the development of karst features through hydrologic processes; and (2) hydrologic systems of karst terranes.

Journal of Hydrology↗
USGS1980

Neogene sedimentation on the outer continental margin, southern Bering Sea

Neogene sedimentary rocks and sediments from sites on the outer continental margin in the southern Bering Sea and on the Alaska Peninsula are dominated by volcanic components that probably were eroded from an emergent Aleutian Ridge. A mainland continental source is subordinate. Most sediment in the marine environment was transported to the depositional sites by longshore currents, debris flows, and turbidity currents during times when sea level was near the outermost continental shelf. Fluctuations of sea level are ascribed both to worldwide glacio-eustatic effects and to regional vertical tectonics. Large drainage systems, such as the Yukon and Kuskokwim Rivers, had little direct influence on sedimentation along the continental slope and Unmak Plateau in the southern Bering Sea. Sediments from those drainage systems probably were transported to the floor of the Aleutian Basin, to the numerous shelf basins that underlie the outer continental shelf, and to the Arctic Ocean after passing through the Bering Strait. Environments of deposition at the sites along the outer continental margin have not changed significantly since the middle Miocene. The site on the Alaska Peninsula, however, is now emergent following shallow-marine and transitional sedimentation during the Neogene.

Alaska↗
USGS1988

Late Pleistocene drainage systems beneath Delaware Bay

Analyses of an extensive grid of seismic-reflection profiles, along with previously published sedimentary data and geologic information from surrounding coastal areas, outline the ancestral drainage systems of the Delaware River beneath lower Delaware Bay. Major paleovalleys within these systems have southeast trends, relief of 10-35 m, widths of 1-8 km, and axial depths of 31-57 m below present sea level. The oldest drainage system was carved into Miocene sands, probably during the late Illinoian lowstand of sea level. It followed a course under the northern half of the bay, continued beneath the Cape May peninsula, and extended onto the present continental shelf. This system was buried by a transgressive sequence of fluvial, estuarine, and shallow-marine sediments during Sangamonian time. At the height of the Sangamonian sea-level transgression, littoral and nearshore processes built the Cape May peninsula southward over the northern drainage system and formed a contiguous submarine sedimentary ridge that extended partway across the present entrance to the bay. When sea level fell during late Wisconsinan time, a second drainage system was eroded beneath the southern half of the bay in response to the southerly shift of the bay mouth. This system, which continued across the shelf, was cut into Coastal Plain deposits of Miocene and younger age and included not only the trunk valley of the Delaware River but a large tributary valley formed by the convergence of secondary streams that drained the Delaware coastal area. During the Holocene rise of sea level, the southern drainage system was covered by a transgressive sequence of fluvial, estuarine, and paralic deposits that accumulated due to the passage of the estuarine circulation cell and to the landward and upward migration of coastal sedimentary environments. Some Holocene deposits have been scoured subsequently by strong tidal currents. The southward migration of the ancestral drainage systems beneath Delaware Bay is analogous to that found under nearby Chesapeake Bay. In both areas, shifts in the bay mouths and river courses have preserved the morphologies and sedimentary fill of former drainage systems and provided a clear record of major sea-level fluctuations. Data from this study demonstrate that important information concerning ancient estuarine environments can be derived from the locations and characteristics of former fluvial systems. ?? 1988.

Delaware, New Jersey↗
USGS1971

Glacial marine sediments in the precambrian Gowganda formation at Whitefish Falls, Ontario (Canada)

Study of a well-exposed section of the Gowganda Formation at Whitefish Falls, Ontario, suggests criteria for the recognition of glacial marine sediments. Thickness of hundreds of feet, lateral continuity, faint internal stratification, sorted lenses of sandstone and conglomerate, and dropstones characterize much of the tillite. Thickness of hundreds of feet, lateral continuity, and marked development of irregular and lenticular laminae instead of varve structure characterize much of the argillite. These characteristics, together with evidence for a nearshore, marine-to-deltaic environment for the overlying beds, suggest a glacial marine interpretation even though no fossil evidence is available. Massive tillite, tillite containing faint stratification and lenses of sorted conglomerate and sandstone, and dropstone-bearing argillite, all of which interfinger, suggest a glacial marine environment composed of: ( 1 ) a subglacial facies; ( 2 ) a periglacial facies; and ( 3 ) a facies of marine ice rafting, respectively. Separation of the two tillite-bearing members by as much as 700 ft. of argillite containing no dropstones suggests two distinct ice ages during Gowganda time.

Ontario↗
USGS1988

Lacustrine varve formation through time

Studies using sediment traps in lakes reveal that the seasonal flux of sediment regulates both the composition and timing of deposition of materials that reach the bottoms of lakes. If the bottom waters of a lake are partly or totally anoxic, the seasonally deposited materials are preserved as annual groupings of laminae (varves). Common components that form individual laminae consist of allochthonous clastic material derived from the drainage basin, precipitated carbonate minerals, diatom frustules, iron-rich and manganese-rich flocs, autochthonous organic detritus, and autochthonous and allochthonous materials resuspended from the bottom. The "style" of varving has changed over geologic time, reflecting changes in biologic evolution and types of materials available. Precipitated iron-rich laminations were common in the middle Precambrian. Graded sets of clastic organic laminations persisted through the Precambrian, prior to the evolution of bioturbating benthic organisms. Glaciolacustrine varves appear to have retained their distinctive character through time. Carbonate-rich varves occurred sporadically in the Precambrian and Phanerozoic. With the exception of diatoms, major components of modern lacustrine varves were present through the Paleozoic and Mesozoic, and yet varves are rare in strata of these ages, and may have accumulated in marine to brackish-water environments. Diatoms were introduced into lacustrine systems in Early Tertiary time and are common components of varves from then on. Diatom laminae, combined with a greater chance for geologic preservation of younger lake deposits, have increased the number of geologically young occurrences of varved sediments. However, seasonal associations of modern varve components, and the processes they represent, are present in ancient deposits and provide clues to the interpretation of ancient environments.

Palaeogeography, Palaeoclimatology, Palaeoecology↗
USGS1989

Dinoflagellate species and organic facies evidence of marine transgression and regression in the atlantic coastal plain

Palynological evidence is used to date and interpret depositional environments of sediments of Campanian, Maestrichtian and early Danian ages cored in three wells from South Carolina and Georgia. The evidence is usefil for distinguishing environments which lithofacies evidence indicates a range from nonmarine to coastal to inner neritic shallow shelf. Numerous dinoflagellate species and an organic facies defined abundant amoprphous debris (amorphous debris facies) distinguish shallow shelf sediments deposited during marine transgression. The nearshore amorphous debris facies of late Campanian age consists of heterogenous assemblages dominated by Palaeohystrichophora infusorioides Deflandre or Hystrichosphaerina varians (May). The farther offshore amorphous debris facies of late early Maestrichtian to late Maestrichtian age consists of heterogenous assemblages dominated by Glaphyrocysta retiintexta (Cookson) and/or Areoligera medusettiformis (Wetzel). The larger number of dinoflagellate species in the offshore facies represents the maximum transgression detected in the investigated interval. A multiple occurrence datum defined by the combination of first appearance, klast appearances and sole occurrence of dinoflagellate species at the base of each interval distinguished by the amorphous debris facies provides the first evidence of marine transgression. Relatively small organic residues consisting of intertinite and few or no palynomorphs define the inertinite facies in nonmarine deltaic and in coastal (lagoonal, tidal flat, interdistributary bary) sediments. Dinocyt{star, open}s are absent in the nonmarine sediments and are represented by few species and few specimens in the coastal inertinite faceis. A third organic facies (vascular tissue facies) is defined by the abundance of land plant tissue. Sporomorph species, including those of the Normapolles pollen group and of pteridophyte spores, comprise a large proportion of the total palynomorph flora in the inertinite and vascular tissue facies. The vascular tissue facies occurs in the proximal prodelta and nearshore shallow shelf lithofacies of early Maestrichtian age. Baed in the sequence of organuic facies, dinoflagellate species abundance, and lithofacies in the investigated wells, the nonmarine and coastal inertinite facies was first deposited and was followed during the late Campanian by a marine trangression when the nearshore amorphous debris facies was deposited. This was followed in the early Maestrichtian by the influx of terrigenous organic matter (vascular tissue facies) in response to deltaic progradation on the shallow shelf. A marine regression occurred towards the close of the early Maestrichtian, emplacing the coastal inertinite facies. The major marine transgression occurred near the end of the early Maestrichtian, developing a farther offshore amorphous debris facies on an expanded continental shelf which persisted through the late Maestrichtian. The inertinite facies returned during marine regression in the approximate position of the Maestrichtian/Danian boudnary. ?? 1989.

Palaeogeography, Palaeoclimatology, Palaeoecology↗
USGS2017

Paleoecological studies at Lake Patzcuaro on the west-central Mexican Plateau and at Chalco in the basin of Mexico

A 1520-cm sediment core from Lake Patzcuaro, Michoacan, Mexico, is 44,000 yr old at the base. All parts of the core have abundant pollen of Pinus (pine), Alnus (alder), and Quercus (oak) with frequent Abies (fir). The interval dated from 44,000 to 11,000 yr ago has a homogeneous flora characterized by abundant Juniperus (juniper) pollen and frequent Artemisia (sagebrush). It is believed to represent an appreciably drier and colder climate than at present. The Holocene at Lake Patzcuaro is characterized by a moderate increase in Pinus pollen and the loss of Juniperus pollen, as the modern type of climate succeeded. Alnus was abundant until about 5000 yr ago; its abrupt decrease with the first appearance of herbaceous weed pollen may reflect the cutting of lake-shore and stream-course alder communities for agricultural purposes, or it may simply reflect a drying tendency in the climate. Pollen of Zea (corn) appears at Lake Patzcuaro along with low peaks of chenopod and grass pollen at 3500 yr B.P. apparently recording a human population large enough to modify the natural environment, as well as the beginning of agriculture. A rich aquatic flora in this phase suggests eutrophication of the lake by slope erosion. In the most recent period corn is absent from the sediments, perhaps reflecting a change in agricultural practices. The environment changes at Lake Patzcuaro are similar to and correlate with those in the Cuenca de Mexico, where diatom stratigraphy from the Chalco basin indicates fluctuations in lake levels and lake chemistry in response to variations in available moisture. Before 10,000 yr ago climates there were cool and dry, and the Chalco basin was occupied by a shallow freshwater marsh that drained north to Lake Texcoco, where saline water accumulated by evaporation. Increases in effective moisture and possible melting of glaciers during the Holocene caused lake levels to rise throughout the Cuenca de Mexico, and Lake Texcoco flooded the Chalco basin with brackish water. After 5000 yr ago such flooding decreased, and shallow freshwater ponds and marshes were restored in the Chalco basin. This environmental change coincides with the appearance of Zea pollen and suggests cultural control of lake levels and salinity. ?? 1982.

Quaternary Research↗
USGS1992

Accuracy of post-bomb 137Cs and 14C in dating fluvial deposits

The accuracy and precision of 137Cs and 14C for dating post-1950 alluvial deposits were evaluated for deposits from known floods on two rivers in Arizona. The presence of 137Cs reliably indicates that deposition occurred after intensive above-ground nuclear testing was initiated around 1950. There was a positive correlation between the measured level of 137Cs activity and the clay content of the sediments, although 137Cs was detected even in sandy flood sediments with low clay content. 137Cs is a valuable dating tool in arid environments where organic materials for 14C or tree-ring dating are scarce and observational records are limited. The 14C activity measured in different types of fine organic detritus yielded dates within 1 to 8 yr of a 1980 flood deposit, and the accuracy was species-dependent. However, undifferentiated mixtures of fine organic materials from several post-bomb deposits of various ages repeatedly yielded dates between 1958 and 1962, and detrital charcoal yielded a date range of 1676-1939. In semiarid environments, the residence time of most types of organic debris precludes accurate annual resolution of post-bomb 14C dates. ?? 1992.

Quaternary Research↗
USGS1990

A dolomitized shelfedge hardground in the northern Gulf of Mexico

An elongated calcareous hardground occurs on the shelfedge northeast of the Mississippi Trough. High-resolution seismic reflection profiles show that the hardground is in 90-110 m of water, is 70-250 m wide, at least 2.3 km long, and of low relief (5-10 m). The hardground is composed of dolostone and coquinoid limestone, and exhibits a dead biofacies of nodular and encrusting calcium carbonate-secreting organisms that are significantly different from those forms living in the adjacent unconsolidated sediments. Cementation of the hardground substrate by primary dolomite was initiated during early diagenesis close to the sea floor and progressed by concretionary growth under an interstitial environment partially open to marine molecular fluxes. The bicarbonate necessary to form the dolomite came from an admixture of isotopically light thermogenic and sedimentary organic carbon sources and an isotopically heavier marine source. Exposed surfaces of the dolostone, which have been heavily bioeroded, are covered by an oxidized, goethite-rich, reddish-brown rind. The coquina is primarily composed of whole and fragmented mollusk shells and was deposited in a higher-energy environment than the precursor sediments of the dolostone. The hardground was preserved during the Holocene transgression because of its lithified nature and the top has been intermittently swept free of finer detritus by current action.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS1990

Variations in fluvial deposition on an alluvial plain: An example from the Tongue River Member of the Fort Union Formation (Paleocene), southeastern Powder River Basin, Wyoming, U.S.A.

The Tongue River Member of the Paleocene Fort Union Formation is an important coal-bearing sedimentary unit in the Powder River Basin of Wyoming and Montana. We studied the depositional environments of a portion of this member at three sites 20 km apart in the southeastern part of the basin. Six lithofacies are recognized that we assign to five depositional facies categorized as either channel or interchannel-wetlands environments. (1) Type A sandstone is cross stratified and occurs as lenticular bodies with concave-upward basal surfaces; these bodies are assigned to the channel facies interpreted to be the product of low-sinuosity streams. (2) Type B sandstone occurs in parallel-bedded units containing mudrock partings and fossil plant debris; these units constitute the levee facies. (3) Type C sandstone typically lacks internal structure and occurs as tabular bodies separating finer grained deposits; these bodies represent the crevasse-splay facies. (4) Gray mudrock is generally nonlaminated and contains ironstone concretions; these deposits constitute the floodplain facies. (5) Carbonaceous shale and coal are assigned to the swamp facies. We recognize two styles of stream deposition in our study area. Laterally continuous complexes of single and multistoried channel bodies occur at our middle study site and we interpret these to be the deposits of sandy braided stream systems. In the two adjacent study sites, single and multistoried channel bodies are isolated in a matrix of finer-grained interchannel sediment suggesting deposition by anastomosed streams. A depositional model for our study area contains northwest-trending braided stream systems. Avulsions of these systems created anastomosed streams that flowed into adjacent interchannel areas. We propose that during late Paleocene a broad alluvial plain existed on the southeastern flank of the Powder River Basin. The braided streams that crossed this surface were tributaries to a northward-flowing, basin-axis trunk stream that existed to the west.

Wyoming↗
USGS1992

Effect of membrane filtration artifacts on dissolved trace element concentrations

Among environment scientists, the current and almost universally accepted definition of dissolved constituents is an operational one-only those materials which pass through a 0.45-μm membrane filter are considered to be dissolved. Detailed laboratory and field studies on Fe and Al indicate that a number of factors associated with filtration, other than just pore size, can substantially alter “dissolved” trace element concentrations; these include: filter type, filter diameter, filtration method, volume of sample processed, suspended sediment concentration, suspended sediment grain-size distribution, concentration of colloids and colloidally-associated trace elements and concentration of organic matter. As such, reported filtered-water concentrations employing the same pore size filter may not be equal. Filtration artifacts may lead to the production of chemical data that indicate seasonal or annual “dissolved” chemical trends which do not reflect actual environmental conditions. Further, the development of worldwide averages for various dissolved chemical constituents, the quantification of geochemical cycles, and the determination of short- or long-term environmental chemical trends may be subject to substantial errors, due to filtration artifacts, when data from the same or multiple sources are combined. Finally, filtration effects could have a substantial impact on various regulatory requirements.

Georgia↗
USGS1981

Physical-chemical conditions of ore deposition

Ore deposits form under a wide range of physical and chemical conditions, but those precipitating from hot, aqueous fluids—i.e. the hydrothermal deposits—form generally below 700°C and at pressures of only 1 or 2 kbar or less. Natural aqueous fluids in rocks may extract metal and sulfur from a variety of rock types or may acquire them as a residual heritage from a crystallizing silicate magma. Ore-forming hydrothermal fluids never appear as hot springs (except in deep, submarine situations) because they boil, mix with surface waters, and cool, thereby losing their ore-bearing ability before reaching the surface. Mineral systems function as chemical buffers and indicators just as buffers and indicators function in a chemical laboratory. By reading the record written in the buffer/indicator assemblages of minerals one can reconstruct many aspects of the former chemical environment. By studying the record of changing conditions one may deduce information regarding the processes functioning to create the succession of chemical environments and the ore deposits they represent. The example of the OH vein at Creede, Colorado, shows a pH buffered by the K-feldspar + muscovite + quartz assemblage and the covariation of S 2 and O 2 buffered by the assemblage chlorite + pyrite + quartz. Boiling of the ore fluid led to its oxidation to hematite-bearing assemblages and simultaneously produced an intensely altered, sericitic capping over the vein in response to the condensation of vapors bearing acidic components. The solubility of metals as calculated from experimental and theoretical studies of mineral solubility appears too low by at least one or two powers of ten to explain the mineralization at Creede. In contrast to Creede where the mineral stabilities all point to a relatively consistent chemistry, the Mississippi Valley type deposits present a puzzle of conflicting chemical clues that are impossible to reconcile with any single equilibrium situation. Thus we must seriously consider metastable equilibria; those most likely involve redox disequilibrium among the sulfur species in solution and perhaps also involve organic compounds.

Physics and Chemistry of the Earth↗
USGS1984

Losses from effluent taxes and quotas under uncertainty

Recent theoretical papers by Adar and Griffin ( J. Environ. Econ. Manag. 3 , 178–188 (1976)), Fishelson ( J. Environ. Econ. Manag. 3 , 189–197 (1976)), and Weitzman ( Rev. Econ. Studies 41 , 477–491 (1974)) show that, different expected social losses arise from using effluent taxes and quotas as alternative control instruments when marginal control costs are uncertain. Key assumptions in these analyses are linear marginal cost and benefit functions and an additive error for the marginal cost function (to reflect uncertainty). In this paper, empirically derived nonlinear functions and more realistic multiplicative error terms are used to estimate expected control and damage costs and to identify (empirically) the mix of control instruments that minimizes expected losses.

Journal of Environmental Economics and Management↗
USGS1981

Aliphatic structure of humic acids; a clue to their origin

Nuclear magnetic resonance spectra (both 1 H and 13 C) of humic acids from diverse depositional environments indicate the presence of aromatic chemical structures, most likely derived from lignin of vascular plants, and complex, paraffinic structures, most likely derived from algal or microbial sources. The latter components account for a major fraction of humic acid structures in both terrestrial and aquatic environments, suggesting that algae or microbes play a large role in humification of organic remains from both systems.

Organic Geochemistry↗
USGS1992

Isolation of hydrophilic organic acids from water using nonionic macroporous resins

A method has been developed for the isolation of hydrophilic organic acids from aquatic environments using Amberlite ∗ XAD-4 resin. The method uses a two column array of XAD-8 and XAD-4 resins in series. The hydrophobic organic acids, composed primarily of aquatic fulvic acid, are removed from the sample on XAD-8, followed by the isolation of the more hydrophilic organic acids on XAD-4. For samples from a number of diverse environments, more of the dissolved organic carbon was isolated on the XAD-8 resin (23–58%) than on the XAD-4 resin (7–25%). For these samples, the hydrophilic acids have lower carbon and hydrogen contents, higher oxygen and nitrogen contents, and are lower in molecular weight than the corresponding fulvic acids. 13 C NMR analyses indicate that the hydrophilic acids have a lower concentration of aromatic carbon and greater heteroaliphatic, ketone and carboxyl content than the fulvic acid.

Organic Geochemistry↗