USGS Science⌕ Search

SEARCH · USGS Science

Results for “Environmental Health”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,657 records · Page 92Linked to original sources

The presence of antibiotic resistance genes in coastal soil and sediment samples from the eastern seaboard of the USA

Infections from antibiotic resistant microorganisms are considered to be one of the greatest global public health challenges that result in huge annual economic losses. While genes that impart resistance to antibiotics (AbR) existed long before the discovery and use of antibiotics, anthropogenic uses of antibiotics in agriculture, domesticated animals, and humans are known to influence the prevalence of these genes in pathogenic microorganisms. It is critical to understand the role that natural and anthropogenic processes have on the occurrence and distribution of antibiotic resistance in microbial populations to minimize health risks associated with exposures. As part of this research, 15 antibiotic resistance genes were analyzed in coastal sediments and soils along the eastern seaboard of the USA using presence/absence quantitative and digital polymerase chain reaction assays. Samples (53 soil and 192 sediment samples including 54 replicates) were collected from a variety of coastal settings where human and wildlife exposure is likely. At least one of the antibiotic resistance genes was detected in 76.4% of the samples. Samples that contained at least five or more antibiotic resistance genes (5.7%) where typically hydrologically down gradient of watersheds influenced by combined sewer outfalls (CSO). The most frequently detected antibiotic resistance target genes were found in 33.2%, 34.4%, and 42.2% of samples (target genes bla SHV , tetO , and aadA2 , respectively). These data provide unique insight into potential exposure of AbR genes over a large geographical region of the eastern seaboard of the USA.

Connecticut, Delaware, District of Columbia, Maine↗

Lead poisoning of waterfowl by contaminated sediment in the Coeur D'Alene River

The Coeur d'Alene River basin in Idaho has been contaminated by mine tailings that have impaired the health of wildlife since the early 1900s. In other parts of the world, virtually all lead poisoning of waterfowl is caused by the ingestion of manmade lead artifacts, primarily spent lead shotshell pellets or, occasionally, fishing sinkers. However, in the Coeur d'Alene River basin in Idaho, nonartifactual lead poisoning was the ultimate cause of death of most of 219 (77%) of 285 waterfowl carcasses that had been found sick or dead from 1992 through 1997. The majority of these 219 waterfowl (172 tundra swans [Cygnus columbianus], 33 Canada geese [Branta canadensis], and 14 other species) were poisoned by ingesting river sediment that was contaminated with lead. The next most common cause of death (20 instances, 7%) was lead poisoning accompanied by ingested shotshell pellets. The remaining 46 waterfowl succumbed to trauma, infectious diseases (aspergillosis, avian cholera, tuberculosis), or miscellaneous problems, or the cause of death was not determined.

Idaho↗

Distribution of Tubifex tubifex lineages and Myxobolus cerebralis infection in the tailwater of the San Juan River, New Mexico

We chose a hypolimnetic-release tailwater of the San Juan River, New Mexico, to characterize the etiology of whirling disease, a parasitic infection of salmonids. We sampled a 2-km reach of the tailwater in August and December 2001 and June 2002 to characterize environmental factors influencing the distribution and density of Tubifex tubifex lineages and Myxobolus cerebralis infection rates. Shortly after the scouring flow, organic matter in sediments and T. tubifex densities increased within deep habitats. In contrast, no differences were observed in T. tubifex densities and organic matter collected from shallow habitats throughout the three sampling dates. Within this study area, we found three sympatric lineages of T. tubifex (lineages I, III, and VI). Lineage VI dominated riffle reaches, whereas lineages I, III, and VI were observed in pool habitats. Myxobolus cerebralis infection rates were higher in T. tubifex collected in pool habitats (3.01%) than in those collected in riffle habitats (0.51%). Only lineage III exhibited infection with M. cerebralis. We suggest that the habitat and genotype of T. tubifex are important in characterizing prevalence of disease within the San Juan River tailwater. Scouring flow may have a beneficial effect on disease severity in salmonid hosts by reducing organic loading and hence T. tubifex abundance in deep habitats.

Journal of Aquatic Animal Health↗

Retrospective Review of Watershed Characteristics and a Framework for Future Research in the Sarasota Bay Watershed, Florida

The U.S. Geological Survey, in cooperation with the Sarasota Bay Estuary Program conducted a retrospective review of characteristics of the Sarasota Bay watershed in west-central Florida. This report describes watershed characteristics, surface- and ground-water processes, and the environmental setting of the Sarasota Bay watershed. Population growth during the last 50 years is transforming the Sarasota Bay watershed from rural and agriculture to urban and suburban. The transition has resulted in land-use changes that influence surface- and ground-water processes in the watershed. Increased impervious cover decreases recharge to ground water and increases overland runoff and the pollutants carried in the runoff. Soil compaction resulting from agriculture, construction, and recreation activities also decreases recharge to ground water. Conventional approaches to stormwater runoff have involved conveyances and large storage areas. Low-impact development approaches, designed to provide recharge near the precipitation point-of-contact, are being used increasingly in the watershed. Simple pollutant loading models applied to the Sarasota Bay watershed have focused on large-scale processes and pollutant loads determined from empirical values and mean event concentrations. Complex watershed models and more intensive data-collection programs can provide the level of information needed to quantify (1) the effects of lot-scale land practices on runoff, storage, and ground-water recharge, (2) dry and wet season flux of nutrients through atmospheric deposition, (3) changes in partitioning of water and contaminants as urbanization alters predevelopment rainfall-runoff relations, and (4) linkages between watershed models and lot-scale models to evaluate the effect of small-scale changes over the entire Sarasota Bay watershed. As urbanization in the Sarasota Bay watershed continues, focused research on water-resources issues can provide information needed by water-resources managers to ensure the future health of the watershed.

Open-File Report↗

Advancements in hydrochemistry mapping: methods and application to groundwater arsenic and iron concentrations in Varanasi, Uttar Pradesh, India

The area east of Varanasi is one of numerous places along the watershed of the Ganges River with groundwater concentrations of arsenic surpassing the maximum value of 10 parts per billion (ppb) recommended by the World Health Organization in drinking water. Here we apply geostatistics and compositional data analysis for the mapping of arsenic and iron to help in understanding the conditions leading to the occurrence of elevated level of arsenic in groundwater. The methodology allows for displaying concentrations of arsenic and iron as maps consistent with the limited information from 95 water wells across an area of approximately 210 km 2 ; visualization of the uncertainty associated with the sampling; and summary of the findings in the form of probability maps. For thousands of years, Varanasi has been on the erosional side in a meander of the river that is free of arsenic values above 10 ppb. Maps reveal two anomalies of high arsenic concentrations on the depositional side of the valley, which has started seeing urban development. The methodology using geostatistics combined with compositional data analysis is completely general, so this study could be used as a prototype for hydrochemistry mapping in other areas.

Uttar Pradesh↗

Linking climate change and health outcomes: Examining the relationship between temperature, precipitation and birth weight in Africa

This paper examined the relationship between birth weight, precipitation, and temperature in 19 African countries. We matched recorded birth weights from Demographic and Health Surveys covering 1986 through 2010 with gridded monthly precipitation and temperature data derived from satellite and ground-based weather stations. Observed weather patterns during various stages of pregnancy were also used to examine the effect of temperature and precipitation on birth weight outcomes. In our empirical model we allowed the effect of weather factors to vary by the dominant food production strategy (livelihood zone) in a given region as well as by household wealth, mother's education and birth season. This allowed us to determine if certain populations are more or less vulnerable to unexpected weather changes after adjusting for known covariates. Finally we measured effect size by observing differences in birth weight outcomes in women who have one low birth weight experience and at least one healthy birth weight baby. The results indicated that climate does indeed impact birth weight and at a level comparable, in some cases, to the impact of increasing women's education or household electricity status.

Global Environmental Change↗

Montana Valley and Foothill Prairies Ecoregion: Chapter 6 in Status and trends of land change in the Western United States--1973 to 2000

The Montana Valley and Foothill Prairies Ecoregion comprises numerous intermountain valleys and low-elevation foothill prairies spread across the western half of Montana, on both sides of the Continental Divide (Omernik, 1987; U.S. Environmental Protection Agency, 1997). The ecoregion, which covers approximately 64,658 km 2 (24,965 mi 2 ), includes the Flathead Valley and the valleys surrounding Helena, Missoula, Bozeman, Billings, Anaconda, Dillon, and Lewistown (fig. 1). These valleys are generally characterized by shortgrass prairie vegetation and are flanked by forested mountains (Woods and others, 1999); thus, the valleys’ biotas with regards to fish and insects are comparable. In many cases, the valleys are conduits for some of the largest rivers in the state, including Clark Fork and the Missouri, Jefferson, Madison, Flathead, Yellowstone, Gallatin, Smith, Big Hole, Bitterroot, and Blackfoot Rivers (fig. 2). The Montana Valley and Foothill Prairies Ecoregion also includes the “Rocky Mountain front,” an area of prairies along the eastern slope of the northern Rocky Mountains. Principal land uses within the ecoregion include farming, grazing, and mining. The valleys serve as major transportation and utility corridors and also contain the majority of Montana’s human population. The Montana Valley and Foothill Prairies Ecoregion extends into 17 mostly rural counties throughout western Montana. Only three of the counties—Carbon, Yellowstone, and Missoula—are part of a metropolitan statistical area with contiguous built-up areas tied to an employment center. Nearly two-thirds of Montana residents live in nonmetropolitan counties (Albrecht, 2008). Ten of the counties within the ecoregion had population growth rates greater than national averages (9–13 percent) between 1970 and 2000 (table 1). Ravalli and Gallatin Counties had the highest growth rates. Population growth was largely due to amenity-related inmigration and an economy dependent on tourism, health care, and services. Counties that had population declines, such as Deer Lodge, Silver Bow, and Meagher Counties, also had declines in agriculture and mining activity, and they had railroad closures as well. Climate varies from north to south and from the east side of the Continental Divide to the west side. However, all areas are semiarid with long cold winters and short growing seasons. In the western part of the ecoregion, Beaverhead, Bitterroot, Flathead, and Lolo National Forests provide the natural resources, particularly timber, that form the economic base for towns within nearby valleys. Mineral resources from mines in and around Anaconda, Deer Lodge, and Butte have long provided an economic base for these towns (fig. 3).

Idaho;Montana;Wyoming↗

A high efficiency method for the extraction and quantitative analysis of 45 PFAS in whole fish

This study describes and validates a new method for extracting perfluoroalkyl and polyfluoroalkyl substances (PFAS) from whole-body fish tissue, demonstrates that freeze-dry preservation of tissue conserves bioaccumulative PFAS, and details a method demonstration on Lake Michigan fish. While fish filets are more commonly analyzed for their significance to human health, whole fish are useful to determine ecological impacts, but published methods such as EPA 1633 do not produce reliable results for this more challenging matrix. Here we show that lipid removal technology produces clean extracts without the need for solid-phase extraction or evaporative concentration, which often lead to loss of some PFAS. This method achieves an accuracy of 96 ± 9% for the detection of 45 PFAS while also offering benefits of a simple procedure, reduced processing time, and decreased waste generation compared to multistep cleanup and concentration methods. A test of freeze-drying demonstrated that compounds detected in Great Lakes fish were retained, but volatile compounds including sulfonamide precursors and ethanols were lost. To demonstrate field performance, the entire method was applied to whole-fish composites from Lake Michigan. Results from these samples reveal that the PFAS concentration was driven by collection location, while the distribution of PFAS was dictated by fish species.

Environmental Science & Technology↗

Geogenic sources of benzene in aquifers used for public supply, California

Statistical evaluation of two large statewide data sets from the California State Water Board's Groundwater Ambient Monitoring and Assessment Program (1973 wells) and the California Department of Public Health (12417 wells) reveals that benzene occurs infrequently (1.7%) and at generally low concentrations (median detected concentration of 0.024 &mu;g/L) in groundwater used for public supply in California. When detected, benzene is more often related to geogenic (45% of detections) than anthropogenic sources (27% of detections). Similar relations are evident for the sum of 17 hydrocarbons analyzed. Benzene occurs most frequently and at the highest concentrations in old, brackish, and reducing groundwater; the detection frequency was 13.0% in groundwater with tritium <1 pCi/L, specific conductance >1600 &mu;S/cm, and anoxic conditions. This groundwater is typically deep (>180 m). Benzene occurs somewhat less frequently in recent, shallow, and reducing groundwater; the detection frequency was 2.6% in groundwater with tritium ≥1 pCi/L, depth <30 m, and anoxic conditions. Evidence for geogenic sources of benzene include: higher concentrations and detection frequencies with increasing well depth, groundwater age, and proximity to oil and gas fields; and higher salinity and lower chloride/iodide ratios in old groundwater with detections of benzene, consistent with interactions with oil-field brines.

California↗

Cancer risk from incidental ingestion exposures to PAHs associated with coal-tar-sealed pavement

Recent (2009–10) studies documented significantly higher concentrations of polycyclic aromatic hydrocarbons (PAHs) in settled house dust in living spaces and soil adjacent to parking lots sealed with coal-tar-based products. To date, no studies have examined the potential human health effects of PAHs from these products in dust and soil. Here we present the results of an analysis of potential cancer risk associated with incidental ingestion exposures to PAHs in settings near coal-tar-sealed pavement. Exposures to benzo[ a ]pyrene equivalents were characterized across five scenarios. The central tendency estimate of excess cancer risk resulting from lifetime exposures to soil and dust from nondietary ingestion in these settings exceeded 1 × 10 –4 , as determined using deterministic and probabilistic methods. Soil was the primary driver of risk, but according to probabilistic calculations, reasonable maximum exposure to affected house dust in the first 6 years of life was sufficient to generate an estimated excess lifetime cancer risk of 6 × 10 –5 . Our results indicate that the presence of coal-tar-based pavement sealants is associated with significant increases in estimated excess lifetime cancer risk for nearby residents. Much of this calculated excess risk arises from exposures to PAHs in early childhood (i.e., 0–6 years of age).

Environmental Science & Technology↗

South Florida wetlands ecosystem; biogeochemical processes in peat

The South Florida wetlands ecosystem is an environment of great size and ecological diversity (figs. 1 and 2). The landscape diversity and subtropical setting of this ecosystem provide a habitat for an abundance of plants and wildlife, some of which are unique to South Florida. South Florida wetlands are currently in crisis, however, due to the combined effects of agriculture, urbanization, and nearly 100 years of water management. Serious problems facing this ecosystem include (1) phosphorus contamination producing nutrient enrichment, which is causing changes in the native vegetation, (2) methylmercury contamination of fish and other wildlife, which poses a potential threat to human health, (3) changes in the natural flow of water in the region, resulting in more frequent drying of wetlands, loss of organic soils, and a reduction in freshwater flow to Florida Bay, (4) hypersalinity, massive algal blooms, and seagrass loss in parts of Florida Bay, and (5) a decrease in wildlife populations, especially those of wading birds. This U.S. Geological Survey (USGS) project focuses on the role of organic-rich sediments (peat) of South Florida wetlands in regulating the concentrations and impact of important chemical species in the environment. The cycling of carbon, nitrogen, phosphorus, and sulfur in peat is an important factor in the regulation of water quality in the South Florida wetlands ecosystem. These elements are central to many of the contamination issues facing South Florida wetlands, such as nutrient enrichment, mercury toxicity, and loss of peat. Many important chemical and biological reactions occur in peat and control the fate of chemical species in wetlands. Wetland scientists often refer to these reactions as biogeochemical processes, because they are chemical reactions usually mediated by microorganisms in a geological environment. An understanding of the biogeochemical processes in peat of South Florida wetlands will provide a basis for evaluating the effects on water quality of (1) constructing buffer wetlands to alleviate nutrient contamination and (2) replumbing the ecosystem to restore natural water flow. The results may also suggest new approaches for solving problems of contamination and water quality in these wetlands. A second focus of this project will be on the geochemical history of the South Florida ecosystem. Peat is a repository of the history of past environmental conditions in the wetland. Before effective action can be taken to correct many of the problems facing these wetlands, we must first study the biogeochemistry of the peat at depth in order to understand whether current problems are the result of recent human activity or are part of a long-term natural cycle. Coordination with other (USGS) projects for South Florida is ongoing. These projects are studying the biological history of the ecosystem by using pollen and shells buried in the peat, together with procedures for dating the peat at various depths, to develop an overall ecosystem history model, with emphasis on the last 100 years.

Fact Sheet↗

A probabilistic model for silver bioaccumulation in aquatic systems and assessment of human health risks

Silver (Ag) is discharged in wastewater effluents and is also a component in a proposed secondary water disinfectant. A steady-state model was developed to simulate bioaccumulation in aquatic biota and assess ecological and human health risks. Trophic levels included phytoplankton, invertebrates, brown trout, and common carp. Uptake routes included water, food, or sediment. Based on an extensive review of the literature, distributions were derived for most inputs for use in Monte Carlo simulations. Three scenarios represented ranges of dilution and turbidity. Compared with the limited field data available, median estimates of Ag in carp (0.07-2.1 I&mu;g/g dry weight) were 0.5 to 9 times measured values, and all measurements were within the predicted interquartile range. Median Ag concentrations in biota were ranked invertebrates > phytoplankton > trout > carp. Biotic concentrations were highest for conditions of low dilution and low turbidity. Critical variables included Ag assimilation eficiency, specific feeding rate, and the phytoplankton bioconcentration factor. Bioaccumulation of Ag seems unlikely to result in txicity to aquatic biota and humans consuming fish. Although the highest predicted Ag concentrations in water (>200 ng/L) may pose chronic risks to early survival and development of salmonids and risks of argyria to subsistence fishers, these results occur under highly conservative conditions.

Environmental Toxicology and Chemistry↗

Contribution of hydroxylated atrazine degradation products to the total atrazine load in midwestern streams

The contribution of hydroxylated atrazine degradation products (HADPs) to the total atrazine load (i.e., atrazine plus stable metabolites) in streams needs to be determined in order to fully assess the impact of atrazine contamination on stream ecosystems and human health. The objectives of this study were (1) to determine the contribution of HADPs to the total atrazine load in streams of nine midwestern states and (2) to discuss the mechanisms controlling the concentrations of HADPs in streams. Stream samples were collected from 95 streams in northern Missouri at preplant and postplant of 1994 and 1995, and an additional 46 streams were sampled in eight midwestern states at postplant of 1995. Samples were analyzed for atrazine, deethylatrazine (DEA), deisopropylatrazine (DIA), and three HADPs. Overall, HADP prevalence (i.e., frequency of detection) ranged from 87 to 100% for hydroxyatrazine (HA), 0 to 58% for deethylhydroxyatrazine (DEHA), and 0% for deisopropylhydroxyatrazine (DIHA) with method detection limits of 0.04−0.10 μg L -1 . Atrazine metabolites accounted for nearly 60% of the atrazine load in northern Missouri streams at preplant, with HA the predominant metabolite present. Data presented in this study and a continuous monitoring study are used to support the hypothesis that a combination of desorption from stream sediments and dissolved-phase transport control HADP concentrations in streams.

Environmental Science & Technology↗

Phosphorus and the Chesapeake Bay: Lingering issues and emerging concerns for agriculture

Hennig Brandt's discovery of phosphorus (P) occurred during the early European colonization of the Chesapeake Bay region. Today, P, an essential nutrient on land and water alike, is one of the principal threats to the health of the bay. Despite widespread implementation of best management practices across the Chesapeake Bay watershed following the implementation in 2010 of a total maximum daily load (TMDL) to improve the health of the bay, P load reductions across the bay's 166,000‐km 2 watershed have been uneven, and dissolved P loads have increased in a number of the bay's tributaries. As the midpoint of the 15‐yr TMDL process has now passed, some of the more stubborn sources of P must now be tackled. For nonpoint agricultural sources, strategies that not only address particulate P but also mitigate dissolved P losses are essential. Lingering concerns include legacy P stored in soils and reservoir sediments, mitigation of P in artificial drainage and stormwater from hotspots and converted farmland, manure management and animal heavy use areas, and critical source areas of P in agricultural landscapes. While opportunities exist to curtail transport of all forms of P, greater attention is required toward adapting P management to new hydrologic regimes and transport pathways imposed by climate change.

Delaware, Maryland, Virginia↗

The contribution of land cover change to the decline of honey yields in the Northern Great Plains

Decreased availability of forage, as well as increased pesticide exposure, are important factors in the decline of honey bee health. Here, we isolate land cover transitions and their effect on honey production at 160 commercial apiaries in the Northern Great Plains. We found that land cover changes from 2008 to 2012 caused an annual decline in honey yields of 0.9% in the study area. Transitions from grassland to soybean (but not corn) were particularly detrimental to honey yields, potentially due to bee contact with pesticides within and around agricultural fields. When our results are applied to known apiary locations across all of North Dakota (U.S.A.), we estimate a 2.5% (1.6 million USD) decline in 2012 honey yields due to land cover changes occurring between 2008 and 2012. Even when controlling for changes in land cover, we found that on average colonies in the study area experienced a 14% annual decline in honey yields. We discuss possible explanations for these non-land-cover-related honey yield declines, including changing economic conditions (e.g. pollination services), changes in land management (e.g. pesticides), and increases in pests or diseases.

South Dakota↗

Mercury concentrations in salmonids from western U.S. National Parks and relationships with age and macrophage aggregates

Mercury accumulation in aquatic foodwebs and its effects on aquatic biota are of growing concern both for the health of the fish and the piscivores that prey upon them. This is of particular concern for western U.S. National Parks because it is known that mountainous and Arctic areas are sinks for some contaminants. The Western Airborne Contaminants Assessment Project seeks, in part, to ascertain mercury concentrations and evaluate effects of contaminants on biota in 14 lakes from 8 National Parks or Preserves. In this paper we report that mercury has accumulated to concentrations in trout that may negatively impact some piscivorous wildlife, indicating potential terrestrial ecosystem effects. Additionally, we show that mercury concentrations increase with age in 4 species of trout, providing evidence of bioaccumulation. Finally, we demonstrate that mercury is associated with tissue damage in the kidney and spleen, as indicated by increases in macrophage aggregates. This finding suggests that mercury, and possibly other contaminants, are negatively affecting the trout that inhabit these remote and protected ecosystems. Our results indicate that mercury is indeed a concern for the U.S. National Parks, from an organismic and potentially an ecosystem perspective. ?? 2008 American Chemical Society.

Environmental Science & Technology↗

Potential for water borne and invertebrate transmission of West Nile virus in the Great Salt Lake, Utah

In November and December of 2013, a large mortality event involving 15,000 - 20,000 eared grebes ( Podiceps nigricollis ) occurred at the Great Salt Lake (GSL), UT. The onset of the outbreak in grebes was followed by a mortality event in > 86 bald eagles ( Haliaeetus leucocephalus ). During the die-off, West Nile virus (WNV) was detected by RT-PCR or viral culture in carcasses of grebes and eagles submitted to the National Wildlife Health Center. However, no mosquito activity, the primary vector of WNV, was detected by the State of Utah's WNV monitoring program. Transmission of WNV has rarely been reported during the winter in North America in the absence of known mosquito activity; however, the size of this die-off, the habitat in which it occurred, and the species involved are unique. We experimentally investigated whether WNV could survive in water with a high saline content, as found at the GSL, and whether brine shrimp, the primary food of migrating eared grebes on the GSL, could have played a role in transmission of WNV to feeding birds. We found that WNV can survive up to 72 h at 4°C in water containing 30 — 150 ppt NaCl and brine shrimp, incubated with WNV in 30 ppt NaCl, may adsorb WNV to their cuticle and, through feeding, may infect epithelial cells of their gut. Both mechanisms may have potentiated the WNV die-off in migrating eared grebes on the GSL.

Utah↗

Centurial persistence of forever chemicals at military fire training sites

Drinking water contamination by per- and polyfluoroalkyl substances (PFAS) is widespread near more than 300 United States (U.S.) military bases that used aqueous film-forming foams (AFFF) for fire training and firefighting activities. Much of the PFAS at these sites consist of precursors that can transform into terminal compounds of known health concern but are omitted from standard analytical methods. Here, we estimate the expected duration and contribution of precursor biotransformation to groundwater PFAS contamination at an AFFF-contaminated military base on Cape Cod, Massachusetts, United States, by optimizing a geochemical box model using measured PFAS concentrations from a multidecadal time series of groundwater and a soil survey in the source zone. A toolbox of analytical techniques used to reconstruct the mass budget of PFAS showed that precursors accounted for 46 ± 8% of the extractable organofluorine (a proxy for total PFAS) across years. Terminal PFAS still exceed regulatory limits by 2000-fold decades after AFFF use ceased. Measurements and numerical modeling show that sulfonamido precursors are retained in the vadose zone and their slow biotransformation into perfluoroalkyl sulfonates (half-life > 66 yr) sustains groundwater concentrations of perfluorobutane sulfonate (PFBS) and perfluorohexane sulfonate (PFHxS). The estimated PFAS reservoir in the vadose zone and modeled flux into groundwater suggest PFAS contamination above regulatory guidelines will persist for centuries without remediation.

Massachusetts↗