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At least 1,657 records · Page 92Linked to original sources

Well predictive performance of play-wide and Subarea Random Forest models for Bakken productivity

In recent years, geologists and petroleum engineers have struggled to clearly identify the mechanisms that drive productivity in horizontal, hydraulically-fractured oil wells producing from the middle member of the Bakken formation. This paper fills a gap in the literature by showing how this play’s heterogeneity affects factors that drive well productivity. It is important because understanding the relative strength of productivity drivers and how predictors vary spatially facilitates best-practices for well site selection and well completion design. The paper describes an application of the Random Forest (RF) machine learning technique to identify these mechanisms and to evaluate their importance across 9 subareas of the North Dakota portion of the Bakken play. The study examined productivity of 7311 wells initiating production from 2010 through 2017. Well productivity varied considerably across the 9 subareas within the play, so it was not surprising that the dominant predictors, the initial 180-day water cut and the 30-day initial gas production, vary spatially to mirror local conditions that strongly affect well productivity. The relative importance of well completion predictor variables, that is, the numbers of fractures stages per well, volume of injected proppant per stage, volume of injected fluids per stage, and lateral length, varied considerably across the subareas. Statistical permutation tests are presented that generally confirm the importance rankings. Subarea Random Forest models explained from 50 percent to 82 percent of the variation in productivity test samples while the play-wide model explained 73 percent of the test sample well productivity. Weakness in the predictive ability of the Random Forest models are traced to the limited variability in the training data. Implications of the empirical findings regarding the Bakken play for operators and for research and government institutions are discussed in the concluding section.

Montana, North Dakota, South Dakota↗

Origin of the J-M Reef and Lower Banded series, Stillwater Complex, Montana, USA

The origin and parental magma for layered cumulates in the Lower Banded series (LBS) and the J-M Reef Pd-Pt deposit of the Stillwater Complex remains poorly constrained. We present whole-rock lithogeochemistry and mineral chemistry from LBS rocks collected from drill holes and surface samples from the Mountain View area of the complex that in total span nearly the entirety of the LBS stratigraphy. Excess S, Pt, and Pd in the noritic and gabbronoritic cumulates of the LBS indicate that small amounts of high tenor sulfide liquid generated at very low degrees of sulfide oversaturation were ubiquitous parts of the cumulate assemblage. We show that a simple two-stage thermodynamic model of assimilation-batch crystallization of a komatiitic parental magma in the lower crust, produces a close match to a common suite of fine-grained gabbronorite dikes and sills that intrude both the complex and its footwall. After fractionating ultramafic cumulates in the lower crust, the model contaminated komatiitic liquid produces upper crustal cumulates by batch crystallization en route to or at the level of the intrusion. The modeled rocks have compositions and mineral assemblages closely resembling pyroxenite of the Bronzitite zone and both norite and gabbronorite cumulates in the lower LBS. The trends from the Bronzitite zone through Norite zone I and Gabbronorite zone I can be understood as the result of deposition of crystals from successive batches of the same contaminated parental magma, with an upward trend toward greater amounts of cooling before the separation of crystals from liquid. The olivine-bearing suite of Olivine-bearing zone I, which includes the J-M Reef, can be modeled by partial remelting of the same norite and gabbronorite cumulates due to a temporarily increased flux of hot, moderately less contaminated LBS parental magma that infiltrated partially molten cumulates because its density exceeded that of the interstitial liquid. This model suggests that infiltration of hot Mg-rich parental liquid into moderately PGE-enriched footwall cumulates may be fundamental to the formation of the extremely high tenor sulfide mineralization in the J-M Reef ore zone, and perhaps other reef-type deposits worldwide. The same metal tenors that would require silicate/sulfide mass ratios (i.e., R-factors) of 10 5 to 10 6 in a single stage of equilibration would be attained during this second stage of interaction by the incremental infiltration and passage of LBS parental magma through previously sulfide saturated cumulate mush.

Montana↗

Coherent changes in relative C4 plant productivity and climate during the late Quaternary in the North American Great Plains

Evolution of the mixed and shortgrass prairie of the North American Great Plains is poorly understood because of limited proxies available for environmental interpretations. Buried soils in the Great Plains provide a solution to the problem because they are widespread both spatially and temporally with their organic reservoirs serving as a link to the plants than once grew on them. Through stable carbon isotopic analysis of soil organic carbon (??13C), the percent carbon from C4 plants (%C4) can be ascertained. Because C4 plants are primarily warm season grasses responding positively to summer temperature, their representation has the added advantage of serving as a climate indicator. To better understand grassland and climate dynamics in the Great Plains during the last 12 ka (ka=1000 radiocarbon years) we developed an isotopic standardization technique by: determining the difference in buried soil ??13C and modern soil ??13C expected for that latitude (????13C), and transferring the ????13C to ??%C4 (% C4) using mass balance calculations. Our analysis reveals two isotopic stages in the mixed and shortgrass prairie of the Great Plains based on trends in ??%C4. In response to orbital forcing mechanisms, ??%C4 was persistently below modern in the Great Plains between 12 and 6.7 ka (isotopic stage II) evidently because of the cooling effect of the Laurentide ice sheet and proglacial lakes in northern latitudes, and glacial meltwater pulses cooling the Gulf of Mexico and North Atlantic Ocean. The ??%C4 after 6.7 ka (isotopic stage I) increased to modern levels as conditioned by the outflow of warm, moist air from the Gulf of Mexico and dry incursions from the west that produced periodic drought. At the millennial-scale, time series analysis demonstrates that ??%C4 oscillated with 0.6 and 1.8 ka periodicities, possibly governed by variations in solar irradiance. Our buried soil isotopic record correlates well with other environmental proxy from the Great Plains and surrounding regions. ?? 2008 Elsevier Ltd.

Quaternary Science Reviews↗

Pinyon and juniper encroachment into sagebrush ecosystems impacts distribution and survival of greater sage-grouse

In sagebrush ( Artemisia spp.) ecosystems, encroachment of pinyon ( Pinus spp.) and juniper ( Juniperus spp.; hereafter, “pinyon-juniper”) trees has increased dramatically since European settlement. Understanding the impacts of this encroachment on behavioral decisions, distributions, and population dynamics of greater sage-grouse (Centrocercus urophasianus) and other sagebrush obligate species could help benefit sagebrush ecosystem management actions. We employed a novel two-stage Bayesian model that linked avoidance across different levels of pinyon-juniper cover to sage-grouse survival. Our analysis relied on extensive telemetry data collected across 6 yr and seven subpopulations within the Bi-State Distinct Population Segment (DPS), on the border of Nevada and California. The first model stage indicated avoidance behavior for all canopy cover classes on average, but individual grouse exhibited a high degree of heterogeneity in avoidance behavior of the lowest cover class (e.g., scattered isolated trees). The second stage modeled survival as a function of estimated avoidance parameters and indicated increased survival rates for individuals that exhibited avoidance of the lowest cover class. A post hoc frailty analysis revealed the greatest increase in hazard (i.e., mortality risk) occurred in areas with scattered isolated trees consisting of relatively high primary plant productivity. Collectively, these results provide clear evidence that local sage-grouse distributions and demographic rates are influenced by pinyon-juniper, especially in habitats with higher primary productivity but relatively low and seemingly benign tree cover. Such areas may function as ecological traps that convey attractive resources but adversely affect population vital rates. To increase sage-grouse survival, our model predictions support reducing actual pinyon-juniper cover as low as 1.5%, which is lower than the published target of 4.0%. These results may represent effects of pinyon-juniper cover in areas with similar ecological conditions to those of the Bi-State DPS, where populations occur at relatively high elevations and pinyon-juniper is abundant and widespread.

Rangeland Ecology and Management↗

Embedded critical material flow: The case of niobium, the United States, and China

Niobium, often classified as critical, is typically embedded within steels essential for infrastructure and transportation. Most niobium-consuming countries are import-dependent on primary stage niobium, meaning traditional material flow analysis, which often excludes critical commodities embedded within products of large-scale industries, would miss important flows in the fabrication and manufacturing stages and underestimate niobium consumption. This study presents the first dynamic (2000–2020) niobium flow analysis for two niobium-consuming, net import-dependent countries: the United States (U.S.) and China. Results demonstrate that the U.S. is import-dependent throughout all stages of the niobium flow cycle including embedded and primary flows, whereas China is only import-dependent on primary niobium. Moreover, while most U.S. imports of niobium embedded within (semi-)finished goods are consumed domestically, most niobium-containing goods manufactured in China are exported, suggesting a supply disruption would affect their economies differently. This research demonstrates the necessity of embedded flows for criticality assessments and evaluating supply restrictions.

Resources, Conservation & Recycling↗

Detecting subtle change from dense landsat time series: Case studies of mountain pine beetle and spruce beetle disturbance

In contrast to abrupt changes caused by land cover conversion, subtle changes driven by a shift in the condition, structure, or other biological attributes of land often lead to minimal and slower alterations of the terrestrial surface. Accurate mapping and monitoring of subtle change are crucial for an early warning of long-term gradual change that may eventually result in land cover conversion. Freely accessible moderate-resolution datasets such as the Landsat archive have great potential to characterize subtle change by capturing low-magnitude spectral changes in long-term observations. However, past studies have reported limited success in accurately extracting subtle changes from satellite-based time series analysis. In this study, we introduce a supervised framework named ‘PIDS’ to detect subtle forest disturbance from a comprehensive Landsat data archive by leveraging disturbance-based calibration sites. PIDS consists of four components: (1) Parameter optimization; (2) Index selection; (3) Dynamic stratified monitoring; and (4) Spatial consideration. PIDS was applied to map the early stage of bark beetle infestations (i.e., a lower per-pixel fraction of trees cover that show visual signs of infestation), which are a typical example of subtle change in conifer forests. Landsat Analysis Ready Data were used as the time series inputs for mapping mountain pine beetle and spruce beetle disturbance between 2001 and 2019 in Colorado, USA. PIDS-detection map assessment showed that the overall performance of PIDS (namely ‘F1 score’) was 0.86 for mountain pine beetle and 0.73 for spruce beetle, making a substantial improvement (> 0.3) compared to other approaches/products including COntinuous monitoring of Land Disturbance, LandTrendr, and the National Land Cover Database forest disturbance product. A sub-pixel analysis of tree canopy mortality percentage was performed by linking classified high-resolution (0.3- and 1-m) aerial imagery and 30-m PIDS-detection maps. Results show that PIDS typically detects mountain pine beetle infestation when ≥56% of a Landsat pixel is occupied by red-stage canopy mortality (one year after initial infestation), and spruce beetle infestation when ≥55% is occupied by gray-stage mortality (two years after initial infestation). This study addresses an important methodological goal pertinent to the utility of event-based reference samples for detecting subtle forest change, which could be potentially applied to other types of subtle land change.

Colorado↗

Maternal transfer of polychlorinated biphenyls in Pacific sand lance (Ammodytes personatus), Puget Sound, Washington

We measured polychlorinated biphenyls (PCBs) in multiple age and size classes of Pacific sand lance ( Ammodytes personatus ), including eggs, young-of-the year, and adults to evaluate maternal transfer as a pathway for contaminant uptake and to add to the limited information on the occurrence of PCBs in sand lance in Puget Sound. Sampling was replicated at an urban embayment (Eagle Harbor) and a state park along an open shoreline (Clayton Beach), during spring and fall. Lipid-normalized concentrations of PCBs in sand lance at Eagle Harbor were 5–11 times higher than PCB concentrations in comparable samples at Clayton Beach. This was true for every life stage and size class of sand lance, including eggs removed from females. The same trend was observed in environmental samples. In Eagle Harbor, PCB concentrations in unfiltered water (0.19 ng/L), sieved (<63 μm) nearshore bed sediments (0.78 ng/g dw) and suspended particulate matter (1.69 ng/g dw) were 2–3 times higher than equivalent samples from near Clayton Beach. Sand lance collected in the fall (buried in sediment during presumed winter dormancy) had lower lipid content and up to four times higher PCB concentrations than comparably sized fish collected in the spring (by beach seine). Lipid content was 5–8% in spring fish and was reduced in fall fish (1–3%). Male sand lance had higher PCB concentrations than comparable females. All egg samples contained PCBs, and the lipid normalized egg/female concentration ratios were close to 1 (0.87–0.96), confirming that maternal transfer of PCBs occurred, resulting in sand lance eggs and early life stages being contaminated with PCBs even before they are exposed to exogenous sources. These life stages are prey for an even wider range of species than consume adult sand lance, creating additional exposure pathways for biota and increasing the challenges for mitigation of PCBs in the food web.

Washington↗

Sequence stratigraphy of the Upper Cambrian (Furongian; Jiangshanian and Sunwaptan) Tunnel City Group, Upper Mississippi Valley: Transgressing assumptions of cratonic flooding

New data from detailed measured sections permit comprehensive analysis of the sequence framework of the Furongian (Upper Cambrian; Jiangshanian and Sunwaptan stages) Tunnel City Group (Lone Rock Formation and Mazomanie Formation) of Wisconsin and Minnesota. The sequence-stratigraphic architecture of the lower part of the Sunwaptan Stage at the base of the Tunnel City Group, at the contact between the Wonewoc Formation and Lone Rock Formation, records the first part of complex polyphase flooding (Sauk III) of the Laurentian craton, at a scale smaller than most events recorded by global sea-level curves. Flat-pebble conglomerate and glauconite document transgressive ravinement and development of a condensed section when creation of accommodation exceeded its consumption by sedimentation. Thinly-bedded, fossiliferous sandstone represents the most distal setting during earliest highstand. Subsequent deposition of sandstone characterized by hummocky or trough cross-stratification records progradational pulses of shallower, storm- and wave-dominated environments across the craton before final flooding of Sauk III commenced with carbonate deposition during the middle part of the Sunwaptan Stage. Comparison of early Sunwaptan flooding of the inner Laurentian craton to published interpretations from other parts of North America suggests that Sauk III was not a single, long-term accommodation event as previously proposed.

Minnesota;Wisconsin↗

Modern, Sangamon and Yarmouth soil development in loess of unglaciated southwestern Illinois

The Thebes Section in unglaciated southwestern Illinois contains a well preserved ??? 500 kyr loess-paleosol sequence with four loesses and three interglacial soils. Various magnetic, mineralogical, and elemental properties were analyzed and compared over the thickness of soil sola. These proxies for soil] development intensity have the following trend: Yarmouth Geosol > Sangamon Geosol > modern soil. Quartz/plagioclase, Zr/Sr, and TiO2/Na2O ratios were most sensitive to weathering. Frequency dependent magnetic susceptibility and anhysteretic remanent magnetization, greatest in A horizons, also correspond well with soil development intensity. Neoformed mixed-layered kaolinite/expandables, suggestive of a warm/humid climate, were detected in the Sangamon and Yarmouth soil sola. Clay illuviation in soils was among the least sensitive indicators of soil development. Differences in properties among interglacial soils are interpreted to primarily reflect soil development duration, with climatic effects being secondary. Assuming logarithmic decreases in weathering rates, the observed weathering in the Sangamon Geosol is consistent with 50 kyr of interglacial weathering (Oxygen Isotope Stage 5) compared to 10 kyr for the modern soil (Oxygen Isotope Stage 1). We propose that the Yarmouth Geosol in the central Midwest formed over 180 kyr of interglacial weathering (including oxygen isotope stages 7, 9, and 11). ?? 2002 Elsevier Science Ltd. All rights reserved.

Quaternary Science Reviews↗

Quantitative characterization of the regressive ecological succession by fractal analysis of plant spatial patterns

We studied the effect of grazing on the degree of regression of successional vegetation dynamic in a semi-arid Mediterranean matorral. We quantified the spatial distribution patterns of the vegetation by fractal analyses, using the fractal information dimension and spatial autocorrelation measured by detrended fluctuation analyses (DFA). It is the first time that fractal analysis of plant spatial patterns has been used to characterize the regressive ecological succession. Plant spatial patterns were compared over a long-term grazing gradient (low, medium and heavy grazing pressure) and on ungrazed sites for two different plant communities: A middle dense matorral of Chamaerops and Periploca at Sabinar-Romeral and a middle dense matorral of Chamaerops, Rhamnus and Ulex at Requena-Montano. The two communities differed also in the microclimatic characteristics (sea oriented at the Sabinar-Romeral site and inland oriented at the Requena-Montano site). The information fractal dimension increased as we moved from a middle dense matorral to discontinuous and scattered matorral and, finally to the late regressive succession, at Stipa steppe stage. At this stage a drastic change in the fractal dimension revealed a change in the vegetation structure, accurately indicating end successional vegetation stages. Long-term correlation analysis (DFA) revealed that an increase in grazing pressure leads to unpredictability (randomness) in species distributions, a reduction in diversity, and an increase in cover of the regressive successional species, e.g. Stipa tenacissima L. These comparisons provide a quantitative characterization of the successional dynamic of plant spatial patterns in response to grazing perturbation gradient. ?? 2002 Elsevier Science B.V. All rights reserved.

Cabo de Gata Natural Park↗

An energy-circuit population model for great egrets (Ardea alba) at Lake Okeechobee, Florida, U.S.A

I simulated the annual population cycles of Great Egrets ( Ardea alba ) at Lake Okeechobee, Florida, to provide a framework for evaluating the local population dynamics of nesting and foraging wading birds. The external forcing functions were solar energy, minimum air temperature, water depth, surface-water drying rate, and season. Solar input controlled the production of prey at moderate to high lake stages, but water area exerted primary control during a two-year drought. Modeling prey production as a linear function of water area resulted in underestimation of prey density during the drought, suggesting that prey organisms maintained high fecundity while concentrated in submerged vegetation at the lakeward fringe of the littoral zone. Simulation confirmed that large influxes of wading birds during the drought were the combined result of a regional refuge response and the availability of concentrated prey. Modeling immigration and emigration as primarily functions of the surface-water drying rate, rather than lake stage, resulted in a closer match of observed and simulated population trends for foraging birds, suggesting that the pattern of surface-water fluctuations was a more important factor than water depth. Simulation indicated an abrupt-threshold response rather than a linear association between foraging efficiency and low temperatures, which reduce activity levels of forage fishes. Great Egret breeder recruitment is primarily a function of prey availability, climate, and hydrologic trends, but simulation confirmed the concurrent involvement of a seasonal or physiological-readiness factor. An attractor function driven by high winter lake stages was necessary to reproduce observed patterns of breeder recruitment, suggesting that Great Egrets initiate nesting based on environmental cues that lead to peak food availability when nestlings are present. Poor correspondence of reproductive effort and nest productivity suggested that the drought compromised the birds' predictive abilities. The need to model breeder recruitment as a function of a maximum rate rather than the size of the local foraging population suggested that birds may nest on the lake even though on-lake foraging conditions are poor. Simulated and observed estimates of egg and hatching production did not match, suggesting that the causes of failure during incubation were complex or more localized than could be accounted for with lakewide hydrologic and climatic data. A forced increase in prey consumption of 12% was necessary to reproduce observed, high levels of nest productivity in 1990, which corresponded to the finding that panhandled fish constituted 10–12% of the biomass fed to Great Egret nestlings that year.

Florida↗

The Whakamaru group ignimbrites, Taupo Volcanic Zone, New Zealand: Evidence for reverse tapping of a zoned silicic magmatic system

The Whakamaru group ignimbrites are widespread voluminous welded ignimbrites which crop out along the eastern and western margins of the Taupo Volcanic Zone (TVZ), New Zealand. The ignimbrites have a combined volume exceeding 1000 km 3 , and were erupted from a large caldera in the central TVZ around 340 ka, following a c. 350 ka hiatus in caldera-forming activity in TVZ. Analysis of individual pumice clasts identifies five distinct magma types (rhyolite types A to D, and high alumina basalt) and significant gradients in temperature, water content, and Sr isotopic composition in the pre-eruptive Whakamaru magmatic system. There is a marked variation in mineral assemblage with composition; type A low-silica rhyolite pumices contain plagioclase, quartz, orthopyroxene, hornblende, biotite, and magnetite/ilmenite with distinctive large rounded quartz phenocrysts. High-silica (types B and C) pumices contain quartz (smaller, subhedral phenocrysts), plagioclase, sanidine, biotite, and magnetite/ilmenite. Type D pumices are rich in plagioclase and biotite phenocrysts, and have anomalously high Rb contents (>200 ppm) relative to all other pumice types. Rhyolite types B and C are related to type A magma by a two-stage crystal fractionation process, probably by side wall crystallisation and convective fractionation. The first stage involved 30–40% fractionation of a plagioclase-dominated (sanidine-free) assemblage to produce a type B magma, which in turn underwent fractionation of a plagioclase/quartz/sanidine assemblage to produce the highly evolved, but relatively Ba-depleted, type C magmas. Stratigraphic variations in modal proportions of mineral phases, and calculated Fe–Ti oxide equilibrium temperatures indicate that eruptions commenced with the hottest, least evolved magmas, and more evolved magmas became important at a later stage in the eruption along with a high alumina basalt component. This reverse-zoned sequence precludes simple sequential tapping of a large zoned magma chamber, and indicates a complex magma chamber configuration and/or withdrawal dynamics during eruption. Type D magma, which appears to be unrelated to either types A or B by crystal fractionation, may have formed a separate subjacent chamber that was ruptured and incorporated into the eruption. The Whakamaru magma system provides clear evidence that (less evolved) low silica rhyolites undergo significant fractionation at shallow crustal levels in central TVZ, to produce the generally more evolved rhyolites more commonly erupted at the surface, and suggests large ignimbrite eruptions may tap multiple magma chambers.

Journal of Volcanology and Geothermal Research↗

Deep-sea ostracode species diversity: Response to late Quaternary climate change

Late Quaternary ostracode assemblages from the North Atlantic Ocean were studied to establish the effect of climatic changes of the past 210,000 yr (marine oxygen isotope stages 7–1) on deep-sea benthic biodiversity and faunal composition. Two-hundred and twenty five samples from the Chain 82-24 Core 4PC (41°43′N, 32°51′W, 3427 m water depth) on the western Mid-Atlantic Ridge revealed high amplitude fluctuations in ostracode abundance and diversity coincident with orbital and suborbital scale climate oscillations measured by several paleoceanographic proxy records. During the past 210,000 yr, ostracode biodiversity as measured by species number ( S ) and the Shannon–Weaver index, H ( S ), oscillated from H ( S )=0.4 during glacial periods (marine isotope stages 6, 5d, 5b, 4, and 2) to H ( S )=1.1 during interglacial and interstadial periods (stages 7, 5e, 5c, 5a, 3 and 1). A total of 23 diversity peaks could be recognized. Eleven of these signify major periods of high diversity [ H ( S )>0.8, S = 10–21] occurring every 15–20 ka. Twelve were minor peaks which may represent millennial-scale diversity oscillations. The composition of ostracode assemblages varies with Krithe -dominated assemblages characterizing glacial intervals, and Argilloecia–Cytheropteron characterizing deglacials, and trachyleberid genera ( Poseidonamicus , Echinocythereis , Henryhowella , Oxycythereis ) abundant during interglacials. Diversity and faunal composition changes can be matched to independent deep-sea paleoceanographic tracers such as benthic foraminiferal carbon isotopes, Krithe trace elements (Mg/Ca ratios), and to North Atlantic region climate records such as Greenland ice cores. When interpreted in light of ostracode species' ecology, these faunal and diversity patterns provide evidence that deep-sea benthic ecosystems experience significant reorganization in response to climate changes over orbital to millennial timescales.

Marine Micropaleontology↗

Paleopedology plus TL, 10Be, and14C dating as tools in stratigraphic and paleoclimatic investigations, Mississippi River Valley, U.S.A.

Thick ( ??? 35 m) loess deposits are present on ridges and high bluffs in the northern-half of the Lower Mississippi Valley (LMV), U.S.A. Detailed descriptions of the loess sections and pedologic, physiochemical, and mineralogic analyses and TL, 14C, and 10Be age determinations, allow preliminary paleoclimatic reconstructions for the late Quaternary of central North America. No age data are available for the oldest (Fifth) loess. 10Be and TL age data suggest a 250-200 ka age for the Fourth or Crowleys Ridge(?) Loess, and indicate that the Loveland or Third Loess is time equivalent to oxygen isotope stage 6, ??? 190-120 ka. A weakly developed paleosol is present in the basal-half of the Loveland. The Sangamon Geosol is present in the upper 5 m and represents all of oxygen isotope stage 5, ??? 130-60 ka. It formed in a climate as warm as, but drier and (or) with greater variation in precipitation, than the present. The Roxana Silt (second loess) was deposited during oxygen isotope stages 4 and 3, ??? 65-26 ka. The early Wisconsinan interglacial-glacial transition, represented by the Sangamon Geosol and the unnamed paleosol in the basal Roxana Silt, was slow. The paleoclimate during the 35 k yr of Roxana deposition was cool to cold and wet. Age and pedologic data indicate that deposition of the Peoria Loess (the youngest) began around 25 ka when the area's climate changed abruptly from cool or cold and wet to cold and dry, with periods of sustained high winds.

Quaternary International↗

Late glacial–Younger Dryas climate in interior Alaska as inferred from the isotope values of land snail shells

The isotope values of fossil snail shells can be important archives of climate. Here, we present the first carbon (δ 13 C) and oxygen (δ 18 O) isotope values of snail shells in interior Alaska to explore changes in vegetation and humidity through the late-glacial period. Snail shell δ 13 C values were relatively consistent through the late glacial. However, late-glacial shell δ 13 C values are 2.8‰ higher than those of modern shells. This offset is best explained by the Suess effect and changes in the δ 13 C values of snail diet. Snail shell δ 18 O values varied through the late glacial, which can be partially explained by changes in relative humidity (RH). RH during the snail growing period was modeled based on a published flux balance model. Results suggest a dry period toward the beginning of the Bølling–Allerød (~14 ka) followed by two distinct stages of the Younger Dryas, a wetter stage in the early Younger Dryas from 12.9 to 12.3 ka, and subsequent drier stage in the late Younger Dryas between 12.3 and 11.7 ka. The results show that land snail isotopes in high-latitude regions may be used as a supplementary paleoclimate proxy to help clarify complex climate histories, such as those of interior Alaska during the Younger Dryas.

Alaska↗

Relationships between silicic plutonism and volcanism: Geochemical evidence

Field associations (voluminous ash flow deposits, rhyolitic stocks and dykes, ring complexes), evidence of repeated influxes of mafic magma, and thermal constraints indicate that many high-level silicic plutons (magma chambers) acted as open systems for considerable parts of their history. The long thermal lifetime, as well as other evidence from the volcanic record, suggests that some such systems reached a quasi-steady state in which magma input was balanced by magma output for times longer than those required for crystallisation. Reconstruction of the evolution of large, long-lived caldera-forming systems, such as that of the Jemez Mountains, New Mexico, indicates that many chambers have lost a highly fractionated silicic cap, in some cases cyclically. Crystallised plutons may contain no obvious record of this evolutionary phase. Geochemical data from silicic ash flow deposits can be used to reconstruct the volcanic stage of pluton development. Many silicic systems, especially of alkaline affinity, apparently pass from a stage in which melt evolution is dominated by crystal-liquid processes to one in which other processes may also contribute to differentiation. Apparently, the transition is most readily achieved in volatile-rich, alkaline silicic systems emplaced in complex, ancient sialic crust of the cratons. Once established, the preservation of highly fractionated caps on magma chambers requires a balance between thermal input and cooling-induced crystallisation. If heat enters the system too quickly, the cap may get stirred into the dominant magma volume by convection. If heat input is too slow, the magma body will crystallise inward from the margins, and the plutonic-consolidation stage will begin. © 1988, Royal Society of Edinburgh. All rights reserved.

Transactions of the Royal Society of Edinburgh, Ea↗

miR133b microinjection during early development targets transcripts of sardiomyocyte ion channels and induces oil-like cardiotoxicity in zebrafish (Danio rerio) embryos

Previous studies have shown that altered expression of a family of small noncoding RNAs (microRNAs, or miRs) regulates the expression of downstream mRNAs and is associated with diseases and developmental disorders. miR133b is highly expressed in mammalian cardiac and skeletal muscle, and aberrant expression is associated with cardiac disorders and electrophysiological changes in cardiomyocytes. Similarly, cardiac dysfunction has been observed in early life-stage mahi-mahi ( Coryphaena hippurus ) exposed to crude oil, a phenotype that has been associated with an upregulation of miR133b as well as subsequent downregulation of a delayed rectifier potassium channel (I Kr ) and calcium signaling genes that are important for proper heart development during embryogenesis. To examine the potential role of miR133b in oil-induced early life-stage cardiotoxicity in fish, cleavage-stage zebrafish ( Danio rerio ) embryos were either (1) microinjected with ∼3 nL of negative control miR (75 μM) or miR133b (75 μM) or (2) exposed to a treatment solution containing 5 μM benzo(a)pyrene (BaP), a model polycyclic aromatic hydrocarbon, as a positive control. At 72 h post fertilization (hpf), miR133b-injected fish exhibited BaP-like cardiovascular malformations, including a significantly increased pericardial area relative to negative control miR-injected embryos, as well as a significantly reduced eye area. qPCR revealed that miR133b microinjection decreased the abundance of cardiac-specific I Kr kcnh6 at 5 hpf, which may contribute to action potential elongation in oil-exposed cardiomyocytes. Additionally, ryanodine receptor 2, a crucial calcium receptor in the sarcoplasmic reticulum, was also downregulated by miR133b. These results indicate that an oil-induced increase in miR133b may contribute to cardiac abnormalities in oil-exposed fish by targeting cardiac-specific genes essential for proper heart development.

Chemical Research in Toxicology↗

Complex life histories alter patterns of mercury exposure and accumulation in a pond-breeding amphibian

Quantifying how contaminants change across life cycles of species that undergo metamorphosis is critical to assessing organismal risk, particularly for consumers. Pond-breeding amphibians can dominate aquatic animal biomass as larvae and are terrestrial prey as juveniles and adults. Thus, amphibians can be vectors of mercury exposure in both aquatic and terrestrial food webs. However, it is still unclear how mercury concentrations are affected by exogenous (e.g., habitat or diet) vs endogenous factors (e.g., catabolism during hibernation) as amphibians undergo large diet shifts and periods of fasting during ontogeny. We measured total mercury (THg), methylmercury (MeHg), and isotopic compositions (δ 13 C, δ 15 N) in boreal chorus frogs ( Pseudacris maculata ) across five life stages in two Colorado (USA) metapopulations. We found large differences in concentrations and percent MeHg (of THg) among life stages. Frog MeHg concentrations peaked during metamorphosis and hibernation coinciding with the most energetically demanding life cycle stages. Indeed, life history transitions involving periods of fasting coupled with high metabolic demands led to large increases in mercury concentrations. The endogenous processes of metamorphosis and hibernation resulted in MeHg bioamplification, thus decoupling it from the light isotopic proxies of diet and trophic position. These step changes are not often considered in conventional expectations of how MeHg concentrations within organisms are assessed.

Environmental Science & Technology↗