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At least 1,657 records · Page 92Linked to original sources
USGS2018

Association between degradation of pharmaceuticals and endocrine-disrupting compounds and microbial communities along a treated wastewater effluent gradient in Lake Mead

The role of microbial communities in the degradation of trace organic contaminants in the environment is little understood. In this study, the biotransformation potential of 27 pharmaceuticals and endocrine-disrupting compounds was examined in parallel with a characterization of the native microbial community in water samples from four sites variously impacted by urban run-off and wastewater discharge in Lake Mead, Nevada and Arizona, USA. Samples included relatively pristine Colorado River water at the upper end of the lake, nearly pure tertiary-treated municipal wastewater entering via the Las Vegas Wash, and waters of mixed influence (Las Vegas Bay and Boulder Basin), which represented a gradient of treated wastewater effluent impact. Microbial diversity analysis based on 16S rRNA gene censuses revealed the community at this site to be distinct from the less urban-impacted locations, although all sites were similar in overall diversity and richness. Similarly, Biolog EcoPlate assays demonstrated that the microbial community at Las Vegas Wash was the most metabolically versatile and active. Organic contaminants added as a mixture to laboratory microcosms were more rapidly and completely degraded in the most wastewater-impacted sites (Las Vegas Wash and Las Vegas Bay), with the majority exhibiting shorter half-lives than at the other sites or in a bacteriostatic control. Although the reasons for enhanced degradation capacity in the wastewater-impacted sites remain to be established, these data are consistent with the acclimatization of native microorganisms (either through changes in community structure or metabolic regulation) to effluent-derived trace contaminants. This study suggests that in urban, wastewater-impacted watersheds, prior exposure to organic contaminants fundamentally alters the structure and function of microbial communities, which in turn translates into greater potential for the natural attenuation of these compounds compared to more pristine sites.

Arizona, Nevada↗
USGS2022

Stable isotopes provide insight into sources and cycling of N compounds in the Sacramento-San Joaquin Delta, California, USA

River deltas and their diverse array of aquatic environments are increasingly impacted by anthropogenic inputs of nitrogen (N). These inputs can alter the N biogeochemistry of these systems and promote undesirable phenomena including harmful algae blooms and invasive aquatic macrophytes. To examine N sources and biogeochemical processes in the Sacramento-San Joaquin Delta, a river delta located in central California, USA, that is fed primarily by the Sacramento River, we utilized a multi-tracer approach that measured N species concentrations and stable isotope values monthly from April 2011 to November 2012 in samples collected from the channelized mainstem of the Sacramento River, two channelized distributaries of the Sacramento River, and the Cache Slough Complex, a network of Sacramento River tributaries and shallow water wetland habitat. We found that the Sacramento River and its channelized distributaries received N primarily in the form of NH 4 + from treated wastewater effluent and that NH 4 + was lost rapidly while NO 3 − was gained more slowly during subsequent downstream transit, driven by an array of biogeochemical processes whose identities could be constrained via examination of stable isotope values. The Cache Slough Complex, which was characterized by lower net flows and higher water residence times than the Sacramento River and its distributaries, received variable inputs of low conductivity water elevated in NH 4 + from the Sacramento River and higher conductivity water elevated in NO 3 − from landward tributaries. Deviations from expected conservative mixing of these sources were spatially variable but broadly indicative of local inputs of treated wastewater effluent NO 3 − , conversion of Sacramento River NH 4 + to NO 3 − via nitrification, uptake of NH 4 + and NO 3 − by phytoplankton, and remineralization of organic N. These findings highlight both the diversity in N dynamics in anthropogenically impacted river delta environments and the utility of a multi-tracer approach in constraining these processes in such complex systems.

California↗
USGS2004

Reconstruction of the Upper Jurassic Morrison Formation extinct ecosystem - A synthesis

A synthesis of recent and previous studies of the Morrison Formation and related beds, in the context of a conceptual climatic/hydrologic framework, permits reconstruction of the Late Jurassic dinosaurian ecosystem throughout the Western Interior of the United States and Canada. Climate models and geologic evidence indicate that a dry climate persisted in the Western Interior during the Late Jurassic. Early and Middle Kimmeridgian eolian deposits and Late Kimmeridgian alkaline, saline wetland/lacustrine deposits demonstrate that dryness persisted throughout the Kimmeridgian. Tithonian-age coal reflects lower evaporation rates associated with a slight cooling trend, but not a significant climate change. With a subtropical high over the Paleo-Pacific Ocean and atmospheric circulation generally toward the east, moisture carried by prevailing winds "rained out" progressively eastward, leaving the continental interior-and the Morrison depositional basin-dry. Within the basin, high evaporation rates associated with the southerly paleolatitude and greenhouse effects added to the dryness. Consequently, the two main sources of water-groundwater and surface water-originated outside the basin, through recharge of regional aquifers and streams that originated in the western uplands. Precipitation that fell west of the basin recharged aquifers that underlay the basin and discharged in wetlands and lakes in the distal, low-lying part of the basin. Precipitation west of the basin also fed intermittent and scarce perennial streams that flowed eastward. The streams were probably "losing" streams in their upstream reaches, and contributed to a locally raised water table. Elsewhere in the basin, where the floodplain intersected the water table, small lakes dotted the landscape. Seasonal storms, perhaps in part from the Paleo-Gulf of Mexico, brought some precipitation directly to the basin, although it was also subjected to "rain out" en route. Thus, meteoric input to the basin was appreciably less than groundwater and surface water contributions. The terrestrial Morrison ecosystem, which can be likened to a savannah, expanded with the northward retreat of the Late Jurassic Western Interior Seaway. The ecosystem was a complex mosaic, the components of which shifted through time. Riparian environments probably were the most diverse parts of the ecosystem, where a multi-storeyed canopy supported a diverse fauna, from insects to dinosaurs. Equable conditions also existed in wetlands, lakes, and elsewhere on the floodplain when seasonal rainfall brought an herbaceous groundcover to life. Eolian environments and alkaline, saline wetlands were inhospitable to life.Large herbivorous dinosaurs were adapted to this semi-arid landscape. Their size was an adaptive asset based on considerations of food requirements associated with a low metabolism and was also an advantage for migration during drought. Some of the large sauropods were adapted to browsing the higher vegetation associated with riparian environments; others to grazing the herbaceous groundcover on the floodplain and charophytes in the wetlands. The extensive distal wetlands may, in fact, have been refugia for some of these herbivores during the dry season and droughts. Extended periods of drought account for some of the dinosaur death assemblages; yet, the ecosystem could also sustain the most unusual life forms that ever roamed the Earth. ?? 2004 Elsevier B.V. All rights reserved.

Sedimentary Geology↗
USGS2011

Geological effects and implications of the 2010 tsunami along the central coast of Chile

Geological effects of the 2010 Chilean tsunami were quantified at five near-field sites along a 200 km segment of coast located between the two zones of predominant fault slip. Field measurements, including topography, flow depths, flow directions, scour depths, and deposit thicknesses, provide insights into the processes and morphological changes associated with tsunami inundation and return flow. The superposition of downed trees recorded multiple strong onshore and alongshore flows that arrived at different times and from different directions. The most likely explanation for the diverse directions and timing of coastal inundation combines (1) variable fault rupture and asymmetrical slip displacement of the seafloor away from the epicenter with (2) resonant amplification of coastal edge waves. Other possible contributing factors include local interaction of incoming flow and return flow and delayed wave reflection by the southern coast of Peru. Coastal embayments amplified the maximum inundation distances at two sites (2.4 and 2.6 km, respectively). Tsunami vertical erosion included scour and planation of the land surface, inundation scour around the bases of trees, and channel incision from return flow. Sheets and wedges of sand and gravel were deposited at all of the sites. Locally derived boulders up to 1 m in diameter were transported as much as 400 m inland and deposited as fields of dispersed clasts. The presence of lobate bedforms at one site indicates that at least some of the late-stage sediment transport was as bed load and not as suspended load. Most of the tsunami deposits were less than 25 cm thick. Exceptions were thick deposits near open-ocean river mouths where sediment supply was abundant. Human alterations of the land surface at most of the sites provided opportunities to examine some tsunami effects that otherwise would not have been possible, including flow histories, boulder dispersion, and vegetation controls on deposit thickness.

Central Coast↗
USGS2013

Effects of canopy tree species on belowground biogeochemistry in a lowland wet tropical forest

Tropical rain forests are known for their high biological diversity, but the effects of plant diversity on important ecosystem processes in this biome remain unclear. Interspecies differences in both the demand for nutrients and in foliar and litter nutrient concentrations could drive variations in both the pool sizes and fluxes of important belowground resources, yet our understanding of the effects and importance of aboveground heterogeneity on belowground biogeochemistry is poor, especially in the species-rich forests of the wet tropics. To investigate the effects of individual tree species on belowground biogeochemical processes, we used both field and laboratory studies to examine how carbon (C), nitrogen (N), and phosphorus (P) cycles vary under nine different canopy tree species – including three legume and six non-legume species – that vary in foliar nutrient concentrations in a wet tropical forest in southwestern Costa Rica. We found significant differences in belowground C, N and P cycling under different canopy tree species: total C, N and P pools in standing litter varied by species, as did total soil and microbial C and N pools. Rates of soil extracellular acid phosphatase activity also varied significantly among species and functional groups, with higher rates of phosphatase activity under legumes. In addition, across all tree species, phosphatase activity was significantly positively correlated with litter N/P ratios, suggesting a tight coupling between relative N and P inputs and resource allocation to P acquisition. Overall, our results suggest the importance of aboveground plant community composition in promoting belowground biogeochemical heterogeneity at relatively small spatial scales.

Soil Biology and Biochemistry↗
USGS2022

The influence of soil development on the depth distribution and structure of soil microbial communities.

Although it has been shown that the interaction of climate and time shape the dynamics of soil organic matter (SOM) storage and preservation in soil, the role of soil microbial communities in this dynamic remains unclear. Microbial communities are present throughout soil profiles and likely play critical roles in SOM and nutrient cycling, however the influence of other factors such as soil development (i.e., age) and the composition SOM on microbial community variation with depth has yet to be quantified. Improving our understanding of the relationship between soil development, soil depth, and microbial communities may provide insight to the critical role they play in cycling and preservation of SOM, as well as more mechanistic predictions of the response of soil communities to change, such as landscape-scale changes in available moisture or temperature regimes. Here we compare soils spanning a soil age by climate gradient (i.e., climo-chronosequence) to better understand the mechanisms which influence soil microbial community structure and the molecular composition of SOM. While we observed little depth-dependence in metrics of microbial community structure (i.e., composition, diversity, dissimilarity) across the range of soil development under a wetter climate, we found significant depth-dependent changes in community metrics under a drier climate, which became more pronounced as soils became older. This shift in bacterial and archaeal community structure and diversity is most apparent below a clay-rich argillic horizon formed in the older, drier soils. The molecular composition of SOM as measured by high resolution mass spectrometry (i.e., FTICR MS) also exhibited similar shifts in composition with soil depth and age. Our results highlight how soil moisture shapes the interaction of soil development, SOM, and microbial community composition. Differences in the moisture regime between our two study sites drives differences in biogeochemical depth gradients and subsequent variation in soil microbes and SOM. This suggests that knowledge of not just the pedogenic trajectory of soil development, but also the spatial position relative to distinct pedogenic features, are important for explaining variations in the depth-dependencies of microbial communities and associated SOM.

California↗
USGS2007

Sequence analysis of the msp4 gene of Anaplasma ovis strains

Anaplasma ovis (Rickettsiales: Anaplasmataceae) is a tick-borne pathogen of sheep, goats and wild ruminants. The genetic diversity of A. ovis strains has not been well characterized due to the lack of sequence information. In this study, we evaluated bighorn sheep ( Ovis canadensis ) and mule deer (Odocoileus hemionus ) from Montana for infection with A. ovis by serology and sequence analysis of the msp4 gene. Antibodies to Anaplasma spp. were detected in 37% and 39% of bighorn sheep and mule deer analyzed, respectively. Four new msp4 genotypes were identified. The A. ovis msp4 sequences identified herein were analyzed together with sequences reported previously for the characterization of the genetic diversity of A. ovis strains in comparison with other Anaplasma spp. The results of these studies demonstrated that although A. ovis msp4 genotypes may vary among geographic regions and between sheep and deer hosts, the variation observed was less than the variation observed between A. marginale and A. phagocytophilum strains. The results reported herein further confirm that A. ovis infection occurs in natural wild ruminant populations in Western United States and that bighorn sheep and mule deer may serve as wildlife reservoirs of A. ovis . ?? 2006.

Veterinary Microbiology↗
USGS2021

Complex evolutionary history of felid anelloviruses

Anellovirus infections are highly prevalent in mammals, however, prior to this study only a handful of anellovirus genomes had been identified in members of the Felidae family. Here we characterise anelloviruses in pumas ( Puma concolor ), bobcats ( Lynx rufus ), Canada lynx ( Lynx canadensis ), caracals ( Caracal caracal ) and domestic cats ( Felis catus ). The complete anellovirus genomes (n = 220) recovered from 149 individuals were diverse. ORF1 protein sequence similarity network analysis coupled with phylogenetic analysis, revealed two distinct clusters that are populated by felid-derived anellovirus sequences, a pattern mirroring that observed for the porcine anelloviruses. Of the two-felid dominant anellovirus groups, one includes sequences from bobcats, pumas, domestic cats and an ocelot, and the other includes sequences from caracals, Canada lynx, domestic cats and pumas. Coinfections of diverse anelloviruses appear to be common among the felids. Evidence of recombination, both within and between felid-specific anellovirus groups, supports a long coevolution history between host and virus.

Virology↗
USGS2021

A typology of drought decision making: Synthesizing across cases to understand drought preparedness and response actions

Drought is an inescapable reality in many regions, including much of the western United States. With climate change, droughts are predicted to intensify and occur more frequently, making the imperative for drought management even greater. Many diverse actors – including private landowners, business owners, scientists, non-governmental organizations (NGOs), and managers and policymakers within tribal, local, state, and federal government agencies – play multiple, often overlapping roles in preparing for and responding to drought. Managing water is, of course, one of the most important roles that humans play in both mitigating and responding to droughts; but, focusing only on “water managers” or “water management” fails to capture key elements related to the broader category of drought management. The respective roles played by those managing drought (as distinct from water managers), the interactions among them, and the consequences in particular contexts, are not well understood. Our team synthesized insights from 10 in-depth case studies to understand key facets of decision making about drought preparedness and response. We present a typology with four elements that collectively describe how decisions about drought preparedness and response are made (context and objective for a decision; actors responsible; choice being made or action taken; and how decisions interact with and influence other decisions). The typology provides a framework for system-level understanding of how and by whom complex decisions about drought management are made. Greater system-level understanding helps decision makers, program and research funders, and scientists to identify constraints to and opportunities for action, to learn from the past, and to integrate ecological impacts, thereby facilitating social learning among diverse participants in drought preparedness and response.

Colordao, Idaho, Montana, New Mexico, Oklahoma, Or↗
USGS2018

Temporal and spatial variation in pharmaceutical concentrations in an urban river system

Many studies have quantified pharmaceuticals in the environment, few however, have incorporated detailed temporal and spatial variability due to associated costs in terms of time and materials. Here, we target 33 physico-chemically diverse pharmaceuticals in a spatiotemporal exposure study into the occurrence of pharmaceuticals in the wastewater system and the Rivers Ouse and Foss (two diverse river systems) in the city of York, UK. Removal rates in two of the WWTPs sampled (a conventional activated sludge (CAS) and trickling filter plant) ranged from not eliminated (carbamazepine) to >99% (paracetamol). Data comparisons indicate that pharmaceutical exposures in river systems are highly variable regionally, in part due to variability in prescribing practices, hydrology, wastewater management, and urbanisation and that select annual median pharmaceutical concentrations observed in this study were higher than those previously observed in the European Union and Asia thus far. Significant spatial variability was found between all sites in both river systems, while seasonal variability was significant for 86% and 50% of compounds in the River Foss and Ouse, respectively. Seasonal variations in flow, in-stream attenuation, usage and septic effluent releases are suspected drivers behind some of the observed temporal exposure variability. When the data were used to evaluate a simple environmental exposure model for pharmaceuticals, mean ratios of predicted environmental concentrations (PECs), obtained using the model, to measured environmental concentrations (MECs) were 0.51 and 0.04 for the River Foss and River Ouse, respectively. Such PEC/MEC ratios indicate that the model underestimates actual concentrations in both river systems, but to a much greater extent in the larger River Ouse.

River Foss, River Ouse↗
USGS2018

Contaminants of emerging concern in urban stormwater: Spatiotemporal patterns and removal by iron-enhanced sand filters (IESFs)

Numerous contaminants of emerging concern (CECs) typically occur in urban rivers. Wastewater effluents are a major source of many CECs. Urban runoff (stormwater) is a major urban water budget component and may constitute another major CEC pathway. Yet, stormwater-based CEC field studies are rare. This research investigated 384 CECs in 36 stormwater samples in Minneapolis-St. Paul, Minnesota, USA. Nine sampling sites included three large stormwater conveyances (pipes) and three paired iron-enhanced sand filters (IESFs; untreated inlets and treated outlets). The 123 detected compounds included commercial-consumer compounds, veterinary and human pharmaceuticals, lifestyle and personal care compounds, pesticides, and others. Thirty-one CECs were detected in ≥50% of samples. Individual samples contained a median of 35 targeted CECs (range: 18–54). Overall, median concentrations were ≥10 ng/L for 25 CECs and ≥100 ng/L for 9 CECs. Ranked, hierarchical linear modeling indicated significant seasonal- and site type-based concentration variability for 53 and 30 CECs, respectively, with observed patterns corresponding to CEC type, source, usage, and seasonal hydrology. A primarily warm-weather, diffuse, runoff-based profile included many herbicides . A second profile encompassed winter and/or late summer samples enriched with some recalcitrant, hydrophobic compounds (e.g., PAHs), especially at pipes, suggesting conservative, less runoff-dependent sources (e.g., sediments). A third profile, indicative of mixed conservative/non-runoff, runoff, and/or atmospheric sources and transport that collectively affect a variety of conditions, included various fungicides, lifestyle, non-prescription, and commercial-consumer CECs. Generally, pipe sites had large, diverse land-use catchments, and showed more frequent detections of diverse CECs, but often at lower concentrations; while untreated sites (with smaller, more residential-catchments) demonstrated greater detections of “pseudo-persistent” and other ubiquitous or residentially-associated CECs. Although untreated stormwater transports an array of CECs to receiving waters, IESF treatment significantly removed concentrations of 14 (29%) of the 48 most detected CECs; for these, median removal efficiencies were 26%–100%. Efficient removal of some hydrophobic (e.g., PAHs, bisphenol A) and polar-hydrophilic (e.g., caffeine, nicotine) compounds indicated particulate-bound contaminant filtration and for certain dissolved contaminants, sorption.

Minnesota↗
USGS2026

The global proliferation of aquatic, benthic Microcoleus : Taxonomy, distribution, toxin production, ecology, and future directions

There have been sporadic reports of aquatic, benthic Microcoleus proliferations in freshwater rivers, lakes, and reservoirs for four decades, with reports increasing in frequency over the last twenty years, suggesting a possible rise in their global distribution, frequency, and intensity. Microcoleus can produce anatoxins which are neurotoxic, and ingestion of toxic mats has caused hundreds of dog fatalities and raised serious human and ecological health concerns. This review synthesizes and evaluates current knowledge on Microcoleus distribution, taxonomy, toxin production, toxicity, ecology, environmental drivers, and biotic interactions. Toxin-producing Microcoleus have been reported in at least 18 countries, though many regions have not conducted toxin testing, suggesting a broader but under-reported distribution. Proliferations occur across diverse habitats, including cobble-bedded streams, large sandy rivers, reservoirs, and lakes. Microcoleus proliferations also occur on macrophytes, both in lakes and rivers. Genomic analyses currently classify anatoxin-producing Microcoleus into distinct species, with all known anatoxin-producers isolated from freshwater ecosystems. Anatoxin concentrations vary widely over space and time, within and among waterbodies. While studies on environmental drivers remain limited, research in cobble-bedded rivers suggests that moderate enrichment of dissolved inorganic nitrogen and low dissolved reactive phosphorus concentrations in the water column promote proliferation. Metagenomic approaches have revealed unique nutrient acquisition and storage strategies used by Microcoleus . Key knowledge gaps remain around the environmental and ecological triggers of proliferation, toxin production, genomic diversity and microbial interactions. Addressing these gaps through coordinated, global studies using robust datasets and consistent methods is critical to improve prediction, monitoring, and mitigation of this increasingly widespread public and ecological health threat.

Water Research↗
USGS2024

How long have we been mistaken? Multi-tools shedding light into the systematics of the widespread deep-water genus Madrepora Linnaeus, 1758 (Scleractinia)

Deep-water coral reefs are found worldwide and harbor biodiversity levels that are comparable to their shallow-water counterparts. However, the genetic diversity and population structure of deep-water species remain poorly explored, and historical taxonomical issues still need to be resolved. Here we used microsatellite markers as well as ultraconserved elements (UCE) and exons to shed light on the population structure, genetic diversity, and phylogenetic position of the genus Madrepora , which contains M. oculata , one of the most widespread scleractinian species. Population structure of 107 samples from three Southwestern Atlantic sedimentary basins revealed the occurrence of a cryptic species, herein named M. piresae sp. nov. (authored by Kitahara, Capel and Zilberberg), which can be found in sympatry with M. oculata . Phylogeny reconstructions based on 134 UCEs and exon regions corroborated the population genetic data, with the recovery of two well-supported groups, and reinforced the polyphyly of the family Oculinidae. In order to better accommodate the genus Madrepora , while reducing taxonomical confusion associated with the name Madreporidae, we propose the monogeneric family Bathyporidae fam. nov. (authored by Kitahara, Capel, Zilberberg and Cairns). Our findings advance the knowledge on the widespread deep-water genus Madrepora , resolve a long-standing question regarding the phylogenetic position of the genus , and highlight the need of a worldwide review of the genus.

Molecular Phylogenetics and Evolution↗
USGS1997

Beryllium geochemistry in soils: Evaluation of 10Be/9Be ratios in authigenic minerals as a basis for age models

Soils contain a diverse and complex set of chemicals and minerals. Being an 'open system', both in the chemical and nuclear sense, soils have defied quantitative nuclear dating. However, based on the published studies of the cosmogenic atmospheric 10Be in soils, its relatively long half-life (1.5 Ma), and the fact that 10Be gets quickly incorporated in most soil minerals, this radionuclide appears to be potentially the most useful for soil dating. We therefore studied the natural variations in the specific activities of 10Be with respect to the isotope 9Be in mineral phases in eight profiles of diverse soils from temperate to tropical climatic regimes and evaluated the implications of the data for determining the time of formation of soil minerals, following an earlier suggestion [Lal et al., 1991. Development of cosmogenic nuclear methods for the study of soil erosion and formation rates. Current Sci. 61, 636-639.]. We find that the 10Be/9Be ratios in both bulk soils and in the authigenic mineral phases are confined within a narrower range than in 10Be concentrations. Also, the highest 10Be/9Be ratios in authigenic minerals are observed at the soil-rock interface as predicted by the model. We present model 10Be/9Be ages of the B-horizon and the corresponding soil formation rates for several soil profiles. The present study demonstrates that the 10Be/9Be ratios in the authigenic phases, e.g. clay and Fe-hydroxides, can indeed be used for obtaining useful model ages for soils younger than 10-15 Ma. However, the present work has to be pushed considerably further, to take into account more realistic age models in which, for instance, downward transport of 10Be and clays, and in-situ dissolution of clay minerals at depths, altering the 10Be/9Be ratios of the acidic solutions, are included. We show that in the case of younger soils (< 1 Ma) studied here, their 10Be inventories and 10Be/9Be ratios have been significantly disturbed possibly by mixing with transported soils. ?? 1997 Elsevier Science B.V.

Chemical Geology↗
USGS2000

Alachlor transformation patterns in aquatic field mesocosms under variable oxygen and nutrient conditions

Alachlor is one of the most commonly used herbicides in both Europe and North America. Because of its toxic properties, its fate and attenuation in natural waters is practically important. This paper assesses factors that affect alachlor decay rate in aquatic systems using field-scale experimental units. In particular, we used field mesocosms (11.3 m3 outdoor fiberglass tanks) to examine the affect of oxygen level and other factors on decay rate in water columns. This is one of the first studies ever performed where diverse water column conditions have been successfully simulated using common mesocosm-scale facilities. Four treatments were assessed, including aerobic systems (aerobic); low nutrient, oxygen-stratified systems (stratified-LN); moderate nutrient, oxygen-stratified systems (stratified-HN); and anaerobic systems (anaerobic). The lowest half-lives were observed in the anaerobic units (9.7 days) followed by the aerobic (21 days), stratified-HN (22 days), and stratified-LN (46 days) units. Our results indicate that alachlor is transformed most rapidly under anaerobic conditions, although the ambient phosphorus level also appears to influence decay rate. In this study, two common alachlor breakdown products, ethane sulfonic acid (ESA) and oxanilic acid, were also monitored. Oxanilic acid was produced in greater quantities than ESA under all treatments with the highest levels being produced in the stratified-HN units. In general, our results suggest that previous laboratory data, which indicated that high rates of alachlor decay can occur under oxygen-free methanogenic conditions, is translatable to field-scale applications. Copyright (C) 2000 Elsevier Science Ltd.Alachlor is one of the most commonly used herbicides in both Europe and North America. Because of its toxic properties, its fate and attenuation in natural waters is practically important. This paper assesses factors that affect alachlor decay rate in aquatic systems using field-scale experimental units. In particular, we used field mesocosms (11.3 m3 outdoor fiberglass tanks) to examine the affect of oxygen level and other factors on decay rate in water columns. This is one of the first studies ever performed where diverse water column conditions have been successfully simulated using common mesocosm-scale facilities. Four treatments were assessed, including aerobic systems (aerobic); low nutrient, oxygen-stratified systems (stratified-LN); moderate nutrient, oxygen-stratified systems (stratified-HN); and anaerobic systems (anaerobic). The lowest half-lives were observed in the anaerobic units (9.7 days) followed by the aerobic (21 days), stratified-HN (22 days), and stratified-LN (46 days) units. Our results indicate that alachlor is transformed most rapidly under anaerobic conditions, although the ambient phosphorus level also appears to influence decay rate. In this study, two common alachlor breakdown products, ethane sulfonic acid (ESA) and oxanilic acid, were also monitored. Oxanilic acid was produced in greater quantities than ESA under all treatments with the highest levels being produced in the stratified-HN units. In general, our results suggest that previous laboratory data, which indicated that high rates of alachlor decay can occur under oxygen-free methanogenic conditions, is translatable to field-scale applications.Aquatic field mesocosms were used to examine the influence of DO concentration and the presence of nutrients on alachlor transformation. Four treatments were used: wholly aerobic water columns, thermally and oxygen stratified water columns with low nutrient levels, stratified water columns with moderate nutrient levels, and wholly anaerobic water columns. The anaerobic treatment produced the highest rate of alachlor decay, followed by the aerobic and stratified treatments. The lowest decay rate occurred in the aerobic, low-nutrient stratified units.

Water Research↗
USGS2002

Place vs. time and vegetational persistence: A comparison of four tropical mires from the Illinois Basin during the height of the Pennsylvanian Ice Age

Coal balls were collected from four coal beds in the southeastern part of the Illinois Basin. Collections were made from the Springfield, Herrin, and Baker coals in western Kentucky, and from the Danville Coal in southwestern Indiana. These four coal beds are among the principal mineable coals of the Illinois Basin and belong to the Carbondale and Shelburn Formations of late Middle Pennsylvanian age. Vegetational composition was analyzed quantitatively. Coal-ball samples from the Springfield, Herrin, and Baker are dominated by the lycopsid tree Lepidophloios, with lesser numbers of Psaronius tree ferns, medullosan pteridosperms, and the lycopsid trees Synchysidendron and Diaphorodendron. This vegetation is similar to that found in the Springfield and Herrin coals elsewhere in the Illinois Basin, as reported in previous studies. The Danville coal sample, which is considerably smaller than the others, is dominated by Psaronius with the lycopsids Sigillaria and Synchysidendron as subdominants. Coal balls from the Springfield coal were collected in zones directly from the coal bed and their zone-by-zone composition indicates three to four distinct plant assemblages. The other coals were analyzed as whole-seam random samples, averaging the landscape composition of the parent mire environments. This analysis indicates that these coals, separated from each other by marine and terrestrial-clastic deposits, have essentially the same floristic composition and, thus, appear to represent a common species pool that persisted throughout the late Middle Pennsylvanian, despite changes in baselevel and climate attendant the glacial interglacial cyclicity of the Pennsylvanian ice age. Patterns of species abundance and diversity are much the same for the Springfield, Herrin, and Baker, although each coal, both in the local area sampled, and regionally, has its own paleobotanical peculiarities. Despite minor differences, these coals indicate a high degree of recurrence of assemblage and landscape organization. The Danville departs dramatically from the dominance-diversity composition of the older coals, presaging patterns of tree-fern and Sigillaria dominance of Late Pennsylvanian coals of the eastern United States, but, nonetheless, built on a species pool shared with the older coals. ?? 2002 Elsevier Science B.V. All rights reserved.

International Journal of Coal Geology↗
USGS1999

Reconstructing late Quaternary deep-water masses in the eastern Arctic Ocean using benthonic Ostracoda

The distribution of Ostracoda in three long cores from the deep eastern Arctic Ocean was studied to determine the palaeoceanographical history of the Eurasian Basin during the late Quaternary. The samples for this study were obtained from the Lomonosov Ridge, Morris Jesup Rise and Yermak Plateau during the Arctic 91 expedition. Ostracoda previously studied in coretops at the same sites as the present study have shown that individual species have a strong association with different water masses and bathymetry. Throughout the late Quaternary, cores exhibit ostracod-rich layers separated by barren intervals. On the basis of biostratigraphical, isotopic and palaeomagnetic data the fossiliferous levels are interpreted as representing interglacial stages. The twenty most significant species were selected for subsequent quantitative investigation using Cluster and Factor analyses, in order to determine similarity and variance between the assemblages. An additional statistical method employing Modern Analogues and the Squared Chord Distance dissimilarity coefficient was utilized to compare the present late Quaternary fossil samples with a modern Arctic database. The results reveal a major faunal division within the Arctic Ocean Deep Water (AODW). Highly abundant and diverse assemblages within the cores were found to group and have good analogues with the Recent bathyal depth (1000-2500 m) upper AODW assemblages. Conversely, assemblages with low abundance and diversity correlate well with abyssal depth (> 3000 m) lower AODW assemblages. The palaeoceanographical history is complicated by the influence of adjacent water masses such as Canada Basin Deep Water (CBDW), Greenland Sea Deep Water (GSDW) and most importantly, Arctic Intermediate Water (AIW), which all had an influence on the ostracod assemblages during the late Quaternary. An enhanced flow of warm saline AIW into the Eurasian Basin results in species-rich upper AODW assemblages having good analogues down to 2750 m in the water column. In contrast, lower AODW assemblages influenced by cold well-oxygenated GSDW give analogues at depths as shallow as 1000 m. The faunal changes are the consequence of rapid climatic fluctuations in the eastern Arctic Ocean during the late Quaternary that are intrinsically linked to palaeoceanographical alternations in warm and cold current inflow from adjacent basins.

Conference Paper↗
USGS2002

Development of oak plantations established for wildlife

Extensive areas that are currently in agricultural production within the Mississippi Alluvial Valley are being restored to bottomland hardwood forests. Oaks (Quercus sp.), sown as seeds (acorns) or planted as seedlings, are the predominant trees established on most afforested sites. To compare stand development and natural invasion on sites afforested by planting seedlings or by sowing acorns, we sampled woody vegetation on ten 14- to 18-year-old oak plantations established to provide wildlife habitat. Stem densities of about 900 oaks/ha were comparable between stands established by sowing 4000 acorns/ha and stands established by planting 900 seedlings/ha. Densities of oaks in stands established from seedlings increased 38% from densities detected when these stands were 4- to 8-year-old. Densities of oaks established from field-sown acorns increased >100% during this same 10-year span. Oaks that were planted as seedlings were larger than those established from acorns, but trees resulting from either afforestation method were larger than trees naturally colonizing these sites. Natural invasion of woody species varied greatly among afforested sites, but was greater and more diverse on sites sown with acorns. Afforested stands were dominated by planted species, whereas naturally invading species were rare among dominant canopy trees. When afforestation objectives are primarily to provide wildlife habitat, we recommend, sowing acorns rather than planting seedlings. Additionally, planting fewer seeds or seedlings, diversifying the species planted, and leaving non-planted gaps will increase diversity of woody species and promote a more complex forest structure that enhances the suitability of afforested sites for wildlife.

Forest Ecology and Management↗