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USGS2017

Sedimentology, sequence-stratigraphy, and geochemical variations in the Mesoproterozoic Nonesuch Formation, northern Wisconsin, USA

We use core descriptions and portable X-ray fluorescence analyses to identify lithofacies and stratigraphic surfaces for the Mesoproterozoic Nonesuch Formation within the Ashland syncline, Wisconsin. We group lithofacies into facies associations and construct a sequence stratigraphic framework based on lithofacies stacking and stratigraphic surfaces. The fluvial-alluvial facies association (upper Copper Harbor Conglomerate) is overlain across a transgressive surface by the fluctuating-profundal facies association (lower Nonesuch Formation). The fluctuating-profundal facies association comprises a retrogradational sequence set overlain across a maximum flooding surface by an aggradational-progradational sequence set comprising fluctuating-profundal, fluvial-lacustrine, and fluvial-alluvial facies associations (middle Nonesuch through lower Freda Formations). Lithogeochemistry supports sedimentologic and stratigraphic interpretations. Fe/S molar ratios reflect the oxidation state of the lithofacies; values are most depleted above the maximum flooding surface where lithofacies are chemically reduced and are greatest in the chemically oxidized lithofacies. Si/Al and Zr/Al molar ratios reflect the relative abundance of detrital heavy minerals vs. clay minerals; greater values correlate with larger grain size. Vertical facies association stacking records depositional environments that evolved from fluvial and alluvial, to balanced-fill lake, to overfilled lake, and returning to fluvial and alluvial. Elsewhere in the basin, where accommodation was greatest, some volume of fluvial-lacustrine facies is likely present below the transgressive stratigraphic surface. This succession of continental and lake-basin types indicates a predominant tectonic driver of basin evolution. Lithofacies distribution and geochemistry indicate deposition within an asymmetric half-graben bounded on the east by a west-dipping growth fault. While facies assemblages are lacustrine and continental, periodic marine incursions are probable, especially across maximum transgressive surfaces. We demonstrate a sequence-stratigraphic approach may be applied to fine-grained Precambrian sediments using traditional rock description and supporting lithogeochemistry. Identification of a characteristic lithofacies succession in Mesoproterozoic sediments demonstrates fundamental controls commonly interpreted for Phanerozoic lake systems may be extended into the Precambrian. These controls result in a predictable association of lithofacies, with distinct physical, biological, and geochemical properties. This has regional significance for carbon sequestration and the distribution of mineral and hydrocarbon resources and broader significance for addressing Mesoproterozoic paleogeographic reconstructions and questions related to the evolution of terrestrial life.

Wisconsin↗

USGS2001

A preliminary survey of marine contamination from mining-related activities on Marinduque Island, Philippines: porewater toxicity and chemistry results from a field trip, October 14-19, 2000

As a follow-up of an initial overview of environmental problems caused by mining activities on Marinduque Island, Philippines, USGS and TAMU-CC scientists went to Marinduque in October 2000 to do a preliminary assessment of potential impacts of mining-related activities on the marine environment. Like the previous visit in May 2000, the marine assessment was conducted at the invitation of Philippine Congressman Edmund O. Reyes. In this report we present the results of sediment porewater toxicity tests and chemical analyses. Toxicity tests consist of laboratory analyses for the assessment of adverse effects caused by environmental contaminants to animals or plants. Sediments (sand or mud) are known to accumulate contaminants (e.g., copper and other heavy metals). Therefore, it is common to perform toxicity tests using different phases of the sedimentary environment in order to analyze adverse effects of contaminants accumulated in the sediment. Sediment pore water (or interstitial water, i.e., the water distributed among the sediment grains) is a sedimentary phase which controls the bioavailability of contaminants to bottom dwelling aquatic organisms (both plants and animals). There are several different kinds of organisms with which toxicity tests can be performed. Among those, tests with sea urchin early life stages (gametes and embryos) are very common due to their high sensitivity to contaminants, ease of maintenance under laboratory conditions, and ecological importance, particularly in coral reefs. The basis of these tests is the exposure of gametes or embryos to the pore water to be analyzed for toxicity. If the pore water contains contaminants in levels that can adversely affect a number of marine species, fertilization and/or embryological development of sea urchins is inhibited. Chemical analyses provide additional information and aid in the interpretation of the toxicity test results. For the current study, chemical analyses were performed for the measurement of porewater concentrations of several heavy metals associated with copper mining activities. Pore waters for toxicological and chemical analyses were collected at several stations on the coast of Marinduque, near the mouths of the Boac and Mogpog rivers, and near the causeways formed by mine tailings disposal. Porewater samples were also collected at the Tres Reyes Marine Reserve, so that these non-contaminated samples could serve as a reference for test performance. Sea urchin embryological development and fertilization were only significantly impaired by two porewater samples, suggesting the presence of contaminants in toxic amounts at those stations. The toxic samples were collected near the up current side of the Calancan (Marcopper) mine tailings causeway (stations 2 and 3 – see figure 10). The pore water from station 2 also had the highest levels of heavy metals, particularly cadmium, cobalt, copper, nickel, lead and zinc (Table 5). The concentrations of cobalt, nickel and zinc were also elevated 2 at station 3. Copper concentrations were also elevated at the two river mouth stations (8 and 9) and near the CMI tailings causeway (station 7). Visual observations also indicated biological degradation due to heavy siltation and smothered coral at a gradient off the Calancan causeway, suggesting that siltation might also be causing a physical impact. This preliminary survey suggests that effects related to past mining activities are still evident and warrant a more comprehensive study to assess their severity and areal extent.

Open-File Report↗

USGS2006

Processes affecting transport of uranium in a suboxic aquifer

At the Naturita site in Colorado, USA, groundwaters were sampled and analyzed for chemical composition and by culture and culture-independent microbiological techniques. In addition, sediments were extracted with a dilute sodium carbonate solution to determine quantities of labile uranium within the sediments. Samples from the upgradient portion of the contaminated aquifer , where very little dissolved Fe(II) is found in the groundwater, have uranium content that is controlled by U(VI) adsorption and few metal-reducing bacteria are observed. In the extreme downgradient portion of the aquifer, where dissolved Fe(II) is observed, uranium content of the sediments includes significant quantities of reduced U(IV) and diverse populations of Fe(III)-reducing bacteria were present in the subsurface with the potential of reducing U(VI) to U(IV).

Physics and Chemistry of the Earth↗

USGS1974

Water resources of Wisconsin: Lower Wisconsin River basin

This report describes the physical environment, availability, distribution, movement, quality, and use of water in the upper Wisconsin River basin as an aid in planning and water management. The report presents general information on the basin derived from data obtained from Federal, State, and local agencies, New field data were collected in areas where information was lacking. More detailed studies of problem areas may be required in the future, as water needs and related development increase. The upper Wisconsin River basin is the headwaters of the Wisconsin River drainage and includes about 2,730 square miles in northern Wisconsin (upstream from the gage on the Wisconsin River at Merrill). An additional 50 square miles of the basin lies in Michigan and is not covered by this report. The report area includes parts of Forest, Langlade, Lincoln, Marathon, Oneida, Price, Taylor, and Vilas Counties, Many organizations and persons assisted the study by providing data. Among the contributors were the University of Wisconsin-Extension, Geological and Natural History Survey, the Wisconsin Department of Natural Resources, the Public Service Commission of Wisconsin, and the Wisconsin Valley Improvement Company, Municipal water officials furnished water-supply information and well records, Many individuals allowed access to their wells for water-level measurements and collection of water samples for chemical analysis.

Wisconsin↗

USGS1974

Water resources of Wisconsin--Lake Superior basin

Wisconsin↗

USGS1993

Physical properties, mineralogy, and geochemistry of Holocene varved sediments from Elk Lake, Minnesota

Elk Lake in northwestern Minnesota is situated close to a climatically sensitive ecotone, the forest-prairie border, that migrated back and forth over the drainage basin of the lake during the Holocene. The entire postglacial (Holocene) sediment record in the deepest part of Elk Lake is composed of annual layers (varves) that record the seasonal pulses of many sediment components, and, most important, provide high-resolution (seasonal) time calibration of rates and timing of environmental change. These varved sediments contain many allochthonous and autochthonous components that are sensitive to changing environmental conditions in the drainage basin and the lake. The mineral components of Elk Lake sediments consist mainly of authigenic calcium, magnesium, and manganese carbonate minerals (low-Mg calcite, high-Mg calcite, dolomite, and rhodochrosite), opaline silica (from diatoms), X-ray amorphous iron and manganese oxyhydroxides, and an iron phosphate mineral tentatively identified as rock-bridgeite [(Fe, Mn)Fe 4 (PO 4 ) 3 (OH) 5 ], plus minor contributions from fine-grained detrital quartz, feldspar, illite, and kaolinite. The most notable characteristic of the sediments in Elk Lake is that most of the components were formed in the lake. Q-mode factor analysis of sediment geochemistry reduced 23 observed compositional variables, expressed as percent or parts per million of elements, to three composite variables (factor loadings) whose “concentrations” are expressed on a scale of −1.0 to 1.0. Factor 1 expresses the composition of the inorganic clastic fraction based on concentrations of Mg, Na, Al, Cr, V, Y, Sc, Ni, Sr, Co, and Cu. Factor 2 expresses the similarities in variations of Fe, Mn, P, organic carbon, and Mo. Factor 3 loadings are a synthesis of concentrations of Mn, S, Ca, La, and Ba. Geochemical characteristics define three distinct chemical stages in the development of Elk lake: (1) a carbonate-, manganese-, iron-, sulfur-rich early-lake stage that lasted from 10,400 to 8200 varve yr; (2) a clastic- and diatom-rich mid-Holocene prairie-lake stage that lasted from 8200 to 4000 varve yr; and (3) a final iron-, manganese-, phosphate-, and organic-rich modern-lake stage that developed over the past 4000 yr. The chemical characteristics of the sediments deposited during these three lake phases can be represented by the average compositions of three groups of samples: (1) the average composition of sediments deposited over the past 2000 yr, representing the modern-lake stage; (2) the composition of a 50 varve sample centered on 5700 varve yr that represents the maximum clastic influx into the lake during the prairie period; and (3) the average composition of sediments deposited over the initial 2000 yr of the lake’s existence (10,400 to 8400 varve yr). The amplitudes of climatic oscillations, as reflected by changes in concentration of many climatically sensitive elements, were greatest during the prairie period, pronounced cycles having periodicities of several hundred years. The extremes of these oscillations occurred within several centuries or less, which suggests that significant changes in climate may occur abruptly and rapidly. Most notably, the end of the mid-Holocene prairie period, marked by a sudden decrease in the influx of detrital clastic material, occurred within a few decades.

Minnesota↗

USGS2005

Studies of the Chesapeake Bay impact structure - Introduction and discussion

The late Eocene Chesapeake Bay impact structure on the Atlantic margin of Virginia is the largest known impact crater in the United States, and it may be the Earth's best preserved example of a large impact crater that formed on a predominantly siliciclastic continental shelf. The 85-kilometer-wide (53-milewide) crater also coincides with a region of saline ground water. It has a profound influence on ground-water quality and flow in an area of urban growth. The USGS-NASA Langley corehole at Hampton , Va., is the first in a series of new coreholes being drilled in the crater, and it is the first corehole to penetrate the entire crater-fill section and uppermost crystalline basement rock. The Langley corehole is located in the southwestern part of the crater's annular trough. A comprehensive effort to understand the crater's materials, architecture, geologic history , and formative processes, as well as its influence on ground water, includes the drilling of coreholes accompanied by high-resolution seismic-reflection and seismic-refraction surveys, audio-magnetotelluric surveys, and related multidisciplinary research. The studies of the core presented in this volume provide detailed information on the outer part of the crater, including the crystalline basement , the overlying impact -modified and impact -generated sediments (physical geology, paleontology, shocked minerals, and crystalline ejecta), and the upper Eocene to Quaternary postimpact sedimentary section (stratigraphy, paleontology, and paleoenvironments). The USGS-NASA Langley corehole has a total depth below land surface of 635.1 meters (m; 2,083.8 feet (ft)). The deepest unit in the corehole is the Neoproterozoic Langley Granite. The top of this granite at 626.3 m (2,054.7 ft) depth is overlain by 390.6 m (1,281.6 ft) of impact -modified and impact -generated siliciclastic sediments. These crater-fill materials are preserved beneath a 235.6-m-thick (773.12-ft-thick) blanket of postimpact sediments. A high-resolution seismic-reflection and seismic-refraction profile that crosses the Langley drill site is tied to the core by borehole geophysical logs, and it reveals the details of extensional collapse structures in the western annular trough. Electrical cross sections based on audio-magnetotelluric (AMT) soundings image a nearly vertical zone of high resistivity at the outer margin of the annular trough, possibly indicating fresh ground water at that location, and they show impedance trends that match the curvature of the structure . They also image the subsurface contact between conductive sediments and resistive crystalline basement , showing that the depth to crystalline basement is relatively constant in the western part of the annular trough. Chemical and isotopic data indicate that saline ground water of the Virginia inland saltwater wedge or bulge is a mixture of freshwater and seawater, and evidence for a mixing zone at the crater's outer margin supports the concept of differential flushing of residual seawater to create the bulge. Ground-water brine in the central part of the crater was produced by evaporation, and brine production from the heat of the impact is at least theoretically possible.

Chesapeake Bay↗

USGS2012

Characterization of major-ion chemistry and nutrients in headwater streams along the Appalachian National Scenic Trail and within adjacent watersheds, Maine to Georgia

An inventory of water-quality data on field parameters, major ions, and nutrients provided a summary of water quality in headwater (first- and second-order) streams within watersheds along the Appalachian National Scenic Trail (Appalachian Trail). Data from 1,817 sampling sites in 831 catchments were used for the water-quality summary. Catchment delineations from NHDPlus were used as the fundamental geographic units for this project. Criteria used to evaluate sampling sites for inclusion were based on selected physical attributes of the catchments adjacent to the Appalachian Trail, including stream elevation, percentage of developed land cover, and percentage of agricultural land cover. The headwater streams of the Appalachian Trail are generally dilute waters, with low pH, low acid neutralizing capacity (ANC), and low concentrations of nutrients. The median pH value was slightly acidic at 6.7; the median specific conductance value was 23.6 microsiemens per centimeter, and the median ANC value was 98.7 milliequivalents per liter (μeq/L). Median concentrations of cations (calcium, magnesium, sodium, and potassium) were each less than 1.5 milligrams per liter (mg/L), and median concentrations of anions (bicarbonate, chloride, fluoride, sulfate, and nitrate) were less than 10 mg/L. Differences in water-quality constituent levels along the Appalachian Trail may be related to elevation, atmospheric deposition, geology, and land cover. Spatial variations were summarized by ecological sections (ecosections) developed by the U.S. Forest Service. Specific conductance, pH, ANC, and concentrations of major ions (calcium, chloride, magnesium, sodium, and sulfate) were all negatively correlated with elevation. The highest elevation ecosections (White Mountains, Blue Ridge Mountains, and Allegheny Mountains) had the lowest pH, ANC, and concentrations of major ions. The lowest elevation ecosections (Lower New England and Hudson Valley) generally had the highest pH, ANC, and concentrations of major ions. The geology in discrete portions of these two ecosections was classified as containing carbonate minerals which has likely influenced the chemical character of the streamwater. Specific conductance, pH, ANC, and concentrations of major ions (calcium, chloride, magnesium, sodium, and sulfate) were all positively correlated with percentages of developed and agricultural land uses at the lower elevations of the central region of the Appalachian Trail (including the Green-Taconic-Berkshire Mountains, Lower New England, Hudson Valley, and Northern Ridge and Valley ecosections). The distinctly different chemical character of the streams in the central sections of the Appalachian Trail is likely related to the lower elevations, the presence of carbonate minerals in the geology, higher percentages of developed and agricultural land uses, and possibly the higher inputs of sulfate and nitrate from atmospheric deposition. Acid deposition of sulfate and nitrate are important influences on the acid-base chemistry of the surface waters of the Appalachian Trail. Atmospheric deposition estimates are consistently high (more than 18 kilograms per hectare (kg/ha) for sulfate, and more than 16 kg/ha for nitrate) at both the highest and lowest elevations. However, the lowest elevation (Green-Taconic-Berkshire Mountains, Lower New England, Hudson Valley, Northern Glaciated Allegheny Plateau, and Northern Ridge and Valley ecosections) included the largest spatial area of sustained high estimates of atmospheric deposition. Calcium-bicarbonate was the most frequently calculated water type in the Lower New England and Hudson Valley ecosections. In the northern and southern sections of the Appalachian Trail mix-cation water types were most prevalent and sulfate was the predominate anion. The predominance of the sulfate anion in the surface waters of the northern and southern ecosections likely reflects the influence of sulfate deposition. Although the central portion of the Appalachian Trail has the largest spatial area of high atmospheric acid deposition, the lower ionic strength waters in the northern and southern ecosections of the Appalachian Trail may have been more adversely affected by acid deposition. The low ionic strength of the streams in the White Mountains, Blue Ridge Mountains, and Allegheny Mountains ecosections makes parts of these regions susceptible to seasonal or event-driven episodic acidification, which can be detrimental to health of aquatic and terrestrial ecosystems. Median catchment ANC values were classified into three groups - acidic, sensitive, and insensitive. The White Mountains, Blue Ridge Mountains, and Allegheny Mountains ecosections included the highest frequency of catchments classified as acidic or sensitive. More than 56 percent of the catchments from the White Mountains ecosection were classified as sensitive to acidic inputs. In the Blue Ridge ecosection, 1.6 percent of the catchments were classified as acidic, and 38.2 percent of the catchments were classified as sensitive to acidic inputs. In the Allegheny Mountains ecosection, 17.6 percent of the catchments were classified as acidic, and 29.4 percent of the catchments were classified as sensitive to acidic inputs. Median concentrations of nitrogen species were less than 0.4 mg/L, and median concentrations of total phosphorus were less than 0.02 mg/L along the Appalachian Trail. A comparison of median catchment concentrations of nutrients to estimated national background concentrations demonstrated that concentrations along the Appalachian Trail are generally lower. A comparison of median concentrations of total nitrogen and total phosphorus to the U.S. Environmental Protection Agency's (USEPA) nutrient criteria for the Eastern U.S. ecoregions showed that the concentrations of total nitrogen in the northern section of the Appalachian Trail were generally higher than the USEPA criterion. Similarly, median concentrations of total phosphorus in the southern regions of the Appalachian Trail were approximately twice as high as USEPA criteria. Sections of the Appalachian Trail are adjacent to modest amounts of agricultural and developed land areas. These nonforested land areas may be contributing to the percentage of catchments in which concentrations of total nitrogen and total phosphorus are higher than USEPA nutrient ecoregion criteria.

Connecticut, Georgia, Maine, Massachusetts, Maryla↗

USGS2010

The transition of benthic nutrient sources after planned levee breaches adjacent to upper Klamath and Agency Lakes, Oregon

Four sampling trips were coordinated after planned levee breaches that hydrologically reconnected both Upper Klamath Lake and Agency Lake, Oregon, to adjacent wetlands. Sets of nonmetallic pore-water profilers were deployed during these trips in November 2007, June 2008, May 2009, and July 2009. Deployments temporally spanned the annual cyanophyte bloom of Aphanizomenon flos-aquae (AFA) and spatially involved three lake and four wetland sites. Profilers, typically deployed in triplicate at each lake or wetland site, provided high-resolution (centimeter-scale) estimates of the vertical concentration gradients for diffusive-flux determinations. Estimates based on molecular diffusion may underestimate benthic flux because solute transport across the sediment-water interface can be enhanced by processes including bioturbation, bioirrigation and groundwater advection. Water-column and benthic samples were also collected to help interpret spatial and temporal trends in diffusive-flux estimates. Data from these samples complement taxonomic and geochemical analyses of bottom-sediments taken from Upper Klamath Lake (UKL) in prior studies. This ongoing study provides information necessary for developing process-interdependent solute-transport models for the watershed (that is, models integrating physical, geochemical, and biological processes) and supports efforts to evaluate remediation or load-allocation strategies. To augment studies funded by the U.S. Bureau of Reclamation (USBR), the Department of the Interior supported an additional full deployment of pore-water profilers in November 2007 and July 2009, immediately following the levee breaches and after the crash of the annual summer AFA bloom. As observed consistently since 2006, benthic flux of 0.2-micron filtered, soluble reactive phosphorus (that is, biologically available phosphorus, primarily as orthophosphate; SRP) was consistently positive (that is, out of the sediment into the overlying water column) and ranged from a negligible value (-0.19?0.91 milligrams per square meter per day; mg m-2 d-1) within wetlands of the Upper Klamath National Wildlife Refuge to 74?48 mg m-2 d-1 at the newly restored wetland site removed from the levee breach (TNC1); both observed in May 2009 before the annual AFA bloom. When areally averaged (13 km2 for the newly restored wetlands), an SRP flux to the overlying water column is determined of approximately 87,000 kilograms (kg) over the 3-month AFA bloom season that exceeds the magnitude of riverine inputs (42,000 kg for the season). Elevated SRP benthic flux at TNC1 relative to all other lake and wetland sites (including TNC2 near the breached levee) in 2009 suggests that the restored wetlands, at least chemically, remain in a transition period after engineered blasts on October 30, 2007, restored hydrologic connectivity between lake and wetland environments. As reported in previous lake studies, ammonium fluxes to the water column were consistently positive, with the exception of two measurements at the restored wetland sites (TNC1 and TNC2) immediately following the levee breaches in November 2007. The flux of ammonia, particularly at elevated pH in the overlying water column, has toxicological implications for endangered fish populations in both lake and wetland environments. For dissolved nitrate, with the exception of a single positive flux measurement at TNC1 in June 2008 (0.16?0.02 mg m-2 d-1), consistently negative (consumed by the sediment) or undetectable nitrate-flux values were observed (-21?12 mg m-2 d-1 to undetectable fluxes due to concentrations for dissolved nitrate <0.03 milligrams per liter (mg L-1) in both porewaters and overlying waters near the sediment-water interface). Such negative fluxes for dissolved nitrate are typical of microbial transformations, such as dinitrification (dissimilatory nitrate reduction), that benthically consume nitrate from the water column. The diffusive-flux measurements reported herei

Oregon↗

USGS1996

Chemical weathering rates of a soil chronosequence on granitic alluvium: I. Quantification of mineralogical and surface area changes and calculation of primary silicate reaction rates

Mineral weathering rates are determined for a series of soils ranging in age from 0.2-3000 Ky developed on alluvial terraces near Merced in the Central Valley of California. Mineralogical and elemental abundances exhibit time-dependent trends documenting the chemical evolution of granitic sand to residual kaolinite and quartz. Mineral losses with time occur in the order: hornblende > plagioclase > K-feldspar. Maximum volume decreases of >50% occur in the older soils. BET surface areas of the bulk soils increase with age, as do specific surface areas of aluminosilicate mineral fractions such as plagioclase, which increases from 0.4-1.5 m2 g-1 over 600 Ky. Quartz surface areas are lower and change less with time (0.11-0.23 m2 g-1). BET surface areas correspond to increasing external surface roughness (?? = 10-600) and relatively constant internal surface area (??? 1.3 m2 g-1). SEM observations confirm both surface pitting and development of internal porosity. A numerical model describes aluminosilicate dissolution rates as a function of changes in residual mineral abundance, grain size distributions, and mineral surface areas with time. A simple geometric treatment, assuming spherical grains and no surface roughness, predicts average dissolution rates (plagioclase, 10-17.4; K-feldspar, 10-17.8; and hornblende, 10-17.5 mol cm-1 s-1) that are constant with time and comparable to previous estimates of soil weathering. Average rates, based on BET surface area measurements and variable surface roughnesses, are much slower (plagioclase, 10-19.9; K-feldspar, 10-20.5; and hornblende 10-20.1 mol cm-2 s-1). Rates for individual soil horizons decrease by a factor of 101.5 over 3000 Ky indicating that the surface reactivities of minerals decrease as the physical surface areas increase. Rate constants based on BET estimates for the Merced soils are factors of 103-104 slower than reported experimental dissolution rates determined from freshly prepared silicates with low surface roughness (?? <10). This study demonstrates that the utility of experimental rate constants to predict weathering in soils is limited without consideration of variable surface areas and processes that control the evolution of surface reactivity with time.

Geochimica et Cosmochimica Acta↗

USGS2000

Late-kinematic timing of orogenic gold deposits and significance for computer-based exploration techniques with emphasis on the Yilgarn Block, Western Australia

Orogenic gold deposits are a widespread coherent group of epigenetic ore deposits that are sited in accretionary or collisional orogens. They formed over a large crustal-depth range from deep-seated low-salinity H 2 O–CO 2 ±CH 4 ±N 2 ore fluids and with Au transported as thio-complexes. Regional structures provide the main control on deposit distribution. In many terranes, first-order faults or shear zones appear to have controlled regional fluid flow, with greatest ore-fluid fluxes in, and adjacent to, lower-order faults, shear zones and/or large folds. Highly competent and/or chemically reactive rocks are the most common hosts to the larger deposits. Focusing of supralithostatic ore fluids into dilatant zones appears to occur late during the evolutionary history of the host terranes, normally within D 3 or D 4 in a D 1 –D 4 deformation sequence. Reactivation of suitably oriented pre-existing structures during a change in far-field stress orientation is a factor common to many deposits, and repeated reactivation may account for multiple mineralization episodes in some larger deposits. Absolute robust ages of mineralization support their late-kinematic timing, and, in general, suggest that deposits formed diachronously towards the end of the 100 to 200 m.y. long evolutionary history of hosting orogens. For example, in the Yilgarn Block, a region specifically emphasised in this study, orogenic gold deposits formed in the time interval between 40 and 90 m.y., with most about 60 to 70 m.y., after the youngest widespread basic-ultrabasic volcanism and towards the end of felsic magmatism. The late timing of orogenic gold deposits is pivotal to geologically-based exploration methodologies. This is because the present structural geometries of: (i) the deposits, (ii) the hosting goldfields, and (iii) the enclosing terranes are all essentially similar to those during gold mineralization, at least in their relative position to each other. Thus, interpretation of geological maps and cross-sections and three-dimensional models can be used to accurately simulate the physical conditions that existed at the time of ore deposition. It is particularly significant that the deposits are commonly related to repetitive and predictable geometries, such as structural heterogeneities within or adjacent to first-order structures, around rigid granitoid bodies, or in specific “locked-up” fold-thrust structures. Importantly, the two giant greenstone-hosted goldfields, Kalgoorlie and Timmins, show a remarkably similar geometry at the regional scale. Computer-based stress mapping and GIS-based prospectivity mapping are two computer-based quantitative methodologies that can utilize and take advantage of the late timing aspect of this deposit type to provide important geological aids in exploration, both in broad regions and more localized goldfields. Both require an accurate and consistent solid geology map, stress mapping requires knowledge of the far-field stresses during mineralization, and the empirical prospectivity mapping requires data from a significant number of known deposits in the terrane. The Kalgoorlie Terrane, in the Yilgarn Block, meets these criteria, and illustrates the potential of these methodologies in the exploration for orogenic gold deposits. Low minimum stress anomalies, interpreted to represent dilational zones during gold-related deformation, coincide well with the positions of known goldfields rather than individual gold deposits in the terrane, and there are additional as-yet unexplained anomalies. The prospectivity analysis confirms that predictable and repetitive factors controlling the siting of deposits are: (i) proximity to, and orientation and curvature of, granitoid-greenstone contacts, (ii) proximity to segments of crustal faults which strike in a preferred direction, (iii) proximity to specific lithological contacts which have similar preferred strike, (iv) proximity to anticlinal structures, and (v) the presence of preferred reactive host rocks (e.g., dolerite). The prospectivity map defines a series of anomalous areas, which broadly conform to those of the stress map (>78% correspondence). The most prospective category on this map covers less than 0.3% of the greenstone belts and yet hosts 16% of the known deposits, which have produced>80% of known gold. Thus, it discriminates in favour of the larger economically more-attractive deposits in the terrane. The successful application of stress mapping and prospectivity mapping to geology-based exploration for orogenic gold deposits indicates that more quantitative analysis of geological map data is a profitable line of research. The computer-based nature of these methodologies is ideal for the production of an ultimate, integrated, deposit target map, which can be compared to other, more conventional, targeting parameters such as geophysical and geochemical anomalies. Such an integrated strategy appears the way forward in the increasingly difficult task of cost-effective global exploration for orogenic gold deposits in poorly exposed terranes.

Western Australia↗

USGS2005

Water resources on and near the Nottawaseppi Huron band of Potawatomi indian tribal lands, Calhoun County, Michigan, 2000-03

The Nottawaseppi Huron Band of Potawatomi Indians in Calhoun County, Michigan is concerned about the water quality and quantity of streams in and around tribal lands and of shallow ground water. The tribe wanted to establish a database that included streamflow, stage, and water quality of local streams and quality of ground water from wells belonging to the tribe and its members. Concerned about the effects of long-term agricultural activity and increasing numbers of singlefamily dwellings being constructed within the watershed both on and off the reservation, the tribe wants to develop a water-resources management plan. U.S. Geological Survey (USGS) measured streamflow and installed staff gages tied into local datum on three tributaries of the St. Joseph River that cross tribal lands. Water-quality samples were collected from the sites under a variety of flow regimes from spring to fall during 2000-03. Stage-streamflow rating curves were constructed for Pine Creek and Athens & Indian Creek Drain after a number of discharge measurements were made and a thorough basin analysis was completed. Daily streamflow for Pine Creek near Athens was estimated for the period from May 2000 through September 2003. USGS collected 12 water samples at Pine Creek near Athens, Athens & Indian Creek Drain, and an unnamed tributary to Pine Creek during October 2000 through September 2003. Physical properties were measured, and the streams were sampled for major ions, nutrients, trace elements, caffeine, and herbicides/pesticides and their breakdown products (degradates). The tribe also measured physical properties weekly at the three sites during each growing season for the study period. Surface water at the three sites can be classified as hard, with calcium carbonate concentrations exceeding 180 milligrams per liter (mg/L). Concentrations of calcium, magnesium, chloride, and dissolved solids are typical of the area. There were 68 detections of 17 pesticides, degradates, and caffeine. Atrazine and metolachlor were detected in all samples, and the atrazine degradate deethylatrazine was detected in all samples from Pine Creek and Athens & Indian Creek Drain. Another atrazine degradate (2-hydroxy-atrazine, or OIET) was detected five of the six times that it was included in the analyses. A single sample collected from Athens & Indian Creek Drain in May 2001 had relatively higher concentrations of acetochlor, atrazine, CIAT (deethylatrazine), and diuron than the other sampling sites did during the study. Analysis for various species of mercury was completed on samples collected at Pine Creek and Athens & Indian Creek Drain in July 2003, and results were similar to those typical of unimpaired streams in the Midwest. None of the surface-water sites had major ion, nutrient, or trace-element concentrations that exceeded Michigan Department of Environmental Quality standards for nonpotable surface water. USGS also collected 11 ground-water samples from 7 wells on or adjacent to the traditional reservation in 2003. Two wells were sampled twice, and a single well was sampled three times, in order to document any chemical changes that might have occurred as a result of aquifer recharge, which most typically occurs in late winter to spring in the southern Lower Peninsula of Michigan. Samples were analyzed for 184 pesticides and degradates and caffeine. There were five detections of four pesticides or degradates, but none of the detected chemicals are included in current U.S. Environmental Protection Agency drinking-water standards. The remaining 181 analytes were below laboratory reporting limits.

Michigan↗

USGS2006

Continuous water-quality monitoring and regression analysis to estimate constituent concentrations and loads in the Red River of the North, Fargo, North Dakota, 2003-05

This report presents the results of a study by the U.S. Geological Survey, done in cooperation with the Bureau of Reclamation, U.S. Department of the Interior, to estimate water-quality constituent concentrations in the Red River of the North at Fargo, North Dakota. Regression analysis of water-quality data collected in 2003-05 was used to estimate concentrations and loads for alkalinity, dissolved solids, sulfate, chloride, total nitrite plus nitrate, total nitrogen, total phosphorus, and suspended sediment. The explanatory variables examined for regression relation were continuously monitored physical properties of water-streamflow, specific conductance, pH, water temperature, turbidity, and dissolved oxygen. For the conditions observed in 2003-05, streamflow was a significant explanatory variable for all estimated constituents except dissolved solids. pH, water temperature, and dissolved oxygen were not statistically significant explanatory variables for any of the constituents in this study. Specific conductance was a significant explanatory variable for alkalinity, dissolved solids, sulfate, and chloride. Turbidity was a significant explanatory variable for total phosphorus and suspended sediment. For the nutrients, total nitrite plus nitrate, total nitrogen, and total phosphorus, cosine and sine functions of time also were used to explain the seasonality in constituent concentrations. The regression equations were evaluated using common measures of variability, including R2, or the proportion of variability in the estimated constituent explained by the regression equation. R2 values ranged from 0.703 for total nitrogen concentration to 0.990 for dissolved-solids concentration. The regression equations also were evaluated by calculating the median relative percentage difference (RPD) between measured constituent concentration and the constituent concentration estimated by the regression equations. Median RPDs ranged from 1.1 for dissolved solids to 35.2 for total nitrite plus nitrate. Regression equations also were used to estimate daily constituent loads. Load estimates can be used by water-quality managers for comparison of current water-quality conditions to water-quality standards expressed as total maximum daily loads (TMDLs). TMDLs are a measure of the maximum amount of chemical constituents that a water body can receive and still meet established water-quality standards. The peak loads generally occurred in June and July when streamflow also peaked.

North Dakota↗

USGS2004

Hydrologic and geochemical evaluation of aquifer storage recovery in the Santee Limestone/Black Mingo Aquifer, Charleston, South Carolina, 1998-2002

The hydrologic and geochemical effects of aquifer storage recovery were evaluated to determine the potential for supplying the city of Charleston, South Carolina, with large quantities of potable water during emergencies, such as earthquakes, hurricanes, or hard freezes. An aquifer storage recovery system, including a production well and three observation wells, was installed at a site located on the Charleston peninsula. The focus of this study was the 23.2-meter thick Tertiary-age carbonate and sand aquifer of the Santee Limestone and the Black Mingo Group, the northernmost equivalent of the Floridan aquifer system. Four cycles of injection, storage, and recovery were conducted between October 1999 and February 2002. Each cycle consisted of injecting between 6.90 and 7.19 million liters of water for storage periods of 1, 3, or 6 months. The volume of recovered water that did not exceed the U.S. Environmental Protection Agency secondary standard for chloride (250 milligrams per liter) varied from 1.48 to 2.46 million liters, which is equivalent to 21 and 34 percent of the total volume injected for the individual tests. Aquifer storage recovery testing occurred within two productive zones of the brackish Santee Limestone/Black Mingo aquifer. The individual productive zones were determined to be approximately 2 to 4 meters thick, based on borehole geophysical logs, electromagnetic flow-meter testing, and specific-conductance profiles collected within the observation wells. A transmissivity and storage coefficient of 37 meters squared per day and 3 x 10-5, respectively, were determined for the Santee Limestone/Black Mingo aquifer. Water-quality and sediment samples collected during this investigation documented baseline aquifer and injected water quality, aquifer matrix composition, and changes in injected/aquifer water quality during injection, storage, and recovery. A total of 193 water-quality samples were collected and analyzed for physical properties, major and minor ions, and nutrients. The aquifer and treated surface water were sodiumchloride and calcium/sodium-bicarbonate water types, respectively. Forty-five samples were collected and analyzed for total trihalomethane. Total trihalomethane data collected during aquifer storage recovery cycle 4 indicated that this constituent would not restrict the use of recovered water for drinking-water purposes. Analysis of six sediment samples collected from a cored well located near the aquifer storage recovery site showed that quartz and calcite were the dominant minerals in the Santee Limestone/Black Mingo aquifer. Estimated cation exchange capacity ranged from 12 to 36 milliequivalents per 100 grams in the lower section of the aquifer. A reactive transport model was developed that included two 2-meter thick layers to describe each of the production zones. The four layers composing the production zones were assigned porosities ranging from 0.1 to 0.3 and hydraulic conductivities ranging from 1 to 8.4 meters per day. Specific storage of the aquifer and confining units was estimated to be 1.5 x 10-5 meter-1. Longitudinal dispersivity of all layers was specified to be 0.5 meter. Leakage through the confining unit was estimated to be minimal and, therefore, not used in the reactive transport modeling. Inverse geochemical modeling indicates that mixing, cation exchange, and calcite dissolution are the dominant reactions that occur during aquifer storage recovery testing in the Santee Limestone/Black Mingo aquifer. Potable water injected into the Santee Limestone/Black Mingo aquifer evolved chemically by mixing with brackish background water and reaction with calcite and cation exchangers in the sediment. Reactive-transport model simulations indicated that the calcite and exchange reactions could be treated as equilibrium processes.

South Carolina↗

USGS2007

The Quality of Water and Bottom Material in Lunga Reservoir, Virginia, September 2004 through August 2005

Lunga Reservoir is on the U.S. Marine Corps Base in Quantico, which is in the Potomac River basin and the Piedmont Physiographic Province of northern Virginia. Because of the potential use of the reservoir for scuba-diver training and public water supply in addition to current recreational activities, the U.S. Marine Corps wanted to know more about the water quality of Lunga Reservoir and how it compared to Virginia Department of Environmental Quality and Virginia State Water Control Board ambient water-quality standards. Water samples and physical properties were collected by the U.S. Geological Survey at 6 locations throughout Lunga Reservoir, and physical properties were collected at 11 additional locations in the reservoir from September 2004 through August 2005. Water samples for analysis of pesticides and bottom-material trace elements were collected once during the study at four of the sampling locations. Water temperature, dissolved-oxygen concentration, specific conductance, pH, and total chlorophyll concentration in Lunga Reservoir all had similar seasonal and spatial variations as in other lakes and reservoirs in this geographic region - thermal gradient in the summer and fall and isothermal conditions in the winter and early spring. Concentrations of water-quality indicators in Lunga Reservoir were within comparable levels of those in other reservoirs and did not violate the Virginia State Water Control Board standards for public water supplies. Water temperatures throughout Lunga Reservoir during the study period ranged from 4.4 to 30.1 degrees Celsius, well below the State Water Control Board maximum water temperature criteria of 32 degrees Celsius. Dissolved-oxygen concentrations ranged from 0.05 to 14.1 milligrams per liter throughout the reservoir during the study period, but never fell below the State Water Control Board minimum dissolved-oxygen criterion of 4.0 milligrams per liter at the surface of Lunga Reservoir. Specific conductance throughout Lunga Reservoir ranged from 29 to 173 microsiemens per centimeter at 25 degrees Celsius during the study period, with a mean specific conductance of 68 microsiemens per centimeter at 25 degrees Celsius. Measurements of pH throughout the reservoir ranged from 4.8 to 7.6 standard units. Concentrations of chemical constituents analyzed in Lunga Reservoir samples were below any State Water Control Board criteria and generally were similar in concentration to the same chemical constituents in other reservoirs in the State. Four water samples were analyzed for 54 pesticides, and none of these pesticides were above the laboratory minimum reporting level.

Open-File Report↗

USGS1990

UPb ages of zircon rims: A new analytical method using the air-abrasion technique

We present a new technique for directly dating, by conventional techniques, the rims of zircons. Several circumstances, such as a xenocrystic or inherited component in igneous zircon and metamorphic overgrowths on igneous cores, can result in grains with physically distinct age components. Pneumatic abrasion has been previously shown by Krogh to remove overgrowths and damaged areas of zircon, leaving more resistant and isotopically less disturbed parts available for analysis. A new abrader design, which is capable of very gently grinding only tips and interfacial edges of even needle-like grains, permits easy collection of abraded material for dating. Five examples demonstrate the utility of the “dust-collecting” technique, including two studies that compare conventional, ion microprobe and abrader data. Common Pb may be strongly concentrated in the outermost zones of many zircons and this Pb is not easily removed by leaching (even in weak HF). Thus, the benefit of removing only the outermost zones (and avoiding mixing of age components) is somewhat compromised by the much higher common Pb contents which result in less precise age determinations. A very brief abrasion to remove the high common Pb zones prior to collection of material for dating is selected.

Chemical Geology: Isotope Geoscience Section↗

USGS1995

Physical and hydrologic properties of outcrop samples from a nonwelded to welded tuff transition, Yucca Mountain, Nevada

Quantitative material-property data are needed to describe lateral and vertical spatial variability of physical and hydrologic properties and to model ground-water flow and radionuclide transport at the potential Yucca Mountain nuclear-waste repository site in Nevada. As part of ongoing site characterization studies of Yucca Mountain directed toward this understanding of spatial variability, laboratory measurements of porosity, bull* and particle density, saturated hydraulic conductivity, and sorptivity have been obtained for a set of outcrop samples that form a systematic,two dimensional grid that covers a large exposure of the basal Tiva Canyon Tuff of the Paintbrush Group of Miocene age at Yucca Mountain. The samples form a detailed vertical grid roughly parallel to the transport direction of the parent ash flows, and they exhibit material-property varia- tions in an interval of major lithologic change overlying a potential nuclear-waste repository at Yucca Mountain. The observed changes in hydrologic properties were systematic and consistent with the changes expected for the nonwelded to welded transition at the base of a major ash-flow sequence. Porosity, saturated hydraulic conductivity, and sorptivity decreased upward from the base of the Tiva Canyon Tuff, indicating the progressive compaction of ash- rich volcanic debris and the onset of welding with increased overburden pressure from the accumulating ash-flow sheet. The rate of decrease in the values of these material properties varied with vertical position within the transition interval. In contrast, bulk-density values increased upward, a change that also is consistent with progressive compaction and the onset of welding. Particle-density values remained almost constant throughout the transition interval, probably indicating compositional (chemical) homogeneity.

Water-Resources Investigations Report↗

USGS1971

Magnetic susceptibility and triangular exchange coupling in the tourmaline mineral group

Magnetic susceptibilities of three iron-rich tourmaline crystals from Mexquitic (Mexico), Pierpont (New York), and Madagascar with different and known chemical compositions have been studied from 8° to 300°K. The iron atoms in the tourmaline crystal structure, space group R3m , a∼15·9, c∼7·2 , are situated at the three corners of an equilateral triangle and are close enough for magnetic exchange interaction. For buergerite, the Mexquitic sample, the susceptibility data lead to an exchange constant J/k of 7·5°K. Although the amount of aluminum would be sufficient to fill point position 18(c) exactly, the magnetic data are consistent with some substitution of ferric iron for aluminum, as previously determined from X-ray and neutron diffraction studies. Some aluminum thus replaces iron in position 9(b). Exchange constants were also estimated for the other two magnesium-iron specimens, of which the madagascar sample is aluminum deficient. The results agree with the evidence from optical spectra that there is considerable deviation from octahedral symmetry in the oxygen coordination polyhedra about the 9(b) and 18(c) point positions.

New York↗